#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:06:29 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179362 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/59/4325904.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4325904
loop_
_publ_author_name
'Curtis M. Zaleski'
'Choong-Sun Lim'
'Annabel D. Cutland-Van Noord'
'Jeff W. Kampf'
'Vincent L. Pecoraro'
_publ_section_title
;
 Effects of the Central Lanthanide Ion Crystal Radius on the
 15-MCCuII(N)pheHA-5 Structure
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7707
_journal_page_last               7717
_journal_paper_doi               10.1021/ic200740h
_journal_volume                  50
_journal_year                    2011
_chemical_absolute_configuration ad
_chemical_formula_sum            'C90 H130 Cu10 Eu2 N24 O48'
_chemical_formula_weight         3255.50
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           18
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.000(6)
_cell_angle_beta                 90.000(7)
_cell_angle_gamma                90.000(8)
_cell_formula_units_Z            4
_cell_length_a                   24.619(4)
_cell_length_b                   35.302(6)
_cell_length_c                   14.764(3)
_cell_measurement_reflns_used    6893
_cell_measurement_temperature    158(2)
_cell_measurement_theta_max      24.61
_cell_measurement_theta_min      2.36
_cell_volume                     12831(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      158(2)
_diffrn_detector_area_resol_mean 0.80
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0825
_diffrn_reflns_av_sigmaI/netI    0.0408
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       44
_diffrn_reflns_limit_k_min       -44
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            159114
_diffrn_reflns_theta_full        26.47
_diffrn_reflns_theta_max         26.47
_diffrn_reflns_theta_min         1.38
_exptl_absorpt_coefficient_mu    2.678
_exptl_absorpt_correction_T_max  0.675
_exptl_absorpt_correction_T_min  0.419
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, Acta Cryst. (1995) A51 33-38.'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.687
_exptl_crystal_description       block
_exptl_crystal_F_000             6552
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.892
_refine_diff_density_min         -0.845
_refine_diff_density_rms         0.151
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.011(15)
_refine_ls_extinction_coef       0.00016(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1577
_refine_ls_number_reflns         26327
_refine_ls_number_restraints     72
_refine_ls_restrained_S_all      1.084
_refine_ls_R_factor_all          0.0925
_refine_ls_R_factor_gt           0.0663
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1299P)²+7.4160P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1807
_refine_ls_wR_factor_ref         0.2040
_reflns_number_gt                18904
_reflns_number_total             26327
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic200740h_si_001_08.cif
_cod_data_source_block           Eu-2
_cod_original_cell_volume        12832(4)
_cod_database_code               4325904
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.093235(19) 0.401067(14) 0.10704(4) 0.05163(14) Uani 1 1 d .
Eu2 Eu 0.01875(2) 0.094548(15) 0.35172(4) 0.05649(15) Uani 1 1 d .
Cu1 Cu 0.04391(6) 0.38891(5) -0.14166(12) 0.0742(4) Uani 1 1 d .
Cu2 Cu 0.21251(5) 0.36515(3) -0.03426(8) 0.0483(3) Uani 1 1 d .
Cu3 Cu 0.22394(5) 0.41625(4) 0.25158(10) 0.0613(4) Uani 1 1 d .
Cu4 Cu 0.04861(5) 0.43262(4) 0.34432(11) 0.0606(3) Uani 1 1 d .
Cu5 Cu -0.05467(6) 0.44058(5) 0.08840(13) 0.0814(5) Uani 1 1 d .
Cu6 Cu 0.07321(7) 0.08421(6) 0.10623(14) 0.0982(7) Uani 1 1 d .
Cu7 Cu -0.10243(5) 0.10862(4) 0.18647(9) 0.0557(3) Uani 1 1 d .
Cu8 Cu -0.11354(5) 0.09952(4) 0.49424(8) 0.0523(3) Uani 1 1 d .
Cu9 Cu 0.05801(5) 0.08305(5) 0.60503(12) 0.0714(4) Uani 1 1 d .
Cu10 Cu 0.17384(6) 0.07253(4) 0.36633(15) 0.0888(6) Uani 1 1 d .
O1 O 0.0923(3) 0.3607(3) -0.2152(6) 0.073(2) Uani 1 1 d .
O2 O 0.0991(3) 0.3851(2) -0.0504(6) 0.067(2) Uani 1 1 d .
O3 O 0.2785(3) 0.3590(2) 0.0351(4) 0.0501(16) Uani 1 1 d .
O4 O 0.1883(2) 0.3959(2) 0.0660(4) 0.0482(15) Uani 1 1 d .
O5 O 0.2091(3) 0.4190(4) 0.3817(7) 0.114(5) Uani 1 1 d .
O6 O 0.1465(3) 0.4182(2) 0.2385(6) 0.068(2) Uani 1 1 d .
O7 O -0.0263(3) 0.4516(2) 0.3516(7) 0.070(2) Uani 1 1 d .
O8 O 0.0368(3) 0.4365(2) 0.2162(6) 0.063(2) Uani 1 1 d .
O9 O -0.0910(4) 0.4288(3) -0.0282(8) 0.099(4) Uani 1 1 d .
O10 O 0.0063(3) 0.4152(2) 0.0339(6) 0.067(2) Uani 1 1 d .
O11 O 0.0225(4) 0.1017(4) 0.0150(7) 0.104(4) Uani 1 1 d .
O12 O 0.0145(3) 0.0935(2) 0.1892(6) 0.068(2) Uani 1 1 d .
O13 O -0.1692(3) 0.1227(2) 0.2442(5) 0.0564(17) Uani 1 1 d .
O14 O -0.0743(3) 0.0994(2) 0.3082(5) 0.0554(17) Uani 1 1 d .
O15 O -0.1020(2) 0.1032(2) 0.6231(5) 0.0534(16) Uani 1 1 d .
O16 O -0.0366(2) 0.0914(2) 0.4869(5) 0.0549(17) Uani 1 1 d .
O17 O 0.1348(3) 0.0839(3) 0.6282(7) 0.097(4) Uani 1 1 d .
O18 O 0.0774(3) 0.0848(2) 0.4785(6) 0.064(2) Uani 1 1 d .
O19 O 0.2102(5) 0.0720(3) 0.2511(11) 0.115(5) Uani 1 1 d .
O20 O 0.1088(3) 0.0754(2) 0.2955(7) 0.079(3) Uani 1 1 d .
O100 O 0.1107(4) 0.4633(2) 0.0436(6) 0.074(2) Uani 1 1 d .
O101 O 0.1168(6) 0.3332(3) 0.1196(10) 0.130(5) Uani 1 1 d .
O102 O 0.0463(5) 0.3524(3) 0.1959(11) 0.120(4) Uani 1 1 d .
O103 O 0.0702(10) 0.2883(4) 0.1984(13) 0.183(8) Uani 1 1 d .
O104 O 0.0195(4) 0.3635(3) 0.3695(9) 0.111(4) Uani 1 1 d .
O200 O 0.0060(4) 0.03233(12) 0.3451(6) 0.070(2) Uani 1 1 d D
O201 O 0.0000 0.0000 0.4807(16) 0.22(4) Uani 0.50 2 d SPD
O202 O -0.0017(4) 0.1618(2) 0.3811(9) 0.097(3) Uani 1 1 d .
O203 O 0.0487(4) 0.2095(2) 0.3526(7) 0.076(2) Uani 1 1 d .
O205 O -0.1375(6) 0.0406(4) 0.1745(11) 0.141(6) Uani 1 1 d .
O206 O -0.1329(6) 0.0314(3) 0.5174(9) 0.119(4) Uani 1 1 d .
O207 O 0.0747(4) 0.1514(3) 0.3250(8) 0.089(3) Uani 1 1 d .
O303 O 0.2090(8) 0.4182(5) -0.2335(13) 0.166(7) Uani 1 1 d .
O304 O 0.2570(13) 0.4668(8) -0.2071(19) 0.296(18) Uani 1 1 d .
O305 O 0.2559(4) 0.4224(3) -0.1063(7) 0.082(3) Uani 1 1 d .
O306 O 0.0000 0.5000 0.0074(10) 0.082(4) Uani 1 2 d S
O307 O 0.2177(5) 0.4824(3) 0.0037(8) 0.100(3) Uani 1 1 d .
O308 O -0.0400(7) 0.3793(5) 0.5586(10) 0.162(7) Uani 1 1 d .
O309 O 0.1629(9) 0.0841(5) 0.8092(12) 0.181(8) Uani 1 1 d .
N310 N 0.0000 0.5000 -0.0709(18) 0.112(7) Uani 1 2 d S
O311 O 0.3680(6) 0.0726(5) 0.4199(15) 0.182(8) Uani 1 1 d .
O312 O 0.2558(6) 0.4717(4) -0.4058(10) 0.125(4) Uani 1 1 d .
O313 O 0.3137(6) 0.0438(5) 0.2643(13) 0.162(7) Uani 1 1 d .
O314 O 0.2092(13) 0.5008(5) -0.5655(15) 0.241(12) Uani 1 1 d .
O315 O 0.4233(9) 0.0181(4) 0.5040(13) 0.201(10) Uani 1 1 d .
O316 O 0.1388(13) -0.0046(4) 0.3408(11) 0.228(11) Uani 1 1 d .
O317 O -0.1831(7) 0.4587(7) -0.0776(14) 0.213(11) Uani 1 1 d .
O300 O 0.3573(7) 0.4487(4) 0.1017(14) 0.162(7) Uani 1 1 d .
O302 O -0.2509(7) 0.4741(7) 0.1560(17) 0.236(13) Uani 1 1 d .
O318 O -0.0446(9) 0.5085(6) -0.1037(13) 0.224(13) Uani 1 1 d .
O319 O 0.0894(11) 0.0719(9) 0.8754(13) 0.248(12) Uani 1 1 d .
N1 N 0.2291(4) 0.3353(3) -0.1499(6) 0.060(2) Uani 1 1 d .
H1A H 0.2543 0.3478 -0.1826 0.072 Uiso 1 1 calc R
H1B H 0.2428 0.3125 -0.1351 0.072 Uiso 1 1 calc R
N2 N 0.1414(4) 0.3658(3) -0.0853(6) 0.066(2) Uani 1 1 d .
N3 N 0.3057(3) 0.4081(2) 0.2457(6) 0.0485(18) Uani 1 1 d .
H3C H 0.3224 0.4286 0.2222 0.058 Uiso 1 1 calc R
H3D H 0.3193 0.4036 0.3012 0.058 Uiso 1 1 calc R
N4 N 0.2293(3) 0.3958(2) 0.1316(6) 0.0508(19) Uani 1 1 d .
N5 N 0.0709(4) 0.4308(4) 0.4720(8) 0.081(3) Uani 1 1 d .
H5A H 0.0597 0.4522 0.4995 0.098 Uiso 1 1 calc R
H5B H 0.0541 0.4112 0.4990 0.098 Uiso 1 1 calc R
N6 N 0.1242(4) 0.4216(3) 0.3247(7) 0.069(3) Uani 1 1 d .
N7 N -0.1120(5) 0.4697(5) 0.1574(9) 0.122(6) Uani 1 1 d .
H7A H -0.1079 0.4947 0.1475 0.147 Uiso 1 1 calc R
H7B H -0.1452 0.4628 0.1382 0.147 Uiso 1 1 calc R
N8 N -0.0165(4) 0.4465(3) 0.1987(8) 0.071(3) Uani 1 1 d .
N9 N -0.0158(5) 0.4033(4) -0.2254(9) 0.102(4) Uani 1 1 d .
H9A H -0.0081 0.4256 -0.2520 0.122 Uiso 1 1 calc R
H9B H -0.0193 0.3857 -0.2690 0.122 Uiso 1 1 calc R
N10 N -0.0038(4) 0.4088(3) -0.0577(8) 0.069(3) Uani 1 1 d .
N11 N -0.1215(4) 0.1115(3) 0.0538(6) 0.073(3) Uani 1 1 d .
H11A H -0.1360 0.0894 0.0355 0.088 Uiso 1 1 calc R
H11B H -0.1462 0.1299 0.0447 0.088 Uiso 1 1 calc R
N12 N -0.0305(4) 0.1020(3) 0.1381(7) 0.064(2) Uani 1 1 d .
N13 N -0.1940(3) 0.1087(3) 0.4843(7) 0.069(3) Uani 1 1 d .
H13A H -0.2117 0.0867 0.4930 0.082 Uiso 1 1 calc R
H13B H -0.2044 0.1248 0.5282 0.082 Uiso 1 1 calc R
N14 N -0.1181(3) 0.1051(2) 0.3680(5) 0.0499(19) Uani 1 1 d .
N15 N 0.0258(4) 0.0766(3) 0.7298(8) 0.074(3) Uani 1 1 d .
H15A H 0.0218 0.0518 0.7421 0.088 Uiso 1 1 calc R
H15B H 0.0483 0.0866 0.7714 0.088 Uiso 1 1 calc R
N16 N -0.0174(3) 0.0880(3) 0.5744(6) 0.057(2) Uani 1 1 d .
N17 N 0.2343(4) 0.0631(3) 0.4520(11) 0.098(5) Uani 1 1 d .
H17A H 0.2406 0.0380 0.4561 0.117 Uiso 1 1 calc R
H17B H 0.2648 0.0743 0.4315 0.117 Uiso 1 1 calc R
N18 N 0.1350(4) 0.0807(3) 0.4747(10) 0.081(4) Uani 1 1 d .
N19 N 0.1368(5) 0.0705(4) 0.0312(11) 0.121(6) Uani 1 1 d .
H19A H 0.1333 0.0465 0.0114 0.146 Uiso 1 1 calc R
H19B H 0.1386 0.0858 -0.0173 0.146 Uiso 1 1 calc R
N20 N 0.1232(4) 0.0742(3) 0.2031(9) 0.083(4) Uani 1 1 d .
N100 N 0.0774(7) 0.3264(3) 0.1701(10) 0.100(5) Uani 1 1 d .
N200 N 0.0403(4) 0.1756(3) 0.3551(7) 0.057(2) Uani 1 1 d .
N201 N 0.0000 0.0000 0.3909(15) 0.16(2) Uani 1 2 d SPD
N301 N 0.2423(9) 0.4309(5) -0.180(2) 0.165(10) Uani 1 1 d .
C1 C 0.1368(5) 0.3544(3) -0.1681(7) 0.062(3) Uani 1 1 d .
C2 C 0.1796(5) 0.3301(4) -0.2050(8) 0.064(3) Uani 1 1 d .
H2 H 0.1870 0.3373 -0.2680 0.077 Uiso 1 1 calc R
C3 C 0.1586(6) 0.2896(4) -0.2016(9) 0.074(3) Uani 1 1 d .
H3A H 0.1244 0.2881 -0.2341 0.089 Uiso 1 1 calc R
H3B H 0.1516 0.2827 -0.1390 0.089 Uiso 1 1 calc R
C4 C 0.1985(5) 0.2611(3) -0.2427(7) 0.068(3) Uani 1 1 d D
C5 C 0.2070(5) 0.2581(3) -0.3352(7) 0.060(3) Uani 1 1 d D
H5 H 0.1888 0.2738 -0.3757 0.072 Uiso 1 1 calc R
C6 C 0.2442(6) 0.2302(4) -0.3665(12) 0.121(8) Uani 1 1 d D
H6 H 0.2515 0.2272 -0.4279 0.145 Uiso 1 1 calc R
C7 C 0.2694(9) 0.2075(6) -0.3012(16) 0.131(7) Uani 1 1 d D
H7 H 0.2956 0.1901 -0.3196 0.157 Uiso 1 1 calc R
C8 C 0.2572(10) 0.2100(7) -0.2148(16) 0.160(9) Uani 1 1 d D
H8 H 0.2742 0.1938 -0.1740 0.192 Uiso 1 1 calc R
C9 C 0.2186(8) 0.2370(5) -0.1814(12) 0.128(7) Uani 1 1 d D
H9 H 0.2081 0.2376 -0.1209 0.154 Uiso 1 1 calc R
C10 C 0.2717(4) 0.3769(3) 0.1103(6) 0.047(2) Uani 1 1 d .
C11 C 0.3132(4) 0.3743(3) 0.1855(6) 0.049(2) Uani 1 1 d .
H11 H 0.3501 0.3740 0.1604 0.059 Uiso 1 1 calc R
C12 C 0.3034(4) 0.3390(3) 0.2442(6) 0.050(2) Uani 1 1 d .
H12A H 0.3330 0.3369 0.2873 0.059 Uiso 1 1 calc R
H12B H 0.2703 0.3428 0.2785 0.059 Uiso 1 1 calc R
C13 C 0.2986(5) 0.3013(3) 0.1936(7) 0.056(3) Uani 1 1 d .
C14 C 0.2454(6) 0.2916(4) 0.1551(9) 0.077(4) Uani 1 1 d .
H14 H 0.2156 0.3075 0.1623 0.093 Uiso 1 1 calc R
C15 C 0.2412(9) 0.2577(5) 0.1074(11) 0.102(6) Uani 1 1 d .
H15 H 0.2078 0.2505 0.0838 0.122 Uiso 1 1 calc R
C16 C 0.2840(12) 0.2354(4) 0.0951(11) 0.114(8) Uani 1 1 d .
H16 H 0.2801 0.2128 0.0633 0.137 Uiso 1 1 calc R
C17 C 0.3329(11) 0.2451(5) 0.1280(13) 0.122(8) Uani 1 1 d .
H17 H 0.3622 0.2291 0.1175 0.147 Uiso 1 1 calc R
C18 C 0.3417(6) 0.2796(4) 0.1790(8) 0.075(4) Uani 1 1 d .
H18 H 0.3759 0.2862 0.2006 0.090 Uiso 1 1 calc R
C19 C 0.1577(5) 0.4216(5) 0.3905(10) 0.086(4) Uani 1 1 d .
C20 C 0.1318(5) 0.4267(5) 0.4860(10) 0.089(5) Uani 1 1 d .
H20 H 0.1459 0.4501 0.5132 0.107 Uiso 1 1 calc R
C21 C 0.1463(5) 0.3931(5) 0.5477(9) 0.086(5) Uani 1 1 d .
H21A H 0.1854 0.3931 0.5560 0.103 Uiso 1 1 calc R
H21B H 0.1301 0.3978 0.6065 0.103 Uiso 1 1 calc R
C22 C 0.1308(5) 0.3559(5) 0.5201(8) 0.085(5) Uani 1 1 d .
C23 C 0.0894(6) 0.3365(6) 0.5653(10) 0.102(6) Uani 1 1 d .
H23 H 0.0735 0.3479 0.6154 0.122 Uiso 1 1 calc R
C24 C 0.0699(9) 0.2989(5) 0.5375(11) 0.104(6) Uani 1 1 d .
H24 H 0.0433 0.2856 0.5689 0.125 Uiso 1 1 calc R
C25 C 0.0939(8) 0.2859(6) 0.4636(12) 0.103(5) Uani 1 1 d .
H25 H 0.0810 0.2629 0.4413 0.124 Uiso 1 1 calc R
C26 C 0.1349(8) 0.3021(6) 0.4166(10) 0.108(6) Uani 1 1 d .
H26 H 0.1500 0.2898 0.3669 0.129 Uiso 1 1 calc R
C27 C 0.1542(5) 0.3371(4) 0.4432(8) 0.073(3) Uani 1 1 d .
H27 H 0.1824 0.3485 0.4114 0.087 Uiso 1 1 calc R
C28 C -0.0452(5) 0.4537(3) 0.2729(11) 0.074(4) Uani 1 1 d .
C29 C -0.1065(6) 0.4617(5) 0.2525(11) 0.112(7) Uani 1 1 d .
H29 H -0.1171 0.4845 0.2860 0.134 Uiso 1 1 calc R
C30 C -0.1426(5) 0.4291(5) 0.2845(11) 0.095(4) Uani 1 1 d .
H30A H -0.1347 0.4241 0.3477 0.114 Uiso 1 1 calc R
H30B H -0.1803 0.4371 0.2806 0.114 Uiso 1 1 calc R
C31 C -0.1360(5) 0.3939(4) 0.2330(10) 0.089(4) Uani 1 1 d D
C32 C -0.1674(6) 0.3858(5) 0.1573(10) 0.106(5) Uani 1 1 d D
H32 H -0.1942 0.4029 0.1399 0.127 Uiso 1 1 calc R
C33 C -0.1599(9) 0.3525(6) 0.1061(14) 0.150(8) Uani 1 1 d D
H33 H -0.1812 0.3463 0.0563 0.180 Uiso 1 1 calc R
C34 C -0.1171(10) 0.3297(6) 0.1374(16) 0.155(9) Uani 1 1 d D
H34 H -0.1093 0.3073 0.1067 0.186 Uiso 1 1 calc R
C35 C -0.0879(9) 0.3386(6) 0.2081(17) 0.150(8) Uani 1 1 d D
H35 H -0.0586 0.3230 0.2219 0.180 Uiso 1 1 calc R
C36 C -0.0974(9) 0.3707(6) 0.2665(15) 0.152(8) Uani 1 1 d D
H36 H -0.0791 0.3750 0.3207 0.183 Uiso 1 1 calc R
C37 C -0.0531(6) 0.4159(4) -0.0776(12) 0.084(4) Uani 1 1 d .
C38 C -0.0663(5) 0.4064(6) -0.1741(13) 0.111(6) Uani 1 1 d .
H38 H -0.0884 0.4267 -0.1999 0.133 Uiso 1 1 calc R
C39 C -0.0958(7) 0.3678(5) -0.1888(13) 0.114(6) Uani 1 1 d .
H39A H -0.1289 0.3679 -0.1531 0.137 Uiso 1 1 calc R
H39B H -0.1064 0.3662 -0.2520 0.137 Uiso 1 1 calc R
C40 C -0.0642(7) 0.3325(6) -0.1652(17) 0.124(8) Uani 1 1 d .
C41 C -0.0480(9) 0.3092(7) -0.2354(19) 0.136(8) Uani 1 1 d .
H41 H -0.0580 0.3153 -0.2944 0.163 Uiso 1 1 calc R
C42 C -0.0194(8) 0.2793(5) -0.2208(14) 0.106(5) Uani 1 1 d .
H42 H -0.0127 0.2631 -0.2693 0.128 Uiso 1 1 calc R
C43 C 0.0015(9) 0.2699(8) -0.1387(19) 0.141(8) Uani 1 1 d .
H43 H 0.0248 0.2494 -0.1320 0.169 Uiso 1 1 calc R
C44 C -0.0132(8) 0.2924(6) -0.064(2) 0.130(8) Uani 1 1 d .
H44 H -0.0009 0.2858 -0.0069 0.156 Uiso 1 1 calc R
C45 C -0.0469(7) 0.3252(5) -0.0753(15) 0.114(7) Uani 1 1 d .
H45 H -0.0566 0.3407 -0.0269 0.137 Uiso 1 1 calc R
C46 C -0.0229(6) 0.1071(5) 0.0523(9) 0.085(4) Uani 1 1 d .
C47 C -0.0716(6) 0.1198(5) 0.0008(8) 0.092(5) Uani 1 1 d .
H47 H -0.0732 0.1060 -0.0568 0.110 Uiso 1 1 calc R
C48 C -0.0692(6) 0.1627(5) -0.0187(8) 0.081(4) Uani 1 1 d .
H48A H -0.0342 0.1685 -0.0453 0.097 Uiso 1 1 calc R
H48B H -0.0968 0.1687 -0.0633 0.097 Uiso 1 1 calc R
C49 C -0.0775(6) 0.1880(4) 0.0627(8) 0.085(5) Uani 1 1 d D
C50 C -0.1291(7) 0.2029(4) 0.0735(10) 0.094(5) Uani 1 1 d D
H50 H -0.1562 0.1965 0.0324 0.113 Uiso 1 1 calc R
C51 C -0.1410(8) 0.2274(4) 0.1456(13) 0.119(6) Uani 1 1 d D
H51 H -0.1749 0.2389 0.1518 0.143 Uiso 1 1 calc R
C52 C -0.0998(9) 0.2336(5) 0.2064(11) 0.127(8) Uani 1 1 d D
H52 H -0.1076 0.2481 0.2574 0.153 Uiso 1 1 calc R
C53 C -0.0495(8) 0.2203(5) 0.1976(10) 0.117(8) Uani 1 1 d D
H53 H -0.0226 0.2272 0.2386 0.141 Uiso 1 1 calc R
C54 C -0.0372(5) 0.1951(4) 0.1244(8) 0.081(4) Uani 1 1 d D
H54 H -0.0032 0.1839 0.1190 0.097 Uiso 1 1 calc R
C55 C -0.1615(4) 0.1170(3) 0.3309(7) 0.054(2) Uani 1 1 d .
C56 C -0.2095(4) 0.1243(3) 0.3961(8) 0.056(2) Uani 1 1 d .
H56 H -0.2416 0.1108 0.3738 0.067 Uiso 1 1 calc R
C57 C -0.2219(4) 0.1653(3) 0.4005(7) 0.055(3) Uani 1 1 d .
H57A H -0.2573 0.1684 0.4285 0.067 Uiso 1 1 calc R
H57B H -0.2246 0.1749 0.3391 0.067 Uiso 1 1 calc R
C58 C -0.1804(4) 0.1905(3) 0.4531(6) 0.063(3) Uani 1 1 d D
C59 C -0.1958(5) 0.2072(4) 0.5352(7) 0.074(4) Uani 1 1 d D
H59 H -0.2299 0.2027 0.5604 0.088 Uiso 1 1 calc R
C60 C -0.1580(6) 0.2311(4) 0.5783(7) 0.080(4) Uani 1 1 d D
H60 H -0.1675 0.2426 0.6327 0.096 Uiso 1 1 calc R
C61 C -0.1079(6) 0.2380(4) 0.5428(9) 0.089(4) Uani 1 1 d D
H61 H -0.0838 0.2540 0.5724 0.106 Uiso 1 1 calc R
C62 C -0.0936(6) 0.2213(4) 0.4648(9) 0.084(4) Uani 1 1 d D
H62 H -0.0593 0.2254 0.4404 0.101 Uiso 1 1 calc R
C63 C -0.1310(5) 0.1974(3) 0.4198(7) 0.067(3) Uani 1 1 d D
H63 H -0.1209 0.1862 0.3654 0.081 Uiso 1 1 calc R
C64 C -0.0516(4) 0.0953(3) 0.6379(6) 0.052(2) Uani 1 1 d .
C65 C -0.0267(4) 0.0953(4) 0.7350(7) 0.061(3) Uani 1 1 d .
H65 H -0.0503 0.0803 0.7744 0.073 Uiso 1 1 calc R
C66 C -0.0237(5) 0.1346(4) 0.7722(8) 0.070(3) Uani 1 1 d .
H66A H -0.0112 0.1337 0.8344 0.085 Uiso 1 1 calc R
H66B H -0.0597 0.1458 0.7718 0.085 Uiso 1 1 calc R
C67 C 0.0154(4) 0.1594(3) 0.7153(7) 0.058(3) Uani 1 1 d .
C68 C 0.0699(4) 0.1626(3) 0.7451(9) 0.065(3) Uani 1 1 d .
H68 H 0.0814 0.1498 0.7967 0.079 Uiso 1 1 calc R
C69 C 0.1052(5) 0.1846(4) 0.6971(10) 0.079(4) Uani 1 1 d .
H69 H 0.1408 0.1876 0.7168 0.094 Uiso 1 1 calc R
C70 C 0.0875(6) 0.2029(4) 0.6176(9) 0.080(4) Uani 1 1 d .
H70 H 0.1119 0.2175 0.5846 0.096 Uiso 1 1 calc R
C71 C 0.0356(6) 0.1996(4) 0.5885(10) 0.080(4) Uani 1 1 d .
H71 H 0.0243 0.2118 0.5359 0.096 Uiso 1 1 calc R
C72 C 0.0005(5) 0.1784(4) 0.6371(9) 0.075(3) Uani 1 1 d .
H72 H -0.0352 0.1763 0.6172 0.090 Uiso 1 1 calc R
C73 C 0.1609(5) 0.0803(4) 0.5493(13) 0.083(5) Uani 1 1 d .
C74 C 0.2203(5) 0.0785(4) 0.5433(14) 0.106(7) Uani 1 1 d .
H74 H 0.2335 0.0607 0.5894 0.127 Uiso 1 1 calc R
C75 C 0.2462(5) 0.1188(4) 0.5623(13) 0.097(5) Uani 1 1 d .
H75A H 0.2273 0.1304 0.6129 0.116 Uiso 1 1 calc R
H75B H 0.2838 0.1154 0.5799 0.116 Uiso 1 1 calc R
C76 C 0.2439(4) 0.1450(3) 0.4837(10) 0.069(3) Uani 1 1 d .
C77 C 0.2871(6) 0.1526(4) 0.4314(14) 0.103(6) Uani 1 1 d .
H77 H 0.3197 0.1406 0.4450 0.123 Uiso 1 1 calc R
C78 C 0.2860(9) 0.1778(5) 0.3562(16) 0.126(7) Uani 1 1 d .
H78 H 0.3169 0.1817 0.3211 0.151 Uiso 1 1 calc R
C79 C 0.2380(7) 0.1966(4) 0.3363(10) 0.080(4) Uani 1 1 d .
H79 H 0.2362 0.2139 0.2890 0.096 Uiso 1 1 calc R
C80 C 0.1932(6) 0.1887(4) 0.3885(10) 0.083(4) Uani 1 1 d .
H80 H 0.1606 0.2007 0.3750 0.099 Uiso 1 1 calc R
C81 C 0.1950(4) 0.1625(4) 0.4634(9) 0.068(3) Uani 1 1 d .
H81 H 0.1640 0.1575 0.4974 0.081 Uiso 1 1 calc R
C82 C 0.1734(8) 0.0727(4) 0.1858(18) 0.118(8) Uani 1 1 d .
C83 C 0.1878(7) 0.0741(5) 0.0858(13) 0.108(6) Uani 1 1 d .
H83 H 0.2118 0.0527 0.0716 0.130 Uiso 1 1 calc R
C84 C 0.2188(7) 0.1126(5) 0.0635(15) 0.135(9) Uani 1 1 d .
H84A H 0.2463 0.1171 0.1094 0.162 Uiso 1 1 calc R
H84B H 0.2371 0.1102 0.0056 0.162 Uiso 1 1 calc R
C85 C 0.1800(6) 0.1463(4) 0.0603(10) 0.081(4) Uani 1 1 d .
C86 C 0.1648(8) 0.1623(6) -0.0266(12) 0.113(7) Uani 1 1 d .
H86 H 0.1778 0.1523 -0.0807 0.136 Uiso 1 1 calc R
C87 C 0.1309(9) 0.1923(6) -0.0254(11) 0.106(6) Uani 1 1 d .
H87 H 0.1235 0.2047 -0.0796 0.127 Uiso 1 1 calc R
C88 C 0.1088(8) 0.2045(5) 0.0469(12) 0.101(5) Uani 1 1 d .
H88 H 0.0817 0.2229 0.0438 0.121 Uiso 1 1 calc R
C89 C 0.1252(7) 0.1903(5) 0.1311(11) 0.095(5) Uani 1 1 d .
H89 H 0.1126 0.2014 0.1842 0.115 Uiso 1 1 calc R
C90 C 0.1593(5) 0.1606(4) 0.1346(9) 0.069(3) Uani 1 1 d .
H90 H 0.1683 0.1501 0.1904 0.082 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu1 O6 143.6(2) . .
O2 Eu1 O4 71.4(2) . .
O6 Eu1 O4 72.3(2) . .
O2 Eu1 O100 80.1(3) . .
O6 Eu1 O100 89.3(3) . .
O4 Eu1 O100 78.5(3) . .
O2 Eu1 O10 70.9(3) . .
O6 Eu1 O10 141.0(3) . .
O4 Eu1 O10 138.5(2) . .
O100 Eu1 O10 78.5(3) . .
O2 Eu1 O102 112.5(4) . .
O6 Eu1 O102 90.1(4) . .
O4 Eu1 O102 122.4(3) . .
O100 Eu1 O102 157.6(4) . .
O10 Eu1 O102 88.1(3) . .
O2 Eu1 O8 141.9(3) . .
O6 Eu1 O8 69.7(2) . .
O4 Eu1 O8 138.1(2) . .
O100 Eu1 O8 83.8(3) . .
O10 Eu1 O8 72.2(3) . .
O102 Eu1 O8 75.0(4) . .
O2 Eu1 O101 80.2(4) . .
O6 Eu1 O101 93.2(5) . .
O4 Eu1 O101 73.7(4) . .
O100 Eu1 O101 149.9(4) . .
O10 Eu1 O101 115.8(4) . .
O102 Eu1 O101 52.5(4) . .
O8 Eu1 O101 125.1(4) . .
O2 Eu1 N100 96.2(4) . .
O6 Eu1 N100 92.5(3) . .
O4 Eu1 N100 98.3(4) . .
O100 Eu1 N100 175.7(4) . .
O10 Eu1 N100 102.4(4) . .
O102 Eu1 N100 26.4(4) . .
O8 Eu1 N100 100.4(4) . .
O101 Eu1 N100 26.2(4) . .
O200 Eu2 O14 85.6(3) . .
O200 Eu2 O18 88.7(3) . .
O14 Eu2 O18 143.3(2) . .
O200 Eu2 O12 86.2(3) . .
O14 Eu2 O12 72.0(2) . .
O18 Eu2 O12 143.8(2) . .
O200 Eu2 O16 84.9(3) . .
O14 Eu2 O16 71.6(2) . .
O18 Eu2 O16 71.8(2) . .
O12 Eu2 O16 143.0(2) . .
O200 Eu2 O20 80.8(3) . .
O14 Eu2 O20 142.5(3) . .
O18 Eu2 O20 71.4(3) . .
O12 Eu2 O20 72.4(3) . .
O16 Eu2 O20 140.6(3) . .
O200 Eu2 O202 158.6(3) . .
O14 Eu2 O202 77.4(3) . .
O18 Eu2 O202 97.2(4) . .
O12 Eu2 O202 100.5(4) . .
O16 Eu2 O202 77.6(3) . .
O20 Eu2 O202 120.5(3) . .
O200 Eu2 O207 151.3(3) . .
O14 Eu2 O207 115.7(3) . .
O18 Eu2 O207 84.6(3) . .
O12 Eu2 O207 82.9(3) . .
O16 Eu2 O207 119.0(3) . .
O20 Eu2 O207 70.6(3) . .
O202 Eu2 O207 50.1(3) . .
O200 Eu2 N200 177.2(3) . .
O14 Eu2 N200 96.3(3) . .
O18 Eu2 N200 91.0(3) . .
O12 Eu2 N200 92.3(3) . .
O16 Eu2 N200 97.7(3) . .
O20 Eu2 N200 96.4(3) . .
O202 Eu2 N200 24.2(3) . .
O207 Eu2 N200 25.9(3) . .
N10 Cu1 O1 169.9(4) . .
N10 Cu1 O2 90.3(4) . .
O1 Cu1 O2 85.4(4) . .
N10 Cu1 N9 81.4(5) . .
O1 Cu1 N9 104.1(5) . .
O2 Cu1 N9 168.2(5) . .
N2 Cu2 O4 90.8(4) . .
N2 Cu2 O3 169.4(4) . .
O4 Cu2 O3 85.2(3) . .
N2 Cu2 N1 81.9(4) . .
O4 Cu2 N1 172.2(3) . .
O3 Cu2 N1 102.5(3) . .
N4 Cu3 O6 89.4(3) . .
N4 Cu3 O5 159.7(5) . .
O6 Cu3 O5 84.9(4) . .
N4 Cu3 N3 80.8(3) . .
O6 Cu3 N3 169.8(3) . .
O5 Cu3 N3 103.5(3) . .
O8 Cu4 N6 90.7(4) . .
O8 Cu4 N5 172.1(4) . .
N6 Cu4 N5 82.4(4) . .
O8 Cu4 O7 83.5(4) . .
N6 Cu4 O7 170.2(4) . .
N5 Cu4 O7 102.8(4) . .
N8 Cu5 O10 91.4(4) . .
N8 Cu5 O9 173.8(5) . .
O10 Cu5 O9 83.7(4) . .
N8 Cu5 N7 81.7(5) . .
O10 Cu5 N7 172.8(6) . .
O9 Cu5 N7 103.3(6) . .
N20 Cu6 O12 92.2(4) . .
N20 Cu6 O11 171.8(4) . .
O12 Cu6 O11 84.5(4) . .
N20 Cu6 N19 82.2(6) . .
O12 Cu6 N19 173.4(7) . .
O11 Cu6 N19 101.5(6) . .
O13 Cu7 N12 170.3(4) . .
O13 Cu7 O14 86.4(3) . .
N12 Cu7 O14 89.7(4) . .
O13 Cu7 N11 102.6(4) . .
N12 Cu7 N11 82.0(4) . .
O14 Cu7 N11 170.0(4) . .
N14 Cu8 O16 91.1(3) . .
N14 Cu8 O15 168.9(3) . .
O16 Cu8 O15 85.5(3) . .
N14 Cu8 N13 81.5(4) . .
O16 Cu8 N13 172.6(4) . .
O15 Cu8 N13 101.9(3) . .
N16 Cu9 O17 172.9(4) . .
N16 Cu9 O18 90.4(4) . .
O17 Cu9 O18 85.9(4) . .
N16 Cu9 N15 81.1(4) . .
O17 Cu9 N15 103.1(4) . .
O18 Cu9 N15 169.9(4) . .
N18 Cu10 O20 91.8(5) . .
N18 Cu10 O19 171.1(5) . .
O20 Cu10 O19 84.7(6) . .
N18 Cu10 N17 82.3(5) . .
O20 Cu10 N17 170.2(4) . .
O19 Cu10 N17 102.3(6) . .
C1 O1 Cu1 108.1(7) . .
N2 O2 Cu1 108.3(6) . .
N2 O2 Eu1 122.5(6) . .
Cu1 O2 Eu1 128.5(4) . .
C10 O3 Cu2 107.0(6) . .
N4 O4 Cu2 108.0(5) . .
N4 O4 Eu1 121.5(5) . .
Cu2 O4 Eu1 122.2(3) . .
C19 O5 Cu3 106.8(9) . .
N6 O6 Cu3 107.6(6) . .
N6 O6 Eu1 122.8(5) . .
Cu3 O6 Eu1 127.6(3) . .
C28 O7 Cu4 108.6(7) . .
N8 O8 Cu4 110.2(6) . .
N8 O8 Eu1 122.7(7) . .
Cu4 O8 Eu1 121.5(3) . .
C37 O9 Cu5 104.0(9) . .
N10 O10 Cu5 110.0(6) . .
N10 O10 Eu1 123.5(6) . .
Cu5 O10 Eu1 126.3(5) . .
C46 O11 Cu6 108.4(10) . .
N12 O12 Cu6 107.1(6) . .
N12 O12 Eu2 125.4(5) . .
Cu6 O12 Eu2 127.3(4) . .
C55 O13 Cu7 105.8(6) . .
N14 O14 Cu7 106.4(5) . .
N14 O14 Eu2 125.2(5) . .
Cu7 O14 Eu2 126.9(3) . .
C64 O15 Cu8 107.0(6) . .
N16 O16 Cu8 107.4(5) . .
N16 O16 Eu2 125.6(5) . .
Cu8 O16 Eu2 126.6(4) . .
C73 O17 Cu9 108.5(9) . .
N18 O18 Cu9 106.3(8) . .
N18 O18 Eu2 125.8(7) . .
Cu9 O18 Eu2 127.9(3) . .
C82 O19 Cu10 109.1(10) . .
N20 O20 Cu10 108.4(7) . .
N20 O20 Eu2 124.2(8) . .
Cu10 O20 Eu2 125.7(5) . .
N100 O101 Eu1 92.8(9) . .
N100 O102 Eu1 93.6(10) . .
N201 O200 Eu2 147.0(8) . .
N200 O202 Eu2 99.1(7) . .
N200 O207 Eu2 96.8(6) . .
O306 N310 O318 113.1(16) . .
O306 N310 O318 113.1(16) . 2_565
O318 N310 O318 134(3) . 2_565
C2 N1 Cu2 111.0(7) . .
C1 N2 O2 116.9(10) . .
C1 N2 Cu2 116.8(9) . .
O2 N2 Cu2 124.3(6) . .
C11 N3 Cu3 105.1(5) . .
C10 N4 O4 114.7(7) . .
C10 N4 Cu3 118.7(6) . .
O4 N4 Cu3 126.2(6) . .
C20 N5 Cu4 114.2(8) . .
C19 N6 O6 116.2(9) . .
C19 N6 Cu4 120.7(8) . .
O6 N6 Cu4 122.5(8) . .
C29 N7 Cu5 109.1(8) . .
C28 N8 O8 113.5(11) . .
C28 N8 Cu5 117.9(9) . .
O8 N8 Cu5 127.1(8) . .
C38 N9 Cu1 109.0(9) . .
C37 N10 O10 111.2(12) . .
C37 N10 Cu1 121.8(11) . .
O10 N10 Cu1 126.8(7) . .
C47 N11 Cu7 109.2(8) . .
C46 N12 O12 116.9(10) . .
C46 N12 Cu7 118.6(10) . .
O12 N12 Cu7 124.5(7) . .
C56 N13 Cu8 112.4(6) . .
C55 N14 O14 114.9(8) . .
C55 N14 Cu8 120.8(7) . .
O14 N14 Cu8 124.1(6) . .
C65 N15 Cu9 110.3(7) . .
C64 N16 O16 116.1(8) . .
C64 N16 Cu9 118.6(8) . .
O16 N16 Cu9 124.1(6) . .
C74 N17 Cu10 109.9(7) . .
C73 N18 O18 117.7(11) . .
C73 N18 Cu10 118.6(9) . .
O18 N18 Cu10 123.6(10) . .
C83 N19 Cu6 110.0(9) . .
C82 N20 O20 116.4(17) . .
C82 N20 Cu6 118.9(16) . .
O20 N20 Cu6 123.6(7) . .
O101 N100 O102 121.0(14) . .
O101 N100 O103 117.1(16) . .
O102 N100 O103 121.8(18) . .
O101 N100 Eu1 61.0(8) . .
O102 N100 Eu1 60.1(8) . .
O103 N100 Eu1 177.7(13) . .
O202 N200 O203 123.7(10) . .
O202 N200 O207 114.0(9) . .
O203 N200 O207 122.2(9) . .
O202 N200 Eu2 56.7(6) . .
O203 N200 Eu2 177.2(8) . .
O207 N200 Eu2 57.3(5) . .
O201 N201 O200 120.4(8) . 2
O201 N201 O200 120.4(8) . .
O200 N201 O200 119.1(16) 2 .
O305 N301 O303 134(2) . .
O305 N301 O304 116(2) . .
O303 N301 O304 109(2) . .
N2 C1 O1 121.3(12) . .
N2 C1 C2 118.2(11) . .
O1 C1 C2 120.1(10) . .
C1 C2 N1 108.5(9) . .
C1 C2 C3 107.1(10) . .
N1 C2 C3 112.2(11) . .
C2 C3 C4 112.7(10) . .
C9 C4 C5 124.1(13) . .
C9 C4 C3 112.8(12) . .
C5 C4 C3 122.6(10) . .
C4 C5 C6 118.1(12) . .
C7 C6 C5 117.4(14) . .
C8 C7 C6 121.9(17) . .
C7 C8 C9 122.0(18) . .
C4 C9 C8 115.9(16) . .
N4 C10 O3 125.0(9) . .
N4 C10 C11 113.8(8) . .
O3 C10 C11 121.0(8) . .
N3 C11 C10 107.6(8) . .
N3 C11 C12 107.0(7) . .
C10 C11 C12 110.9(8) . .
C13 C12 C11 116.3(8) . .
C18 C13 C14 121.1(12) . .
C18 C13 C12 121.3(12) . .
C14 C13 C12 117.4(10) . .
C15 C14 C13 117.5(14) . .
C16 C15 C14 121.4(17) . .
C15 C16 C17 120.6(16) . .
C16 C17 C18 122.5(17) . .
C13 C18 C17 116.8(16) . .
N6 C19 O5 124.4(13) . .
N6 C19 C20 115.2(10) . .
O5 C19 C20 120.3(12) . .
N5 C20 C21 112.4(12) . .
N5 C20 C19 106.9(11) . .
C21 C20 C19 110.6(12) . .
C22 C21 C20 118.6(11) . .
C23 C22 C21 120.7(12) . .
C23 C22 C27 116.2(15) . .
C21 C22 C27 123.0(15) . .
C22 C23 C24 123.3(14) . .
C25 C24 C23 113.5(19) . .
C24 C25 C26 127(2) . .
C25 C26 C27 119.3(15) . .
C26 C27 C22 120.1(14) . .
O7 C28 N8 123.7(11) . .
O7 C28 C29 123.2(11) . .
N8 C28 C29 112.9(14) . .
N7 C29 C30 113.2(18) . .
N7 C29 C28 108.2(11) . .
C30 C29 C28 111.5(10) . .
C31 C30 C29 114.4(13) . .
C36 C31 C32 124.5(15) . .
C36 C31 C30 113.7(15) . .
C32 C31 C30 121.9(13) . .
C31 C32 C33 121.9(14) . .
C34 C33 C32 113.6(16) . .
C35 C34 C33 122.5(18) . .
C34 C35 C36 125.3(18) . .
C31 C36 C35 111.7(16) . .
O9 C37 N10 129.7(16) . .
O9 C37 C38 117.9(13) . .
N10 C37 C38 112.4(15) . .
N9 C38 C37 109.0(11) . .
N9 C38 C39 105.1(17) . .
C37 C38 C39 115.4(14) . .
C40 C39 C38 116.5(11) . .
C41 C40 C45 121(2) . .
C41 C40 C39 118(2) . .
C45 C40 C39 121(2) . .
C42 C41 C40 121(2) . .
C41 C42 C43 124(2) . .
C42 C43 C44 118(2) . .
C43 C44 C45 121(2) . .
C40 C45 C44 115(2) . .
O11 C46 N12 122.4(15) . .
O11 C46 C47 122.4(12) . .
N12 C46 C47 115.3(12) . .
N11 C47 C46 109.7(12) . .
N11 C47 C48 108.7(12) . .
C46 C47 C48 111.2(11) . .
C49 C48 C47 115.4(10) . .
C54 C49 C50 121.2(12) . .
C54 C49 C48 122.7(14) . .
C50 C49 C48 116.1(11) . .
C49 C50 C51 120.9(13) . .
C52 C51 C50 116.0(15) . .
C53 C52 C51 124.7(16) . .
C52 C53 C54 119.3(13) . .
C49 C54 C53 117.6(13) . .
N14 C55 O13 126.3(9) . .
N14 C55 C56 115.4(9) . .
O13 C55 C56 118.3(9) . .
N13 C56 C57 112.6(10) . .
N13 C56 C55 107.0(8) . .
C57 C56 C55 110.4(9) . .
C56 C57 C58 116.2(8) . .
C63 C58 C59 119.3(11) . .
C63 C58 C57 121.2(9) . .
C59 C58 C57 119.5(10) . .
C58 C59 C60 117.6(11) . .
C61 C60 C59 122.2(11) . .
C62 C61 C60 119.3(12) . .
C61 C62 C63 119.7(12) . .
C58 C63 C62 122.0(10) . .
N16 C64 O15 123.3(9) . .
N16 C64 C65 114.4(9) . .
O15 C64 C65 122.2(8) . .
N15 C65 C66 113.5(10) . .
N15 C65 C64 107.5(9) . .
C66 C65 C64 111.0(9) . .
C65 C66 C67 110.9(10) . .
C72 C67 C68 118.2(10) . .
C72 C67 C66 124.1(10) . .
C68 C67 C66 117.7(10) . .
C69 C68 C67 119.1(11) . .
C68 C69 C70 119.8(11) . .
C71 C70 C69 121.2(12) . .
C72 C71 C70 118.8(12) . .
C71 C72 C67 122.9(11) . .
N18 C73 O17 120.8(10) . .
N18 C73 C74 116.6(16) . .
O17 C73 C74 122.5(16) . .
C73 C74 N17 107.6(16) . .
C73 C74 C75 110.5(12) . .
N17 C74 C75 113.1(12) . .
C76 C75 C74 114.0(14) . .
C77 C76 C81 118.4(13) . .
C77 C76 C75 123.0(11) . .
C81 C76 C75 118.6(11) . .
C76 C77 C78 124.0(15) . .
C79 C78 C77 118.7(14) . .
C80 C79 C78 118.0(13) . .
C79 C80 C81 122.4(13) . .
C76 C81 C80 118.5(12) . .
N20 C82 O19 121(2) . .
N20 C82 C83 115(2) . .
O19 C82 C83 123.4(14) . .
N19 C83 C82 109.0(13) . .
N19 C83 C84 111.4(18) . .
C82 C83 C84 109.8(14) . .
C85 C84 C83 111.7(12) . .
C90 C85 C86 119.4(16) . .
C90 C85 C84 121.1(16) . .
C86 C85 C84 119.5(15) . .
C87 C86 C85 116.9(14) . .
C88 C87 C86 122.8(18) . .
C87 C88 C89 119.9(19) . .
C90 C89 C88 119.7(16) . .
C85 C90 C89 120.7(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O2 2.396(8) .
Eu1 O6 2.419(8) .
Eu1 O4 2.425(6) .
Eu1 O100 2.426(8) .
Eu1 O10 2.448(8) .
Eu1 O102 2.450(11) .
Eu1 O8 2.469(7) .
Eu1 O101 2.472(11) .
Eu1 N100 2.822(14) .
Eu2 O200 2.221(4) .
Eu2 O14 2.386(7) .
Eu2 O18 2.388(8) .
Eu2 O12 2.403(9) .
Eu2 O16 2.420(7) .
Eu2 O20 2.461(8) .
Eu2 O202 2.465(9) .
Eu2 O207 2.467(9) .
Eu2 N200 2.911(9) .
Cu1 N10 1.846(12) .
Cu1 O1 1.895(9) .
Cu1 O2 1.919(7) .
Cu1 N9 1.986(11) .
Cu2 N2 1.906(10) .
Cu2 O4 1.929(6) .
Cu2 O3 1.932(7) .
Cu2 N1 2.048(9) .
Cu3 N4 1.916(8) .
Cu3 O6 1.919(7) .
Cu3 O5 1.958(9) .
Cu3 N3 2.035(7) .
Cu4 O8 1.918(9) .
Cu4 N6 1.922(9) .
Cu4 N5 1.964(12) .
Cu4 O7 1.964(8) .
Cu5 N8 1.891(12) .
Cu5 O10 1.925(8) .
Cu5 O9 1.984(12) .
Cu5 N7 2.021(12) .
Cu6 N20 1.920(15) .
Cu6 O12 1.922(7) .
Cu6 O11 1.937(13) .
Cu6 N19 1.978(10) .
Cu7 O13 1.916(7) .
Cu7 N12 1.924(9) .
Cu7 O14 1.953(8) .
Cu7 N11 2.017(10) .
Cu8 N14 1.878(8) .
Cu8 O16 1.918(6) .
Cu8 O15 1.928(7) .
Cu8 N13 2.013(8) .
Cu9 N16 1.918(8) .
Cu9 O17 1.921(8) .
Cu9 O18 1.930(8) .
Cu9 N15 2.019(11) .
Cu10 N18 1.886(11) .
Cu10 O20 1.916(10) .
Cu10 O19 1.923(12) .
Cu10 N17 1.983(14) .
O1 C1 1.316(14) .
O2 N2 1.347(13) .
O3 C10 1.289(11) .
O4 N4 1.399(10) .
O5 C19 1.276(14) .
O6 N6 1.391(12) .
O7 C28 1.255(17) .
O8 N8 1.385(12) .
O9 C37 1.269(19) .
O10 N10 1.393(14) .
O11 C46 1.261(16) .
O12 N12 1.373(13) .
O13 C55 1.310(13) .
O14 N14 1.408(9) .
O15 C64 1.293(12) .
O16 N16 1.380(12) .
O17 C73 1.336(19) .
O18 N18 1.427(11) .
O19 C82 1.32(3) .
O20 N20 1.411(16) .
O101 N100 1.246(19) .
O102 N100 1.255(18) .
O103 N100 1.42(2) .
O200 N201 1.335(10) .
O201 N201 1.325(10) .
O202 N200 1.206(12) .
O203 N200 1.214(12) .
O207 N200 1.281(12) .
O303 N301 1.22(3) .
O304 N301 1.38(3) .
O305 N301 1.18(3) .
O306 N310 1.16(3) .
N310 O318 1.24(2) .
N310 O318 1.24(2) 2_565
N1 C2 1.477(14) .
N2 C1 1.292(15) .
N3 C11 1.499(12) .
N4 C10 1.279(12) .
N5 C20 1.520(16) .
N6 C19 1.273(17) .
N7 C29 1.438(19) .
N8 C28 1.328(17) .
N9 C38 1.46(2) .
N10 C37 1.273(17) .
N11 C47 1.487(15) .
N12 C46 1.293(17) .
N13 C56 1.465(14) .
N14 C55 1.272(13) .
N15 C65 1.451(13) .
N16 C64 1.286(13) .
N17 C74 1.49(3) .
N18 C73 1.27(2) .
N19 C83 1.50(2) .
N20 C82 1.263(19) .
N201 O200 1.335(10) 2
C1 C2 1.462(17) .
C2 C3 1.524(18) .
C3 C4 1.530(18) .
C4 C9 1.338(15) .
C4 C5 1.387(13) .
C5 C6 1.422(15) .
C6 C7 1.399(17) .
C7 C8 1.314(18) .
C8 C9 1.434(18) .
C10 C11 1.512(13) .
C11 C12 1.538(15) .
C12 C13 1.531(15) .
C13 C18 1.325(16) .
C13 C14 1.469(18) .
C14 C15 1.39(2) .
C15 C16 1.33(3) .
C16 C17 1.34(3) .
C17 C18 1.45(3) .
C19 C20 1.558(18) .
C20 C21 1.54(2) .
C21 C22 1.43(2) .
C22 C23 1.40(2) .
C22 C27 1.436(16) .
C23 C24 1.47(3) .
C24 C25 1.32(3) .
C25 C26 1.35(2) .
C26 C27 1.38(2) .
C28 C29 1.56(2) .
C29 C30 1.53(2) .
C30 C31 1.47(2) .
C31 C36 1.348(16) .
C31 C32 1.388(15) .
C32 C33 1.411(17) .
C33 C34 1.405(18) .
C34 C35 1.307(18) .
C35 C36 1.444(18) .
C37 C38 1.50(3) .
C38 C39 1.56(2) .
C39 C40 1.51(3) .
C40 C41 1.38(3) .
C40 C45 1.42(3) .
C41 C42 1.29(3) .
C42 C43 1.36(3) .
C43 C44 1.40(3) .
C44 C45 1.44(3) .
C46 C47 1.49(2) .
C47 C48 1.54(2) .
C48 C49 1.512(18) .
C49 C54 1.369(13) .
C49 C50 1.384(15) .
C50 C51 1.405(16) .
C51 C52 1.372(17) .
C52 C53 1.331(18) .
C53 C54 1.432(17) .
C55 C56 1.545(14) .
C56 C57 1.481(16) .
C57 C58 1.561(16) .
C58 C63 1.333(13) .
C58 C59 1.403(12) .
C59 C60 1.408(15) .
C60 C61 1.363(15) .
C61 C62 1.339(15) .
C62 C63 1.415(15) .
C64 C65 1.559(15) .
C65 C66 1.493(19) .
C66 C67 1.551(16) .
C67 C72 1.384(17) .
C67 C68 1.415(15) .
C68 C69 1.365(18) .
C69 C70 1.41(2) .
C70 C71 1.353(19) .
C71 C72 1.350(18) .
C73 C74 1.465(16) .
C74 C75 1.59(2) .
C75 C76 1.49(2) .
C76 C77 1.341(19) .
C76 C81 1.387(15) .
C77 C78 1.42(3) .
C78 C79 1.39(3) .
C79 C80 1.37(2) .
C80 C81 1.442(19) .
C82 C83 1.52(3) .
C83 C84 1.59(2) .
C84 C85 1.53(3) .
C85 C90 1.311(18) .
C85 C86 1.45(3) .
C86 C87 1.35(3) .
C87 C88 1.27(3) .
C88 C89 1.40(2) .
C89 C90 1.34(2) .
