#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:16:27 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179369 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/66/4326632.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4326632
loop_
_publ_author_name
'Irene Bassanetti'
'Luciano Marchiò'
_publ_contact_author_address
;
Departimento di Chimica GIAF
Università di Parma
via Usberti 17/a, 43100, Parma, Italy
;
_publ_contact_author_email       marchio@unipr.it
_publ_contact_author_fax         '0039 0521 905557'
_publ_contact_author_name        'Dr. Luciano Marchiò'
_publ_contact_author_phone       '0039 0521 905419'
_publ_section_title
;
 Structural Variability in Ag(I) and Cu(I) Coordination Polymers with
 Thioether-Functionalized Bis(pyrazolyl)methane Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              10786
_journal_page_last               10797
_journal_paper_doi               10.1021/ic201338w
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety         'C38 H32 Ag2 N8 S2 2+, 2(B F4 1-)'
_chemical_formula_sum            'C38 H32 Ag2 B2 F8 N8 S2'
_chemical_formula_weight         1054.20
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.776(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.368(1)
_cell_length_b                   10.170(1)
_cell_length_c                   21.555(2)
_cell_measurement_reflns_used    32637
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.37
_cell_measurement_theta_min      2.16
_cell_volume                     4105.7(6)
_computing_cell_refinement       Saint
_computing_data_collection       Smart
_computing_data_reduction        Saint
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    Sir2004
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Smart APEXII CCD'
_diffrn_measurement_method       'theta & omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0400
_diffrn_reflns_av_sigmaI/netI    0.0282
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            56570
_diffrn_reflns_theta_full        28.37
_diffrn_reflns_theta_max         28.37
_diffrn_reflns_theta_min         2.16
_diffrn_standards_decay_%        none
_exptl_absorpt_coefficient_mu    1.132
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.721
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.705
_exptl_crystal_description       block
_exptl_crystal_F_000             2096
_exptl_crystal_size_max          0.47
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.13
_refine_diff_density_max         2.945
_refine_diff_density_min         -2.319
_refine_diff_density_rms         0.087
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     597
_refine_ls_number_reflns         10270
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0843
_refine_ls_R_factor_gt           0.0554
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0513P)²+9.5299P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1314
_refine_ls_wR_factor_ref         0.1494
_reflns_number_gt                7027
_reflns_number_total             10270
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201338w_si_001_01.cif
_cod_data_source_block           ib118
_cod_database_code               4326632
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x-1/2, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.45334(2) 0.23530(5) 0.20045(2) 0.06458(14) Uani 1 1 d . . .
Ag1 Ag 0.22690(3) 0.43682(6) 0.25989(3) 0.08924(19) Uani 1 1 d . . .
S13 S 0.49454(6) 0.40620(11) 0.29748(6) 0.0465(2) Uani 1 1 d . . .
S16 S 0.18809(5) 0.23227(11) 0.18743(7) 0.0540(3) Uani 1 1 d . . .
C26 C 0.0573(2) 0.1172(4) 0.1448(2) 0.0394(8) Uani 1 1 d . . .
N14 N 0.04784(16) 0.3602(3) 0.12865(16) 0.0390(7) Uani 1 1 d . . .
C46 C 0.0422(3) -0.0929(5) 0.1875(3) 0.0590(12) Uani 1 1 d . . .
H46 H 0.0124 -0.1614 0.1855 0.071 Uiso 1 1 calc R . .
N15 N -0.04997(18) 0.2262(4) 0.05021(18) 0.0490(8) Uani 1 1 d . . .
C32 C 0.3684(3) 0.6357(5) 0.2025(3) 0.0572(12) Uani 1 1 d . . .
H32 H 0.3995 0.7064 0.2133 0.069 Uiso 1 1 calc R . .
C14 C 0.0698(2) 0.5048(5) 0.2075(2) 0.0535(11) Uani 1 1 d . . .
H14 H 0.0736 0.5485 0.2471 0.064 Uiso 1 1 calc R . .
C34 C 0.0757(2) 0.4631(4) 0.1109(2) 0.0479(10) Uani 1 1 d . . .
H34 H 0.0830 0.4684 0.0718 0.058 Uiso 1 1 calc R . .
N12 N 0.35775(18) 0.5628(3) 0.24916(19) 0.0449(8) Uani 1 1 d . . .
C35 C -0.0867(3) 0.2073(5) -0.0201(2) 0.0629(13) Uani 1 1 d . . .
H35 H -0.0678 0.1962 -0.0506 0.076 Uiso 1 1 calc R . .
N22 N 0.3091(2) 0.4665(4) 0.2159(2) 0.0565(10) Uani 1 1 d . . .
N11 N 0.34374(19) 0.6543(4) 0.3440(2) 0.0519(9) Uani 1 1 d . . .
C63 C 0.4879(2) 0.2542(5) 0.3994(2) 0.0513(10) Uani 1 1 d . . .
H63 H 0.5196 0.1994 0.3938 0.062 Uiso 1 1 calc R . .
C76 C 0.13087(19) 0.1073(4) 0.1907(2) 0.0410(8) Uani 1 1 d . . .
N24 N 0.04369(18) 0.3849(4) 0.18879(18) 0.0458(8) Uani 1 1 d . . .
C96 C 0.2600(3) 0.0952(5) 0.1346(3) 0.0644(13) Uani 1 1 d . . .
H96 H 0.2192 0.1067 0.0911 0.077 Uiso 1 1 calc R . .
C73 C 0.4629(2) 0.3670(4) 0.3589(2) 0.0416(8) Uani 1 1 d . . .
C16 C 0.0270(2) 0.2328(4) 0.0937(2) 0.0419(9) Uani 1 1 d . . .
H16 H 0.0472 0.2272 0.0615 0.050 Uiso 1 1 calc R . .
C24 C 0.0911(3) 0.5580(4) 0.1608(3) 0.0542(11) Uani 1 1 d . . .
H24 H 0.1114 0.6401 0.1633 0.065 Uiso 1 1 calc R . .
C36 C 0.0141(2) 0.0141(4) 0.1433(2) 0.0482(10) Uani 1 1 d . . .
H36 H -0.0346 0.0171 0.1120 0.058 Uiso 1 1 calc R . .
C53 C 0.4657(3) 0.2227(5) 0.4483(3) 0.0626(13) Uani 1 1 d . . .
H53 H 0.4816 0.1460 0.4750 0.075 Uiso 1 1 calc R . .
C56 C 0.1138(3) -0.0989(5) 0.2345(3) 0.0573(11) Uani 1 1 d . . .
H56 H 0.1324 -0.1696 0.2654 0.069 Uiso 1 1 calc R . .
N21 N 0.27898(19) 0.6085(4) 0.3317(2) 0.0594(10) Uani 1 1 d . . .
C11 C 0.2579(3) 0.6910(7) 0.3655(3) 0.0805(18) Uani 1 1 d . . .
H11 H 0.2148 0.6847 0.3661 0.097 Uiso 1 1 calc R . .
C116 C 0.3785(3) 0.0136(5) 0.2018(3) 0.0681(15) Uani 1 1 d . . .
H116 H 0.4174 -0.0312 0.2039 0.082 Uiso 1 1 calc R . .
C31 C 0.3631(3) 0.7613(6) 0.3855(3) 0.0773(16) Uani 1 1 d . . .
H31 H 0.4054 0.8083 0.4016 0.093 Uiso 1 1 calc R . .
C33 C 0.3959(3) 0.4178(6) 0.4179(3) 0.0623(13) Uani 1 1 d . . .
H33 H 0.3660 0.4739 0.4256 0.075 Uiso 1 1 calc R . .
C136 C 0.3241(2) 0.1288(5) 0.2600(3) 0.0641(13) Uani 1 1 d . . .
H136 H 0.3266 0.1629 0.3012 0.077 Uiso 1 1 calc R . .
C106 C 0.3186(3) 0.0299(6) 0.1387(3) 0.0770(16) Uani 1 1 d . . .
H106 H 0.3170 -0.0033 0.0977 0.092 Uiso 1 1 calc R . .
C86 C 0.2630(2) 0.1433(4) 0.1959(2) 0.0466(9) Uani 1 1 d . . .
C66 C 0.1584(2) 0.0009(5) 0.2356(3) 0.0555(11) Uani 1 1 d . . .
H66 H 0.2071 -0.0037 0.2668 0.067 Uiso 1 1 calc R . .
C13 C 0.3907(2) 0.5797(4) 0.3253(2) 0.0446(9) Uani 1 1 d . . .
H13 H 0.4336 0.6332 0.3394 0.053 Uiso 1 1 calc R . .
C23 C 0.4152(2) 0.4505(4) 0.3663(2) 0.0442(9) Uani 1 1 d . . .
C126 C 0.3817(3) 0.0629(6) 0.2623(3) 0.0752(16) Uani 1 1 d . . .
H126 H 0.4230 0.0519 0.3054 0.090 Uiso 1 1 calc R . .
C43 C 0.4198(3) 0.3056(6) 0.4572(3) 0.0707(15) Uani 1 1 d . . .
H43 H 0.4050 0.2852 0.4901 0.085 Uiso 1 1 calc R . .
C22 C 0.3251(3) 0.5865(6) 0.1371(3) 0.0700(15) Uani 1 1 d . . .
H22 H 0.3204 0.6163 0.0943 0.084 Uiso 1 1 calc R . .
N25 N -0.09396(18) 0.2384(4) 0.0794(2) 0.0553(9) Uani 1 1 d . . .
C133 C 0.6247(3) 0.2798(5) 0.3507(3) 0.0621(12) Uani 1 1 d . . .
H133 H 0.6006 0.2112 0.3198 0.075 Uiso 1 1 calc R . .
C93 C 0.6239(3) 0.4899(6) 0.3999(3) 0.0765(16) Uani 1 1 d . . .
H93 H 0.5992 0.5645 0.4008 0.092 Uiso 1 1 calc R . .
C83 C 0.5887(2) 0.3886(5) 0.3539(2) 0.0480(10) Uani 1 1 d . . .
C123 C 0.6985(3) 0.2742(8) 0.3950(4) 0.090(2) Uani 1 1 d . . .
H123 H 0.7241 0.2024 0.3924 0.108 Uiso 1 1 calc R . .
C103 C 0.6970(4) 0.4793(9) 0.4450(4) 0.103(2) Uani 1 1 d . . .
H103 H 0.7211 0.5457 0.4775 0.123 Uiso 1 1 calc R . .
C25 C -0.1573(3) 0.2075(6) -0.0380(3) 0.0765(16) Uani 1 1 d . . .
H25 H -0.1962 0.1966 -0.0829 0.092 Uiso 1 1 calc R . .
C15 C -0.1591(2) 0.2274(6) 0.0244(3) 0.0668(14) Uani 1 1 d . . .
H15 H -0.2009 0.2325 0.0277 0.080 Uiso 1 1 calc R . .
C12 C 0.2896(3) 0.4831(6) 0.1475(3) 0.0673(14) Uani 1 1 d . . .
H12 H 0.2561 0.4310 0.1112 0.081 Uiso 1 1 calc R . .
C113 C 0.7332(3) 0.3724(10) 0.4416(3) 0.097(2) Uani 1 1 d . . .
H113 H 0.7821 0.3663 0.4716 0.117 Uiso 1 1 calc R . .
C21 C 0.3084(4) 0.7878(8) 0.3996(4) 0.102(2) Uani 1 1 d . . .
H21 H 0.3058 0.8567 0.4266 0.122 Uiso 1 1 calc R . .
B1 B 0.1069(3) 0.3155(7) -0.0411(3) 0.0603(14) Uani 1 1 d D . .
F1 F 0.08428(17) 0.3136(3) -0.11240(14) 0.0742(8) Uani 1 1 d D A .
F3 F 0.0690(7) 0.2381(15) -0.0241(5) 0.115(5) Uani 0.66(2) 1 d P A 1
F4 F 0.1759(4) 0.2923(15) -0.0092(5) 0.107(4) Uani 0.66(2) 1 d P A 1
F2 F 0.0985(8) 0.4469(7) -0.0245(4) 0.109(4) Uani 0.66(2) 1 d P A 1
F3A F 0.105(2) 0.1802(17) -0.0207(10) 0.153(12) Uani 0.34(2) 1 d PD A 2
F2A F 0.0578(13) 0.370(5) -0.0283(7) 0.153(17) Uani 0.34(2) 1 d PD A 2
F4A F 0.1723(12) 0.353(3) 0.0057(11) 0.152(13) Uani 0.34(2) 1 d PD A 2
B2 B 0.0594(3) 0.6179(8) 0.3794(4) 0.080(2) Uani 1 1 d D . .
F5 F 0.0517(3) 0.5076(4) 0.3419(2) 0.1142(14) Uani 1 1 d D B .
F8 F 0.1168(8) 0.689(2) 0.4137(10) 0.097(5) Uani 0.474(16) 1 d P B 3
F7 F 0.0833(8) 0.5456(10) 0.4504(5) 0.103(4) Uani 0.474(16) 1 d P B 3
F6 F 0.0085(5) 0.6890(11) 0.3727(8) 0.099(5) Uani 0.474(16) 1 d P B 3
F7A F 0.0141(7) 0.6962(10) 0.3162(8) 0.172(8) Uani 0.526(16) 1 d PD B 4
F6A F 0.0230(11) 0.600(2) 0.4121(10) 0.196(12) Uani 0.526(16) 1 d PD B 4
F8A F 0.1211(9) 0.672(2) 0.3908(12) 0.133(8) Uani 0.526(16) 1 d PD B 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N25 Ag2 N24 82.96(12) 4_665 4_665
N25 Ag2 S13 129.92(11) 4_665 .
N24 Ag2 S13 117.36(9) 4_665 .
N21 Ag1 N22 87.70(13) . .
N21 Ag1 S16 171.13(10) . .
N22 Ag1 S16 86.73(10) . .
C83 S13 C73 100.14(19) . .
C83 S13 Ag2 108.84(15) . .
C73 S13 Ag2 110.63(14) . .
C86 S16 C76 103.51(19) . .
C86 S16 Ag1 110.52(15) . .
C76 S16 Ag1 126.60(14) . .
C36 C26 C76 118.0(4) . .
C36 C26 C16 121.3(3) . .
C76 C26 C16 120.4(3) . .
C34 N14 N24 111.5(3) . .
C34 N14 C16 127.7(3) . .
N24 N14 C16 120.7(3) . .
C56 C46 C36 120.4(4) . .
C56 C46 H46 119.8 . .
C36 C46 H46 119.8 . .
C35 N15 N25 112.0(4) . .
C35 N15 C16 126.9(4) . .
N25 N15 C16 121.1(3) . .
N12 C32 C22 107.2(4) . .
N12 C32 H32 126.4 . .
C22 C32 H32 126.4 . .
N24 C14 C24 111.9(4) . .
N24 C14 H14 124.0 . .
C24 C14 H14 124.0 . .
N14 C34 C24 107.3(4) . .
N14 C34 H34 126.3 . .
C24 C34 H34 126.3 . .
C32 N12 N22 111.3(4) . .
C32 N12 C13 127.7(4) . .
N22 N12 C13 121.0(3) . .
N15 C35 C25 106.5(5) . .
N15 C35 H35 126.7 . .
C25 C35 H35 126.7 . .
C12 N22 N12 104.2(4) . .
C12 N22 Ag1 123.9(3) . .
N12 N22 Ag1 113.9(3) . .
C31 N11 N21 111.5(4) . .
C31 N11 C13 125.0(4) . .
N21 N11 C13 122.5(4) . .
C73 C63 C53 120.1(4) . .
C73 C63 H63 119.9 . .
C53 C63 H63 119.9 . .
C66 C76 C26 120.4(4) . .
C66 C76 S16 121.1(3) . .
C26 C76 S16 118.5(3) . .
C14 N24 N14 104.4(3) . .
C14 N24 Ag2 133.0(3) . 4_565
N14 N24 Ag2 115.4(2) . 4_565
C106 C96 C86 119.1(5) . .
C106 C96 H96 120.5 . .
C86 C96 H96 120.5 . .
C63 C73 C23 121.0(4) . .
C63 C73 S13 118.7(3) . .
C23 C73 S13 120.3(3) . .
N15 C16 N14 110.2(3) . .
N15 C16 C26 112.7(3) . .
N14 C16 C26 113.2(3) . .
N15 C16 H16 106.8 . .
N14 C16 H16 106.8 . .
C26 C16 H16 106.8 . .
C34 C24 C14 104.8(4) . .
C34 C24 H24 127.6 . .
C14 C24 H24 127.6 . .
C46 C36 C26 121.1(4) . .
C46 C36 H36 119.4 . .
C26 C36 H36 119.4 . .
C43 C53 C63 119.4(5) . .
C43 C53 H53 120.3 . .
C63 C53 H53 120.3 . .
C46 C56 C66 119.6(4) . .
C46 C56 H56 120.2 . .
C66 C56 H56 120.2 . .
C11 N21 N11 105.0(5) . .
C11 N21 Ag1 133.3(4) . .
N11 N21 Ag1 121.5(3) . .
N21 C11 C21 111.0(5) . .
N21 C11 H11 124.5 . .
C21 C11 H11 124.5 . .
C106 C116 C126 120.1(5) . .
C106 C116 H116 120.0 . .
C126 C116 H116 120.0 . .
N11 C31 C21 106.6(6) . .
N11 C31 H31 126.7 . .
C21 C31 H31 126.7 . .
C43 C33 C23 121.7(4) . .
C43 C33 H33 119.2 . .
C23 C33 H33 119.2 . .
C86 C136 C126 119.1(5) . .
C86 C136 H136 120.5 . .
C126 C136 H136 120.5 . .
C116 C106 C96 120.7(5) . .
C116 C106 H106 119.6 . .
C96 C106 H106 119.6 . .
C136 C86 C96 120.4(4) . .
C136 C86 S16 122.2(4) . .
C96 C86 S16 117.3(3) . .
C76 C66 C56 120.4(4) . .
C76 C66 H66 119.8 . .
C56 C66 H66 119.8 . .
N12 C13 N11 110.4(3) . .
N12 C13 C23 113.4(3) . .
N11 C13 C23 112.0(3) . .
N12 C13 H13 106.8 . .
N11 C13 H13 106.8 . .
C23 C13 H13 106.8 . .
C73 C23 C33 117.2(4) . .
C73 C23 C13 121.5(4) . .
C33 C23 C13 121.0(4) . .
C116 C126 C136 120.6(5) . .
C116 C126 H126 119.7 . .
C136 C126 H126 119.7 . .
C33 C43 C53 120.5(4) . .
C33 C43 H43 119.7 . .
C53 C43 H43 119.7 . .
C32 C22 C12 105.5(4) . .
C32 C22 H22 127.3 . .
C12 C22 H22 127.3 . .
C15 N25 N15 103.9(4) . .
C15 N25 Ag2 135.7(3) . 4_565
N15 N25 Ag2 120.4(3) . 4_565
C83 C133 C123 118.4(5) . .
C83 C133 H133 120.8 . .
C123 C133 H133 120.8 . .
C83 C93 C103 119.1(6) . .
C83 C93 H93 120.4 . .
C103 C93 H93 120.4 . .
C133 C83 C93 121.1(5) . .
C133 C83 S13 121.4(4) . .
C93 C83 S13 117.4(4) . .
C113 C123 C133 120.7(6) . .
C113 C123 H123 119.6 . .
C133 C123 H123 119.6 . .
C113 C103 C93 120.1(7) . .
C113 C103 H103 119.9 . .
C93 C103 H103 119.9 . .
C35 C25 C15 105.6(4) . .
C35 C25 H25 127.2 . .
C15 C25 H25 127.2 . .
N25 C15 C25 111.9(5) . .
N25 C15 H15 124.0 . .
C25 C15 H15 124.0 . .
N22 C12 C22 111.8(5) . .
N22 C12 H12 124.1 . .
C22 C12 H12 124.1 . .
C103 C113 C123 120.5(6) . .
C103 C113 H113 119.7 . .
C123 C113 H113 119.7 . .
C31 C21 C11 105.8(5) . .
C31 C21 H21 127.1 . .
C11 C21 H21 127.1 . .
F3 B1 F4 116.0(10) . .
F3 B1 F4A 122.2(13) . .
F4 B1 F4A 31.5(14) . .
F3 B1 F2A 62.3(16) . .
F4 B1 F2A 140.0(10) . .
F4A B1 F2A 111.7(14) . .
F3 B1 F1 112.0(6) . .
F4 B1 F1 106.6(6) . .
F4A B1 F1 121.9(12) . .
F2A B1 F1 110.5(7) . .
F3 B1 F2 109.1(7) . .
F4 B1 F2 106.5(7) . .
F4A B1 F2 75.6(14) . .
F2A B1 F2 48.9(17) . .
F1 B1 F2 106.1(6) . .
F3 B1 F3A 40.0(13) . .
F4 B1 F3A 81.6(15) . .
F4A B1 F3A 102.3(14) . .
F2A B1 F3A 101.7(14) . .
F1 B1 F3A 106.2(9) . .
F2 B1 F3A 142.7(12) . .
F6 B2 F6A 55.0(10) . .
F6 B2 F8 105.9(13) . .
F6A B2 F8 114.8(12) . .
F6 B2 F8A 120.5(14) . .
F6A B2 F8A 139.3(13) . .
F8 B2 F8A 24.9(14) . .
F6 B2 F5 124.2(8) . .
F6A B2 F5 106.2(8) . .
F8 B2 F5 127.8(11) . .
F8A B2 F5 106.2(11) . .
F6 B2 F7A 55.5(8) . .
F6A B2 F7A 106.3(12) . .
F8 B2 F7A 104.3(13) . .
F8A B2 F7A 95.7(13) . .
F5 B2 F7A 93.4(7) . .
F6 B2 F7 104.0(8) . .
F6A B2 F7 52.4(11) . .
F8 B2 F7 86.0(12) . .
F8A B2 F7 100.8(13) . .
F5 B2 F7 94.9(7) . .
F7A B2 F7 158.7(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag2 N25 2.316(4) 4_665
Ag2 N24 2.398(3) 4_665
Ag2 S13 2.5293(12) .
Ag1 N21 2.241(4) .
Ag1 N22 2.384(4) .
Ag1 S16 2.4916(13) .
S13 C83 1.790(4) .
S13 C73 1.798(4) .
S16 C86 1.769(4) .
S16 C76 1.789(4) .
C26 C36 1.386(6) .
C26 C76 1.401(5) .
C26 C16 1.526(6) .
N14 C34 1.348(5) .
N14 N24 1.364(4) .
N14 C16 1.457(5) .
C46 C56 1.370(7) .
C46 C36 1.379(7) .
C46 H46 0.9300 .
N15 C35 1.343(6) .
N15 N25 1.365(5) .
N15 C16 1.451(5) .
C32 N12 1.354(5) .
C32 C22 1.355(7) .
C32 H32 0.9300 .
C14 N24 1.321(6) .
C14 C24 1.399(6) .
C14 H14 0.9300 .
C34 C24 1.362(6) .
C34 H34 0.9300 .
N12 N22 1.355(5) .
N12 C13 1.451(5) .
C35 C25 1.366(7) .
C35 H35 0.9300 .
N22 C12 1.336(6) .
N11 C31 1.341(6) .
N11 N21 1.359(5) .
N11 C13 1.462(5) .
C63 C73 1.384(6) .
C63 C53 1.386(6) .
C63 H63 0.9300 .
C76 C66 1.380(6) .
N24 Ag2 2.398(3) 4_565
C96 C106 1.382(7) .
C96 C86 1.383(7) .
C96 H96 0.9300 .
C73 C23 1.393(5) .
C16 H16 0.9800 .
C24 H24 0.9300 .
C36 H36 0.9300 .
C53 C43 1.373(7) .
C53 H53 0.9300 .
C56 C66 1.384(7) .
C56 H56 0.9300 .
N21 C11 1.324(7) .
C11 C21 1.382(10) .
C11 H11 0.9300 .
C116 C106 1.356(8) .
C116 C126 1.369(8) .
C116 H116 0.9300 .
C31 C21 1.368(9) .
C31 H31 0.9300 .
C33 C43 1.365(7) .
C33 C23 1.400(6) .
C33 H33 0.9300 .
C136 C86 1.378(6) .
C136 C126 1.381(7) .
C136 H136 0.9300 .
C106 H106 0.9300 .
C66 H66 0.9300 .
C13 C23 1.529(6) .
C13 H13 0.9800 .
C126 H126 0.9300 .
C43 H43 0.9300 .
C22 C12 1.376(8) .
C22 H22 0.9300 .
N25 C15 1.328(6) .
N25 Ag2 2.316(4) 4_565
C133 C83 1.368(7) .
C133 C123 1.397(7) .
C133 H133 0.9300 .
C93 C83 1.375(7) .
C93 C103 1.391(9) .
C93 H93 0.9300 .
C123 C113 1.357(10) .
C123 H123 0.9300 .
C103 C113 1.356(11) .
C103 H103 0.9300 .
C25 C15 1.379(8) .
C25 H25 0.9300 .
C15 H15 0.9300 .
C12 H12 0.9300 .
C113 H113 0.9300 .
C21 H21 0.9300 .
B1 F3 1.303(10) .
B1 F4 1.313(9) .
B1 F4A 1.326(13) .
B1 F2A 1.329(11) .
B1 F1 1.372(6) .
B1 F2 1.418(9) .
B1 F3A 1.449(14) .
B2 F6 1.257(10) .
B2 F6A 1.291(10) .
B2 F8 1.30(2) .
B2 F8A 1.336(14) .
B2 F5 1.345(8) .
B2 F7A 1.469(12) .
B2 F7 1.546(12) .
