#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:42:09 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179390 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/87/4328735.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328735
loop_
_publ_author_name
'Chao Fang'
'Qi-Kui Liu'
'Jian-Ping Ma'
'Yu-Bin Dong'
_publ_section_title
;
 Independent 1D Nanosized Metal-Organic Tube: Anion Exchange, Separation,
 and Anion-Responsive Luminescence
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3923
_journal_page_last               3925
_journal_paper_doi               10.1021/ic201765u
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C53 H50 Ag2 F12 N8 O2 Sb2'
_chemical_formula_weight         1518.25
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           68
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-C 2a 2ac'
_symmetry_space_group_name_H-M   'C c c a :2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   24.238(4)
_cell_length_b                   30.052(6)
_cell_length_c                   15.646(3)
_cell_measurement_reflns_used    5001
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.928
_cell_measurement_theta_min      2.515
_cell_volume                     11397(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0651
_diffrn_reflns_av_sigmaI/netI    0.0538
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            28358
_diffrn_reflns_theta_full        25.60
_diffrn_reflns_theta_max         25.60
_diffrn_reflns_theta_min         1.36
_exptl_absorpt_coefficient_mu    1.702
_exptl_absorpt_correction_T_max  0.8219
_exptl_absorpt_correction_T_min  0.6855
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.770
_exptl_crystal_description       block
_exptl_crystal_F_000             5952
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.876
_refine_diff_density_min         -0.406
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.993
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         5374
_refine_ls_number_restraints     22
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.1025
_refine_ls_R_factor_gt           0.0502
_refine_ls_shift/su_max          0.012
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0856P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1288
_refine_ls_wR_factor_ref         0.1621
_reflns_number_gt                2902
_reflns_number_total             5374
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201765u_si_002_3.cif
_cod_data_source_block           3
_cod_original_cell_volume        11396(4)
_cod_original_sg_symbol_H-M      'C c c a'
_cod_database_code               4328735
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z'
'-x, y, -z+1/2'
'x+1/2, -y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1, -y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'x+1, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z'
'x, -y, z-1/2'
'-x-1/2, y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x, y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
'-x, y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.74261(4) 0.2500 0.7500 0.0739(3) Uani 1 2 d S . .
Ag2 Ag 0.5000 0.04925(3) 1.2500 0.0992(4) Uani 1 2 d S . .
C1 C 0.6533(3) 0.2005(3) 0.8675(4) 0.0633(19) Uani 1 1 d . . .
H1 H 0.6461 0.2295 0.8845 0.076 Uiso 1 1 calc R . .
C2 C 0.6257(3) 0.1659(2) 0.9085(4) 0.0602(18) Uani 1 1 d . . .
H2 H 0.6004 0.1724 0.9513 0.072 Uiso 1 1 calc R . .
C3 C 0.6354(3) 0.1220(2) 0.8869(4) 0.0565(17) Uani 1 1 d . . .
C4 C 0.6720(3) 0.1156(3) 0.8180(5) 0.073(2) Uani 1 1 d . . .
H4 H 0.6787 0.0871 0.7973 0.088 Uiso 1 1 calc R . .
C5 C 0.6977(3) 0.1513(3) 0.7817(5) 0.076(2) Uani 1 1 d . . .
H5 H 0.7226 0.1459 0.7377 0.091 Uiso 1 1 calc R . .
C6 C 0.6118(3) 0.0847(2) 0.9360(4) 0.0565(17) Uani 1 1 d . . .
C7 C 0.5666(3) 0.0907(3) 0.9876(5) 0.075(2) Uani 1 1 d . . .
H7 H 0.5481 0.1178 0.9863 0.090 Uiso 1 1 calc R . .
C8 C 0.5480(3) 0.0578(3) 1.0407(5) 0.083(3) Uani 1 1 d . . .
H8 H 0.5171 0.0629 1.0746 0.100 Uiso 1 1 calc R . .
C9 C 0.5747(3) 0.0168(3) 1.0447(4) 0.068(2) Uani 1 1 d . . .
C10 C 0.6176(4) 0.0101(3) 0.9887(5) 0.073(2) Uani 1 1 d . . .
H10 H 0.6345 -0.0176 0.9863 0.088 Uiso 1 1 calc R . .
C11 C 0.6362(3) 0.0435(3) 0.9363(4) 0.0664(19) Uani 1 1 d . . .
H11 H 0.6659 0.0381 0.9002 0.080 Uiso 1 1 calc R . .
C12 C 0.5579(4) -0.0188(3) 1.1041(6) 0.088(3) Uani 1 1 d . . .
H12 H 0.5682 -0.0478 1.0909 0.106 Uiso 1 1 calc R . .
C13 C 0.5243(6) -0.0516(3) 1.2282(8) 0.138(5) Uani 1 1 d . . .
H13A H 0.5267 -0.0786 1.1944 0.166 Uiso 1 1 calc R . .
H13B H 0.5545 -0.0519 1.2689 0.166 Uiso 1 1 calc R . .
C14 C 0.6214(5) 0.0732(3) 0.3061(8) 0.116(4) Uani 1 1 d . . .
H14 H 0.6291 0.0501 0.2684 0.139 Uiso 1 1 calc R . .
C15 C 0.6626(5) 0.0887(3) 0.3550(7) 0.106(3) Uani 1 1 d . . .
H15 H 0.6979 0.0772 0.3480 0.127 Uiso 1 1 calc R . .
C16 C 0.6539(4) 0.1218(3) 0.4163(6) 0.089(3) Uani 1 1 d . . .
C17 C 0.6008(4) 0.1388(3) 0.4186(7) 0.104(3) Uani 1 1 d . . .
H17 H 0.5920 0.1615 0.4566 0.124 Uiso 1 1 calc R . .
C18 C 0.5620(5) 0.1224(3) 0.3660(8) 0.113(4) Uani 1 1 d . . .
H18 H 0.5269 0.1349 0.3691 0.136 Uiso 1 1 calc R . .
C19 C 0.6976(4) 0.1374(3) 0.4739(6) 0.086(3) Uani 1 1 d . . .
C20 C 0.7396(4) 0.1099(4) 0.5027(7) 0.107(4) Uani 1 1 d . . .
H20 H 0.7400 0.0803 0.4853 0.129 Uiso 1 1 calc R . .
C21 C 0.7799(5) 0.1245(4) 0.5549(7) 0.108(4) Uani 1 1 d . . .
H21 H 0.8074 0.1048 0.5721 0.129 Uiso 1 1 calc R . .
C22 C 0.7814(4) 0.1681(4) 0.5838(6) 0.091(3) Uani 1 1 d . . .
C23 C 0.7396(4) 0.1965(3) 0.5556(5) 0.082(3) Uani 1 1 d . . .
H23 H 0.7394 0.2260 0.5735 0.098 Uiso 1 1 calc R . .
C24 C 0.6994(4) 0.1819(3) 0.5029(6) 0.082(3) Uani 1 1 d . . .
H24 H 0.6721 0.2017 0.4851 0.098 Uiso 1 1 calc R . .
C25 C 0.8258(4) 0.1827(4) 0.6407(7) 0.110(4) Uani 1 1 d . . .
H25 H 0.8593 0.1676 0.6384 0.132 Uiso 1 1 calc R . .
C26 C 0.8691(4) 0.2263(4) 0.7443(7) 0.124(5) Uani 1 1 d . . .
H26A H 0.8670 0.2117 0.7994 0.149 Uiso 1 1 calc R . .
H26B H 0.9030 0.2171 0.7165 0.149 Uiso 1 1 calc R . .
C27 C 0.5185(9) 0.8346(9) 0.1887(18) 0.144(9) Uani 0.50 1 d PDU A 1
H27A H 0.5212 0.8243 0.2466 0.216 Uiso 0.50 1 calc PR A 1
H27B H 0.4995 0.8128 0.1549 0.216 Uiso 0.50 1 calc PR A 1
H27C H 0.4985 0.8621 0.1872 0.216 Uiso 0.50 1 calc PR A 1
F1 F 0.7500 1.0000 0.3109(3) 0.0719(15) Uani 1 2 d S . .
F2 F 0.7500 1.0000 0.0720(4) 0.0848(18) Uani 1 2 d S . .
F3 F 0.67568(19) 0.98455(19) 0.1940(3) 0.1012(16) Uani 1 1 d . . .
F4 F 0.7312(2) 1.05972(15) 0.1945(3) 0.0928(15) Uani 1 1 d . . .
F5 F 0.5769(2) 0.25627(17) 0.0382(5) 0.131(2) Uani 1 1 d . . .
F6 F 0.5102(4) 0.1917(3) 0.0291(15) 0.292(10) Uani 1 1 d . . .
F7 F 0.493(2) 0.2159(12) 0.135(2) 0.145(17) Uani 0.25 1 d P B 1
F8 F 0.5030(13) 0.2147(12) -0.047(3) 0.149(16) Uani 0.25 1 d P C 1
F7' F 0.5000 0.2500 0.1542(13) 0.22(2) Uani 0.50 2 d SP C 2
F8' F 0.5000 0.2500 -0.0777(19) 0.173(10) Uani 0.50 2 d SP C 2
N1 N 0.6895(2) 0.1936(2) 0.8051(4) 0.0630(15) Uani 1 1 d . . .
N2 N 0.5307(4) -0.0127(2) 1.1711(5) 0.094(2) Uani 1 1 d . . .
N3 N 0.5700(4) 0.0891(2) 0.3088(6) 0.111(3) Uani 1 1 d . . .
N4 N 0.8213(3) 0.2137(3) 0.6914(5) 0.092(2) Uani 1 1 d . . .
O1 O 0.5749(9) 0.8416(9) 0.1534(16) 0.250(11) Uani 0.50 1 d PDU A 1
H1A H 0.5917 0.8181 0.1475 0.375 Uiso 0.50 1 d PR A 1
O2 O 0.5401(13) 0.7909(13) 0.21833(3) 0.333(18) Uani 0.50 1 d PDU D 2
H2A H 0.5275 0.7672 0.2514 0.499 Uiso 0.50 1 d PRD D 2
H2B H 0.5486 0.8219 0.2045 0.499 Uiso 0.50 1 d PRD D 2
Sb1 Sb 0.7500(13) 1.0000(13) 0.19116(3) 0.0597(2) Uani 1 2 d SR . .
Sb2 Sb 0.5000(13) 0.2500(13) 0.03985(3) 0.0794(3) Uani 1 2 d SR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N1 111.9(3) 8_456 .
N1 Ag1 N4 104.8(3) 8_456 8_456
N1 Ag1 N4 130.0(2) . 8_456
N1 Ag1 N4 130.0(2) 8_456 .
N1 Ag1 N4 104.8(3) . .
N4 Ag1 N4 73.5(5) 8_456 .
N3 Ag2 N3 116.3(4) 1_556 3_656
N3 Ag2 N2 113.2(3) 1_556 .
N3 Ag2 N2 116.1(3) 3_656 .
N3 Ag2 N2 116.1(3) 1_556 3_657
N3 Ag2 N2 113.2(3) 3_656 3_657
N2 Ag2 N2 75.5(3) . 3_657
N1 C1 C2 122.6(7) . .
N1 C1 H1 118.7 . .
C2 C1 H1 118.7 . .
C3 C2 C1 121.3(7) . .
C3 C2 H2 119.4 . .
C1 C2 H2 119.4 . .
C2 C3 C4 115.0(7) . .
C2 C3 C6 122.1(6) . .
C4 C3 C6 122.7(7) . .
C5 C4 C3 119.9(7) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
N1 C5 C4 124.5(7) . .
N1 C5 H5 117.8 . .
C4 C5 H5 117.8 . .
C7 C6 C11 117.3(7) . .
C7 C6 C3 121.2(6) . .
C11 C6 C3 121.3(6) . .
C8 C7 C6 121.8(7) . .
C8 C7 H7 119.1 . .
C6 C7 H7 119.1 . .
C7 C8 C9 120.9(7) . .
C7 C8 H8 119.5 . .
C9 C8 H8 119.5 . .
C10 C9 C8 116.9(7) . .
C10 C9 C12 120.3(8) . .
C8 C9 C12 122.8(8) . .
C11 C10 C9 121.5(8) . .
C11 C10 H10 119.3 . .
C9 C10 H10 119.3 . .
C10 C11 C6 121.3(7) . .
C10 C11 H11 119.3 . .
C6 C11 H11 119.3 . .
N2 C12 C9 124.6(8) . .
N2 C12 H12 117.7 . .
C9 C12 H12 117.7 . .
C13 C13 N2 113.2(11) 3_657 .
C13 C13 H13A 108.9 3_657 .
N2 C13 H13A 108.9 . .
C13 C13 H13B 108.9 3_657 .
N2 C13 H13B 108.9 . .
H13A C13 H13B 107.8 . .
N3 C14 C15 123.5(10) . .
N3 C14 H14 118.2 . .
C15 C14 H14 118.2 . .
C14 C15 C16 121.8(10) . .
C14 C15 H15 119.1 . .
C16 C15 H15 119.1 . .
C17 C16 C15 114.8(11) . .
C17 C16 C19 122.5(9) . .
C15 C16 C19 122.7(9) . .
C18 C17 C16 120.0(10) . .
C18 C17 H17 120.0 . .
C16 C17 H17 120.0 . .
C17 C18 N3 125.0(10) . .
C17 C18 H18 117.5 . .
N3 C18 H18 117.5 . .
C20 C19 C24 115.9(11) . .
C20 C19 C16 122.7(10) . .
C24 C19 C16 121.4(9) . .
C21 C20 C19 122.5(11) . .
C21 C20 H20 118.8 . .
C19 C20 H20 118.8 . .
C20 C21 C22 121.6(11) . .
C20 C21 H21 119.2 . .
C22 C21 H21 119.2 . .
C21 C22 C23 117.2(11) . .
C21 C22 C25 120.0(10) . .
C23 C22 C25 122.9(11) . .
C24 C23 C22 121.2(10) . .
C24 C23 H23 119.4 . .
C22 C23 H23 119.4 . .
C23 C24 C19 121.7(9) . .
C23 C24 H24 119.1 . .
C19 C24 H24 119.1 . .
N4 C25 C22 123.6(10) . .
N4 C25 H25 118.2 . .
C22 C25 H25 118.2 . .
C26 C26 N4 109.0(7) 8_456 .
C26 C26 H26A 109.9 8_456 .
N4 C26 H26A 109.9 . .
C26 C26 H26B 109.9 8_456 .
N4 C26 H26B 109.9 . .
H26A C26 H26B 108.3 . .
O1 C27 H2B 52.5 . .
H27A C27 H2B 61.8 . .
H27B C27 H2B 105.2 . .
H27C C27 H2B 145.0 . .
F8 F6 Sb2 64.7(8) . .
F6 F8 Sb2 68.7(19) . .
C1 N1 C5 116.5(7) . .
C1 N1 Ag1 122.1(5) . .
C5 N1 Ag1 121.1(5) . .
C12 N2 C13 116.5(7) . .
C12 N2 Ag2 136.1(6) . .
C13 N2 Ag2 105.9(6) . .
C14 N3 C18 114.7(10) . .
C14 N3 Ag2 119.7(7) . 1_554
C18 N3 Ag2 123.3(7) . 1_554
C25 N4 C26 119.1(9) . .
C25 N4 Ag1 131.9(8) . .
C26 N4 Ag1 107.2(7) . .
C27 O1 H1A 112.0 . .
C27 O1 H2B 35.2 . .
H1A O1 H2B 85.0 . .
H2A O2 H2B 156.9 . .
F4 Sb1 F4 176.7(3) 2_675 .
F4 Sb1 F3 89.8(17) 2_675 .
F4 Sb1 F3 90.1(15) . .
F4 Sb1 F3 90.2(15) 2_675 2_675
F4 Sb1 F3 89.7(17) . 2_675
F3 Sb1 F3 177.2(4) . 2_675
F4 Sb1 F2 91.6(13) 2_675 .
F4 Sb1 F2 91.6(13) . .
F3 Sb1 F2 91.4(10) . .
F3 Sb1 F2 91.4(10) 2_675 .
F4 Sb1 F1 88.4(12) 2_675 .
F4 Sb1 F1 88.4(12) . .
F3 Sb1 F1 88.6(10) . .
F3 Sb1 F1 88.6(10) 2_675 .
F2 Sb1 F1 180(3) . .
F8 Sb2 F8 76(4) . 6
F8 Sb2 F6 46.6(17) . .
F8 Sb2 F6 123(2) 6 .
F8 Sb2 F6 123(2) . 6
F8 Sb2 F6 46.6(18) 6 6
F6 Sb2 F6 169.1(15) . 6
F8 Sb2 F7' 142(3) . .
F8 Sb2 F7' 142(3) 6 .
F6 Sb2 F7' 95.5(15) . .
F6 Sb2 F7' 95.4(16) 6 .
F8 Sb2 F7 108(3) . .
F8 Sb2 F7 172(3) 6 .
F6 Sb2 F7 62.2(17) . .
F6 Sb2 F7 128(2) 6 .
F7' Sb2 F7 35.0(11) . .
F8 Sb2 F7 172(3) . 6
F8 Sb2 F7 107(3) 6 6
F6 Sb2 F7 129(2) . 6
F6 Sb2 F7 62.1(18) 6 6
F7' Sb2 F7 34.9(11) . 6
F7 Sb2 F7 70(2) . 6
F8 Sb2 F8' 38.1(18) . .
F8 Sb2 F8' 38.1(18) 6 .
F6 Sb2 F8' 84.6(14) . .
F6 Sb2 F8' 84.5(13) 6 .
F7' Sb2 F8' 180(3) . .
F7 Sb2 F8' 145(2) . .
F7 Sb2 F8' 145(2) 6 .
F8 Sb2 F5 88.3(17) . 6
F8 Sb2 F5 90.5(17) 6 6
F6 Sb2 F5 92.2(17) . 6
F6 Sb2 F5 87.7(15) 6 6
F7' Sb2 F5 90.8(11) . 6
F7 Sb2 F5 82.2(19) . 6
F7 Sb2 F5 99(2) 6 6
F8' Sb2 F5 89.2(10) . 6
F8 Sb2 F5 90.5(17) . .
F8 Sb2 F5 88.2(17) 6 .
F6 Sb2 F5 87.7(16) . .
F6 Sb2 F5 92.1(17) 6 .
F7' Sb2 F5 90.8(10) . .
F7 Sb2 F5 99.1(19) . .
F7 Sb2 F5 82.1(19) 6 .
F8' Sb2 F5 89.2(10) . .
F5 Sb2 F5 178.4(6) 6 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.296(6) 8_456
Ag1 N1 2.296(6) .
Ag1 N4 2.381(8) 8_456
Ag1 N4 2.381(8) .
Ag2 N3 2.271(9) 1_556
Ag2 N3 2.271(8) 3_656
Ag2 N2 2.356(7) .
Ag2 N2 2.356(7) 3_657
C1 N1 1.330(8) .
C1 C2 1.393(9) .
C1 H1 0.9300 .
C2 C3 1.382(9) .
C2 H2 0.9300 .
C3 C4 1.411(9) .
C3 C6 1.473(10) .
C4 C5 1.365(11) .
C4 H4 0.9300 .
C5 N1 1.336(10) .
C5 H5 0.9300 .
C6 C7 1.371(9) .
C6 C11 1.374(9) .
C7 C8 1.367(10) .
C7 H7 0.9300 .
C8 C9 1.391(10) .
C8 H8 0.9300 .
C9 C10 1.376(10) .
C9 C12 1.476(11) .
C10 C11 1.370(10) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 N2 1.250(10) .
C12 H12 0.9300 .
C13 C13 1.36(2) 3_657
C13 N2 1.478(11) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 N3 1.336(13) .
C14 C15 1.341(14) .
C14 H14 0.9300 .
C15 C16 1.396(12) .
C15 H15 0.9300 .
C16 C17 1.387(13) .
C16 C19 1.468(13) .
C17 C18 1.343(13) .
C17 H17 0.9300 .
C18 N3 1.356(11) .
C18 H18 0.9300 .
C19 C20 1.386(12) .
C19 C24 1.414(11) .
C20 C21 1.346(14) .
C20 H20 0.9300 .
C21 C22 1.386(14) .
C21 H21 0.9300 .
C22 C23 1.397(11) .
C22 C25 1.465(15) .
C23 C24 1.350(11) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 N4 1.230(13) .
C25 H25 0.9300 .
C26 C26 1.43(2) 8_456
C26 N4 1.473(12) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 O1 1.490(10) .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C27 H2B 0.8589 .
F1 Sb1 1.873(5) .
F2 Sb1 1.864(6) .
F3 Sb1 1.86(3) .
F4 Sb1 1.85(4) .
F5 Sb2 1.87(3) .
F6 F8 1.39(5) .
F6 Sb2 1.78(4) .
F7 Sb2 1.81(4) .
F8 Sb2 1.72(4) .
F7' Sb2 1.79(2) .
F8' Sb2 1.84(3) .
N3 Ag2 2.271(8) 1_554
O1 H1A 0.8200 .
O1 H2B 1.1827 .
O2 H2A 0.9317 .
O2 H2B 0.9784 .
Sb1 F4 1.85(4) 2_675
Sb1 F3 1.86(3) 2_675
Sb2 F8 1.73(3) 6
Sb2 F6 1.78(4) 6
Sb2 F7 1.81(4) 6
Sb2 F5 1.87(3) 6
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2A O2 0.93 1.83 2.65(7) 144.7 8_465
O2 H2A O2 0.93 2.45 3.13(7) 130.3 6_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 0.9(11) . .
C1 C2 C3 C4 -3.6(10) . .
C1 C2 C3 C6 172.6(6) . .
C2 C3 C4 C5 4.2(11) . .
C6 C3 C4 C5 -172.0(7) . .
C3 C4 C5 N1 -2.2(13) . .
C2 C3 C6 C7 20.5(10) . .
C4 C3 C6 C7 -163.5(7) . .
C2 C3 C6 C11 -155.3(7) . .
C4 C3 C6 C11 20.7(10) . .
C11 C6 C7 C8 3.4(12) . .
C3 C6 C7 C8 -172.6(7) . .
C6 C7 C8 C9 0.3(13) . .
C7 C8 C9 C10 -4.5(12) . .
C7 C8 C9 C12 176.8(8) . .
C8 C9 C10 C11 5.2(12) . .
C12 C9 C10 C11 -176.2(7) . .
C9 C10 C11 C6 -1.6(12) . .
C7 C6 C11 C10 -2.7(11) . .
C3 C6 C11 C10 173.2(7) . .
C10 C9 C12 N2 159.8(9) . .
C8 C9 C12 N2 -21.7(14) . .
N3 C14 C15 C16 3.2(18) . .
C14 C15 C16 C17 -3.7(14) . .
C14 C15 C16 C19 176.3(10) . .
C15 C16 C17 C18 1.8(14) . .
C19 C16 C17 C18 -178.1(9) . .
C16 C17 C18 N3 0.6(17) . .
C17 C16 C19 C20 148.2(9) . .
C15 C16 C19 C20 -31.7(13) . .
C17 C16 C19 C24 -32.3(12) . .
C15 C16 C19 C24 147.8(8) . .
C24 C19 C20 C21 -0.2(13) . .
C16 C19 C20 C21 179.4(9) . .
C19 C20 C21 C22 0.6(15) . .
C20 C21 C22 C23 -0.6(13) . .
C20 C21 C22 C25 179.9(9) . .
C21 C22 C23 C24 0.3(12) . .
C25 C22 C23 C24 179.8(8) . .
C22 C23 C24 C19 0.1(12) . .
C20 C19 C24 C23 -0.2(11) . .
C16 C19 C24 C23 -179.8(7) . .
C21 C22 C25 N4 -154.0(10) . .
C23 C22 C25 N4 26.5(14) . .
C2 C1 N1 C5 1.3(10) . .
C2 C1 N1 Ag1 -172.0(5) . .
C4 C5 N1 C1 -0.7(12) . .
C4 C5 N1 Ag1 172.8(6) . .
N1 Ag1 N1 C1 -58.9(5) 8_456 .
N4 Ag1 N1 C1 75.2(6) 8_456 .
N4 Ag1 N1 C1 155.9(5) . .
N1 Ag1 N1 C5 128.1(6) 8_456 .
N4 Ag1 N1 C5 -97.9(6) 8_456 .
N4 Ag1 N1 C5 -17.2(6) . .
C9 C12 N2 C13 -172.0(10) . .
C9 C12 N2 Ag2 -8.0(16) . .
C13 C13 N2 C12 -148.3(14) 3_657 .
C13 C13 N2 Ag2 43.2(18) 3_657 .
N3 Ag2 N2 C12 -65.9(11) 1_556 .
N3 Ag2 N2 C12 72.5(11) 3_656 .
N2 Ag2 N2 C12 -178.5(13) 3_657 .
N3 Ag2 N2 C13 99.2(8) 1_556 .
N3 Ag2 N2 C13 -122.4(8) 3_656 .
N2 Ag2 N2 C13 -13.4(7) 3_657 .
C15 C14 N3 C18 -0.6(16) . .
C15 C14 N3 Ag2 -164.2(9) . 1_554
C17 C18 N3 C14 -1.3(15) . .
C17 C18 N3 Ag2 161.6(8) . 1_554
C22 C25 N4 C26 -178.5(8) . .
C22 C25 N4 Ag1 18.7(15) . .
C26 C26 N4 C25 144.9(11) 8_456 .
C26 C26 N4 Ag1 -48.5(10) 8_456 .
N1 Ag1 N4 C25 -84.0(10) 8_456 .
N1 Ag1 N4 C25 52.4(9) . .
N4 Ag1 N4 C25 -179.7(11) 8_456 .
N1 Ag1 N4 C26 111.7(5) 8_456 .
N1 Ag1 N4 C26 -111.9(6) . .
N4 Ag1 N4 C26 16.1(4) 8_456 .
F6 F8 Sb2 F8 174(3) . 6
F6 F8 Sb2 F6 179(2) . 6
F6 F8 Sb2 F7' -6(4) . .
F6 F8 Sb2 F7 -13(3) . .
F6 F8 Sb2 F7 58(19) . 6
F6 F8 Sb2 F8' 174(3) . .
F6 F8 Sb2 F5 -94.7(18) . 6
F6 F8 Sb2 F5 86.3(17) . .
F8 F6 Sb2 F8 -7(4) . 6
F8 F6 Sb2 F6 -4(10) . 6
F8 F6 Sb2 F7' 177(2) . .
F8 F6 Sb2 F7 165(3) . .
F8 F6 Sb2 F7 -171(3) . 6
F8 F6 Sb2 F8' -3.5(18) . .
F8 F6 Sb2 F5 85.5(17) . 6
F8 F6 Sb2 F5 -92.9(18) . .
