#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:13:23 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179367 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/64/4326497.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4326497
loop_
_publ_author_name
'Qi-Bing Bo'
'Hong-Yan Wang'
'Da-Qi Wang'
'Zhen-Wei Zhang'
'Jin-Ling Miao'
'Guo-Xin Sun'
_publ_section_title
;
 Structure and Photoluminescence Tuning Features of Mn2+- and
 Ln3+-Activated Zn-Based Heterometal-Organic Frameworks (MOFs) with a
 Single 5-Methylisophthalic Acid Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              10163
_journal_page_last               10177
_journal_paper_doi               10.1021/ic201124c
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'C54 H45 Eu O29 Zn5'
_chemical_formula_weight         1636.71
_chemical_name_systematic
; 

 ? 

;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.758(6)
_cell_angle_beta                 100.424(6)
_cell_angle_gamma                108.033(8)
_cell_formula_units_Z            2
_cell_length_a                   13.2812(11)
_cell_length_b                   15.1611(13)
_cell_length_c                   15.6701(9)
_cell_measurement_temperature    293(2)
_cell_volume                     2849.7(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0470
_diffrn_reflns_av_sigmaI/netI    0.0566
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            35372
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.89
_exptl_absorpt_coefficient_mu    3.249
_exptl_absorpt_correction_T_max  0.6245
_exptl_absorpt_correction_T_min  0.4324
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.907
_exptl_crystal_F_000             1628
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.208
_refine_diff_density_min         -0.805
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     808
_refine_ls_number_reflns         11617
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0518
_refine_ls_R_factor_gt           0.0353
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0287P)²+2.0372P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0743
_refine_ls_wR_factor_ref         0.0829
_reflns_number_gt                9214
_reflns_number_total             11617
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201124c_si_002_6.cif
_cod_data_source_block           Zn-Eu2
_cod_database_code               4326497
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.909676(16) 0.785023(14) 0.331746(13) 0.01842(6) Uani 1 1 d .
Zn1 Zn 1.21078(4) 0.98232(4) 0.35926(3) 0.02660(12) Uani 1 1 d .
Zn2 Zn 0.81526(4) 0.50356(3) 0.31606(3) 0.02289(12) Uani 1 1 d .
Zn3 Zn 0.58208(4) 0.25259(3) 0.17003(3) 0.02101(11) Uani 1 1 d .
Zn4 Zn 0.44270(4) 0.12564(3) -0.01650(3) 0.02028(11) Uani 1 1 d .
Zn5 Zn 0.37451(4) 0.05138(3) 0.16291(3) 0.02551(12) Uani 1 1 d .
O1 O 1.1964(2) 0.8816(2) 0.2566(2) 0.0346(8) Uani 1 1 d .
O2 O 1.0187(3) 0.7938(2) 0.2297(2) 0.0396(8) Uani 1 1 d .
O3 O 1.3979(2) 0.8396(2) 0.0328(2) 0.0280(7) Uani 1 1 d .
O4 O 1.3071(2) 0.7359(2) -0.10226(19) 0.0279(7) Uani 1 1 d .
O5 O 1.0820(2) 0.8589(2) 0.4321(2) 0.0362(8) Uani 1 1 d .
O6 O 1.2483(3) 0.9664(2) 0.4811(2) 0.0371(8) Uani 1 1 d .
O7 O 1.3739(2) 0.9947(2) 0.8928(2) 0.0316(7) Uani 1 1 d .
O8 O 1.3699(3) 1.1027(2) 0.8176(2) 0.0417(9) Uani 1 1 d .
O9 O 0.8168(3) 0.7084(2) 0.4256(2) 0.0424(9) Uani 1 1 d .
O10 O 0.7375(3) 0.5500(2) 0.3966(2) 0.0428(9) Uani 1 1 d .
O11 O 0.6621(2) 0.9024(2) 0.6342(2) 0.0368(8) Uani 1 1 d .
O12 O 0.6414(2) 0.8447(2) 0.7528(2) 0.0371(8) Uani 1 1 d .
O13 O 0.7413(3) 0.3644(2) 0.30433(19) 0.0302(7) Uani 1 1 d .
O14 O 0.5973(2) 0.2421(2) 0.2948(2) 0.0352(8) Uani 1 1 d .
O15 O 1.0338(3) 0.4741(2) 0.6184(2) 0.0402(8) Uani 1 1 d .
O16 O 1.0170(2) 0.3412(2) 0.6609(2) 0.0377(8) Uani 1 1 d .
O19 O 0.7858(2) 0.6533(2) 0.21779(19) 0.0294(7) Uani 1 1 d .
O20 O 0.7740(2) 0.5009(2) 0.19072(19) 0.0283(7) Uani 1 1 d .
O21 O 0.2321(2) -0.0166(2) 0.0791(2) 0.0342(7) Uani 1 1 d .
O22 O 0.2853(2) 0.1002(2) 0.0119(2) 0.0302(7) Uani 1 1 d .
O23 O 0.0709(3) 0.0707(2) -0.2879(2) 0.0377(8) Uani 1 1 d .
O24 O -0.0970(3) -0.0383(2) -0.3427(2) 0.0370(8) Uani 1 1 d .
O25 O 0.4924(2) 0.11184(18) 0.10999(18) 0.0207(6) Uani 1 1 d .
H25 H 0.5366 0.0818 0.1101 0.031 Uiso 1 1 d R
O26 O 0.4772(7) 0.9790(6) 0.5934(6) 0.216(4) Uani 1 1 d .
H26C H 0.5125 0.9412 0.5868 0.259 Uiso 1 1 d R
H26D H 0.4180 0.9562 0.5521 0.259 Uiso 1 1 d R
O1W O 0.9026(3) 0.9091(2) 0.4634(2) 0.0419(8) Uani 1 1 d .
H1WC H 0.8585 0.9388 0.4560 0.050 Uiso 1 1 d R
H1WD H 0.9195 0.9118 0.5189 0.050 Uiso 1 1 d R
O2W O 0.7257(3) 0.8055(2) 0.2944(3) 0.0473(9) Uani 1 1 d .
H2WB H 0.7096 0.8065 0.2398 0.057 Uiso 1 1 d R
H2WC H 0.7101 0.7550 0.3135 0.057 Uiso 1 1 d R
O3W O 0.4362(3) -0.0289(3) 0.2299(3) 0.0589(11) Uani 1 1 d .
H3WC H 0.4822 -0.0502 0.2105 0.071 Uiso 1 1 d R
H3WD H 0.4571 -0.0111 0.2868 0.071 Uiso 1 1 d R
C1 C 1.1076(4) 0.8140(3) 0.2087(3) 0.0271(10) Uani 1 1 d .
C2 C 1.1125(3) 0.7581(3) 0.1206(3) 0.0240(9) Uani 1 1 d .
C3 C 1.0200(4) 0.6836(3) 0.0642(3) 0.0276(10) Uani 1 1 d .
H3 H 0.9556 0.6654 0.0828 0.033 Uiso 1 1 calc R
C4 C 1.0231(4) 0.6364(3) -0.0195(3) 0.0291(10) Uani 1 1 d .
C5 C 0.9245(4) 0.5544(3) -0.0799(4) 0.0456(13) Uani 1 1 d .
H5B H 0.9178 0.4977 -0.0591 0.068 Uiso 1 1 calc R
H5C H 0.9328 0.5431 -0.1401 0.068 Uiso 1 1 calc R
H5A H 0.8600 0.5702 -0.0790 0.068 Uiso 1 1 calc R
C6 C 1.1200(3) 0.6673(3) -0.0466(3) 0.0270(10) Uani 1 1 d .
H6 H 1.1227 0.6371 -0.1031 0.032 Uiso 1 1 calc R
C7 C 1.2116(3) 0.7417(3) 0.0085(3) 0.0229(9) Uani 1 1 d .
C8 C 1.3146(3) 0.7759(3) -0.0211(3) 0.0216(9) Uani 1 1 d .
C9 C 1.2082(3) 0.7861(3) 0.0934(3) 0.0225(9) Uani 1 1 d .
H9 H 1.2703 0.8347 0.1319 0.027 Uiso 1 1 calc R
C10 C 1.1670(3) 0.9049(3) 0.4940(3) 0.0242(9) Uani 1 1 d .
C11 C 1.1733(3) 0.8886(3) 0.5847(3) 0.0230(9) Uani 1 1 d .
C12 C 1.0976(4) 0.8100(3) 0.5985(3) 0.0275(10) Uani 1 1 d .
H12 H 1.0408 0.7682 0.5501 0.033 Uiso 1 1 calc R
C13 C 1.1035(4) 0.7914(3) 0.6825(3) 0.0280(10) Uani 1 1 d .
C14 C 1.0217(4) 0.7050(3) 0.6968(4) 0.0443(13) Uani 1 1 d .
H14A H 0.9507 0.7104 0.6856 0.066 Uiso 1 1 calc R
H14C H 1.0432 0.7016 0.7576 0.066 Uiso 1 1 calc R
H14B H 1.0191 0.6480 0.6563 0.066 Uiso 1 1 calc R
C15 C 1.1882(4) 0.8578(3) 0.7544(3) 0.0287(10) Uani 1 1 d .
H15 H 1.1964 0.8465 0.8111 0.034 Uiso 1 1 calc R
C16 C 1.3398(3) 1.0174(3) 0.8218(3) 0.0271(10) Uani 1 1 d .
C17 C 1.2597(3) 0.9397(3) 0.7420(3) 0.0254(10) Uani 1 1 d .
C18 C 1.2540(3) 0.9546(3) 0.6578(3) 0.0236(9) Uani 1 1 d .
H18 H 1.3041 1.0088 0.6498 0.028 Uiso 1 1 calc R
C19 C 0.7567(4) 0.6345(3) 0.4402(3) 0.0294(10) Uani 1 1 d .
C20 C 0.7025(4) 0.6450(3) 0.5154(3) 0.0303(10) Uani 1 1 d .
C21 C 0.6600(4) 0.5656(3) 0.5478(3) 0.0400(12) Uani 1 1 d .
H21 H 0.6627 0.5067 0.5206 0.048 Uiso 1 1 calc R
C22 C 0.6135(4) 0.5730(3) 0.6201(3) 0.0407(12) Uani 1 1 d .
C23 C 0.5700(6) 0.4866(4) 0.6554(4) 0.070(2) Uani 1 1 d .
H23A H 0.5473 0.4291 0.6077 0.104 Uiso 1 1 calc R
H23B H 0.5084 0.4900 0.6782 0.104 Uiso 1 1 calc R
H23C H 0.6263 0.4857 0.7028 0.104 Uiso 1 1 calc R
C24 C 0.6128(4) 0.6620(3) 0.6602(3) 0.0360(11) Uani 1 1 d .
H24 H 0.5847 0.6688 0.7103 0.043 Uiso 1 1 calc R
C25 C 0.6526(3) 0.8370(3) 0.6752(3) 0.0287(10) Uani 1 1 d .
C26 C 0.6524(4) 0.7408(3) 0.6279(3) 0.0286(10) Uani 1 1 d .
C27 C 0.6978(3) 0.7321(3) 0.5550(3) 0.0283(10) Uani 1 1 d .
H27 H 0.7249 0.7851 0.5329 0.034 Uiso 1 1 calc R
C28 C 0.6839(4) 0.3088(3) 0.3414(3) 0.0241(9) Uani 1 1 d .
C29 C 0.7172(3) 0.3148(3) 0.4388(3) 0.0251(10) Uani 1 1 d .
C30 C 0.6427(4) 0.2645(4) 0.4790(3) 0.0387(12) Uani 1 1 d .
H30 H 0.5700 0.2339 0.4461 0.046 Uiso 1 1 calc R
C31 C 0.6711(4) 0.2574(4) 0.5666(3) 0.0459(14) Uani 1 1 d .
C32 C 0.5886(5) 0.2053(6) 0.6101(5) 0.089(3) Uani 1 1 d .
H32A H 0.5198 0.2120 0.5880 0.134 Uiso 1 1 calc R
H32C H 0.6132 0.2318 0.6740 0.134 Uiso 1 1 calc R
H32B H 0.5797 0.1384 0.5962 0.134 Uiso 1 1 calc R
C33 C 0.7820(4) 0.2998(4) 0.6114(3) 0.0373(12) Uani 1 1 d .
H33 H 0.8052 0.2927 0.6685 0.045 Uiso 1 1 calc R
C34 C 0.9770(4) 0.3909(3) 0.6210(3) 0.0277(10) Uani 1 1 d .
C35 C 0.8584(3) 0.3520(3) 0.5734(3) 0.0269(10) Uani 1 1 d .
C36 C 0.8254(3) 0.3626(3) 0.4882(3) 0.0250(9) Uani 1 1 d .
H36 H 0.8753 0.4017 0.4641 0.030 Uiso 1 1 calc R
C38 C 0.5952(3) 0.6036(3) -0.0407(3) 0.0203(9) Uani 1 1 d .
C39 C 0.6596(3) 0.6223(3) 0.0450(3) 0.0217(9) Uani 1 1 d .
H39 H 0.6768 0.6811 0.0858 0.026 Uiso 1 1 calc R
C40 C 0.6991(3) 0.5534(3) 0.0706(3) 0.0198(9) Uani 1 1 d .
C41 C 0.7583(3) 0.5713(3) 0.1658(3) 0.0208(9) Uani 1 1 d .
C42 C 0.6752(3) 0.4673(3) 0.0081(3) 0.0229(9) Uani 1 1 d .
H42 H 0.7011 0.4211 0.0251 0.028 Uiso 1 1 calc R
C43 C 0.6137(3) 0.4484(3) -0.0789(3) 0.0244(9) Uani 1 1 d .
C44 C 0.5889(5) 0.3541(3) -0.1467(3) 0.0441(13) Uani 1 1 d .
H44B H 0.5420 0.3520 -0.2020 0.066 Uiso 1 1 calc R
H44C H 0.5528 0.3018 -0.1237 0.066 Uiso 1 1 calc R
H44A H 0.6560 0.3488 -0.1573 0.066 Uiso 1 1 calc R
C45 C 0.5731(3) 0.5170(3) -0.1026(3) 0.0227(9) Uani 1 1 d .
H45 H 0.5306 0.5049 -0.1605 0.027 Uiso 1 1 calc R
C46 C 0.2176(3) 0.0242(3) 0.0166(3) 0.0254(10) Uani 1 1 d .
C47 C 0.1132(3) -0.0228(3) -0.0553(3) 0.0236(9) Uani 1 1 d .
C48 C 0.0312(3) -0.1039(3) -0.0503(3) 0.0294(10) Uani 1 1 d .
H48 H 0.0411 -0.1279 -0.0002 0.035 Uiso 1 1 calc R
C49 C -0.0652(3) -0.1501(3) -0.1183(3) 0.0282(10) Uani 1 1 d .
C50 C -0.1549(4) -0.2360(4) -0.1126(4) 0.0454(13) Uani 1 1 d .
H50C H -0.1662 -0.2899 -0.1612 0.068 Uiso 1 1 calc R
H50B H -0.2213 -0.2223 -0.1165 0.068 Uiso 1 1 calc R
H50A H -0.1348 -0.2507 -0.0564 0.068 Uiso 1 1 calc R
C51 C -0.0750(3) -0.1141(3) -0.1935(3) 0.0289(10) Uani 1 1 d .
H51 H -0.1377 -0.1446 -0.2407 0.035 Uiso 1 1 calc R
C52 C 0.0060(3) -0.0338(3) -0.2003(3) 0.0239(9) Uani 1 1 d .
C53 C -0.0066(4) 0.0027(3) -0.2820(3) 0.0278(10) Uani 1 1 d .
C54 C 0.0993(3) 0.0131(3) -0.1296(3) 0.0244(9) Uani 1 1 d .
H54 H 0.1523 0.0688 -0.1323 0.029 Uiso 1 1 calc R
C37 C 0.5457(3) 0.6754(3) -0.0631(3) 0.0220(9) Uani 1 1 d .
O17 O 0.5029(2) 0.6661(2) -0.14493(19) 0.0293(7) Uani 1 1 d .
O18 O 0.5490(2) 0.73947(19) 0.00129(19) 0.0271(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O9 98.31(12) . .
O5 Eu1 O19 148.96(11) . .
O9 Eu1 O19 84.02(11) . .
O5 Eu1 O2 80.51(11) . .
O9 Eu1 O2 152.71(12) . .
O19 Eu1 O2 83.59(11) . .
O5 Eu1 O23 89.64(11) . 2_665
O9 Eu1 O23 135.13(11) . 2_665
O19 Eu1 O23 110.56(11) . 2_665
O2 Eu1 O23 72.13(12) . 2_665
O5 Eu1 O16 74.53(11) . 2_766
O9 Eu1 O16 78.45(11) . 2_766
O19 Eu1 O16 75.68(10) . 2_766
O2 Eu1 O16 74.96(12) . 2_766
O23 Eu1 O16 145.38(11) 2_665 2_766
O5 Eu1 O2W 140.71(11) . .
O9 Eu1 O2W 76.90(12) . .
O19 Eu1 O2W 70.11(11) . .
O2 Eu1 O2W 120.90(12) . .
O23 Eu1 O2W 69.69(11) 2_665 .
O16 Eu1 O2W 139.40(11) 2_766 .
O5 Eu1 O1W 70.11(11) . .
O9 Eu1 O1W 69.70(11) . .
O19 Eu1 O1W 137.55(11) . .
O2 Eu1 O1W 133.05(11) . .
O23 Eu1 O1W 71.92(11) 2_665 .
O16 Eu1 O1W 127.34(11) 2_766 .
O2W Eu1 O1W 71.78(12) . .
O5 Eu1 H2WC 144.2 . .
O9 Eu1 H2WC 59.5 . .
O19 Eu1 H2WC 62.3 . .
O2 Eu1 H2WC 132.5 . .
O23 Eu1 H2WC 89.1 2_665 .
O16 Eu1 H2WC 121.6 2_766 .
O2W Eu1 H2WC 19.5 . .
O1W Eu1 H2WC 75.5 . .
O1 Zn1 O24 113.76(14) . 2_665
O1 Zn1 O6 119.91(14) . .
O24 Zn1 O6 112.50(14) 2_665 .
O1 Zn1 O11 108.25(13) . 2_776
O24 Zn1 O11 98.06(13) 2_665 2_776
O6 Zn1 O11 100.89(14) . 2_776
O20 Zn2 O10 118.96(14) . .
O20 Zn2 O15 123.47(14) . 2_766
O10 Zn2 O15 110.64(15) . 2_766
O20 Zn2 O13 97.91(12) . .
O10 Zn2 O13 96.73(13) . .
O15 Zn2 O13 101.67(13) 2_766 .
O4 Zn3 O17 111.27(12) 2_765 2_665
O4 Zn3 O14 127.19(13) 2_765 .
O17 Zn3 O14 110.90(13) 2_665 .
O4 Zn3 O25 96.67(11) 2_765 .
O17 Zn3 O25 110.99(12) 2_665 .
O14 Zn3 O25 96.57(12) . .
O18 Zn4 O7 141.45(12) 2_665 1_444
O18 Zn4 O25 105.90(11) 2_665 .
O7 Zn4 O25 110.86(11) 1_444 .
O18 Zn4 O3 91.64(12) 2_665 2_765
O7 Zn4 O3 98.38(12) 1_444 2_765
O25 Zn4 O3 91.69(11) . 2_765
O18 Zn4 O22 85.26(12) 2_665 .
O7 Zn4 O22 86.74(12) 1_444 .
O25 Zn4 O22 84.99(11) . .
O3 Zn4 O22 174.65(11) 2_765 .
O21 Zn5 O12 106.31(13) . 2_666
O21 Zn5 O25 115.35(12) . .
O12 Zn5 O25 106.29(12) 2_666 .
O21 Zn5 O3W 115.38(14) . .
O12 Zn5 O3W 110.15(16) 2_666 .
O25 Zn5 O3W 103.03(13) . .
C1 O1 Zn1 126.8(3) . .
C1 O2 Eu1 154.0(3) . .
C8 O3 Zn4 125.3(3) . 2_765
C8 O4 Zn3 130.7(3) . 2_765
C10 O5 Eu1 170.7(3) . .
C10 O6 Zn1 109.6(3) . .
C16 O7 Zn4 101.4(3) . 1_666
C19 O9 Eu1 150.4(3) . .
C19 O10 Zn2 129.0(3) . .
C25 O11 Zn1 131.8(3) . 2_776
C25 O12 Zn5 131.3(3) . 2_666
C28 O13 Zn2 141.1(3) . .
C28 O14 Zn3 106.7(3) . .
C34 O15 Zn2 105.6(3) . 2_766
C34 O16 Eu1 153.9(3) . 2_766
C41 O19 Eu1 152.4(3) . .
C41 O20 Zn2 122.0(3) . .
C46 O21 Zn5 111.4(3) . .
C46 O22 Zn4 129.5(3) . .
C53 O23 Eu1 135.8(3) . 2_665
C53 O24 Zn1 123.1(3) . 2_665
Zn5 O25 Zn3 116.07(13) . .
Zn5 O25 Zn4 115.47(13) . .
Zn3 O25 Zn4 97.66(11) . .
Zn5 O25 H25 110.2 . .
Zn3 O25 H25 107.3 . .
Zn4 O25 H25 109.4 . .
H26C O26 H26D 108.5 . .
Eu1 O1W H1WC 120.5 . .
Eu1 O1W H1WD 127.9 . .
H1WC O1W H1WD 107.4 . .
Eu1 O2W H2WB 109.3 . .
Eu1 O2W H2WC 77.8 . .
H2WB O2W H2WC 125.2 . .
Zn5 O3W H3WC 118.3 . .
Zn5 O3W H3WD 119.3 . .
H3WC O3W H3WD 108.3 . .
O2 C1 O1 124.4(4) . .
O2 C1 C2 118.8(4) . .
O1 C1 C2 116.8(4) . .
C9 C2 C3 120.3(4) . .
C9 C2 C1 118.8(4) . .
C3 C2 C1 120.7(4) . .
C4 C3 C2 120.5(4) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C3 C4 C6 118.4(4) . .
C3 C4 C5 120.8(4) . .
C6 C4 C5 120.8(4) . .
C4 C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C4 C5 H5A 109.5 . .
H5B C5 H5A 109.5 . .
H5C C5 H5A 109.5 . .
C7 C6 C4 121.5(4) . .
C7 C6 H6 119.2 . .
C4 C6 H6 119.2 . .
C6 C7 C9 119.3(4) . .
C6 C7 C8 121.5(4) . .
C9 C7 C8 119.2(4) . .
O3 C8 O4 126.1(4) . .
O3 C8 C7 119.4(4) . .
O4 C8 C7 114.5(4) . .
C2 C9 C7 120.0(4) . .
C2 C9 H9 120.0 . .
C7 C9 H9 120.0 . .
O5 C10 O6 121.4(4) . .
O5 C10 C11 119.9(4) . .
O6 C10 C11 118.8(4) . .
C12 C11 C18 119.1(4) . .
C12 C11 C10 121.1(4) . .
C18 C11 C10 119.8(4) . .
C11 C12 C13 122.2(4) . .
C11 C12 H12 118.9 . .
C13 C12 H12 118.9 . .
C12 C13 C15 117.1(4) . .
C12 C13 C14 121.9(4) . .
C15 C13 C14 121.0(4) . .
C13 C14 H14A 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
H14C C14 H14B 109.5 . .
C17 C15 C13 120.8(4) . .
C17 C15 H15 119.6 . .
C13 C15 H15 119.6 . .
O8 C16 O7 121.2(4) . .
O8 C16 C17 119.6(4) . .
O7 C16 C17 119.2(4) . .
C18 C17 C15 120.6(4) . .
C18 C17 C16 119.0(4) . .
C15 C17 C16 120.2(4) . .
C17 C18 C11 119.9(4) . .
C17 C18 H18 120.1 . .
C11 C18 H18 120.1 . .
O9 C19 O10 125.2(4) . .
O9 C19 C20 118.6(4) . .
O10 C19 C20 116.1(4) . .
C27 C20 C21 119.7(4) . .
C27 C20 C19 121.3(4) . .
C21 C20 C19 119.0(4) . .
C22 C21 C20 121.0(4) . .
C22 C21 H21 119.5 . .
C20 C21 H21 119.5 . .
C24 C22 C21 118.0(4) . .
C24 C22 C23 121.7(5) . .
C21 C22 C23 120.2(5) . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C26 C24 C22 121.7(4) . .
C26 C24 H24 119.2 . .
C22 C24 H24 119.2 . .
O12 C25 O11 125.0(4) . .
O12 C25 C26 115.7(4) . .
O11 C25 C26 119.3(4) . .
C24 C26 C27 119.6(4) . .
C24 C26 C25 119.8(4) . .
C27 C26 C25 120.5(4) . .
C20 C27 C26 120.0(4) . .
C20 C27 H27 120.0 . .
C26 C27 H27 120.0 . .
O13 C28 O14 119.7(4) . .
O13 C28 C29 122.6(4) . .
O14 C28 C29 117.6(4) . .
C30 C29 C36 118.9(4) . .
C30 C29 C28 119.8(4) . .
C36 C29 C28 121.0(4) . .
C29 C30 C31 122.9(4) . .
C29 C30 H30 118.5 . .
C31 C30 H30 118.5 . .
C30 C31 C33 116.4(4) . .
C30 C31 C32 122.2(5) . .
C33 C31 C32 121.4(5) . .
C31 C32 H32A 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
H32C C32 H32B 109.5 . .
C35 C33 C31 122.0(4) . .
C35 C33 H33 119.0 . .
C31 C33 H33 119.0 . .
O16 C34 O15 122.3(4) . .
O16 C34 C35 119.6(4) . .
O15 C34 C35 118.1(4) . .
C33 C35 C36 119.7(4) . .
C33 C35 C34 120.3(4) . .
C36 C35 C34 119.8(4) . .
C35 C36 C29 119.7(4) . .
C35 C36 H36 120.1 . .
C29 C36 H36 120.1 . .
C39 C38 C45 119.6(4) . .
C39 C38 C37 118.9(4) . .
C45 C38 C37 121.5(4) . .
C38 C39 C40 120.4(4) . .
C38 C39 H39 119.8 . .
C40 C39 H39 119.8 . .
C42 C40 C39 119.0(4) . .
C42 C40 C41 121.7(3) . .
C39 C40 C41 119.2(4) . .
O19 C41 O20 123.6(4) . .
O19 C41 C40 118.9(3) . .
O20 C41 C40 117.4(4) . .
C43 C42 C40 121.6(4) . .
C43 C42 H42 119.2 . .
C40 C42 H42 119.2 . .
C42 C43 C45 118.6(4) . .
C42 C43 C44 121.0(4) . .
C45 C43 C44 120.4(4) . .
C43 C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C43 C44 H44A 109.5 . .
H44B C44 H44A 109.5 . .
H44C C44 H44A 109.5 . .
C43 C45 C38 120.8(4) . .
C43 C45 H45 119.6 . .
C38 C45 H45 119.6 . .
O22 C46 O21 124.0(4) . .
O22 C46 C47 118.7(4) . .
O21 C46 C47 117.2(4) . .
C54 C47 C48 119.5(4) . .
C54 C47 C46 119.1(4) . .
C48 C47 C46 121.4(4) . .
C49 C48 C47 121.8(4) . .
C49 C48 H48 119.1 . .
C47 C48 H48 119.1 . .
C51 C49 C48 117.2(4) . .
C51 C49 C50 120.5(4) . .
C48 C49 C50 122.2(4) . .
C49 C50 H50C 109.5 . .
C49 C50 H50B 109.5 . .
H50C C50 H50B 109.5 . .
C49 C50 H50A 109.5 . .
H50C C50 H50A 109.5 . .
H50B C50 H50A 109.5 . .
C52 C51 C49 121.9(4) . .
C52 C51 H51 119.0 . .
C49 C51 H51 119.0 . .
C51 C52 C54 119.4(4) . .
C51 C52 C53 120.7(4) . .
C54 C52 C53 119.9(4) . .
O23 C53 O24 123.5(4) . .
O23 C53 C52 118.6(4) . .
O24 C53 C52 117.9(4) . .
C47 C54 C52 120.0(4) . .
C47 C54 H54 120.0 . .
C52 C54 H54 120.0 . .
O18 C37 O17 125.1(4) . .
O18 C37 C38 116.7(4) . .
O17 C37 C38 118.2(4) . .
C37 O17 Zn3 117.0(3) . 2_665
C37 O18 Zn4 134.2(3) . 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.327(3) .
Eu1 O9 2.333(3) .
Eu1 O19 2.336(3) .
Eu1 O2 2.340(3) .
Eu1 O23 2.366(3) 2_665
Eu1 O16 2.413(3) 2_766
Eu1 O2W 2.536(3) .
Eu1 O1W 2.556(3) .
Eu1 H2WC 2.4985 .
Zn1 O1 1.936(3) .
Zn1 O24 1.951(3) 2_665
Zn1 O6 1.962(3) .
Zn1 O11 1.990(3) 2_776
Zn2 O20 1.931(3) .
Zn2 O10 1.935(3) .
Zn2 O15 1.974(3) 2_766
Zn2 O13 1.989(3) .
Zn3 O4 1.949(3) 2_765
Zn3 O17 1.957(3) 2_665
Zn3 O14 1.971(3) .
Zn3 O25 2.032(3) .
Zn4 O18 1.980(3) 2_665
Zn4 O7 2.037(3) 1_444
Zn4 O25 2.043(3) .
Zn4 O3 2.093(3) 2_765
Zn4 O22 2.148(3) .
Zn5 O21 1.937(3) .
Zn5 O12 1.950(3) 2_666
Zn5 O25 1.960(3) .
Zn5 O3W 2.010(3) .
O1 C1 1.284(5) .
O2 C1 1.244(5) .
O3 C8 1.252(5) .
O3 Zn4 2.093(3) 2_765
O4 C8 1.274(5) .
O4 Zn3 1.949(3) 2_765
O5 C10 1.252(5) .
O6 C10 1.265(5) .
O7 C16 1.272(5) .
O7 Zn4 2.037(3) 1_666
O8 C16 1.249(5) .
O9 C19 1.246(5) .
O10 C19 1.258(5) .
O11 C25 1.266(5) .
O11 Zn1 1.990(3) 2_776
O12 C25 1.241(5) .
O12 Zn5 1.950(3) 2_666
O13 C28 1.254(5) .
O14 C28 1.257(5) .
O15 C34 1.266(5) .
O15 Zn2 1.974(3) 2_766
O16 C34 1.243(5) .
O16 Eu1 2.413(3) 2_766
O19 C41 1.256(5) .
O20 C41 1.264(5) .
O21 C46 1.268(5) .
O22 C46 1.247(5) .
O23 C53 1.242(5) .
O23 Eu1 2.366(3) 2_665
O24 C53 1.279(5) .
O24 Zn1 1.951(3) 2_665
O25 H25 0.8477 .
O26 H26C 0.8487 .
O26 H26D 0.8493 .
O1W H1WC 0.8474 .
O1W H1WD 0.8482 .
O2W H2WB 0.8480 .
O2W H2WC 0.8535 .
O3W H3WC 0.8488 .
O3W H3WD 0.8490 .
C1 C2 1.503(6) .
C2 C9 1.380(5) .
C2 C3 1.394(6) .
C3 C4 1.386(6) .
C3 H3 0.9300 .
C4 C6 1.398(6) .
C4 C5 1.503(6) .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C5 H5A 0.9600 .
C6 C7 1.381(6) .
C6 H6 0.9300 .
C7 C9 1.390(5) .
C7 C8 1.496(5) .
C9 H9 0.9300 .
C10 C11 1.480(6) .
C11 C12 1.383(6) .
C11 C18 1.388(6) .
C12 C13 1.390(6) .
C12 H12 0.9300 .
C13 C15 1.402(6) .
C13 C14 1.503(6) .
C14 H14A 0.9600 .
C14 H14C 0.9600 .
C14 H14B 0.9600 .
C15 C17 1.382(6) .
C15 H15 0.9300 .
C16 C17 1.509(6) .
C17 C18 1.372(6) .
C18 H18 0.9300 .
C19 C20 1.497(6) .
C20 C27 1.376(6) .
C20 C21 1.392(6) .
C21 C22 1.386(6) .
C21 H21 0.9300 .
C22 C24 1.382(6) .
C22 C23 1.508(7) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 C26 1.377(6) .
C24 H24 0.9300 .
C25 C26 1.506(6) .
C26 C27 1.388(6) .
C27 H27 0.9300 .
C28 C29 1.487(6) .
C29 C30 1.378(6) .
C29 C36 1.390(6) .
C30 C31 1.389(6) .
C30 H30 0.9300 .
C31 C33 1.395(6) .
C31 C32 1.492(7) .
C32 H32A 0.9600 .
C32 H32C 0.9600 .
C32 H32B 0.9600 .
C33 C35 1.381(6) .
C33 H33 0.9300 .
C34 C35 1.489(6) .
C35 C36 1.384(6) .
C36 H36 0.9300 .
C38 C39 1.381(5) .
C38 C45 1.391(5) .
C38 C37 1.496(5) .
C39 C40 1.394(5) .
C39 H39 0.9300 .
C40 C42 1.384(5) .
C40 C41 1.488(5) .
C42 C43 1.383(6) .
C42 H42 0.9300 .
C43 C45 1.390(5) .
C43 C44 1.514(6) .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C44 H44A 0.9600 .
C45 H45 0.9300 .
C46 C47 1.491(6) .
C47 C54 1.382(6) .
C47 C48 1.393(6) .
C48 C49 1.392(6) .
C48 H48 0.9300 .
C49 C51 1.391(6) .
C49 C50 1.499(6) .
C50 H50C 0.9600 .
C50 H50B 0.9600 .
C50 H50A 0.9600 .
C51 C52 1.389(6) .
C51 H51 0.9300 .
C52 C54 1.390(6) .
C52 C53 1.490(6) .
C54 H54 0.9300 .
C37 O18 1.248(5) .
C37 O17 1.268(5) .
O17 Zn3 1.957(3) 2_665
O18 Zn4 1.980(3) 2_665
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O25 H25 O7 0.85 1.90 2.747(4) 175.5 2_766
O26 H26C O11 0.85 2.28 3.043(9) 149.7 .
O26 H26D O6 0.85 2.39 3.156(9) 150.2 1_455
O1W H1WC O6 0.85 2.51 3.271(5) 150.2 2_776
O1W H1WD O24 0.85 2.23 2.992(5) 149.1 1_666
O2W H2WB O8 0.85 2.20 2.798(5) 127.6 2_776
O2W H2WC O9 0.85 2.40 3.032(5) 131.0 .
O3W H3WC O8 0.85 2.42 3.256(5) 170.1 2_766
O3W H3WD O26 0.85 1.82 2.663(10) 169.7 2_666
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O24 Zn1 O1 C1 -42.7(4) 2_665 .
O6 Zn1 O1 C1 94.7(4) . .
O11 Zn1 O1 C1 -150.5(3) 2_776 .
O5 Eu1 O2 C1 2.0(7) . .
O9 Eu1 O2 C1 -87.7(7) . .
O19 Eu1 O2 C1 -151.2(7) . .
O23 Eu1 O2 C1 94.7(7) 2_665 .
O16 Eu1 O2 C1 -74.4(7) 2_766 .
O2W Eu1 O2 C1 146.6(7) . .
O1W Eu1 O2 C1 53.1(8) . .
O9 Eu1 O5 C10 -58.2(19) . .
O19 Eu1 O5 C10 -150.4(18) . .
O2 Eu1 O5 C10 149.4(19) . .
O23 Eu1 O5 C10 77.5(19) 2_665 .
O16 Eu1 O5 C10 -133.7(19) 2_766 .
O2W Eu1 O5 C10 21(2) . .
O1W Eu1 O5 C10 6.6(19) . .
O1 Zn1 O6 C10 -72.0(3) . .
O24 Zn1 O6 C10 65.8(3) 2_665 .
O11 Zn1 O6 C10 169.4(3) 2_776 .
O5 Eu1 O9 C19 -128.0(6) . .
O19 Eu1 O9 C19 20.8(6) . .
O2 Eu1 O9 C19 -42.6(8) . .
O23 Eu1 O9 C19 134.1(6) 2_665 .
O16 Eu1 O9 C19 -55.7(6) 2_766 .
O2W Eu1 O9 C19 91.7(7) . .
O1W Eu1 O9 C19 166.9(7) . .
O20 Zn2 O10 C19 -87.9(4) . .
O15 Zn2 O10 C19 64.0(4) 2_766 .
O13 Zn2 O10 C19 169.2(4) . .
O20 Zn2 O13 C28 -137.0(5) . .
O10 Zn2 O13 C28 -16.4(5) . .
O15 Zn2 O13 C28 96.4(5) 2_766 .
O4 Zn3 O14 C28 50.1(3) 2_765 .
O17 Zn3 O14 C28 -90.9(3) 2_665 .
O25 Zn3 O14 C28 153.7(3) . .
O5 Eu1 O19 C41 1.9(7) . .
O9 Eu1 O19 C41 -94.3(6) . .
O2 Eu1 O19 C41 61.3(6) . .
O23 Eu1 O19 C41 129.5(6) 2_665 .
O16 Eu1 O19 C41 -14.7(6) 2_766 .
O2W Eu1 O19 C41 -172.5(6) . .
O1W Eu1 O19 C41 -145.1(6) . .
O10 Zn2 O20 C41 46.1(4) . .
O15 Zn2 O20 C41 -102.0(3) 2_766 .
O13 Zn2 O20 C41 148.3(3) . .
O12 Zn5 O21 C46 83.4(3) 2_666 .
O25 Zn5 O21 C46 -34.1(3) . .
O3W Zn5 O21 C46 -154.2(3) . .
O18 Zn4 O22 C46 -179.4(4) 2_665 .
O7 Zn4 O22 C46 38.3(4) 1_444 .
O25 Zn4 O22 C46 -73.0(4) . .
O3 Zn4 O22 C46 -124.8(12) 2_765 .
O21 Zn5 O25 Zn3 128.94(14) . .
O12 Zn5 O25 Zn3 11.41(17) 2_666 .
O3W Zn5 O25 Zn3 -104.45(17) . .
O21 Zn5 O25 Zn4 15.52(18) . .
O12 Zn5 O25 Zn4 -102.02(15) 2_666 .
O3W Zn5 O25 Zn4 142.13(16) . .
O4 Zn3 O25 Zn5 172.07(14) 2_765 .
O17 Zn3 O25 Zn5 -72.08(16) 2_665 .
O14 Zn3 O25 Zn5 43.31(16) . .
O4 Zn3 O25 Zn4 -64.64(13) 2_765 .
O17 Zn3 O25 Zn4 51.21(14) 2_665 .
O14 Zn3 O25 Zn4 166.60(12) . .
O18 Zn4 O25 Zn5 100.17(14) 2_665 .
O7 Zn4 O25 Zn5 -68.02(16) 1_444 .
O3 Zn4 O25 Zn5 -167.65(14) 2_765 .
O22 Zn4 O25 Zn5 16.56(14) . .
O18 Zn4 O25 Zn3 -23.56(13) 2_665 .
O7 Zn4 O25 Zn3 168.26(10) 1_444 .
O3 Zn4 O25 Zn3 68.63(11) 2_765 .
O22 Zn4 O25 Zn3 -107.17(12) . .
Eu1 O2 C1 O1 -28.3(10) . .
Eu1 O2 C1 C2 153.4(5) . .
Zn1 O1 C1 O2 -11.9(6) . .
Zn1 O1 C1 C2 166.4(3) . .
O2 C1 C2 C9 174.1(4) . .
O1 C1 C2 C9 -4.4(6) . .
O2 C1 C2 C3 -1.4(6) . .
O1 C1 C2 C3 -179.8(4) . .
C9 C2 C3 C4 0.4(6) . .
C1 C2 C3 C4 175.8(4) . .
C2 C3 C4 C6 -1.9(7) . .
C2 C3 C4 C5 178.5(4) . .
C3 C4 C6 C7 1.3(6) . .
C5 C4 C6 C7 -179.2(4) . .
C4 C6 C7 C9 0.9(6) . .
C4 C6 C7 C8 -179.0(4) . .
Zn4 O3 C8 O4 -15.9(6) 2_765 .
Zn4 O3 C8 C7 164.9(3) 2_765 .
Zn3 O4 C8 O3 5.8(6) 2_765 .
Zn3 O4 C8 C7 -175.0(3) 2_765 .
C6 C7 C8 O3 -175.7(4) . .
C9 C7 C8 O3 4.4(6) . .
C6 C7 C8 O4 5.0(6) . .
C9 C7 C8 O4 -174.8(4) . .
C3 C2 C9 C7 1.7(6) . .
C1 C2 C9 C7 -173.7(4) . .
C6 C7 C9 C2 -2.4(6) . .
C8 C7 C9 C2 177.5(4) . .
Eu1 O5 C10 O6 -118.5(18) . .
Eu1 O5 C10 C11 61(2) . .
Zn1 O6 C10 O5 5.3(5) . .
Zn1 O6 C10 C11 -174.0(3) . .
O5 C10 C11 C12 13.8(6) . .
O6 C10 C11 C12 -166.8(4) . .
O5 C10 C11 C18 -163.9(4) . .
O6 C10 C11 C18 15.4(6) . .
C18 C11 C12 C13 -4.2(6) . .
C10 C11 C12 C13 178.0(4) . .
C11 C12 C13 C15 2.0(6) . .
C11 C12 C13 C14 -179.1(4) . .
C12 C13 C15 C17 2.3(6) . .
C14 C13 C15 C17 -176.5(4) . .
Zn4 O7 C16 O8 13.0(5) 1_666 .
Zn4 O7 C16 C17 -165.8(3) 1_666 .
C13 C15 C17 C18 -4.5(6) . .
C13 C15 C17 C16 171.0(4) . .
O8 C16 C17 C18 25.4(6) . .
O7 C16 C17 C18 -155.7(4) . .
O8 C16 C17 C15 -150.2(4) . .
O7 C16 C17 C15 28.7(6) . .
C15 C17 C18 C11 2.3(6) . .
C16 C17 C18 C11 -173.3(4) . .
C12 C11 C18 C17 2.0(6) . .
C10 C11 C18 C17 179.8(4) . .
Eu1 O9 C19 O10 17.0(10) . .
Eu1 O9 C19 C20 -163.3(4) . .
Zn2 O10 C19 O9 16.0(7) . .
Zn2 O10 C19 C20 -163.7(3) . .
O9 C19 C20 C27 14.4(7) . .
O10 C19 C20 C27 -165.9(4) . .
O9 C19 C20 C21 -163.1(5) . .
O10 C19 C20 C21 16.7(7) . .
C27 C20 C21 C22 -0.5(8) . .
C19 C20 C21 C22 177.0(5) . .
C20 C21 C22 C24 -1.3(8) . .
C20 C21 C22 C23 -178.8(5) . .
C21 C22 C24 C26 2.7(8) . .
C23 C22 C24 C26 -179.9(5) . .
Zn5 O12 C25 O11 4.1(7) 2_666 .
Zn5 O12 C25 C26 -174.8(3) 2_666 .
Zn1 O11 C25 O12 79.5(5) 2_776 .
Zn1 O11 C25 C26 -101.6(4) 2_776 .
C22 C24 C26 C27 -2.1(7) . .
C22 C24 C26 C25 -178.4(4) . .
O12 C25 C26 C24 16.8(6) . .
O11 C25 C26 C24 -162.1(4) . .
O12 C25 C26 C27 -159.4(4) . .
O11 C25 C26 C27 21.6(6) . .
C21 C20 C27 C26 1.1(7) . .
C19 C20 C27 C26 -176.4(4) . .
C24 C26 C27 C20 0.2(7) . .
C25 C26 C27 C20 176.5(4) . .
Zn2 O13 C28 O14 130.5(4) . .
Zn2 O13 C28 C29 -53.1(6) . .
Zn3 O14 C28 O13 -1.0(5) . .
Zn3 O14 C28 C29 -177.6(3) . .
O13 C28 C29 C30 167.9(4) . .
O14 C28 C29 C30 -15.6(6) . .
O13 C28 C29 C36 -18.4(6) . .
O14 C28 C29 C36 158.0(4) . .
C36 C29 C30 C31 -1.6(7) . .
C28 C29 C30 C31 172.2(5) . .
C29 C30 C31 C33 -3.6(8) . .
C29 C30 C31 C32 178.0(6) . .
C30 C31 C33 C35 4.6(8) . .
C32 C31 C33 C35 -177.0(6) . .
Eu1 O16 C34 O15 -100.3(7) 2_766 .
Eu1 O16 C34 C35 79.0(8) 2_766 .
Zn2 O15 C34 O16 1.6(5) 2_766 .
Zn2 O15 C34 C35 -177.7(3) 2_766 .
C31 C33 C35 C36 -0.4(7) . .
C31 C33 C35 C34 -176.2(5) . .
O16 C34 C35 C33 40.3(6) . .
O15 C34 C35 C33 -140.4(4) . .
O16 C34 C35 C36 -135.5(4) . .
O15 C34 C35 C36 43.9(6) . .
C33 C35 C36 C29 -4.9(6) . .
C34 C35 C36 C29 170.8(4) . .
C30 C29 C36 C35 5.9(6) . .
C28 C29 C36 C35 -167.8(4) . .
C45 C38 C39 C40 -2.3(6) . .
C37 C38 C39 C40 174.4(4) . .
C38 C39 C40 C42 1.7(6) . .
C38 C39 C40 C41 -173.6(4) . .
Eu1 O19 C41 O20 45.5(8) . .
Eu1 O19 C41 C40 -137.7(5) . .
Zn2 O20 C41 O19 12.7(6) . .
Zn2 O20 C41 C40 -164.2(3) . .
C42 C40 C41 O19 174.2(4) . .
C39 C40 C41 O19 -10.6(6) . .
C42 C40 C41 O20 -8.8(6) . .
C39 C40 C41 O20 166.4(4) . .
C39 C40 C42 C43 0.4(6) . .
C41 C40 C42 C43 175.5(4) . .
C40 C42 C43 C45 -1.7(6) . .
C40 C42 C43 C44 179.6(4) . .
C42 C43 C45 C38 1.0(6) . .
C44 C43 C45 C38 179.8(4) . .
C39 C38 C45 C43 1.0(6) . .
C37 C38 C45 C43 -175.7(4) . .
Zn4 O22 C46 O21 69.9(5) . .
Zn4 O22 C46 C47 -109.6(4) . .
Zn5 O21 C46 O22 -2.2(5) . .
Zn5 O21 C46 C47 177.3(3) . .
O22 C46 C47 C54 6.7(6) . .
O21 C46 C47 C54 -172.9(4) . .
O22 C46 C47 C48 -175.4(4) . .
O21 C46 C47 C48 5.1(6) . .
C54 C47 C48 C49 -0.1(6) . .
C46 C47 C48 C49 -178.1(4) . .
C47 C48 C49 C51 2.3(6) . .
C47 C48 C49 C50 -178.6(4) . .
C48 C49 C51 C52 -1.7(6) . .
C50 C49 C51 C52 179.1(4) . .
C49 C51 C52 C54 -0.9(6) . .
C49 C51 C52 C53 179.6(4) . .
Eu1 O23 C53 O24 44.9(7) 2_665 .
Eu1 O23 C53 C52 -135.5(3) 2_665 .
Zn1 O24 C53 O23 -77.3(5) 2_665 .
Zn1 O24 C53 C52 103.1(4) 2_665 .
C51 C52 C53 O23 -175.2(4) . .
C54 C52 C53 O23 5.3(6) . .
C51 C52 C53 O24 4.4(6) . .
C54 C52 C53 O24 -175.1(4) . .
C48 C47 C54 C52 -2.6(6) . .
C46 C47 C54 C52 175.3(4) . .
C51 C52 C54 C47 3.2(6) . .
C53 C52 C54 C47 -177.4(4) . .
C39 C38 C37 O18 -12.7(6) . .
C45 C38 C37 O18 163.9(4) . .
C39 C38 C37 O17 168.1(4) . .
C45 C38 C37 O17 -15.3(6) . .
O18 C37 O17 Zn3 -9.0(5) . 2_665
C38 C37 O17 Zn3 170.1(3) . 2_665
O17 C37 O18 Zn4 -31.1(6) . 2_665
C38 C37 O18 Zn4 149.8(3) . 2_665
