#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:37:19 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179386 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/83/4328318.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328318
loop_
_publ_author_name
'Baoming Ji'
'Dongsheng Deng'
'Xiao He'
'Bin Liu'
'Shaobin Miao'
'Ning Ma'
'Weizhou Wang'
'Liguo Ji'
'Peng Liu'
'Xianfei Li'
_publ_contact_author_address
; 
College of Chemistry and Chemical Engineering
Luoyang Normal University
Luoyang 471022
P. R. China 
;
_publ_contact_author_email       dengdongsheng168@sina.com
_publ_contact_author_fax         '086 379 65523821'
_publ_contact_author_name        'Dong-sheng Deng'
_publ_contact_author_phone       '086 379 65523821'
_publ_section_title
;
 Syntheses, Structures, Luminescence, and Magnetic Properties of
 One-dimensional Lanthanide Coordination Polymers with a Rigid
 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic Acid Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2170
_journal_page_last               2177
_journal_paper_doi               10.1021/ic202063h
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C14 H11 N2 O11 Tb'
_chemical_formula_weight         542.17
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                87.255(6)
_cell_angle_beta                 86.232(6)
_cell_angle_gamma                85.446(6)
_cell_formula_units_Z            2
_cell_length_a                   9.236(6)
_cell_length_b                   9.236(6)
_cell_length_c                   9.447(6)
_cell_measurement_reflns_used    5749
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      0.00
_cell_measurement_theta_min      0.00
_cell_volume                     800.8(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0149
_diffrn_reflns_av_sigmaI/netI    0.0209
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            6149
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         3.00
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.486
_exptl_absorpt_correction_T_max  0.6882
_exptl_absorpt_correction_T_min  0.2876
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.248
_exptl_crystal_description       block
_exptl_crystal_F_000             524
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.705
_refine_diff_density_min         -0.977
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     254
_refine_ls_number_reflns         2968
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0174
_refine_ls_R_factor_gt           0.0167
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0285P)²+0.3539P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0428
_refine_ls_wR_factor_ref         0.0433
_reflns_number_gt                2885
_reflns_number_total             2968
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic202063h_si_005.cif
_cod_data_source_block           a
_cod_original_cell_volume        800.8(8)
_cod_database_code               4328318
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Tb1 Tb 0.370014(11) -0.087159(11) 0.146663(11) 0.01206(6) Uani 1 1 d .
O1 O 0.37388(19) -0.2851(2) 0.32205(19) 0.0183(4) Uani 1 1 d .
O2 O 0.2552(2) -0.4671(2) 0.4310(2) 0.0294(5) Uani 1 1 d .
O3 O -0.2536(2) 0.04562(19) 0.07892(19) 0.0174(4) Uani 1 1 d .
O4 O -0.3888(2) -0.0981(2) 0.2240(2) 0.0235(4) Uani 1 1 d .
O5 O 0.44435(19) 0.14157(19) 0.0554(2) 0.0177(4) Uani 1 1 d .
O6 O 0.3994(3) 0.3782(3) 0.0009(4) 0.0694(11) Uani 1 1 d .
O7 O -0.2298(2) 0.1318(2) 0.4086(2) 0.0256(4) Uani 1 1 d .
O8 O -0.3135(2) 0.3152(2) 0.2641(2) 0.0252(4) Uani 1 1 d .
H8 H -0.3866 0.3126 0.3181 0.038 Uiso 1 1 calc R
O9 O 0.3601(2) 0.0370(2) 0.3710(2) 0.0286(5) Uani 1 1 d .
H1W H 0.4019 0.1085 0.3984 0.043 Uiso 1 1 d R
H2W H 0.3330 -0.0067 0.4483 0.043 Uiso 1 1 d R
O10 O 0.3024(2) -0.3141(2) 0.0473(2) 0.0202(4) Uani 1 1 d .
H3W H 0.2966 -0.2993 -0.0417 0.030 Uiso 1 1 d R
H4W H 0.3543 -0.3920 0.0662 0.030 Uiso 1 1 d R
O11 O 0.4603(2) 0.3088(2) 0.4399(2) 0.0244(4) Uani 1 1 d .
H5W H 0.4962 0.2989 0.5207 0.037 Uiso 1 1 d R
H6W H 0.3989 0.3824 0.4397 0.037 Uiso 1 1 d R
N1 N 0.1232(2) -0.1346(2) 0.2693(2) 0.0140(4) Uani 1 1 d .
N2 N 0.1660(2) 0.1197(2) 0.1495(2) 0.0156(4) Uani 1 1 d .
C1 C 0.1152(3) -0.2689(3) 0.3286(3) 0.0147(5) Uani 1 1 d .
C2 C -0.0168(3) -0.3300(3) 0.3576(3) 0.0203(6) Uani 1 1 d .
H2 H -0.0214 -0.4192 0.4069 0.024 Uiso 1 1 calc R
C3 C -0.1413(3) -0.2543(3) 0.3110(3) 0.0197(6) Uani 1 1 d .
H3 H -0.2299 -0.2961 0.3228 0.024 Uiso 1 1 calc R
C4 C -0.1350(3) -0.1154(3) 0.2465(3) 0.0144(5) Uani 1 1 d .
C5 C 0.0003(3) -0.0536(3) 0.2382(2) 0.0129(5) Uani 1 1 d .
C6 C 0.0287(3) 0.1017(3) 0.2012(3) 0.0133(5) Uani 1 1 d .
C7 C -0.0704(3) 0.2241(3) 0.2235(3) 0.0156(5) Uani 1 1 d .
C8 C -0.0280(3) 0.3608(3) 0.1786(3) 0.0218(6) Uani 1 1 d .
H8A H -0.0939 0.4418 0.1875 0.026 Uiso 1 1 calc R
C9 C 0.1119(3) 0.3772(3) 0.1208(3) 0.0240(6) Uani 1 1 d .
H9 H 0.1412 0.4679 0.0893 0.029 Uiso 1 1 calc R
C10 C 0.2067(3) 0.2529(3) 0.1116(3) 0.0179(5) Uani 1 1 d .
C11 C 0.2596(3) -0.3489(3) 0.3634(3) 0.0169(5) Uani 1 1 d .
C12 C -0.2709(3) -0.0489(3) 0.1793(3) 0.0158(5) Uani 1 1 d .
C13 C 0.3623(3) 0.2620(3) 0.0523(3) 0.0266(7) Uani 1 1 d .
C14 C -0.2136(3) 0.2171(3) 0.3069(3) 0.0176(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Tb1 O4 79.44(7) . 1_655
O5 Tb1 O1 151.77(7) . .
O4 Tb1 O1 76.67(6) 1_655 .
O5 Tb1 O3 75.23(6) . 2
O4 Tb1 O3 136.77(6) 1_655 2
O1 Tb1 O3 132.95(6) . 2
O5 Tb1 O9 81.66(7) . .
O4 Tb1 O9 72.39(7) 1_655 .
O1 Tb1 O9 76.98(8) . .
O3 Tb1 O9 135.66(7) 2 .
O5 Tb1 O10 136.60(7) . .
O4 Tb1 O10 114.69(7) 1_655 .
O1 Tb1 O10 68.50(8) . .
O3 Tb1 O10 66.94(7) 2 .
O9 Tb1 O10 141.06(6) . .
O5 Tb1 O5 73.87(7) . 2_655
O4 Tb1 O5 68.84(8) 1_655 2_655
O1 Tb1 O5 110.46(7) . 2_655
O3 Tb1 O5 70.74(7) 2 2_655
O9 Tb1 O5 137.07(7) . 2_655
O10 Tb1 O5 74.20(6) . 2_655
O5 Tb1 N1 126.20(6) . .
O4 Tb1 N1 133.86(7) 1_655 .
O1 Tb1 N1 65.05(7) . .
O3 Tb1 N1 89.23(7) 2 .
O9 Tb1 N1 74.64(7) . .
O10 Tb1 N1 74.84(7) . .
O5 Tb1 N1 147.83(6) 2_655 .
O5 Tb1 N2 65.50(7) . .
O4 Tb1 N2 131.17(7) 1_655 .
O1 Tb1 N2 122.09(7) . .
O3 Tb1 N2 66.17(7) 2 .
O9 Tb1 N2 69.90(7) . .
O10 Tb1 N2 114.14(7) . .
O5 Tb1 N2 126.29(7) 2_655 .
N1 Tb1 N2 61.14(7) . .
O5 Tb1 Tb1 38.20(4) . 2_655
O4 Tb1 Tb1 69.91(6) 1_655 2_655
O1 Tb1 Tb1 139.46(5) . 2_655
O3 Tb1 Tb1 68.47(6) 2 2_655
O9 Tb1 Tb1 112.53(6) . 2_655
O10 Tb1 Tb1 105.42(5) . 2_655
O5 Tb1 Tb1 35.67(5) 2_655 2_655
N1 Tb1 Tb1 154.62(5) . 2_655
N2 Tb1 Tb1 97.43(6) . 2_655
C11 O1 Tb1 122.25(16) . .
C12 O3 Tb1 131.35(16) . 2
C12 O4 Tb1 136.10(17) . 1_455
C13 O5 Tb1 125.31(17) . .
C13 O5 Tb1 119.95(17) . 2_655
Tb1 O5 Tb1 106.13(7) . 2_655
C14 O8 H8 109.5 . .
Tb1 O9 H1W 133.5 . .
Tb1 O9 H2W 120.3 . .
H1W O9 H2W 103.4 . .
Tb1 O10 H3W 108.1 . .
Tb1 O10 H4W 117.6 . .
H3W O10 H4W 111.3 . .
H5W O11 H6W 108.8 . .
C1 N1 C5 119.9(2) . .
C1 N1 Tb1 114.53(16) . .
C5 N1 Tb1 122.09(16) . .
C10 N2 C6 120.3(2) . .
C10 N2 Tb1 116.12(17) . .
C6 N2 Tb1 123.17(17) . .
N1 C1 C2 122.1(2) . .
N1 C1 C11 115.6(2) . .
C2 C1 C11 122.3(2) . .
C1 C2 C3 118.1(2) . .
C1 C2 H2 120.9 . .
C3 C2 H2 120.9 . .
C2 C3 C4 120.5(2) . .
C2 C3 H3 119.8 . .
C4 C3 H3 119.8 . .
C3 C4 C5 117.6(2) . .
C3 C4 C12 117.2(2) . .
C5 C4 C12 125.0(2) . .
N1 C5 C4 120.8(2) . .
N1 C5 C6 111.9(2) . .
C4 C5 C6 127.4(2) . .
N2 C6 C7 120.0(2) . .
N2 C6 C5 113.8(2) . .
C7 C6 C5 126.1(2) . .
C8 C7 C6 118.7(2) . .
C8 C7 C14 117.5(2) . .
C6 C7 C14 123.4(2) . .
C7 C8 C9 120.5(3) . .
C7 C8 H8A 119.8 . .
C9 C8 H8A 119.8 . .
C8 C9 C10 117.4(3) . .
C8 C9 H9 121.3 . .
C10 C9 H9 121.3 . .
N2 C10 C9 122.8(2) . .
N2 C10 C13 116.5(2) . .
C9 C10 C13 120.7(2) . .
O2 C11 O1 126.6(2) . .
O2 C11 C1 117.3(2) . .
O1 C11 C1 116.1(2) . .
O4 C12 O3 126.3(2) . .
O4 C12 C4 116.5(2) . .
O3 C12 C4 117.1(2) . .
O6 C13 O5 125.1(3) . .
O6 C13 C10 118.7(3) . .
O5 C13 C10 116.1(2) . .
O7 C14 O8 124.8(2) . .
O7 C14 C7 121.8(2) . .
O8 C14 C7 113.3(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 O5 2.378(2) .
Tb1 O4 2.383(2) 1_655
Tb1 O1 2.408(2) .
Tb1 O3 2.450(2) 2
Tb1 O9 2.450(2) .
Tb1 O10 2.477(2) .
Tb1 O5 2.522(2) 2_655
Tb1 N1 2.548(2) .
Tb1 N2 2.574(2) .
Tb1 Tb1 3.9176(15) 2_655
O1 C11 1.279(3) .
O2 C11 1.240(3) .
O3 C12 1.269(3) .
O3 Tb1 2.450(2) 2
O4 C12 1.253(3) .
O4 Tb1 2.383(2) 1_455
O5 C13 1.296(3) .
O5 Tb1 2.522(2) 2_655
O6 C13 1.222(4) .
O7 C14 1.222(3) .
O8 C14 1.311(3) .
O8 H8 0.8200 .
O9 H1W 0.8499 .
O9 H2W 0.8500 .
O10 H3W 0.8500 .
O10 H4W 0.8500 .
O11 H5W 0.8500 .
O11 H6W 0.8500 .
N1 C1 1.342(3) .
N1 C5 1.350(3) .
N2 C10 1.340(3) .
N2 C6 1.349(3) .
C1 C2 1.389(4) .
C1 C11 1.521(4) .
C2 C3 1.383(4) .
C2 H2 0.9300 .
C3 C4 1.397(4) .
C3 H3 0.9300 .
C4 C5 1.411(3) .
C4 C12 1.517(4) .
C5 C6 1.499(4) .
C6 C7 1.412(4) .
C7 C8 1.390(4) .
C7 C14 1.499(4) .
C8 C9 1.386(4) .
C8 H8A 0.9300 .
C9 C10 1.390(4) .
C9 H9 0.9300 .
C10 C13 1.515(4) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O8 H8 O11 0.82 1.76 2.584(3) 177.6 1_455
O9 H1W O11 0.85 2.03 2.862(3) 165.6 .
O9 H2W O7 0.85 1.98 2.805(3) 162.9 2_556
O10 H3W O8 0.85 2.11 2.937(3) 165.1 2
O10 H4W O6 0.85 2.24 2.955(3) 142.0 1_545
O11 H5W O1 0.85 1.96 2.793(3) 165.0 2_656
O11 H6W O2 0.85 1.85 2.695(3) 175.0 1_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Tb1 O1 C11 140.87(18) . .
O4 Tb1 O1 C11 173.7(2) 1_655 .
O3 Tb1 O1 C11 -42.9(2) 2 .
O9 Tb1 O1 C11 99.1(2) . .
O10 Tb1 O1 C11 -62.57(19) . .
O5 Tb1 O1 C11 -125.22(19) 2_655 .
N1 Tb1 O1 C11 20.15(18) . .
N2 Tb1 O1 C11 43.2(2) . .
Tb1 Tb1 O1 C11 -151.37(16) 2_655 .
O4 Tb1 O5 C13 -141.8(2) 1_655 .
O1 Tb1 O5 C13 -109.3(2) . .
O3 Tb1 O5 C13 73.5(2) 2 .
O9 Tb1 O5 C13 -68.3(2) . .
O10 Tb1 O5 C13 103.3(2) . .
O5 Tb1 O5 C13 147.3(3) 2_655 .
N1 Tb1 O5 C13 -4.4(3) . .
N2 Tb1 O5 C13 3.3(2) . .
Tb1 Tb1 O5 C13 147.3(3) 2_655 .
O4 Tb1 O5 Tb1 70.84(8) 1_655 2_655
O1 Tb1 O5 Tb1 103.34(13) . 2_655
O3 Tb1 O5 Tb1 -73.81(8) 2 2_655
O9 Tb1 O5 Tb1 144.36(8) . 2_655
O10 Tb1 O5 Tb1 -44.08(12) . 2_655
O5 Tb1 O5 Tb1 0.0 2_655 2_655
N1 Tb1 O5 Tb1 -151.68(7) . 2_655
N2 Tb1 O5 Tb1 -143.99(9) . 2_655
O5 Tb1 N1 C1 -171.18(16) . .
O4 Tb1 N1 C1 -58.3(2) 1_655 .
O1 Tb1 N1 C1 -21.44(16) . .
O3 Tb1 N1 C1 117.82(17) 2 .
O9 Tb1 N1 C1 -103.98(18) . .
O10 Tb1 N1 C1 51.54(17) . .
O5 Tb1 N1 C1 67.7(2) 2_655 .
N2 Tb1 N1 C1 -179.2(2) . .
Tb1 Tb1 N1 C1 145.64(14) 2_655 .
O5 Tb1 N1 C5 29.8(2) . .
O4 Tb1 N1 C5 142.70(17) 1_655 .
O1 Tb1 N1 C5 179.6(2) . .
O3 Tb1 N1 C5 -41.15(18) 2 .
O9 Tb1 N1 C5 97.04(19) . .
O10 Tb1 N1 C5 -107.44(19) . .
O5 Tb1 N1 C5 -91.3(2) 2_655 .
N2 Tb1 N1 C5 21.85(17) . .
Tb1 Tb1 N1 C5 -13.3(3) 2_655 .
O5 Tb1 N2 C10 -6.12(17) . .
O4 Tb1 N2 C10 42.1(2) 1_655 .
O1 Tb1 N2 C10 142.88(17) . .
O3 Tb1 N2 C10 -90.10(19) 2 .
O9 Tb1 N2 C10 83.71(19) . .
O10 Tb1 N2 C10 -138.25(18) . .
O5 Tb1 N2 C10 -50.6(2) 2_655 .
N1 Tb1 N2 C10 166.8(2) . .
Tb1 Tb1 N2 C10 -27.63(18) 2_655 .
O5 Tb1 N2 C6 -178.6(2) . .
O4 Tb1 N2 C6 -130.35(18) 1_655 .
O1 Tb1 N2 C6 -29.6(2) . .
O3 Tb1 N2 C6 97.43(19) 2 .
O9 Tb1 N2 C6 -88.76(19) . .
O10 Tb1 N2 C6 49.3(2) . .
O5 Tb1 N2 C6 136.93(17) 2_655 .
N1 Tb1 N2 C6 -5.67(17) . .
Tb1 Tb1 N2 C6 159.90(18) 2_655 .
C5 N1 C1 C2 1.1(4) . .
Tb1 N1 C1 C2 -158.4(2) . .
C5 N1 C1 C11 -178.2(2) . .
Tb1 N1 C1 C11 22.3(3) . .
N1 C1 C2 C3 6.3(4) . .
C11 C1 C2 C3 -174.5(2) . .
C1 C2 C3 C4 -4.9(4) . .
C2 C3 C4 C5 -3.4(4) . .
C2 C3 C4 C12 171.3(3) . .
C1 N1 C5 C4 -9.9(3) . .
Tb1 N1 C5 C4 148.00(18) . .
C1 N1 C5 C6 168.3(2) . .
Tb1 N1 C5 C6 -33.8(3) . .
C3 C4 C5 N1 10.9(4) . .
C12 C4 C5 N1 -163.3(2) . .
C3 C4 C5 C6 -167.0(2) . .
C12 C4 C5 C6 18.8(4) . .
C10 N2 C6 C7 -3.8(4) . .
Tb1 N2 C6 C7 168.39(17) . .
C10 N2 C6 C5 179.8(2) . .
Tb1 N2 C6 C5 -8.0(3) . .
N1 C5 C6 N2 25.8(3) . .
C4 C5 C6 N2 -156.2(2) . .
N1 C5 C6 C7 -150.4(2) . .
C4 C5 C6 C7 27.7(4) . .
N2 C6 C7 C8 6.1(4) . .
C5 C6 C7 C8 -178.0(2) . .
N2 C6 C7 C14 -167.2(2) . .
C5 C6 C7 C14 8.8(4) . .
C6 C7 C8 C9 -3.7(4) . .
C14 C7 C8 C9 169.9(3) . .
C7 C8 C9 C10 -0.8(4) . .
C6 N2 C10 C9 -1.0(4) . .
Tb1 N2 C10 C9 -173.7(2) . .
C6 N2 C10 C13 -179.0(2) . .
Tb1 N2 C10 C13 8.3(3) . .
C8 C9 C10 N2 3.3(4) . .
C8 C9 C10 C13 -178.8(3) . .
Tb1 O1 C11 O2 165.2(2) . .
Tb1 O1 C11 C1 -16.4(3) . .
N1 C1 C11 O2 173.0(2) . .
C2 C1 C11 O2 -6.3(4) . .
N1 C1 C11 O1 -5.6(3) . .
C2 C1 C11 O1 175.1(2) . .
Tb1 O4 C12 O3 10.9(4) 1_455 .
Tb1 O4 C12 C4 -165.32(17) 1_455 .
Tb1 O3 C12 O4 -37.2(4) 2 .
Tb1 O3 C12 C4 139.03(18) 2 .
C3 C4 C12 O4 22.3(3) . .
C5 C4 C12 O4 -163.4(2) . .
C3 C4 C12 O3 -154.3(2) . .
C5 C4 C12 O3 20.0(4) . .
Tb1 O5 C13 O6 -177.3(3) . .
Tb1 O5 C13 O6 -34.1(5) 2_655 .
Tb1 O5 C13 C10 -0.4(4) . .
Tb1 O5 C13 C10 142.8(2) 2_655 .
N2 C10 C13 O6 171.4(3) . .
C9 C10 C13 O6 -6.6(5) . .
N2 C10 C13 O5 -5.6(4) . .
C9 C10 C13 O5 176.3(3) . .
C8 C7 C14 O7 -140.2(3) . .
C6 C7 C14 O7 33.2(4) . .
C8 C7 C14 O8 36.4(3) . .
C6 C7 C14 O8 -150.3(2) . .
