#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:09:16 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179364 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/61/4326107.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4326107
loop_
_publ_author_name
'Vincent J. Catalano'
'Lyndsay B. Munro'
'Christoph E. Strasser'
'Ahmad F. Samin'
_publ_contact_author_address
;
Department of Chemistry
University of Nevada
Reno, NV  89557
;
_publ_contact_author_email       vjc@unr.edu
_publ_contact_author_name        'Professor Vincent J. Catalano'
_publ_contact_author_phone       '775 784 1329'
_publ_section_title
;
 Modulation of Metal-Metal Separations in a Series of Ag(I) and Intensely
 Blue Photoluminescent Cu(I) NHC-Bridged Triangular Clusters
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8465
_journal_page_last               8476
_journal_paper_doi               10.1021/ic201053t
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety         'C45 H48 Ag3 N12, 3(B F4), 4(C2 H3 N)'
_chemical_formula_sum            'C53 H60 Ag3 B3 F12 N16'
_chemical_formula_weight         1505.2
_chemical_name_common
;
Tris{η³-μ-1,3-bis[(2-pyridyl)methyl]-4,5-dihydroimidazol-2-
ylidene}trisilver(I) tetrafluoroborate acetonitrile tetrasolvate
;
_chemical_name_systematic
; 
Triangulo-tris{η³-μ₂-1,3-bis[(2-pyridyl-\kN)methyl]-
4,5-dihydro-2H-imidazol-2-ylidene-\kC}trisilver(I)
 3(Ag---Ag) tetrafluoroborate ethanenitrile tetrasolvate
;
_space_group_IT_number           159
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      159
_symmetry_space_group_name_Hall  'P 3 -2c'
_symmetry_space_group_name_H-M   'P 3 1 c'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   13.0585(3)
_cell_length_b                   13.0585(3)
_cell_length_c                   21.1922(5)
_cell_measurement_reflns_used    5428
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.699
_cell_measurement_theta_min      3.401
_cell_volume                     3129.63(13)
_computing_cell_refinement       SAINT
_computing_data_collection       'SAINT (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'Diamond 3.2 (Crystal Impact, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'φ- and ω-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0192
_diffrn_reflns_av_sigmaI/netI    0.0244
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            7681
_diffrn_reflns_theta_full        32.78
_diffrn_reflns_theta_max         32.78
_diffrn_reflns_theta_min         0.96
_exptl_absorpt_coefficient_mu    1.015
_exptl_absorpt_correction_T_max  0.9644
_exptl_absorpt_correction_T_min  0.8660
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker 2002)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.597
_exptl_crystal_description       plate
_exptl_crystal_F_000             1508
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.200
_refine_diff_density_min         -0.511
_refine_diff_density_rms         0.098
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     269
_refine_ls_number_reflns         3853
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0482
_refine_ls_R_factor_gt           0.0373
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0685P)²+0.5834P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1097
_refine_ls_wR_factor_ref         0.1154
_reflns_number_gt                2983
_reflns_number_total             3853
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic201053t_si_002_01.cif
_cod_data_source_block           Compound-3e.4MeCN
_cod_database_code               4326107
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, z+1/2'
'x-y, -y, z+1/2'
'-x, -x+y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.11962(3) 0.12168(3) 0.47952(14) 0.01969(9) Uani 1 1 d . . .
N4 N 0.0273(6) -0.2250(5) 0.5635(3) 0.0308(11) Uani 1 1 d . . .
N3 N 0.2631(5) 0.2296(6) 0.4019(3) 0.0330(11) Uani 1 1 d . . .
N1 N 0.2471(5) -0.0018(4) 0.5399(4) 0.0298(14) Uani 1 1 d . . .
C10 C 0.1851(6) -0.0361(7) 0.5997(3) 0.0357(13) Uani 1 1 d . . .
H10A H 0.1322 -0.0024 0.6030 0.043 Uiso 1 1 calc R . .
H10B H 0.2430 -0.0035 0.6346 0.043 Uiso 1 1 calc R . .
C8 C 0.4039(7) 0.4183(8) 0.3593(4) 0.0399(18) Uani 1 1 d . . .
H8 H 0.4336 0.5010 0.3563 0.048 Uiso 1 1 calc R . .
C5 C 0.3136(6) 0.1799(6) 0.3678(3) 0.0365(14) Uani 1 1 d . . .
C11 C 0.1125(6) -0.1700(5) 0.6059(3) 0.0330(13) Uani 1 1 d . . .
C1 C 0.1975(5) 0.0030(5) 0.4846(5) 0.0273(12) Uani 1 1 d . . .
C9 C 0.3062(6) 0.3482(6) 0.3961(3) 0.0359(13) Uani 1 1 d . . .
H9 H 0.2681 0.3834 0.4180 0.043 Uiso 1 1 calc R . .
C7 C 0.4586(7) 0.3651(7) 0.3264(3) 0.0450(17) Uani 1 1 d . . .
H7 H 0.5267 0.4115 0.3013 0.054 Uiso 1 1 calc R . .
C6 C 0.4114(6) 0.2437(6) 0.3312(3) 0.0412(14) Uani 1 1 d . . .
H6 H 0.4466 0.2055 0.3094 0.049 Uiso 1 1 calc R . .
N2 N 0.2701(7) 0.0110(5) 0.4382(4) 0.0368(16) Uani 1 1 d . . .
C15 C -0.0405(7) -0.3418(6) 0.5678(3) 0.0343(13) Uani 1 1 d . . .
H15 H -0.1006 -0.3814 0.5371 0.041 Uiso 1 1 calc R . .
C14 C -0.0282(9) -0.4096(8) 0.6152(4) 0.0408(17) Uani 1 1 d . . .
H14 H -0.0790 -0.4928 0.6174 0.049 Uiso 1 1 calc R . .
C2 C 0.3540(8) -0.0089(7) 0.5305(7) 0.059(3) Uani 1 1 d . . .
H2A H 0.3386 -0.0905 0.5367 0.071 Uiso 1 1 calc R . .
H2B H 0.4182 0.0452 0.5592 0.071 Uiso 1 1 calc R . .
C4 C 0.2581(7) 0.0462(6) 0.3758(3) 0.0455(17) Uani 1 1 d . . .
H4A H 0.1729 0.0080 0.3652 0.055 Uiso 1 1 calc R . .
H4B H 0.2954 0.0172 0.3455 0.055 Uiso 1 1 calc R . .
C3 C 0.3840(8) 0.0300(9) 0.4617(5) 0.055(2) Uani 1 1 d . . .
H3A H 0.4464 0.1142 0.4585 0.066 Uiso 1 1 calc R . .
H3B H 0.4096 -0.0194 0.4387 0.066 Uiso 1 1 calc R . .
C13 C 0.0649(8) -0.3473(7) 0.6601(4) 0.0539(19) Uani 1 1 d . . .
H13 H 0.0794 -0.3892 0.6922 0.065 Uiso 1 1 calc R . .
C12 C 0.1305(6) -0.2305(7) 0.6564(4) 0.0445(16) Uani 1 1 d . . .
H12 H 0.1892 -0.1876 0.6874 0.053 Uiso 1 1 calc R . .
N2S N 0.5989(6) 0.6085(6) 0.2309(7) 0.0577(17) Uani 1 1 d . . .
C3S C 0.5843(10) 0.6826(7) 0.2358(4) 0.068(2) Uani 1 1 d . . .
C4S C 0.578(2) 0.7899(16) 0.2428(8) 0.262(15) Uani 1 1 d . . .
H4S1 H 0.6289 0.8483 0.2115 0.394 Uiso 1 1 calc R . .
H4S2 H 0.6035 0.8222 0.2853 0.394 Uiso 1 1 calc R . .
H4S3 H 0.4958 0.7716 0.2363 0.394 Uiso 1 1 calc R . .
C2S C 0.3333 0.6667 0.6022(7) 0.067(5) Uani 1 3 d S . .
H1S H 0.3577 0.6113 0.5868 0.101 Uiso 0.33 1 calc PR . .
H3S H 0.3887 0.7464 0.5868 0.101 Uiso 0.33 1 calc PR . .
H2S H 0.2536 0.6423 0.5868 0.101 Uiso 0.33 1 calc PR . .
C1S C 0.3333 0.6667 0.6777(8) 0.051(3) Uani 1 3 d S . .
N1S N 0.3333 0.6667 0.7251(6) 0.049(2) Uani 1 3 d S . .
B4 B 0.3333 0.6667 0.4158(7) 0.074(6) Uani 1 3 d SD . .
B2 B 0.3333 0.6667 0.0792(14) 0.101(15) Uiso 0.80 3 d SPD A 1
F6 F 0.2417(7) 0.5684(7) 0.4244(12) 0.321(16) Uani 1 1 d D . .
F7 F 0.3333 0.6667 0.3565(6) 0.33(2) Uani 1 3 d SD . .
B1 B 0.0000 0.0000 0.2321(13) 0.27(8) Uani 1 3 d SD . .
F4 F 0.2459(5) 0.5631(5) 0.0773(7) 0.185(7) Uani 1 1 d D A .
F1 F 0.0000 0.0000 0.2916(13) 0.142(12) Uani 1 3 d SD . .
F2 F 0.078(4) -0.029(5) 0.2255(16) 0.61(4) Uani 1 1 d D . .
F3 F 0.3333 0.6667 0.1391(15) 1.4(3) Uiso 0.80 3 d SPD A 1
F5 F 0.3333 0.6667 0.0122(16) 0.26(7) Uiso 0.20 3 d SPD A 2
B3 B 0.3333 0.6667 0.0715(16) 0.018(11) Uiso 0.20 3 d SPD A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C1 163.8(3) 2 .
C1 Ag1 N3 107.6(3) 2 .
C1 Ag1 N3 87.0(3) . .
C1 Ag1 N4 86.5(3) 2 2
C1 Ag1 N4 99.2(3) . 2
N3 Ag1 N4 95.26(18) . 2
C1 Ag1 Ag1 52.53(14) 2 2
C1 Ag1 Ag1 112.28(14) . 2
N3 Ag1 Ag1 133.70(17) . 2
N4 Ag1 Ag1 120.59(16) 2 2
C1 Ag1 Ag1 112.45(14) 2 3
C1 Ag1 Ag1 52.36(14) . 3
N3 Ag1 Ag1 120.68(16) . 3
N4 Ag1 Ag1 128.29(16) 2 3
Ag1 Ag1 Ag1 60.0 2 3
C11 N4 C15 118.1(6) . .
C11 N4 Ag1 121.0(4) . 3
C15 N4 Ag1 120.7(5) . 3
C5 N3 C9 118.5(6) . .
C5 N3 Ag1 121.4(5) . .
C9 N3 Ag1 119.7(5) . .
C1 N1 C10 124.3(6) . .
C1 N1 C2 112.3(9) . .
C10 N1 C2 120.4(8) . .
N1 C10 C11 111.2(5) . .
N1 C10 H10A 109.4 . .
C11 C10 H10A 109.4 . .
N1 C10 H10B 109.4 . .
C11 C10 H10B 109.4 . .
H10A C10 H10B 108.0 . .
C9 C8 C7 118.8(8) . .
C9 C8 H8 120.6 . .
C7 C8 H8 120.6 . .
N3 C5 C6 123.1(6) . .
N3 C5 C4 115.2(6) . .
C6 C5 C4 121.6(6) . .
N4 C11 C12 122.5(6) . .
N4 C11 C10 115.8(5) . .
C12 C11 C10 121.6(6) . .
N2 C1 N1 107.7(7) . .
N2 C1 Ag1 122.2(6) . 3
N1 C1 Ag1 114.2(5) . 3
N2 C1 Ag1 117.4(6) . .
N1 C1 Ag1 117.7(5) . .
Ag1 C1 Ag1 75.11(19) 3 .
N3 C9 C8 121.6(8) . .
N3 C9 H9 119.2 . .
C8 C9 H9 119.2 . .
C6 C7 C8 118.9(7) . .
C6 C7 H7 120.6 . .
C8 C7 H7 120.6 . .
C5 C6 C7 119.0(6) . .
C5 C6 H6 120.5 . .
C7 C6 H6 120.5 . .
C1 N2 C4 121.2(8) . .
C1 N2 C3 112.6(8) . .
C4 N2 C3 121.5(7) . .
N4 C15 C14 123.6(7) . .
N4 C15 H15 118.2 . .
C14 C15 H15 118.2 . .
C15 C14 C13 116.7(8) . .
C15 C14 H14 121.6 . .
C13 C14 H14 121.6 . .
N1 C2 C3 101.8(8) . .
N1 C2 H2A 111.4 . .
C3 C2 H2A 111.4 . .
N1 C2 H2B 111.4 . .
C3 C2 H2B 111.4 . .
H2A C2 H2B 109.3 . .
N2 C4 C5 113.7(6) . .
N2 C4 H4A 108.8 . .
C5 C4 H4A 108.8 . .
N2 C4 H4B 108.8 . .
C5 C4 H4B 108.8 . .
H4A C4 H4B 107.7 . .
N2 C3 C2 101.4(7) . .
N2 C3 H3A 111.5 . .
C2 C3 H3A 111.5 . .
N2 C3 H3B 111.5 . .
C2 C3 H3B 111.5 . .
H3A C3 H3B 109.3 . .
C12 C13 C14 119.4(7) . .
C12 C13 H13 120.3 . .
C14 C13 H13 120.3 . .
C13 C12 C11 119.5(7) . .
C13 C12 H12 120.2 . .
C11 C12 H12 120.2 . .
N2S C3S C4S 174.2(15) . .
C3S C4S H4S1 109.5 . .
C3S C4S H4S2 109.5 . .
H4S1 C4S H4S2 109.5 . .
C3S C4S H4S3 109.5 . .
H4S1 C4S H4S3 109.5 . .
H4S2 C4S H4S3 109.5 . .
C1S C2S H1S 109.5 . .
C1S C2S H3S 109.5 . .
H1S C2S H3S 109.5 . .
C1S C2S H2S 109.5 . .
H1S C2S H2S 109.5 . .
H3S C2S H2S 109.5 . .
N1S C1S C2S 180.000(9) . .
F6 B4 F6 117.9(6) 3_565 .
F6 B4 F6 117.9(6) 3_565 2_665
F6 B4 F6 117.9(6) . 2_665
F6 B4 F7 98.4(12) 3_565 .
F6 B4 F7 98.4(12) . .
F6 B4 F7 98.4(12) 2_665 .
F4 B2 F4 119.90(16) 3_565 .
F4 B2 F4 119.90(16) 3_565 2_665
F4 B2 F4 119.90(16) . 2_665
F4 B2 F3 91.9(14) 3_565 .
F4 B2 F3 91.9(14) . .
F4 B2 F3 91.9(14) 2_665 .
F2 B1 F2 118.8(6) 3 2
F2 B1 F2 118.8(6) 3 .
F2 B1 F2 118.8(6) 2 .
F2 B1 F1 96.3(15) 3 .
F2 B1 F1 96.3(15) 2 .
F2 B1 F1 96.3(15) . .
F5 B3 F4 95.6(14) . 3_565
F5 B3 F4 95.6(14) . .
F4 B3 F4 119.1(5) 3_565 .
F5 B3 F4 95.6(14) . 2_665
F4 B3 F4 119.1(5) 3_565 2_665
F4 B3 F4 119.1(5) . 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.236(6) 2
Ag1 C1 2.241(6) .
Ag1 N3 2.358(6) .
Ag1 N4 2.372(6) 2
Ag1 Ag1 2.7292(5) 2
Ag1 Ag1 2.7292(5) 3
N4 C11 1.327(9) .
N4 C15 1.329(10) .
N4 Ag1 2.372(6) 3
N3 C5 1.343(9) .
N3 C9 1.363(10) .
N1 C1 1.356(12) .
N1 C10 1.448(10) .
N1 C2 1.458(11) .
C10 C11 1.523(10) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C8 C9 1.381(11) .
C8 C7 1.406(12) .
C8 H8 0.9500 .
C5 C6 1.365(9) .
C5 C4 1.529(9) .
C11 C12 1.418(9) .
C1 N2 1.333(11) .
C1 Ag1 2.236(6) 3
C9 H9 0.9500 .
C7 C6 1.389(10) .
C7 H7 0.9500 .
C6 H6 0.9500 .
N2 C4 1.434(11) .
N2 C3 1.468(12) .
C15 C14 1.399(10) .
C15 H15 0.9500 .
C14 C13 1.434(12) .
C14 H14 0.9500 .
C2 C3 1.529(17) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C13 C12 1.327(11) .
C13 H13 0.9500 .
C12 H12 0.9500 .
N2S C3S 1.080(10) .
C3S C4S 1.455(16) .
C4S H4S1 0.9801 .
C4S H4S2 0.9801 .
C4S H4S3 0.9801 .
C2S C1S 1.60(2) .
C2S H1S 0.9801 .
C2S H3S 0.9801 .
C2S H2S 0.9801 .
C1S N1S 1.004(16) .
B4 F6 1.255(7) 3_565
B4 F6 1.255(7) .
B4 F6 1.255(7) 2_665
B4 F7 1.256(9) .
B2 F4 1.261(6) 3_565
B2 F4 1.261(6) .
B2 F4 1.261(6) 2_665
B2 F3 1.268(10) .
B1 F2 1.259(10) 3
B1 F2 1.259(10) 2
B1 F2 1.259(10) .
B1 F1 1.262(10) .
F4 B3 1.266(6) .
F5 B3 1.257(10) .
B3 F4 1.266(6) 3_565
B3 F4 1.266(6) 2_665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ag1 N3 C5 -149.7(6) 2 .
C1 Ag1 N3 C5 23.3(6) . .
N4 Ag1 N3 C5 122.3(5) 2 .
Ag1 Ag1 N3 C5 -95.0(6) 2 .
Ag1 Ag1 N3 C5 -18.8(6) 3 .
C1 Ag1 N3 C9 38.1(6) 2 .
C1 Ag1 N3 C9 -149.0(6) . .
N4 Ag1 N3 C9 -49.9(6) 2 .
Ag1 Ag1 N3 C9 92.7(5) 2 .
Ag1 Ag1 N3 C9 169.0(5) 3 .
C1 N1 C10 C11 81.5(7) . .
C2 N1 C10 C11 -77.2(8) . .
C9 N3 C5 C6 4.9(11) . .
Ag1 N3 C5 C6 -167.4(5) . .
C9 N3 C5 C4 -178.6(7) . .
Ag1 N3 C5 C4 9.1(9) . .
C15 N4 C11 C12 -2.4(11) . .
Ag1 N4 C11 C12 -179.5(5) 3 .
C15 N4 C11 C10 -178.4(6) . .
Ag1 N4 C11 C10 4.4(8) 3 .
N1 C10 C11 N4 -62.0(8) . .
N1 C10 C11 C12 121.9(7) . .
C10 N1 C1 N2 -166.1(6) . .
C2 N1 C1 N2 -5.9(7) . .
C10 N1 C1 Ag1 -26.9(7) . 3
C2 N1 C1 Ag1 133.2(5) . 3
C10 N1 C1 Ag1 58.4(6) . .
C2 N1 C1 Ag1 -141.5(5) . .
C1 Ag1 C1 N2 140.8(16) 2 .
N3 Ag1 C1 N2 -14.4(6) . .
N4 Ag1 C1 N2 -109.2(6) 2 .
Ag1 Ag1 C1 N2 122.1(5) 2 .
Ag1 Ag1 C1 N2 118.9(7) 3 .
C1 Ag1 C1 N1 -87.9(17) 2 .
N3 Ag1 C1 N1 116.9(5) . .
N4 Ag1 C1 N1 22.0(5) 2 .
Ag1 Ag1 C1 N1 -106.6(4) 2 .
Ag1 Ag1 C1 N1 -109.8(6) 3 .
C1 Ag1 C1 Ag1 22(2) 2 3
N3 Ag1 C1 Ag1 -133.3(3) . 3
N4 Ag1 C1 Ag1 131.9(2) 2 3
Ag1 Ag1 C1 Ag1 3.2(3) 2 3
C5 N3 C9 C8 -3.9(11) . .
Ag1 N3 C9 C8 168.6(6) . .
C7 C8 C9 N3 1.0(11) . .
C9 C8 C7 C6 1.0(11) . .
N3 C5 C6 C7 -3.0(11) . .
C4 C5 C6 C7 -179.3(7) . .
C8 C7 C6 C5 -0.1(10) . .
N1 C1 N2 C4 -164.6(5) . .
Ag1 C1 N2 C4 60.2(7) 3 .
Ag1 C1 N2 C4 -28.9(8) . .
N1 C1 N2 C3 -8.6(8) . .
Ag1 C1 N2 C3 -143.8(6) 3 .
Ag1 C1 N2 C3 127.1(6) . .
C11 N4 C15 C14 1.1(11) . .
Ag1 N4 C15 C14 178.3(6) 3 .
N4 C15 C14 C13 -1.2(13) . .
C1 N1 C2 C3 16.7(7) . .
C10 N1 C2 C3 177.7(6) . .
C1 N2 C4 C5 80.8(8) . .
C3 N2 C4 C5 -73.0(9) . .
N3 C5 C4 N2 -64.8(9) . .
C6 C5 C4 N2 111.8(7) . .
C1 N2 C3 C2 18.3(8) . .
C4 N2 C3 C2 174.2(6) . .
N1 C2 C3 N2 -19.5(8) . .
C15 C14 C13 C12 2.6(13) . .
C14 C13 C12 C11 -3.9(13) . .
N4 C11 C12 C13 3.9(12) . .
C10 C11 C12 C13 179.7(7) . .
F4 B2 F4 B3 87(2) 3_565 .
F4 B2 F4 B3 -87(2) 2_665 .
F3 B2 F4 B3 180.000(17) . .
B2 F4 B3 F5 180.000(18) . .
B2 F4 B3 F4 -80(2) . 3_565
B2 F4 B3 F4 80(2) . 2_665
