#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:44:02 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179391 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/88/4328853.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328853
loop_
_publ_author_name
'Alina S. Dinca'
'Alberto Ghirri'
'Augustin M. Madalan'
'Marco Affronte'
'Marius Andruh'
_publ_section_title
;
 Dodecanuclear [CuII6GdIII6] Nanoclusters as Magnetic Refrigerants
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3935
_journal_page_last               3937
_journal_paper_doi               10.1021/ic3001762
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C150 H192 Cu6 Gd6 N30 O72'
_chemical_formula_weight         4892.08
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           148
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   27.497(3)
_cell_length_b                   27.497(3)
_cell_length_c                   21.844(3)
_cell_measurement_reflns_used    16283
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.39
_cell_measurement_theta_min      2.45
_cell_volume                     14303(3)
_computing_cell_refinement       X-Area
_computing_data_collection       X-Area
_computing_data_reduction        X-Area
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'STOE IPDS II'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2159
_diffrn_reflns_av_sigmaI/netI    0.1506
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            20436
_diffrn_reflns_theta_full        25.39
_diffrn_reflns_theta_max         25.39
_diffrn_reflns_theta_min         2.45
_exptl_absorpt_coefficient_mu    2.803
_exptl_absorpt_correction_T_max  1.4392
_exptl_absorpt_correction_T_min  0.4292
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.704
_exptl_crystal_description       prism
_exptl_crystal_F_000             7308
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.437
_refine_diff_density_min         -2.591
_refine_diff_density_rms         0.172
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.963
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     392
_refine_ls_number_reflns         5813
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      0.962
_refine_ls_R_factor_all          0.1059
_refine_ls_R_factor_gt           0.0654
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0523P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1453
_refine_ls_wR_factor_ref         0.1630
_reflns_number_gt                3881
_reflns_number_total             5813
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic3001762_si_001.cif
_cod_data_source_block           shelxl
_cod_original_cell_volume        14302(3)
_cod_original_sg_symbol_H-M      'R -3'
_cod_database_code               4328853
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.1443(4) 0.1832(4) 1.0010(5) 0.031(2) Uani 1 1 d .
C2 C 0.2038(4) 0.2284(4) 0.9907(6) 0.037(3) Uani 1 1 d .
C3 C 0.2306(5) 0.2652(5) 1.0372(6) 0.054(3) Uani 1 1 d .
H3 H 0.2105 0.2644 1.0719 0.064 Uiso 1 1 calc R
C4 C 0.2883(5) 0.3046(5) 1.0332(7) 0.062(4) Uani 1 1 d .
H4 H 0.3066 0.3285 1.0659 0.074 Uiso 1 1 calc R
C5 C 0.3166(5) 0.3077(5) 0.9826(8) 0.068(4) Uani 1 1 d .
H5 H 0.3546 0.3342 0.9807 0.082 Uiso 1 1 calc R
C6 C 0.2911(4) 0.2723(4) 0.9318(6) 0.045(3) Uani 1 1 d .
C7 C 0.2336(4) 0.2297(4) 0.9372(6) 0.038(3) Uani 1 1 d .
C8 C 0.3249(5) 0.2804(5) 0.8779(7) 0.053(3) Uani 1 1 d .
H8 H 0.3632 0.3051 0.8815 0.064 Uiso 1 1 calc R
C9 C 0.2001(5) 0.1753(5) 0.6746(7) 0.061(4) Uani 1 1 d .
H9 H 0.2114 0.1754 0.6344 0.074 Uiso 1 1 calc R
C10 C 0.1399(5) 0.1470(5) 0.6873(6) 0.050(3) Uani 1 1 d .
C11 C 0.1052(6) 0.1275(6) 0.6361(7) 0.071(4) Uani 1 1 d .
H11 H 0.1213 0.1335 0.5973 0.085 Uiso 1 1 calc R
C12 C 0.0479(6) 0.0997(7) 0.6416(7) 0.075(4) Uani 1 1 d .
H12 H 0.0253 0.0876 0.6070 0.090 Uiso 1 1 calc R
C13 C 0.0246(5) 0.0901(5) 0.6983(6) 0.054(3) Uani 1 1 d .
H13 H -0.0142 0.0725 0.7020 0.065 Uiso 1 1 calc R
C14 C 0.0573(4) 0.1058(4) 0.7509(6) 0.042(3) Uani 1 1 d .
C15 C 0.1161(4) 0.1350(4) 0.7461(5) 0.039(2) Uani 1 1 d .
C16 C 0.0297(4) 0.0926(4) 0.8120(5) 0.036(2) Uani 1 1 d .
C17 C 0.2172(5) 0.0850(5) 0.7774(6) 0.047(3) Uani 1 1 d .
H17 H 0.1823 0.0689 0.7584 0.056 Uiso 1 1 calc R
C18 C 0.3131(6) 0.1114(10) 0.7727(10) 0.119(8) Uani 1 1 d .
H18A H 0.3388 0.1105 0.7436 0.179 Uiso 1 1 calc R
H18B H 0.3118 0.0904 0.8085 0.179 Uiso 1 1 calc R
H18C H 0.3256 0.1496 0.7839 0.179 Uiso 1 1 calc R
C19 C 0.2508(8) 0.0686(10) 0.6831(10) 0.119(8) Uani 1 1 d .
H19A H 0.2859 0.0745 0.6673 0.179 Uiso 1 1 calc R
H19B H 0.2384 0.0897 0.6592 0.179 Uiso 1 1 calc R
H19C H 0.2233 0.0293 0.6808 0.179 Uiso 1 1 calc R
C20 C 0.2353(7) 0.3326(5) 0.8136(9) 0.179(16) Uani 1 1 d D
H20 H 0.2568 0.3386 0.8486 0.215 Uiso 1 1 calc R
C21 C 0.2124(19) 0.381(2) 0.739(3) 0.36(4) Uani 1 1 d .
H21A H 0.2161 0.4179 0.7374 0.537 Uiso 1 1 calc R
H21B H 0.1735 0.3531 0.7362 0.537 Uiso 1 1 calc R
H21C H 0.2331 0.3770 0.7065 0.537 Uiso 1 1 calc R
C22 C 0.2607(13) 0.4275(13) 0.824(3) 0.32(3) Uani 1 1 d .
H22A H 0.2520 0.4536 0.8051 0.475 Uiso 1 1 calc R
H22B H 0.3005 0.4421 0.8229 0.475 Uiso 1 1 calc R
H22C H 0.2485 0.4222 0.8663 0.475 Uiso 1 1 calc R
C23 C 0.4379(13) 0.1503(9) 0.8690(17) 0.48(6) Uani 1 1 d D
H23 H 0.4306 0.1230 0.8983 0.578 Uiso 1 1 calc R
C24 C 0.3944(16) 0.193(2) 0.933(2) 0.35(4) Uani 1 1 d .
H24A H 0.3990 0.2304 0.9338 0.521 Uiso 1 1 calc R
H24B H 0.4079 0.1868 0.9711 0.521 Uiso 1 1 calc R
H24C H 0.3553 0.1661 0.9286 0.521 Uiso 1 1 calc R
C25 C 0.4431(14) 0.2250(11) 0.8316(13) 0.33(4) Uani 1 1 d D
H25A H 0.4652 0.2157 0.8051 0.502 Uiso 1 1 calc R
H25B H 0.4652 0.2632 0.8448 0.502 Uiso 1 1 calc R
H25C H 0.4108 0.2203 0.8097 0.502 Uiso 1 1 calc R
Cu1 Cu 0.22793(5) 0.20948(5) 0.80301(7) 0.0404(4) Uani 1 1 d .
Gd1 Gd 0.141537(17) 0.098170(17) 0.88559(2) 0.02762(16) Uani 1 1 d .
N1 N 0.3075(3) 0.2572(4) 0.8264(6) 0.046(3) Uani 1 1 d .
N2 N 0.2394(4) 0.2006(4) 0.7166(5) 0.048(3) Uani 1 1 d .
N3 N 0.2578(4) 0.0867(5) 0.7458(6) 0.065(3) Uani 1 1 d .
N4 N 0.2329(6) 0.3756(4) 0.7933(12) 0.144(10) Uani 1 1 d D
N5 N 0.4255(8) 0.1888(7) 0.8834(12) 0.132(8) Uani 1 1 d D
O1 O 0.1225(3) 0.1400(3) 0.9694(4) 0.0401(17) Uani 1 1 d .
O2 O 0.1180(3) 0.1919(3) 1.0436(4) 0.0460(19) Uani 1 1 d .
O3 O 0.2087(2) 0.1952(2) 0.8904(4) 0.0364(17) Uani 1 1 d .
O4 O 0.3472(3) 0.2697(4) 0.7828(5) 0.075(3) Uani 1 1 d .
O5 O 0.0547(3) 0.0891(3) 0.8589(4) 0.0428(18) Uani 1 1 d .
O6 O -0.0201(3) 0.0828(3) 0.8154(4) 0.050(2) Uani 1 1 d .
O7 O 0.1496(3) 0.1517(3) 0.7950(3) 0.0370(16) Uani 1 1 d .
O8 O 0.2927(3) 0.2235(4) 0.6939(5) 0.065(3) Uani 1 1 d .
O9 O 0.2198(3) 0.1023(3) 0.8297(4) 0.0465(19) Uani 1 1 d .
O10 O 0.2130(4) 0.2854(4) 0.7925(7) 0.105(5) Uani 1 1 d D
O11 O 0.0724(3) 0.0234(2) 0.9451(4) 0.0359(16) Uani 1 1 d .
O12 O 0.458(3) 0.147(2) 0.821(2) 0.55(4) Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O2 122.7(9) . .
O1 C1 C2 121.1(9) . .
O2 C1 C2 116.3(8) . .
C3 C2 C7 120.5(9) . .
C3 C2 C1 117.7(11) . .
C7 C2 C1 121.5(9) . .
C2 C3 C4 120.5(13) . .
C2 C3 H3 119.8 . .
C4 C3 H3 119.8 . .
C5 C4 C3 120.0(12) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C4 C5 C6 122.5(11) . .
C4 C5 H5 118.7 . .
C6 C5 H5 118.7 . .
C5 C6 C7 117.7(12) . .
C5 C6 C8 118.5(10) . .
C7 C6 C8 123.8(11) . .
O3 C7 C2 122.2(8) . .
O3 C7 C6 119.1(10) . .
C2 C7 C6 118.6(11) . .
N1 C8 C6 126.7(10) . .
N1 C8 H8 116.7 . .
C6 C8 H8 116.7 . .
N2 C9 C10 124.1(13) . .
N2 C9 H9 118.0 . .
C10 C9 H9 118.0 . .
C11 C10 C15 119.7(11) . .
C11 C10 C9 115.4(12) . .
C15 C10 C9 124.7(12) . .
C12 C11 C10 121.3(14) . .
C12 C11 H11 119.4 . .
C10 C11 H11 119.4 . .
C13 C12 C11 119.2(15) . .
C13 C12 H12 120.4 . .
C11 C12 H12 120.4 . .
C12 C13 C14 121.7(11) . .
C12 C13 H13 119.2 . .
C14 C13 H13 119.2 . .
C13 C14 C15 119.8(11) . .
C13 C14 C16 119.6(9) . .
C15 C14 C16 120.6(10) . .
O7 C15 C14 122.5(10) . .
O7 C15 C10 119.4(9) . .
C14 C15 C10 118.1(11) . .
O6 C16 O5 120.8(10) . .
O6 C16 C14 118.2(10) . .
O5 C16 C14 120.9(8) . .
O9 C17 N3 127.1(12) . .
O9 C17 H17 116.5 . .
N3 C17 H17 116.5 . .
N3 C18 H18A 109.5 . .
N3 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N3 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N3 C19 H19A 109.5 . .
N3 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N3 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O10 C20 N4 128(2) . .
O10 C20 H20 115.9 . .
N4 C20 H20 115.9 . .
N4 C21 H21A 109.5 . .
N4 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N4 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N4 C22 H22A 109.5 . .
N4 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
N4 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
O12 C23 N5 126(4) . .
O12 C23 H23 116.9 . .
N5 C23 H23 116.9 . .
N5 C24 H24A 109.5 . .
N5 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
N5 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
N5 C25 H25A 109.5 . .
N5 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
N5 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
O7 Cu1 N2 89.5(4) . .
O7 Cu1 O3 81.2(3) . .
N2 Cu1 O3 163.5(3) . .
O7 Cu1 N1 166.9(4) . .
N2 Cu1 N1 98.0(4) . .
O3 Cu1 N1 88.8(4) . .
O7 Cu1 O10 96.0(3) . .
N2 Cu1 O10 97.4(5) . .
O3 Cu1 O10 97.1(4) . .
N1 Cu1 O10 93.6(4) . .
O7 Cu1 Gd1 45.9(2) . .
N2 Cu1 Gd1 119.8(3) . .
O3 Cu1 Gd1 44.85(17) . .
N1 Cu1 Gd1 121.1(3) . .
O10 Cu1 Gd1 121.0(3) . .
O5 Gd1 O1 77.4(3) . .
O5 Gd1 O3 108.1(2) . .
O1 Gd1 O3 69.8(2) . .
O5 Gd1 O11 73.3(2) . .
O1 Gd1 O11 73.7(2) . .
O3 Gd1 O11 142.0(3) . .
O5 Gd1 O2 146.5(2) . 11_557
O1 Gd1 O2 86.2(3) . 11_557
O3 Gd1 O2 92.9(2) . 11_557
O11 Gd1 O2 74.2(2) . 11_557
O5 Gd1 O6 77.0(3) . 3
O1 Gd1 O6 145.4(2) . 3
O3 Gd1 O6 141.2(3) . 3
O11 Gd1 O6 76.8(3) . 3
O2 Gd1 O6 102.9(3) 11_557 3
O5 Gd1 O7 68.9(2) . .
O1 Gd1 O7 108.4(2) . .
O3 Gd1 O7 64.3(2) . .
O11 Gd1 O7 140.3(2) . .
O2 Gd1 O7 144.6(2) 11_557 .
O6 Gd1 O7 83.5(3) 3 .
O5 Gd1 O9 135.3(3) . .
O1 Gd1 O9 141.0(3) . .
O3 Gd1 O9 78.3(2) . .
O11 Gd1 O9 128.6(2) . .
O2 Gd1 O9 73.4(3) 11_557 .
O6 Gd1 O9 72.9(3) 3 .
O7 Gd1 O9 75.5(2) . .
O5 Gd1 Cu1 100.64(17) . .
O1 Gd1 Cu1 101.75(16) . .
O3 Gd1 Cu1 35.84(19) . .
O11 Gd1 Cu1 172.94(16) . .
O2 Gd1 Cu1 111.29(16) 11_557 .
O6 Gd1 Cu1 105.62(19) 3 .
O7 Gd1 Cu1 35.37(15) . .
O9 Gd1 Cu1 58.27(18) . .
C8 N1 O4 116.4(10) . .
C8 N1 Cu1 125.4(8) . .
O4 N1 Cu1 118.1(9) . .
C9 N2 O8 113.4(11) . .
C9 N2 Cu1 126.8(8) . .
O8 N2 Cu1 119.8(9) . .
C17 N3 C19 122.2(13) . .
C17 N3 C18 119.1(13) . .
C19 N3 C18 118.6(13) . .
C20 N4 C21 128(3) . .
C20 N4 C22 121(3) . .
C21 N4 C22 110(3) . .
C23 N5 C25 104(2) . .
C23 N5 C24 132(3) . .
C25 N5 C24 124(3) . .
C1 O1 Gd1 141.4(6) . .
C1 O2 Gd1 140.4(6) . 12_557
C7 O3 Cu1 127.9(6) . .
C7 O3 Gd1 132.2(6) . .
Cu1 O3 Gd1 99.3(3) . .
C16 O5 Gd1 139.2(6) . .
C16 O6 Gd1 139.7(7) . 2
C15 O7 Cu1 130.4(6) . .
C15 O7 Gd1 127.6(6) . .
Cu1 O7 Gd1 98.7(3) . .
C17 O9 Gd1 125.0(7) . .
C20 O10 Cu1 134.3(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.239(11) .
C1 O2 1.272(12) .
C1 C2 1.497(13) .
C2 C3 1.362(16) .
C2 C7 1.416(16) .
C3 C4 1.408(16) .
C3 H3 0.9300 .
C4 C5 1.33(2) .
C4 H4 0.9300 .
C5 C6 1.410(19) .
C5 H5 0.9300 .
C6 C7 1.428(13) .
C6 C8 1.446(19) .
C7 O3 1.327(13) .
C8 N1 1.262(17) .
C8 H8 0.9300 .
C9 N2 1.319(17) .
C9 C10 1.460(16) .
C9 H9 0.9300 .
C10 C11 1.392(19) .
C10 C15 1.405(16) .
C11 C12 1.370(18) .
C11 H11 0.9300 .
C12 C13 1.358(19) .
C12 H12 0.9300 .
C13 C14 1.388(17) .
C13 H13 0.9300 .
C14 C15 1.403(14) .
C14 C16 1.489(15) .
C15 O7 1.333(13) .
C16 O6 1.257(11) .
C16 O5 1.265(12) .
C17 O9 1.224(14) .
C17 N3 1.293(14) .
C17 H17 0.9300 .
C18 N3 1.445(18) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 N3 1.44(2) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 O10 1.215(5) .
C20 N4 1.295(5) .
C20 H20 0.9300 .
C21 N4 1.35(5) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 N4 1.41(3) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 O12 1.221(5) .
C23 N5 1.303(5) .
C23 H23 0.9300 .
C24 N5 1.43(3) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 N5 1.422(5) .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
Cu1 O7 1.942(6) .
Cu1 N2 1.949(11) .
Cu1 O3 1.967(8) .
Cu1 N1 1.975(10) .
Cu1 O10 2.330(8) .
Cu1 Gd1 3.3157(13) .
Gd1 O5 2.347(6) .
Gd1 O1 2.356(7) .
Gd1 O3 2.370(6) .
Gd1 O11 2.371(6) .
Gd1 O2 2.383(8) 11_557
Gd1 O6 2.410(8) 3
Gd1 O7 2.410(7) .
Gd1 O9 2.427(7) .
N1 O4 1.356(12) .
N2 O8 1.367(10) .
O2 Gd1 2.383(8) 12_557
O6 Gd1 2.410(8) 2
