#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:36:03 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179385 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/82/4328267.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328267
loop_
_publ_author_name
'Evelyn Wuttke'
'Florian Pevny'
'Yves-Marie Hervault'
'Lucie Norel'
'Malte Drescher'
'Rainer F. Winter'
'Stéphane Rigaut'
_publ_section_title
;
 Fully Delocalized (Ethynyl)(vinyl)phenylene Bridged Triruthenium
 Complexes in up to Five Different Oxidation States
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1902
_journal_page_last               1915
_journal_paper_doi               10.1021/ic2022177
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C48 H92 Cl2 O2 P4 Ru2, 4(C H2 Cl2)'
_chemical_formula_sum            'C52 H100 Cl10 O2 P4 Ru2'
_chemical_formula_weight         1437.84
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.24(3)
_cell_angle_beta                 92.59(3)
_cell_angle_gamma                106.72(3)
_cell_formula_units_Z            1
_cell_length_a                   8.8205(18)
_cell_length_b                   11.857(2)
_cell_length_c                   16.901(3)
_cell_measurement_reflns_used    47042
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.24
_cell_measurement_theta_min      1.79
_cell_volume                     1668.4(6)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0561
_diffrn_reflns_av_sigmaI/netI    0.0384
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            23111
_diffrn_reflns_theta_full        26.74
_diffrn_reflns_theta_max         26.74
_diffrn_reflns_theta_min         1.82
_exptl_absorpt_coefficient_mu    0.985
_exptl_absorpt_correction_T_max  0.8919
_exptl_absorpt_correction_T_min  0.6396
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   empirical
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.431
_exptl_crystal_description       block
_exptl_crystal_F_000             746
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.300
_refine_diff_density_max         1.633
_refine_diff_density_min         -1.156
_refine_diff_density_rms         0.080
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         7028
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0339
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0336P)²+2.9418P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0823
_refine_ls_wR_factor_ref         0.0838
_reflns_number_gt                6549
_reflns_number_total             7028
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic2022177_si_002_4.cif
_cod_data_source_block           ewbw11
_cod_database_code               4328267
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.86298(2) 0.920302(16) 0.734634(11) 0.01353(6) Uani 1 1 d .
P1 P 0.70703(7) 0.71619(5) 0.71127(4) 0.01569(12) Uani 1 1 d .
O1 O 1.0781(2) 0.86983(18) 0.85334(14) 0.0321(5) Uani 1 1 d .
C1 C 0.7351(3) 0.9612(2) 0.82089(15) 0.0178(5) Uani 1 1 d .
H1A H 0.6541 0.9919 0.8024 0.021 Uiso 1 1 calc R
Cl1 Cl 0.70908(7) 0.95324(5) 0.62298(4) 0.02149(13) Uani 1 1 d .
C2 C 0.7361(3) 0.9560(2) 0.89831(15) 0.0215(5) Uani 1 1 d .
H2A H 0.8207 0.9344 0.9226 0.026 Uiso 1 1 calc R
P2 P 1.04185(7) 1.11571(5) 0.74234(4) 0.01723(13) Uani 1 1 d .
Cl2 Cl 1.46135(9) 0.71728(7) 0.41895(5) 0.03863(17) Uani 1 1 d .
C3 C 0.6162(3) 0.9810(2) 0.94939(15) 0.0205(5) Uani 1 1 d .
Cl3 Cl 1.19609(10) 0.75169(10) 0.50237(5) 0.0493(2) Uani 1 1 d .
C4 C 0.5990(4) 0.9388(3) 1.02133(17) 0.0334(7) Uani 1 1 d .
H4A H 0.6685 0.8965 1.0375 0.040 Uiso 1 1 calc R
Cl4 Cl 0.71071(14) 1.36348(11) 0.97362(7) 0.0678(3) Uani 1 1 d .
C5 C 0.5149(4) 1.0441(3) 0.92963(18) 0.0346(7) Uani 1 1 d .
H5A H 0.5242 1.0765 0.8812 0.042 Uiso 1 1 calc R
Cl5 Cl 0.89821(13) 1.41115(9) 1.12489(7) 0.0595(3) Uani 1 1 d .
C6 C 0.9939(3) 0.8895(2) 0.80700(16) 0.0208(5) Uani 1 1 d .
C11 C 0.7981(3) 0.6339(2) 0.63630(16) 0.0205(5) Uani 1 1 d .
H11A H 0.7404 0.5468 0.6313 0.025 Uiso 1 1 calc R
C12 C 0.9713(3) 0.6531(3) 0.66459(17) 0.0256(5) Uani 1 1 d .
H12A H 1.0189 0.6088 0.6246 0.038 Uiso 1 1 calc R
H12B H 0.9773 0.6246 0.7159 0.038 Uiso 1 1 calc R
H12C H 1.0293 0.7384 0.6715 0.038 Uiso 1 1 calc R
C13 C 0.7873(4) 0.6699(3) 0.55406(17) 0.0303(6) Uani 1 1 d .
H13A H 0.8369 0.6236 0.5164 0.045 Uiso 1 1 calc R
H13B H 0.8427 0.7552 0.5577 0.045 Uiso 1 1 calc R
H13C H 0.6754 0.6540 0.5350 0.045 Uiso 1 1 calc R
C14 C 0.7027(3) 0.6371(2) 0.79806(16) 0.0234(5) Uani 1 1 d .
H14A H 0.8074 0.6756 0.8304 0.028 Uiso 1 1 calc R
C15 C 0.6882(4) 0.5053(2) 0.77875(19) 0.0314(6) Uani 1 1 d .
H15A H 0.6866 0.4721 0.8287 0.047 Uiso 1 1 calc R
H15B H 0.7792 0.4951 0.7505 0.047 Uiso 1 1 calc R
H15C H 0.5896 0.4635 0.7446 0.047 Uiso 1 1 calc R
C16 C 0.5763(4) 0.6533(3) 0.85386(19) 0.0348(7) Uani 1 1 d .
H16A H 0.5793 0.6093 0.8985 0.052 Uiso 1 1 calc R
H16B H 0.4711 0.6228 0.8239 0.052 Uiso 1 1 calc R
H16C H 0.5976 0.7383 0.8750 0.052 Uiso 1 1 calc R
C17 C 0.5037(3) 0.6857(2) 0.66454(17) 0.0228(5) Uani 1 1 d .
H17A H 0.5178 0.7184 0.6131 0.027 Uiso 1 1 calc R
C18 C 0.4121(3) 0.5555(3) 0.6394(2) 0.0357(7) Uani 1 1 d .
H18A H 0.3059 0.5485 0.6154 0.054 Uiso 1 1 calc R
H18B H 0.4024 0.5153 0.6866 0.054 Uiso 1 1 calc R
H18C H 0.4686 0.5181 0.6000 0.054 Uiso 1 1 calc R
C19 C 0.4044(3) 0.7528(3) 0.7103(2) 0.0334(7) Uani 1 1 d .
H19A H 0.2984 0.7319 0.6816 0.050 Uiso 1 1 calc R
H19B H 0.4557 0.8389 0.7149 0.050 Uiso 1 1 calc R
H19C H 0.3946 0.7312 0.7641 0.050 Uiso 1 1 calc R
C20 C 1.1601(3) 1.1814(2) 0.83943(16) 0.0240(5) Uani 1 1 d .
H20A H 1.1941 1.1151 0.8578 0.029 Uiso 1 1 calc R
C21 C 1.3129(4) 1.2814(3) 0.8382(2) 0.0369(7) Uani 1 1 d .
H21A H 1.3653 1.3092 0.8928 0.055 Uiso 1 1 calc R
H21B H 1.2881 1.3478 0.8175 0.055 Uiso 1 1 calc R
H21C H 1.3839 1.2518 0.8035 0.055 Uiso 1 1 calc R
C22 C 1.0638(4) 1.2197(3) 0.90421(18) 0.0369(7) Uani 1 1 d .
H22A H 1.1328 1.2539 0.9541 0.055 Uiso 1 1 calc R
H22B H 0.9779 1.1503 0.9131 0.055 Uiso 1 1 calc R
H22C H 1.0183 1.2797 0.8874 0.055 Uiso 1 1 calc R
C23 C 0.9517(3) 1.2224(2) 0.70607(17) 0.0239(5) Uani 1 1 d .
H23A H 0.9018 1.1832 0.6509 0.029 Uiso 1 1 calc R
C24 C 1.0656(4) 1.3403(3) 0.6946(2) 0.0376(7) Uani 1 1 d .
H24A H 1.0055 1.3903 0.6752 0.056 Uiso 1 1 calc R
H24B H 1.1389 1.3260 0.6552 0.056 Uiso 1 1 calc R
H24C H 1.1261 1.3811 0.7459 0.056 Uiso 1 1 calc R
C25 C 0.8161(4) 1.2404(3) 0.7521(2) 0.0388(7) Uani 1 1 d .
H25A H 0.7732 1.2980 0.7298 0.058 Uiso 1 1 calc R
H25B H 0.8543 1.2710 0.8087 0.058 Uiso 1 1 calc R
H25C H 0.7324 1.1641 0.7478 0.058 Uiso 1 1 calc R
C26 C 1.1948(3) 1.1070(2) 0.67308(16) 0.0242(5) Uani 1 1 d .
H26A H 1.2697 1.1892 0.6763 0.029 Uiso 1 1 calc R
C27 C 1.2899(3) 1.0273(3) 0.6971(2) 0.0352(7) Uani 1 1 d .
H27A H 1.3703 1.0244 0.6593 0.053 Uiso 1 1 calc R
H27B H 1.2185 0.9466 0.6962 0.053 Uiso 1 1 calc R
H27C H 1.3425 1.0594 0.7513 0.053 Uiso 1 1 calc R
C28 C 1.1224(4) 1.0648(3) 0.58708(18) 0.0352(7) Uani 1 1 d .
H28A H 1.2065 1.0614 0.5517 0.053 Uiso 1 1 calc R
H28B H 1.0678 1.1205 0.5713 0.053 Uiso 1 1 calc R
H28C H 1.0459 0.9852 0.5826 0.053 Uiso 1 1 calc R
C100 C 1.3818(3) 0.8212(3) 0.47238(18) 0.0299(6) Uani 1 1 d .
H10A H 1.4551 0.8645 0.5203 0.036 Uiso 1 1 calc R
H10B H 1.3716 0.8802 0.4382 0.036 Uiso 1 1 calc R
C101 C 0.7815(4) 1.3013(3) 1.04860(19) 0.0373(7) Uani 1 1 d .
H10C H 0.8455 1.2507 1.0253 0.045 Uiso 1 1 calc R
H10D H 0.6907 1.2496 1.0715 0.045 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C6 Ru1 C1 90.00(11) .
C6 Ru1 P2 89.50(8) .
C1 Ru1 P2 96.40(8) .
C6 Ru1 P1 90.36(9) .
C1 Ru1 P1 92.30(8) .
P2 Ru1 P1 171.30(2) .
C6 Ru1 Cl1 171.90(8) .
C1 Ru1 Cl1 98.09(8) .
P2 Ru1 Cl1 89.93(4) .
P1 Ru1 Cl1 88.98(4) .
C17 P1 C11 102.90(12) .
C17 P1 C14 109.78(13) .
C11 P1 C14 103.40(12) .
C17 P1 Ru1 115.51(9) .
C11 P1 Ru1 108.23(9) .
C14 P1 Ru1 115.50(9) .
C2 C1 Ru1 134.8(2) .
C2 C1 H1A 112.6 .
Ru1 C1 H1A 112.6 .
C1 C2 C3 124.6(2) .
C1 C2 H2A 117.7 .
C3 C2 H2A 117.7 .
C23 P2 C26 103.74(13) .
C23 P2 C20 110.66(13) .
C26 P2 C20 102.85(13) .
C23 P2 Ru1 114.06(9) .
C26 P2 Ru1 107.96(9) .
C20 P2 Ru1 116.12(9) .
C4 C3 C5 116.6(2) .
C4 C3 C2 119.6(2) .
C5 C3 C2 123.8(2) .
C5 C4 C3 122.2(3) 2_677
C5 C4 H4A 118.9 2_677
C3 C4 H4A 118.9 .
C4 C5 C3 121.2(3) 2_677
C4 C5 H5A 119.4 2_677
C3 C5 H5A 119.4 .
O1 C6 Ru1 179.9(3) .
C13 C11 C12 109.7(2) .
C13 C11 P1 112.51(18) .
C12 C11 P1 109.89(18) .
C13 C11 H11A 108.2 .
C12 C11 H11A 108.2 .
P1 C11 H11A 108.2 .
C11 C12 H12A 109.5 .
C11 C12 H12B 109.5 .
H12A C12 H12B 109.5 .
C11 C12 H12C 109.5 .
H12A C12 H12C 109.5 .
H12B C12 H12C 109.5 .
C11 C13 H13A 109.5 .
C11 C13 H13B 109.5 .
H13A C13 H13B 109.5 .
C11 C13 H13C 109.5 .
H13A C13 H13C 109.5 .
H13B C13 H13C 109.5 .
C15 C14 C16 108.9(2) .
C15 C14 P1 116.1(2) .
C16 C14 P1 113.1(2) .
C15 C14 H14A 106.0 .
C16 C14 H14A 106.0 .
P1 C14 H14A 106.0 .
C14 C15 H15A 109.5 .
C14 C15 H15B 109.5 .
H15A C15 H15B 109.5 .
C14 C15 H15C 109.5 .
H15A C15 H15C 109.5 .
H15B C15 H15C 109.5 .
C14 C16 H16A 109.5 .
C14 C16 H16B 109.5 .
H16A C16 H16B 109.5 .
C14 C16 H16C 109.5 .
H16A C16 H16C 109.5 .
H16B C16 H16C 109.5 .
C18 C17 C19 111.1(2) .
C18 C17 P1 115.62(19) .
C19 C17 P1 114.5(2) .
C18 C17 H17A 104.8 .
C19 C17 H17A 104.8 .
P1 C17 H17A 104.8 .
C17 C18 H18A 109.5 .
C17 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
C17 C18 H18C 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
C17 C19 H19A 109.5 .
C17 C19 H19B 109.5 .
H19A C19 H19B 109.5 .
C17 C19 H19C 109.5 .
H19A C19 H19C 109.5 .
H19B C19 H19C 109.5 .
C22 C20 C21 109.5(2) .
C22 C20 P2 113.25(19) .
C21 C20 P2 116.8(2) .
C22 C20 H20A 105.5 .
C21 C20 H20A 105.5 .
P2 C20 H20A 105.5 .
C20 C21 H21A 109.5 .
C20 C21 H21B 109.5 .
H21A C21 H21B 109.5 .
C20 C21 H21C 109.5 .
H21A C21 H21C 109.5 .
H21B C21 H21C 109.5 .
C20 C22 H22A 109.5 .
C20 C22 H22B 109.5 .
H22A C22 H22B 109.5 .
C20 C22 H22C 109.5 .
H22A C22 H22C 109.5 .
H22B C22 H22C 109.5 .
C25 C23 C24 111.4(3) .
C25 C23 P2 113.5(2) .
C24 C23 P2 116.1(2) .
C25 C23 H23A 104.8 .
C24 C23 H23A 104.8 .
P2 C23 H23A 104.8 .
C23 C24 H24A 109.5 .
C23 C24 H24B 109.5 .
H24A C24 H24B 109.5 .
C23 C24 H24C 109.5 .
H24A C24 H24C 109.5 .
H24B C24 H24C 109.5 .
C23 C25 H25A 109.5 .
C23 C25 H25B 109.5 .
H25A C25 H25B 109.5 .
C23 C25 H25C 109.5 .
H25A C25 H25C 109.5 .
H25B C25 H25C 109.5 .
C28 C26 C27 110.6(3) .
C28 C26 P2 111.35(19) .
C27 C26 P2 111.29(19) .
C28 C26 H26A 107.8 .
C27 C26 H26A 107.8 .
P2 C26 H26A 107.8 .
C26 C27 H27A 109.5 .
C26 C27 H27B 109.5 .
H27A C27 H27B 109.5 .
C26 C27 H27C 109.5 .
H27A C27 H27C 109.5 .
H27B C27 H27C 109.5 .
C26 C28 H28A 109.5 .
C26 C28 H28B 109.5 .
H28A C28 H28B 109.5 .
C26 C28 H28C 109.5 .
H28A C28 H28C 109.5 .
H28B C28 H28C 109.5 .
Cl3 C100 Cl2 111.27(16) .
Cl3 C100 H10A 109.4 .
Cl2 C100 H10A 109.4 .
Cl3 C100 H10B 109.4 .
Cl2 C100 H10B 109.4 .
H10A C100 H10B 108.0 .
Cl4 C101 Cl5 111.42(19) .
Cl4 C101 H10C 109.3 .
Cl5 C101 H10C 109.3 .
Cl4 C101 H10D 109.3 .
Cl5 C101 H10D 109.3 .
H10C C101 H10D 108.0 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C6 1.791(3) .
Ru1 C1 1.973(2) .
Ru1 P2 2.3804(11) .
Ru1 P1 2.3805(10) .
Ru1 Cl1 2.4168(9) .
P1 C17 1.841(3) .
P1 C11 1.842(3) .
P1 C14 1.847(3) .
O1 C6 1.148(3) .
C1 C2 1.319(4) .
C1 H1A 0.9500 .
C2 C3 1.464(3) .
C2 H2A 0.9500 .
P2 C23 1.834(3) .
P2 C26 1.841(3) .
P2 C20 1.843(3) .
Cl2 C100 1.749(3) .
C3 C4 1.378(4) .
C3 C5 1.378(4) .
Cl3 C100 1.743(3) .
C4 C5 1.372(4) 2_677
C4 H4A 0.9500 .
Cl4 C101 1.733(3) .
C5 C4 1.372(4) 2_677
C5 H5A 0.9500 .
Cl5 C101 1.745(4) .
C11 C13 1.518(4) .
C11 C12 1.522(3) .
C11 H11A 1.0000 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C15 1.516(4) .
C14 C16 1.528(4) .
C14 H14A 1.0000 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C18 1.510(4) .
C17 C19 1.512(4) .
C17 H17A 1.0000 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 C22 1.513(4) .
C20 C21 1.521(4) .
C20 H20A 1.0000 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C25 1.505(4) .
C23 C24 1.513(4) .
C23 H23A 1.0000 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 C28 1.515(4) .
C26 C27 1.516(4) .
C26 H26A 1.0000 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C100 H10A 0.9900 .
C100 H10B 0.9900 .
C101 H10C 0.9900 .
C101 H10D 0.9900 .
