#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:11:56 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179366 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/63/4326365.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4326365
loop_
_publ_author_name
'Rui Cao'
'Brian D. McCarthy'
'Stephen J. Lippard'
_publ_section_title
;
 Immobilization, Trapping, and Anion Exchange of Perrhenate Ion Using
 Copper-Based Tripodal Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9499
_journal_page_last               9507
_journal_paper_doi               10.1021/ic201172r
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'C60 H60 Cl3 Cu3 F6 N10 O8 P Re2'
_chemical_formula_weight         1863.52
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.9300(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.0723(18)
_cell_length_b                   13.7658(11)
_cell_length_c                   23.2674(18)
_cell_measurement_reflns_used    9850
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.36
_cell_measurement_theta_min      2.39
_cell_volume                     7669.0(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0485
_diffrn_reflns_av_sigmaI/netI    0.0520
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            65495
_diffrn_reflns_theta_full        26.41
_diffrn_reflns_theta_max         26.41
_diffrn_reflns_theta_min         1.70
_exptl_absorpt_coefficient_mu    4.156
_exptl_absorpt_correction_T_max  0.7322
_exptl_absorpt_correction_T_min  0.5745
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.614
_exptl_crystal_description       prism
_exptl_crystal_F_000             3644
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         3.621
_refine_diff_density_min         -2.129
_refine_diff_density_rms         0.200
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.029(8)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     838
_refine_ls_number_reflns         15712
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0559
_refine_ls_R_factor_gt           0.0493
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1034P)²+15.6418P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1407
_refine_ls_wR_factor_ref         0.1483
_reflns_number_gt                14417
_reflns_number_total             15712
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201172r_si_004.cif
_cod_data_source_block           2
_cod_database_code               4326365
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7573(4) 0.3005(8) 0.3516(4) 0.034(2) Uani 1 1 d .
H1A H 0.7639 0.2829 0.3930 0.041 Uiso 1 1 calc R
H1B H 0.7284 0.3518 0.3476 0.041 Uiso 1 1 calc R
C2 C 0.7362(4) 0.2141(8) 0.3184(5) 0.037(2) Uani 1 1 d .
C3 C 0.7380(5) 0.1225(9) 0.3435(5) 0.045(3) Uani 1 1 d .
H3 H 0.7528 0.1162 0.3828 0.054 Uiso 1 1 calc R
C4 C 0.7194(6) 0.0413(9) 0.3141(7) 0.057(3) Uani 1 1 d .
H4 H 0.7200 -0.0191 0.3338 0.068 Uiso 1 1 calc R
C5 C 0.7001(5) 0.0449(8) 0.2570(6) 0.046(3) Uani 1 1 d .
H5 H 0.6883 -0.0124 0.2365 0.055 Uiso 1 1 calc R
C6 C 0.6979(4) 0.1375(8) 0.2288(6) 0.042(3) Uani 1 1 d .
H6 H 0.6853 0.1423 0.1889 0.050 Uiso 1 1 calc R
C7 C 0.7143(4) 0.2196(7) 0.2599(4) 0.030(2) Uani 1 1 d .
C8 C 0.7066(3) 0.3172(7) 0.2272(4) 0.0273(19) Uani 1 1 d .
H8A H 0.7313 0.3664 0.2476 0.033 Uiso 1 1 calc R
H8B H 0.7186 0.3089 0.1880 0.033 Uiso 1 1 calc R
C9 C 0.6388(4) 0.4176(7) 0.1721(5) 0.034(2) Uani 1 1 d .
H9A H 0.6743 0.4502 0.1659 0.040 Uiso 1 1 calc R
H9B H 0.6114 0.4684 0.1798 0.040 Uiso 1 1 calc R
C10 C 0.6175(4) 0.3631(8) 0.1182(4) 0.032(2) Uani 1 1 d .
C11 C 0.6149(4) 0.4040(10) 0.0638(5) 0.044(3) Uani 1 1 d .
H11 H 0.6300 0.4668 0.0588 0.053 Uiso 1 1 calc R
C12 C 0.5906(5) 0.3544(13) 0.0177(5) 0.055(4) Uani 1 1 d .
H12 H 0.5874 0.3832 -0.0196 0.066 Uiso 1 1 calc R
C13 C 0.5699(5) 0.2587(10) 0.0253(5) 0.046(3) Uani 1 1 d .
H13 H 0.5528 0.2210 -0.0059 0.055 Uiso 1 1 calc R
C14 C 0.5764(4) 0.2266(10) 0.0797(5) 0.041(2) Uani 1 1 d .
H14 H 0.5645 0.1618 0.0852 0.049 Uiso 1 1 calc R
C15 C 0.6338(4) 0.4006(8) 0.2756(4) 0.0302(18) Uani 1 1 d .
H15A H 0.6042 0.4496 0.2663 0.036 Uiso 1 1 calc R
H15B H 0.6672 0.4346 0.2943 0.036 Uiso 1 1 calc R
C16 C 0.6142(4) 0.3270(7) 0.3170(4) 0.032(2) Uani 1 1 d .
C17 C 0.6147(5) 0.3491(10) 0.3760(4) 0.046(3) Uani 1 1 d .
H17 H 0.6304 0.4079 0.3916 0.055 Uiso 1 1 calc R
C18 C 0.5918(6) 0.2833(12) 0.4097(5) 0.060(4) Uani 1 1 d .
H18 H 0.5906 0.2973 0.4495 0.071 Uiso 1 1 calc R
C19 C 0.5701(6) 0.1960(12) 0.3879(6) 0.064(4) Uani 1 1 d .
H19 H 0.5543 0.1498 0.4119 0.077 Uiso 1 1 calc R
C20 C 0.5725(5) 0.1791(10) 0.3287(5) 0.047(3) Uani 1 1 d .
H20 H 0.5590 0.1194 0.3122 0.056 Uiso 1 1 calc R
C21 C 0.8226(5) 0.4360(10) 0.3569(4) 0.042(3) Uani 1 1 d .
H21A H 0.8611 0.4545 0.3500 0.051 Uiso 1 1 calc R
H21B H 0.8208 0.4333 0.3992 0.051 Uiso 1 1 calc R
C22 C 0.7830(5) 0.5118(8) 0.3317(5) 0.038(2) Uani 1 1 d .
C23 C 0.7418(5) 0.5522(10) 0.3654(6) 0.050(3) Uani 1 1 d .
H23 H 0.7410 0.5316 0.4043 0.060 Uiso 1 1 calc R
C24 C 0.7032(5) 0.6203(9) 0.3429(7) 0.058(4) Uani 1 1 d .
H24 H 0.6789 0.6508 0.3670 0.069 Uiso 1 1 calc R
C25 C 0.7006(5) 0.6428(8) 0.2863(7) 0.048(3) Uani 1 1 d .
H25 H 0.6719 0.6850 0.2700 0.058 Uiso 1 1 calc R
C26 C 0.7391(4) 0.6054(7) 0.2515(6) 0.037(2) Uani 1 1 d .
H26 H 0.7375 0.6232 0.2119 0.045 Uiso 1 1 calc R
C27 C 0.7816(4) 0.5392(6) 0.2761(4) 0.0270(19) Uani 1 1 d .
C28 C 0.8251(4) 0.5109(6) 0.2371(4) 0.0266(19) Uani 1 1 d .
H28A H 0.8063 0.4974 0.1981 0.032 Uiso 1 1 calc R
H28B H 0.8432 0.4499 0.2518 0.032 Uiso 1 1 calc R
C29 C 0.8960(4) 0.5729(6) 0.1774(4) 0.0248(18) Uani 1 1 d .
H29A H 0.8984 0.5027 0.1688 0.030 Uiso 1 1 calc R
H29B H 0.9343 0.6001 0.1813 0.030 Uiso 1 1 calc R
C30 C 0.8613(4) 0.6228(8) 0.1295(5) 0.033(2) Uani 1 1 d .
C31 C 0.8634(5) 0.5979(9) 0.0721(5) 0.045(3) Uani 1 1 d .
H31 H 0.8866 0.5471 0.0606 0.054 Uiso 1 1 calc R
C32 C 0.8281(6) 0.6541(13) 0.0309(6) 0.064(5) Uani 1 1 d .
H32 H 0.8274 0.6408 -0.0093 0.077 Uiso 1 1 calc R
C33 C 0.7963(6) 0.7253(11) 0.0492(7) 0.066(5) Uani 1 1 d .
H33 H 0.7731 0.7624 0.0219 0.079 Uiso 1 1 calc R
C34 C 0.7970(5) 0.7438(9) 0.1039(6) 0.052(3) Uani 1 1 d .
H34 H 0.7737 0.7948 0.1150 0.063 Uiso 1 1 calc R
C35 C 0.9125(4) 0.5856(8) 0.2821(4) 0.033(2) Uani 1 1 d .
H35A H 0.9192 0.5177 0.2950 0.040 Uiso 1 1 calc R
H35B H 0.9480 0.6120 0.2709 0.040 Uiso 1 1 calc R
C36 C 0.8948(5) 0.6430(10) 0.3302(5) 0.048(3) Uani 1 1 d .
C37 C 0.9148(7) 0.6243(12) 0.3890(6) 0.065(4) Uani 1 1 d .
H37 H 0.9395 0.5716 0.3988 0.078 Uiso 1 1 calc R
C38 C 0.8981(10) 0.6830(16) 0.4304(7) 0.096(7) Uani 1 1 d .
H38 H 0.9128 0.6749 0.4696 0.115 Uiso 1 1 calc R
C39 C 0.8587(8) 0.7562(15) 0.4149(8) 0.089(6) Uani 1 1 d .
H39 H 0.8452 0.7962 0.4436 0.106 Uiso 1 1 calc R
C40 C 0.8403(6) 0.7691(11) 0.3580(6) 0.062(4) Uani 1 1 d .
H40 H 0.8142 0.8193 0.3475 0.074 Uiso 1 1 calc R
C41 C 0.8582(5) 0.2692(9) 0.3464(5) 0.045(3) Uani 1 1 d .
H41A H 0.8696 0.2695 0.3885 0.054 Uiso 1 1 calc R
H41B H 0.8454 0.2028 0.3353 0.054 Uiso 1 1 calc R
C42 C 0.9070(4) 0.2950(8) 0.3150(5) 0.039(2) Uani 1 1 d .
C43 C 0.9540(5) 0.3319(9) 0.3468(7) 0.055(3) Uani 1 1 d .
H43 H 0.9549 0.3349 0.3876 0.066 Uiso 1 1 calc R
C44 C 1.0017(5) 0.3660(8) 0.3198(5) 0.044(3) Uani 1 1 d .
H44 H 1.0337 0.3925 0.3415 0.052 Uiso 1 1 calc R
C45 C 0.9978(5) 0.3576(9) 0.2589(6) 0.050(3) Uani 1 1 d .
H45 H 1.0275 0.3801 0.2385 0.060 Uiso 1 1 calc R
C46 C 0.9520(5) 0.3176(7) 0.2297(6) 0.043(3) Uani 1 1 d .
H46 H 0.9509 0.3120 0.1889 0.051 Uiso 1 1 calc R
C47 C 0.9065(4) 0.2845(7) 0.2559(5) 0.034(2) Uani 1 1 d .
C48 C 0.8592(4) 0.2361(7) 0.2184(5) 0.032(2) Uani 1 1 d .
H48A H 0.8253 0.2376 0.2391 0.038 Uiso 1 1 calc R
H48B H 0.8512 0.2743 0.1825 0.038 Uiso 1 1 calc R
C49 C 0.8318(4) 0.1037(8) 0.1526(5) 0.038(2) Uani 1 1 d .
H49A H 0.7956 0.1369 0.1547 0.046 Uiso 1 1 calc R
H49B H 0.8252 0.0328 0.1538 0.046 Uiso 1 1 calc R
C50 C 0.8540(5) 0.1294(7) 0.0972(5) 0.038(2) Uani 1 1 d .
C51 C 0.8202(5) 0.1283(9) 0.0455(6) 0.049(3) Uani 1 1 d .
H51 H 0.7817 0.1128 0.0450 0.058 Uiso 1 1 calc R
C52 C 0.8420(5) 0.1494(9) -0.0043(6) 0.047(3) Uani 1 1 d .
H52 H 0.8191 0.1494 -0.0401 0.056 Uiso 1 1 calc R
C53 C 0.9010(6) 0.1719(11) -0.0020(5) 0.058(3) Uani 1 1 d .
H53 H 0.9181 0.1881 -0.0357 0.069 Uiso 1 1 calc R
C54 C 0.9302(4) 0.1688(8) 0.0505(5) 0.042(3) Uani 1 1 d .
H54 H 0.9691 0.1819 0.0529 0.050 Uiso 1 1 calc R
C55 C 0.8700(4) 0.0643(8) 0.2518(5) 0.040(3) Uani 1 1 d .
H55A H 0.8606 -0.0018 0.2373 0.048 Uiso 1 1 calc R
H55B H 0.8409 0.0849 0.2764 0.048 Uiso 1 1 calc R
C56 C 0.9277(5) 0.0624(8) 0.2886(5) 0.038(2) Uani 1 1 d .
C57 C 0.9332(6) 0.0342(9) 0.3420(7) 0.057(4) Uani 1 1 d .
H57 H 0.9017 0.0120 0.3598 0.068 Uiso 1 1 calc R
C58 C 0.9858(7) 0.0367(10) 0.3727(7) 0.061(4) Uani 1 1 d .
H58 H 0.9905 0.0194 0.4125 0.073 Uiso 1 1 calc R
C59 C 1.0316(6) 0.0648(10) 0.3450(6) 0.052(3) Uani 1 1 d .
H59 H 1.0682 0.0668 0.3646 0.062 Uiso 1 1 calc R
C60 C 1.0212(5) 0.0897(8) 0.2874(5) 0.042(3) Uani 1 1 d .
H60 H 1.0518 0.1077 0.2669 0.051 Uiso 1 1 calc R
Cl1 Cl 0.54481(10) 0.10231(18) 0.19669(13) 0.0399(6) Uani 1 1 d .
Cl2 Cl 0.78453(13) 0.8547(2) 0.22965(19) 0.0642(10) Uani 1 1 d .
Cl3 Cl 1.03594(10) 0.1290(2) 0.14993(13) 0.0406(6) Uani 1 1 d .
Cu1 Cu 0.59283(4) 0.24064(8) 0.20906(5) 0.0261(2) Uani 1 1 d .
Cu2 Cu 0.83637(5) 0.72167(8) 0.23078(6) 0.0355(3) Uani 1 1 d .
Cu3 Cu 0.94962(5) 0.11983(8) 0.17586(5) 0.0302(3) Uani 1 1 d .
F1 F 0.6830(4) 0.4347(9) 0.4857(4) 0.085(3) Uani 1 1 d .
F2 F 0.7132(6) 0.5848(12) 0.5110(4) 0.144(7) Uani 1 1 d .
F3 F 0.6766(5) 0.4868(9) 0.5766(3) 0.095(4) Uani 1 1 d .
F4 F 0.6330(5) 0.5690(8) 0.4514(4) 0.091(3) Uani 1 1 d .
F5 F 0.5997(4) 0.4664(8) 0.5152(4) 0.080(3) Uani 1 1 d .
F6 F 0.6287(8) 0.6165(9) 0.5416(5) 0.136(6) Uani 1 1 d .
N1 N 0.8103(3) 0.3406(6) 0.3326(3) 0.0287(16) Uani 1 1 d .
N2 N 0.6478(3) 0.3542(6) 0.2218(3) 0.0243(15) Uani 1 1 d .
N3 N 0.5971(3) 0.2722(6) 0.1266(3) 0.0294(17) Uani 1 1 d .
N4 N 0.5938(3) 0.2466(6) 0.2947(3) 0.0316(18) Uani 1 1 d .
N5 N 0.8703(3) 0.5869(6) 0.2319(3) 0.0251(16) Uani 1 1 d .
N6 N 0.8282(3) 0.6960(6) 0.1459(4) 0.035(2) Uani 1 1 d .
N7 N 0.8580(4) 0.7126(7) 0.3166(5) 0.044(2) Uani 1 1 d .
N8 N 0.8705(3) 0.1319(6) 0.2024(4) 0.0330(19) Uani 1 1 d .
N9 N 0.9080(3) 0.1484(5) 0.0991(4) 0.0278(17) Uani 1 1 d .
N10 N 0.9702(4) 0.0895(6) 0.2593(4) 0.0354(19) Uani 1 1 d .
O1 O 0.5250(3) 0.3688(4) 0.2035(3) 0.0318(16) Uani 1 1 d .
O2 O 0.4222(3) 0.2864(5) 0.2243(3) 0.0369(16) Uani 1 1 d .
O3 O 0.4239(3) 0.4559(5) 0.1552(4) 0.0446(19) Uani 1 1 d .
O4 O 0.4570(3) 0.2762(5) 0.1126(3) 0.0369(16) Uani 1 1 d .
O5 O 0.3447(3) 0.8793(5) 0.1070(3) 0.0356(16) Uani 1 1 d .
O6 O 0.2407(3) 0.7893(5) 0.0893(3) 0.0353(16) Uani 1 1 d .
O7 O 0.2750(3) 0.9102(7) 0.0042(4) 0.050(2) Uani 1 1 d .
O8 O 0.2460(3) 0.9914(5) 0.1084(3) 0.0347(15) Uani 1 1 d .
P1 P 0.6504(2) 0.5299(3) 0.51280(13) 0.0751(15) Uani 1 1 d .
Re1 Re 0.457534(13) 0.34748(2) 0.173881(16) 0.02595(10) Uani 1 1 d .
Re2 Re 0.276425(14) 0.89407(3) 0.076233(15) 0.02615(10) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C2 C1 N1 113.7(9) .
C2 C1 H1A 108.8 .
N1 C1 H1A 108.8 .
C2 C1 H1B 108.8 .
N1 C1 H1B 108.8 .
H1A C1 H1B 107.7 .
C3 C2 C7 116.5(11) .
C3 C2 C1 121.1(9) .
C7 C2 C1 122.3(9) .
C4 C3 C2 122.7(11) .
C4 C3 H3 118.7 .
C2 C3 H3 118.7 .
C5 C4 C3 121.5(11) .
C5 C4 H4 119.2 .
C3 C4 H4 119.2 .
C4 C5 C6 118.1(11) .
C4 C5 H5 120.9 .
C6 C5 H5 120.9 .
C7 C6 C5 119.7(11) .
C7 C6 H6 120.2 .
C5 C6 H6 120.2 .
C6 C7 C2 121.4(10) .
C6 C7 C8 116.2(9) .
C2 C7 C8 122.4(9) .
N2 C8 C7 113.7(7) .
N2 C8 H8A 108.8 .
C7 C8 H8A 108.8 .
N2 C8 H8B 108.8 .
C7 C8 H8B 108.8 .
H8A C8 H8B 107.7 .
N2 C9 C10 112.0(8) .
N2 C9 H9A 109.2 .
C10 C9 H9A 109.2 .
N2 C9 H9B 109.2 .
C10 C9 H9B 109.2 .
H9A C9 H9B 107.9 .
N3 C10 C11 121.5(10) .
N3 C10 C9 115.6(8) .
C11 C10 C9 122.7(10) .
C12 C11 C10 119.8(13) .
C12 C11 H11 120.1 .
C10 C11 H11 120.1 .
C11 C12 C13 119.8(12) .
C11 C12 H12 120.1 .
C13 C12 H12 120.1 .
C14 C13 C12 114.5(11) .
C14 C13 H13 122.8 .
C12 C13 H13 122.8 .
N3 C14 C13 128.9(13) .
N3 C14 H14 115.5 .
C13 C14 H14 115.5 .
N2 C15 C16 111.4(8) .
N2 C15 H15A 109.4 .
C16 C15 H15A 109.4 .
N2 C15 H15B 109.4 .
C16 C15 H15B 109.4 .
H15A C15 H15B 108.0 .
N4 C16 C17 122.7(10) .
N4 C16 C15 116.7(8) .
C17 C16 C15 120.4(10) .
C18 C17 C16 117.3(13) .
C18 C17 H17 121.4 .
C16 C17 H17 121.4 .
C17 C18 C19 122.0(12) .
C17 C18 H18 119.0 .
C19 C18 H18 119.0 .
C18 C19 C20 116.8(12) .
C18 C19 H19 121.6 .
C20 C19 H19 121.6 .
N4 C20 C19 121.1(12) .
N4 C20 H20 119.4 .
C19 C20 H20 119.4 .
N1 C21 C22 112.6(8) .
N1 C21 H21A 109.1 .
C22 C21 H21A 109.1 .
N1 C21 H21B 109.1 .
C22 C21 H21B 109.1 .
H21A C21 H21B 107.8 .
C27 C22 C23 117.7(11) .
C27 C22 C21 121.8(9) .
C23 C22 C21 120.3(11) .
C24 C23 C22 121.9(12) .
C24 C23 H23 119.0 .
C22 C23 H23 119.0 .
C25 C24 C23 119.2(11) .
C25 C24 H24 120.4 .
C23 C24 H24 120.4 .
C24 C25 C26 121.1(12) .
C24 C25 H25 119.5 .
C26 C25 H25 119.5 .
C25 C26 C27 119.4(11) .
C25 C26 H26 120.3 .
C27 C26 H26 120.3 .
C22 C27 C26 120.4(9) .
C22 C27 C28 123.8(9) .
C26 C27 C28 115.7(9) .
C27 C28 N5 114.6(7) .
C27 C28 H28A 108.6 .
N5 C28 H28A 108.6 .
C27 C28 H28B 108.6 .
N5 C28 H28B 108.6 .
H28A C28 H28B 107.6 .
N5 C29 C30 109.2(8) .
N5 C29 H29A 109.8 .
C30 C29 H29A 109.8 .
N5 C29 H29B 109.8 .
C30 C29 H29B 109.8 .
H29A C29 H29B 108.3 .
N6 C30 C31 122.2(11) .
N6 C30 C29 115.5(9) .
C31 C30 C29 122.3(11) .
C30 C31 C32 115.6(14) .
C30 C31 H31 122.2 .
C32 C31 H31 122.2 .
C33 C32 C31 119.9(13) .
C33 C32 H32 120.0 .
C31 C32 H32 120.0 .
C34 C33 C32 120.4(11) .
C34 C33 H33 119.8 .
C32 C33 H33 119.8 .
C33 C34 N6 124.6(14) .
C33 C34 H34 117.7 .
N6 C34 H34 117.7 .
C36 C35 N5 111.6(9) .
C36 C35 H35A 109.3 .
N5 C35 H35A 109.3 .
C36 C35 H35B 109.3 .
N5 C35 H35B 109.3 .
H35A C35 H35B 108.0 .
N7 C36 C37 120.8(12) .
N7 C36 C35 116.6(11) .
C37 C36 C35 122.6(12) .
C38 C37 C36 118.8(17) .
C38 C37 H37 120.6 .
C36 C37 H37 120.6 .
C37 C38 C39 119.2(16) .
C37 C38 H38 120.4 .
C39 C38 H38 120.4 .
C40 C39 C38 119.1(14) .
C40 C39 H39 120.5 .
C38 C39 H39 120.5 .
N7 C40 C39 121.8(16) .
N7 C40 H40 119.1 .
C39 C40 H40 119.1 .
C42 C41 N1 111.2(9) .
C42 C41 H41A 109.4 .
N1 C41 H41A 109.4 .
C42 C41 H41B 109.4 .
N1 C41 H41B 109.4 .
H41A C41 H41B 108.0 .
C43 C42 C47 119.6(11) .
C43 C42 C41 118.0(11) .
C47 C42 C41 122.5(10) .
C42 C43 C44 122.1(13) .
C42 C43 H43 119.0 .
C44 C43 H43 119.0 .
C45 C44 C43 115.8(11) .
C45 C44 H44 122.1 .
C43 C44 H44 122.1 .
C46 C45 C44 120.2(11) .
C46 C45 H45 119.9 .
C44 C45 H45 119.9 .
C45 C46 C47 123.7(13) .
C45 C46 H46 118.2 .
C47 C46 H46 118.2 .
C42 C47 C46 118.5(11) .
C42 C47 C48 123.2(9) .
C46 C47 C48 118.3(10) .
N8 C48 C47 114.5(8) .
N8 C48 H48A 108.6 .
C47 C48 H48A 108.6 .
N8 C48 H48B 108.6 .
C47 C48 H48B 108.6 .
H48A C48 H48B 107.6 .
N8 C49 C50 111.5(9) .
N8 C49 H49A 109.3 .
C50 C49 H49A 109.3 .
N8 C49 H49B 109.3 .
C50 C49 H49B 109.3 .
H49A C49 H49B 108.0 .
N9 C50 C51 121.4(12) .
N9 C50 C49 117.2(10) .
C51 C50 C49 121.3(11) .
C52 C51 C50 120.0(12) .
C52 C51 H51 120.0 .
C50 C51 H51 120.0 .
C51 C52 C53 118.6(11) .
C51 C52 H52 120.7 .
C53 C52 H52 120.7 .
C54 C53 C52 116.5(12) .
C54 C53 H53 121.8 .
C52 C53 H53 121.8 .
N9 C54 C53 124.0(11) .
N9 C54 H54 118.0 .
C53 C54 H54 118.0 .
N8 C55 C56 111.1(8) .
N8 C55 H55A 109.4 .
C56 C55 H55A 109.4 .
N8 C55 H55B 109.4 .
C56 C55 H55B 109.4 .
H55A C55 H55B 108.0 .
C57 C56 N10 124.4(11) .
C57 C56 C55 122.0(11) .
N10 C56 C55 113.6(9) .
C56 C57 C58 118.9(13) .
C56 C57 H57 120.5 .
C58 C57 H57 120.5 .
C59 C58 C57 119.5(14) .
C59 C58 H58 120.3 .
C57 C58 H58 120.3 .
C60 C59 C58 116.7(13) .
C60 C59 H59 121.7 .
C58 C59 H59 121.7 .
N10 C60 C59 122.8(12) .
N10 C60 H60 118.6 .
C59 C60 H60 118.6 .
N3 Cu1 N4 164.5(4) .
N3 Cu1 N2 82.8(3) .
N4 Cu1 N2 83.3(3) .
N3 Cu1 Cl1 98.1(3) .
N4 Cu1 Cl1 96.7(3) .
N2 Cu1 Cl1 171.0(2) .
N3 Cu1 O1 83.6(3) .
N4 Cu1 O1 87.8(3) .
N2 Cu1 O1 82.7(3) .
Cl1 Cu1 O1 106.27(17) .
N6 Cu2 N7 163.4(4) .
N6 Cu2 N5 81.3(3) .
N7 Cu2 N5 82.4(3) .
N6 Cu2 Cl2 97.9(3) .
N7 Cu2 Cl2 98.7(3) .
N5 Cu2 Cl2 169.5(2) .
N6 Cu2 O2 90.0(3) 3
N7 Cu2 O2 86.9(3) 3
N5 Cu2 O2 89.6(3) 3
Cl2 Cu2 O2 101.0(2) 3
N9 Cu3 N10 164.3(4) .
N9 Cu3 N8 81.8(3) .
N10 Cu3 N8 82.6(4) .
N9 Cu3 Cl3 98.2(2) .
N10 Cu3 Cl3 97.5(3) .
N8 Cu3 Cl3 172.0(3) .
N9 Cu3 O3 84.8(3) 3_545
N10 Cu3 O3 91.8(3) 3_545
N8 Cu3 O3 84.8(3) 3_545
Cl3 Cu3 O3 103.3(2) 3_545
C21 N1 C1 111.4(8) .
C21 N1 C41 112.5(8) .
C1 N1 C41 110.5(8) .
C9 N2 C15 112.8(8) .
C9 N2 C8 109.6(7) .
C15 N2 C8 111.8(7) .
C9 N2 Cu1 107.7(5) .
C15 N2 Cu1 104.6(5) .
C8 N2 Cu1 110.1(6) .
C14 N3 C10 115.4(9) .
C14 N3 Cu1 130.4(8) .
C10 N3 Cu1 113.4(6) .
C16 N4 C20 120.1(9) .
C16 N4 Cu1 113.6(7) .
C20 N4 Cu1 126.2(8) .
C35 N5 C29 111.4(7) .
C35 N5 C28 111.7(7) .
C29 N5 C28 110.1(7) .
C35 N5 Cu2 105.5(6) .
C29 N5 Cu2 108.2(5) .
C28 N5 Cu2 109.9(5) .
C34 N6 C30 117.3(11) .
C34 N6 Cu2 128.6(9) .
C30 N6 Cu2 114.0(7) .
C36 N7 C40 120.2(12) .
C36 N7 Cu2 112.4(8) .
C40 N7 Cu2 127.4(10) .
C49 N8 C55 113.1(9) .
C49 N8 C48 109.3(8) .
C55 N8 C48 112.8(9) .
C49 N8 Cu3 105.9(7) .
C55 N8 Cu3 105.3(6) .
C48 N8 Cu3 110.2(6) .
C50 N9 C54 119.5(9) .
C50 N9 Cu3 113.2(7) .
C54 N9 Cu3 126.4(7) .
C60 N10 C56 117.7(10) .
C60 N10 Cu3 127.0(8) .
C56 N10 Cu3 115.3(7) .
Re1 O1 Cu1 120.3(3) .
Re1 O2 Cu2 138.5(4) 3_445
Re1 O3 Cu3 131.5(4) 3_455
F6 P1 F5 97.1(8) .
F6 P1 F4 93.6(7) .
F5 P1 F4 95.4(6) .
F6 P1 F3 90.1(7) .
F5 P1 F3 89.6(5) .
F4 P1 F3 173.4(7) .
F6 P1 F1 172.4(8) .
F5 P1 F1 88.5(6) .
F4 P1 F1 91.0(6) .
F3 P1 F1 84.8(6) .
F6 P1 F2 90.5(9) .
F5 P1 F2 171.0(9) .
F4 P1 F2 88.8(6) .
F3 P1 F2 85.7(6) .
F1 P1 F2 83.5(8) .
O1 Re1 O4 110.7(3) .
O1 Re1 O3 110.5(3) .
O4 Re1 O3 108.5(4) .
O1 Re1 O2 108.7(3) .
O4 Re1 O2 108.7(3) .
O3 Re1 O2 109.8(4) .
O7 Re2 O6 109.0(4) .
O7 Re2 O8 111.2(4) .
O6 Re2 O8 109.2(3) .
O7 Re2 O5 110.3(4) .
O6 Re2 O5 107.4(3) .
O8 Re2 O5 109.6(3) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.478(15) .
C1 N1 1.496(12) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 C3 1.389(16) .
C2 C7 1.411(14) .
C3 C4 1.361(19) .
C3 H3 0.9500 .
C4 C5 1.36(2) .
C4 H4 0.9500 .
C5 C6 1.433(16) .
C5 H5 0.9500 .
C6 C7 1.377(15) .
C6 H6 0.9500 .
C7 C8 1.545(13) .
C8 N2 1.498(10) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 N2 1.447(12) .
C9 C10 1.505(14) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 N3 1.365(14) .
C10 C11 1.380(15) .
C11 C12 1.352(18) .
C11 H11 0.9500 .
C12 C13 1.43(2) .
C12 H12 0.9500 .
C13 C14 1.335(17) .
C13 H13 0.9500 .
C14 N3 1.313(14) .
C14 H14 0.9500 .
C15 N2 1.477(12) .
C15 C16 1.506(13) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 N4 1.297(13) .
C16 C17 1.407(14) .
C17 C18 1.352(19) .
C17 H17 0.9500 .
C18 C19 1.39(2) .
C18 H18 0.9500 .
C19 C20 1.40(2) .
C19 H19 0.9500 .
C20 N4 1.355(14) .
C20 H20 0.9500 .
C21 N1 1.449(15) .
C21 C22 1.491(17) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C27 1.343(15) .
C22 C23 1.440(15) .
C23 C24 1.38(2) .
C23 H23 0.9500 .
C24 C25 1.35(2) .
C24 H24 0.9500 .
C25 C26 1.393(15) .
C25 H25 0.9500 .
C26 C27 1.443(14) .
C26 H26 0.9500 .
C27 C28 1.507(13) .
C28 N5 1.523(11) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 N5 1.481(12) .
C29 C30 1.489(14) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
C30 N6 1.363(14) .
C30 C31 1.386(16) .
C31 C32 1.44(2) .
C31 H31 0.9500 .
C32 C33 1.34(2) .
C32 H32 0.9500 .
C33 C34 1.30(2) .
C33 H33 0.9500 .
C34 N6 1.344(14) .
C34 H34 0.9500 .
C35 C36 1.466(16) .
C35 N5 1.467(12) .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 N7 1.321(17) .
C36 C37 1.426(19) .
C37 C38 1.35(2) .
C37 H37 0.9500 .
C38 C39 1.41(3) .
C38 H38 0.9500 .
C39 C40 1.36(2) .
C39 H39 0.9500 .
C40 N7 1.343(15) .
C40 H40 0.9500 .
C41 C42 1.489(16) .
C41 N1 1.524(14) .
C41 H41A 0.9900 .
C41 H41B 0.9900 .
C42 C43 1.381(16) .
C42 C47 1.383(16) .
C43 C44 1.443(17) .
C43 H43 0.9500 .
C44 C45 1.414(18) .
C44 H44 0.9500 .
C45 C46 1.351(17) .
C45 H45 0.9500 .
C46 C47 1.383(15) .
C46 H46 0.9500 .
C47 C48 1.516(14) .
C48 N8 1.514(12) .
C48 H48A 0.9900 .
C48 H48B 0.9900 .
C49 N8 1.462(14) .
C49 C50 1.489(17) .
C49 H49A 0.9900 .
C49 H49B 0.9900 .
C50 N9 1.321(14) .
C50 C51 1.380(16) .
C51 C52 1.352(19) .
C51 H51 0.9500 .
C52 C53 1.45(2) .
C52 H52 0.9500 .
C53 C54 1.345(17) .
C53 H53 0.9500 .
C54 N9 1.332(14) .
C54 H54 0.9500 .
C55 N8 1.481(14) .
C55 C56 1.554(15) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C56 C57 1.295(18) .
C56 N10 1.341(14) .
C57 C58 1.39(2) .
C57 H57 0.9500 .
C58 C59 1.39(2) .
C58 H58 0.9500 .
C59 C60 1.381(18) .
C59 H59 0.9500 .
C60 N10 1.330(14) .
C60 H60 0.9500 .
Cl1 Cu1 2.231(3) .
Cl2 Cu2 2.214(3) .
Cl3 Cu3 2.226(3) .
Cu1 N3 1.979(8) .
Cu1 N4 1.991(8) .
Cu1 N2 2.049(8) .
Cu1 O1 2.399(6) .
Cu2 N6 1.996(10) .
Cu2 N7 2.014(11) .
Cu2 N5 2.025(8) .
Cu2 O2 2.270(7) 3
Cu3 N9 1.995(8) .
Cu3 N10 1.996(9) .
Cu3 N8 2.068(8) .
Cu3 O3 2.376(7) 3_545
F1 P1 1.682(12) .
F2 P1 1.695(11) .
F3 P1 1.661(10) .
F4 P1 1.544(10) .
F5 P1 1.506(10) .
F6 P1 1.490(15) .
O1 Re1 1.722(6) .
O2 Re1 1.735(7) .
O2 Cu2 2.270(7) 3_445
O3 Re1 1.731(7) .
O3 Cu3 2.376(7) 3_455
O4 Re1 1.730(7) .
O5 Re2 1.734(7) .
O6 Re2 1.722(6) .
O7 Re2 1.686(8) .
O8 Re2 1.733(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N1 C1 C2 C3 109.4(12) .
N1 C1 C2 C7 -69.2(12) .
C7 C2 C3 C4 -0.6(18) .
C1 C2 C3 C4 -179.2(12) .
C2 C3 C4 C5 3(2) .
C3 C4 C5 C6 -2.0(19) .
C4 C5 C6 C7 -1.1(16) .
C5 C6 C7 C2 3.5(15) .
C5 C6 C7 C8 -175.7(9) .
C3 C2 C7 C6 -2.6(15) .
C1 C2 C7 C6 176.0(9) .
C3 C2 C7 C8 176.5(9) .
C1 C2 C7 C8 -4.9(15) .
C6 C7 C8 N2 78.8(11) .
C2 C7 C8 N2 -100.3(11) .
N2 C9 C10 N3 16.0(11) .
N2 C9 C10 C11 -168.6(8) .
N3 C10 C11 C12 1.2(14) .
C9 C10 C11 C12 -173.9(9) .
C10 C11 C12 C13 -2.4(16) .
C11 C12 C13 C14 0.5(16) .
C12 C13 C14 N3 2.9(17) .
N2 C15 C16 N4 -23.4(11) .
N2 C15 C16 C17 160.9(9) .
N4 C16 C17 C18 -1.2(17) .
C15 C16 C17 C18 174.2(11) .
C16 C17 C18 C19 2(2) .
C17 C18 C19 C20 0(2) .
C18 C19 C20 N4 -2(2) .
N1 C21 C22 C27 -66.9(13) .
N1 C21 C22 C23 107.9(11) .
C27 C22 C23 C24 -2.8(17) .
C21 C22 C23 C24 -177.8(11) .
C22 C23 C24 C25 6.4(18) .
C23 C24 C25 C26 -5.7(18) .
C24 C25 C26 C27 1.7(16) .
C23 C22 C27 C26 -1.3(15) .
C21 C22 C27 C26 173.6(9) .
C23 C22 C27 C28 173.9(9) .
C21 C22 C27 C28 -11.2(15) .
C25 C26 C27 C22 1.9(15) .
C25 C26 C27 C28 -173.7(9) .
C22 C27 C28 N5 -96.9(11) .
C26 C27 C28 N5 78.5(10) .
N5 C29 C30 N6 22.8(11) .
N5 C29 C30 C31 -158.5(8) .
N6 C30 C31 C32 -0.3(14) .
C29 C30 C31 C32 -178.9(9) .
C30 C31 C32 C33 0.2(15) .
C31 C32 C33 C34 -0.1(18) .
C32 C33 C34 N6 0.1(18) .
N5 C35 C36 N7 -24.4(14) .
N5 C35 C36 C37 154.2(12) .
N7 C36 C37 C38 -4(2) .
C35 C36 C37 C38 177.5(16) .
C36 C37 C38 C39 4(3) .
C37 C38 C39 C40 -3(3) .
C38 C39 C40 N7 1(3) .
N1 C41 C42 C43 108.9(11) .
N1 C41 C42 C47 -70.4(14) .
C47 C42 C43 C44 4.1(17) .
C41 C42 C43 C44 -175.1(11) .
C42 C43 C44 C45 -1.2(17) .
C43 C44 C45 C46 -1.4(16) .
C44 C45 C46 C47 1.1(17) .
C43 C42 C47 C46 -4.4(15) .
C41 C42 C47 C46 174.8(10) .
C43 C42 C47 C48 174.1(10) .
C41 C42 C47 C48 -6.7(16) .
C45 C46 C47 C42 1.9(15) .
C45 C46 C47 C48 -176.7(9) .
C42 C47 C48 N8 -100.2(11) .
C46 C47 C48 N8 78.3(11) .
N8 C49 C50 N9 17.0(13) .
N8 C49 C50 C51 -166.4(9) .
N9 C50 C51 C52 -1.7(17) .
C49 C50 C51 C52 -178.2(11) .
C50 C51 C52 C53 0.5(18) .
C51 C52 C53 C54 0.9(19) .
C52 C53 C54 N9 -1.3(19) .
N8 C55 C56 C57 158.3(11) .
N8 C55 C56 N10 -23.7(13) .
N10 C56 C57 C58 4(2) .
C55 C56 C57 C58 -178.3(11) .
C56 C57 C58 C59 -3(2) .
C57 C58 C59 C60 0.6(19) .
C58 C59 C60 N10 1.5(18) .
C22 C21 N1 C1 -69.9(10) .
C22 C21 N1 C41 165.4(9) .
C2 C1 N1 C21 167.2(8) .
C2 C1 N1 C41 -67.0(10) .
C42 C41 N1 C21 -69.4(12) .
C42 C41 N1 C1 165.4(9) .
C10 C9 N2 C15 -143.9(8) .
C10 C9 N2 C8 90.8(9) .
C10 C9 N2 Cu1 -29.0(9) .
C16 C15 N2 C9 150.0(7) .
C16 C15 N2 C8 -85.9(9) .
C16 C15 N2 Cu1 33.2(8) .
C7 C8 N2 C9 -155.3(8) .
C7 C8 N2 C15 78.8(10) .
C7 C8 N2 Cu1 -37.0(9) .
N3 Cu1 N2 C9 26.0(6) .
N4 Cu1 N2 C9 -147.1(6) .
Cl1 Cu1 N2 C9 122.2(14) .
O1 Cu1 N2 C9 -58.5(6) .
N3 Cu1 N2 C15 146.2(6) .
N4 Cu1 N2 C15 -26.9(6) .
Cl1 Cu1 N2 C15 -117.5(14) .
O1 Cu1 N2 C15 61.8(5) .
N3 Cu1 N2 C8 -93.4(6) .
N4 Cu1 N2 C8 93.5(6) .
Cl1 Cu1 N2 C8 2.8(18) .
O1 Cu1 N2 C8 -177.9(6) .
C13 C14 N3 C10 -4.0(15) .
C13 C14 N3 Cu1 164.7(9) .
C11 C10 N3 C14 1.7(13) .
C9 C10 N3 C14 177.2(8) .
C11 C10 N3 Cu1 -169.0(7) .
C9 C10 N3 Cu1 6.5(10) .
N4 Cu1 N3 C14 -160.7(11) .
N2 Cu1 N3 C14 172.7(9) .
Cl1 Cu1 N3 C14 1.7(9) .
O1 Cu1 N3 C14 -103.9(9) .
N4 Cu1 N3 C10 8.2(15) .
N2 Cu1 N3 C10 -18.3(6) .
Cl1 Cu1 N3 C10 170.7(6) .
O1 Cu1 N3 C10 65.1(6) .
C17 C16 N4 C20 -0.9(15) .
C15 C16 N4 C20 -176.4(9) .
C17 C16 N4 Cu1 174.9(8) .
C15 C16 N4 Cu1 -0.6(11) .
C19 C20 N4 C16 2.3(18) .
C19 C20 N4 Cu1 -172.9(10) .
N3 Cu1 N4 C16 -10.2(16) .
N2 Cu1 N4 C16 16.3(7) .
Cl1 Cu1 N4 C16 -172.7(7) .
O1 Cu1 N4 C16 -66.6(7) .
N3 Cu1 N4 C20 165.3(11) .
N2 Cu1 N4 C20 -168.2(10) .
Cl1 Cu1 N4 C20 2.8(9) .
O1 Cu1 N4 C20 108.9(9) .
C36 C35 N5 C29 152.6(9) .
C36 C35 N5 C28 -84.0(11) .
C36 C35 N5 Cu2 35.4(10) .
C30 C29 N5 C35 -151.2(8) .
C30 C29 N5 C28 84.4(9) .
C30 C29 N5 Cu2 -35.7(8) .
C27 C28 N5 C35 78.9(10) .
C27 C28 N5 C29 -156.8(8) .
C27 C28 N5 Cu2 -37.8(9) .
N6 Cu2 N5 C35 148.9(6) .
N7 Cu2 N5 C35 -28.2(6) .
Cl2 Cu2 N5 C35 -124.7(13) .
O2 Cu2 N5 C35 58.8(6) 3
N6 Cu2 N5 C29 29.6(6) .
N7 Cu2 N5 C29 -147.5(6) .
Cl2 Cu2 N5 C29 116.0(14) .
O2 Cu2 N5 C29 -60.5(6) 3
N6 Cu2 N5 C28 -90.6(6) .
N7 Cu2 N5 C28 92.3(6) .
Cl2 Cu2 N5 C28 -4.2(18) .
O2 Cu2 N5 C28 179.3(6) 3
C33 C34 N6 C30 -0.1(15) .
C33 C34 N6 Cu2 176.3(9) .
C31 C30 N6 C34 0.3(14) .
C29 C30 N6 C34 178.9(8) .
C31 C30 N6 Cu2 -176.7(7) .
C29 C30 N6 Cu2 2.0(10) .
N7 Cu2 N6 C34 175.7(11) .
N5 Cu2 N6 C34 165.4(9) .
Cl2 Cu2 N6 C34 -4.0(9) .
O2 Cu2 N6 C34 -105.1(9) 3
N7 Cu2 N6 C30 -7.8(15) .
N5 Cu2 N6 C30 -18.1(6) .
Cl2 Cu2 N6 C30 172.5(6) .
O2 Cu2 N6 C30 71.4(6) 3
C37 C36 N7 C40 2.2(19) .
C35 C36 N7 C40 -179.2(11) .
C37 C36 N7 Cu2 -179.2(11) .
C35 C36 N7 Cu2 -0.6(13) .
C39 C40 N7 C36 -1(2) .
C39 C40 N7 Cu2 -179.2(12) .
N6 Cu2 N7 C36 6.7(17) .
N5 Cu2 N7 C36 17.0(8) .
Cl2 Cu2 N7 C36 -173.6(8) .
O2 Cu2 N7 C36 -73.0(8) 3
N6 Cu2 N7 C40 -174.8(12) .
N5 Cu2 N7 C40 -164.5(11) .
Cl2 Cu2 N7 C40 4.9(11) .
O2 Cu2 N7 C40 105.6(11) 3
C50 C49 N8 C55 -146.2(9) .
C50 C49 N8 C48 87.3(10) .
C50 C49 N8 Cu3 -31.4(10) .
C56 C55 N8 C49 151.0(9) .
C56 C55 N8 C48 -84.3(10) .
C56 C55 N8 Cu3 35.8(10) .
C47 C48 N8 C49 -161.6(9) .
C47 C48 N8 C55 71.6(10) .
C47 C48 N8 Cu3 -45.7(10) .
N9 Cu3 N8 C49 28.3(6) .
N10 Cu3 N8 C49 -149.8(7) .
Cl3 Cu3 N8 C49 119.4(18) .
O3 Cu3 N8 C49 -57.2(7) 3_545
N9 Cu3 N8 C55 148.4(7) .
N10 Cu3 N8 C55 -29.7(7) .
Cl3 Cu3 N8 C55 -120.5(18) .
O3 Cu3 N8 C55 62.9(7) 3_545
N9 Cu3 N8 C48 -89.8(7) .
N10 Cu3 N8 C48 92.2(7) .
Cl3 Cu3 N8 C48 1(2) .
O3 Cu3 N8 C48 -175.3(7) 3_545
C51 C50 N9 C54 1.3(15) .
C49 C50 N9 C54 177.9(9) .
C51 C50 N9 Cu3 -168.6(8) .
C49 C50 N9 Cu3 8.1(11) .
C53 C54 N9 C50 0.2(16) .
C53 C54 N9 Cu3 168.7(10) .
N10 Cu3 N9 C50 -13.6(17) .
N8 Cu3 N9 C50 -20.9(7) .
Cl3 Cu3 N9 C50 167.2(6) .
O3 Cu3 N9 C50 64.6(7) 3_545
N10 Cu3 N9 C54 177.3(11) .
N8 Cu3 N9 C54 170.1(9) .
Cl3 Cu3 N9 C54 -1.8(9) .
O3 Cu3 N9 C54 -104.5(9) 3_545
C59 C60 N10 C56 -1.0(16) .
C59 C60 N10 Cu3 -178.0(9) .
C57 C56 N10 C60 -1.8(17) .
C55 C56 N10 C60 -179.8(9) .
C57 C56 N10 Cu3 175.5(10) .
C55 C56 N10 Cu3 -2.5(12) .
N9 Cu3 N10 C60 -171.5(11) .
N8 Cu3 N10 C60 -164.3(9) .
Cl3 Cu3 N10 C60 7.6(9) .
O3 Cu3 N10 C60 111.3(9) 3_545
N9 Cu3 N10 C56 11.5(18) .
N8 Cu3 N10 C56 18.7(7) .
Cl3 Cu3 N10 C56 -169.4(7) .
O3 Cu3 N10 C56 -65.8(8) 3_545
N3 Cu1 O1 Re1 79.7(4) .
N4 Cu1 O1 Re1 -113.2(4) .
N2 Cu1 O1 Re1 163.2(4) .
Cl1 Cu1 O1 Re1 -16.9(4) .
Cu1 O1 Re1 O4 -41.7(5) .
Cu1 O1 Re1 O3 -161.9(4) .
Cu1 O1 Re1 O2 77.6(4) .
Cu3 O3 Re1 O1 -10.4(7) 3_455
Cu3 O3 Re1 O4 -132.0(6) 3_455
Cu3 O3 Re1 O2 109.4(6) 3_455
Cu2 O2 Re1 O1 -178.1(5) 3_445
Cu2 O2 Re1 O4 -57.6(7) 3_445
Cu2 O2 Re1 O3 60.9(7) 3_445
