#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:22:53 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179374 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/71/4327101.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4327101
loop_
_publ_author_name
'Alessandro Ceriotti'
'Matteo Daghetta'
'Simona El Afefey'
'Andrea Ienco'
'Giuliano Longoni'
'Gabriele Manca'
'Carlo Mealli'
'Stefano Zacchini'
'Salvatore Zarra'
_publ_section_title
;
 Electronic Stabilization of trigonal Bipyramidal Clusters: the Role of
 the Sn(II) Ions in [Pt5(CO)5{Cl2Sn(μ-OR)SnCl2}3]3- (R = H, Me, Et, iPr)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              12553
_journal_page_last               12561
_journal_paper_doi               10.1021/ic201519j
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'C51 H96 Cl12 N9 Na O8 Pt5 Sn6'
_chemical_formula_weight         3099.35
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.844(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   14.007(3)
_cell_length_b                   22.740(5)
_cell_length_c                   14.397(3)
_cell_measurement_reflns_used    9930
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.0805
_cell_measurement_theta_min      2.289
_cell_volume                     4583.3(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1028
_diffrn_reflns_av_sigmaI/netI    0.0764
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            42865
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.42
_exptl_absorpt_coefficient_mu    9.600
_exptl_absorpt_correction_T_max  0.4182
_exptl_absorpt_correction_T_min  0.3088
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            bright-red
_exptl_crystal_density_diffrn    2.246
_exptl_crystal_description       prism
_exptl_crystal_F_000             2868
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.11
_refine_diff_density_max         5.652
_refine_diff_density_min         -2.416
_refine_diff_density_rms         0.352
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     448
_refine_ls_number_reflns         8302
_refine_ls_number_restraints     166
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0974
_refine_ls_R_factor_gt           0.0644
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1016P)²+69.6824P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1655
_refine_ls_wR_factor_ref         0.1920
_reflns_number_gt                5941
_reflns_number_total             8302
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201519j_si_001.cif
_cod_data_source_block           p21m
_cod_original_cell_volume        4583.3(18)
_cod_database_code               4327101
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.19892(5) 0.68758(3) 0.20883(4) 0.03267(19) Uani 1 1 d .
Pt2 Pt 0.32970(7) 0.7500 0.32812(6) 0.0325(2) Uani 1 2 d S
Pt3 Pt 0.35932(7) 0.7500 0.13448(6) 0.0331(2) Uani 1 2 d S
Pt4 Pt 0.13206(7) 0.7500 0.36855(7) 0.0342(2) Uani 1 2 d S
Sn1 Sn 0.39300(9) 0.64985(5) 0.22447(8) 0.0363(3) Uani 1 1 d .
Sn2 Sn 0.23067(9) 0.65191(5) 0.39972(9) 0.0383(3) Uani 1 1 d .
Sn3 Sn 0.19130(12) 0.7500 0.04044(11) 0.0347(4) Uani 1 2 d S
Sn4 Sn 0.02556(12) 0.7500 0.21107(12) 0.0356(4) Uani 1 2 d S
Cl1 Cl 0.3968(4) 0.56365(19) 0.1271(3) 0.0499(11) Uani 1 1 d .
Cl2 Cl 0.5616(3) 0.6398(2) 0.2722(3) 0.0481(11) Uani 1 1 d .
Cl3 Cl 0.1289(4) 0.5674(2) 0.4193(4) 0.0535(12) Uani 1 1 d .
Cl4 Cl 0.2990(4) 0.6442(2) 0.5562(3) 0.0513(11) Uani 1 1 d .
Cl5 Cl 0.1902(4) 0.8273(2) -0.0751(3) 0.0543(12) Uani 1 1 d .
Cl6 Cl -0.0958(3) 0.8262(2) 0.2122(4) 0.0509(12) Uani 1 1 d .
C1 C 0.1454(11) 0.6177(7) 0.1618(14) 0.042(4) Uani 1 1 d .
C2 C 0.4298(19) 0.7500 0.4150(19) 0.042(6) Uani 1 2 d S
C3 C 0.441(2) 0.7500 0.040(2) 0.053(7) Uani 1 2 d SU
C4 C 0.0307(17) 0.7500 0.4476(16) 0.038(6) Uani 1 2 d S
O1 O 0.1140(10) 0.5735(7) 0.1368(10) 0.062(4) Uani 1 1 d U
O2 O 0.4947(13) 0.7500 0.4679(14) 0.054(5) Uani 1 2 d S
O3 O 0.4845(18) 0.7500 -0.0288(18) 0.083(7) Uani 1 2 d SU
O4 O -0.0324(14) 0.7500 0.4973(15) 0.066(6) Uani 1 2 d S
O5 O 0.3437(8) 0.6056(5) 0.3418(8) 0.041(3) Uani 1 1 d .
H5 H 0.3691 0.5697 0.3653 0.049 Uiso 1 1 calc R
O6 O 0.0266(13) 0.7500 0.0517(13) 0.051(5) Uani 1 2 d SU
H6 H -0.0236 0.7500 0.0057 0.061 Uiso 1 2 calc SR
N1 N 0.2343(16) 0.9885(10) 0.7659(15) 0.107(3) Uani 1 1 d DU
C101 C 0.241(2) 1.0367(12) 0.8340(17) 0.109(4) Uani 1 1 d DU
H10A H 0.1795 1.0585 0.8296 0.131 Uiso 1 1 calc R
H10B H 0.2910 1.0639 0.8138 0.131 Uiso 1 1 calc R
C102 C 0.261(2) 1.0229(13) 0.9366(17) 0.112(4) Uani 1 1 d DU
H10C H 0.3276 1.0087 0.9443 0.135 Uiso 1 1 calc R
H10D H 0.2183 0.9906 0.9555 0.135 Uiso 1 1 calc R
C103 C 0.2474(19) 1.0754(13) 1.002(2) 0.114(5) Uani 1 1 d DU
H10E H 0.2722 1.1117 0.9730 0.137 Uiso 1 1 calc R
H10F H 0.2830 1.0688 1.0613 0.137 Uiso 1 1 calc R
C104 C 0.1404(19) 1.0823(16) 1.019(2) 0.122(6) Uani 1 1 d DU
H10G H 0.1306 1.1162 1.0598 0.182 Uiso 1 1 calc R
H10H H 0.1167 1.0466 1.0489 0.182 Uiso 1 1 calc R
H10I H 0.1056 1.0884 0.9598 0.182 Uiso 1 1 calc R
C105 C 0.3093(16) 0.9436(12) 0.781(2) 0.107(4) Uani 1 1 d DU
H10J H 0.3010 0.9131 0.7323 0.129 Uiso 1 1 calc R
H10K H 0.2995 0.9245 0.8416 0.129 Uiso 1 1 calc R
C106 C 0.4119(17) 0.9661(12) 0.780(2) 0.107(4) Uani 1 1 d DU
H10L H 0.4205 0.9975 0.8268 0.129 Uiso 1 1 calc R
H10M H 0.4236 0.9834 0.7180 0.129 Uiso 1 1 calc R
C107 C 0.485(2) 0.9173(13) 0.7997(19) 0.106(4) Uani 1 1 d DU
H10N H 0.4670 0.8833 0.7600 0.127 Uiso 1 1 calc R
H10O H 0.5477 0.9316 0.7781 0.127 Uiso 1 1 calc R
C108 C 0.502(2) 0.8940(15) 0.8983(18) 0.111(6) Uani 1 1 d DU
H10P H 0.5505 0.8629 0.8981 0.167 Uiso 1 1 calc R
H10Q H 0.4423 0.8781 0.9212 0.167 Uiso 1 1 calc R
H10R H 0.5244 0.9261 0.9389 0.167 Uiso 1 1 calc R
C109 C 0.246(2) 1.0116(15) 0.6709(17) 0.111(4) Uani 1 1 d DU
H10S H 0.2615 0.9780 0.6304 0.133 Uiso 1 1 calc R
H10T H 0.3016 1.0382 0.6725 0.133 Uiso 1 1 calc R
C110 C 0.162(2) 1.0446(14) 0.624(2) 0.112(4) Uani 1 1 d DU
H11A H 0.1326 1.0713 0.6690 0.135 Uiso 1 1 calc R
H11B H 0.1132 1.0165 0.6007 0.135 Uiso 1 1 calc R
C111 C 0.201(2) 1.0800(14) 0.543(2) 0.112(5) Uani 1 1 d DU
H11C H 0.2491 1.1095 0.5650 0.135 Uiso 1 1 calc R
H11D H 0.2307 1.0541 0.4966 0.135 Uiso 1 1 calc R
C112 C 0.111(2) 1.1093(15) 0.504(2) 0.117(6) Uani 1 1 d DU
H11E H 0.1269 1.1347 0.4515 0.175 Uiso 1 1 calc R
H11F H 0.0821 1.1330 0.5523 0.175 Uiso 1 1 calc R
H11G H 0.0655 1.0790 0.4824 0.175 Uiso 1 1 calc R
C113 C 0.1409(19) 0.9592(13) 0.775(2) 0.110(4) Uani 1 1 d DU
H11H H 0.0908 0.9886 0.7594 0.132 Uiso 1 1 calc R
H11I H 0.1345 0.9491 0.8415 0.132 Uiso 1 1 calc R
C114 C 0.1178(19) 0.9040(13) 0.719(2) 0.114(4) Uani 1 1 d DU
H11J H 0.1579 0.8708 0.7415 0.137 Uiso 1 1 calc R
H11K H 0.1308 0.9107 0.6524 0.137 Uiso 1 1 calc R
C115 C 0.012(2) 0.8898(13) 0.730(3) 0.119(5) Uani 1 1 d DU
H11L H -0.0282 0.9150 0.6891 0.143 Uiso 1 1 calc R
H11M H -0.0058 0.8958 0.7952 0.143 Uiso 1 1 calc R
C116 C 0.002(3) 0.8251(13) 0.703(3) 0.133(7) Uani 1 1 d DU
H11N H -0.0647 0.8128 0.7101 0.199 Uiso 1 1 calc R
H11O H 0.0440 0.8010 0.7423 0.199 Uiso 1 1 calc R
H11P H 0.0186 0.8202 0.6375 0.199 Uiso 1 1 calc R
Na1 Na 0.6913(8) 0.7500 0.7296(8) 0.052(3) Uani 1 2 d S
N2 N 0.7259(14) 0.8548(7) 0.7299(13) 0.064(5) Uani 1 1 d .
C201 C 0.7468(15) 0.9022(8) 0.7365(14) 0.053(4) Uani 1 1 d U
C202 C 0.7743(15) 0.9647(8) 0.7454(14) 0.054(4) Uani 1 1 d U
H20A H 0.7248 0.9861 0.7780 0.081 Uiso 1 1 calc R
H20B H 0.7813 0.9816 0.6834 0.081 Uiso 1 1 calc R
H20C H 0.8352 0.9677 0.7806 0.081 Uiso 1 1 calc R
N3 N 0.711(2) 0.7500 0.906(2) 0.067(7) Uani 1 2 d S
C301 C 0.706(3) 0.7500 0.981(3) 0.098(10) Uani 1 2 d SU
C302 C 0.698(3) 0.7500 1.084(3) 0.100(10) Uani 1 2 d SU
H30A H 0.6548 0.7187 1.1021 0.150 Uiso 0.50 1 calc PR
H30B H 0.6738 0.7881 1.1040 0.150 Uiso 0.50 1 calc PR
H30C H 0.7617 0.7432 1.1129 0.150 Uiso 0.50 1 calc PR
N4 N 0.516(2) 0.7500 0.7212(18) 0.066(7) Uani 1 2 d S
C401 C 0.436(2) 0.7500 0.731(2) 0.052(6) Uani 1 2 d SU
C402 C 0.341(2) 0.7500 0.750(2) 0.057(6) Uani 1 2 d SU
H40A H 0.3311 0.7273 0.8066 0.086 Uiso 0.50 1 calc PR
H40B H 0.3043 0.7322 0.6980 0.086 Uiso 0.50 1 calc PR
H40C H 0.3193 0.7905 0.7589 0.086 Uiso 0.50 1 calc PR
N5 N 0.7238(18) 0.7500 0.5649(19) 0.061(7) Uani 1 2 d S
C501 C 0.730(2) 0.7500 0.488(2) 0.066(7) Uani 1 2 d SU
C502 C 0.734(2) 0.7500 0.378(2) 0.067(7) Uani 1 2 d SU
H50A H 0.7152 0.7113 0.3542 0.101 Uiso 0.50 1 calc PR
H50B H 0.7999 0.7585 0.3601 0.101 Uiso 0.50 1 calc PR
H50C H 0.6911 0.7801 0.3525 0.101 Uiso 0.50 1 calc PR
N6 N 0.4084(15) 0.4940(7) 0.4093(14) 0.070(5) Uani 1 1 d .
C601 C 0.4256(15) 0.4488(8) 0.4321(15) 0.052(4) Uani 1 1 d U
C602 C 0.4499(14) 0.3871(8) 0.4645(14) 0.051(4) Uani 1 1 d U
H60A H 0.5122 0.3758 0.4411 0.076 Uiso 1 1 calc R
H60B H 0.4009 0.3598 0.4407 0.076 Uiso 1 1 calc R
H60C H 0.4523 0.3860 0.5325 0.076 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 Sn3 96.5(6) . .
C1 Pt1 Sn4 95.5(5) . .
Sn3 Pt1 Sn4 75.29(5) . .
C1 Pt1 Pt1 148.0(5) . 4_575
Sn3 Pt1 Pt1 59.64(2) . 4_575
Sn4 Pt1 Pt1 59.71(2) . 4_575
C1 Pt1 Pt2 151.9(5) . .
Sn3 Pt1 Pt2 105.93(4) . .
Sn4 Pt1 Pt2 106.27(4) . .
Pt1 Pt1 Pt2 60.119(17) 4_575 .
C1 Pt1 Sn1 98.2(5) . .
Sn3 Pt1 Sn1 103.29(5) . .
Sn4 Pt1 Sn1 166.27(4) . .
Pt1 Pt1 Sn1 107.51(3) 4_575 .
Pt2 Pt1 Sn1 60.64(3) . .
C1 Pt1 Pt4 124.7(6) . .
Sn3 Pt1 Pt4 115.80(3) . .
Sn4 Pt1 Pt4 55.95(4) . .
Pt1 Pt1 Pt4 60.519(17) 4_575 .
Pt2 Pt1 Pt4 59.55(3) . .
Sn1 Pt1 Pt4 114.72(4) . .
C1 Pt1 Sn2 98.8(6) . .
Sn3 Pt1 Sn2 164.68(4) . .
Sn4 Pt1 Sn2 103.74(5) . .
Pt1 Pt1 Sn2 106.32(3) 4_575 .
Pt2 Pt1 Sn2 59.31(3) . .
Sn1 Pt1 Sn2 73.92(4) . .
Pt4 Pt1 Sn2 54.77(3) . .
C1 Pt1 Pt3 126.1(6) . .
Sn3 Pt1 Pt3 56.00(4) . .
Sn4 Pt1 Pt3 115.96(3) . .
Pt1 Pt1 Pt3 60.605(17) 4_575 .
Pt2 Pt1 Pt3 59.10(3) . .
Sn1 Pt1 Pt3 55.05(3) . .
Pt4 Pt1 Pt3 109.25(3) . .
Sn2 Pt1 Pt3 113.12(4) . .
C2 Pt2 Pt3 122.3(8) . .
C2 Pt2 Sn2 97.1(5) . 4_575
Pt3 Pt2 Sn2 116.51(3) . 4_575
C2 Pt2 Sn2 97.1(5) . .
Pt3 Pt2 Sn2 116.51(3) . .
Sn2 Pt2 Sn2 103.62(6) 4_575 .
C2 Pt2 Pt4 125.7(8) . .
Pt3 Pt2 Pt4 112.06(4) . .
Sn2 Pt2 Pt4 55.66(3) 4_575 .
Sn2 Pt2 Pt4 55.66(3) . .
C2 Pt2 Pt1 150.09(4) . .
Pt3 Pt2 Pt1 61.20(3) . .
Sn2 Pt2 Pt1 107.35(4) 4_575 .
Sn2 Pt2 Pt1 61.00(3) . .
Pt4 Pt2 Pt1 60.84(3) . .
C2 Pt2 Pt1 150.09(4) . 4_575
Pt3 Pt2 Pt1 61.20(3) . 4_575
Sn2 Pt2 Pt1 61.00(3) 4_575 4_575
Sn2 Pt2 Pt1 107.35(4) . 4_575
Pt4 Pt2 Pt1 60.84(3) . 4_575
Pt1 Pt2 Pt1 59.76(3) . 4_575
C2 Pt2 Sn1 96.4(5) . 4_575
Pt3 Pt2 Sn1 55.41(3) . 4_575
Sn2 Pt2 Sn1 74.26(4) 4_575 4_575
Sn2 Pt2 Sn1 166.54(5) . 4_575
Pt4 Pt2 Sn1 115.07(3) . 4_575
Pt1 Pt2 Sn1 106.53(4) . 4_575
Pt1 Pt2 Sn1 59.74(3) 4_575 4_575
C2 Pt2 Sn1 96.4(5) . .
Pt3 Pt2 Sn1 55.41(3) . .
Sn2 Pt2 Sn1 166.54(5) 4_575 .
Sn2 Pt2 Sn1 74.26(4) . .
Pt4 Pt2 Sn1 115.07(3) . .
Pt1 Pt2 Sn1 59.74(3) . .
Pt1 Pt2 Sn1 106.53(4) 4_575 .
Sn1 Pt2 Sn1 104.60(6) 4_575 .
C3 Pt3 Sn1 105.1(4) . 4_575
C3 Pt3 Sn1 105.1(4) . .
Sn1 Pt3 Sn1 118.15(6) 4_575 .
C3 Pt3 Sn3 100.9(9) . .
Sn1 Pt3 Sn3 112.72(4) 4_575 .
Sn1 Pt3 Sn3 112.72(4) . .
C3 Pt3 Pt2 149.0(9) . .
Sn1 Pt3 Pt2 63.19(3) 4_575 .
Sn1 Pt3 Pt2 63.19(3) . .
Sn3 Pt3 Pt2 110.10(5) . .
C3 Pt3 Pt1 143.0(5) . 4_575
Sn1 Pt3 Pt1 61.72(3) 4_575 4_575
Sn1 Pt3 Pt1 111.62(4) . 4_575
Sn3 Pt3 Pt1 60.42(4) . 4_575
Pt2 Pt3 Pt1 59.69(3) . 4_575
C3 Pt3 Pt1 143.0(5) . .
Sn1 Pt3 Pt1 111.62(4) 4_575 .
Sn1 Pt3 Pt1 61.72(3) . .
Sn3 Pt3 Pt1 60.42(4) . .
Pt2 Pt3 Pt1 59.69(3) . .
Pt1 Pt3 Pt1 58.79(3) 4_575 .
C4 Pt4 Sn2 107.6(4) . 4_575
C4 Pt4 Sn2 107.6(4) . .
Sn2 Pt4 Sn2 114.37(7) 4_575 .
C4 Pt4 Sn4 96.0(7) . .
Sn2 Pt4 Sn4 114.61(4) 4_575 .
Sn2 Pt4 Sn4 114.61(4) . .
C4 Pt4 Pt2 153.8(7) . .
Sn2 Pt4 Pt2 62.00(3) 4_575 .
Sn2 Pt4 Pt2 62.00(3) . .
Sn4 Pt4 Pt2 110.26(5) . .
C4 Pt4 Pt1 140.1(5) . 4_575
Sn2 Pt4 Pt1 62.65(3) 4_575 4_575
Sn2 Pt4 Pt1 111.58(4) . 4_575
Sn4 Pt4 Pt1 60.69(4) . 4_575
Pt2 Pt4 Pt1 59.61(3) . 4_575
C4 Pt4 Pt1 140.1(5) . .
Sn2 Pt4 Pt1 111.58(4) 4_575 .
Sn2 Pt4 Pt1 62.65(3) . .
Sn4 Pt4 Pt1 60.69(4) . .
Pt2 Pt4 Pt1 59.61(3) . .
Pt1 Pt4 Pt1 58.96(3) 4_575 .
O5 Sn1 Cl1 95.3(3) . .
O5 Sn1 Cl2 93.9(3) . .
Cl1 Sn1 Cl2 92.77(17) . .
O5 Sn1 Pt3 138.1(3) . .
Cl1 Sn1 Pt3 114.87(12) . .
Cl2 Sn1 Pt3 111.82(12) . .
O5 Sn1 Pt1 82.5(3) . .
Cl1 Sn1 Pt1 103.74(13) . .
Cl2 Sn1 Pt1 163.35(13) . .
Pt3 Sn1 Pt1 63.23(3) . .
O5 Sn1 Pt2 81.2(3) . .
Cl1 Sn1 Pt2 163.23(14) . .
Cl2 Sn1 Pt2 103.80(12) . .
Pt3 Sn1 Pt2 61.40(4) . .
Pt1 Sn1 Pt2 59.62(3) . .
O5 Sn2 Cl3 95.9(3) . .
O5 Sn2 Cl4 93.0(4) . .
Cl3 Sn2 Cl4 92.90(18) . .
O5 Sn2 Pt4 138.6(3) . .
Cl3 Sn2 Pt4 112.50(13) . .
Cl4 Sn2 Pt4 113.93(13) . .
O5 Sn2 Pt2 82.3(3) . .
Cl3 Sn2 Pt2 164.83(14) . .
Cl4 Sn2 Pt2 102.23(13) . .
Pt4 Sn2 Pt2 62.34(4) . .
O5 Sn2 Pt1 81.8(3) . .
Cl3 Sn2 Pt1 105.14(14) . .
Cl4 Sn2 Pt1 161.62(13) . .
Pt4 Sn2 Pt1 62.57(3) . .
Pt2 Sn2 Pt1 59.69(3) . .
O6 Sn3 Cl5 93.7(3) . .
O6 Sn3 Cl5 93.7(3) . 4_575
Cl5 Sn3 Cl5 93.2(3) . 4_575
O6 Sn3 Pt3 145.6(5) . .
Cl5 Sn3 Pt3 109.49(14) . .
Cl5 Sn3 Pt3 109.49(14) 4_575 .
O6 Sn3 Pt1 87.1(4) . 4_575
Cl5 Sn3 Pt1 103.04(12) . 4_575
Cl5 Sn3 Pt1 163.70(13) 4_575 4_575
Pt3 Sn3 Pt1 63.58(4) . 4_575
O6 Sn3 Pt1 87.1(4) . .
Cl5 Sn3 Pt1 163.70(13) . .
Cl5 Sn3 Pt1 103.04(12) 4_575 .
Pt3 Sn3 Pt1 63.58(4) . .
Pt1 Sn3 Pt1 60.72(4) 4_575 .
O6 Sn4 Cl6 91.9(4) . .
O6 Sn4 Cl6 91.9(4) . 4_575
Cl6 Sn4 Cl6 91.0(2) . 4_575
O6 Sn4 Pt4 145.7(5) . .
Cl6 Sn4 Pt4 111.48(13) . .
Cl6 Sn4 Pt4 111.48(13) 4_575 .
O6 Sn4 Pt1 87.4(4) . 4_575
Cl6 Sn4 Pt1 104.19(12) . 4_575
Cl6 Sn4 Pt1 164.77(13) 4_575 4_575
Pt4 Sn4 Pt1 63.35(4) . 4_575
O6 Sn4 Pt1 87.4(4) . .
Cl6 Sn4 Pt1 164.77(13) . .
Cl6 Sn4 Pt1 104.19(12) 4_575 .
Pt4 Sn4 Pt1 63.35(4) . .
Pt1 Sn4 Pt1 60.59(4) 4_575 .
O1 C1 Pt1 176.7(18) . .
O2 C2 Pt2 178(2) . .
O3 C3 Pt3 172(3) . .
O4 C4 Pt4 180(2) . .
Sn2 O5 Sn1 110.6(5) . .
Sn2 O5 H5 124.7 . .
Sn1 O5 H5 124.7 . .
Sn4 O6 Sn3 96.2(7) . .
Sn4 O6 H6 131.9 . .
Sn3 O6 H6 131.9 . .
C101 N1 C105 113(2) . .
C101 N1 C113 108(2) . .
C105 N1 C113 108(2) . .
C101 N1 C109 110(2) . .
C105 N1 C109 107(2) . .
C113 N1 C109 111(2) . .
N1 C101 C102 120(2) . .
N1 C101 H10A 107.4 . .
C102 C101 H10A 107.4 . .
N1 C101 H10B 107.4 . .
C102 C101 H10B 107.4 . .
H10A C101 H10B 106.9 . .
C101 C102 C103 114(2) . .
C101 C102 H10C 108.7 . .
C103 C102 H10C 108.7 . .
C101 C102 H10D 108.7 . .
C103 C102 H10D 108.7 . .
H10C C102 H10D 107.6 . .
C102 C103 C104 109(2) . .
C102 C103 H10E 110.0 . .
C104 C103 H10E 110.0 . .
C102 C103 H10F 110.0 . .
C104 C103 H10F 110.0 . .
H10E C103 H10F 108.3 . .
C103 C104 H10G 109.5 . .
C103 C104 H10H 109.5 . .
H10G C104 H10H 109.5 . .
C103 C104 H10I 109.5 . .
H10G C104 H10I 109.5 . .
H10H C104 H10I 109.5 . .
N1 C105 C106 116(2) . .
N1 C105 H10J 108.4 . .
C106 C105 H10J 108.4 . .
N1 C105 H10K 108.4 . .
C106 C105 H10K 108.4 . .
H10J C105 H10K 107.4 . .
C105 C106 C107 112(2) . .
C105 C106 H10L 109.1 . .
C107 C106 H10L 109.1 . .
C105 C106 H10M 109.1 . .
C107 C106 H10M 109.1 . .
H10L C106 H10M 107.8 . .
C108 C107 C106 121(3) . .
C108 C107 H10N 107.2 . .
C106 C107 H10N 107.2 . .
C108 C107 H10O 107.2 . .
C106 C107 H10O 107.2 . .
H10N C107 H10O 106.8 . .
C107 C108 H10P 109.5 . .
C107 C108 H10Q 109.5 . .
H10P C108 H10Q 109.5 . .
C107 C108 H10R 109.5 . .
H10P C108 H10R 109.5 . .
H10Q C108 H10R 109.5 . .
N1 C109 C110 119(2) . .
N1 C109 H10S 107.6 . .
C110 C109 H10S 107.6 . .
N1 C109 H10T 107.6 . .
C110 C109 H10T 107.6 . .
H10S C109 H10T 107.1 . .
C109 C110 C111 108(2) . .
C109 C110 H11A 110.1 . .
C111 C110 H11A 110.1 . .
C109 C110 H11B 110.1 . .
C111 C110 H11B 110.1 . .
H11A C110 H11B 108.4 . .
C112 C111 C110 101(2) . .
C112 C111 H11C 111.5 . .
C110 C111 H11C 111.5 . .
C112 C111 H11D 111.5 . .
C110 C111 H11D 111.5 . .
H11C C111 H11D 109.3 . .
C111 C112 H11E 109.5 . .
C111 C112 H11F 109.5 . .
H11E C112 H11F 109.5 . .
C111 C112 H11G 109.5 . .
H11E C112 H11G 109.5 . .
H11F C112 H11G 109.5 . .
N1 C113 C114 120(2) . .
N1 C113 H11H 107.4 . .
C114 C113 H11H 107.4 . .
N1 C113 H11I 107.4 . .
C114 C113 H11I 107.4 . .
H11H C113 H11I 106.9 . .
C113 C114 C115 108(2) . .
C113 C114 H11J 110.1 . .
C115 C114 H11J 110.1 . .
C113 C114 H11K 110.1 . .
C115 C114 H11K 110.1 . .
H11J C114 H11K 108.4 . .
C114 C115 C116 105(2) . .
C114 C115 H11L 110.7 . .
C116 C115 H11L 110.7 . .
C114 C115 H11M 110.7 . .
C116 C115 H11M 110.7 . .
H11L C115 H11M 108.8 . .
C115 C116 H11N 109.5 . .
C115 C116 H11O 109.5 . .
H11N C116 H11O 109.5 . .
C115 C116 H11P 109.5 . .
H11N C116 H11P 109.5 . .
H11O C116 H11P 109.5 . .
N5 Na1 N2 87.6(6) . .
N5 Na1 N2 87.6(6) . 4_575
N2 Na1 N2 157.0(11) . 4_575
N5 Na1 N4 99.8(10) . .
N2 Na1 N4 101.5(5) . .
N2 Na1 N4 101.5(5) 4_575 .
N5 Na1 N3 162.9(10) . .
N2 Na1 N3 89.0(6) . .
N2 Na1 N3 89.0(6) 4_575 .
N4 Na1 N3 97.3(10) . .
C201 N2 Na1 174.1(19) . .
N2 C201 C202 180(3) . .
C201 C202 H20A 109.5 . .
C201 C202 H20B 109.5 . .
H20A C202 H20B 109.5 . .
C201 C202 H20C 109.5 . .
H20A C202 H20C 109.5 . .
H20B C202 H20C 109.5 . .
C301 N3 Na1 170(4) . .
N3 C301 C302 180(5) . .
C301 C302 H30A 109.5 . .
C301 C302 H30B 109.5 . .
H30A C302 H30B 109.5 . .
C301 C302 H30C 109.5 . .
H30A C302 H30C 109.5 . .
H30B C302 H30C 109.5 . .
C401 N4 Na1 170(3) . .
N4 C401 C402 175(3) . .
C401 C402 H40A 109.5 . .
C401 C402 H40B 109.5 . .
H40A C402 H40B 109.5 . .
C401 C402 H40C 109.5 . .
H40A C402 H40C 109.5 . .
H40B C402 H40C 109.5 . .
C501 N5 Na1 174(3) . .
N5 C501 C502 178(3) . .
C501 C502 H50A 109.5 . .
C501 C502 H50B 109.5 . .
H50A C502 H50B 109.5 . .
C501 C502 H50C 109.5 . .
H50A C502 H50C 109.5 . .
H50B C502 H50C 109.5 . .
N6 C601 C602 179(3) . .
C601 C602 H60A 109.5 . .
C601 C602 H60B 109.5 . .
H60A C602 H60B 109.5 . .
C601 C602 H60C 109.5 . .
H60A C602 H60C 109.5 . .
H60B C602 H60C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 1.874(16) .
Pt1 Sn3 2.8084(16) .
Pt1 Sn4 2.8138(16) .
Pt1 Pt1 2.8387(14) 4_575
Pt1 Pt2 2.8490(11) .
Pt1 Sn1 2.8525(15) .
Pt1 Pt4 2.8840(11) .
Pt1 Sn2 2.8861(15) .
Pt1 Pt3 2.8918(11) .
Pt2 C2 1.85(3) .
Pt2 Pt3 2.8317(15) .
Pt2 Sn2 2.8379(13) 4_575
Pt2 Sn2 2.8379(13) .
Pt2 Pt4 2.8470(14) .
Pt2 Pt1 2.8490(11) 4_575
Pt2 Sn1 2.8784(13) 4_575
Pt2 Sn1 2.8784(13) .
Pt3 C3 1.81(3) .
Pt3 Sn1 2.6549(13) 4_575
Pt3 Sn1 2.6549(13) .
Pt3 Sn3 2.6770(19) .
Pt3 Pt1 2.8918(11) 4_575
Pt4 C4 1.85(2) .
Pt4 Sn2 2.6541(13) 4_575
Pt4 Sn2 2.6541(13) .
Pt4 Sn4 2.6736(19) .
Pt4 Pt1 2.8840(11) 4_575
Sn1 O5 2.102(12) .
Sn1 Cl1 2.411(4) .
Sn1 Cl2 2.449(5) .
Sn2 O5 2.096(11) .
Sn2 Cl3 2.416(5) .
Sn2 Cl4 2.426(5) .
Sn3 O6 2.317(18) .
Sn3 Cl5 2.419(5) .
Sn3 Cl5 2.419(5) 4_575
Sn3 Pt1 2.8084(16) 4_575
Sn4 O6 2.296(19) .
Sn4 Cl6 2.428(5) .
Sn4 Cl6 2.428(5) 4_575
Sn4 Pt1 2.8138(16) 4_575
C1 O1 1.15(2) .
C2 O2 1.17(3) .
C3 O3 1.18(3) .
C4 O4 1.15(3) .
O5 H5 0.9500 .
O6 H6 0.9500 .
N1 C101 1.472(10) .
N1 C105 1.475(10) .
N1 C113 1.477(10) .
N1 C109 1.479(10) .
C101 C102 1.528(10) .
C101 H10A 0.9900 .
C101 H10B 0.9900 .
C102 C103 1.534(10) .
C102 H10C 0.9900 .
C102 H10D 0.9900 .
C103 C104 1.536(10) .
C103 H10E 0.9900 .
C103 H10F 0.9900 .
C104 H10G 0.9800 .
C104 H10H 0.9800 .
C104 H10I 0.9800 .
C105 C106 1.527(10) .
C105 H10J 0.9900 .
C105 H10K 0.9900 .
C106 C107 1.535(10) .
C106 H10L 0.9900 .
C106 H10M 0.9900 .
C107 C108 1.525(10) .
C107 H10N 0.9900 .
C107 H10O 0.9900 .
C108 H10P 0.9800 .
C108 H10Q 0.9800 .
C108 H10R 0.9800 .
C109 C110 1.528(10) .
C109 H10S 0.9900 .
C109 H10T 0.9900 .
C110 C111 1.532(10) .
C110 H11A 0.9900 .
C110 H11B 0.9900 .
C111 C112 1.525(10) .
C111 H11C 0.9900 .
C111 H11D 0.9900 .
C112 H11E 0.9800 .
C112 H11F 0.9800 .
C112 H11G 0.9800 .
C113 C114 1.524(10) .
C113 H11H 0.9900 .
C113 H11I 0.9900 .
C114 C115 1.525(10) .
C114 H11J 0.9900 .
C114 H11K 0.9900 .
C115 C116 1.529(10) .
C115 H11L 0.9900 .
C115 H11M 0.9900 .
C116 H11N 0.9800 .
C116 H11O 0.9800 .
C116 H11P 0.9800 .
Na1 N5 2.43(3) .
Na1 N2 2.432(17) .
Na1 N2 2.432(17) 4_575
Na1 N4 2.46(3) .
Na1 N3 2.54(3) .
N2 C201 1.12(2) .
C201 C202 1.48(2) .
C202 H20A 0.9800 .
C202 H20B 0.9800 .
C202 H20C 0.9800 .
N3 C301 1.09(5) .
C301 C302 1.49(6) .
C302 H30A 0.9800 .
C302 H30B 0.9800 .
C302 H30C 0.9800 .
N4 C401 1.14(4) .
C401 C402 1.37(4) .
C402 H40A 0.9800 .
C402 H40B 0.9800 .
C402 H40C 0.9800 .
N5 C501 1.11(4) .
C501 C502 1.58(5) .
C502 H50A 0.9800 .
C502 H50B 0.9800 .
C502 H50C 0.9800 .
N6 C601 1.10(2) .
C601 C602 1.51(2) .
C602 H60A 0.9800 .
C602 H60B 0.9800 .
C602 H60C 0.9800 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O5 H5 N6 0.95 1.91 2.86(2) 174.4
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Pt1 Pt2 C2 4(2) . .
Sn3 Pt1 Pt2 C2 -137.4(15) . .
Sn4 Pt1 Pt2 C2 143.6(15) . .
Pt1 Pt1 Pt2 C2 -177.0(15) 4_575 .
Sn1 Pt1 Pt2 C2 -40.9(15) . .
Pt4 Pt1 Pt2 C2 111.7(15) . .
Sn2 Pt1 Pt2 C2 47.1(15) . .
Pt3 Pt1 Pt2 C2 -105.5(15) . .
C1 Pt1 Pt2 Pt3 109.7(12) . .
Sn3 Pt1 Pt2 Pt3 -31.95(4) . .
Sn4 Pt1 Pt2 Pt3 -110.90(4) . .
Pt1 Pt1 Pt2 Pt3 -71.59(2) 4_575 .
Sn1 Pt1 Pt2 Pt3 64.57(3) . .
Pt4 Pt1 Pt2 Pt3 -142.89(3) . .
Sn2 Pt1 Pt2 Pt3 152.53(4) . .
C1 Pt1 Pt2 Sn2 -139.1(12) . 4_575
Sn3 Pt1 Pt2 Sn2 79.26(5) . 4_575
Sn4 Pt1 Pt2 Sn2 0.32(5) . 4_575
Pt1 Pt1 Pt2 Sn2 39.63(3) 4_575 4_575
Sn1 Pt1 Pt2 Sn2 175.79(5) . 4_575
Pt4 Pt1 Pt2 Sn2 -31.67(3) . 4_575
Sn2 Pt1 Pt2 Sn2 -96.25(6) . 4_575
Pt3 Pt1 Pt2 Sn2 111.22(4) . 4_575
C1 Pt1 Pt2 Sn2 -42.9(12) . .
Sn3 Pt1 Pt2 Sn2 175.52(5) . .
Sn4 Pt1 Pt2 Sn2 96.57(5) . .
Pt1 Pt1 Pt2 Sn2 135.88(3) 4_575 .
Sn1 Pt1 Pt2 Sn2 -87.96(4) . .
Pt4 Pt1 Pt2 Sn2 64.58(3) . .
Pt3 Pt1 Pt2 Sn2 -152.53(4) . .
C1 Pt1 Pt2 Pt4 -107.5(12) . .
Sn3 Pt1 Pt2 Pt4 110.93(4) . .
Sn4 Pt1 Pt2 Pt4 31.99(4) . .
Pt1 Pt1 Pt2 Pt4 71.30(2) 4_575 .
Sn1 Pt1 Pt2 Pt4 -152.54(4) . .
Sn2 Pt1 Pt2 Pt4 -64.58(3) . .
Pt3 Pt1 Pt2 Pt4 142.89(2) . .
C1 Pt1 Pt2 Pt1 -178.8(12) . 4_575
Sn3 Pt1 Pt2 Pt1 39.63(4) . 4_575
Sn4 Pt1 Pt2 Pt1 -39.31(4) . 4_575
Sn1 Pt1 Pt2 Pt1 136.16(3) . 4_575
Pt4 Pt1 Pt2 Pt1 -71.30(2) . 4_575
Sn2 Pt1 Pt2 Pt1 -135.88(3) . 4_575
Pt3 Pt1 Pt2 Pt1 71.59(2) . 4_575
C1 Pt1 Pt2 Sn1 142.6(12) . 4_575
Sn3 Pt1 Pt2 Sn1 1.02(5) . 4_575
Sn4 Pt1 Pt2 Sn1 -77.92(5) . 4_575
Pt1 Pt1 Pt2 Sn1 -38.61(3) 4_575 4_575
Sn1 Pt1 Pt2 Sn1 97.55(6) . 4_575
Pt4 Pt1 Pt2 Sn1 -109.91(4) . 4_575
Sn2 Pt1 Pt2 Sn1 -174.50(5) . 4_575
Pt3 Pt1 Pt2 Sn1 32.97(3) . 4_575
C1 Pt1 Pt2 Sn1 45.1(12) . .
Sn3 Pt1 Pt2 Sn1 -96.53(5) . .
Sn4 Pt1 Pt2 Sn1 -175.47(5) . .
Pt1 Pt1 Pt2 Sn1 -136.16(3) 4_575 .
Pt4 Pt1 Pt2 Sn1 152.54(4) . .
Sn2 Pt1 Pt2 Sn1 87.96(4) . .
Pt3 Pt1 Pt2 Sn1 -64.57(3) . .
C2 Pt2 Pt3 C3 0.000(3) . .
Sn2 Pt2 Pt3 C3 118.55(4) 4_575 .
Sn2 Pt2 Pt3 C3 -118.55(4) . .
Pt4 Pt2 Pt3 C3 180.0 . .
Pt1 Pt2 Pt3 C3 -145.353(18) . .
Pt1 Pt2 Pt3 C3 145.353(19) 4_575 .
Sn1 Pt2 Pt3 C3 73.98(3) 4_575 .
Sn1 Pt2 Pt3 C3 -73.98(3) . .
C2 Pt2 Pt3 Sn1 -73.98(3) . 4_575
Sn2 Pt2 Pt3 Sn1 44.57(5) 4_575 4_575
Sn2 Pt2 Pt3 Sn1 167.46(5) . 4_575
Pt4 Pt2 Pt3 Sn1 106.02(3) . 4_575
Pt1 Pt2 Pt3 Sn1 140.67(4) . 4_575
Pt1 Pt2 Pt3 Sn1 71.37(4) 4_575 4_575
Sn1 Pt2 Pt3 Sn1 -147.96(7) . 4_575
C2 Pt2 Pt3 Sn1 73.98(3) . .
Sn2 Pt2 Pt3 Sn1 -167.46(5) 4_575 .
Sn2 Pt2 Pt3 Sn1 -44.57(5) . .
Pt4 Pt2 Pt3 Sn1 -106.02(3) . .
Pt1 Pt2 Pt3 Sn1 -71.37(4) . .
Pt1 Pt2 Pt3 Sn1 -140.67(4) 4_575 .
Sn1 Pt2 Pt3 Sn1 147.96(7) 4_575 .
C2 Pt2 Pt3 Sn3 180.000(1) . .
Sn2 Pt2 Pt3 Sn3 -61.45(4) 4_575 .
Sn2 Pt2 Pt3 Sn3 61.45(4) . .
Pt4 Pt2 Pt3 Sn3 0.000(1) . .
Pt1 Pt2 Pt3 Sn3 34.647(19) . .
Pt1 Pt2 Pt3 Sn3 -34.647(18) 4_575 .
Sn1 Pt2 Pt3 Sn3 -106.02(3) 4_575 .
Sn1 Pt2 Pt3 Sn3 106.02(3) . .
C2 Pt2 Pt3 Pt1 -145.353(18) . 4_575
Sn2 Pt2 Pt3 Pt1 -26.80(4) 4_575 4_575
Sn2 Pt2 Pt3 Pt1 96.09(5) . 4_575
Pt4 Pt2 Pt3 Pt1 34.647(19) . 4_575
Pt1 Pt2 Pt3 Pt1 69.29(4) . 4_575
Sn1 Pt2 Pt3 Pt1 -71.37(4) 4_575 4_575
Sn1 Pt2 Pt3 Pt1 140.67(4) . 4_575
C2 Pt2 Pt3 Pt1 145.353(19) . .
Sn2 Pt2 Pt3 Pt1 -96.09(5) 4_575 .
Sn2 Pt2 Pt3 Pt1 26.80(4) . .
Pt4 Pt2 Pt3 Pt1 -34.647(18) . .
Pt1 Pt2 Pt3 Pt1 -69.29(4) 4_575 .
Sn1 Pt2 Pt3 Pt1 -140.67(4) 4_575 .
Sn1 Pt2 Pt3 Pt1 71.37(4) . .
C1 Pt1 Pt3 C3 4.2(14) . .
Sn3 Pt1 Pt3 C3 -66.9(12) . .
Sn4 Pt1 Pt3 C3 -115.0(12) . .
Pt1 Pt1 Pt3 C3 -138.3(12) 4_575 .
Pt2 Pt1 Pt3 C3 150.9(12) . .
Sn1 Pt1 Pt3 C3 77.1(12) . .
Pt4 Pt1 Pt3 C3 -175.6(12) . .
Sn2 Pt1 Pt3 C3 125.4(12) . .
C1 Pt1 Pt3 Sn1 175.8(7) . 4_575
Sn3 Pt1 Pt3 Sn1 104.65(5) . 4_575
Sn4 Pt1 Pt3 Sn1 56.64(6) . 4_575
Pt1 Pt1 Pt3 Sn1 33.29(3) 4_575 4_575
Pt2 Pt1 Pt3 Sn1 -37.48(4) . 4_575
Sn1 Pt1 Pt3 Sn1 -111.29(7) . 4_575
Pt4 Pt1 Pt3 Sn1 -4.05(5) . 4_575
Sn2 Pt1 Pt3 Sn1 -63.03(5) . 4_575
C1 Pt1 Pt3 Sn1 -72.9(7) . .
Sn3 Pt1 Pt3 Sn1 -144.06(4) . .
Sn4 Pt1 Pt3 Sn1 167.93(5) . .
Pt1 Pt1 Pt3 Sn1 144.58(4) 4_575 .
Pt2 Pt1 Pt3 Sn1 73.81(4) . .
Pt4 Pt1 Pt3 Sn1 107.24(4) . .
Sn2 Pt1 Pt3 Sn1 48.26(4) . .
C1 Pt1 Pt3 Sn3 71.1(7) . .
Sn4 Pt1 Pt3 Sn3 -48.01(5) . .
Pt1 Pt1 Pt3 Sn3 -71.35(3) 4_575 .
Pt2 Pt1 Pt3 Sn3 -142.13(3) . .
Sn1 Pt1 Pt3 Sn3 144.06(4) . .
Pt4 Pt1 Pt3 Sn3 -108.70(4) . .
Sn2 Pt1 Pt3 Sn3 -167.68(4) . .
C1 Pt1 Pt3 Pt2 -146.7(7) . .
Sn3 Pt1 Pt3 Pt2 142.13(3) . .
Sn4 Pt1 Pt3 Pt2 94.12(5) . .
Pt1 Pt1 Pt3 Pt2 70.78(2) 4_575 .
Sn1 Pt1 Pt3 Pt2 -73.81(4) . .
Pt4 Pt1 Pt3 Pt2 33.43(3) . .
Sn2 Pt1 Pt3 Pt2 -25.55(3) . .
C1 Pt1 Pt3 Pt1 142.5(7) . 4_575
Sn3 Pt1 Pt3 Pt1 71.35(3) . 4_575
Sn4 Pt1 Pt3 Pt1 23.34(5) . 4_575
Pt2 Pt1 Pt3 Pt1 -70.78(2) . 4_575
Sn1 Pt1 Pt3 Pt1 -144.58(4) . 4_575
Pt4 Pt1 Pt3 Pt1 -37.34(3) . 4_575
Sn2 Pt1 Pt3 Pt1 -96.33(3) . 4_575
C2 Pt2 Pt4 C4 0.000(6) . .
Pt3 Pt2 Pt4 C4 180.000(5) . .
Sn2 Pt2 Pt4 C4 -72.15(4) 4_575 .
Sn2 Pt2 Pt4 C4 72.15(4) . .
Pt1 Pt2 Pt4 C4 145.214(19) . .
Pt1 Pt2 Pt4 C4 -145.21(2) 4_575 .
Sn1 Pt2 Pt4 C4 -119.13(4) 4_575 .
Sn1 Pt2 Pt4 C4 119.13(4) . .
C2 Pt2 Pt4 Sn2 72.15(4) . 4_575
Pt3 Pt2 Pt4 Sn2 -107.85(3) . 4_575
Sn2 Pt2 Pt4 Sn2 144.30(7) . 4_575
Pt1 Pt2 Pt4 Sn2 -142.64(4) . 4_575
Pt1 Pt2 Pt4 Sn2 -73.06(4) 4_575 4_575
Sn1 Pt2 Pt4 Sn2 -46.98(5) 4_575 4_575
Sn1 Pt2 Pt4 Sn2 -168.72(5) . 4_575
C2 Pt2 Pt4 Sn2 -72.15(3) . .
Pt3 Pt2 Pt4 Sn2 107.85(4) . .
Sn2 Pt2 Pt4 Sn2 -144.30(7) 4_575 .
Pt1 Pt2 Pt4 Sn2 73.06(4) . .
Pt1 Pt2 Pt4 Sn2 142.64(4) 4_575 .
Sn1 Pt2 Pt4 Sn2 168.72(5) 4_575 .
Sn1 Pt2 Pt4 Sn2 46.98(5) . .
C2 Pt2 Pt4 Sn4 180.0 . .
Pt3 Pt2 Pt4 Sn4 0.000(2) . .
Sn2 Pt2 Pt4 Sn4 107.85(4) 4_575 .
Sn2 Pt2 Pt4 Sn4 -107.85(3) . .
Pt1 Pt2 Pt4 Sn4 -34.785(19) . .
Pt1 Pt2 Pt4 Sn4 34.786(18) 4_575 .
Sn1 Pt2 Pt4 Sn4 60.87(4) 4_575 .
Sn1 Pt2 Pt4 Sn4 -60.87(4) . .
C2 Pt2 Pt4 Pt1 145.214(18) . 4_575
Pt3 Pt2 Pt4 Pt1 -34.785(19) . 4_575
Sn2 Pt2 Pt4 Pt1 73.06(4) 4_575 4_575
Sn2 Pt2 Pt4 Pt1 -142.64(4) . 4_575
Pt1 Pt2 Pt4 Pt1 -69.57(4) . 4_575
Sn1 Pt2 Pt4 Pt1 26.09(4) 4_575 4_575
Sn1 Pt2 Pt4 Pt1 -95.66(5) . 4_575
C2 Pt2 Pt4 Pt1 -145.215(19) . .
Pt3 Pt2 Pt4 Pt1 34.786(18) . .
Sn2 Pt2 Pt4 Pt1 142.64(4) 4_575 .
Sn2 Pt2 Pt4 Pt1 -73.06(4) . .
Pt1 Pt2 Pt4 Pt1 69.57(4) 4_575 .
Sn1 Pt2 Pt4 Pt1 95.66(5) 4_575 .
Sn1 Pt2 Pt4 Pt1 -26.09(4) . .
C1 Pt1 Pt4 C4 -10.0(11) . .
Sn3 Pt1 Pt4 C4 109.2(9) . .
Sn4 Pt1 Pt4 C4 61.0(9) . .
Pt1 Pt1 Pt4 C4 132.5(9) 4_575 .
Pt2 Pt1 Pt4 C4 -156.9(9) . .
Sn1 Pt1 Pt4 C4 -130.6(9) . .
Sn2 Pt1 Pt4 C4 -84.9(9) . .
Pt3 Pt1 Pt4 C4 169.9(9) . .
C1 Pt1 Pt4 Sn2 -177.9(7) . 4_575
Sn3 Pt1 Pt4 Sn2 -58.79(6) . 4_575
Sn4 Pt1 Pt4 Sn2 -106.95(5) . 4_575
Pt1 Pt1 Pt4 Sn2 -35.46(3) 4_575 4_575
Pt2 Pt1 Pt4 Sn2 35.19(4) . 4_575
Sn1 Pt1 Pt4 Sn2 61.45(5) . 4_575
Sn2 Pt1 Pt4 Sn2 107.15(7) . 4_575
Pt3 Pt1 Pt4 Sn2 1.93(5) . 4_575
C1 Pt1 Pt4 Sn2 74.9(7) . .
Sn3 Pt1 Pt4 Sn2 -165.95(5) . .
Sn4 Pt1 Pt4 Sn2 145.89(4) . .
Pt1 Pt1 Pt4 Sn2 -142.61(4) 4_575 .
Pt2 Pt1 Pt4 Sn2 -71.97(4) . .
Sn1 Pt1 Pt4 Sn2 -45.71(4) . .
Pt3 Pt1 Pt4 Sn2 -105.23(4) . .
C1 Pt1 Pt4 Sn4 -71.0(7) . .
Sn3 Pt1 Pt4 Sn4 48.16(5) . .
Pt1 Pt1 Pt4 Sn4 71.50(3) 4_575 .
Pt2 Pt1 Pt4 Sn4 142.14(3) . .
Sn1 Pt1 Pt4 Sn4 168.40(4) . .
Sn2 Pt1 Pt4 Sn4 -145.89(4) . .
Pt3 Pt1 Pt4 Sn4 108.88(4) . .
C1 Pt1 Pt4 Pt2 146.9(7) . .
Sn3 Pt1 Pt4 Pt2 -93.98(5) . .
Sn4 Pt1 Pt4 Pt2 -142.14(3) . .
Pt1 Pt1 Pt4 Pt2 -70.64(2) 4_575 .
Sn1 Pt1 Pt4 Pt2 26.26(3) . .
Sn2 Pt1 Pt4 Pt2 71.97(4) . .
Pt3 Pt1 Pt4 Pt2 -33.26(3) . .
C1 Pt1 Pt4 Pt1 -142.5(7) . 4_575
Sn3 Pt1 Pt4 Pt1 -23.34(5) . 4_575
Sn4 Pt1 Pt4 Pt1 -71.50(3) . 4_575
Pt2 Pt1 Pt4 Pt1 70.64(2) . 4_575
Sn1 Pt1 Pt4 Pt1 96.90(3) . 4_575
Sn2 Pt1 Pt4 Pt1 142.61(4) . 4_575
Pt3 Pt1 Pt4 Pt1 37.38(3) . 4_575
C3 Pt3 Sn1 O5 178.8(10) . .
Sn1 Pt3 Sn1 O5 62.1(5) 4_575 .
Sn3 Pt3 Sn1 O5 -72.3(5) . .
Pt2 Pt3 Sn1 O5 29.6(5) . .
Pt1 Pt3 Sn1 O5 -6.4(5) 4_575 .
Pt1 Pt3 Sn1 O5 -38.7(5) . .
C3 Pt3 Sn1 Cl1 -49.1(9) . .
Sn1 Pt3 Sn1 Cl1 -165.85(14) 4_575 .
Sn3 Pt3 Sn1 Cl1 59.80(15) . .
Pt2 Pt3 Sn1 Cl1 161.68(15) . .
Pt1 Pt3 Sn1 Cl1 125.62(14) 4_575 .
Pt1 Pt3 Sn1 Cl1 93.40(15) . .
C3 Pt3 Sn1 Cl2 54.9(8) . .
Sn1 Pt3 Sn1 Cl2 -61.79(15) 4_575 .
Sn3 Pt3 Sn1 Cl2 163.86(13) . .
Pt2 Pt3 Sn1 Cl2 -94.27(13) . .
Pt1 Pt3 Sn1 Cl2 -130.32(13) 4_575 .
Pt1 Pt3 Sn1 Cl2 -162.54(14) . .
C3 Pt3 Sn1 Pt1 -142.6(8) . .
Sn1 Pt3 Sn1 Pt1 100.75(6) 4_575 .
Sn3 Pt3 Sn1 Pt1 -33.60(5) . .
Pt2 Pt3 Sn1 Pt1 68.27(3) . .
Pt1 Pt3 Sn1 Pt1 32.22(3) 4_575 .
C3 Pt3 Sn1 Pt2 149.2(8) . .
Sn1 Pt3 Sn1 Pt2 32.48(6) 4_575 .
Sn3 Pt3 Sn1 Pt2 -101.88(6) . .
Pt1 Pt3 Sn1 Pt2 -36.06(4) 4_575 .
Pt1 Pt3 Sn1 Pt2 -68.27(3) . .
C1 Pt1 Sn1 O5 -76.2(7) . .
Sn3 Pt1 Sn1 O5 -174.9(3) . .
Sn4 Pt1 Sn1 O5 102.8(4) . .
Pt1 Pt1 Sn1 O5 123.2(3) 4_575 .
Pt2 Pt1 Sn1 O5 84.1(3) . .
Pt4 Pt1 Sn1 O5 58.2(3) . .
Sn2 Pt1 Sn1 O5 20.7(3) . .
Pt3 Pt1 Sn1 O5 155.1(3) . .
C1 Pt1 Sn1 Cl1 17.5(6) . .
Sn3 Pt1 Sn1 Cl1 -81.20(13) . .
Sn4 Pt1 Sn1 Cl1 -163.6(2) . .
Pt1 Pt1 Sn1 Cl1 -143.16(12) 4_575 .
Pt2 Pt1 Sn1 Cl1 177.81(13) . .
Pt4 Pt1 Sn1 Cl1 151.85(12) . .
Sn2 Pt1 Sn1 Cl1 114.37(13) . .
Pt3 Pt1 Sn1 Cl1 -111.20(13) . .
C1 Pt1 Sn1 Cl2 -154.9(8) . .
Sn3 Pt1 Sn1 Cl2 106.4(4) . .
Sn4 Pt1 Sn1 Cl2 24.1(5) . .
Pt1 Pt1 Sn1 Cl2 44.5(4) 4_575 .
Pt2 Pt1 Sn1 Cl2 5.4(4) . .
Pt4 Pt1 Sn1 Cl2 -20.5(4) . .
Sn2 Pt1 Sn1 Cl2 -58.0(4) . .
Pt3 Pt1 Sn1 Cl2 76.4(4) . .
C1 Pt1 Sn1 Pt3 128.7(6) . .
Sn3 Pt1 Sn1 Pt3 30.00(4) . .
Sn4 Pt1 Sn1 Pt3 -52.4(2) . .
Pt1 Pt1 Sn1 Pt3 -31.97(3) 4_575 .
Pt2 Pt1 Sn1 Pt3 -71.00(4) . .
Pt4 Pt1 Sn1 Pt3 -96.95(4) . .
Sn2 Pt1 Sn1 Pt3 -134.43(4) . .
C1 Pt1 Sn1 Pt2 -160.3(6) . .
Sn3 Pt1 Sn1 Pt2 100.99(4) . .
Sn4 Pt1 Sn1 Pt2 18.6(2) . .
Pt1 Pt1 Sn1 Pt2 39.03(3) 4_575 .
Pt4 Pt1 Sn1 Pt2 -25.95(3) . .
Sn2 Pt1 Sn1 Pt2 -63.43(4) . .
Pt3 Pt1 Sn1 Pt2 71.00(4) . .
C2 Pt2 Sn1 O5 74.4(7) . .
Pt3 Pt2 Sn1 O5 -160.5(3) . .
Sn2 Pt2 Sn1 O5 -104.0(4) 4_575 .
Sn2 Pt2 Sn1 O5 -21.2(3) . .
Pt4 Pt2 Sn1 O5 -60.1(3) . .
Pt1 Pt2 Sn1 O5 -86.5(3) . .
Pt1 Pt2 Sn1 O5 -125.1(3) 4_575 .
Sn1 Pt2 Sn1 O5 172.7(3) 4_575 .
C2 Pt2 Sn1 Cl1 153.4(7) . .
Pt3 Pt2 Sn1 Cl1 -81.4(4) . .
Sn2 Pt2 Sn1 Cl1 -24.9(5) 4_575 .
Sn2 Pt2 Sn1 Cl1 57.8(4) . .
Pt4 Pt2 Sn1 Cl1 19.0(4) . .
Pt1 Pt2 Sn1 Cl1 -7.4(4) . .
Pt1 Pt2 Sn1 Cl1 -46.0(4) 4_575 .
Sn1 Pt2 Sn1 Cl1 -108.3(4) 4_575 .
C2 Pt2 Sn1 Cl2 -17.6(6) . .
Pt3 Pt2 Sn1 Cl2 107.58(13) . .
Sn2 Pt2 Sn1 Cl2 164.1(2) 4_575 .
Sn2 Pt2 Sn1 Cl2 -113.15(12) . .
Pt4 Pt2 Sn1 Cl2 -152.00(12) . .
Pt1 Pt2 Sn1 Cl2 -178.39(13) . .
Pt1 Pt2 Sn1 Cl2 142.98(12) 4_575 .
Sn1 Pt2 Sn1 Cl2 80.75(13) 4_575 .
C2 Pt2 Sn1 Pt3 -125.1(6) . .
Sn2 Pt2 Sn1 Pt3 56.52(19) 4_575 .
Sn2 Pt2 Sn1 Pt3 139.27(5) . .
Pt4 Pt2 Sn1 Pt3 100.43(5) . .
Pt1 Pt2 Sn1 Pt3 74.03(4) . .
Pt1 Pt2 Sn1 Pt3 35.41(4) 4_575 .
Sn1 Pt2 Sn1 Pt3 -26.83(5) 4_575 .
C2 Pt2 Sn1 Pt1 160.8(6) . .
Pt3 Pt2 Sn1 Pt1 -74.03(4) . .
Sn2 Pt2 Sn1 Pt1 -17.51(19) 4_575 .
Sn2 Pt2 Sn1 Pt1 65.24(4) . .
Pt4 Pt2 Sn1 Pt1 26.40(4) . .
Pt1 Pt2 Sn1 Pt1 -38.62(3) 4_575 .
Sn1 Pt2 Sn1 Pt1 -100.86(5) 4_575 .
C4 Pt4 Sn2 O5 171.6(8) . .
Sn2 Pt4 Sn2 O5 -69.0(5) 4_575 .
Sn4 Pt4 Sn2 O5 66.3(5) . .
Pt2 Pt4 Sn2 O5 -34.6(5) . .
Pt1 Pt4 Sn2 O5 -0.3(5) 4_575 .
Pt1 Pt4 Sn2 O5 33.7(5) . .
C4 Pt4 Sn2 Cl3 41.9(7) . .
Sn2 Pt4 Sn2 Cl3 161.32(14) 4_575 .
Sn4 Pt4 Sn2 Cl3 -63.41(16) . .
Pt2 Pt4 Sn2 Cl3 -164.23(15) . .
Pt1 Pt4 Sn2 Cl3 -129.97(15) 4_575 .
Pt1 Pt4 Sn2 Cl3 -95.95(15) . .
C4 Pt4 Sn2 Cl4 -62.2(7) . .
Sn2 Pt4 Sn2 Cl4 57.22(15) 4_575 .
Sn4 Pt4 Sn2 Cl4 -167.51(14) . .
Pt2 Pt4 Sn2 Cl4 91.66(14) . .
Pt1 Pt4 Sn2 Cl4 125.93(14) 4_575 .
Pt1 Pt4 Sn2 Cl4 159.95(14) . .
C4 Pt4 Sn2 Pt2 -153.8(7) . .
Sn2 Pt4 Sn2 Pt2 -34.44(6) 4_575 .
Sn4 Pt4 Sn2 Pt2 100.82(6) . .
Pt1 Pt4 Sn2 Pt2 34.26(4) 4_575 .
Pt1 Pt4 Sn2 Pt2 68.29(3) . .
C4 Pt4 Sn2 Pt1 137.9(7) . .
Sn2 Pt4 Sn2 Pt1 -102.73(6) 4_575 .
Sn4 Pt4 Sn2 Pt1 32.54(5) . .
Pt2 Pt4 Sn2 Pt1 -68.29(3) . .
Pt1 Pt4 Sn2 Pt1 -34.02(3) 4_575 .
C2 Pt2 Sn2 O5 -73.4(7) . .
Pt3 Pt2 Sn2 O5 58.1(3) . .
Sn2 Pt2 Sn2 O5 -172.5(3) 4_575 .
Pt4 Pt2 Sn2 O5 157.8(3) . .
Pt1 Pt2 Sn2 O5 85.0(3) . .
Pt1 Pt2 Sn2 O5 124.0(3) 4_575 .
Sn1 Pt2 Sn2 O5 108.2(4) 4_575 .
Sn1 Pt2 Sn2 O5 21.2(3) . .
C2 Pt2 Sn2 Cl3 -157.6(8) . .
Pt3 Pt2 Sn2 Cl3 -26.0(5) . .
Sn2 Pt2 Sn2 Cl3 103.3(5) 4_575 .
Pt4 Pt2 Sn2 Cl3 73.6(5) . .
Pt1 Pt2 Sn2 Cl3 0.8(5) . .
Pt1 Pt2 Sn2 Cl3 39.9(5) 4_575 .
Sn1 Pt2 Sn2 Cl3 24.1(6) 4_575 .
Sn1 Pt2 Sn2 Cl3 -62.9(5) . .
C2 Pt2 Sn2 Cl4 18.0(6) . .
Pt3 Pt2 Sn2 Cl4 149.57(13) . .
Sn2 Pt2 Sn2 Cl4 -81.07(14) 4_575 .
Pt4 Pt2 Sn2 Cl4 -110.79(13) . .
Pt1 Pt2 Sn2 Cl4 176.43(13) . .
Pt1 Pt2 Sn2 Cl4 -144.52(13) 4_575 .
Sn1 Pt2 Sn2 Cl4 -160.3(2) 4_575 .
Sn1 Pt2 Sn2 Cl4 112.68(13) . .
C2 Pt2 Sn2 Pt4 128.8(6) . .
Pt3 Pt2 Sn2 Pt4 -99.64(5) . .
Sn2 Pt2 Sn2 Pt4 29.72(6) 4_575 .
Pt1 Pt2 Sn2 Pt4 -72.78(4) . .
Pt1 Pt2 Sn2 Pt4 -33.73(4) 4_575 .
Sn1 Pt2 Sn2 Pt4 -49.52(19) 4_575 .
Sn1 Pt2 Sn2 Pt4 -136.53(5) . .
C2 Pt2 Sn2 Pt1 -158.4(6) . .
Pt3 Pt2 Sn2 Pt1 -26.86(4) . .
Sn2 Pt2 Sn2 Pt1 102.51(5) 4_575 .
Pt4 Pt2 Sn2 Pt1 72.78(4) . .
Pt1 Pt2 Sn2 Pt1 39.06(3) 4_575 .
Sn1 Pt2 Sn2 Pt1 23.26(19) 4_575 .
Sn1 Pt2 Sn2 Pt1 -63.74(4) . .
C1 Pt1 Sn2 O5 75.3(6) . .
Sn3 Pt1 Sn2 O5 -102.4(4) . .
Sn4 Pt1 Sn2 O5 173.2(3) . .
Pt1 Pt1 Sn2 O5 -124.8(3) 4_575 .
Pt2 Pt1 Sn2 O5 -85.8(3) . .
Sn1 Pt1 Sn2 O5 -20.8(3) . .
Pt4 Pt1 Sn2 O5 -158.2(3) . .
Pt3 Pt1 Sn2 O5 -60.3(3) . .
C1 Pt1 Sn2 Cl3 -18.7(5) . .
Sn3 Pt1 Sn2 Cl3 163.7(2) . .
Sn4 Pt1 Sn2 Cl3 79.25(13) . .
Pt1 Pt1 Sn2 Cl3 141.25(13) 4_575 .
Pt2 Pt1 Sn2 Cl3 -179.78(13) . .
Sn1 Pt1 Sn2 Cl3 -114.75(13) . .
Pt4 Pt1 Sn2 Cl3 107.83(13) . .
Pt3 Pt1 Sn2 Cl3 -154.28(13) . .
C1 Pt1 Sn2 Cl4 150.0(7) . .
Sn3 Pt1 Sn2 Cl4 -27.7(5) . .
Sn4 Pt1 Sn2 Cl4 -112.1(4) . .
Pt1 Pt1 Sn2 Cl4 -50.1(4) 4_575 .
Pt2 Pt1 Sn2 Cl4 -11.1(4) . .
Sn1 Pt1 Sn2 Cl4 53.9(4) . .
Pt4 Pt1 Sn2 Cl4 -83.5(4) . .
Pt3 Pt1 Sn2 Cl4 14.4(4) . .
C1 Pt1 Sn2 Pt4 -126.5(5) . .
Sn3 Pt1 Sn2 Pt4 55.86(18) . .
Sn4 Pt1 Sn2 Pt4 -28.57(4) . .
Pt1 Pt1 Sn2 Pt4 33.42(3) 4_575 .
Pt2 Pt1 Sn2 Pt4 72.40(4) . .
Sn1 Pt1 Sn2 Pt4 137.42(4) . .
Pt3 Pt1 Sn2 Pt4 97.89(4) . .
C1 Pt1 Sn2 Pt2 161.1(5) . .
Sn3 Pt1 Sn2 Pt2 -16.53(18) . .
Sn4 Pt1 Sn2 Pt2 -100.97(4) . .
Pt1 Pt1 Sn2 Pt2 -38.97(3) 4_575 .
Sn1 Pt1 Sn2 Pt2 65.02(4) . .
Pt4 Pt1 Sn2 Pt2 -72.40(4) . .
Pt3 Pt1 Sn2 Pt2 25.49(3) . .
C3 Pt3 Sn3 O6 180.0 . .
Sn1 Pt3 Sn3 O6 -68.44(4) 4_575 .
Sn1 Pt3 Sn3 O6 68.44(4) . .
Pt2 Pt3 Sn3 O6 0.0 . .
Pt1 Pt3 Sn3 O6 -34.36(2) 4_575 .
Pt1 Pt3 Sn3 O6 34.36(2) . .
C3 Pt3 Sn3 Cl5 -50.40(14) . .
Sn1 Pt3 Sn3 Cl5 61.16(15) 4_575 .
Sn1 Pt3 Sn3 Cl5 -161.96(14) . .
Pt2 Pt3 Sn3 Cl5 129.60(14) . .
Pt1 Pt3 Sn3 Cl5 95.24(14) 4_575 .
Pt1 Pt3 Sn3 Cl5 163.96(14) . .
C3 Pt3 Sn3 Cl5 50.40(14) . 4_575
Sn1 Pt3 Sn3 Cl5 161.96(14) 4_575 4_575
Sn1 Pt3 Sn3 Cl5 -61.16(15) . 4_575
Pt2 Pt3 Sn3 Cl5 -129.60(14) . 4_575
Pt1 Pt3 Sn3 Cl5 -163.96(14) 4_575 4_575
Pt1 Pt3 Sn3 Cl5 -95.24(14) . 4_575
C3 Pt3 Sn3 Pt1 -145.64(2) . 4_575
Sn1 Pt3 Sn3 Pt1 -34.08(5) 4_575 4_575
Sn1 Pt3 Sn3 Pt1 102.80(5) . 4_575
Pt2 Pt3 Sn3 Pt1 34.36(2) . 4_575
Pt1 Pt3 Sn3 Pt1 68.72(4) . 4_575
C3 Pt3 Sn3 Pt1 145.64(2) . .
Sn1 Pt3 Sn3 Pt1 -102.80(5) 4_575 .
Sn1 Pt3 Sn3 Pt1 34.08(5) . .
Pt2 Pt3 Sn3 Pt1 -34.36(2) . .
Pt1 Pt3 Sn3 Pt1 -68.72(4) 4_575 .
C1 Pt1 Sn3 O6 68.9(6) . .
Sn4 Pt1 Sn3 O6 -25.1(2) . .
Pt1 Pt1 Sn3 O6 -88.3(2) 4_575 .
Pt2 Pt1 Sn3 O6 -128.2(2) . .
Sn1 Pt1 Sn3 O6 169.0(2) . .
Pt4 Pt1 Sn3 O6 -64.8(2) . .
Sn2 Pt1 Sn3 O6 -113.4(3) . .
Pt3 Pt1 Sn3 O6 -161.4(2) . .
C1 Pt1 Sn3 Cl5 162.2(8) . .
Sn4 Pt1 Sn3 Cl5 68.1(5) . .
Pt1 Pt1 Sn3 Cl5 4.9(5) 4_575 .
Pt2 Pt1 Sn3 Cl5 -34.9(5) . .
Sn1 Pt1 Sn3 Cl5 -97.8(5) . .
Pt4 Pt1 Sn3 Cl5 28.5(6) . .
Sn2 Pt1 Sn3 Cl5 -20.2(6) . .
Pt3 Pt1 Sn3 Cl5 -68.2(5) . .
C1 Pt1 Sn3 Cl5 -24.2(5) . 4_575
Sn4 Pt1 Sn3 Cl5 -118.20(15) . 4_575
Pt1 Pt1 Sn3 Cl5 178.58(15) 4_575 4_575
Pt2 Pt1 Sn3 Cl5 138.72(15) . 4_575
Sn1 Pt1 Sn3 Cl5 75.88(15) . 4_575
Pt4 Pt1 Sn3 Cl5 -157.86(14) . 4_575
Sn2 Pt1 Sn3 Cl5 153.5(2) . 4_575
Pt3 Pt1 Sn3 Cl5 105.50(15) . 4_575
C1 Pt1 Sn3 Pt3 -129.7(5) . .
Sn4 Pt1 Sn3 Pt3 136.29(3) . .
Pt1 Pt1 Sn3 Pt3 73.08(2) 4_575 .
Pt2 Pt1 Sn3 Pt3 33.22(3) . .
Sn1 Pt1 Sn3 Pt3 -29.62(3) . .
Pt4 Pt1 Sn3 Pt3 96.64(4) . .
Sn2 Pt1 Sn3 Pt3 47.96(18) . .
C1 Pt1 Sn3 Pt1 157.2(5) . 4_575
Sn4 Pt1 Sn3 Pt1 63.22(3) . 4_575
Pt2 Pt1 Sn3 Pt1 -39.86(4) . 4_575
Sn1 Pt1 Sn3 Pt1 -102.70(3) . 4_575
Pt4 Pt1 Sn3 Pt1 23.56(5) . 4_575
Sn2 Pt1 Sn3 Pt1 -25.12(19) . 4_575
Pt3 Pt1 Sn3 Pt1 -73.08(2) . 4_575
C4 Pt4 Sn4 O6 180.000(2) . .
Sn2 Pt4 Sn4 O6 67.58(4) 4_575 .
Sn2 Pt4 Sn4 O6 -67.58(4) . .
Pt2 Pt4 Sn4 O6 0.000(3) . .
Pt1 Pt4 Sn4 O6 34.36(2) 4_575 .
Pt1 Pt4 Sn4 O6 -34.36(2) . .
C4 Pt4 Sn4 Cl6 50.06(14) . .
Sn2 Pt4 Sn4 Cl6 -62.36(15) 4_575 .
Sn2 Pt4 Sn4 Cl6 162.48(14) . .
Pt2 Pt4 Sn4 Cl6 -129.94(14) . .
Pt1 Pt4 Sn4 Cl6 -95.58(14) 4_575 .
Pt1 Pt4 Sn4 Cl6 -164.30(14) . .
C4 Pt4 Sn4 Cl6 -50.06(14) . 4_575
Sn2 Pt4 Sn4 Cl6 -162.48(14) 4_575 4_575
Sn2 Pt4 Sn4 Cl6 62.36(15) . 4_575
Pt2 Pt4 Sn4 Cl6 129.94(14) . 4_575
Pt1 Pt4 Sn4 Cl6 164.30(14) 4_575 4_575
Pt1 Pt4 Sn4 Cl6 95.58(14) . 4_575
C4 Pt4 Sn4 Pt1 145.64(2) . 4_575
Sn2 Pt4 Sn4 Pt1 33.22(5) 4_575 4_575
Sn2 Pt4 Sn4 Pt1 -101.94(5) . 4_575
Pt2 Pt4 Sn4 Pt1 -34.36(2) . 4_575
Pt1 Pt4 Sn4 Pt1 -68.72(4) . 4_575
C4 Pt4 Sn4 Pt1 -145.64(2) . .
Sn2 Pt4 Sn4 Pt1 101.94(5) 4_575 .
Sn2 Pt4 Sn4 Pt1 -33.22(5) . .
Pt2 Pt4 Sn4 Pt1 34.36(2) . .
Pt1 Pt4 Sn4 Pt1 68.72(4) 4_575 .
C1 Pt1 Sn4 O6 -69.9(7) . .
Sn3 Pt1 Sn4 O6 25.4(2) . .
Pt1 Pt1 Sn4 O6 88.5(2) 4_575 .
Pt2 Pt1 Sn4 O6 128.0(2) . .
Sn1 Pt1 Sn4 O6 111.2(3) . .
Pt4 Pt1 Sn4 O6 161.5(2) . .
Sn2 Pt1 Sn4 O6 -170.4(2) . .
Pt3 Pt1 Sn4 O6 64.9(2) . .
C1 Pt1 Sn4 Cl6 -157.8(8) . .
Sn3 Pt1 Sn4 Cl6 -62.6(6) . .
Pt1 Pt1 Sn4 Cl6 0.6(5) 4_575 .
Pt2 Pt1 Sn4 Cl6 40.1(6) . .
Sn1 Pt1 Sn4 Cl6 23.2(7) . .
Pt4 Pt1 Sn4 Cl6 73.5(6) . .
Sn2 Pt1 Sn4 Cl6 101.6(6) . .
Pt3 Pt1 Sn4 Cl6 -23.0(6) . .
C1 Pt1 Sn4 Cl6 21.4(6) . 4_575
Sn3 Pt1 Sn4 Cl6 116.71(14) . 4_575
Pt1 Pt1 Sn4 Cl6 179.85(15) 4_575 4_575
Pt2 Pt1 Sn4 Cl6 -140.65(14) . 4_575
Sn1 Pt1 Sn4 Cl6 -157.5(2) . 4_575
Pt4 Pt1 Sn4 Cl6 -107.20(14) . 4_575
Sn2 Pt1 Sn4 Cl6 -79.07(14) . 4_575
Pt3 Pt1 Sn4 Cl6 156.28(14) . 4_575
C1 Pt1 Sn4 Pt4 128.6(6) . .
Sn3 Pt1 Sn4 Pt4 -136.09(3) . .
Pt1 Pt1 Sn4 Pt4 -72.95(2) 4_575 .
Pt2 Pt1 Sn4 Pt4 -33.45(3) . .
Sn1 Pt1 Sn4 Pt4 -50.3(2) . .
Sn2 Pt1 Sn4 Pt4 28.13(3) . .
Pt3 Pt1 Sn4 Pt4 -96.52(4) . .
C1 Pt1 Sn4 Pt1 -158.4(6) . 4_575
Sn3 Pt1 Sn4 Pt1 -63.14(3) . 4_575
Pt2 Pt1 Sn4 Pt1 39.51(4) . 4_575
Sn1 Pt1 Sn4 Pt1 22.7(2) . 4_575
Pt4 Pt1 Sn4 Pt1 72.95(2) . 4_575
Sn2 Pt1 Sn4 Pt1 101.09(3) . 4_575
Pt3 Pt1 Sn4 Pt1 -23.57(5) . 4_575
Sn3 Pt1 C1 O1 167(29) . .
Sn4 Pt1 C1 O1 -118(29) . .
Pt1 Pt1 C1 O1 -154(29) 4_575 .
Pt2 Pt1 C1 O1 24(30) . .
Sn1 Pt1 C1 O1 62(30) . .
Pt4 Pt1 C1 O1 -66(30) . .
Sn2 Pt1 C1 O1 -13(30) . .
Pt3 Pt1 C1 O1 114(29) . .
Pt3 Pt2 C2 O2 0.00(11) . .
Sn2 Pt2 C2 O2 -127.63(15) 4_575 .
Sn2 Pt2 C2 O2 127.62(15) . .
Pt4 Pt2 C2 O2 180.00(11) . .
Pt1 Pt2 C2 O2 87.4(13) . .
Pt1 Pt2 C2 O2 -87.4(13) 4_575 .
Sn1 Pt2 C2 O2 -52.77(15) 4_575 .
Sn1 Pt2 C2 O2 52.76(15) . .
Sn1 Pt3 C3 O3 -117.3(2) 4_575 .
Sn1 Pt3 C3 O3 117.3(2) . .
Sn3 Pt3 C3 O3 0.000(8) . .
Pt2 Pt3 C3 O3 180.000(6) . .
Pt1 Pt3 C3 O3 -54.6(10) 4_575 .
Pt1 Pt3 C3 O3 54.6(10) . .
Sn2 Pt4 C4 O4 -62(100) 4_575 .
Sn2 Pt4 C4 O4 62(100) . .
Sn4 Pt4 C4 O4 180(100) . .
Pt2 Pt4 C4 O4 0(100) . .
Pt1 Pt4 C4 O4 -130(100) 4_575 .
Pt1 Pt4 C4 O4 130(100) . .
Cl3 Sn2 O5 Sn1 134.2(5) . .
Cl4 Sn2 O5 Sn1 -132.6(5) . .
Pt4 Sn2 O5 Sn1 -0.2(9) . .
Pt2 Sn2 O5 Sn1 -30.7(4) . .
Pt1 Sn2 O5 Sn1 29.7(4) . .
Cl1 Sn1 O5 Sn2 -133.2(5) . .
Cl2 Sn1 O5 Sn2 133.7(5) . .
Pt3 Sn1 O5 Sn2 4.2(8) . .
Pt1 Sn1 O5 Sn2 -30.0(4) . .
Pt2 Sn1 O5 Sn2 30.3(4) . .
Cl6 Sn4 O6 Sn3 134.45(12) . .
Cl6 Sn4 O6 Sn3 -134.45(12) 4_575 .
Pt4 Sn4 O6 Sn3 0.000(2) . .
Pt1 Sn4 O6 Sn3 30.33(2) 4_575 .
Pt1 Sn4 O6 Sn3 -30.33(2) . .
Cl5 Sn3 O6 Sn4 -133.29(13) . .
Cl5 Sn3 O6 Sn4 133.29(13) 4_575 .
Pt3 Sn3 O6 Sn4 0.0 . .
Pt1 Sn3 O6 Sn4 -30.40(2) 4_575 .
Pt1 Sn3 O6 Sn4 30.40(2) . .
C105 N1 C101 C102 -43(4) . .
C113 N1 C101 C102 76(3) . .
C109 N1 C101 C102 -162(3) . .
N1 C101 C102 C103 -169(3) . .
C101 C102 C103 C104 80(4) . .
C101 N1 C105 C106 -57(4) . .
C113 N1 C105 C106 -177(3) . .
C109 N1 C105 C106 64(3) . .
N1 C105 C106 C107 178(2) . .
C105 C106 C107 C108 -75(4) . .
C101 N1 C109 C110 -75(4) . .
C105 N1 C109 C110 162(3) . .
C113 N1 C109 C110 45(4) . .
N1 C109 C110 C111 162(3) . .
C109 C110 C111 C112 179(3) . .
C101 N1 C113 C114 -175(3) . .
C105 N1 C113 C114 -52(4) . .
C109 N1 C113 C114 64(4) . .
N1 C113 C114 C115 -171(3) . .
C113 C114 C115 C116 -161(3) . .
N5 Na1 N2 C201 -131(19) . .
N2 Na1 N2 C201 -53(21) 4_575 .
N4 Na1 N2 C201 129(19) . .
N3 Na1 N2 C201 32(19) . .
Na1 N2 C201 C202 -24(100) . .
N5 Na1 N3 C301 180.00(8) . .
N2 Na1 N3 C301 101.4(5) . .
N2 Na1 N3 C301 -101.4(5) 4_575 .
N4 Na1 N3 C301 0.00(8) . .
Na1 N3 C301 C302 0(100) . .
N5 Na1 N4 C401 180.00(3) . .
N2 Na1 N4 C401 -90.5(6) . .
N2 Na1 N4 C401 90.5(6) 4_575 .
N3 Na1 N4 C401 0.00(3) . .
Na1 N4 C401 C402 0.00(13) . .
N2 Na1 N5 C501 -101.2(5) . .
N2 Na1 N5 C501 101.2(5) 4_575 .
N4 Na1 N5 C501 0.00(5) . .
N3 Na1 N5 C501 180.00(5) . .
Na1 N5 C501 C502 0.0(2) . .
