#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:29:29 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179380 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/77/4327756.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4327756
loop_
_publ_author_name
'Pavlo Solokha'
'Serena De Negri'
'Monika Skrobanska'
'Adriana Saccone'
'Volodymyr Pavlyuk'
'Davide M. Proserpio'
_publ_section_title
;
 New Ternary Germanides La4Mg5Ge6 and La4Mg7Ge6: Crystal Structure and
 Chemical Bonding
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              207
_journal_page_last               214
_journal_paper_doi               10.1021/ic2014732
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'Ge6 La4 Mg5'
_chemical_formula_sum            'Ge6 La4 Mg5'
_chemical_formula_weight         1112.73
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           36
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'C 2c -2'
_symmetry_space_group_name_H-M   'C m c 21'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   4.5030(7)
_cell_length_b                   20.085(3)
_cell_length_c                   16.207(3)
_cell_measurement_temperature    296(2)
_cell_volume                     1465.8(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_sigmaI/netI    0.0297
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            9328
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.39
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    23.661
_exptl_crystal_density_diffrn    5.042
_exptl_crystal_F_000             1920
_refine_diff_density_max         1.730
_refine_diff_density_min         -0.834
_refine_diff_density_rms         0.196
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.49(3)
_refine_ls_extinction_coef       0.00003(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_matrix_type           full
_refine_ls_number_parameters     93
_refine_ls_number_reflns         1470
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0202
_refine_ls_R_factor_gt           0.0192
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0246P)²+0.2105P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0451
_refine_ls_wR_factor_ref         0.0455
_reflns_number_gt                1431
_reflns_number_total             1470
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic2014732_si_001.cif
_cod_data_source_block           la4mg5ge6
_cod_database_code               4327756
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x, -y, z+1/2'
'-x, y, z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
La1 La 0.0000 0.01407(4) 0.26386(4) 0.01031(17) Uani 1 2 d S
La2 La 0.0000 0.03174(3) 0.00121(5) 0.00940(16) Uani 1 2 d S
La3 La 0.0000 0.16623(4) 0.46131(4) 0.00943(17) Uani 1 2 d S
La4 La 0.0000 0.17532(4) 0.82109(4) 0.00967(18) Uani 1 2 d S
Ge1 Ge 0.0000 0.11321(6) 0.64388(10) 0.0103(2) Uani 1 2 d S
Ge2 Ge 0.0000 0.22442(7) 0.28371(8) 0.0097(3) Uani 1 2 d S
Ge3 Ge 0.0000 0.23000(6) 0.00000(9) 0.0095(3) Uani 1 2 d S
Ge4 Ge 0.0000 0.43406(7) 0.36541(9) 0.0097(3) Uani 1 2 d S
Ge5 Ge 0.0000 0.55554(7) 0.41274(9) 0.0102(3) Uani 1 2 d S
Ge6 Ge 0.0000 0.57176(6) 0.13771(10) 0.0091(2) Uani 1 2 d S
Mg1 Mg 0.0000 0.15518(18) 0.1405(3) 0.0126(7) Uani 1 2 d S
Mg2 Mg 0.0000 0.30125(18) 0.1438(3) 0.0144(8) Uani 1 2 d S
Mg3 Mg 0.0000 0.34066(19) 0.4987(3) 0.0103(9) Uani 1 2 d S
Mg4 Mg 0.0000 0.4414(2) 0.0970(3) 0.0173(9) Uani 1 2 d S
Mg5 Mg 0.0000 0.6499(2) 0.2834(3) 0.0133(10) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 La1 Ge4 84.96(4) 2_554 5_545
Ge1 La1 Ge4 84.96(4) 2_554 5_445
Ge4 La1 Ge4 88.77(4) 5_545 5_445
Ge1 La1 Ge6 84.44(3) 2_554 5_445
Ge4 La1 Ge6 169.38(4) 5_545 5_445
Ge4 La1 Ge6 90.86(2) 5_445 5_445
Ge1 La1 Ge6 84.44(3) 2_554 5_545
Ge4 La1 Ge6 90.86(2) 5_545 5_545
Ge4 La1 Ge6 169.38(4) 5_445 5_545
Ge6 La1 Ge6 87.55(4) 5_445 5_545
Ge1 La1 Ge5 128.60(3) 2_554 5_545
Ge4 La1 Ge5 45.33(3) 5_545 5_545
Ge4 La1 Ge5 102.85(4) 5_445 5_545
Ge6 La1 Ge5 144.67(4) 5_445 5_545
Ge6 La1 Ge5 84.30(3) 5_545 5_545
Ge1 La1 Ge5 128.60(3) 2_554 5_445
Ge4 La1 Ge5 102.85(4) 5_545 5_445
Ge4 La1 Ge5 45.33(3) 5_445 5_445
Ge6 La1 Ge5 84.30(3) 5_445 5_445
Ge6 La1 Ge5 144.67(4) 5_545 5_445
Ge5 La1 Ge5 82.83(4) 5_545 5_445
Ge1 La1 Mg1 107.53(9) 2_554 .
Ge4 La1 Mg1 134.65(2) 5_545 .
Ge4 La1 Mg1 134.65(2) 5_445 .
Ge6 La1 Mg1 49.23(4) 5_445 .
Ge6 La1 Mg1 49.23(4) 5_545 .
Ge5 La1 Mg1 102.05(6) 5_545 .
Ge5 La1 Mg1 102.05(6) 5_445 .
Ge1 La1 Mg5 131.72(6) 2_554 5_545
Ge4 La1 Mg5 83.95(6) 5_545 5_545
Ge4 La1 Mg5 141.39(8) 5_445 5_545
Ge6 La1 Mg5 102.77(7) 5_445 5_545
Ge6 La1 Mg5 49.00(7) 5_545 5_545
Ge5 La1 Mg5 47.89(8) 5_545 5_545
Ge5 La1 Mg5 99.68(7) 5_445 5_545
Mg1 La1 Mg5 54.81(9) . 5_545
Ge1 La1 Mg5 131.72(6) 2_554 5_445
Ge4 La1 Mg5 141.39(8) 5_545 5_445
Ge4 La1 Mg5 83.95(6) 5_445 5_445
Ge6 La1 Mg5 49.00(7) 5_445 5_445
Ge6 La1 Mg5 102.77(7) 5_545 5_445
Ge5 La1 Mg5 99.68(7) 5_545 5_445
Ge5 La1 Mg5 47.89(8) 5_445 5_445
Mg1 La1 Mg5 54.81(8) . 5_445
Mg5 La1 Mg5 78.68(10) 5_545 5_445
Ge1 La1 Mg4 42.71(5) 2_554 5_445
Ge4 La1 Mg4 125.80(7) 5_545 5_445
Ge4 La1 Mg4 76.00(6) 5_445 5_445
Ge6 La1 Mg4 44.08(6) 5_445 5_445
Ge6 La1 Mg4 95.71(6) 5_545 5_445
Ge5 La1 Mg4 171.08(6) 5_545 5_445
Ge5 La1 Mg4 101.89(4) 5_445 5_445
Mg1 La1 Mg4 84.49(9) . 5_445
Mg5 La1 Mg4 137.09(10) 5_545 5_445
Mg5 La1 Mg4 89.03(8) 5_445 5_445
Ge1 La1 Mg4 42.71(5) 2_554 5_545
Ge4 La1 Mg4 76.00(6) 5_545 5_545
Ge4 La1 Mg4 125.80(7) 5_445 5_545
Ge6 La1 Mg4 95.71(6) 5_445 5_545
Ge6 La1 Mg4 44.08(6) 5_545 5_545
Ge5 La1 Mg4 101.89(4) 5_545 5_545
Ge5 La1 Mg4 171.08(6) 5_445 5_545
Mg1 La1 Mg4 84.49(9) . 5_545
Mg5 La1 Mg4 89.03(8) 5_545 5_545
Mg5 La1 Mg4 137.09(10) 5_445 5_545
Mg4 La1 Mg4 72.46(8) 5_445 5_545
Ge5 La2 Ge5 89.66(4) 6_454 6_554
Ge5 La2 Ge4 46.98(3) 6_454 6_454
Ge5 La2 Ge4 107.63(4) 6_554 6_454
Ge5 La2 Ge4 107.63(4) 6_454 6_554
Ge5 La2 Ge4 46.98(3) 6_554 6_554
Ge4 La2 Ge4 88.64(4) 6_454 6_554
Ge5 La2 Ge6 158.09(4) 6_454 5_545
Ge5 La2 Ge6 87.31(3) 6_554 5_545
Ge4 La2 Ge6 153.41(4) 6_454 5_545
Ge4 La2 Ge6 85.89(3) 6_554 5_545
Ge5 La2 Ge6 87.31(3) 6_454 5_445
Ge5 La2 Ge6 158.09(4) 6_554 5_445
Ge4 La2 Ge6 85.89(3) 6_454 5_445
Ge4 La2 Ge6 153.41(4) 6_554 5_445
Ge6 La2 Ge6 87.46(4) 5_545 5_445
Ge5 La2 Mg4 54.92(7) 6_454 5_445
Ge5 La2 Mg4 113.11(7) 6_554 5_445
Ge4 La2 Mg4 87.81(6) 6_454 5_445
Ge4 La2 Mg4 156.95(8) 6_554 5_445
Ge6 La2 Mg4 106.81(7) 5_545 5_445
Ge6 La2 Mg4 48.78(7) 5_445 5_445
Ge5 La2 Mg4 113.11(7) 6_454 5_545
Ge5 La2 Mg4 54.92(7) 6_554 5_545
Ge4 La2 Mg4 156.95(8) 6_454 5_545
Ge4 La2 Mg4 87.81(6) 6_554 5_545
Ge6 La2 Mg4 48.78(7) 5_545 5_545
Ge6 La2 Mg4 106.81(7) 5_445 5_545
Mg4 La2 Mg4 86.61(10) 5_445 5_545
Ge5 La2 Mg1 135.09(2) 6_454 .
Ge5 La2 Mg1 135.09(2) 6_554 .
Ge4 La2 Mg1 107.58(6) 6_454 .
Ge4 La2 Mg1 107.58(6) 6_554 .
Ge6 La2 Mg1 50.23(4) 5_545 .
Ge6 La2 Mg1 50.23(4) 5_445 .
Mg4 La2 Mg1 95.19(9) 5_445 .
Mg4 La2 Mg1 95.19(9) 5_545 .
Ge5 La2 Mg3 150.72(9) 6_454 6_554
Ge5 La2 Mg3 86.65(6) 6_554 6_554
Ge4 La2 Mg3 107.02(7) 6_454 6_554
Ge4 La2 Mg3 50.99(8) 6_554 6_554
Ge6 La2 Mg3 50.70(8) 5_545 6_554
Ge6 La2 Mg3 106.20(8) 5_445 6_554
Mg4 La2 Mg3 150.90(11) 5_445 6_554
Mg4 La2 Mg3 88.19(8) 5_545 6_554
Mg1 La2 Mg3 56.81(9) . 6_554
Ge5 La2 Mg3 86.65(6) 6_454 6_454
Ge5 La2 Mg3 150.72(9) 6_554 6_454
Ge4 La2 Mg3 50.99(8) 6_454 6_454
Ge4 La2 Mg3 107.02(7) 6_554 6_454
Ge6 La2 Mg3 106.20(8) 5_545 6_454
Ge6 La2 Mg3 50.70(8) 5_445 6_454
Mg4 La2 Mg3 88.19(8) 5_445 6_454
Mg4 La2 Mg3 150.90(11) 5_545 6_454
Mg1 La2 Mg3 56.81(9) . 6_454
Mg3 La2 Mg3 82.59(9) 6_554 6_454
Ge5 La2 La1 55.64(3) 6_454 2_554
Ge5 La2 La1 55.64(3) 6_554 2_554
Ge4 La2 La1 52.07(3) 6_454 2_554
Ge4 La2 La1 52.07(3) 6_554 2_554
Ge6 La2 La1 135.89(2) 5_545 2_554
Ge6 La2 La1 135.89(2) 5_445 2_554
Mg4 La2 La1 109.36(8) 5_445 2_554
Mg4 La2 La1 109.36(8) 5_545 2_554
Mg1 La2 La1 145.76(8) . 2_554
Mg3 La2 La1 99.38(9) 6_554 2_554
Mg3 La2 La1 99.38(9) 6_454 2_554
Ge2 La3 Ge3 86.28(4) . 6
Ge2 La3 Ge3 86.28(4) . 6_455
Ge3 La3 Ge3 91.94(4) 6 6_455
Ge2 La3 Ge1 177.70(5) . .
Ge3 La3 Ge1 92.12(4) 6 .
Ge3 La3 Ge1 92.12(4) 6_455 .
Ge2 La3 Ge5 91.88(4) . 5_445
Ge3 La3 Ge5 176.98(4) 6 5_445
Ge3 La3 Ge5 90.33(3) 6_455 5_445
Ge1 La3 Ge5 89.79(4) . 5_445
Ge2 La3 Ge5 91.88(4) . 5_545
Ge3 La3 Ge5 90.33(3) 6 5_545
Ge3 La3 Ge5 176.98(4) 6_455 5_545
Ge1 La3 Ge5 89.79(4) . 5_545
Ge5 La3 Ge5 87.34(4) 5_445 5_545
Ge2 La3 Mg3 77.70(9) . .
Ge3 La3 Mg3 46.38(2) 6 .
Ge3 La3 Mg3 46.38(2) 6_455 .
Ge1 La3 Mg3 99.99(9) . .
Ge5 La3 Mg3 135.48(2) 5_445 .
Ge5 La3 Mg3 135.48(2) 5_545 .
Ge2 La3 Mg5 46.07(6) . 5_445
Ge3 La3 Mg5 131.10(7) 6 5_445
Ge3 La3 Mg5 77.05(6) 6_455 5_445
Ge1 La3 Mg5 135.11(6) . 5_445
Ge5 La3 Mg5 47.65(7) 5_445 5_445
Ge5 La3 Mg5 99.96(7) 5_545 5_445
Mg3 La3 Mg5 102.80(10) . 5_445
Ge2 La3 Mg5 46.07(6) . 5_545
Ge3 La3 Mg5 77.05(6) 6 5_545
Ge3 La3 Mg5 131.10(7) 6_455 5_545
Ge1 La3 Mg5 135.11(6) . 5_545
Ge5 La3 Mg5 99.96(7) 5_445 5_545
Ge5 La3 Mg5 47.65(7) 5_545 5_545
Mg3 La3 Mg5 102.80(10) . 5_545
Mg5 La3 Mg5 75.61(9) 5_445 5_545
Ge2 La3 Mg2 131.38(6) . 6
Ge3 La3 Mg2 45.49(6) 6 6
Ge3 La3 Mg2 99.02(6) 6_455 6
Ge1 La3 Mg2 47.25(6) . 6
Ge5 La3 Mg2 135.98(7) 5_445 6
Ge5 La3 Mg2 83.99(5) 5_545 6
Mg3 La3 Mg2 72.31(8) . 6
Mg5 La3 Mg2 175.10(9) 5_445 6
Mg5 La3 Mg2 105.37(6) 5_545 6
Ge2 La3 Mg2 131.38(6) . 6_455
Ge3 La3 Mg2 99.02(6) 6 6_455
Ge3 La3 Mg2 45.49(6) 6_455 6_455
Ge1 La3 Mg2 47.25(6) . 6_455
Ge5 La3 Mg2 83.99(5) 5_445 6_455
Ge5 La3 Mg2 135.98(7) 5_545 6_455
Mg3 La3 Mg2 72.31(8) . 6_455
Mg5 La3 Mg2 105.37(6) 5_445 6_455
Mg5 La3 Mg2 175.10(9) 5_545 6_455
Mg2 La3 Mg2 73.24(10) 6 6_455
Ge2 La3 Mg4 138.30(5) . 6
Ge3 La3 Mg4 80.64(5) 6 6
Ge3 La3 Mg4 133.27(7) 6_455 6
Ge1 La3 Mg4 42.80(5) . 6
Ge5 La3 Mg4 99.22(6) 5_445 6
Ge5 La3 Mg4 49.15(6) 5_545 6
Mg3 La3 Mg4 117.37(9) . 6
Mg5 La3 Mg4 139.75(10) 5_445 6
Mg5 La3 Mg4 92.31(8) 5_545 6
Mg2 La3 Mg4 45.15(8) 6 6
Mg2 La3 Mg4 89.90(8) 6_455 6
Ge2 La4 Ge2 93.91(4) 6 6_455
Ge2 La4 Ge3 87.27(3) 6 1_556
Ge2 La4 Ge3 87.27(3) 6_455 1_556
Ge2 La4 Ge1 94.59(4) 6 .
Ge2 La4 Ge1 94.59(4) 6_455 .
Ge3 La4 Ge1 177.27(4) 1_556 .
Ge2 La4 Ge4 177.13(4) 6 6_455
Ge2 La4 Ge4 88.79(3) 6_455 6_455
Ge3 La4 Ge4 91.89(4) 1_556 6_455
Ge1 La4 Ge4 86.16(4) . 6_455
Ge2 La4 Ge4 88.79(3) 6 6
Ge2 La4 Ge4 177.13(3) 6_455 6
Ge3 La4 Ge4 91.89(4) 1_556 6
Ge1 La4 Ge4 86.16(4) . 6
Ge4 La4 Ge4 88.50(4) 6_455 6
Ge2 La4 Mg5 47.34(2) 6 2_565
Ge2 La4 Mg5 47.34(2) 6_455 2_565
Ge3 La4 Mg5 79.13(8) 1_556 2_565
Ge1 La4 Mg5 103.60(8) . 2_565
Ge4 La4 Mg5 135.15(2) 6_455 2_565
Ge4 La4 Mg5 135.15(2) 6 2_565
Ge2 La4 Mg3 76.28(6) 6 6
Ge2 La4 Mg3 131.30(7) 6_455 6
Ge3 La4 Mg3 45.35(6) 1_556 6
Ge1 La4 Mg3 133.22(6) . 6
Ge4 La4 Mg3 101.19(6) 6_455 6
Ge4 La4 Mg3 48.51(7) 6 6
Mg5 La4 Mg3 102.75(9) 2_565 6
Ge2 La4 Mg3 131.30(7) 6 6_455
Ge2 La4 Mg3 76.28(6) 6_455 6_455
Ge3 La4 Mg3 45.35(6) 1_556 6_455
Ge1 La4 Mg3 133.22(6) . 6_455
Ge4 La4 Mg3 48.51(7) 6_455 6_455
Ge4 La4 Mg3 101.19(6) 6 6_455
Mg5 La4 Mg3 102.75(9) 2_565 6_455
Mg3 La4 Mg3 75.73(10) 6 6_455
Ge2 La4 Mg2 102.12(6) 6 6_455
Ge2 La4 Mg2 46.83(6) 6_455 6_455
Ge3 La4 Mg2 133.21(6) 1_556 6_455
Ge1 La4 Mg2 48.31(6) . 6_455
Ge4 La4 Mg2 80.44(6) 6_455 6_455
Ge4 La4 Mg2 133.45(7) 6 6_455
Mg5 La4 Mg2 74.94(8) 2_565 6_455
Mg3 La4 Mg2 177.67(9) 6 6_455
Mg3 La4 Mg2 104.36(6) 6_455 6_455
Ge2 La4 Mg2 46.83(6) 6 6
Ge2 La4 Mg2 102.12(6) 6_455 6
Ge3 La4 Mg2 133.21(6) 1_556 6
Ge1 La4 Mg2 48.31(6) . 6
Ge4 La4 Mg2 133.45(7) 6_455 6
Ge4 La4 Mg2 80.44(5) 6 6
Mg5 La4 Mg2 74.94(8) 2_565 6
Mg3 La4 Mg2 104.36(6) 6 6
Mg3 La4 Mg2 177.67(9) 6_455 6
Mg2 La4 Mg2 75.44(10) 6_455 6
Ge2 La4 La1 126.05(3) 6 2
Ge2 La4 La1 126.05(3) 6_455 2
Ge3 La4 La1 124.45(3) 1_556 2
Ge1 La4 La1 52.82(3) . 2
Ge4 La4 La1 52.50(2) 6_455 2
Ge4 La4 La1 52.50(2) 6 2
Mg5 La4 La1 156.42(8) 2_565 2
Mg3 La4 La1 95.79(6) 6 2
Mg3 La4 La1 95.79(6) 6_455 2
Mg2 La4 La1 86.52(6) 6_455 2
Mg2 La4 La1 86.52(6) 6 2
Mg4 Ge1 Mg4 118.72(17) 6_455 6
Mg4 Ge1 Mg2 159.73(16) 6_455 6
Mg4 Ge1 Mg2 64.54(10) 6 6
Mg4 Ge1 Mg2 64.54(10) 6_455 6_455
Mg4 Ge1 Mg2 159.73(16) 6 6_455
Mg2 Ge1 Mg2 105.31(12) 6 6_455
Mg4 Ge1 La4 115.66(10) 6_455 .
Mg4 Ge1 La4 115.66(10) 6 .
Mg2 Ge1 La4 76.03(11) 6 .
Mg2 Ge1 La4 76.03(11) 6_455 .
Mg4 Ge1 La3 82.46(11) 6_455 .
Mg4 Ge1 La3 82.46(11) 6 .
Mg2 Ge1 La3 78.13(11) 6 .
Mg2 Ge1 La3 78.13(11) 6_455 .
La4 Ge1 La3 136.73(4) . .
Mg4 Ge1 La1 80.92(10) 6_455 2
Mg4 Ge1 La1 80.92(10) 6 2
Mg2 Ge1 La1 118.88(9) 6 2
Mg2 Ge1 La1 118.88(9) 6_455 2
La4 Ge1 La1 76.22(4) . 2
La3 Ge1 La1 147.05(5) . 2
Mg5 Ge2 Mg5 112.78(18) 5_445 5_545
Mg5 Ge2 Mg1 73.38(11) 5_445 .
Mg5 Ge2 Mg1 73.38(11) 5_545 .
Mg5 Ge2 Mg2 108.06(11) 5_445 .
Mg5 Ge2 Mg2 108.06(11) 5_545 .
Mg1 Ge2 Mg2 65.16(13) . .
Mg5 Ge2 La4 166.12(10) 5_445 6_554
Mg5 Ge2 La4 75.73(9) 5_545 6_554
Mg1 Ge2 La4 120.30(6) . 6_554
Mg2 Ge2 La4 78.16(7) . 6_554
Mg5 Ge2 La4 75.73(9) 5_445 6_454
Mg5 Ge2 La4 166.12(10) 5_545 6_454
Mg1 Ge2 La4 120.30(6) . 6_454
Mg2 Ge2 La4 78.16(7) . 6_454
La4 Ge2 La4 93.91(4) 6_554 6_454
Mg5 Ge2 La3 78.08(10) 5_445 .
Mg5 Ge2 La3 78.08(10) 5_545 .
Mg1 Ge2 La3 126.98(11) . .
Mg2 Ge2 La3 167.86(10) . .
La4 Ge2 La3 93.65(4) 6_554 .
La4 Ge2 La3 93.65(4) 6_454 .
Mg3 Ge3 Mg3 115.55(15) 6_454 6_554
Mg3 Ge3 Mg1 73.33(11) 6_454 .
Mg3 Ge3 Mg1 73.33(11) 6_554 .
Mg3 Ge3 Mg2 106.61(12) 6_454 .
Mg3 Ge3 Mg2 106.61(12) 6_554 .
Mg1 Ge3 Mg2 64.97(12) . .
Mg3 Ge3 La4 78.67(11) 6_454 1_554
Mg3 Ge3 La4 78.67(11) 6_554 1_554
Mg1 Ge3 La4 125.82(10) . 1_554
Mg2 Ge3 La4 169.20(10) . 1_554
Mg3 Ge3 La3 164.04(11) 6_454 6_554
Mg3 Ge3 La3 75.23(7) 6_554 6_554
Mg1 Ge3 La3 122.26(5) . 6_554
Mg2 Ge3 La3 79.77(7) . 6_554
La4 Ge3 La3 92.78(4) 1_554 6_554
Mg3 Ge3 La3 75.23(7) 6_454 6_454
Mg3 Ge3 La3 164.04(11) 6_554 6_454
Mg1 Ge3 La3 122.26(5) . 6_454
Mg2 Ge3 La3 79.77(7) . 6_454
La4 Ge3 La3 92.78(4) 1_554 6_454
La3 Ge3 La3 91.94(4) 6_554 6_454
Ge5 Ge4 Mg3 113.53(10) . .
Ge5 Ge4 La1 71.16(3) . 5
Mg3 Ge4 La1 135.52(2) . 5
Ge5 Ge4 La1 71.16(3) . 5_455
Mg3 Ge4 La1 135.52(2) . 5_455
La1 Ge4 La1 88.77(4) 5 5_455
Ge5 Ge4 La2 65.91(3) . 6
Mg3 Ge4 La2 67.93(7) . 6
La1 Ge4 La2 75.76(2) 5 6
La1 Ge4 La2 137.01(5) 5_455 6
Ge5 Ge4 La2 65.91(3) . 6_455
Mg3 Ge4 La2 67.93(7) . 6_455
La1 Ge4 La2 137.01(5) 5 6_455
La1 Ge4 La2 75.76(2) 5_455 6_455
La2 Ge4 La2 88.64(4) 6 6_455
Ge5 Ge4 La4 135.75(2) . 6_454
Mg3 Ge4 La4 73.83(7) . 6_454
La1 Ge4 La4 135.58(5) 5 6_454
La1 Ge4 La4 74.81(3) 5_455 6_454
La2 Ge4 La4 141.69(5) 6 6_454
La2 Ge4 La4 79.03(2) 6_455 6_454
Ge5 Ge4 La4 135.75(2) . 6_554
Mg3 Ge4 La4 73.83(7) . 6_554
La1 Ge4 La4 74.81(3) 5 6_554
La1 Ge4 La4 135.58(5) 5_455 6_554
La2 Ge4 La4 79.03(2) 6 6_554
La2 Ge4 La4 141.69(5) 6_455 6_554
La4 Ge4 La4 88.50(4) 6_454 6_554
Ge4 Ge5 Mg5 114.67(10) . .
Ge4 Ge5 Mg4 108.64(10) . 2_565
Mg5 Ge5 Mg4 136.69(14) . 2_565
Ge4 Ge5 La2 67.11(3) . 6_455
Mg5 Ge5 La2 134.52(3) . 6_455
Mg4 Ge5 La2 64.06(6) 2_565 6_455
Ge4 Ge5 La2 67.11(3) . 6
Mg5 Ge5 La2 134.52(3) . 6
Mg4 Ge5 La2 64.06(6) 2_565 6
La2 Ge5 La2 89.66(4) 6_455 6
Ge4 Ge5 La3 136.292(19) . 5
Mg5 Ge5 La3 73.84(7) . 5
Mg4 Ge5 La3 75.20(7) 2_565 5
La2 Ge5 La3 138.83(5) 6_455 5
La2 Ge5 La3 77.24(2) 6 5
Ge4 Ge5 La3 136.292(19) . 5_455
Mg5 Ge5 La3 73.84(7) . 5_455
Mg4 Ge5 La3 75.20(7) 2_565 5_455
La2 Ge5 La3 77.24(2) 6_455 5_455
La2 Ge5 La3 138.83(5) 6 5_455
La3 Ge5 La3 87.34(4) 5 5_455
Ge4 Ge5 La1 63.51(3) . 5_455
Mg5 Ge5 La1 68.79(7) . 5_455
Mg4 Ge5 La1 135.55(4) 2_565 5_455
La2 Ge5 La1 73.60(2) 6_455 5_455
La2 Ge5 La1 130.57(5) 6 5_455
La3 Ge5 La1 142.63(5) 5 5_455
La3 Ge5 La1 83.18(2) 5_455 5_455
Ge4 Ge5 La1 63.51(3) . 5
Mg5 Ge5 La1 68.79(7) . 5
Mg4 Ge5 La1 135.55(4) 2_565 5
La2 Ge5 La1 130.57(5) 6_455 5
La2 Ge5 La1 73.60(2) 6 5
La3 Ge5 La1 83.18(2) 5 5
La3 Ge5 La1 142.63(5) 5_455 5
La1 Ge5 La1 82.83(4) 5_455 5
Mg4 Ge6 Mg1 125.64(7) . 5
Mg4 Ge6 Mg1 125.64(7) . 5_455
Mg1 Ge6 Mg1 106.67(12) 5 5_455
Mg4 Ge6 Mg5 137.75(13) . .
Mg1 Ge6 Mg5 69.90(12) 5 .
Mg1 Ge6 Mg5 69.90(12) 5_455 .
Mg4 Ge6 Mg3 113.84(13) . 2_564
Mg1 Ge6 Mg3 69.22(11) 5 2_564
Mg1 Ge6 Mg3 69.22(11) 5_455 2_564
Mg5 Ge6 Mg3 108.41(11) . 2_564
Mg4 Ge6 La1 78.94(7) . 5
Mg1 Ge6 La1 69.37(9) 5 5
Mg1 Ge6 La1 139.24(12) 5_455 5
Mg5 Ge6 La1 70.97(7) . 5
Mg3 Ge6 La1 135.58(2) 2_564 5
Mg4 Ge6 La1 78.94(7) . 5_455
Mg1 Ge6 La1 139.24(12) 5 5_455
Mg1 Ge6 La1 69.37(9) 5_455 5_455
Mg5 Ge6 La1 70.97(7) . 5_455
Mg3 Ge6 La1 135.58(2) 2_564 5_455
La1 Ge6 La1 87.55(4) 5 5_455
Mg4 Ge6 La2 66.10(6) . 5_455
Mg1 Ge6 La2 135.44(12) 5 5_455
Mg1 Ge6 La2 66.65(9) 5_455 5_455
Mg5 Ge6 La2 134.61(3) . 5_455
Mg3 Ge6 La2 67.45(6) 2_564 5_455
La1 Ge6 La2 144.79(4) 5 5_455
La1 Ge6 La2 81.99(2) 5_455 5_455
Mg4 Ge6 La2 66.10(6) . 5
Mg1 Ge6 La2 66.65(9) 5 5
Mg1 Ge6 La2 135.44(12) 5_455 5
Mg5 Ge6 La2 134.61(3) . 5
Mg3 Ge6 La2 67.45(6) 2_564 5
La1 Ge6 La2 81.99(2) 5 5
La1 Ge6 La2 144.79(4) 5_455 5
La2 Ge6 La2 87.46(4) 5_455 5
Ge2 Mg1 Ge3 115.65(13) . .
Ge2 Mg1 Ge6 108.68(14) . 5_445
Ge3 Mg1 Ge6 108.40(14) . 5_445
Ge2 Mg1 Ge6 108.68(14) . 5_545
Ge3 Mg1 Ge6 108.40(14) . 5_545
Ge6 Mg1 Ge6 106.67(12) 5_445 5_545
Ge2 Mg1 Mg2 58.01(13) . .
Ge3 Mg1 Mg2 57.64(13) . .
Ge6 Mg1 Mg2 126.66(6) 5_445 .
Ge6 Mg1 Mg2 126.66(6) 5_545 .
Ge2 Mg1 Mg3 126.82(10) . 6_454
Ge3 Mg1 Mg3 52.39(10) . 6_454
Ge6 Mg1 Mg3 56.15(9) 5_445 6_454
Ge6 Mg1 Mg3 124.43(18) 5_545 6_454
Mg2 Mg1 Mg3 89.28(14) . 6_454
Ge2 Mg1 Mg3 126.82(10) . 6_554
Ge3 Mg1 Mg3 52.39(10) . 6_554
Ge6 Mg1 Mg3 124.43(18) 5_445 6_554
Ge6 Mg1 Mg3 56.15(9) 5_545 6_554
Mg2 Mg1 Mg3 89.28(14) . 6_554
Mg3 Mg1 Mg3 88.79(18) 6_454 6_554
Ge2 Mg1 Mg5 53.27(11) . 5_545
Ge3 Mg1 Mg5 128.04(11) . 5_545
Ge6 Mg1 Mg5 123.40(19) 5_445 5_545
Ge6 Mg1 Mg5 55.46(9) 5_545 5_545
Mg2 Mg1 Mg5 91.11(15) . 5_545
Mg3 Mg1 Mg5 179.55(18) 6_454 5_545
Mg3 Mg1 Mg5 91.45(6) 6_554 5_545
Ge2 Mg1 Mg5 53.27(11) . 5_445
Ge3 Mg1 Mg5 128.04(11) . 5_445
Ge6 Mg1 Mg5 55.46(9) 5_445 5_445
Ge6 Mg1 Mg5 123.40(19) 5_545 5_445
Mg2 Mg1 Mg5 91.11(15) . 5_445
Mg3 Mg1 Mg5 91.45(6) 6_454 5_445
Mg3 Mg1 Mg5 179.55(18) 6_554 5_445
Mg5 Mg1 Mg5 88.30(18) 5_545 5_445
Ge2 Mg1 La2 163.23(17) . .
Ge3 Mg1 La2 81.12(14) . .
Ge6 Mg1 La2 63.12(8) 5_445 .
Ge6 Mg1 La2 63.12(8) 5_545 .
Mg2 Mg1 La2 138.8(2) . .
Mg3 Mg1 La2 62.52(11) 6_454 .
Mg3 Mg1 La2 62.52(11) 6_554 .
Mg5 Mg1 La2 117.27(11) 5_545 .
Mg5 Mg1 La2 117.27(11) 5_445 .
Ge2 Mg1 La1 85.71(14) . .
Ge3 Mg1 La1 158.64(17) . .
Ge6 Mg1 La1 61.41(8) 5_445 .
Ge6 Mg1 La1 61.41(8) 5_545 .
Mg2 Mg1 La1 143.7(2) . .
Mg3 Mg1 La1 115.65(10) 6_454 .
Mg3 Mg1 La1 115.65(10) 6_554 .
Mg5 Mg1 La1 63.89(12) 5_545 .
Mg5 Mg1 La1 63.89(12) 5_445 .
La2 Mg1 La1 77.52(8) . .
Ge3 Mg2 Ge2 114.21(13) . .
Ge3 Mg2 Ge1 108.51(13) . 6_554
Ge2 Mg2 Ge1 109.95(13) . 6_554
Ge3 Mg2 Ge1 108.51(13) . 6_454
Ge2 Mg2 Ge1 109.95(13) . 6_454
Ge1 Mg2 Ge1 105.31(12) 6_554 6_454
Ge3 Mg2 Mg4 106.46(18) . .
Ge2 Mg2 Mg4 139.33(19) . .
Ge1 Mg2 Mg4 54.15(7) 6_554 .
Ge1 Mg2 Mg4 54.15(7) 6_454 .
Ge3 Mg2 Mg1 57.38(13) . .
Ge2 Mg2 Mg1 56.83(13) . .
Ge1 Mg2 Mg1 127.34(6) 6_554 .
Ge1 Mg2 Mg1 127.34(6) 6_454 .
Mg4 Mg2 Mg1 163.8(2) . .
Ge3 Mg2 La4 137.07(6) . 6_554
Ge2 Mg2 La4 55.02(8) . 6_554
Ge1 Mg2 La4 55.66(7) 6_554 6_554
Ge1 Mg2 La4 114.12(14) 6_454 6_554
Mg4 Mg2 La4 94.57(11) . 6_554
Mg1 Mg2 La4 98.19(13) . 6_554
Ge3 Mg2 La4 137.07(6) . 6_454
Ge2 Mg2 La4 55.02(8) . 6_454
Ge1 Mg2 La4 114.12(14) 6_554 6_454
Ge1 Mg2 La4 55.66(7) 6_454 6_454
Mg4 Mg2 La4 94.57(11) . 6_454
Mg1 Mg2 La4 98.19(13) . 6_454
La4 Mg2 La4 75.44(10) 6_554 6_454
Ge3 Mg2 La3 54.73(8) . 6_454
Ge2 Mg2 La3 138.18(7) . 6_454
Ge1 Mg2 La3 111.68(14) 6_554 6_454
Ge1 Mg2 La3 54.62(7) 6_454 6_454
Mg4 Mg2 La3 68.22(10) . 6_454
Mg1 Mg2 La3 99.11(14) . 6_454
La4 Mg2 La3 162.67(11) 6_554 6_454
La4 Mg2 La3 102.99(3) 6_454 6_454
Ge3 Mg2 La3 54.73(8) . 6_554
Ge2 Mg2 La3 138.18(7) . 6_554
Ge1 Mg2 La3 54.62(7) 6_554 6_554
Ge1 Mg2 La3 111.68(14) 6_454 6_554
Mg4 Mg2 La3 68.22(10) . 6_554
Mg1 Mg2 La3 99.11(14) . 6_554
La4 Mg2 La3 102.99(3) 6_554 6_554
La4 Mg2 La3 162.67(11) 6_454 6_554
La3 Mg2 La3 73.24(10) 6_454 6_554
Ge3 Mg3 Ge3 115.55(15) 6_455 6
Ge3 Mg3 Ge6 108.76(12) 6_455 2_565
Ge3 Mg3 Ge6 108.76(12) 6 2_565
Ge3 Mg3 Ge4 110.85(12) 6_455 .
Ge3 Mg3 Ge4 110.85(12) 6 .
Ge6 Mg3 Ge4 101.05(13) 2_565 .
Ge3 Mg3 Mg1 126.86(18) 6_455 6
Ge3 Mg3 Mg1 54.28(9) 6 6
Ge6 Mg3 Mg1 54.63(10) 2_565 6
Ge4 Mg3 Mg1 121.47(11) . 6
Ge3 Mg3 Mg1 54.28(9) 6_455 6_455
Ge3 Mg3 Mg1 126.86(18) 6 6_455
Ge6 Mg3 Mg1 54.63(10) 2_565 6_455
Ge4 Mg3 Mg1 121.47(11) . 6_455
Mg1 Mg3 Mg1 88.79(18) 6 6_455
Ge3 Mg3 La2 163.48(12) 6_455 6
Ge3 Mg3 La2 80.92(4) 6 6
Ge6 Mg3 La2 61.85(7) 2_565 6
Ge4 Mg3 La2 61.09(7) . 6
Mg1 Mg3 La2 60.67(8) 6 6
Mg1 Mg3 La2 115.69(15) 6_455 6
Ge3 Mg3 La2 80.92(4) 6_455 6_455
Ge3 Mg3 La2 163.48(12) 6 6_455
Ge6 Mg3 La2 61.85(7) 2_565 6_455
Ge4 Mg3 La2 61.09(7) . 6_455
Mg1 Mg3 La2 115.69(15) 6 6_455
Mg1 Mg3 La2 60.67(8) 6_455 6_455
La2 Mg3 La2 82.59(9) 6 6_455
Ge3 Mg3 La3 58.40(8) 6_455 .
Ge3 Mg3 La3 58.40(8) 6 .
Ge6 Mg3 La3 137.78(16) 2_565 .
Ge4 Mg3 La3 121.18(16) . .
Mg1 Mg3 La3 98.46(11) 6 .
Mg1 Mg3 La3 98.46(11) 6_455 .
La2 Mg3 La3 137.93(5) 6 .
La2 Mg3 La3 137.93(5) 6_455 .
Ge3 Mg3 La4 55.98(7) 6_455 6_454
Ge3 Mg3 La4 118.62(15) 6 6_454
Ge6 Mg3 La4 132.24(8) 2_565 6_454
Ge4 Mg3 La4 57.66(8) . 6_454
Mg1 Mg3 La4 172.72(13) 6 6_454
Mg1 Mg3 La4 97.65(7) 6_455 6_454
La2 Mg3 La4 118.71(13) 6 6_454
La2 Mg3 La4 70.74(6) 6_455 6_454
La3 Mg3 La4 77.31(8) . 6_454
Ge3 Mg3 La4 118.62(15) 6_455 6_554
Ge3 Mg3 La4 55.98(7) 6 6_554
Ge6 Mg3 La4 132.24(8) 2_565 6_554
Ge4 Mg3 La4 57.66(8) . 6_554
Mg1 Mg3 La4 97.65(7) 6 6_554
Mg1 Mg3 La4 172.72(13) 6_455 6_554
La2 Mg3 La4 70.74(6) 6 6_554
La2 Mg3 La4 118.71(13) 6_455 6_554
La3 Mg3 La4 77.31(8) . 6_554
La4 Mg3 La4 75.73(10) 6_454 6_554
Ge1 Mg4 Ge1 118.72(17) 6_454 6_554
Ge1 Mg4 Ge6 109.60(11) 6_454 .
Ge1 Mg4 Ge6 109.60(11) 6_554 .
Ge1 Mg4 Mg2 61.31(8) 6_454 .
Ge1 Mg4 Mg2 61.31(8) 6_554 .
Ge6 Mg4 Mg2 150.78(19) . .
Ge1 Mg4 Ge5 107.39(11) 6_454 2_564
Ge1 Mg4 Ge5 107.39(11) 6_554 2_564
Ge6 Mg4 Ge5 102.94(14) . 2_564
Mg2 Mg4 Ge5 106.28(17) . 2_564
Ge1 Mg4 La2 163.55(14) 6_454 5
Ge1 Mg4 La2 77.22(4) 6_554 5
Ge6 Mg4 La2 65.12(8) . 5
Mg2 Mg4 La2 131.07(9) . 5
Ge5 Mg4 La2 61.02(7) 2_564 5
Ge1 Mg4 La2 77.22(4) 6_454 5_455
Ge1 Mg4 La2 163.55(14) 6_554 5_455
Ge6 Mg4 La2 65.12(8) . 5_455
Mg2 Mg4 La2 131.07(9) . 5_455
Ge5 Mg4 La2 61.02(7) 2_564 5_455
La2 Mg4 La2 86.61(10) 5 5_455
Ge1 Mg4 La1 117.59(15) 6_454 5
Ge1 Mg4 La1 56.37(7) 6_554 5
Ge6 Mg4 La1 56.98(7) . 5
Mg2 Mg4 La1 100.68(12) . 5
Ge5 Mg4 La1 134.56(9) 2_564 5
La2 Mg4 La1 73.65(5) 5 5
La2 Mg4 La1 121.95(12) 5_455 5
Ge1 Mg4 La1 56.37(7) 6_454 5_455
Ge1 Mg4 La1 117.59(15) 6_554 5_455
Ge6 Mg4 La1 56.98(7) . 5_455
Mg2 Mg4 La1 100.68(12) . 5_455
Ge5 Mg4 La1 134.56(9) 2_564 5_455
La2 Mg4 La1 121.95(12) 5 5_455
La2 Mg4 La1 73.65(5) 5_455 5_455
La1 Mg4 La1 72.46(8) 5 5_455
Ge1 Mg4 La3 54.74(7) 6_454 6_454
Ge1 Mg4 La3 115.94(14) 6_554 6_454
Ge6 Mg4 La3 133.60(9) . 6_454
Mg2 Mg4 La3 66.63(11) . 6_454
Ge5 Mg4 La3 55.65(7) 2_564 6_454
La2 Mg4 La3 116.42(12) 5 6_454
La2 Mg4 La3 68.65(5) 5_455 6_454
La1 Mg4 La3 167.00(13) 5 6_454
La1 Mg4 La3 106.10(2) 5_455 6_454
Ge1 Mg4 La3 115.94(14) 6_454 6_554
Ge1 Mg4 La3 54.74(7) 6_554 6_554
Ge6 Mg4 La3 133.60(9) . 6_554
Mg2 Mg4 La3 66.63(11) . 6_554
Ge5 Mg4 La3 55.65(7) 2_564 6_554
La2 Mg4 La3 68.65(5) 5 6_554
La2 Mg4 La3 116.42(12) 5_455 6_554
La1 Mg4 La3 106.10(2) 5 6_554
La1 Mg4 La3 167.00(13) 5_455 6_554
La3 Mg4 La3 72.27(8) 6_454 6_554
Ge2 Mg5 Ge2 112.78(18) 5 5_455
Ge2 Mg5 Ge5 111.71(11) 5 .
Ge2 Mg5 Ge5 111.71(11) 5_455 .
Ge2 Mg5 Ge6 107.94(11) 5 .
Ge2 Mg5 Ge6 107.94(11) 5_455 .
Ge5 Mg5 Ge6 104.26(15) . .
Ge2 Mg5 Mg1 124.28(18) 5 5_455
Ge2 Mg5 Mg1 53.35(9) 5_455 5_455
Ge5 Mg5 Mg1 123.61(13) . 5_455
Ge6 Mg5 Mg1 54.64(9) . 5_455
Ge2 Mg5 Mg1 53.35(9) 5 5
Ge2 Mg5 Mg1 124.28(18) 5_455 5
Ge5 Mg5 Mg1 123.61(13) . 5
Ge6 Mg5 Mg1 54.64(9) . 5
Mg1 Mg5 Mg1 88.30(18) 5_455 5
Ge2 Mg5 La1 162.43(14) 5 5_455
Ge2 Mg5 La1 84.11(5) 5_455 5_455
Ge5 Mg5 La1 63.31(8) . 5_455
Ge6 Mg5 La1 60.03(8) . 5_455
Mg1 Mg5 La1 61.29(8) 5_455 5_455
Mg1 Mg5 La1 113.75(14) 5 5_455
Ge2 Mg5 La1 84.11(5) 5 5
Ge2 Mg5 La1 162.43(14) 5_455 5
Ge5 Mg5 La1 63.31(8) . 5
Ge6 Mg5 La1 60.03(8) . 5
Mg1 Mg5 La1 113.75(14) 5_455 5
Mg1 Mg5 La1 61.29(8) 5 5
La1 Mg5 La1 78.68(10) 5_455 5
Ge2 Mg5 La4 56.93(9) 5 2_564
Ge2 Mg5 La4 56.93(9) 5_455 2_564
Ge5 Mg5 La4 122.25(15) . 2_564
Ge6 Mg5 La4 133.49(16) . 2_564
Mg1 Mg5 La4 95.20(13) 5_455 2_564
Mg1 Mg5 La4 95.20(13) 5 2_564
La1 Mg5 La4 140.55(5) 5_455 2_564
La1 Mg5 La4 140.55(5) 5 2_564
Ge2 Mg5 La3 55.85(6) 5 5
Ge2 Mg5 La3 117.36(15) 5_455 5
Ge5 Mg5 La3 58.50(8) . 5
Ge6 Mg5 La3 134.68(9) . 5
Mg1 Mg5 La3 170.66(15) 5_455 5
Mg1 Mg5 La3 97.63(7) 5 5
La1 Mg5 La3 121.82(13) 5_455 5
La1 Mg5 La3 75.52(6) 5 5
La4 Mg5 La3 77.14(8) 2_564 5
Ge2 Mg5 La3 117.36(15) 5 5_455
Ge2 Mg5 La3 55.85(6) 5_455 5_455
Ge5 Mg5 La3 58.50(8) . 5_455
Ge6 Mg5 La3 134.68(9) . 5_455
Mg1 Mg5 La3 97.63(7) 5_455 5_455
Mg1 Mg5 La3 170.66(15) 5 5_455
La1 Mg5 La3 75.52(6) 5_455 5_455
La1 Mg5 La3 121.82(13) 5 5_455
La4 Mg5 La3 77.14(8) 2_564 5_455
La3 Mg5 La3 75.61(9) 5 5_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
La1 Ge1 3.2120(15) 2_554
La1 Ge4 3.2188(11) 5_545
La1 Ge4 3.2188(11) 5_445
La1 Ge6 3.2545(12) 5_445
La1 Ge6 3.2545(12) 5_545
La1 Ge5 3.4037(13) 5_545
La1 Ge5 3.4037(13) 5_445
La1 Mg1 3.469(4) .
La1 Mg5 3.552(4) 5_545
La1 Mg5 3.552(4) 5_445
La1 Mg4 3.810(4) 5_445
La1 Mg4 3.810(4) 5_545
La2 Ge5 3.1935(11) 6_454
La2 Ge5 3.1935(11) 6_554
La2 Ge4 3.2226(12) 6_454
La2 Ge4 3.2226(12) 6_554
La2 Ge6 3.2572(13) 5_545
La2 Ge6 3.2572(13) 5_445
La2 Mg4 3.283(3) 5_445
La2 Mg4 3.283(3) 5_545
La2 Mg1 3.353(5) .
La2 Mg3 3.412(3) 6_554
La2 Mg3 3.412(3) 6_454
La2 La1 3.9553(11) 2_554
La3 Ge2 3.1066(16) .
La3 Ge3 3.1315(11) 6
La3 Ge3 3.1315(11) 6_455
La3 Ge1 3.1447(19) .
La3 Ge5 3.2607(11) 5_445
La3 Ge5 3.2607(11) 5_545
La3 Mg3 3.555(4) .
La3 Mg5 3.673(4) 5_445
La3 Mg5 3.673(4) 5_545
La3 Mg2 3.775(4) 6
La3 Mg2 3.775(4) 6_455
La3 Mg4 3.818(4) 6
La4 Ge2 3.0808(11) 6
La4 Ge2 3.0808(11) 6_455
La4 Ge3 3.1007(18) 1_556
La4 Ge1 3.1312(18) .
La4 Ge4 3.2266(11) 6_455
La4 Ge4 3.2266(11) 6
La4 Mg5 3.563(5) 2_565
La4 Mg3 3.668(4) 6
La4 Mg3 3.668(4) 6_455
La4 Mg2 3.680(4) 6_455
La4 Mg2 3.680(4) 6
La4 La1 3.9154(12) 2
Ge1 Mg4 2.617(2) 6_455
Ge1 Mg4 2.617(2) 6
Ge1 Mg2 2.832(2) 6
Ge1 Mg2 2.832(2) 6_455
Ge1 La1 3.2120(15) 2
Ge2 Mg5 2.703(3) 5_445
Ge2 Mg5 2.703(3) 5_545
Ge2 Mg1 2.706(5) .
Ge2 Mg2 2.742(5) .
Ge2 La4 3.0808(11) 6_554
Ge2 La4 3.0808(11) 6_454
Ge3 Mg3 2.662(2) 6_454
Ge3 Mg3 2.662(2) 6_554
Ge3 Mg1 2.728(5) .
Ge3 Mg2 2.735(5) .
Ge3 La4 3.1007(18) 1_554
Ge3 La3 3.1315(11) 6_554
Ge3 La3 3.1315(11) 6_454
Ge4 Ge5 2.5577(16) .
Ge4 Mg3 2.861(5) .
Ge4 La1 3.2188(11) 5
Ge4 La1 3.2188(11) 5_455
Ge4 La2 3.2226(12) 6
Ge4 La2 3.2226(12) 6_455
Ge4 La4 3.2266(11) 6_454
Ge4 La4 3.2266(11) 6_554
Ge5 Mg5 2.826(5) .
Ge5 Mg4 2.987(4) 2_565
Ge5 La2 3.1935(11) 6_455
Ge5 La2 3.1935(11) 6
Ge5 La3 3.2607(11) 5
Ge5 La3 3.2607(11) 5_455
Ge5 La1 3.4037(13) 5_455
Ge5 La1 3.4037(13) 5
Ge6 Mg4 2.701(4) .
Ge6 Mg1 2.807(2) 5
Ge6 Mg1 2.807(2) 5_455
Ge6 Mg5 2.835(5) .
Ge6 Mg3 2.859(5) 2_564
Ge6 La1 3.2545(12) 5
Ge6 La1 3.2545(12) 5_455
Ge6 La2 3.2572(13) 5_455
Ge6 La2 3.2572(13) 5
Mg1 Ge6 2.807(2) 5_445
Mg1 Ge6 2.807(2) 5_545
Mg1 Mg2 2.934(5) .
Mg1 Mg3 3.218(5) 6_454
Mg1 Mg3 3.218(5) 6_554
Mg1 Mg5 3.232(5) 5_545
Mg1 Mg5 3.232(5) 5_445
Mg2 Ge1 2.832(2) 6_554
Mg2 Ge1 2.832(2) 6_454
Mg2 Mg4 2.915(6) .
Mg2 La4 3.680(4) 6_554
Mg2 La4 3.680(4) 6_454
Mg2 La3 3.775(4) 6_454
Mg2 La3 3.775(4) 6_554
Mg3 Ge3 2.662(2) 6_455
Mg3 Ge3 2.662(2) 6
Mg3 Ge6 2.859(5) 2_565
Mg3 Mg1 3.218(5) 6
Mg3 Mg1 3.218(5) 6_455
Mg3 La2 3.412(3) 6
Mg3 La2 3.412(3) 6_455
Mg3 La4 3.668(4) 6_454
Mg3 La4 3.668(4) 6_554
Mg4 Ge1 2.617(2) 6_454
Mg4 Ge1 2.617(2) 6_554
Mg4 Ge5 2.987(4) 2_564
Mg4 La2 3.283(3) 5
Mg4 La2 3.283(3) 5_455
Mg4 La1 3.810(4) 5
Mg4 La1 3.810(4) 5_455
Mg4 La3 3.818(4) 6_454
Mg4 La3 3.818(4) 6_554
Mg5 Ge2 2.703(3) 5
Mg5 Ge2 2.703(3) 5_455
Mg5 Mg1 3.232(5) 5_455
Mg5 Mg1 3.232(5) 5
Mg5 La1 3.552(4) 5_455
Mg5 La1 3.552(4) 5
Mg5 La4 3.563(5) 2_564
Mg5 La3 3.673(4) 5
Mg5 La3 3.673(4) 5_455
