#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:29:29 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179380 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/77/4327715.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4327715
loop_
_publ_author_name
'Deirdre I. Arnold'
'F. Albert Cotton'
'Fritz E. Kühn'
_publ_section_title
;
 Preparation and Characterization of
 Bis[dihalo(μ-bis(diphenylphosphino)amine)molybdenum(II)] Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5764
_journal_page_last               5769
_journal_paper_doi               10.1021/ic960325+
_journal_volume                  35
_journal_year                    1996
_chemical_compound_source        synthesized
_chemical_formula_analytical     'not done'
_chemical_formula_moiety         '(Mo2+)2, ( Cl1-)4, (C24 H21 N P2)2'
_chemical_formula_structural     (Mo(NH(P(C6H5)2)2)(Cl)2)2
_chemical_formula_sum            'C48 H42 Cl4 Mo2 N2 P4'
_chemical_formula_weight         1104.40
_chemical_name_systematic
;
 Bis[dichloroμ-bis(diphenylphosphino)amine)molybdenum(II)]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 91.15(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.522(4)
_cell_length_b                   17.881(5)
_cell_length_c                   16.898(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30
_cell_measurement_theta_min      20
_cell_volume                     4689(2)
_computing_data_reduction        'Enraf Nonius SDP'
_computing_molecular_graphics    'SHELXTL V5'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       CAD4
_diffrn_measurement_method       omega/2theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.70930
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_sigmaI/netI    0.0705
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            6932
_diffrn_reflns_theta_max         22.45
_diffrn_reflns_theta_min         2.10
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.936
_exptl_absorpt_correction_T_max  0.9992
_exptl_absorpt_correction_T_min  0.7812
_exptl_absorpt_correction_type   'psi scans'
_exptl_crystal_colour            'emerald green'
_exptl_crystal_density_diffrn    1.564
_exptl_crystal_description       'hexagonal plates'
_exptl_crystal_F_000             2224
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.630
_refine_diff_density_min         -0.526
_refine_diff_density_rms         0.086
_refine_ls_extinction_coef       none
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.022
_refine_ls_goodness_of_fit_obs   1.054
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_parameters     543
_refine_ls_number_reflns         6127
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_restrained_S_obs      1.054
_refine_ls_R_factor_all          0.0812
_refine_ls_R_factor_obs          0.0369
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0425P)²+1.9215P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0995
_refine_ls_wR_factor_obs         0.0845
_reflns_number_observed          4324
_reflns_number_total             6127
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic9603252B_1.cif
_cod_data_source_block           1981(2)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0425P)^2^+1.9215P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0425P)^2^+1.9215P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        4689.0(20)
_cod_original_sg_symbol_H-M      'P 1 21/c 1'
_cod_database_code               4327715
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x-1/2, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Mo2 Mo 0.20803(3) 0.95367(3) 0.23078(3) 0.02982(15) Uani 1 d .
Mo1 Mo 0.32359(3) 0.99180(3) 0.28815(3) 0.03028(15) Uani 1 d .
P3 P 0.41783(10) 1.00068(9) 0.16364(9) 0.0401(4) Uani 1 d .
P1 P 0.26941(9) 0.99865(8) 0.43006(8) 0.0307(3) Uani 1 d .
P2 P 0.10463(9) 0.98368(8) 0.34478(8) 0.0295(3) Uani 1 d .
Cl4 Cl 0.14913(10) 1.05834(8) 0.15946(8) 0.0467(4) Uani 1 d .
Cl2 Cl 0.31500(11) 1.12508(8) 0.29007(10) 0.0538(4) Uani 1 d .
P4 P 0.27253(10) 0.91888(9) 0.09741(8) 0.0385(4) Uani 1 d .
Cl3 Cl 0.19399(11) 0.82374(8) 0.25658(9) 0.0531(4) Uani 1 d .
Cl1 Cl 0.40253(10) 0.88615(9) 0.33233(9) 0.0499(4) Uani 1 d .
N1 N 0.1620(3) 1.0084(2) 0.4264(2) 0.0339(11) Uani 1 d .
H1 H 0.1358(3) 1.0262(2) 0.4666(2) 0.065(15) Uiso 1 calc R
N2 N 0.3597(3) 0.9730(3) 0.0841(3) 0.0491(14) Uani 1 d .
H2 H 0.3743(3) 0.9862(3) 0.0373(3) 0.065(15) Uiso 1 calc R
C3A C 0.4565(4) 1.0929(4) 0.1379(4) 0.052(2) Uani 1 d .
C3B C 0.5414(5) 1.1139(4) 0.1439(4) 0.070(2) Uani 1 d .
H3B H 0.5833(5) 1.0787(4) 0.1575(4) 0.061(3) Uiso 1 calc R
C3C C 0.5652(6) 1.1871(5) 0.1300(6) 0.100(3) Uani 1 d .
H3C H 0.6228(6) 1.2008(5) 0.1345(6) 0.061(3) Uiso 1 calc R
C3D C 0.5062(7) 1.2380(5) 0.1100(6) 0.102(3) Uani 1 d .
H3D H 0.5232(7) 1.2871(5) 0.1010(6) 0.061(3) Uiso 1 calc R
C3E C 0.4224(7) 1.2198(5) 0.1026(6) 0.105(3) Uani 1 d .
H3E H 0.3820(7) 1.2559(5) 0.0881(6) 0.061(3) Uiso 1 calc R
C3F C 0.3968(5) 1.1470(4) 0.1168(4) 0.077(2) Uani 1 d .
H3F H 0.3388(5) 1.1343(4) 0.1120(4) 0.061(3) Uiso 1 calc R
C3G C 0.5169(4) 0.9464(4) 0.1648(4) 0.050(2) Uani 1 d .
C3H C 0.5413(5) 0.9024(5) 0.1024(5) 0.078(2) Uani 1 d .
H3H H 0.5054(5) 0.8986(5) 0.0578(5) 0.061(3) Uiso 1 calc R
C3I C 0.6176(6) 0.8640(6) 0.1051(7) 0.112(4) Uani 1 d .
H3I H 0.6336(6) 0.8343(6) 0.0628(7) 0.061(3) Uiso 1 calc R
C3K C 0.6695(7) 0.8699(7) 0.1699(8) 0.119(4) Uani 1 d .
H3K H 0.7208(7) 0.8431(7) 0.1722(8) 0.061(3) Uiso 1 calc R
C3L C 0.6482(5) 0.9140(6) 0.2313(6) 0.101(4) Uani 1 d .
H3L H 0.6857(5) 0.9189(6) 0.2747(6) 0.061(3) Uiso 1 calc R
C3M C 0.5710(5) 0.9516(5) 0.2294(4) 0.073(2) Uani 1 d .
H3M H 0.5554(5) 0.9808(5) 0.2724(4) 0.061(3) Uiso 1 calc R
C1A C 0.2896(4) 0.9216(3) 0.5000(3) 0.0330(13) Uani 1 d .
C1B C 0.2454(4) 0.8559(3) 0.4908(3) 0.0412(15) Uani 1 d .
H1B H 0.2077(4) 0.8499(3) 0.4478(3) 0.061(3) Uiso 1 calc R
C1C C 0.2564(4) 0.7979(3) 0.5448(4) 0.050(2) Uani 1 d .
H1C H 0.2245(4) 0.7541(3) 0.5392(4) 0.061(3) Uiso 1 calc R
C1D C 0.3144(4) 0.8056(4) 0.6060(4) 0.054(2) Uani 1 d .
H1D H 0.3218(4) 0.7671(4) 0.6425(4) 0.061(3) Uiso 1 calc R
C1E C 0.3612(5) 0.8693(4) 0.6138(4) 0.063(2) Uani 1 d .
H1E H 0.4020(5) 0.8734(4) 0.6546(4) 0.061(3) Uiso 1 calc R
C1F C 0.3491(4) 0.9279(4) 0.5621(4) 0.052(2) Uani 1 d .
H1F H 0.3807(4) 0.9718(4) 0.5686(4) 0.061(3) Uiso 1 calc R
C1G C 0.3097(3) 1.0770(3) 0.4861(3) 0.0324(13) Uani 1 d .
C1H C 0.2644(4) 1.1110(3) 0.5453(3) 0.0370(14) Uani 1 d .
H1H H 0.2077(4) 1.0967(3) 0.5539(3) 0.061(3) Uiso 1 calc R
C1I C 0.3015(4) 1.1660(3) 0.5922(3) 0.044(2) Uani 1 d .
H1I H 0.2691(4) 1.1899(3) 0.6303(3) 0.061(3) Uiso 1 calc R
C1K C 0.3859(4) 1.1854(3) 0.5825(4) 0.052(2) Uani 1 d .
H1K H 0.4114(4) 1.2216(3) 0.6149(4) 0.061(3) Uiso 1 calc R
C1L C 0.4325(4) 1.1514(4) 0.5252(4) 0.054(2) Uani 1 d .
H1L H 0.4899(4) 1.1646(4) 0.5187(4) 0.061(3) Uiso 1 calc R
C1M C 0.3953(4) 1.0976(3) 0.4765(3) 0.048(2) Uani 1 d .
H1M H 0.4276(4) 1.0751(3) 0.4373(3) 0.061(3) Uiso 1 calc R
C4A C 0.3082(4) 0.8239(4) 0.0804(4) 0.049(2) Uani 1 d .
C4B C 0.2805(4) 0.7805(4) 0.0173(4) 0.061(2) Uani 1 d .
H4B H 0.2395(4) 0.7995(4) -0.0182(4) 0.061(3) Uiso 1 calc R
C4C C 0.3122(5) 0.7100(5) 0.0059(5) 0.078(2) Uani 1 d .
H4C H 0.2930(5) 0.6821(5) -0.0375(5) 0.061(3) Uiso 1 calc R
C4D C 0.3704(6) 0.6808(4) 0.0564(5) 0.080(3) Uani 1 d .
H4D H 0.3902(6) 0.6323(4) 0.0487(5) 0.061(3) Uiso 1 calc R
C4E C 0.4012(6) 0.7221(5) 0.1200(5) 0.087(3) Uani 1 d .
H4E H 0.4436(6) 0.7028(5) 0.1540(5) 0.061(3) Uiso 1 calc R
C4F C 0.3676(5) 0.7928(4) 0.1319(4) 0.066(2) Uani 1 d .
H4F H 0.3858(5) 0.8200(4) 0.1761(4) 0.061(3) Uiso 1 calc R
C4G C 0.2031(4) 0.9367(3) 0.0119(3) 0.0396(15) Uani 1 d .
C4H C 0.1177(4) 0.9192(4) 0.0162(4) 0.058(2) Uani 1 d .
H4H H 0.0965(4) 0.9000(4) 0.0632(4) 0.061(3) Uiso 1 calc R
C4I C 0.0621(4) 0.9294(4) -0.0479(4) 0.058(2) Uani 1 d .
H4I H 0.0042(4) 0.9171(4) -0.0437(4) 0.061(3) Uiso 1 calc R
C4K C 0.0914(5) 0.9571(4) -0.1161(4) 0.067(2) Uani 1 d .
H4K H 0.0542(5) 0.9636(4) -0.1594(4) 0.061(3) Uiso 1 calc R
C4L C 0.1756(6) 0.9754(5) -0.1212(4) 0.093(3) Uani 1 d .
H4L H 0.1959(6) 0.9946(5) -0.1685(4) 0.061(3) Uiso 1 calc R
C4M C 0.2325(5) 0.9662(5) -0.0575(4) 0.075(2) Uani 1 d .
H4M H 0.2900(5) 0.9799(5) -0.0617(4) 0.061(3) Uiso 1 calc R
C2A C 0.0344(3) 0.9076(3) 0.3743(3) 0.0315(13) Uani 1 d .
C2B C -0.0099(4) 0.8687(3) 0.3154(3) 0.044(2) Uani 1 d .
H2B H -0.0013(4) 0.8802(3) 0.2625(3) 0.061(3) Uiso 1 calc R
C2C C -0.0667(4) 0.8128(3) 0.3353(4) 0.044(2) Uani 1 d .
H2C H -0.0968(4) 0.7872(3) 0.2956(4) 0.061(3) Uiso 1 calc R
C2D C -0.0789(4) 0.7948(3) 0.4132(4) 0.046(2) Uani 1 d .
H2D H -0.1168(4) 0.7567(3) 0.4262(4) 0.061(3) Uiso 1 calc R
C2E C -0.0356(4) 0.8328(3) 0.4715(4) 0.048(2) Uani 1 d .
H2E H -0.0444(4) 0.8206(3) 0.5242(4) 0.061(3) Uiso 1 calc R
C2F C 0.0216(4) 0.8894(3) 0.4529(3) 0.041(2) Uani 1 d .
H2F H 0.0512(4) 0.9149(3) 0.4929(3) 0.061(3) Uiso 1 calc R
C2G C 0.0285(4) 1.0601(3) 0.3315(3) 0.0343(14) Uani 1 d .
C2H C -0.0603(4) 1.0501(3) 0.3361(3) 0.046(2) Uani 1 d .
H2H H -0.0824(4) 1.0028(3) 0.3462(3) 0.061(3) Uiso 1 calc R
C2I C -0.1156(4) 1.1098(4) 0.3259(4) 0.061(2) Uani 1 d .
H2I H -0.1749(4) 1.1032(4) 0.3291(4) 0.061(3) Uiso 1 calc R
C2K C -0.0820(5) 1.1787(4) 0.3110(4) 0.065(2) Uani 1 d .
H2K H -0.1191(5) 1.2192(4) 0.3045(4) 0.061(3) Uiso 1 calc R
C2L C 0.0051(5) 1.1900(4) 0.3053(4) 0.062(2) Uani 1 d .
H2L H 0.0263(5) 1.2376(4) 0.2950(4) 0.061(3) Uiso 1 calc R
C2M C 0.0609(4) 1.1311(3) 0.3149(4) 0.051(2) Uani 1 d .
H2M H 0.1199(4) 1.1384(3) 0.3103(4) 0.061(3) Uiso 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
Mo1 Mo2 Cl3 107.98(5) y
Mo1 Mo2 Cl4 106.71(5) y
Cl3 Mo2 Cl4 145.15(6) y
Mo1 Mo2 P4 97.90(4) y
Cl3 Mo2 P4 87.87(5) ?
Cl4 Mo2 P4 84.22(5) ?
Mo1 Mo2 P2 97.11(4) y
Cl3 Mo2 P2 90.32(5) ?
Cl4 Mo2 P2 88.64(5) ?
P4 Mo2 P2 164.69(5) y
Mo2 Mo1 Cl1 108.28(5) y
Mo2 Mo1 Cl2 106.17(5) y
Cl1 Mo1 Cl2 145.30(6) y
Mo2 Mo1 P1 98.73(4) y
Cl1 Mo1 P1 85.43(5) ?
Cl2 Mo1 P1 85.41(5) ?
Mo2 Mo1 P3 97.69(4) y
Cl1 Mo1 P3 90.46(5) ?
Cl2 Mo1 P3 89.00(6) ?
P1 Mo1 P3 163.54(5) y
N2 P3 C3A 104.6(3) ?
N2 P3 C3G 107.0(3) ?
C3A P3 C3G 101.8(3) ?
N2 P3 Mo1 109.2(2) ?
C3A P3 Mo1 116.5(2) ?
C3G P3 Mo1 116.7(2) ?
N1 P1 C1G 105.9(2) ?
N1 P1 C1A 104.9(2) ?
C1G P1 C1A 101.1(2) ?
N1 P1 Mo1 108.4(2) ?
C1G P1 Mo1 114.4(2) ?
C1A P1 Mo1 120.8(2) ?
N1 P2 C2G 103.6(2) ?
N1 P2 C2A 106.3(2) ?
C2G P2 C2A 101.8(3) ?
N1 P2 Mo2 109.8(2) ?
C2G P2 Mo2 118.4(2) ?
C2A P2 Mo2 115.7(2) ?
N2 P4 C4A 105.6(3) ?
N2 P4 C4G 105.0(3) ?
C4A P4 C4G 102.5(3) ?
N2 P4 Mo2 107.9(2) ?
C4A P4 Mo2 119.6(2) ?
C4G P4 Mo2 115.0(2) ?
P1 N1 P2 120.8(3) y
P3 N2 P4 118.9(3) y
C3B C3A C3F 117.8(7) ?
C3B C3A P3 123.7(6) ?
C3F C3A P3 118.4(5) ?
C3A C3B C3C 120.4(8) ?
C3D C3C C3B 120.5(8) ?
C3C C3D C3E 121.1(9) ?
C3D C3E C3F 119.6(9) ?
C3A C3F C3E 120.6(8) ?
C3M C3G C3H 118.5(7) ?
C3M C3G P3 118.6(5) ?
C3H C3G P3 122.9(5) ?
C3I C3H C3G 120.8(8) ?
C3K C3I C3H 119.3(10) ?
C3I C3K C3L 121.2(9) ?
C3K C3L C3M 119.7(9) ?
C3G C3M C3L 120.4(8) ?
C1B C1A C1F 118.7(5) ?
C1B C1A P1 119.5(4) ?
C1F C1A P1 121.8(4) ?
C1A C1B C1C 120.8(6) ?
C1D C1C C1B 119.5(6) ?
C1E C1D C1C 120.2(6) ?
C1D C1E C1F 120.8(6) ?
C1E C1F C1A 119.9(6) ?
C1H C1G C1M 118.1(5) ?
C1H C1G P1 123.3(4) ?
C1M C1G P1 117.9(4) ?
C1G C1H C1I 121.2(6) ?
C1K C1I C1H 120.1(6) ?
C1L C1K C1I 119.6(6) ?
C1K C1L C1M 120.7(6) ?
C1L C1M C1G 120.2(6) ?
C4F C4A C4B 117.2(7) ?
C4F C4A P4 118.9(5) ?
C4B C4A P4 124.0(5) ?
C4C C4B C4A 121.3(7) ?
C4D C4C C4B 120.6(8) ?
C4C C4D C4E 120.5(8) ?
C4D C4E C4F 118.4(8) ?
C4A C4F C4E 121.9(7) ?
C4H C4G C4M 118.4(6) ?
C4H C4G P4 118.6(5) ?
C4M C4G P4 123.1(5) ?
C4G C4H C4I 121.2(6) ?
C4K C4I C4H 120.3(6) ?
C4I C4K C4L 119.3(7) ?
C4K C4L C4M 121.5(7) ?
C4G C4M C4L 119.4(7) ?
C2B C2A C2F 119.4(5) ?
C2B C2A P2 118.1(4) ?
C2F C2A P2 122.5(4) ?
C2C C2B C2A 120.0(5) ?
C2D C2C C2B 120.3(6) ?
C2E C2D C2C 120.1(6) ?
C2D C2E C2F 120.6(6) ?
C2A C2F C2E 119.6(5) ?
C2H C2G C2M 119.2(5) ?
C2H C2G P2 122.6(5) ?
C2M C2G P2 118.2(5) ?
C2I C2H C2G 120.6(6) ?
C2K C2I C2H 118.9(7) ?
C2I C2K C2L 121.8(7) ?
C2M C2L C2K 120.0(7) ?
C2L C2M C2G 119.5(6) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Mo2 Mo1 2.1336(8) y
Mo2 Cl3 2.375(2) y
Mo2 Cl4 2.397(2) y
Mo2 P4 2.561(2) y
Mo2 P2 2.588(2) y
Mo1 Cl1 2.365(2) y
Mo1 Cl2 2.387(2) y
Mo1 P1 2.560(2) y
Mo1 P3 2.591(2) y
P3 N2 1.678(5) y
P3 C3A 1.811(7) y
P3 C3G 1.818(6) y
P1 N1 1.677(4) y
P1 C1G 1.797(5) y
P1 C1A 1.838(5) y
P2 N1 1.685(4) y
P2 C2G 1.817(6) y
P2 C2A 1.819(5) y
P4 N2 1.683(5) y
P4 C4A 1.811(7) y
P4 C4G 1.814(6) y
C3A C3B 1.372(9) ?
C3A C3F 1.382(9) ?
C3B C3C 1.380(10) ?
C3C C3D 1.330(12) ?
C3D C3E 1.344(11) ?
C3E C3F 1.383(11) ?
C3G C3M 1.367(9) ?
C3G C3H 1.375(9) ?
C3H C3I 1.369(11) ?
C3I C3K 1.349(13) ?
C3K C3L 1.350(13) ?
C3L C3M 1.375(10) ?
C1A C1B 1.368(8) ?
C1A C1F 1.388(7) ?
C1B C1C 1.389(8) ?
C1C C1D 1.365(8) ?
C1D C1E 1.356(9) ?
C1E C1F 1.376(8) ?
C1G C1H 1.377(7) ?
C1G C1M 1.390(8) ?
C1H C1I 1.381(7) ?
C1I C1K 1.369(8) ?
C1K C1L 1.363(9) ?
C1L C1M 1.386(8) ?
C4A C4F 1.373(9) ?
C4A C4B 1.381(8) ?
C4B C4C 1.367(10) ?
C4C C4D 1.337(10) ?
C4D C4E 1.381(11) ?
C4E C4F 1.384(10) ?
C4G C4H 1.365(8) ?
C4G C4M 1.371(8) ?
C4H C4I 1.384(9) ?
C4I C4K 1.343(9) ?
C4K C4L 1.352(10) ?
C4L C4M 1.389(9) ?
C2A C2B 1.386(7) ?
C2A C2F 1.386(7) ?
C2B C2C 1.377(8) ?
C2C C2D 1.373(8) ?
C2D C2E 1.362(8) ?
C2E C2F 1.386(8) ?
C2G C2H 1.393(8) ?
C2G C2M 1.397(8) ?
C2H C2I 1.379(8) ?
C2I C2K 1.364(9) ?
C2K C2L 1.372(10) ?
C2L C2M 1.371(8) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
P4 Mo2 Mo1 P3 13.37(6) y
P2 Mo2 Mo1 P1 15.27(5) y
Cl3 Mo2 Mo1 Cl1 10.65(6) y
Cl4 Mo2 Mo1 Cl2 18.26(6) y
