#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:38:40 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179387 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/84/4328428.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328428
loop_
_publ_author_name
'Stanislav S. Stoyko'
'Mansura Khatun'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Ternary Arsenides A2Zn2As3 (A = Sr, Eu) and Their Stuffed Derivatives
 A2Ag2ZnAs3
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2621
_journal_page_last               2628
_journal_paper_doi               10.1021/ic202580m
_journal_volume                  51
_journal_year                    2012
_chemical_formula_structural     'Sr2 Zn2 As3'
_chemical_formula_sum            'As3 Sr2 Zn2'
_chemical_formula_weight         530.74
_chemical_name_common            'strontium zinc arsenide (2/2/3)'
_chemical_name_systematic        'strontium zinc arsenide (2/2/3)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 126.271(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.212(5)
_cell_length_b                   4.2754(12)
_cell_length_c                   11.955(3)
_cell_measurement_reflns_used    2588
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.35
_cell_measurement_theta_min      3.12
_cell_volume                     668.1(3)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_sigmaI/netI    0.0293
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            4595
_diffrn_reflns_theta_full        33.04
_diffrn_reflns_theta_max         33.04
_diffrn_reflns_theta_min         2.11
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    37.588
_exptl_absorpt_correction_T_max  0.6515
_exptl_absorpt_correction_T_min  0.0545
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    5.277
_exptl_crystal_description       needle
_exptl_crystal_F_000             940
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.324
_refine_diff_density_min         -0.988
_refine_diff_density_rms         0.243
_refine_ls_extinction_coef       0.00206(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_matrix_type           full
_refine_ls_number_parameters     44
_refine_ls_number_reflns         1374
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0300
_refine_ls_R_factor_gt           0.0216
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0196P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0428
_refine_ls_wR_factor_ref         0.0456
_reflns_number_gt                1171
_reflns_number_total             1374
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic202580m_si_002_2.cif
_cod_data_source_block           Sr2Zn2As3
_cod_database_code               4328428
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sr1 Sr 0.26694(3) 0.0000 0.66409(4) 0.00711(8) Uani 1 2 d S
Sr2 Sr 0.39248(3) 0.0000 0.04821(4) 0.00766(9) Uani 1 2 d S
Zn1 Zn 0.03802(4) 0.0000 0.31432(5) 0.00852(10) Uani 1 2 d S
Zn2 Zn 0.41130(4) 0.0000 0.34890(5) 0.00893(10) Uani 1 2 d S
As1 As 0.07517(3) 0.0000 0.12467(4) 0.00728(9) Uani 1 2 d S
As2 As 0.15194(3) 0.0000 0.79726(4) 0.00684(9) Uani 1 2 d S
As3 As 0.38920(3) 0.0000 0.54186(4) 0.00636(9) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -1.5307 3.2498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
As3 Sr1 As2 177.904(17) . .
As3 Sr1 As3 94.31(2) . 7_546
As2 Sr1 As3 87.21(2) . 7_546
As3 Sr1 As3 94.31(2) . 7_556
As2 Sr1 As3 87.21(2) . 7_556
As3 Sr1 As3 86.88(2) 7_546 7_556
As3 Sr1 As1 86.24(2) . 7_556
As2 Sr1 As1 92.23(2) . 7_556
As3 Sr1 As1 179.221(16) 7_546 7_556
As3 Sr1 As1 93.63(2) 7_556 7_556
As3 Sr1 As1 86.24(2) . 7_546
As2 Sr1 As1 92.23(2) . 7_546
As3 Sr1 As1 93.63(2) 7_546 7_546
As3 Sr1 As1 179.221(16) 7_556 7_546
As1 Sr1 As1 85.86(2) 7_556 7_546
As3 Sr1 Zn2 136.064(15) . 7_546
As2 Sr1 Zn2 44.982(14) . 7_546
As3 Sr1 Zn2 44.404(17) 7_546 7_546
As3 Sr1 Zn2 96.89(2) 7_556 7_546
As1 Sr1 Zn2 134.91(2) 7_556 7_546
As1 Sr1 Zn2 83.07(2) 7_546 7_546
As3 Sr1 Zn2 136.064(15) . 7_556
As2 Sr1 Zn2 44.982(14) . 7_556
As3 Sr1 Zn2 96.89(2) 7_546 7_556
As3 Sr1 Zn2 44.404(17) 7_556 7_556
As1 Sr1 Zn2 83.07(2) 7_556 7_556
As1 Sr1 Zn2 134.91(2) 7_546 7_556
Zn2 Sr1 Zn2 74.71(3) 7_546 7_556
As3 Sr1 Zn1 87.67(3) . .
As2 Sr1 Zn1 94.42(3) . .
As3 Sr1 Zn1 44.068(12) 7_546 .
As3 Sr1 Zn1 44.068(12) 7_556 .
As1 Sr1 Zn1 136.551(12) 7_556 .
As1 Sr1 Zn1 136.551(12) 7_546 .
Zn2 Sr1 Zn1 72.12(2) 7_546 .
Zn2 Sr1 Zn1 72.12(2) 7_556 .
As3 Sr1 Zn1 43.066(14) . 7_556
As2 Sr1 Zn1 135.790(14) . 7_556
As3 Sr1 Zn1 135.63(2) 7_546 7_556
As3 Sr1 Zn1 85.40(2) 7_556 7_556
As1 Sr1 Zn1 45.036(17) 7_556 7_556
As1 Sr1 Zn1 94.64(2) 7_546 7_556
Zn2 Sr1 Zn1 177.678(11) 7_546 7_556
Zn2 Sr1 Zn1 107.31(2) 7_556 7_556
Zn1 Sr1 Zn1 109.47(2) . 7_556
As3 Sr1 Zn1 43.066(14) . 7_546
As2 Sr1 Zn1 135.790(15) . 7_546
As3 Sr1 Zn1 85.40(2) 7_546 7_546
As3 Sr1 Zn1 135.63(2) 7_556 7_546
As1 Sr1 Zn1 94.64(2) 7_556 7_546
As1 Sr1 Zn1 45.036(17) 7_546 7_546
Zn2 Sr1 Zn1 107.31(2) 7_546 7_546
Zn2 Sr1 Zn1 177.678(11) 7_556 7_546
Zn1 Sr1 Zn1 109.47(2) . 7_546
Zn1 Sr1 Zn1 70.65(2) 7_556 7_546
As3 Sr1 Sr2 122.91(2) . 1_556
As2 Sr1 Sr2 54.99(2) . 1_556
As3 Sr1 Sr2 124.429(14) 7_546 1_556
As3 Sr1 Sr2 124.429(14) 7_556 1_556
As1 Sr1 Sr2 54.792(13) 7_556 1_556
As1 Sr1 Sr2 54.792(13) 7_546 1_556
Zn2 Sr1 Sr2 83.755(15) 7_546 1_556
Zn2 Sr1 Sr2 83.755(14) 7_556 1_556
Zn1 Sr1 Sr2 149.415(17) . 1_556
Zn1 Sr1 Sr2 95.279(14) 7_556 1_556
Zn1 Sr1 Sr2 95.279(14) 7_546 1_556
As2 Sr2 As2 84.67(2) 7_556 7_546
As2 Sr2 As2 88.60(2) 7_556 1_554
As2 Sr2 As2 88.60(2) 7_546 1_554
As2 Sr2 As1 176.743(17) 7_556 7_545
As2 Sr2 As1 96.06(2) 7_546 7_545
As2 Sr2 As1 88.24(2) 1_554 7_545
As2 Sr2 As1 96.06(2) 7_556 7
As2 Sr2 As1 176.743(17) 7_546 7
As2 Sr2 As1 88.24(2) 1_554 7
As1 Sr2 As1 83.05(2) 7_545 7
As2 Sr2 As1 83.02(2) 7_556 3
As2 Sr2 As1 138.387(19) 7_546 3
As2 Sr2 As1 130.501(17) 1_554 3
As1 Sr2 As1 98.44(2) 7_545 3
As1 Sr2 As1 44.864(17) 7 3
As2 Sr2 As1 138.387(19) 7_556 3_545
As2 Sr2 As1 83.02(2) 7_546 3_545
As2 Sr2 As1 130.501(17) 1_554 3_545
As1 Sr2 As1 44.864(17) 7_545 3_545
As1 Sr2 As1 98.44(2) 7 3_545
As1 Sr2 As1 80.37(3) 3 3_545
As2 Sr2 Zn1 45.34(2) 7_556 3
As2 Sr2 Zn1 98.67(3) 7_546 3
As2 Sr2 Zn1 131.660(13) 1_554 3
As1 Sr2 Zn1 137.43(2) 7_545 3
As1 Sr2 Zn1 84.04(2) 7 3
As1 Sr2 Zn1 47.035(15) 3 3
As1 Sr2 Zn1 97.84(2) 3_545 3
As2 Sr2 Zn1 98.67(3) 7_556 3_545
As2 Sr2 Zn1 45.34(2) 7_546 3_545
As2 Sr2 Zn1 131.660(13) 1_554 3_545
As1 Sr2 Zn1 84.04(2) 7_545 3_545
As1 Sr2 Zn1 137.43(2) 7 3_545
As1 Sr2 Zn1 97.84(2) 3 3_545
As1 Sr2 Zn1 47.035(15) 3_545 3_545
Zn1 Sr2 Zn1 78.66(2) 3 3_545
As2 Sr2 Zn2 45.473(13) 7_556 .
As2 Sr2 Zn2 45.473(13) 7_546 .
As2 Sr2 Zn2 106.55(2) 1_554 .
As1 Sr2 Zn2 136.535(13) 7_545 .
As1 Sr2 Zn2 136.535(13) 7 .
As1 Sr2 Zn2 101.571(14) 3 .
As1 Sr2 Zn2 101.571(14) 3_545 .
Zn1 Sr2 Zn2 55.351(18) 3 .
Zn1 Sr2 Zn2 55.351(18) 3_545 .
As2 Sr2 Sr1 124.394(16) 7_556 1_554
As2 Sr2 Sr1 124.394(17) 7_546 1_554
As2 Sr2 Sr1 51.727(14) 1_554 1_554
As1 Sr2 Sr1 52.680(16) 7_545 1_554
As1 Sr2 Sr1 52.680(16) 7 1_554
As1 Sr2 Sr1 94.961(12) 3 1_554
As1 Sr2 Sr1 94.961(12) 3_545 1_554
Zn1 Sr2 Sr1 136.243(14) 3 1_554
Zn1 Sr2 Sr1 136.243(14) 3_545 1_554
Zn2 Sr2 Sr1 158.278(18) . 1_554
As2 Sr2 Sr2 131.271(13) 7_556 5_655
As2 Sr2 Sr2 131.271(13) 7_546 5_655
As2 Sr2 Sr2 118.73(3) 1_554 5_655
As1 Sr2 Sr2 50.114(12) 7_545 5_655
As1 Sr2 Sr2 50.114(12) 7 5_655
As1 Sr2 Sr2 48.325(15) 3 5_655
As1 Sr2 Sr2 48.325(15) 3_545 5_655
Zn1 Sr2 Sr2 91.57(2) 3 5_655
Zn1 Sr2 Sr2 91.57(2) 3_545 5_655
Zn2 Sr2 Sr2 134.720(18) . 5_655
Sr1 Sr2 Sr2 67.002(19) 1_554 5_655
As2 Zn1 As3 106.768(17) 5_556 7_556
As2 Zn1 As3 106.768(17) 5_556 7_546
As3 Zn1 As3 113.71(3) 7_556 7_546
As2 Zn1 As1 111.60(3) 5_556 .
As3 Zn1 As1 109.00(2) 7_556 .
As3 Zn1 As1 109.00(2) 7_546 .
As2 Zn1 Zn2 52.098(17) 5_556 3_445
As3 Zn1 Zn2 123.78(3) 7_556 3_445
As3 Zn1 Zn2 54.70(2) 7_546 3_445
As1 Zn1 Zn2 127.074(16) . 3_445
As2 Zn1 Zn2 52.098(17) 5_556 3_455
As3 Zn1 Zn2 54.70(2) 7_556 3_455
As3 Zn1 Zn2 123.78(3) 7_546 3_455
As1 Zn1 Zn2 127.074(16) . 3_455
Zn2 Zn1 Zn2 85.24(3) 3_445 3_455
As2 Zn1 Sr2 63.171(14) 5_556 3_445
As3 Zn1 Sr2 162.292(17) 7_556 3_445
As3 Zn1 Sr2 83.76(2) 7_546 3_445
As1 Zn1 Sr2 65.30(2) . 3_445
Zn2 Zn1 Sr2 63.13(2) 3_445 3_445
Zn2 Zn1 Sr2 113.98(3) 3_455 3_445
As2 Zn1 Sr2 63.171(14) 5_556 3_455
As3 Zn1 Sr2 83.76(2) 7_556 3_455
As3 Zn1 Sr2 162.292(17) 7_546 3_455
As1 Zn1 Sr2 65.30(2) . 3_455
Zn2 Zn1 Sr2 113.98(3) 3_445 3_455
Zn2 Zn1 Sr2 63.13(2) 3_455 3_455
Sr2 Zn1 Sr2 78.66(2) 3_445 3_455
As2 Zn1 Sr1 135.31(2) 5_556 .
As3 Zn1 Sr1 57.879(16) 7_556 .
As3 Zn1 Sr1 57.879(16) 7_546 .
As1 Zn1 Sr1 113.09(3) . .
Zn2 Zn1 Sr1 98.73(2) 3_445 .
Zn2 Zn1 Sr1 98.73(2) 3_455 .
Sr2 Zn1 Sr1 139.698(12) 3_445 .
Sr2 Zn1 Sr1 139.698(13) 3_455 .
As2 Zn1 Sr1 139.525(16) 5_556 7_556
As3 Zn1 Sr1 55.489(16) 7_556 7_556
As3 Zn1 Sr1 113.68(2) 7_546 7_556
As1 Zn1 Sr1 56.332(14) . 7_556
Zn2 Zn1 Sr1 168.051(18) 3_445 7_556
Zn2 Zn1 Sr1 101.26(2) 3_455 7_556
Sr2 Zn1 Sr1 121.63(2) 3_445 7_556
Sr2 Zn1 Sr1 77.97(2) 3_455 7_556
Sr1 Zn1 Sr1 70.53(2) . 7_556
As2 Zn1 Sr1 139.525(16) 5_556 7_546
As3 Zn1 Sr1 113.68(2) 7_556 7_546
As3 Zn1 Sr1 55.489(16) 7_546 7_546
As1 Zn1 Sr1 56.332(14) . 7_546
Zn2 Zn1 Sr1 101.26(2) 3_445 7_546
Zn2 Zn1 Sr1 168.051(18) 3_455 7_546
Sr2 Zn1 Sr1 77.97(2) 3_445 7_546
Sr2 Zn1 Sr1 121.63(2) 3_455 7_546
Sr1 Zn1 Sr1 70.53(2) . 7_546
Sr1 Zn1 Sr1 70.65(2) 7_556 7_546
As3 Zn2 As2 113.952(19) . 7_546
As3 Zn2 As2 113.95(2) . 7_556
As2 Zn2 As2 113.22(3) 7_546 7_556
As3 Zn2 As3 109.66(2) . 5_656
As2 Zn2 As3 102.316(16) 7_546 5_656
As2 Zn2 As3 102.316(16) 7_556 5_656
As3 Zn2 Zn2 57.05(3) . 5_656
As2 Zn2 Zn2 122.179(16) 7_546 5_656
As2 Zn2 Zn2 122.179(16) 7_556 5_656
As3 Zn2 Zn2 52.61(2) 5_656 5_656
As3 Zn2 Zn1 124.916(17) . 3
As2 Zn2 Zn1 120.32(3) 7_546 3
As2 Zn2 Zn1 51.25(2) 7_556 3
As3 Zn2 Zn1 51.094(17) 5_656 3
Zn2 Zn2 Zn1 85.60(3) 5_656 3
As3 Zn2 Zn1 124.916(17) . 3_545
As2 Zn2 Zn1 51.248(19) 7_546 3_545
As2 Zn2 Zn1 120.32(3) 7_556 3_545
As3 Zn2 Zn1 51.094(17) 5_656 3_545
Zn2 Zn2 Zn1 85.60(3) 5_656 3_545
Zn1 Zn2 Zn1 85.24(3) 3 3_545
As3 Zn2 Sr2 169.34(2) . .
As2 Zn2 Sr2 62.115(17) 7_546 .
As2 Zn2 Sr2 62.115(17) 7_556 .
As3 Zn2 Sr2 81.006(19) 5_656 .
Zn2 Zn2 Sr2 133.61(3) 5_656 .
Zn1 Zn2 Sr2 61.515(14) 3 .
Zn1 Zn2 Sr2 61.515(14) 3_545 .
As3 Zn2 Sr1 59.097(14) . 7_546
As2 Zn2 Sr1 58.431(17) 7_546 7_546
As2 Zn2 Sr1 119.32(2) 7_556 7_546
As3 Zn2 Sr1 138.080(16) 5_656 7_546
Zn2 Zn2 Sr1 103.28(2) 5_656 7_546
Zn1 Zn2 Sr1 170.196(19) 3 7_546
Zn1 Zn2 Sr1 99.42(2) 3_545 7_546
Sr2 Zn2 Sr1 113.108(14) . 7_546
As3 Zn2 Sr1 59.097(14) . 7_556
As2 Zn2 Sr1 119.32(2) 7_546 7_556
As2 Zn2 Sr1 58.431(16) 7_556 7_556
As3 Zn2 Sr1 138.080(16) 5_656 7_556
Zn2 Zn2 Sr1 103.28(2) 5_656 7_556
Zn1 Zn2 Sr1 99.42(2) 3 7_556
Zn1 Zn2 Sr1 170.196(19) 3_545 7_556
Sr2 Zn2 Sr1 113.108(14) . 7_556
Sr1 Zn2 Sr1 74.71(3) 7_546 7_556
As1 As1 Zn1 117.58(4) 5 .
As1 As1 Sr1 135.750(13) 5 7_556
Zn1 As1 Sr1 78.63(2) . 7_556
As1 As1 Sr1 135.750(13) 5 7_546
Zn1 As1 Sr1 78.63(2) . 7_546
Sr1 As1 Sr1 85.86(2) 7_556 7_546
As1 As1 Sr2 69.44(2) 5 7_545
Zn1 As1 Sr2 138.476(12) . 7_545
Sr1 As1 Sr2 127.07(2) 7_556 7_545
Sr1 As1 Sr2 72.53(2) 7_546 7_545
As1 As1 Sr2 69.44(2) 5 7
Zn1 As1 Sr2 138.476(12) . 7
Sr1 As1 Sr2 72.53(2) 7_556 7
Sr1 As1 Sr2 127.07(2) 7_546 7
Sr2 As1 Sr2 83.04(2) 7_545 7
As1 As1 Sr2 65.699(19) 5 3_445
Zn1 As1 Sr2 67.668(17) . 3_445
Sr1 As1 Sr2 146.300(19) 7_556 3_445
Sr1 As1 Sr2 87.30(2) 7_546 3_445
Sr2 As1 Sr2 81.56(2) 7_545 3_445
Sr2 As1 Sr2 135.136(17) 7 3_445
As1 As1 Sr2 65.699(19) 5 3_455
Zn1 As1 Sr2 67.668(17) . 3_455
Sr1 As1 Sr2 87.30(2) 7_556 3_455
Sr1 As1 Sr2 146.300(19) 7_546 3_455
Sr2 As1 Sr2 135.136(17) 7_545 3_455
Sr2 As1 Sr2 81.56(2) 7 3_455
Sr2 As1 Sr2 80.37(3) 3_445 3_455
Zn1 As2 Zn2 76.654(16) 5_556 7_546
Zn1 As2 Zn2 76.654(16) 5_556 7_556
Zn2 As2 Zn2 113.22(3) 7_546 7_556
Zn1 As2 Sr1 130.27(3) 5_556 .
Zn2 As2 Sr1 76.59(2) 7_546 .
Zn2 As2 Sr1 76.59(2) 7_556 .
Zn1 As2 Sr2 71.484(17) 5_556 7_556
Zn2 As2 Sr2 145.33(2) 7_546 7_556
Zn2 As2 Sr2 72.41(2) 7_556 7_556
Sr1 As2 Sr2 135.612(12) . 7_556
Zn1 As2 Sr2 71.484(17) 5_556 7_546
Zn2 As2 Sr2 72.41(2) 7_546 7_546
Zn2 As2 Sr2 145.33(2) 7_556 7_546
Sr1 As2 Sr2 135.612(13) . 7_546
Sr2 As2 Sr2 84.67(2) 7_556 7_546
Zn1 As2 Sr2 156.45(2) 5_556 1_556
Zn2 As2 Sr2 114.280(16) 7_546 1_556
Zn2 As2 Sr2 114.280(16) 7_556 1_556
Sr1 As2 Sr2 73.28(3) . 1_556
Sr2 As2 Sr2 91.40(2) 7_556 1_556
Sr2 As2 Sr2 91.40(2) 7_546 1_556
Zn2 As3 Zn1 110.79(2) . 7_556
Zn2 As3 Zn1 110.79(2) . 7_546
Zn1 As3 Zn1 113.72(3) 7_556 7_546
Zn2 As3 Zn2 70.34(2) . 5_656
Zn1 As3 Zn2 74.208(16) 7_556 5_656
Zn1 As3 Zn2 74.208(16) 7_546 5_656
Zn2 As3 Sr1 155.30(2) . .
Zn1 As3 Sr1 81.45(2) 7_556 .
Zn1 As3 Sr1 81.45(2) 7_546 .
Zn2 As3 Sr1 134.36(3) 5_656 .
Zn2 As3 Sr1 76.50(2) . 7_546
Zn1 As3 Sr1 160.82(2) 7_556 7_546
Zn1 As3 Sr1 78.05(2) 7_546 7_546
Zn2 As3 Sr1 124.673(16) 5_656 7_546
Sr1 As3 Sr1 85.69(2) . 7_546
Zn2 As3 Sr1 76.50(2) . 7_556
Zn1 As3 Sr1 78.05(2) 7_556 7_556
Zn1 As3 Sr1 160.82(2) 7_546 7_556
Zn2 As3 Sr1 124.673(16) 5_656 7_556
Sr1 As3 Sr1 85.69(2) . 7_556
Sr1 As3 Sr1 86.88(2) 7_546 7_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sr1 As3 3.0808(8) .
Sr1 As2 3.0859(8) .
Sr1 As3 3.1089(7) 7_546
Sr1 As3 3.1089(7) 7_556
Sr1 As1 3.1387(7) 7_556
Sr1 As1 3.1387(7) 7_546
Sr1 Zn2 3.5230(9) 7_546
Sr1 Zn2 3.5230(9) 7_556
Sr1 Zn1 3.5912(10) .
Sr1 Zn1 3.6973(9) 7_556
Sr1 Zn1 3.6973(9) 7_546
Sr1 Sr2 3.7646(13) 1_556
Sr2 As2 3.1742(7) 7_556
Sr2 As2 3.1742(7) 7_546
Sr2 As2 3.2195(9) 1_554
Sr2 As1 3.2247(7) 7_545
Sr2 As1 3.2247(7) 7
Sr2 As1 3.3128(8) 3
Sr2 As1 3.3128(8) 3_545
Sr2 Zn1 3.3730(8) 3
Sr2 Zn1 3.3730(8) 3_545
Sr2 Zn2 3.4233(12) .
Sr2 Sr1 3.7646(13) 1_554
Sr2 Sr2 4.2706(12) 5_655
Zn1 As2 2.5304(10) 5_556
Zn1 As3 2.5530(6) 7_556
Zn1 As3 2.5530(6) 7_546
Zn1 As1 2.6683(9) .
Zn1 Zn2 3.1570(8) 3_445
Zn1 Zn2 3.1570(8) 3_455
Zn1 Sr2 3.3729(8) 3_445
Zn1 Sr2 3.3729(8) 3_455
Zn1 Sr1 3.6972(9) 7_556
Zn1 Sr1 3.6972(9) 7_546
Zn2 As3 2.5353(9) .
Zn2 As2 2.5602(6) 7_546
Zn2 As2 2.5602(6) 7_556
Zn2 As3 2.6775(10) 5_656
Zn2 Zn2 3.0050(12) 5_656
Zn2 Zn1 3.1569(8) 3
Zn2 Zn1 3.1569(8) 3_545
Zn2 Sr1 3.5231(9) 7_546
Zn2 Sr1 3.5231(9) 7_556
As1 As1 2.4959(10) 5
As1 Sr1 3.1386(7) 7_556
As1 Sr1 3.1386(7) 7_546
As1 Sr2 3.2247(7) 7_545
As1 Sr2 3.2247(7) 7
As1 Sr2 3.3128(8) 3_445
As1 Sr2 3.3128(8) 3_455
As2 Zn1 2.5303(10) 5_556
As2 Zn2 2.5602(7) 7_546
As2 Zn2 2.5602(6) 7_556
As2 Sr2 3.1742(7) 7_556
As2 Sr2 3.1742(7) 7_546
As2 Sr2 3.2195(9) 1_556
As3 Zn1 2.5530(6) 7_556
As3 Zn1 2.5530(6) 7_546
As3 Zn2 2.6776(10) 5_656
As3 Sr1 3.1089(7) 7_546
As3 Sr1 3.1089(7) 7_556
