#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:21:30 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179373 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/70/4327085.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4327085
loop_
_publ_author_name
'Luís M. P. Lima'
'Alexandre Lecointre'
'Jean-François Morfin'
'Andrés de Blas'
'Dimitris Visvikis'
'Loïc J. Charbonnière'
'Carlos Platas-Iglesias'
'Raphaël Tripier'
_publ_contact_author_address
;
Laboratoire de chimie,
electrochimie moleculaire et chimie analytique (UMR 6521)
Universite de Bretagne occidentale
6, avenue Victor Le Gorgeu
CS 93837
F-29238 BREST cedex 3
FRANCE 
;
_publ_contact_author_email       'Tripier, Raphael'
_publ_contact_author_name        'Tripier, Raphael'
_publ_section_title
;
 Positively Charged Lanthanide Complexes with Cyclen-Based Ligands:
 Synthesis, Solid-State and Solution Structure, and Fluoride Interaction
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              12508
_journal_page_last               12521
_journal_paper_doi               10.1021/ic201447c
_journal_volume                  50
_journal_year                    2011
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety
'C64 H104 Eu2 F N16 O12, 3(Cl), 2(F), 18.16(O)'
_chemical_formula_sum            'C64 H104 Cl3 Eu2 F3 N16 O30.16'
_chemical_formula_weight         2047.45
_chemical_name_common            RTLIEU
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      13
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_date             2011-06-04T20:20:38-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 90.018(1)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.3092(3)
_cell_length_b                   16.5654(3)
_cell_length_c                   20.9868(4)
_cell_measurement_reflns_used    4915
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.13
_cell_measurement_theta_min      2.76
_cell_measurement_wavelength     0.71073
_cell_volume                     4627.01(16)
_computing_cell_refinement       'APEX2 v2011.4-1 (Bruker AXS, 2011)'
_computing_data_collection       'APEX2 v2011.4-1 (Bruker AXS, 2011)'
_computing_data_reduction        'APEX2 v2011.4-1 (Bruker AXS, 2011)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker X8 kappa APEXII CCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0675
_diffrn_reflns_av_unetI/netI     0.0501
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            84946
_diffrn_reflns_theta_full        29.39
_diffrn_reflns_theta_max         29.39
_diffrn_reflns_theta_min         0.97
_exptl_absorpt_coefficient_mu    1.516
_exptl_absorpt_correction_T_max  0.8879
_exptl_absorpt_correction_T_min  0.7714
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'BRUKER AXS - SADABS'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.470
_exptl_crystal_description       prism
_exptl_crystal_F_000             2090.4
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.656
_refine_diff_density_min         -0.794
_refine_diff_density_rms         0.14
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     739
_refine_ls_number_reflns         12766
_refine_ls_number_restraints     806
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0727
_refine_ls_R_factor_gt           0.0417
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0523P)²+10.3248P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0976
_refine_ls_wR_factor_ref         0.1117
_reflns_number_gt                9325
_reflns_number_total             12766
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic201447c_si_001.cif
_cod_data_source_block           uc01tra2n
_cod_original_sg_symbol_H-M      'P 2/n'
_cod_database_code               4327085
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.25 0.395660(11) 0.25 0.01378(5) Uani 1 2 d SU . .
N1 N 0.1005(3) 0.4992(2) 0.21718(19) 0.0226(8) Uani 1 1 d U . .
C2 C 0.0857(3) 0.5647(2) 0.2646(2) 0.0266(11) Uani 1 1 d U . .
H2A H 0.018 0.5883 0.2585 0.032 Uiso 1 1 calc R . .
H2B H 0.1356 0.6078 0.2565 0.032 Uiso 1 1 calc R . .
C3 C 0.0957(4) 0.5370(3) 0.3323(3) 0.0284(10) Uani 1 1 d U . .
H3A H 0.0863 0.5836 0.3612 0.034 Uiso 1 1 calc R . .
H3B H 0.0424 0.4971 0.3418 0.034 Uiso 1 1 calc R . .
N4 N 0.1952(3) 0.5001(2) 0.34441(18) 0.0237(8) Uani 1 1 d U . .
C5 C 0.2702(4) 0.5664(2) 0.3495(2) 0.0276(11) Uani 1 1 d U . .
H5A H 0.2603 0.5946 0.3906 0.033 Uiso 1 1 calc R . .
H5B H 0.2577 0.6059 0.315 0.033 Uiso 1 1 calc R . .
C6 C 0.3787(4) 0.5382(3) 0.3454(2) 0.0272(11) Uani 1 1 d U . .
H6A H 0.4241 0.5849 0.3512 0.033 Uiso 1 1 calc R . .
H6B H 0.3922 0.4992 0.3802 0.033 Uiso 1 1 calc R . .
C7 C 0.0073(4) 0.4504(3) 0.2106(3) 0.0335(11) Uani 1 1 d U . .
H7A H 0.0106 0.4189 0.1705 0.04 Uiso 1 1 calc R . .
H7B H -0.0512 0.4872 0.2076 0.04 Uiso 1 1 calc R . .
C8 C -0.0079(4) 0.3939(2) 0.2653(3) 0.0315(13) Uani 1 1 d U . .
N9 N 0.0747(3) 0.3537(2) 0.2852(2) 0.0245(8) Uani 1 1 d U . .
C10 C 0.0627(4) 0.2980(2) 0.3312(3) 0.0318(11) Uani 1 1 d U . .
H10 H 0.1201 0.2692 0.3458 0.038 Uiso 1 1 calc R . .
C11 C -0.0303(5) 0.2807(3) 0.3582(3) 0.0488(15) Uani 1 1 d U . .
H11 H -0.0364 0.2402 0.39 0.059 Uiso 1 1 calc R . .
C12 C -0.1135(5) 0.3234(3) 0.3379(4) 0.0627(18) Uani 1 1 d U . .
H12 H -0.1775 0.3141 0.3566 0.075 Uiso 1 1 calc R . .
C13 C -0.1022(4) 0.3801(3) 0.2900(4) 0.0544(17) Uani 1 1 d U . .
H13 H -0.1587 0.409 0.2744 0.065 Uiso 1 1 calc R . .
C14 C 0.1925(4) 0.4538(3) 0.4048(2) 0.0300(10) Uani 1 1 d U A .
H14A H 0.1264 0.427 0.409 0.036 Uiso 1 1 calc R . .
H14B H 0.2006 0.4913 0.4411 0.036 Uiso 1 1 calc R . .
C15 C 0.2745(4) 0.3911(2) 0.4070(2) 0.0306(13) Uani 1 1 d U . .
O16 O 0.3019(3) 0.35868(17) 0.35664(15) 0.0257(7) Uani 1 1 d U A .
N17A N 0.3191(6) 0.3750(4) 0.4627(4) 0.0246(14) Uani 0.577(4) 1 d PDU A 1
H17A H 0.2994 0.4034 0.4958 0.029 Uiso 0.577(4) 1 calc PR A 1
C18A C 0.3983(7) 0.3143(5) 0.4738(5) 0.0397(18) Uani 0.577(4) 1 d PDU A 1
H18A H 0.4108 0.2845 0.4338 0.048 Uiso 0.577(4) 1 calc PR A 1
H18B H 0.3743 0.275 0.506 0.048 Uiso 0.577(4) 1 calc PR A 1
C19A C 0.4936(7) 0.3503(5) 0.4961(4) 0.0448(18) Uani 0.577(4) 1 d PDU A 1
H19A H 0.4817 0.3849 0.5339 0.054 Uiso 0.577(4) 1 calc PR A 1
H19B H 0.542 0.3075 0.5079 0.054 Uiso 0.577(4) 1 calc PR A 1
O20A O 0.5329(6) 0.3987(4) 0.4430(4) 0.0499(17) Uani 0.577(4) 1 d PDU A 1
C21A C 0.6235(8) 0.4391(7) 0.4616(5) 0.064(2) Uani 0.577(4) 1 d PDU A 1
H21A H 0.606 0.4843 0.4904 0.076 Uiso 0.577(4) 1 calc PR A 1
H21B H 0.666 0.4009 0.4859 0.076 Uiso 0.577(4) 1 calc PR A 1
C22A C 0.6785(9) 0.4690(8) 0.4106(6) 0.076(3) Uani 0.577(4) 1 d PDU A 1
H22A H 0.6314 0.4959 0.3809 0.091 Uiso 0.577(4) 1 calc PR A 1
H22B H 0.7083 0.4226 0.3876 0.091 Uiso 0.577(4) 1 calc PR A 1
O23A O 0.7685(7) 0.5323(6) 0.4274(5) 0.089(3) Uani 0.577(4) 1 d PDU A 1
H23A H 0.8086 0.5108 0.4532 0.133 Uiso 0.577(4) 1 calc PR A 1
N17B N 0.2867(7) 0.3653(6) 0.4659(6) 0.029(2) Uani 0.423(4) 1 d PDU A 2
H17B H 0.2478 0.3842 0.4963 0.034 Uiso 0.423(4) 1 calc PR A 2
C18B C 0.3638(8) 0.3058(7) 0.4814(7) 0.038(2) Uani 0.423(4) 1 d PDU A 2
H18C H 0.3351 0.2666 0.512 0.045 Uiso 0.423(4) 1 calc PR A 2
H18D H 0.3811 0.2758 0.4421 0.045 Uiso 0.423(4) 1 calc PR A 2
C19B C 0.4558(9) 0.3387(9) 0.5084(6) 0.052(3) Uani 0.423(4) 1 d PDU A 2
H19C H 0.4986 0.2942 0.5244 0.062 Uiso 0.423(4) 1 calc PR A 2
H19D H 0.4392 0.3743 0.5448 0.062 Uiso 0.423(4) 1 calc PR A 2
O20B O 0.5103(7) 0.3846(7) 0.4600(6) 0.055(2) Uani 0.423(4) 1 d PDU A 2
C21B C 0.6098(9) 0.4039(10) 0.4840(6) 0.064(3) Uani 0.423(4) 1 d PDU A 2
H21C H 0.6051 0.4483 0.5155 0.076 Uiso 0.423(4) 1 calc PR A 2
H21D H 0.6388 0.3562 0.5056 0.076 Uiso 0.423(4) 1 calc PR A 2
C22B C 0.6731(12) 0.4278(8) 0.4327(9) 0.083(3) Uani 0.423(4) 1 d PDU A 2
H22C H 0.6631 0.3912 0.3959 0.1 Uiso 0.423(4) 1 calc PR A 2
H22D H 0.7444 0.4246 0.4459 0.1 Uiso 0.423(4) 1 calc PR A 2
O23B O 0.6445(11) 0.5219(7) 0.4121(7) 0.089(4) Uani 0.423(4) 1 d PDU A 2
H23B H 0.5875 0.5338 0.4264 0.134 Uiso 0.423(4) 1 calc PR A 2
Eu2 Eu 0.25 0.114759(11) 0.25 0.01297(6) Uani 1 2 d SU . .
N51 N 0.1099(3) 0.0125(2) 0.2925(2) 0.0234(8) Uani 1 1 d U . .
C52 C 0.1416(4) -0.0259(2) 0.3538(2) 0.0282(10) Uani 1 1 d U . .
H52A H 0.1358 0.0141 0.3887 0.034 Uiso 1 1 calc R . .
H52B H 0.096 -0.0714 0.3637 0.034 Uiso 1 1 calc R . .
C53 C 0.2455(6) -0.05570(19) 0.35094(19) 0.0264(8) Uani 1 1 d U . .
H53A H 0.2511 -0.0955 0.3159 0.032 Uiso 1 1 calc R . .
H53B H 0.2617 -0.0838 0.3913 0.032 Uiso 1 1 calc R . .
N54 N 0.3208(3) 0.0105(2) 0.34028(19) 0.0238(8) Uani 1 1 d U . .
C55 C 0.4198(4) -0.0262(3) 0.3213(3) 0.0304(10) Uani 1 1 d U . .
H55A H 0.474 0.0142 0.3269 0.037 Uiso 1 1 calc R . .
H55B H 0.4347 -0.0728 0.3492 0.037 Uiso 1 1 calc R . .
C56 C 0.4169(3) -0.0534(2) 0.2531(3) 0.0287(9) Uani 1 1 d U . .
H56A H 0.4836 -0.0754 0.2414 0.034 Uiso 1 1 calc R . .
H56B H 0.3673 -0.0976 0.2489 0.034 Uiso 1 1 calc R . .
C57 C 0.0182(4) 0.0621(3) 0.3066(3) 0.0373(12) Uani 1 1 d U . .
H57A H -0.0393 0.0255 0.3145 0.045 Uiso 1 1 calc R . .
H57B H 0.0299 0.0937 0.3459 0.045 Uiso 1 1 calc R . .
C58 C -0.0079(3) 0.1181(2) 0.2539(4) 0.0361(12) Uani 1 1 d U . .
N59 N 0.0689(3) 0.15599(19) 0.22603(19) 0.0230(8) Uani 1 1 d U . .
C60 C 0.0482(4) 0.2120(3) 0.1814(3) 0.0296(11) Uani 1 1 d U . .
H60 H 0.1023 0.2408 0.1626 0.036 Uiso 1 1 calc R . .
C61 C -0.0480(5) 0.2290(3) 0.1621(4) 0.0533(16) Uani 1 1 d U . .
H61 H -0.0596 0.269 0.1304 0.064 Uiso 1 1 calc R . .
C62 C -0.1255(5) 0.1892(4) 0.1879(5) 0.083(2) Uani 1 1 d U . .
H62 H -0.1923 0.2002 0.1745 0.1 Uiso 1 1 calc R . .
C63 C -0.1071(4) 0.1317(3) 0.2343(5) 0.074(2) Uani 1 1 d U . .
H63 H -0.1609 0.102 0.2527 0.089 Uiso 1 1 calc R . .
C64 C 0.3357(5) 0.0557(3) 0.4010(2) 0.0338(11) Uani 1 1 d U B .
H64A H 0.4031 0.0811 0.4011 0.041 Uiso 1 1 calc R . .
H64B H 0.3321 0.0178 0.4374 0.041 Uiso 1 1 calc R . .
C65 C 0.2565(6) 0.1194(2) 0.40787(19) 0.0320(11) Uani 1 1 d U . .
O66 O 0.2183(3) 0.15188(16) 0.35918(15) 0.0273(8) Uani 1 1 d U B .
N67A N 0.2485(8) 0.1415(3) 0.4675(3) 0.0276(13) Uani 0.579(2) 1 d PDU B 1
H67A H 0.2865 0.1189 0.4968 0.033 Uiso 0.579(2) 1 calc PR B 1
C68A C 0.1751(6) 0.2049(4) 0.4855(4) 0.0291(16) Uani 0.579(2) 1 d PDU B 1
H68A H 0.2079 0.2435 0.5149 0.035 Uiso 0.579(2) 1 calc PR B 1
H68B H 0.1548 0.2349 0.4468 0.035 Uiso 0.579(2) 1 calc PR B 1
C69A C 0.0847(7) 0.1718(5) 0.5164(4) 0.0354(17) Uani 0.579(2) 1 d PDU B 1
H69A H 0.1047 0.1361 0.5521 0.042 Uiso 0.579(2) 1 calc PR B 1
H69B H 0.0437 0.2164 0.534 0.042 Uiso 0.579(2) 1 calc PR B 1
O70A O 0.0251(5) 0.1258(3) 0.4699(3) 0.0326(14) Uani 0.579(2) 1 d PDU B 1
C71A C -0.0685(7) 0.0903(5) 0.4952(4) 0.0364(16) Uani 0.579(2) 1 d PDU B 1
H71A H -0.051 0.0488 0.5274 0.044 Uiso 0.579(2) 1 calc PR B 1
H71B H -0.1075 0.133 0.517 0.044 Uiso 0.579(2) 1 calc PR B 1
C72A C -0.1305(7) 0.0538(4) 0.4470(4) 0.0311(15) Uani 0.579(2) 1 d PDU B 1
H72A H -0.188 0.0278 0.4688 0.037 Uiso 0.579(2) 1 calc PR B 1
H72B H -0.0908 0.0103 0.4268 0.037 Uiso 0.579(2) 1 calc PR B 1
O73A O -0.1731(5) 0.1067(3) 0.3936(3) 0.0331(14) Uani 0.579(2) 1 d PDU B 1
H73A H -0.194 0.0771 0.3639 0.05 Uiso 0.579(2) 1 calc PR B 1
N67B N 0.2130(8) 0.1362(6) 0.4652(6) 0.0304(19) Uani 0.421(2) 1 d PDU B 2
H67B H 0.2318 0.1061 0.4976 0.037 Uiso 0.421(2) 1 calc PR B 2
C68B C 0.1375(8) 0.1997(7) 0.4790(7) 0.038(2) Uani 0.421(2) 1 d PDU B 2
H68C H 0.1659 0.2384 0.5101 0.046 Uiso 0.421(2) 1 calc PR B 2
H68D H 0.1222 0.2296 0.4393 0.046 Uiso 0.421(2) 1 calc PR B 2
C69B C 0.0435(9) 0.1656(8) 0.5050(6) 0.046(2) Uani 0.421(2) 1 d PDU B 2
H69C H 0.0586 0.1326 0.5431 0.055 Uiso 0.421(2) 1 calc PR B 2
H69D H -0.0021 0.2098 0.5178 0.055 Uiso 0.421(2) 1 calc PR B 2
O70B O -0.0050(7) 0.1156(7) 0.4568(6) 0.054(2) Uani 0.421(2) 1 d PDU B 2
C71B C -0.1129(9) 0.0970(10) 0.4674(8) 0.070(3) Uani 0.421(2) 1 d PDU B 2
H71C H -0.1235 0.0381 0.4636 0.085 Uiso 0.421(2) 1 calc PR B 2
H71D H -0.132 0.1133 0.5111 0.085 Uiso 0.421(2) 1 calc PR B 2
C72B C -0.1762(12) 0.1382(9) 0.4222(9) 0.081(3) Uani 0.421(2) 1 d PDU B 2
H72C H -0.2304 0.1003 0.41 0.097 Uiso 0.421(2) 1 calc PR B 2
H72D H -0.1354 0.1478 0.3835 0.097 Uiso 0.421(2) 1 calc PR B 2
O73B O -0.2321(15) 0.2276(8) 0.4415(6) 0.109(5) Uani 0.421(2) 1 d PDU B 2
H73B H -0.1894 0.2649 0.4399 0.164 Uiso 0.421(2) 1 calc PR B 2
F1 F 0.25 0.25503(14) 0.25 0.0150(5) Uani 1 2 d S . .
Cl1 Cl 0.25 0.75565(6) 0.25 0.0270(2) Uani 1 2 d S . .
O1W O 0.4036(5) 0.7468(2) 0.3668(3) 0.0636(17) Uani 1 1 d U . .
O2W O 0.4111(6) 0.7625(3) 0.1389(3) 0.0692(19) Uani 1 1 d U . .
O3W O 0.3570(4) 0.6807(3) 0.0265(3) 0.0673(15) Uani 1 1 d U . .
O4W O 0.7524(8) 0.5594(3) 0.2871(3) 0.0364(15) Uani 0.5 1 d PU C -1
Cl2A Cl -0.3184(3) 0.1915(2) 0.4985(2) 0.0862(12) Uani 0.579(2) 1 d PU B 1
O11W O 0.7867(12) 0.6647(9) 0.3725(7) 0.149(5) Uani 0.577(4) 1 d PU A 1
O21W O 0.5934(9) 0.7721(7) 0.3378(6) 0.095(4) Uani 0.577(4) 1 d PU A 1
O31W O 0.4399(9) -0.0374(6) 0.5461(5) 0.089(3) Uani 0.579(2) 1 d PU B 1
O33W O 0.3298(6) 0.0882(5) 0.5841(3) 0.0469(19) Uani 0.579(2) 1 d PU B 1
F41 F 0.7244(4) 0.9683(3) 0.3082(2) 0.0416(15) Uani 0.579(2) 1 d PU B 1
O51W O 1.0242(11) 0.4123(8) 0.5067(7) 0.128(4) Uani 0.577(4) 1 d PU A 1
O61W O 0.5938(9) 0.7688(7) 0.1865(6) 0.089(4) Uani 0.577(4) 1 d PU A 1
Cl2B Cl -0.4332(4) 0.1291(3) 0.5122(3) 0.0810(16) Uani 0.421(2) 1 d PU B 2
O12W O 0.8450(12) 0.6014(9) 0.4245(8) 0.091(5) Uani 0.423(4) 1 d PU A 2
O22W O 0.6019(10) 0.7132(8) 0.3024(7) 0.069(3) Uani 0.423(4) 1 d PU A 2
O32W O 0.3807(8) 0.0471(6) 0.5565(5) 0.047(3) Uani 0.421(2) 1 d PU B 2
F42 F 0.8277(9) 0.9192(7) 0.3224(6) 0.088(3) Uani 0.421(2) 1 d PU B 2
O52W O 0.9500(8) 0.4434(6) 0.4647(5) 0.046(2) Uani 0.423(4) 1 d PU A 2
O62W O 0.756(2) 0.8042(12) 0.3663(10) 0.150(6) Uani 0.423(4) 1 d PU A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
F1 Eu1 O16 75.34(7) . 2
F1 Eu1 O16 75.34(7) . .
O16 Eu1 O16 150.68(13) 2 .
F1 Eu1 N9 74.16(8) . .
O16 Eu1 N9 86.44(13) 2 .
O16 Eu1 N9 85.64(13) . .
F1 Eu1 N9 74.16(8) . 2
O16 Eu1 N9 85.64(13) 2 2
O16 Eu1 N9 86.44(13) . 2
N9 Eu1 N9 148.32(15) . 2
F1 Eu1 N1 129.15(8) . 2
O16 Eu1 N1 127.09(12) 2 2
O16 Eu1 N1 73.53(11) . 2
N9 Eu1 N1 140.43(12) . 2
N9 Eu1 N1 64.77(11) 2 2
F1 Eu1 N1 129.15(8) . .
O16 Eu1 N1 73.53(11) 2 .
O16 Eu1 N1 127.09(12) . .
N9 Eu1 N1 64.77(11) . .
N9 Eu1 N1 140.43(12) 2 .
N1 Eu1 N1 101.70(15) 2 .
F1 Eu1 N4 129.33(7) . 2
O16 Eu1 N4 64.24(11) 2 2
O16 Eu1 N4 139.05(12) . 2
N9 Eu1 N4 128.97(13) . 2
N9 Eu1 N4 73.56(12) 2 2
N1 Eu1 N4 65.67(12) 2 2
N1 Eu1 N4 67.15(12) . 2
F1 Eu1 N4 129.33(7) . .
O16 Eu1 N4 139.05(12) 2 .
O16 Eu1 N4 64.24(11) . .
N9 Eu1 N4 73.56(12) . .
N9 Eu1 N4 128.97(13) 2 .
N1 Eu1 N4 67.15(12) 2 .
N1 Eu1 N4 65.67(12) . .
N4 Eu1 N4 101.34(15) 2 .
C2 N1 C7 110.4(4) . .
C2 N1 C6 107.3(3) . 2
C7 N1 C6 108.0(4) . 2
C2 N1 Eu1 112.9(3) . .
C7 N1 Eu1 107.0(2) . .
C6 N1 Eu1 111.1(3) 2 .
N1 C2 C3 113.5(3) . .
N1 C2 H2A 108.9 . .
C3 C2 H2A 108.9 . .
N1 C2 H2B 108.9 . .
C3 C2 H2B 108.9 . .
H2A C2 H2B 107.7 . .
N4 C3 C2 111.6(4) . .
N4 C3 H3A 109.3 . .
C2 C3 H3A 109.3 . .
N4 C3 H3B 109.3 . .
C2 C3 H3B 109.3 . .
H3A C3 H3B 108 . .
C3 N4 C14 109.8(4) . .
C3 N4 C5 107.9(3) . .
C14 N4 C5 109.7(4) . .
C3 N4 Eu1 112.1(3) . .
C14 N4 Eu1 107.4(2) . .
C5 N4 Eu1 109.9(3) . .
N4 C5 C6 113.9(3) . .
N4 C5 H5A 108.8 . .
C6 C5 H5A 108.8 . .
N4 C5 H5B 108.8 . .
C6 C5 H5B 108.8 . .
H5A C5 H5B 107.7 . .
N1 C6 C5 111.1(4) 2 .
N1 C6 H6A 109.4 2 .
C5 C6 H6A 109.4 . .
N1 C6 H6B 109.4 2 .
C5 C6 H6B 109.4 . .
H6A C6 H6B 108 . .
N1 C7 C8 112.4(4) . .
N1 C7 H7A 109.1 . .
C8 C7 H7A 109.1 . .
N1 C7 H7B 109.1 . .
C8 C7 H7B 109.1 . .
H7A C7 H7B 107.9 . .
N9 C8 C13 122.9(5) . .
N9 C8 C7 115.9(4) . .
C13 C8 C7 121.1(5) . .
C10 N9 C8 117.7(4) . .
C10 N9 Eu1 120.3(3) . .
C8 N9 Eu1 121.4(3) . .
N9 C10 C11 122.6(5) . .
N9 C10 H10 118.7 . .
C11 C10 H10 118.7 . .
C12 C11 C10 118.9(5) . .
C12 C11 H11 120.6 . .
C10 C11 H11 120.6 . .
C11 C12 C13 118.9(6) . .
C11 C12 H12 120.5 . .
C13 C12 H12 120.5 . .
C8 C13 C12 119.0(6) . .
C8 C13 H13 120.5 . .
C12 C13 H13 120.5 . .
N4 C14 C15 111.5(4) . .
N4 C14 H14A 109.3 . .
C15 C14 H14A 109.3 . .
N4 C14 H14B 109.3 . .
C15 C14 H14B 109.3 . .
H14A C14 H14B 108 . .
O16 C15 N17B 128.5(6) . .
O16 C15 N17A 121.9(5) . .
O16 C15 C14 118.9(4) . .
N17B C15 C14 110.0(6) . .
N17A C15 C14 119.1(5) . .
C15 O16 Eu1 126.5(3) . .
C15 N17A C18A 126.3(7) . .
C15 N17A H17A 116.9 . .
C18A N17A H17A 116.9 . .
N17A C18A C19A 112.8(7) . .
N17A C18A H18A 109 . .
C19A C18A H18A 109 . .
N17A C18A H18B 109 . .
C19A C18A H18B 109 . .
H18A C18A H18B 107.8 . .
O20A C19A C18A 106.6(7) . .
O20A C19A H19A 110.4 . .
C18A C19A H19A 110.4 . .
O20A C19A H19B 110.4 . .
C18A C19A H19B 110.4 . .
H19A C19A H19B 108.6 . .
C21A O20A C19A 110.2(7) . .
C22A C21A O20A 113.5(9) . .
C22A C21A H21A 108.9 . .
O20A C21A H21A 108.9 . .
C22A C21A H21B 108.9 . .
O20A C21A H21B 108.9 . .
H21A C21A H21B 107.7 . .
C21A C22A O23A 116.7(10) . .
C21A C22A H22A 108.1 . .
O23A C22A H22A 108.1 . .
C21A C22A H22B 108.1 . .
O23A C22A H22B 108.1 . .
H22A C22A H22B 107.3 . .
C15 N17B C18B 121.0(10) . .
C15 N17B H17B 119.5 . .
C18B N17B H17B 119.5 . .
C19B C18B N17B 115.2(10) . .
C19B C18B H18C 108.5 . .
N17B C18B H18C 108.5 . .
C19B C18B H18D 108.5 . .
N17B C18B H18D 108.5 . .
H18C C18B H18D 107.5 . .
C18B C19B O20B 110.0(10) . .
C18B C19B H19C 109.7 . .
O20B C19B H19C 109.7 . .
C18B C19B H19D 109.7 . .
O20B C19B H19D 109.7 . .
H19C C19B H19D 108.2 . .
C21B O20B C19B 109.1(10) . .
C22B C21B O20B 109.8(12) . .
C22B C21B H21C 109.7 . .
O20B C21B H21C 109.7 . .
C22B C21B H21D 109.7 . .
O20B C21B H21D 109.7 . .
H21C C21B H21D 108.2 . .
C21B C22B O23B 108.8(12) . .
C21B C22B H22C 109.9 . .
O23B C22B H22C 109.9 . .
C21B C22B H22D 109.9 . .
O23B C22B H22D 109.9 . .
H22C C22B H22D 108.3 . .
C22B O23B H23B 109.5 . .
F1 Eu2 O66 75.21(6) . .
F1 Eu2 O66 75.21(6) . 2
O66 Eu2 O66 150.43(13) . 2
F1 Eu2 N59 74.49(7) . 2
O66 Eu2 N59 84.83(12) . 2
O66 Eu2 N59 87.34(12) 2 2
F1 Eu2 N59 74.49(7) . .
O66 Eu2 N59 87.34(12) . .
O66 Eu2 N59 84.83(12) 2 .
N59 Eu2 N59 148.99(15) 2 .
F1 Eu2 N51 129.34(8) . .
O66 Eu2 N51 73.85(11) . .
O66 Eu2 N51 126.99(12) 2 .
N59 Eu2 N51 139.61(12) 2 .
N59 Eu2 N51 64.99(11) . .
F1 Eu2 N51 129.34(8) . 2
O66 Eu2 N51 126.99(12) . 2
O66 Eu2 N51 73.85(11) 2 2
N59 Eu2 N51 64.99(11) 2 2
N59 Eu2 N51 139.61(12) . 2
N51 Eu2 N51 101.33(15) . 2
F1 Eu2 N54 129.22(7) . 2
O66 Eu2 N54 139.51(11) . 2
O66 Eu2 N54 64.03(10) 2 2
N59 Eu2 N54 129.12(12) 2 2
N59 Eu2 N54 72.97(12) . 2
N51 Eu2 N54 65.82(12) . 2
N51 Eu2 N54 66.93(12) 2 2
F1 Eu2 N54 129.22(7) . .
O66 Eu2 N54 64.03(10) . .
O66 Eu2 N54 139.51(11) 2 .
N59 Eu2 N54 72.97(12) 2 .
N59 Eu2 N54 129.12(12) . .
N51 Eu2 N54 66.93(12) . .
N51 Eu2 N54 65.82(12) 2 .
N54 Eu2 N54 101.57(15) 2 .
C56 N51 C52 107.9(3) 2 .
C56 N51 C57 109.3(4) 2 .
C52 N51 C57 107.0(4) . .
C56 N51 Eu2 114.6(3) 2 .
C52 N51 Eu2 111.1(3) . .
C57 N51 Eu2 106.6(2) . .
C53 C52 N51 111.9(4) . .
C53 C52 H52A 109.2 . .
N51 C52 H52A 109.2 . .
C53 C52 H52B 109.2 . .
N51 C52 H52B 109.2 . .
H52A C52 H52B 107.9 . .
C52 C53 N54 112.8(3) . .
C52 C53 H53A 109 . .
N54 C53 H53A 109 . .
C52 C53 H53B 109 . .
N54 C53 H53B 109 . .
H53A C53 H53B 107.8 . .
C64 N54 C53 109.1(4) . .
C64 N54 C55 108.2(4) . .
C53 N54 C55 109.2(3) . .
C64 N54 Eu2 108.8(2) . .
C53 N54 Eu2 109.6(3) . .
C55 N54 Eu2 111.9(3) . .
C56 C55 N54 110.6(4) . .
C56 C55 H55A 109.5 . .
N54 C55 H55A 109.5 . .
C56 C55 H55B 109.5 . .
N54 C55 H55B 109.5 . .
H55A C55 H55B 108.1 . .
N51 C56 C55 113.4(3) 2 .
N51 C56 H56A 108.9 2 .
C55 C56 H56A 108.9 . .
N51 C56 H56B 108.9 2 .
C55 C56 H56B 108.9 . .
H56A C56 H56B 107.7 . .
C58 C57 N51 112.6(5) . .
C58 C57 H57A 109.1 . .
N51 C57 H57A 109.1 . .
C58 C57 H57B 109.1 . .
N51 C57 H57B 109.1 . .
H57A C57 H57B 107.8 . .
N59 C58 C63 121.2(6) . .
N59 C58 C57 116.2(4) . .
C63 C58 C57 122.6(5) . .
C58 N59 C60 118.2(4) . .
C58 N59 Eu2 120.7(3) . .
C60 N59 Eu2 120.9(3) . .
N59 C60 C61 122.6(5) . .
N59 C60 H60 118.7 . .
C61 C60 H60 118.7 . .
C62 C61 C60 119.8(6) . .
C62 C61 H61 120.1 . .
C60 C61 H61 120.1 . .
C61 C62 C63 119.2(6) . .
C61 C62 H62 120.4 . .
C63 C62 H62 120.4 . .
C62 C63 C58 119.0(6) . .
C62 C63 H63 120.5 . .
C58 C63 H63 120.5 . .
N54 C64 C65 110.0(4) . .
N54 C64 H64A 109.7 . .
C65 C64 H64A 109.7 . .
N54 C64 H64B 109.7 . .
C65 C64 H64B 109.7 . .
H64A C64 H64B 108.2 . .
O66 C65 N67A 128.5(6) . .
O66 C65 N67B 117.1(7) . .
O66 C65 C64 120.4(4) . .
N67A C65 C64 110.3(6) . .
N67B C65 C64 121.9(6) . .
C65 O66 Eu2 126.2(3) . .
C65 N67A C68A 119.8(7) . .
C65 N67A H67A 120.1 . .
C68A N67A H67A 120.1 . .
C69A C68A N67A 112.8(7) . .
C69A C68A H68A 109 . .
N67A C68A H68A 109 . .
C69A C68A H68B 109 . .
N67A C68A H68B 109 . .
H68A C68A H68B 107.8 . .
O70A C69A C68A 109.9(6) . .
O70A C69A H69A 109.7 . .
C68A C69A H69A 109.7 . .
O70A C69A H69B 109.7 . .
C68A C69A H69B 109.7 . .
H69A C69A H69B 108.2 . .
C69A O70A C71A 115.0(6) . .
C72A C71A O70A 113.4(7) . .
C72A C71A H71A 108.9 . .
O70A C71A H71A 108.9 . .
C72A C71A H71B 108.9 . .
O70A C71A H71B 108.9 . .
H71A C71A H71B 107.7 . .
C71A C72A O73A 119.2(6) . .
C71A C72A H72A 107.5 . .
O73A C72A H72A 107.5 . .
C71A C72A H72B 107.5 . .
O73A C72A H72B 107.5 . .
H72A C72A H72B 107 . .
C65 N67B C68B 127.2(10) . .
C65 N67B H67B 116.4 . .
C68B N67B H67B 116.4 . .
C69B C68B N67B 112.1(10) . .
C69B C68B H68C 109.2 . .
N67B C68B H68C 109.2 . .
C69B C68B H68D 109.2 . .
N67B C68B H68D 109.2 . .
H68C C68B H68D 107.9 . .
O70B C69B C68B 109.7(10) . .
O70B C69B H69C 109.7 . .
C68B C69B H69C 109.7 . .
O70B C69B H69D 109.7 . .
C68B C69B H69D 109.7 . .
H69C C69B H69D 108.2 . .
C69B O70B C71B 116.3(11) . .
C72B C71B O70B 111.6(12) . .
C72B C71B H71C 109.3 . .
O70B C71B H71C 109.3 . .
C72B C71B H71D 109.3 . .
O70B C71B H71D 109.3 . .
H71C C71B H71D 108 . .
C71B C72B O73B 120.7(14) . .
C71B C72B H72C 107.2 . .
O73B C72B H72C 107.2 . .
C71B C72B H72D 107.2 . .
O73B C72B H72D 107.2 . .
H72C C72B H72D 106.8 . .
C72B O73B H73B 109.5 . .
Eu2 F1 Eu1 180 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 F1 2.330(2) .
Eu1 O16 2.421(3) 2
Eu1 O16 2.421(3) .
Eu1 N9 2.545(4) .
Eu1 N9 2.545(4) 2
Eu1 N1 2.715(4) 2
Eu1 N1 2.715(4) .
Eu1 N4 2.730(4) 2
Eu1 N4 2.730(4) .
N1 C2 1.486(6) .
N1 C7 1.486(6) .
N1 C6 1.491(6) 2
C2 C3 1.500(7) .
C2 H2A 0.99 .
C2 H2B 0.99 .
C3 N4 1.480(6) .
C3 H3A 0.99 .
C3 H3B 0.99 .
N4 C14 1.481(6) .
N4 C5 1.488(6) .
C5 C6 1.520(7) .
C5 H5A 0.99 .
C5 H5B 0.99 .
C6 N1 1.491(6) 2
C6 H6A 0.99 .
C6 H6B 0.99 .
C7 C8 1.495(7) .
C7 H7A 0.99 .
C7 H7B 0.99 .
C8 N9 1.350(6) .
C8 C13 1.378(8) .
N9 C10 1.345(6) .
C10 C11 1.391(8) .
C10 H10 0.95 .
C11 C12 1.381(9) .
C11 H11 0.95 .
C12 C13 1.384(9) .
C12 H12 0.95 .
C13 H13 0.95 .
C14 C15 1.507(7) .
C14 H14A 0.99 .
C14 H14B 0.99 .
C15 O16 1.241(5) .
C15 N17B 1.317(12) .
C15 N17A 1.337(9) .
N17A C18A 1.476(9) .
N17A H17A 0.88 .
C18A C19A 1.477(11) .
C18A H18A 0.99 .
C18A H18B 0.99 .
C19A O20A 1.470(10) .
C19A H19A 0.99 .
C19A H19B 0.99 .
O20A C21A 1.433(10) .
C21A C22A 1.390(13) .
C21A H21A 0.99 .
C21A H21B 0.99 .
C22A O23A 1.631(12) .
C22A H22A 0.99 .
C22A H22B 0.99 .
O23A H23A 0.84 .
N17B C18B 1.459(11) .
N17B H17B 0.88 .
C18B C19B 1.455(13) .
C18B H18C 0.99 .
C18B H18D 0.99 .
C19B O20B 1.461(13) .
C19B H19C 0.99 .
C19B H19D 0.99 .
O20B C21B 1.452(12) .
C21B C22B 1.422(15) .
C21B H21C 0.99 .
C21B H21D 0.99 .
C22B O23B 1.662(14) .
C22B H22C 0.99 .
C22B H22D 0.99 .
O23B H23B 0.84 .
Eu2 F1 2.324(2) .
Eu2 O66 2.410(3) .
Eu2 O66 2.410(3) 2
Eu2 N59 2.555(4) 2
Eu2 N59 2.555(4) .
Eu2 N51 2.673(4) .
Eu2 N51 2.673(4) 2
Eu2 N54 2.731(4) 2
Eu2 N54 2.731(4) .
N51 C56 1.495(6) 2
N51 C52 1.496(6) .
N51 C57 1.501(6) .
C52 C53 1.470(9) .
C52 H52A 0.99 .
C52 H52B 0.99 .
C53 N54 1.502(7) .
C53 H53A 0.99 .
C53 H53B 0.99 .
N54 C64 1.490(6) .
N54 C55 1.505(6) .
C55 C56 1.503(8) .
C55 H55A 0.99 .
C55 H55B 0.99 .
C56 N51 1.495(7) 2
C56 H56A 0.99 .
C56 H56B 0.99 .
C57 C58 1.485(9) .
C57 H57A 0.99 .
C57 H57B 0.99 .
C58 N59 1.335(6) .
C58 C63 1.401(7) .
N59 C60 1.347(6) .
C60 C61 1.372(7) .
C60 H60 0.95 .
C61 C62 1.340(9) .
C61 H61 0.95 .
C62 C63 1.385(10) .
C62 H62 0.95 .
C63 H63 0.95 .
C64 C65 1.499(8) .
C64 H64A 0.99 .
C64 H64B 0.99 .
C65 O66 1.262(6) .
C65 N67A 1.308(8) .
C65 N67B 1.365(12) .
N67A C68A 1.483(9) .
N67A H67A 0.88 .
C68A C69A 1.473(10) .
C68A H68A 0.99 .
C68A H68B 0.99 .
C69A O70A 1.471(9) .
C69A H69A 0.99 .
C69A H69B 0.99 .
O70A C71A 1.477(9) .
C71A C72A 1.438(11) .
C71A H71A 0.99 .
C71A H71B 0.99 .
C72A O73A 1.531(9) .
C72A H72A 0.99 .
C72A H72B 0.99 .
O73A H73A 0.84 .
N67B C68B 1.483(12) .
N67B H67B 0.88 .
C68B C69B 1.476(13) .
C68B H68C 0.99 .
C68B H68D 0.99 .
C69B O70B 1.457(13) .
C69B H69C 0.99 .
C69B H69D 0.99 .
O70B C71B 1.485(12) .
C71B C72B 1.440(15) .
C71B H71C 0.99 .
C71B H71D 0.99 .
C72B O73B 1.706(15) .
C72B H72C 0.99 .
C72B H72D 0.99 .
O73B H73B 0.84 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
F1 Eu1 N1 C2 132.8(2) . .
O16 Eu1 N1 C2 -172.7(3) 2 .
O16 Eu1 N1 C2 30.9(3) . .
N9 Eu1 N1 C2 93.4(3) . .
N9 Eu1 N1 C2 -111.6(3) 2 .
N1 Eu1 N1 C2 -47.2(2) 2 .
N4 Eu1 N1 C2 -104.3(3) 2 .
N4 Eu1 N1 C2 10.9(3) . .
F1 Eu1 N1 C7 11.1(4) . .
O16 Eu1 N1 C7 65.6(3) 2 .
O16 Eu1 N1 C7 -90.8(3) . .
N9 Eu1 N1 C7 -28.3(3) . .
N9 Eu1 N1 C7 126.8(3) 2 .
N1 Eu1 N1 C7 -168.9(4) 2 .
N4 Eu1 N1 C7 134.1(3) 2 .
N4 Eu1 N1 C7 -110.8(3) . .
F1 Eu1 N1 C6 -106.5(3) . 2
O16 Eu1 N1 C6 -52.0(3) 2 2
O16 Eu1 N1 C6 151.6(3) . 2
N9 Eu1 N1 C6 -145.9(3) . 2
N9 Eu1 N1 C6 9.1(4) 2 2
N1 Eu1 N1 C6 73.5(3) 2 2
N4 Eu1 N1 C6 16.4(3) 2 2
N4 Eu1 N1 C6 131.6(3) . 2
C7 N1 C2 C3 80.5(5) . .
C6 N1 C2 C3 -162.1(4) 2 .
Eu1 N1 C2 C3 -39.3(5) . .
N1 C2 C3 N4 57.9(5) . .
C2 C3 N4 C14 -164.3(4) . .
C2 C3 N4 C5 76.2(5) . .
C2 C3 N4 Eu1 -45.0(4) . .
F1 Eu1 N4 C3 -104.1(3) . .
O16 Eu1 N4 C3 12.3(4) 2 .
O16 Eu1 N4 C3 -144.8(3) . .
N9 Eu1 N4 C3 -51.6(3) . .
N9 Eu1 N4 C3 153.9(3) 2 .
N1 Eu1 N4 C3 133.2(3) 2 .
N1 Eu1 N4 C3 17.6(3) . .
N4 Eu1 N4 C3 75.9(3) 2 .
F1 Eu1 N4 C14 16.6(4) . .
O16 Eu1 N4 C14 133.0(3) 2 .
O16 Eu1 N4 C14 -24.0(3) . .
N9 Eu1 N4 C14 69.1(3) . .
N9 Eu1 N4 C14 -85.4(3) 2 .
N1 Eu1 N4 C14 -106.1(3) 2 .
N1 Eu1 N4 C14 138.3(3) . .
N4 Eu1 N4 C14 -163.4(4) 2 .
F1 Eu1 N4 C5 135.9(2) . .
O16 Eu1 N4 C5 -107.7(3) 2 .
O16 Eu1 N4 C5 95.2(3) . .
N9 Eu1 N4 C5 -171.7(3) . .
N9 Eu1 N4 C5 33.8(3) 2 .
N1 Eu1 N4 C5 13.2(3) 2 .
N1 Eu1 N4 C5 -102.4(3) . .
N4 Eu1 N4 C5 -44.1(2) 2 .
C3 N4 C5 C6 -165.6(4) . .
C14 N4 C5 C6 74.8(5) . .
Eu1 N4 C5 C6 -43.0(4) . .
N4 C5 C6 N1 61.7(5) . 2
C2 N1 C7 C8 -76.2(5) . .
C6 N1 C7 C8 166.7(4) 2 .
Eu1 N1 C7 C8 47.0(4) . .
N1 C7 C8 N9 -43.2(6) . .
N1 C7 C8 C13 141.4(5) . .
C13 C8 N9 C10 0.0(8) . .
C7 C8 N9 C10 -175.2(4) . .
C13 C8 N9 Eu1 -170.8(4) . .
C7 C8 N9 Eu1 13.9(6) . .
F1 Eu1 N9 C10 48.6(3) . .
O16 Eu1 N9 C10 124.4(3) 2 .
O16 Eu1 N9 C10 -27.4(3) . .
N9 Eu1 N9 C10 48.6(3) 2 .
N1 Eu1 N9 C10 -84.8(4) 2 .
N1 Eu1 N9 C10 -162.2(4) . .
N4 Eu1 N9 C10 176.8(3) 2 .
N4 Eu1 N9 C10 -91.8(4) . .
F1 Eu1 N9 C8 -140.7(4) . .
O16 Eu1 N9 C8 -65.0(4) 2 .
O16 Eu1 N9 C8 143.3(4) . .
N9 Eu1 N9 C8 -140.7(4) 2 .
N1 Eu1 N9 C8 85.9(4) 2 .
N1 Eu1 N9 C8 8.5(3) . .
N4 Eu1 N9 C8 -12.6(4) 2 .
N4 Eu1 N9 C8 78.9(4) . .
C8 N9 C10 C11 0.1(7) . .
Eu1 N9 C10 C11 171.1(4) . .
N9 C10 C11 C12 -1.2(9) . .
C10 C11 C12 C13 2.1(10) . .
N9 C8 C13 C12 0.9(9) . .
C7 C8 C13 C12 175.9(6) . .
C11 C12 C13 C8 -2.0(10) . .
C3 N4 C14 C15 158.3(4) . .
C5 N4 C14 C15 -83.3(4) . .
Eu1 N4 C14 C15 36.1(5) . .
N4 C14 C15 O16 -32.1(6) . .
N4 C14 C15 N17B 164.3(6) . .
N4 C14 C15 N17A 144.4(5) . .
N17B C15 O16 Eu1 167.4(7) . .
N17A C15 O16 Eu1 -169.1(4) . .
C14 C15 O16 Eu1 7.3(6) . .
F1 Eu1 O16 C15 -138.6(4) . .
O16 Eu1 O16 C15 -138.6(4) 2 .
N9 Eu1 O16 C15 -63.8(4) . .
N9 Eu1 O16 C15 146.9(4) 2 .
N1 Eu1 O16 C15 82.2(4) 2 .
N1 Eu1 O16 C15 -10.2(4) . .
N4 Eu1 O16 C15 87.2(4) 2 .
N4 Eu1 O16 C15 10.0(4) . .
O16 C15 N17A C18A -5.3(10) . .
N17B C15 N17A C18A 110(2) . .
C14 C15 N17A C18A 178.2(6) . .
C15 N17A C18A C19A 117.9(9) . .
N17A C18A C19A O20A -66.7(10) . .
C18A C19A O20A C21A 177.3(8) . .
C19A O20A C21A C22A 164.6(10) . .
O20A C21A C22A O23A 166.9(9) . .
O16 C15 N17B C18B 20.2(14) . .
N17A C15 N17B C18B -57.7(16) . .
C14 C15 N17B C18B -178.2(8) . .
C15 N17B C18B C19B 99.5(14) . .
N17B C18B C19B O20B -69.1(16) . .
C18B C19B O20B C21B -169.4(12) . .
C19B O20B C21B C22B 163.7(13) . .
O20B C21B C22B O23B 77.0(16) . .
F1 Eu2 N51 C56 131.6(2) . 2
O66 Eu2 N51 C56 -173.9(3) . 2
O66 Eu2 N51 C56 29.8(3) 2 2
N59 Eu2 N51 C56 -113.0(3) 2 2
N59 Eu2 N51 C56 91.4(3) . 2
N51 Eu2 N51 C56 -48.4(2) 2 2
N54 Eu2 N51 C56 9.7(3) 2 2
N54 Eu2 N51 C56 -105.8(3) . 2
F1 Eu2 N51 C52 -105.8(3) . .
O66 Eu2 N51 C52 -51.3(3) . .
O66 Eu2 N51 C52 152.4(3) 2 .
N59 Eu2 N51 C52 9.7(4) 2 .
N59 Eu2 N51 C52 -146.0(3) . .
N51 Eu2 N51 C52 74.2(3) 2 .
N54 Eu2 N51 C52 132.3(3) 2 .
N54 Eu2 N51 C52 16.8(3) . .
F1 Eu2 N51 C57 10.4(4) . .
O66 Eu2 N51 C57 64.9(3) . .
O66 Eu2 N51 C57 -91.4(3) 2 .
N59 Eu2 N51 C57 125.9(3) 2 .
N59 Eu2 N51 C57 -29.8(3) . .
N51 Eu2 N51 C57 -169.6(4) 2 .
N54 Eu2 N51 C57 -111.4(3) 2 .
N54 Eu2 N51 C57 133.1(3) . .
C56 N51 C52 C53 79.4(5) 2 .
C57 N51 C52 C53 -163.0(4) . .
Eu2 N51 C52 C53 -47.0(4) . .
N51 C52 C53 N54 62.5(5) . .
C52 C53 N54 C64 76.3(5) . .
C52 C53 N54 C55 -165.6(4) . .
C52 C53 N54 Eu2 -42.7(4) . .
F1 Eu2 N54 C64 16.0(4) . .
O66 Eu2 N54 C64 -24.2(3) . .
O66 Eu2 N54 C64 132.7(3) 2 .
N59 Eu2 N54 C64 68.4(3) 2 .
N59 Eu2 N54 C64 -86.6(4) . .
N51 Eu2 N54 C64 -106.8(4) . .
N51 Eu2 N54 C64 138.0(4) 2 .
N54 Eu2 N54 C64 -164.0(4) 2 .
F1 Eu2 N54 C53 135.2(2) . .
O66 Eu2 N54 C53 95.1(3) . .
O66 Eu2 N54 C53 -108.1(3) 2 .
N59 Eu2 N54 C53 -172.4(3) 2 .
N59 Eu2 N54 C53 32.6(3) . .
N51 Eu2 N54 C53 12.5(3) . .
N51 Eu2 N54 C53 -102.7(3) 2 .
N54 Eu2 N54 C53 -44.8(2) 2 .
F1 Eu2 N54 C55 -103.5(3) . .
O66 Eu2 N54 C55 -143.7(3) . .
O66 Eu2 N54 C55 13.2(3) 2 .
N59 Eu2 N54 C55 -51.1(3) 2 .
N59 Eu2 N54 C55 153.9(3) . .
N51 Eu2 N54 C55 133.7(3) . .
N51 Eu2 N54 C55 18.6(3) 2 .
N54 Eu2 N54 C55 76.5(3) 2 .
C64 N54 C55 C56 -165.1(4) . .
C53 N54 C55 C56 76.3(4) . .
Eu2 N54 C55 C56 -45.2(4) . .
N54 C55 C56 N51 56.5(5) . 2
C56 N51 C57 C58 -76.5(5) 2 .
C52 N51 C57 C58 166.9(4) . .
Eu2 N51 C57 C58 48.0(5) . .
N51 C57 C58 N59 -41.3(7) . .
N51 C57 C58 C63 139.3(6) . .
C63 C58 N59 C60 4.5(9) . .
C57 C58 N59 C60 -174.9(5) . .
C63 C58 N59 Eu2 -170.4(5) . .
C57 C58 N59 Eu2 10.2(7) . .
F1 Eu2 N59 C58 -137.1(5) . .
O66 Eu2 N59 C58 -61.7(4) . .
O66 Eu2 N59 C58 146.8(5) 2 .
N59 Eu2 N59 C58 -137.1(5) 2 .
N51 Eu2 N59 C58 11.7(4) . .
N51 Eu2 N59 C58 89.3(5) 2 .
N54 Eu2 N59 C58 82.4(4) 2 .
N54 Eu2 N59 C58 -8.8(5) . .
F1 Eu2 N59 C60 48.2(3) . .
O66 Eu2 N59 C60 123.5(3) . .
O66 Eu2 N59 C60 -27.9(3) 2 .
N59 Eu2 N59 C60 48.2(3) 2 .
N51 Eu2 N59 C60 -163.1(4) . .
N51 Eu2 N59 C60 -85.4(4) 2 .
N54 Eu2 N59 C60 -92.3(4) 2 .
N54 Eu2 N59 C60 176.5(3) . .
C58 N59 C60 C61 -2.5(8) . .
Eu2 N59 C60 C61 172.3(4) . .
N59 C60 C61 C62 0.0(10) . .
C60 C61 C62 C63 0.6(12) . .
C61 C62 C63 C58 1.3(13) . .
N59 C58 C63 C62 -3.9(12) . .
C57 C58 C63 C62 175.4(7) . .
C53 N54 C64 C65 -84.7(5) . .
C55 N54 C64 C65 156.6(4) . .
Eu2 N54 C64 C65 34.8(5) . .
N54 C64 C65 O66 -29.6(8) . .
N54 C64 C65 N67A 160.1(6) . .
N54 C64 C65 N67B 140.9(7) . .
N67A C65 O66 Eu2 173.6(7) . .
N67B C65 O66 Eu2 -165.7(6) . .
C64 C65 O66 Eu2 5.2(8) . .
F1 Eu2 O66 C65 -137.7(5) . .
O66 Eu2 O66 C65 -137.7(5) 2 .
N59 Eu2 O66 C65 -62.4(5) 2 .
N59 Eu2 O66 C65 147.6(5) . .
N51 Eu2 O66 C65 82.9(5) . .
N51 Eu2 O66 C65 -9.2(5) 2 .
N54 Eu2 O66 C65 88.0(5) 2 .
N54 Eu2 O66 C65 11.2(4) . .
O66 C65 N67A C68A 10.0(13) . .
N67B C65 N67A C68A -52.8(17) . .
C64 C65 N67A C68A 179.4(6) . .
C65 N67A C68A C69A 103.9(9) . .
N67A C68A C69A O70A -68.8(9) . .
C68A C69A O70A C71A -179.3(7) . .
C69A O70A C71A C72A 173.2(7) . .
O70A C71A C72A O73A -62.2(10) . .
O66 C65 N67B C68B -12.0(14) . .
N67A C65 N67B C68B 116(2) . .
C64 C65 N67B C68B 177.2(9) . .
C65 N67B C68B C69B 121.0(13) . .
N67B C68B C69B O70B -65.4(15) . .
C68B C69B O70B C71B -162.3(11) . .
C69B O70B C71B C72B 109.9(15) . .
O70B C71B C72B O73B -96.4(18) . .
