#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/87/4328714.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328714
loop_
_publ_author_name
'Jin-Cheng Wu'
'Liang Zhao'
'De-Xian Wang'
'Mei-Xiang Wang'
_publ_section_title
;
 Structural Diversity in Coordination Self-Assembled Networks of a
 Multimodal Ligand Azacalix[4]pyrazine
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3860
_journal_page_last               3867
_journal_paper_doi               10.1021/ic3000679
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C80 H80 Ag4 B4 F16 N48 O0.5'
_chemical_formula_weight         2500.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.69(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.797(4)
_cell_length_b                   18.883(4)
_cell_length_c                   31.934(6)
_cell_measurement_reflns_used    25323
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.3029
_cell_measurement_theta_min      1.2505
_cell_volume                     11334(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1293
_diffrn_reflns_av_sigmaI/netI    0.1001
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            106059
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.26
_exptl_absorpt_coefficient_mu    0.770
_exptl_absorpt_correction_T_max  0.9625
_exptl_absorpt_correction_T_min  0.9270
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Pale-yellow
_exptl_crystal_density_diffrn    1.465
_exptl_crystal_description       Plate
_exptl_crystal_F_000             5008
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.651
_refine_diff_density_min         -1.540
_refine_diff_density_rms         0.213
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.142
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1301
_refine_ls_number_reflns         19981
_refine_ls_number_restraints     126
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.1621
_refine_ls_R_factor_gt           0.1330
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1333P)²+200.7487P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3131
_refine_ls_wR_factor_ref         0.3324
_reflns_number_gt                16100
_reflns_number_total             19981
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic3000679_si_002_4.cif
_cod_data_source_block           3
_cod_original_formula_sum        'C80 H80 Ag4 B4 F16 N48 O0.50'
_cod_database_code               4328714
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.53616(5) 0.82413(6) -0.37496(3) 0.0344(3) Uani 1 1 d .
Ag2 Ag 0.03524(16) 0.78671(17) -0.47590(9) 0.0309(6) Uani 0.90 1 d P
Ag2' Ag 0.0212(15) 0.7891(19) -0.4756(12) 0.044(9) Uiso 0.10 1 d P
Ag3 Ag 0.93319(5) 0.78234(7) -0.17370(3) 0.0379(3) Uani 1 1 d .
Ag4 Ag 0.20349(5) 0.95730(5) -0.29516(3) 0.0294(3) Uani 1 1 d .
N1 N 0.5437(6) 0.7672(6) -0.5344(3) 0.031(2) Uani 1 1 d U
C1 C 0.5246(6) 0.7000(7) -0.5454(4) 0.0266(13) Uani 1 1 d U
C2 C 0.4876(6) 0.6902(7) -0.5844(4) 0.0266(13) Uani 1 1 d U
H2A H 0.4759 0.6449 -0.5935 0.032 Uiso 1 1 calc R
N2 N 0.4703(6) 0.7453(6) -0.6072(3) 0.028(2) Uani 1 1 d U
C3 C 0.4870(6) 0.8096(7) -0.5960(4) 0.0266(13) Uani 1 1 d U
H3A H 0.4757 0.8475 -0.6134 0.032 Uiso 1 1 calc R
C4 C 0.5222(6) 0.8212(7) -0.5574(4) 0.0266(13) Uani 1 1 d U
N3 N 0.5455(6) 0.8873(5) -0.5441(3) 0.031(3) Uani 1 1 d .
C5 C 0.5298(8) 0.9519(7) -0.5694(5) 0.043(4) Uani 1 1 d .
H5A H 0.5483 0.9928 -0.5552 0.064 Uiso 1 1 calc R
H5B H 0.4793 0.9567 -0.5731 0.064 Uiso 1 1 calc R
H5C H 0.5517 0.9477 -0.5963 0.064 Uiso 1 1 calc R
N4 N 0.6541(5) 0.9039(6) -0.5095(3) 0.026(2) Uani 1 1 d U
C6 C 0.5847(6) 0.8951(6) -0.5066(4) 0.0235(13) Uani 1 1 d U
C7 C 0.5524(7) 0.8863(6) -0.4682(4) 0.0235(13) Uani 1 1 d U
H7A H 0.5032 0.8814 -0.4677 0.028 Uiso 1 1 calc R
N5 N 0.5889(5) 0.8844(6) -0.4317(3) 0.028(2) Uani 1 1 d U
C8 C 0.6586(6) 0.8969(6) -0.4351(4) 0.0235(13) Uani 1 1 d U
H8A H 0.6863 0.8995 -0.4108 0.028 Uiso 1 1 calc R
C9 C 0.6904(6) 0.9059(6) -0.4725(4) 0.0235(13) Uani 1 1 d U
N6 N 0.7661(6) 0.9139(6) -0.4753(4) 0.034(3) Uani 1 1 d .
C10 C 0.7947(8) 0.9677(7) -0.5047(4) 0.036(3) Uani 1 1 d .
H10A H 0.8457 0.9684 -0.5027 0.053 Uiso 1 1 calc R
H10B H 0.7763 1.0135 -0.4977 0.053 Uiso 1 1 calc R
H10C H 0.7805 0.9558 -0.5329 0.053 Uiso 1 1 calc R
N7 N 0.7691(6) 0.7921(6) -0.4594(3) 0.033(3) Uani 1 1 d .
C11 C 0.8082(8) 0.8530(7) -0.4678(4) 0.034(3) Uani 1 1 d .
C12 C 0.8824(7) 0.8511(7) -0.4708(4) 0.035(3) Uani 1 1 d .
H12A H 0.9073 0.8925 -0.4762 0.042 Uiso 1 1 calc R
N8 N 0.9178(6) 0.7898(6) -0.4658(3) 0.032(3) Uani 1 1 d .
C13 C 0.8814(7) 0.7312(7) -0.4583(4) 0.030(3) Uani 1 1 d .
H13A H 0.9058 0.6889 -0.4541 0.036 Uiso 1 1 calc R
C14 C 0.8044(7) 0.7314(8) -0.4565(4) 0.034(3) Uani 1 1 d .
N9 N 0.7681(6) 0.6715(6) -0.4505(3) 0.033(3) Uani 1 1 d .
C15 C 0.7951(8) 0.6027(8) -0.4653(5) 0.043(4) Uani 1 1 d .
H15A H 0.8462 0.6030 -0.4645 0.065 Uiso 1 1 calc R
H15B H 0.7788 0.5946 -0.4935 0.065 Uiso 1 1 calc R
H15C H 0.7779 0.5656 -0.4475 0.065 Uiso 1 1 calc R
N10 N 0.6564(6) 0.6566(5) -0.4842(3) 0.031(2) Uani 1 1 d .
C16 C 0.6912(8) 0.6780(7) -0.4498(4) 0.034(3) Uani 1 1 d .
C17 C 0.6574(7) 0.7092(7) -0.4149(4) 0.027(3) Uani 1 1 d .
H17A H 0.6846 0.7238 -0.3920 0.032 Uiso 1 1 calc R
N11 N 0.5878(6) 0.7178(6) -0.4148(3) 0.033(3) Uani 1 1 d .
C18 C 0.5496(8) 0.6938(7) -0.4482(5) 0.041(3) Uani 1 1 d .
H18A H 0.5002 0.6962 -0.4483 0.049 Uiso 1 1 calc R
C19 C 0.5866(8) 0.6643(6) -0.4838(4) 0.031(3) Uani 1 1 d .
N12 N 0.5455(6) 0.6481(6) -0.5196(3) 0.030(2) Uani 1 1 d .
C20 C 0.5291(8) 0.5733(8) -0.5274(5) 0.045(4) Uani 1 1 d .
H20A H 0.5005 0.5692 -0.5524 0.068 Uiso 1 1 calc R
H20B H 0.5035 0.5544 -0.5041 0.068 Uiso 1 1 calc R
H20C H 0.5726 0.5474 -0.5309 0.068 Uiso 1 1 calc R
N13 N 0.2695(5) 0.8050(5) -0.3899(3) 0.022(2) Uani 1 1 d .
C21 C 0.3122(8) 0.7480(6) -0.3868(4) 0.032(3) Uani 1 1 d .
C22 C 0.3865(7) 0.7546(7) -0.3832(4) 0.029(3) Uani 1 1 d .
H22A H 0.4142 0.7141 -0.3803 0.034 Uiso 1 1 calc R
N14 N 0.4165(6) 0.8150(6) -0.3837(4) 0.035(3) Uani 1 1 d .
C23 C 0.3744(7) 0.8736(8) -0.3862(4) 0.039(3) Uani 1 1 d .
H23A H 0.3957 0.9181 -0.3853 0.047 Uiso 1 1 calc R
C24 C 0.3021(6) 0.8694(6) -0.3900(3) 0.019(2) Uiso 1 1 d .
N15 N 0.2575(5) 0.9273(6) -0.3906(4) 0.033(3) Uani 1 1 d .
C25 C 0.2844(7) 0.9999(7) -0.3892(5) 0.035(3) Uani 1 1 d .
H25A H 0.2451 1.0324 -0.3886 0.052 Uiso 1 1 calc R
H25B H 0.3125 1.0088 -0.4135 0.052 Uiso 1 1 calc R
H25C H 0.3134 1.0062 -0.3645 0.052 Uiso 1 1 calc R
N16 N 0.1471(6) 0.9248(5) -0.3553(3) 0.026(2) Uani 1 1 d .
C26 C 0.1850(6) 0.9139(6) -0.3900(4) 0.023(3) Uani 1 1 d .
C27 C 0.1476(7) 0.8905(7) -0.4274(4) 0.032(3) Uani 1 1 d .
H27A H 0.1733 0.8823 -0.4516 0.039 Uiso 1 1 calc R
N17 N 0.0769(6) 0.8803(6) -0.4283(3) 0.035(3) Uani 1 1 d .
C28 C 0.0418(7) 0.8879(7) -0.3912(4) 0.031(3) Uani 1 1 d .
H28A H -0.0065 0.8775 -0.3900 0.037 Uiso 1 1 calc R
C29 C 0.0789(6) 0.9116(6) -0.3538(4) 0.022(3) Uani 1 1 d .
N18 N 0.0425(6) 0.9189(6) -0.3166(3) 0.029(2) Uani 1 1 d .
C30 C 0.0134(8) 0.9877(7) -0.3035(5) 0.040(4) Uani 1 1 d .
H30A H 0.0315 1.0244 -0.3212 0.059 Uiso 1 1 calc R
H30B H 0.0272 0.9970 -0.2750 0.059 Uiso 1 1 calc R
H30C H -0.0376 0.9866 -0.3057 0.059 Uiso 1 1 calc R
N19 N 0.0488(5) 0.7962(6) -0.3135(3) 0.028(2) Uani 1 1 d .
C31 C 0.0243(6) 0.8548(6) -0.2951(3) 0.022(3) Uani 1 1 d .
C32 C -0.0088(7) 0.8557(7) -0.2566(4) 0.028(3) Uani 1 1 d .
H32A H -0.0227 0.8986 -0.2450 0.034 Uiso 1 1 calc R
N20 N -0.0205(6) 0.7974(7) -0.2369(4) 0.036(3) Uani 1 1 d .
C33 C 0.0016(7) 0.7348(8) -0.2541(4) 0.036(3) Uani 1 1 d .
H33A H -0.0052 0.6922 -0.2401 0.043 Uiso 1 1 calc R
C34 C 0.0344(6) 0.7361(7) -0.2930(4) 0.029(3) Uani 1 1 d .
N21 N 0.0567(7) 0.6762(6) -0.3126(4) 0.039(3) Uani 1 1 d .
C35 C 0.0724(12) 0.6105(8) -0.2882(6) 0.068(6) Uani 1 1 d .
H35A H 0.0883 0.5741 -0.3068 0.102 Uiso 1 1 calc R
H35B H 0.0301 0.5951 -0.2744 0.102 Uiso 1 1 calc R
H35C H 0.1090 0.6202 -0.2677 0.102 Uiso 1 1 calc R
N22 N 0.1664(6) 0.6740(6) -0.3499(4) 0.0337(19) Uani 1 1 d .
C36 C 0.0970(7) 0.6832(7) -0.3512(4) 0.029(3) Uani 1 1 d .
C37 C 0.0593(7) 0.7010(6) -0.3872(4) 0.025(3) Uani 1 1 d .
H37A H 0.0100 0.7054 -0.3868 0.030 Uiso 1 1 calc R
N23 N 0.0945(6) 0.7116(6) -0.4217(4) 0.0337(19) Uani 1 1 d .
C38 C 0.1637(7) 0.7024(7) -0.4218(5) 0.034(3) Uani 1 1 d .
H38A H 0.1881 0.7078 -0.4467 0.041 Uiso 1 1 calc R
C39 C 0.2009(6) 0.6852(6) -0.3861(4) 0.024(3) Uani 1 1 d .
N24 N 0.2777(6) 0.6834(6) -0.3859(4) 0.040(3) Uani 1 1 d .
C40 C 0.3139(7) 0.6202(7) -0.3696(5) 0.035(3) Uani 1 1 d .
H40A H 0.3644 0.6267 -0.3710 0.053 Uiso 1 1 calc R
H40B H 0.3003 0.5798 -0.3861 0.053 Uiso 1 1 calc R
H40C H 0.3005 0.6126 -0.3410 0.053 Uiso 1 1 calc R
N25 N 0.6943(6) 0.7447(5) -0.0981(3) 0.030(3) Uani 1 1 d .
C41 C 0.6811(7) 0.6778(9) -0.0850(4) 0.038(3) Uani 1 1 d .
C42 C 0.6385(6) 0.6652(7) -0.0484(4) 0.032(3) Uani 1 1 d .
H42A H 0.6292 0.6193 -0.0394 0.038 Uiso 1 1 calc R
N26 N 0.6127(6) 0.7213(6) -0.0276(4) 0.034(3) Uani 1 1 d .
C43 C 0.6250(7) 0.7879(9) -0.0421(4) 0.039(3) Uani 1 1 d .
H43A H 0.6051 0.8268 -0.0287 0.047 Uiso 1 1 calc R
C44 C 0.6681(7) 0.7973(7) -0.0772(4) 0.032(3) Uani 1 1 d .
N27 N 0.6824(6) 0.8636(6) -0.0937(3) 0.035(3) Uani 1 1 d .
C45 C 0.6398(11) 0.9273(8) -0.0786(6) 0.065(5) Uani 1 1 d .
H45A H 0.6143 0.9147 -0.0538 0.097 Uiso 1 1 calc R
H45B H 0.6068 0.9417 -0.1001 0.097 Uiso 1 1 calc R
H45C H 0.6717 0.9657 -0.0723 0.097 Uiso 1 1 calc R
N28 N 0.6889(6) 0.8922(6) -0.1645(3) 0.034(3) Uani 1 1 d .
C46 C 0.7241(6) 0.8717(6) -0.1295(4) 0.020(2) Uiso 1 1 d .
C47 C 0.7942(7) 0.8515(6) -0.1302(4) 0.029(3) Uani 1 1 d .
H47A H 0.8144 0.8317 -0.1062 0.034 Uiso 1 1 calc R
N29 N 0.8347(5) 0.8591(6) -0.1643(3) 0.028(2) Uani 1 1 d .
C48 C 0.8013(6) 0.8823(7) -0.1984(4) 0.026(3) Uani 1 1 d .
H48A H 0.8280 0.8882 -0.2225 0.031 Uiso 1 1 calc R
C49 C 0.7324(7) 0.8978(7) -0.2006(4) 0.029(3) Uani 1 1 d .
N30 N 0.6943(6) 0.9134(6) -0.2381(3) 0.034(3) Uani 1 1 d .
C50 C 0.6861(9) 0.9859(8) -0.2504(5) 0.053(4) Uani 1 1 d .
H50A H 0.7068 1.0161 -0.2293 0.079 Uiso 1 1 calc R
H50B H 0.6364 0.9967 -0.2535 0.079 Uiso 1 1 calc R
H50C H 0.7096 0.9935 -0.2765 0.079 Uiso 1 1 calc R
N31 N 0.6864(5) 0.7936(6) -0.2465(4) 0.034(3) Uani 1 1 d .
C51 C 0.6709(7) 0.8579(8) -0.2605(4) 0.035(3) Uani 1 1 d .
C52 C 0.6313(6) 0.8654(7) -0.2997(4) 0.029(3) Uani 1 1 d .
H52A H 0.6222 0.9101 -0.3108 0.034 Uiso 1 1 calc R
N32 N 0.6087(5) 0.8084(6) -0.3190(3) 0.029(2) Uani 1 1 d .
C53 C 0.6257(6) 0.7435(7) -0.3064(4) 0.024(3) Uani 1 1 d .
H53A H 0.6119 0.7039 -0.3218 0.029 Uiso 1 1 calc R
C54 C 0.6661(8) 0.7363(10) -0.2684(5) 0.049(4) Uani 1 1 d .
N33 N 0.6823(6) 0.6690(5) -0.2522(3) 0.028(2) Uani 1 1 d .
C55 C 0.6374(8) 0.6072(7) -0.2623(4) 0.037(3) Uani 1 1 d .
H55A H 0.6111 0.6162 -0.2877 0.055 Uiso 1 1 calc R
H55B H 0.6048 0.5989 -0.2399 0.055 Uiso 1 1 calc R
H55C H 0.6669 0.5662 -0.2659 0.055 Uiso 1 1 calc R
N34 N 0.6962(6) 0.6402(6) -0.1800(4) 0.035(3) Uani 1 1 d .
C56 C 0.7261(8) 0.6673(7) -0.2163(4) 0.034(3) Uani 1 1 d .
C57 C 0.7945(6) 0.6960(6) -0.2154(4) 0.022(2) Uiso 1 1 d .
H57A H 0.8107 0.7181 -0.2395 0.027 Uiso 1 1 calc R
N35 N 0.8368(6) 0.6938(6) -0.1834(3) 0.030(2) Uani 1 1 d .
C58 C 0.8096(7) 0.6638(8) -0.1466(4) 0.038(3) Uani 1 1 d .
H58A H 0.8386 0.6598 -0.1230 0.046 Uiso 1 1 calc R
C59 C 0.7404(7) 0.6403(6) -0.1455(4) 0.030(3) Uani 1 1 d .
N36 N 0.7109(6) 0.6205(5) -0.1075(3) 0.031(2) Uani 1 1 d .
C60 C 0.6840(13) 0.5480(10) -0.1011(5) 0.078(7) Uani 1 1 d .
H60A H 0.7094 0.5158 -0.1187 0.117 Uiso 1 1 calc R
H60B H 0.6342 0.5464 -0.1081 0.117 Uiso 1 1 calc R
H60C H 0.6908 0.5347 -0.0723 0.117 Uiso 1 1 calc R
N37 N 0.2738(5) 0.7195(6) -0.2289(4) 0.032(3) Uani 1 1 d .
C61 C 0.2240(7) 0.6829(7) -0.2092(4) 0.034(3) Uani 1 1 d .
C62 C 0.2261(6) 0.6098(6) -0.2073(4) 0.026(3) Uani 1 1 d .
H62A H 0.1897 0.5852 -0.1943 0.031 Uiso 1 1 calc R
N38 N 0.2801(5) 0.5746(6) -0.2240(4) 0.031(3) Uani 1 1 d .
C63 C 0.3317(7) 0.6100(7) -0.2420(5) 0.035(3) Uani 1 1 d .
H63A H 0.3706 0.5859 -0.2527 0.042 Uiso 1 1 calc R
C64 C 0.3281(6) 0.6849(7) -0.2452(4) 0.030(3) Uani 1 1 d .
N39 N 0.3770(6) 0.7239(5) -0.2644(4) 0.032(2) Uani 1 1 d .
C65 C 0.4501(7) 0.6943(6) -0.2695(5) 0.032(2) Uani 1 1 d .
H65A H 0.4472 0.6440 -0.2732 0.049 Uiso 1 1 calc R
H65B H 0.4782 0.7048 -0.2450 0.049 Uiso 1 1 calc R
H65C H 0.4718 0.7152 -0.2936 0.049 Uiso 1 1 calc R
N40 N 0.4156(5) 0.8297(5) -0.2289(3) 0.023(2) Uani 1 1 d .
C66 C 0.3746(6) 0.7978(6) -0.2596(4) 0.025(3) Uani 1 1 d .
C67 C 0.3266(7) 0.8365(7) -0.2822(4) 0.029(3) Uani 1 1 d .
H67A H 0.2989 0.8137 -0.3025 0.035 Uiso 1 1 calc R
N41 N 0.3177(6) 0.9066(5) -0.2764(3) 0.029(2) Uani 1 1 d .
C68 C 0.3546(6) 0.9347(7) -0.2460(4) 0.028(3) Uani 1 1 d .
H68A H 0.3473 0.9822 -0.2395 0.033 Uiso 1 1 calc R
C69 C 0.4050(6) 0.8962(7) -0.2228(4) 0.028(3) Uani 1 1 d .
N42 N 0.4431(6) 0.9305(6) -0.1895(4) 0.035(3) Uani 1 1 d .
C70 C 0.5197(7) 0.9195(9) -0.1875(5) 0.046(4) Uani 1 1 d .
H70A H 0.5362 0.9041 -0.2144 0.068 Uiso 1 1 calc R
H70B H 0.5306 0.8840 -0.1669 0.068 Uiso 1 1 calc R
H70C H 0.5429 0.9630 -0.1800 0.068 Uiso 1 1 calc R
N43 N 0.3364(6) 0.9375(6) -0.1537(3) 0.031(2) Uani 1 1 d .
C71 C 0.4045(7) 0.9525(7) -0.1532(4) 0.033(3) Uani 1 1 d .
C72 C 0.4383(10) 0.9871(9) -0.1209(5) 0.055(4) Uani 1 1 d .
H72A H 0.4867 0.9971 -0.1220 0.066 Uiso 1 1 calc R
N44 N 0.3989(7) 1.0066(8) -0.0871(4) 0.057(4) Uani 1 1 d .
C73 C 0.3311(10) 0.9942(8) -0.0863(5) 0.051(4) Uani 1 1 d .
H73A H 0.3044 1.0102 -0.0638 0.061 Uiso 1 1 calc R
C74 C 0.2957(10) 0.9546(8) -0.1210(5) 0.046(4) Uani 1 1 d .
N45 N 0.2266(6) 0.9333(6) -0.1224(4) 0.035(3) Uani 1 1 d .
C75 C 0.1909(11) 0.9238(12) -0.0814(5) 0.080(7) Uani 1 1 d .
H75A H 0.1425 0.9094 -0.0861 0.120 Uiso 1 1 calc R
H75B H 0.1917 0.9678 -0.0663 0.120 Uiso 1 1 calc R
H75C H 0.2154 0.8882 -0.0654 0.120 Uiso 1 1 calc R
N46 N 0.1931(6) 0.8289(6) -0.1556(3) 0.030(2) Uani 1 1 d .
C76 C 0.2023(7) 0.8991(6) -0.1574(4) 0.031(3) Uani 1 1 d .
C77 C 0.1919(7) 0.9356(6) -0.1953(4) 0.030(3) Uani 1 1 d .
H77A H 0.1975 0.9845 -0.1957 0.036 Uiso 1 1 calc R
N47 N 0.1748(5) 0.9028(6) -0.2300(3) 0.028(2) Uani 1 1 d .
C78 C 0.1654(7) 0.8331(6) -0.2293(5) 0.033(3) Uani 1 1 d .
H78A H 0.1512 0.8090 -0.2534 0.040 Uiso 1 1 calc R
C79 C 0.1770(7) 0.7973(8) -0.1924(5) 0.037(3) Uani 1 1 d .
N48 N 0.1682(6) 0.7233(6) -0.1910(5) 0.047(3) Uani 1 1 d .
C80 C 0.1262(10) 0.6897(9) -0.1572(5) 0.057(5) Uani 1 1 d .
H80A H 0.1250 0.6393 -0.1614 0.085 Uiso 1 1 calc R
H80B H 0.0785 0.7080 -0.1579 0.085 Uiso 1 1 calc R
H80C H 0.1478 0.6999 -0.1305 0.085 Uiso 1 1 calc R
B1 B 1.0057(13) 0.5179(14) -0.1859(7) 0.068(3) Uani 1 1 d .
F11 F 0.9755(6) 0.5869(6) -0.1855(4) 0.086(4) Uani 1 1 d .
F12 F 0.9701(7) 0.4815(6) -0.1555(3) 0.082(4) Uani 1 1 d .
F13 F 0.9905(5) 0.4876(6) -0.2234(3) 0.063(3) Uani 1 1 d .
F14 F 1.0763(5) 0.5259(5) -0.1772(3) 0.055(2) Uani 1 1 d .
B2 B 0.8215(14) 0.8914(15) 0.0032(7) 0.068(3) Uani 1 1 d U
F21 F 0.7663(10) 0.8643(17) 0.0105(6) 0.203(11) Uani 1 1 d U
F22 F 0.8145(14) 0.9608(11) 0.0005(6) 0.174(9) Uani 1 1 d U
F23 F 0.8740(10) 0.8746(11) 0.0323(5) 0.145(7) Uani 1 1 d U
F24 F 0.8491(9) 0.8721(9) -0.0353(5) 0.117(5) Uani 1 1 d U
B3 B 0.0103(13) 1.0131(14) -0.1667(7) 0.068(3) Uani 1 1 d .
F31 F 0.0321(9) 0.9666(9) -0.1383(5) 0.127(6) Uani 1 1 d .
F32 F -0.0059(9) 1.0807(7) -0.1499(4) 0.106(5) Uani 1 1 d .
F33 F -0.0497(7) 0.9909(8) -0.1868(5) 0.102(4) Uani 1 1 d .
F34 F 0.0608(6) 1.0253(6) -0.1978(4) 0.082(4) Uani 1 1 d .
B4 B 0.6727(8) 0.3668(12) -0.1668(5) 0.068(3) Uani 1 1 d DU
F41 F 0.6618(18) 0.4316(14) -0.1824(10) 0.245(13) Uani 1 1 d DU
F42 F 0.7292(8) 0.3547(16) -0.1427(5) 0.190(10) Uani 1 1 d DU
F43 F 0.6153(9) 0.3685(15) -0.1428(6) 0.183(10) Uani 1 1 d DU
F44 F 0.6688(9) 0.3234(9) -0.2001(5) 0.122(5) Uani 1 1 d DU
O1W O 0.292(3) 1.042(2) -0.209(2) 0.25(4) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N32 Ag1 N14 132.5(4) . .
N32 Ag1 N5 114.5(4) . .
N14 Ag1 N5 111.5(4) . .
N32 Ag1 N11 93.5(4) . .
N14 Ag1 N11 105.0(4) . .
N5 Ag1 N11 80.4(4) . .
N26 Ag2 N8 140.1(4) 4_575 1_455
N26 Ag2 N17 107.6(4) 4_575 .
N8 Ag2 N17 101.6(4) 1_455 .
N26 Ag2 N23 100.7(4) 4_575 .
N8 Ag2 N23 110.4(4) 1_455 .
N17 Ag2 N23 81.0(4) . .
N8 Ag2' N26 145.2(19) 1_455 4_575
N8 Ag2' N17 107.7(15) 1_455 .
N26 Ag2' N17 100.0(12) 4_575 .
N8 Ag2' N23 114.2(16) 1_455 .
N26 Ag2' N23 91.9(10) 4_575 .
N17 Ag2' N23 77.2(10) . .
N20 Ag3 N2 138.8(4) 1_655 4_676
N20 Ag3 N29 110.5(4) 1_655 .
N2 Ag3 N29 104.6(4) 4_676 .
N20 Ag3 N35 105.4(4) 1_655 .
N2 Ag3 N35 100.1(4) 4_676 .
N29 Ag3 N35 81.8(4) . .
N16 Ag4 N38 122.8(4) . 2_554
N16 Ag4 N47 120.9(4) . .
N38 Ag4 N47 102.2(4) 2_554 .
N16 Ag4 N41 120.5(4) . .
N38 Ag4 N41 101.4(3) 2_554 .
N47 Ag4 N41 79.8(4) . .
C4 N1 C1 119.9(11) . .
N12 C1 N1 116.7(11) . .
N12 C1 C2 125.2(12) . .
N1 C1 C2 117.9(11) . .
N2 C2 C1 119.7(12) . .
N2 C2 H2A 120.1 . .
C1 C2 H2A 120.1 . .
C3 N2 C2 122.1(11) . .
C3 N2 Ag3 122.4(9) . 4_575
C2 N2 Ag3 113.9(8) . 4_575
N2 C3 C4 119.5(12) . .
N2 C3 H3A 120.2 . .
C4 C3 H3A 120.2 . .
N1 C4 N3 115.7(11) . .
N1 C4 C3 120.3(12) . .
N3 C4 C3 123.3(12) . .
C4 N3 C6 120.9(10) . .
C4 N3 C5 120.8(11) . .
C6 N3 C5 118.3(10) . .
N3 C5 H5A 109.5 . .
N3 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
N3 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C6 N4 C9 115.5(10) . .
N4 C6 C7 121.4(10) . .
N4 C6 N3 117.6(11) . .
C7 C6 N3 120.7(11) . .
N5 C7 C6 123.1(11) . .
N5 C7 H7A 118.5 . .
C6 C7 H7A 118.5 . .
C8 N5 C7 114.4(10) . .
C8 N5 Ag1 124.6(8) . .
C7 N5 Ag1 117.5(8) . .
N5 C8 C9 122.6(11) . .
N5 C8 H8A 118.7 . .
C9 C8 H8A 118.7 . .
C8 C9 N4 122.8(11) . .
C8 C9 N6 121.0(11) . .
N4 C9 N6 116.1(11) . .
C11 N6 C9 117.2(10) . .
C11 N6 C10 117.1(11) . .
C9 N6 C10 118.4(11) . .
N6 C10 H10A 109.5 . .
N6 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
N6 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C14 N7 C11 117.5(12) . .
N7 C11 C12 121.4(12) . .
N7 C11 N6 114.1(12) . .
C12 C11 N6 124.4(11) . .
N8 C12 C11 120.5(12) . .
N8 C12 H12A 119.7 . .
C11 C12 H12A 119.7 . .
C13 N8 C12 118.9(11) . .
C13 N8 Ag2' 122.3(14) . 1_655
C12 N8 Ag2' 118.5(14) . 1_655
C13 N8 Ag2 121.2(8) . 1_655
C12 N8 Ag2 119.7(9) . 1_655
Ag2' N8 Ag2 1.3(12) 1_655 1_655
N8 C13 C14 121.6(12) . .
N8 C13 H13A 119.2 . .
C14 C13 H13A 119.2 . .
N7 C14 N9 119.0(12) . .
N7 C14 C13 119.9(12) . .
N9 C14 C13 121.1(13) . .
C14 N9 C16 116.2(11) . .
C14 N9 C15 121.4(12) . .
C16 N9 C15 115.2(11) . .
N9 C15 H15A 109.5 . .
N9 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
N9 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C19 N10 C16 115.8(11) . .
N10 C16 C17 123.6(13) . .
N10 C16 N9 116.1(12) . .
C17 C16 N9 120.2(12) . .
N11 C17 C16 120.5(12) . .
N11 C17 H17A 119.7 . .
C16 C17 H17A 119.7 . .
C17 N11 C18 118.2(12) . .
C17 N11 Ag1 118.5(9) . .
C18 N11 Ag1 116.8(9) . .
N11 C18 C19 119.4(13) . .
N11 C18 H18A 120.3 . .
C19 C18 H18A 120.3 . .
N10 C19 N12 120.4(11) . .
N10 C19 C18 122.3(12) . .
N12 C19 C18 117.2(13) . .
C1 N12 C19 119.7(11) . .
C1 N12 C20 122.9(11) . .
C19 N12 C20 117.4(10) . .
N12 C20 H20A 109.5 . .
N12 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
N12 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C21 N13 C24 116.5(10) . .
N13 C21 N24 115.3(12) . .
N13 C21 C22 121.8(11) . .
N24 C21 C22 122.9(11) . .
N14 C22 C21 121.3(12) . .
N14 C22 H22A 119.4 . .
C21 C22 H22A 119.4 . .
C22 N14 C23 118.1(12) . .
C22 N14 Ag1 120.4(9) . .
C23 N14 Ag1 121.3(9) . .
N14 C23 C24 122.3(13) . .
N14 C23 H23A 118.9 . .
C24 C23 H23A 118.9 . .
N13 C24 C23 120.0(11) . .
N13 C24 N15 115.8(10) . .
C23 C24 N15 124.0(11) . .
C24 N15 C26 116.9(10) . .
C24 N15 C25 122.3(10) . .
C26 N15 C25 120.7(11) . .
N15 C25 H25A 109.5 . .
N15 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
N15 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C29 N16 C26 122.1(10) . .
C29 N16 Ag4 118.0(8) . .
C26 N16 Ag4 119.7(8) . .
N16 C26 N15 121.0(11) . .
N16 C26 C27 118.2(11) . .
N15 C26 C27 120.8(11) . .
N17 C27 C26 122.1(12) . .
N17 C27 H27A 118.9 . .
C26 C27 H27A 118.9 . .
C27 N17 C28 117.0(11) . .
C27 N17 Ag2 115.1(9) . .
C28 N17 Ag2 117.2(8) . .
C27 N17 Ag2' 121.1(11) . .
C28 N17 Ag2' 112.9(11) . .
Ag2 N17 Ag2' 6.0(7) . .
N17 C28 C29 120.8(11) . .
N17 C28 H28A 119.6 . .
C29 C28 H28A 119.6 . .
N16 C29 N18 120.5(11) . .
N16 C29 C28 119.6(11) . .
N18 C29 C28 119.9(11) . .
C29 N18 C31 116.8(10) . .
C29 N18 C30 121.4(10) . .
C31 N18 C30 121.1(10) . .
N18 C30 H30A 109.5 . .
N18 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
N18 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C31 N19 C34 114.6(11) . .
N19 C31 C32 124.0(11) . .
N19 C31 N18 113.8(10) . .
C32 C31 N18 121.8(11) . .
N20 C32 C31 120.3(12) . .
N20 C32 H32A 119.9 . .
C31 C32 H32A 119.9 . .
C32 N20 C33 119.3(12) . .
C32 N20 Ag3 128.5(10) . 1_455
C33 N20 Ag3 112.1(9) . 1_455
N20 C33 C34 118.7(12) . .
N20 C33 H33A 120.6 . .
C34 C33 H33A 120.6 . .
N19 C34 N21 114.4(12) . .
N19 C34 C33 123.0(13) . .
N21 C34 C33 122.6(12) . .
C34 N21 C36 118.7(10) . .
C34 N21 C35 120.6(13) . .
C36 N21 C35 114.5(13) . .
N21 C35 H35A 109.5 . .
N21 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
N21 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C36 N22 C39 116.2(11) . .
N22 C36 C37 123.6(12) . .
N22 C36 N21 119.1(12) . .
C37 C36 N21 117.2(12) . .
N23 C37 C36 118.5(12) . .
N23 C37 H37A 120.7 . .
C36 C37 H37A 120.7 . .
C37 N23 C38 119.6(12) . .
C37 N23 Ag2 116.5(9) . .
C38 N23 Ag2 120.5(9) . .
C37 N23 Ag2' 111.7(11) . .
C38 N23 Ag2' 125.6(11) . .
Ag2 N23 Ag2' 5.0(7) . .
N23 C38 C39 121.8(14) . .
N23 C38 H38A 119.1 . .
C39 C38 H38A 119.1 . .
N22 C39 C38 120.2(11) . .
N22 C39 N24 119.0(11) . .
C38 C39 N24 120.7(12) . .
C21 N24 C39 116.7(11) . .
C21 N24 C40 120.7(11) . .
C39 N24 C40 118.6(11) . .
N24 C40 H40A 109.5 . .
N24 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
N24 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C44 N25 C41 118.9(12) . .
N25 C41 N36 118.7(11) . .
N25 C41 C42 120.6(13) . .
N36 C41 C42 120.7(13) . .
N26 C42 C41 118.4(12) . .
N26 C42 H42A 120.8 . .
C41 C42 H42A 120.8 . .
C42 N26 C43 119.9(11) . .
C42 N26 Ag2 123.9(9) . 4_676
C43 N26 Ag2 115.5(9) . 4_676
C42 N26 Ag2' 122.7(12) . 4_676
C43 N26 Ag2' 115.7(12) . 4_676
Ag2 N26 Ag2' 4.6(9) 4_676 4_676
N26 C43 C44 119.3(13) . .
N26 C43 H43A 120.3 . .
C44 C43 H43A 120.3 . .
N25 C44 N27 114.9(12) . .
N25 C44 C43 122.7(13) . .
N27 C44 C43 122.3(12) . .
C44 N27 C46 121.4(11) . .
C44 N27 C45 119.2(12) . .
C46 N27 C45 118.1(11) . .
N27 C45 H45A 109.5 . .
N27 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
N27 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
C46 N28 C49 114.3(10) . .
N28 C46 C47 121.8(11) . .
N28 C46 N27 115.7(10) . .
C47 C46 N27 122.0(11) . .
N29 C47 C46 122.5(12) . .
N29 C47 H47A 118.7 . .
C46 C47 H47A 118.7 . .
C48 N29 C47 115.7(11) . .
C48 N29 Ag3 117.5(8) . .
C47 N29 Ag3 119.1(8) . .
N29 C48 C49 124.7(11) . .
N29 C48 H48A 117.7 . .
C49 C48 H48A 117.7 . .
C48 C49 N30 125.0(12) . .
C48 C49 N28 120.5(11) . .
N30 C49 N28 114.2(11) . .
C51 N30 C49 116.5(11) . .
C51 N30 C50 124.6(12) . .
C49 N30 C50 118.9(11) . .
N30 C50 H50A 109.5 . .
N30 C50 H50B 109.5 . .
H50A C50 H50B 109.5 . .
N30 C50 H50C 109.5 . .
H50A C50 H50C 109.5 . .
H50B C50 H50C 109.5 . .
C51 N31 C54 120.2(12) . .
N31 C51 N30 117.9(12) . .
N31 C51 C52 119.2(13) . .
N30 C51 C52 122.9(12) . .
N32 C52 C51 119.0(12) . .
N32 C52 H52A 120.5 . .
C51 C52 H52A 120.5 . .
C52 N32 C53 122.7(11) . .
C52 N32 Ag1 117.1(9) . .
C53 N32 Ag1 120.2(8) . .
N32 C53 C54 117.9(12) . .
N32 C53 H53A 121.1 . .
C54 C53 H53A 121.1 . .
N31 C54 N33 118.5(13) . .
N31 C54 C53 120.7(14) . .
N33 C54 C53 120.6(15) . .
C56 N33 C54 116.4(11) . .
C56 N33 C55 119.4(10) . .
C54 N33 C55 120.9(11) . .
N33 C55 H55A 109.5 . .
N33 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
N33 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
C59 N34 C56 114.9(11) . .
N34 C56 C57 120.6(12) . .
N34 C56 N33 116.6(12) . .
C57 C56 N33 122.6(11) . .
N35 C57 C56 124.2(12) . .
N35 C57 H57A 117.9 . .
C56 C57 H57A 117.9 . .
C57 N35 C58 116.7(11) . .
C57 N35 Ag3 121.3(9) . .
C58 N35 Ag3 116.1(8) . .
C59 C58 N35 120.3(12) . .
C59 C58 H58A 119.8 . .
N35 C58 H58A 119.8 . .
N34 C59 C58 122.9(12) . .
N34 C59 N36 117.2(12) . .
C58 C59 N36 119.7(12) . .
C59 N36 C41 113.5(10) . .
C59 N36 C60 120.8(11) . .
C41 N36 C60 120.0(12) . .
N36 C60 H60A 109.5 . .
N36 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
N36 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
C64 N37 C61 118.7(11) . .
N37 C61 C62 121.4(12) . .
N37 C61 N48 116.1(11) . .
C62 C61 N48 122.5(12) . .
N38 C62 C61 120.2(11) . .
N38 C62 H62A 119.9 . .
C61 C62 H62A 119.9 . .
C63 N38 C62 119.4(11) . .
C63 N38 Ag4 120.3(8) . 2_544
C62 N38 Ag4 118.1(8) . 2_544
N38 C63 C64 120.2(12) . .
N38 C63 H63A 119.9 . .
C64 C63 H63A 119.9 . .
N37 C64 N39 116.6(11) . .
N37 C64 C63 120.1(12) . .
N39 C64 C63 123.3(12) . .
C64 N39 C66 118.3(10) . .
C64 N39 C65 118.9(10) . .
C66 N39 C65 114.5(10) . .
N39 C65 H65A 109.5 . .
N39 C65 H65B 109.5 . .
H65A C65 H65B 109.5 . .
N39 C65 H65C 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
C69 N40 C66 116.6(10) . .
C67 C66 N40 120.3(11) . .
C67 C66 N39 119.8(12) . .
N40 C66 N39 119.5(11) . .
N41 C67 C66 122.4(12) . .
N41 C67 H67A 118.8 . .
C66 C67 H67A 118.8 . .
C68 N41 C67 116.1(11) . .
C68 N41 Ag4 119.2(8) . .
C67 N41 Ag4 117.7(8) . .
N41 C68 C69 122.4(12) . .
N41 C68 H68A 118.8 . .
C69 C68 H68A 118.8 . .
N40 C69 C68 122.1(12) . .
N40 C69 N42 118.5(12) . .
C68 C69 N42 119.3(11) . .
C69 N42 C71 118.5(10) . .
C69 N42 C70 117.0(12) . .
C71 N42 C70 121.0(11) . .
N42 C70 H70A 109.5 . .
N42 C70 H70B 109.5 . .
H70A C70 H70B 109.5 . .
N42 C70 H70C 109.5 . .
H70A C70 H70C 109.5 . .
H70B C70 H70C 109.5 . .
C71 N43 C74 120.2(13) . .
N43 C71 C72 123.8(15) . .
N43 C71 N42 115.5(11) . .
C72 C71 N42 120.7(13) . .
N44 C72 C71 118.2(16) . .
N44 C72 H72A 120.9 . .
C71 C72 H72A 120.9 . .
C73 N44 C72 120.6(14) . .
N44 C73 C74 120.4(15) . .
N44 C73 H73A 119.8 . .
C74 C73 H73A 119.8 . .
N43 C74 N45 117.1(13) . .
N43 C74 C73 116.7(15) . .
N45 C74 C73 126.2(15) . .
C74 N45 C76 118.4(12) . .
C74 N45 C75 116.6(12) . .
C76 N45 C75 120.9(12) . .
N45 C75 H75A 109.5 . .
N45 C75 H75B 109.5 . .
H75A C75 H75B 109.5 . .
N45 C75 H75C 109.5 . .
H75A C75 H75C 109.5 . .
H75B C75 H75C 109.5 . .
C76 N46 C79 115.4(11) . .
N46 C76 N45 118.3(12) . .
N46 C76 C77 120.4(12) . .
N45 C76 C77 121.1(11) . .
N47 C77 C76 122.0(11) . .
N47 C77 H77A 119.0 . .
C76 C77 H77A 119.0 . .
C77 N47 C78 119.1(11) . .
C77 N47 Ag4 118.6(9) . .
C78 N47 Ag4 118.3(9) . .
N47 C78 C79 118.9(13) . .
N47 C78 H78A 120.6 . .
C79 C78 H78A 120.6 . .
N46 C79 C78 124.1(13) . .
N46 C79 N48 115.9(12) . .
C78 C79 N48 119.9(14) . .
C79 N48 C61 115.5(11) . .
C79 N48 C80 120.8(13) . .
C61 N48 C80 117.8(12) . .
N48 C80 H80A 109.5 . .
N48 C80 H80B 109.5 . .
H80A C80 H80B 109.5 . .
N48 C80 H80C 109.5 . .
H80A C80 H80C 109.5 . .
H80B C80 H80C 109.5 . .
F13 B1 F14 114.9(17) . .
F13 B1 F12 108.4(18) . .
F14 B1 F12 113.2(19) . .
F13 B1 F11 108.4(19) . .
F14 B1 F11 106.5(18) . .
F12 B1 F11 104.8(17) . .
F21 B2 F22 111(3) . .
F21 B2 F23 113(2) . .
F22 B2 F23 110(2) . .
F21 B2 F24 114(2) . .
F22 B2 F24 104(2) . .
F23 B2 F24 105(2) . .
F31 B3 F33 112(2) . .
F31 B3 F34 113(2) . .
F33 B3 F34 106.5(17) . .
F31 B3 F32 113.7(18) . .
F33 B3 F32 106(2) . .
F34 B3 F32 105.7(19) . .
F42 B4 F43 108.5(17) . .
F42 B4 F41 120(3) . .
F43 B4 F41 94(2) . .
F42 B4 F44 112.9(18) . .
F43 B4 F44 115.7(19) . .
F41 B4 F44 104.9(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N32 2.253(10) .
Ag1 N14 2.269(11) .
Ag1 N5 2.367(10) .
Ag1 N11 2.574(11) .
Ag2 N26 2.220(11) 4_575
Ag2 N8 2.235(11) 1_455
Ag2 N17 2.454(11) .
Ag2 N23 2.491(11) .
Ag2' N8 1.97(3) 1_455
Ag2' N26 2.41(3) 4_575
Ag2' N17 2.51(4) .
Ag2' N23 2.63(4) .
Ag3 N20 2.228(11) 1_655
Ag3 N2 2.288(10) 4_676
Ag3 N29 2.373(10) .
Ag3 N35 2.482(11) .
Ag4 N16 2.266(9) .
Ag4 N38 2.318(10) 2_554
Ag4 N47 2.389(10) .
Ag4 N41 2.419(10) .
N1 C4 1.317(17) .
N1 C1 1.363(17) .
C1 N12 1.335(16) .
C1 C2 1.432(17) .
C2 N2 1.308(17) .
C2 H2A 0.9300 .
N2 C3 1.302(16) .
N2 Ag3 2.288(10) 4_575
C3 C4 1.411(17) .
C3 H3A 0.9300 .
C4 N3 1.388(16) .
N3 C6 1.407(15) .
N3 C5 1.490(16) .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
N4 C6 1.319(15) .
N4 C9 1.355(15) .
C6 C7 1.385(18) .
C7 N5 1.348(15) .
C7 H7A 0.9300 .
N5 C8 1.336(15) .
C8 C9 1.354(18) .
C8 H8A 0.9300 .
C9 N6 1.435(16) .
N6 C11 1.415(17) .
N6 C10 1.489(16) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
N7 C14 1.328(17) .
N7 C11 1.392(17) .
C11 C12 1.399(19) .
C12 N8 1.343(17) .
C12 H12A 0.9300 .
N8 C13 1.325(17) .
N8 Ag2' 1.97(3) 1_655
N8 Ag2 2.235(11) 1_655
C13 C14 1.449(18) .
C13 H13A 0.9300 .
C14 N9 1.336(17) .
N9 C16 1.451(18) .
N9 C15 1.476(17) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
N10 C19 1.321(18) .
N10 C16 1.333(17) .
C16 C17 1.416(18) .
C17 N11 1.319(16) .
C17 H17A 0.9300 .
N11 C18 1.357(18) .
C18 C19 1.45(2) .
C18 H18A 0.9300 .
C19 N12 1.407(16) .
N12 C20 1.466(19) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
N13 C21 1.346(16) .
N13 C24 1.361(15) .
C21 N24 1.382(17) .
C21 C22 1.404(19) .
C22 N14 1.272(17) .
C22 H22A 0.9300 .
N14 C23 1.363(18) .
C23 C24 1.367(18) .
C23 H23A 0.9300 .
C24 N15 1.377(16) .
N15 C26 1.387(16) .
N15 C25 1.462(16) .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
N16 C29 1.306(16) .
N16 C26 1.341(16) .
C26 C27 1.448(17) .
C27 N17 1.342(17) .
C27 H27A 0.9300 .
N17 C28 1.372(17) .
C28 C29 1.446(18) .
C28 H28A 0.9300 .
C29 N18 1.385(15) .
N18 C31 1.434(16) .
N18 C30 1.473(16) .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
N19 C31 1.338(16) .
N19 C34 1.339(16) .
C31 C32 1.385(17) .
C32 N20 1.288(17) .
C32 H32A 0.9300 .
N20 C33 1.370(19) .
N20 Ag3 2.228(11) 1_455
C33 C34 1.393(19) .
C33 H33A 0.9300 .
C34 N21 1.361(18) .
N21 C36 1.459(17) .
N21 C35 1.493(19) .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
N22 C36 1.317(17) .
N22 C39 1.348(17) .
C36 C37 1.385(17) .
C37 N23 1.307(17) .
C37 H37A 0.9300 .
N23 C38 1.312(17) .
C38 C39 1.370(19) .
C38 H38A 0.9300 .
C39 N24 1.444(15) .
N24 C40 1.466(17) .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
N25 C44 1.297(16) .
N25 C41 1.354(18) .
C41 N36 1.418(18) .
C41 C42 1.446(18) .
C42 N26 1.343(17) .
C42 H42A 0.9300 .
N26 C43 1.360(19) .
N26 Ag2 2.220(11) 4_676
N26 Ag2' 2.41(3) 4_676
C43 C44 1.404(19) .
C43 H43A 0.9300 .
C44 N27 1.385(18) .
N27 C46 1.402(16) .
N27 C45 1.528(19) .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
N28 C46 1.348(16) .
N28 C49 1.427(17) .
C46 C47 1.373(17) .
C47 N29 1.344(16) .
C47 H47A 0.9300 .
N29 C48 1.323(16) .
C48 C49 1.330(18) .
C48 H48A 0.9300 .
C49 N30 1.417(16) .
N30 C51 1.342(18) .
N30 C50 1.431(19) .
C50 H50A 0.9600 .
C50 H50B 0.9600 .
C50 H50C 0.9600 .
N31 C51 1.323(18) .
N31 C54 1.34(2) .
C51 C52 1.456(18) .
C52 N32 1.310(17) .
C52 H52A 0.9300 .
N32 C53 1.329(16) .
C53 C54 1.430(19) .
C53 H53A 0.9300 .
C54 N33 1.406(19) .
N33 C56 1.404(16) .
N33 C55 1.474(16) .
C55 H55A 0.9600 .
C55 H55B 0.9600 .
C55 H55C 0.9600 .
N34 C59 1.371(17) .
N34 C56 1.391(17) .
C56 C57 1.395(19) .
C57 N35 1.287(15) .
C57 H57A 0.9300 .
N35 C58 1.405(18) .
C58 C59 1.38(2) .
C58 H58A 0.9300 .
C59 N36 1.392(17) .
N36 C60 1.47(2) .
C60 H60A 0.9600 .
C60 H60B 0.9600 .
C60 H60C 0.9600 .
N37 C64 1.323(17) .
N37 C61 1.329(17) .
C61 C62 1.382(17) .
C61 N48 1.428(18) .
C62 N38 1.331(15) .
C62 H62A 0.9300 .
N38 C63 1.315(16) .
N38 Ag4 2.318(10) 2_544
C63 C64 1.420(18) .
C63 H63A 0.9300 .
C64 N39 1.335(16) .
N39 C66 1.403(15) .
N39 C65 1.493(16) .
C65 H65A 0.9600 .
C65 H65B 0.9600 .
C65 H65C 0.9600 .
N40 C69 1.288(16) .
N40 C66 1.380(16) .
C66 C67 1.362(18) .
C67 N41 1.348(16) .
C67 H67A 0.9300 .
N41 C68 1.298(16) .
C68 C69 1.401(18) .
C68 H68A 0.9300 .
C69 N42 1.430(16) .
N42 C71 1.436(19) .
N42 C70 1.456(18) .
C70 H70A 0.9600 .
C70 H70B 0.9600 .
C70 H70C 0.9600 .
N43 C71 1.312(17) .
N43 C74 1.342(19) .
C71 C72 1.37(2) .
C72 N44 1.37(2) .
C72 H72A 0.9300 .
N44 C73 1.30(2) .
C73 C74 1.49(2) .
C73 H73A 0.9300 .
C74 N45 1.36(2) .
N45 C76 1.365(17) .
N45 C75 1.49(2) .
C75 H75A 0.9600 .
C75 H75B 0.9600 .
C75 H75C 0.9600 .
N46 C76 1.339(16) .
N46 C79 1.349(19) .
C76 C77 1.403(18) .
C77 N47 1.307(17) .
C77 H77A 0.9300 .
N47 C78 1.327(16) .
C78 C79 1.375(19) .
C78 H78A 0.9300 .
C79 N48 1.407(18) .
N48 C80 1.487(19) .
C80 H80A 0.9600 .
C80 H80B 0.9600 .
C80 H80C 0.9600 .
B1 F13 1.35(2) .
B1 F14 1.36(3) .
B1 F12 1.37(3) .
B1 F11 1.42(3) .
B2 F21 1.18(3) .
B2 F22 1.32(3) .
B2 F23 1.38(3) .
B2 F24 1.39(3) .
B3 F31 1.32(3) .
B3 F33 1.36(3) .
B3 F34 1.40(2) .
B3 F32 1.42(3) .
B4 F42 1.324(14) .
B4 F43 1.333(15) .
B4 F41 1.335(16) .
B4 F44 1.343(14) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C4 N1 C1 N12 -176.9(12) . .
C4 N1 C1 C2 6.4(18) . .
N12 C1 C2 N2 -179.6(12) . .
N1 C1 C2 N2 -3.3(18) . .
C1 C2 N2 C3 1.6(18) . .
C1 C2 N2 Ag3 167.7(9) . 4_575
C2 N2 C3 C4 -2.8(18) . .
Ag3 N2 C3 C4 -167.8(9) 4_575 .
C1 N1 C4 N3 -178.7(11) . .
C1 N1 C4 C3 -7.8(18) . .
N2 C3 C4 N1 6.0(19) . .
N2 C3 C4 N3 176.2(12) . .
N1 C4 N3 C6 -4.9(18) . .
C3 C4 N3 C6 -175.5(12) . .
N1 C4 N3 C5 174.9(12) . .
C3 C4 N3 C5 4.3(19) . .
C9 N4 C6 C7 -2.0(17) . .
C9 N4 C6 N3 -175.3(10) . .
C4 N3 C6 N4 102.5(14) . .
C5 N3 C6 N4 -77.3(16) . .
C4 N3 C6 C7 -70.9(16) . .
C5 N3 C6 C7 109.3(14) . .
N4 C6 C7 N5 -1.6(18) . .
N3 C6 C7 N5 171.5(11) . .
C6 C7 N5 C8 4.5(17) . .
C6 C7 N5 Ag1 -155.4(9) . .
N32 Ag1 N5 C8 12.6(11) . .
N14 Ag1 N5 C8 -179.3(9) . .
N11 Ag1 N5 C8 -76.9(10) . .
N32 Ag1 N5 C7 170.3(8) . .
N14 Ag1 N5 C7 -21.7(10) . .
N11 Ag1 N5 C7 80.8(9) . .
C7 N5 C8 C9 -4.2(17) . .
Ag1 N5 C8 C9 154.1(9) . .
N5 C8 C9 N4 0.9(18) . .
N5 C8 C9 N6 -175.3(11) . .
C6 N4 C9 C8 2.3(17) . .
C6 N4 C9 N6 178.7(10) . .
C8 C9 N6 C11 72.1(16) . .
N4 C9 N6 C11 -104.3(13) . .
C8 C9 N6 C10 -138.6(12) . .
N4 C9 N6 C10 45.0(15) . .
C14 N7 C11 C12 -3.4(19) . .
C14 N7 C11 N6 173.1(12) . .
C9 N6 C11 N7 1.1(17) . .
C10 N6 C11 N7 -148.6(12) . .
C9 N6 C11 C12 177.5(13) . .
C10 N6 C11 C12 27.7(19) . .
N7 C11 C12 N8 0(2) . .
N6 C11 C12 N8 -175.7(13) . .
C11 C12 N8 C13 0(2) . .
C11 C12 N8 Ag2' 174.4(16) . 1_655
C11 C12 N8 Ag2 175.0(10) . 1_655
C12 N8 C13 C14 1.7(19) . .
Ag2' N8 C13 C14 -172.1(16) 1_655 .
Ag2 N8 C13 C14 -172.9(9) 1_655 .
C11 N7 C14 N9 -176.8(12) . .
C11 N7 C14 C13 5.3(18) . .
N8 C13 C14 N7 -5(2) . .
N8 C13 C14 N9 177.4(12) . .
N7 C14 N9 C16 3.0(18) . .
C13 C14 N9 C16 -179.1(12) . .
N7 C14 N9 C15 152.0(13) . .
C13 C14 N9 C15 -30.2(19) . .
C19 N10 C16 C17 -1.8(18) . .
C19 N10 C16 N9 -178.2(11) . .
C14 N9 C16 N10 103.6(14) . .
C15 N9 C16 N10 -47.2(16) . .
C14 N9 C16 C17 -72.9(16) . .
C15 N9 C16 C17 136.2(13) . .
N10 C16 C17 N11 1(2) . .
N9 C16 C17 N11 177.3(12) . .
C16 C17 N11 C18 2.1(19) . .
C16 C17 N11 Ag1 -148.6(10) . .
N32 Ag1 N11 C17 -43.8(10) . .
N14 Ag1 N11 C17 -179.6(9) . .
N5 Ag1 N11 C17 70.5(9) . .
N32 Ag1 N11 C18 165.1(10) . .
N14 Ag1 N11 C18 29.2(11) . .
N5 Ag1 N11 C18 -80.6(10) . .
C17 N11 C18 C19 -4.2(19) . .
Ag1 N11 C18 C19 147.0(10) . .
C16 N10 C19 N12 175.5(11) . .
C16 N10 C19 C18 -0.5(18) . .
N11 C18 C19 N10 4(2) . .
N11 C18 C19 N12 -172.5(12) . .
N1 C1 N12 C19 -1.6(18) . .
C2 C1 N12 C19 174.8(12) . .
N1 C1 N12 C20 -179.8(12) . .
C2 C1 N12 C20 -3(2) . .
N10 C19 N12 C1 -98.4(15) . .
C18 C19 N12 C1 77.7(16) . .
N10 C19 N12 C20 79.9(16) . .
C18 C19 N12 C20 -104.0(14) . .
C24 N13 C21 N24 178.8(11) . .
C24 N13 C21 C22 1.2(18) . .
N13 C21 C22 N14 -2(2) . .
N24 C21 C22 N14 -179.2(13) . .
C21 C22 N14 C23 2.5(19) . .
C21 C22 N14 Ag1 177.4(9) . .
N32 Ag1 N14 C22 -71.1(12) . .
N5 Ag1 N14 C22 123.7(10) . .
N11 Ag1 N14 C22 38.3(11) . .
N32 Ag1 N14 C23 103.6(11) . .
N5 Ag1 N14 C23 -61.6(11) . .
N11 Ag1 N14 C23 -147.0(10) . .
C22 N14 C23 C24 -3(2) . .
Ag1 N14 C23 C24 -177.8(9) . .
C21 N13 C24 C23 -1.5(17) . .
C21 N13 C24 N15 -176.2(11) . .
N14 C23 C24 N13 2.5(19) . .
N14 C23 C24 N15 176.6(12) . .
N13 C24 N15 C26 1.3(16) . .
C23 C24 N15 C26 -173.1(12) . .
N13 C24 N15 C25 177.6(11) . .
C23 C24 N15 C25 3.2(19) . .
N38 Ag4 N16 C29 -93.5(9) 2_554 .
N47 Ag4 N16 C29 39.3(10) . .
N41 Ag4 N16 C29 135.7(8) . .
N38 Ag4 N16 C26 92.2(9) 2_554 .
N47 Ag4 N16 C26 -135.0(8) . .
N41 Ag4 N16 C26 -38.6(10) . .
C29 N16 C26 N15 -179.0(11) . .
Ag4 N16 C26 N15 -4.9(14) . .
C29 N16 C26 C27 3.5(17) . .
Ag4 N16 C26 C27 177.6(8) . .
C24 N15 C26 N16 105.7(13) . .
C25 N15 C26 N16 -70.6(16) . .
C24 N15 C26 C27 -76.8(15) . .
C25 N15 C26 C27 106.8(14) . .
N16 C26 C27 N17 0.7(19) . .
N15 C26 C27 N17 -176.8(12) . .
C26 C27 N17 C28 -4.8(19) . .
C26 C27 N17 Ag2 -148.4(10) . .
C26 C27 N17 Ag2' -149.6(14) . .
N26 Ag2 N17 C27 -28.1(10) 4_575 .
N8 Ag2 N17 C27 179.5(9) 1_455 .
N23 Ag2 N17 C27 70.4(9) . .
N26 Ag2 N17 C28 -171.6(9) 4_575 .
N8 Ag2 N17 C28 36.0(10) 1_455 .
N23 Ag2 N17 C28 -73.1(9) . .
N26 Ag2 N17 Ag2' 142(9) 4_575 .
N8 Ag2 N17 Ag2' -10(9) 1_455 .
N23 Ag2 N17 Ag2' -119(9) . .
N8 Ag2' N17 C27 178.4(13) 1_455 .
N26 Ag2' N17 C27 -22.9(18) 4_575 .
N23 Ag2' N17 C27 66.8(14) . .
N8 Ag2' N17 C28 32(2) 1_455 .
N26 Ag2' N17 C28 -168.9(11) 4_575 .
N23 Ag2' N17 C28 -79.2(11) . .
N8 Ag2' N17 Ag2 168(10) 1_455 .
N26 Ag2' N17 Ag2 -33(8) 4_575 .
N23 Ag2' N17 Ag2 57(8) . .
C27 N17 C28 C29 5.1(19) . .
Ag2 N17 C28 C29 148.0(9) . .
Ag2' N17 C28 C29 152.7(12) . .
C26 N16 C29 N18 175.5(10) . .
Ag4 N16 C29 N18 1.3(14) . .
C26 N16 C29 C28 -3.2(17) . .
Ag4 N16 C29 C28 -177.4(8) . .
N17 C28 C29 N16 -1.3(18) . .
N17 C28 C29 N18 180.0(11) . .
N16 C29 N18 C31 -104.2(13) . .
C28 C29 N18 C31 74.5(14) . .
N16 C29 N18 C30 85.7(15) . .
C28 C29 N18 C30 -95.6(15) . .
C34 N19 C31 C32 4.5(17) . .
C34 N19 C31 N18 177.7(10) . .
C29 N18 C31 N19 3.2(15) . .
C30 N18 C31 N19 173.3(11) . .
C29 N18 C31 C32 176.5(11) . .
C30 N18 C31 C32 -13.4(17) . .
N19 C31 C32 N20 -3.0(19) . .
N18 C31 C32 N20 -175.7(11) . .
C31 C32 N20 C33 1.4(18) . .
C31 C32 N20 Ag3 176.4(8) . 1_455
C32 N20 C33 C34 -1.6(19) . .
Ag3 N20 C33 C34 -177.5(9) 1_455 .
C31 N19 C34 N21 177.3(11) . .
C31 N19 C34 C33 -4.8(17) . .
N20 C33 C34 N19 3.5(19) . .
N20 C33 C34 N21 -178.7(12) . .
N19 C34 N21 C36 4.1(17) . .
C33 C34 N21 C36 -173.9(12) . .
N19 C34 N21 C35 154.8(13) . .
C33 C34 N21 C35 -23(2) . .
C39 N22 C36 C37 2.0(18) . .
C39 N22 C36 N21 -176.3(10) . .
C34 N21 C36 N22 102.9(15) . .
C35 N21 C36 N22 -49.5(17) . .
C34 N21 C36 C37 -75.5(15) . .
C35 N21 C36 C37 132.1(13) . .
N22 C36 C37 N23 -2.2(19) . .
N21 C36 C37 N23 176.2(11) . .
C36 C37 N23 C38 2.6(18) . .
C36 C37 N23 Ag2 -156.8(9) . .
C36 C37 N23 Ag2' -158.4(12) . .
N26 Ag2 N23 C37 -175.5(9) 4_575 .
N8 Ag2 N23 C37 -20.9(10) 1_455 .
N17 Ag2 N23 C37 78.1(9) . .
N26 Ag2 N23 C38 25.4(11) 4_575 .
N8 Ag2 N23 C38 180.0(10) 1_455 .
N17 Ag2 N23 C38 -81.0(10) . .
N26 Ag2 N23 Ag2' -158(10) 4_575 .
N8 Ag2 N23 Ag2' -3(10) 1_455 .
N17 Ag2 N23 Ag2' 96(10) . .
N8 Ag2' N23 C37 -21(2) 1_455 .
N26 Ag2' N23 C37 -177.0(11) 4_575 .
N17 Ag2' N23 C37 83.1(11) . .
N8 Ag2' N23 C38 179.6(14) 1_455 .
N26 Ag2' N23 C38 23.3(18) 4_575 .
N17 Ag2' N23 C38 -76.5(14) . .
N8 Ag2' N23 Ag2 176(11) 1_455 .
N26 Ag2' N23 Ag2 20(9) 4_575 .
N17 Ag2' N23 Ag2 -80(10) . .
C37 N23 C38 C39 -3.1(19) . .
Ag2 N23 C38 C39 155.4(9) . .
Ag2' N23 C38 C39 155.1(14) . .
C36 N22 C39 C38 -2.3(17) . .
C36 N22 C39 N24 173.5(11) . .
N23 C38 C39 N22 3.0(19) . .
N23 C38 C39 N24 -172.8(12) . .
N13 C21 N24 C39 -3.1(18) . .
C22 C21 N24 C39 174.4(12) . .
N13 C21 N24 C40 -160.4(12) . .
C22 C21 N24 C40 17(2) . .
N22 C39 N24 C21 -102.6(14) . .
C38 C39 N24 C21 73.3(16) . .
N22 C39 N24 C40 55.3(16) . .
C38 C39 N24 C40 -128.9(13) . .
C44 N25 C41 N36 -178.9(12) . .
C44 N25 C41 C42 -0.1(19) . .
N25 C41 C42 N26 -0.2(19) . .
N36 C41 C42 N26 178.5(12) . .
C41 C42 N26 C43 2.1(19) . .
C41 C42 N26 Ag2 171.7(9) . 4_676
C41 C42 N26 Ag2' 166.5(13) . 4_676
C42 N26 C43 C44 -3.6(19) . .
Ag2 N26 C43 C44 -174.1(10) 4_676 .
Ag2' N26 C43 C44 -169.1(13) 4_676 .
C41 N25 C44 N27 -177.9(12) . .
C41 N25 C44 C43 -1.5(19) . .
N26 C43 C44 N25 3(2) . .
N26 C43 C44 N27 179.6(12) . .
N25 C44 N27 C46 -1.9(18) . .
C43 C44 N27 C46 -178.4(12) . .
N25 C44 N27 C45 165.0(13) . .
C43 C44 N27 C45 -11(2) . .
C49 N28 C46 C47 -6.2(17) . .
C49 N28 C46 N27 -178.1(11) . .
C44 N27 C46 N28 109.1(14) . .
C45 N27 C46 N28 -58.0(17) . .
C44 N27 C46 C47 -62.8(17) . .
C45 N27 C46 C47 130.2(14) . .
N28 C46 C47 N29 8.7(19) . .
N27 C46 C47 N29 -179.9(11) . .
C46 C47 N29 C48 -5.1(18) . .
C46 C47 N29 Ag3 -153.9(9) . .
N20 Ag3 N29 C48 23.4(10) 1_655 .
N2 Ag3 N29 C48 -178.5(9) 4_676 .
N35 Ag3 N29 C48 -80.1(9) . .
N20 Ag3 N29 C47 171.6(9) 1_655 .
N2 Ag3 N29 C47 -30.3(10) 4_676 .
N35 Ag3 N29 C47 68.2(9) . .
C47 N29 C48 C49 -0.2(19) . .
Ag3 N29 C48 C49 149.1(11) . .
N29 C48 C49 N30 -171.0(12) . .
N29 C48 C49 N28 2(2) . .
C46 N28 C49 C48 1.1(18) . .
C46 N28 C49 N30 174.9(11) . .
C48 C49 N30 C51 83.2(17) . .
N28 C49 N30 C51 -90.3(14) . .
C48 C49 N30 C50 -94.0(17) . .
N28 C49 N30 C50 92.5(16) . .
C54 N31 C51 N30 -178.1(13) . .
C54 N31 C51 C52 0.4(19) . .
C49 N30 C51 N31 -1.4(18) . .
C50 N30 C51 N31 175.6(14) . .
C49 N30 C51 C52 -179.8(12) . .
C50 N30 C51 C52 -3(2) . .
N31 C51 C52 N32 3.6(18) . .
N30 C51 C52 N32 -178.0(12) . .
C51 C52 N32 C53 -6.3(18) . .
C51 C52 N32 Ag1 172.5(9) . .
N14 Ag1 N32 C52 -101.3(10) . .
N5 Ag1 N32 C52 63.5(10) . .
N11 Ag1 N32 C52 144.6(9) . .
N14 Ag1 N32 C53 77.5(10) . .
N5 Ag1 N32 C53 -117.7(9) . .
N11 Ag1 N32 C53 -36.6(9) . .
C52 N32 C53 C54 4.8(18) . .
Ag1 N32 C53 C54 -174.0(9) . .
C51 N31 C54 N33 -178.8(12) . .
C51 N31 C54 C53 -2(2) . .
N32 C53 C54 N31 -1(2) . .
N32 C53 C54 N33 176.3(12) . .
N31 C54 N33 C56 -7.2(19) . .
C53 C54 N33 C56 175.9(12) . .
N31 C54 N33 C55 152.1(12) . .
C53 C54 N33 C55 -25(2) . .
C59 N34 C56 C57 -3.9(18) . .
C59 N34 C56 N33 -179.2(11) . .
C54 N33 C56 N34 116.2(13) . .
C55 N33 C56 N34 -43.5(17) . .
C54 N33 C56 C57 -59.1(17) . .
C55 N33 C56 C57 141.2(13) . .
N34 C56 C57 N35 7(2) . .
N33 C56 C57 N35 -178.2(12) . .
C56 C57 N35 C58 -3.6(18) . .
C56 C57 N35 Ag3 -155.5(10) . .
N20 Ag3 N35 C57 -41.4(10) 1_655 .
N2 Ag3 N35 C57 171.2(9) 4_676 .
N29 Ag3 N35 C57 67.8(10) . .
N20 Ag3 N35 C58 166.6(9) 1_655 .
N2 Ag3 N35 C58 19.1(9) 4_676 .
N29 Ag3 N35 C58 -84.3(9) . .
C57 N35 C58 C59 -1.9(19) . .
Ag3 N35 C58 C59 151.5(10) . .
C56 N34 C59 C58 -1.5(18) . .
C56 N34 C59 N36 173.7(11) . .
N35 C58 C59 N34 5(2) . .
N35 C58 C59 N36 -170.6(11) . .
N34 C59 N36 C41 -88.9(14) . .
C58 C59 N36 C41 86.4(15) . .
N34 C59 N36 C60 64.4(18) . .
C58 C59 N36 C60 -120.2(17) . .
N25 C41 N36 C59 -11.2(17) . .
C42 C41 N36 C59 170.1(12) . .
N25 C41 N36 C60 -164.8(14) . .
C42 C41 N36 C60 16(2) . .
C64 N37 C61 C62 -3(2) . .
C64 N37 C61 N48 177.8(12) . .
N37 C61 C62 N38 2(2) . .
N48 C61 C62 N38 -178.5(13) . .
C61 C62 N38 C63 1(2) . .
C61 C62 N38 Ag4 164.0(10) . 2_544
C62 N38 C63 C64 -3(2) . .
Ag4 N38 C63 C64 -165.7(10) 2_544 .
C61 N37 C64 N39 -179.7(12) . .
C61 N37 C64 C63 1(2) . .
N38 C63 C64 N37 2(2) . .
N38 C63 C64 N39 -177.3(13) . .
N37 C64 N39 C66 11.2(19) . .
C63 C64 N39 C66 -169.5(13) . .
N37 C64 N39 C65 157.9(12) . .
C63 C64 N39 C65 -23(2) . .
C69 N40 C66 C67 1.0(16) . .
C69 N40 C66 N39 -172.1(10) . .
C64 N39 C66 C67 -78.5(16) . .
C65 N39 C66 C67 133.3(12) . .
C64 N39 C66 N40 94.6(14) . .
C65 N39 C66 N40 -53.6(15) . .
N40 C66 C67 N41 1.2(18) . .
N39 C66 C67 N41 174.2(11) . .
C66 C67 N41 C68 -4.1(18) . .
C66 C67 N41 Ag4 -154.6(9) . .
N16 Ag4 N41 C68 167.9(9) . .
N38 Ag4 N41 C68 28.4(10) 2_554 .
N47 Ag4 N41 C68 -72.2(10) . .
N16 Ag4 N41 C67 -42.5(11) . .
N38 Ag4 N41 C67 178.0(9) 2_554 .
N47 Ag4 N41 C67 77.4(9) . .
C67 N41 C68 C69 4.9(18) . .
Ag4 N41 C68 C69 155.0(9) . .
C66 N40 C69 C68 -0.1(17) . .
C66 N40 C69 N42 176.2(10) . .
N41 C68 C69 N40 -3.1(19) . .
N41 C68 C69 N42 -179.4(12) . .
N40 C69 N42 C71 -109.5(13) . .
C68 C69 N42 C71 67.0(15) . .
N40 C69 N42 C70 49.8(16) . .
C68 C69 N42 C70 -133.8(13) . .
C74 N43 C71 C72 -2(2) . .
C74 N43 C71 N42 178.8(11) . .
C69 N42 C71 N43 1.2(16) . .
C70 N42 C71 N43 -157.2(12) . .
C69 N42 C71 C72 -178.4(13) . .
C70 N42 C71 C72 23.2(19) . .
N43 C71 C72 N44 1(2) . .
N42 C71 C72 N44 -179.8(13) . .
C71 C72 N44 C73 -2(2) . .
C72 N44 C73 C74 4(3) . .
C71 N43 C74 N45 -175.7(12) . .
C71 N43 C74 C73 3.3(19) . .
N44 C73 C74 N43 -5(2) . .
N44 C73 C74 N45 174.4(15) . .
N43 C74 N45 C76 -3.0(19) . .
C73 C74 N45 C76 178.1(13) . .
N43 C74 N45 C75 154.6(15) . .
C73 C74 N45 C75 -24(2) . .
C79 N46 C76 N45 -172.7(12) . .
C79 N46 C76 C77 2.8(19) . .
C74 N45 C76 N46 104.1(15) . .
C75 N45 C76 N46 -52(2) . .
C74 N45 C76 C77 -71.4(17) . .
C75 N45 C76 C77 132.1(17) . .
N46 C76 C77 N47 -2(2) . .
N45 C76 C77 N47 173.8(12) . .
C76 C77 N47 C78 1.5(19) . .
C76 C77 N47 Ag4 -155.6(10) . .
N16 Ag4 N47 C77 -160.3(9) . .
N38 Ag4 N47 C77 -19.4(9) 2_554 .
N41 Ag4 N47 C77 80.2(9) . .
N16 Ag4 N47 C78 42.5(10) . .
N38 Ag4 N47 C78 -176.6(9) 2_554 .
N41 Ag4 N47 C78 -77.1(9) . .
C77 N47 C78 C79 -2.8(18) . .
Ag4 N47 C78 C79 154.4(10) . .
C76 N46 C79 C78 -4.4(19) . .
C76 N46 C79 N48 179.2(11) . .
N47 C78 C79 N46 5(2) . .
N47 C78 C79 N48 -179.2(11) . .
N46 C79 N48 C61 -107.7(15) . .
C78 C79 N48 C61 75.8(17) . .
N46 C79 N48 C80 44.7(18) . .
C78 C79 N48 C80 -131.8(16) . .
N37 C61 N48 C79 -6.2(19) . .
C62 C61 N48 C79 174.6(13) . .
N37 C61 N48 C80 -159.4(14) . .
C62 C61 N48 C80 21(2) . .
