#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/90/4329060.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329060
loop_
_publ_author_name
'Timothy R. Cook'
'Brian D. McCarthy'
'Daniel A. Lutterman'
'Daniel G. Nocera'
_publ_section_title
;
 Halogen Oxidation and Halogen Photoelimination Chemistry of a
 Platinum-Rhodium Heterobimetallic Core
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5152
_journal_page_last               5163
_journal_paper_doi               10.1021/ic300004x
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C23.50 H31 Cl6 F24 N3 O8 P4 Pt Rh'
_chemical_formula_sum            'C23.5 H31 Cl6 F24 N3 O8 P4 Pt Rh'
_chemical_formula_weight         1574.09
_chemical_name_common            'trans PtRh(tfepma)2(tBuNC)Cl5'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.0650(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.5258(15)
_cell_length_b                   11.3342(9)
_cell_length_c                   24.5896(19)
_cell_measurement_reflns_used    9075
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.53
_cell_measurement_theta_min      2.50
_cell_volume                     4908.7(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0489
_diffrn_reflns_av_sigmaI/netI    0.0285
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            104526
_diffrn_reflns_theta_full        29.13
_diffrn_reflns_theta_max         29.13
_diffrn_reflns_theta_min         1.16
_exptl_absorpt_coefficient_mu    3.776
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.5671
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.130
_exptl_crystal_description       block
_exptl_crystal_F_000             3032
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.656
_refine_diff_density_min         -1.144
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     810
_refine_ls_number_reflns         13214
_refine_ls_number_restraints     1024
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0300
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0281P)²+13.1821P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0683
_refine_ls_wR_factor_ref         0.0726
_reflns_number_gt                11528
_reflns_number_total             13214
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300004x_si_004.cif
_cod_data_source_block           09144t
_cod_original_formula_sum        'C23.50 H31 Cl6 F24 N3 O8 P4 Pt Rh'
_cod_database_code               4329060
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.698904(6) -0.172523(10) 0.759863(5) 0.01325(3) Uani 1 1 d U . .
Rh1 Rh 0.786832(13) -0.34099(2) 0.734495(10) 0.01575(5) Uani 1 1 d U A .
P1 P 0.65842(5) -0.11174(7) 0.66568(3) 0.01707(15) Uani 1 1 d U . .
P2 P 0.70790(5) -0.34228(8) 0.64155(4) 0.02113(17) Uani 1 1 d DU . .
P3 P 0.73835(4) -0.23450(7) 0.85388(3) 0.01534(15) Uani 1 1 d U . .
P4 P 0.86519(5) -0.34593(7) 0.82779(4) 0.01894(16) Uani 1 1 d U . .
Cl1 Cl 0.61497(4) -0.02712(7) 0.78708(3) 0.01898(14) Uani 1 1 d U . .
Cl2 Cl 0.59586(4) -0.30159(7) 0.73346(3) 0.01870(14) Uani 1 1 d U . .
Cl3 Cl 0.79653(4) -0.03412(7) 0.78510(3) 0.01887(14) Uani 1 1 d U . .
Cl4 Cl 0.85906(4) -0.20428(7) 0.70016(3) 0.02256(16) Uani 1 1 d U . .
Cl5 Cl 0.86061(5) -0.49696(8) 0.71128(4) 0.02743(17) Uani 1 1 d U . .
N1 N 0.66717(15) -0.2116(3) 0.61863(11) 0.0210(5) Uani 1 1 d U A .
N2 N 0.82355(15) -0.2967(2) 0.87537(11) 0.0189(5) Uani 1 1 d U A .
N3 N 0.70656(15) -0.5461(2) 0.77523(13) 0.0226(6) Uani 1 1 d U A .
O1 O 0.68947(13) 0.0104(2) 0.65007(10) 0.0238(5) Uani 1 1 d U . .
O2 O 0.57028(13) -0.0861(2) 0.64193(10) 0.0215(5) Uani 1 1 d U . .
O4 O 0.74080(13) -0.3814(3) 0.59182(11) 0.0293(6) Uani 1 1 d DU A .
O5 O 0.73965(13) -0.1396(2) 0.90178(9) 0.0193(4) Uani 1 1 d U . .
O6 O 0.68662(13) -0.33091(19) 0.87056(10) 0.0187(4) Uani 1 1 d U . .
O7 O 0.94908(13) -0.2937(2) 0.84687(11) 0.0255(5) Uani 1 1 d U A .
O8 O 0.88514(14) -0.4761(2) 0.85284(11) 0.0265(5) Uani 1 1 d DU A .
F1 F 0.82840(19) 0.1770(2) 0.61331(18) 0.0712(11) Uani 1 1 d U . .
F2 F 0.75370(18) 0.2330(2) 0.66057(17) 0.0691(10) Uani 1 1 d U . .
F3 F 0.7077(2) 0.1751(3) 0.57483(15) 0.0773(11) Uani 1 1 d U . .
F4 F 0.51071(16) 0.0735(2) 0.55303(10) 0.0444(6) Uani 1 1 d U . .
F5 F 0.42794(14) -0.0369(2) 0.57283(12) 0.0487(7) Uani 1 1 d U . .
F6 F 0.43733(14) 0.1465(2) 0.59772(11) 0.0412(6) Uani 1 1 d U . .
F13 F 0.83910(16) -0.0521(3) 1.00390(11) 0.0546(7) Uani 1 1 d U . .
F14 F 0.81184(17) 0.1257(2) 0.97395(11) 0.0512(7) Uani 1 1 d U . .
F15 F 0.72583(16) 0.0105(3) 0.98642(12) 0.0585(8) Uani 1 1 d U . .
F16 F 0.65450(15) -0.2666(3) 0.97056(10) 0.0483(7) Uani 1 1 d U . .
F17 F 0.62236(15) -0.4444(2) 0.94422(12) 0.0450(6) Uani 1 1 d U . .
F18 F 0.53594(13) -0.3103(2) 0.93144(11) 0.0388(6) Uani 1 1 d U . .
F19 F 1.03525(16) -0.0121(2) 0.88018(12) 0.0536(7) Uani 1 1 d U . .
F20 F 0.95501(15) -0.0903(2) 0.91679(11) 0.0457(6) Uani 1 1 d U . .
F21 F 1.06129(15) -0.1757(2) 0.92564(11) 0.0483(7) Uani 1 1 d U . .
C1 C 0.7629(2) 0.0315(3) 0.64326(15) 0.0253(7) Uani 1 1 d U . .
H1A H 0.7724 -0.0247 0.6154 0.030 Uiso 1 1 calc R . .
H1B H 0.8035 0.0218 0.6803 0.030 Uiso 1 1 calc R . .
C2 C 0.7618(3) 0.1548(4) 0.6222(2) 0.0435(11) Uani 1 1 d U . .
C3 C 0.53336(19) 0.0208(3) 0.64962(14) 0.0228(7) Uani 1 1 d U . .
H3A H 0.5710 0.0851 0.6625 0.027 Uiso 1 1 calc R . .
H3B H 0.5072 0.0095 0.6787 0.027 Uiso 1 1 calc R . .
C4 C 0.4773(2) 0.0507(3) 0.59302(16) 0.0308(8) Uani 1 1 d U . .
C9 C 0.6270(2) -0.1899(3) 0.55661(14) 0.0263(7) Uani 1 1 d U . .
H9A H 0.6266 -0.1051 0.5488 0.039 Uiso 1 1 calc R A .
H9B H 0.5747 -0.2187 0.5470 0.039 Uiso 1 1 calc R . .
H9C H 0.6534 -0.2316 0.5334 0.039 Uiso 1 1 calc R . .
C11 C 0.7862(2) 0.0143(4) 0.96856(16) 0.0319(8) Uani 1 1 d U . .
C10 C 0.7698(2) -0.0222(3) 0.90726(15) 0.0265(7) Uani 1 1 d U . .
H10A H 0.7326 0.0323 0.8819 0.032 Uiso 1 1 calc R . .
H10B H 0.8170 -0.0204 0.8964 0.032 Uiso 1 1 calc R . .
C12 C 0.61107(19) -0.3033(3) 0.87134(14) 0.0222(7) Uani 1 1 d U . .
H12A H 0.5733 -0.3508 0.8423 0.027 Uiso 1 1 calc R . .
H12B H 0.6000 -0.2187 0.8625 0.027 Uiso 1 1 calc R . .
C13 C 0.6069(2) -0.3311(3) 0.92998(17) 0.0296(8) Uani 1 1 d U . .
C14 C 0.97053(19) -0.1776(3) 0.83394(15) 0.0252(7) Uani 1 1 d U . .
H14A H 0.9253 -0.1340 0.8104 0.030 Uiso 1 1 calc R A .
H14B H 1.0073 -0.1832 0.8122 0.030 Uiso 1 1 calc R . .
C15 C 1.0059(2) -0.1142(4) 0.88964(17) 0.0339(8) Uani 1 1 d U A .
C18 C 0.8597(2) -0.3241(3) 0.93744(15) 0.0289(8) Uani 1 1 d U . .
H18A H 0.8379 -0.2730 0.9605 0.043 Uiso 1 1 calc R A .
H18B H 0.9145 -0.3103 0.9479 0.043 Uiso 1 1 calc R . .
H18C H 0.8503 -0.4068 0.9446 0.043 Uiso 1 1 calc R . .
C19 C 0.73132(19) -0.4640(3) 0.75907(15) 0.0225(6) Uani 1 1 d U . .
C20 C 0.6787(2) -0.6502(3) 0.79719(15) 0.0261(7) Uani 1 1 d DU . .
C22A C 0.7082(5) -0.6488(7) 0.8629(3) 0.0331(16) Uani 0.530(3) 1 d PDU A 1
H22A H 0.6744 -0.6007 0.8776 0.050 Uiso 0.530(3) 1 calc PR A 1
H22B H 0.7595 -0.6154 0.8756 0.050 Uiso 0.530(3) 1 calc PR A 1
H22C H 0.7095 -0.7296 0.8773 0.050 Uiso 0.530(3) 1 calc PR A 1
C23A C 0.5915(4) -0.6457(7) 0.7774(3) 0.0366(18) Uani 0.530(3) 1 d PDU A 1
H23A H 0.5744 -0.5705 0.7581 0.055 Uiso 0.530(3) 1 calc PR A 1
H23B H 0.5733 -0.6529 0.8107 0.055 Uiso 0.530(3) 1 calc PR A 1
H23C H 0.5713 -0.7109 0.7509 0.055 Uiso 0.530(3) 1 calc PR A 1
C21A C 0.7085(5) -0.7527(6) 0.7724(4) 0.0404(19) Uani 0.530(3) 1 d PDU A 1
H21A H 0.6746 -0.7688 0.7338 0.061 Uiso 0.530(3) 1 calc PR A 1
H21B H 0.7110 -0.8223 0.7966 0.061 Uiso 0.530(3) 1 calc PR A 1
H21C H 0.7594 -0.7342 0.7706 0.061 Uiso 0.530(3) 1 calc PR A 1
C22B C 0.7507(7) -0.7197(11) 0.8274(7) 0.082(4) Uani 0.470(3) 1 d PDU A 2
H22D H 0.7697 -0.7580 0.7988 0.122 Uiso 0.470(3) 1 calc PR A 2
H22E H 0.7391 -0.7798 0.8521 0.122 Uiso 0.470(3) 1 calc PR A 2
H22F H 0.7895 -0.6658 0.8506 0.122 Uiso 0.470(3) 1 calc PR A 2
C23B C 0.6368(8) -0.6075(9) 0.8349(5) 0.063(3) Uani 0.470(3) 1 d PDU A 2
H23D H 0.5915 -0.5646 0.8123 0.094 Uiso 0.470(3) 1 calc PR A 2
H23E H 0.6693 -0.5547 0.8637 0.094 Uiso 0.470(3) 1 calc PR A 2
H23F H 0.6215 -0.6747 0.8539 0.094 Uiso 0.470(3) 1 calc PR A 2
C21B C 0.6306(8) -0.7174(10) 0.7456(4) 0.061(3) Uani 0.470(3) 1 d PDU A 2
H21D H 0.5845 -0.6724 0.7268 0.092 Uiso 0.470(3) 1 calc PR A 2
H21E H 0.6167 -0.7942 0.7578 0.092 Uiso 0.470(3) 1 calc PR A 2
H21F H 0.6595 -0.7294 0.7187 0.092 Uiso 0.470(3) 1 calc PR A 2
C6A C 0.5694(7) -0.5973(11) 0.5953(5) 0.030(3) Uani 0.470(3) 1 d PDU A 1
C5A C 0.6459(3) -0.5439(5) 0.6141(3) 0.0205(12) Uani 0.530(3) 1 d PDU A 1
H5AA H 0.6904 -0.5805 0.6106 0.025 Uiso 0.530(3) 1 calc PR A 1
O3A O 0.6442(4) -0.4444(6) 0.6352(3) 0.0220(14) Uani 0.530(3) 1 d PDU A 1
F7A F 0.5291(6) -0.5707(14) 0.6307(8) 0.044(3) Uani 0.530(3) 1 d PDU A 1
F9A F 0.5253(3) -0.5609(5) 0.54404(19) 0.0387(11) Uani 0.530(3) 1 d PDU A 1
F8A F 0.5736(3) -0.7143(4) 0.5941(3) 0.0498(15) Uani 0.530(3) 1 d PDU A 1
C6B C 0.5525(6) -0.5930(9) 0.5957(5) 0.025(2) Uani 0.530(3) 1 d PDU A 2
C5B C 0.6035(4) -0.5033(7) 0.5829(3) 0.0259(16) Uani 0.470(3) 1 d PDU A 2
H5BA H 0.6142 -0.5086 0.5476 0.031 Uiso 0.470(3) 1 calc PR A 2
O3B O 0.6336(5) -0.4194(6) 0.6172(3) 0.0173(14) Uani 0.470(3) 1 d PDU A 2
F7B F 0.5081(7) -0.5517(15) 0.6258(8) 0.034(2) Uani 0.470(3) 1 d PDU A 2
F9B F 0.5068(3) -0.6379(6) 0.5465(2) 0.0457(15) Uani 0.470(3) 1 d PDU A 2
F8B F 0.5895(4) -0.6826(5) 0.6271(3) 0.0418(14) Uani 0.470(3) 1 d PDU A 2
C17A C 0.9863(6) -0.5974(10) 0.9007(4) 0.045(2) Uani 0.530(3) 1 d PDU A 1
C16A C 0.9478(11) -0.5411(18) 0.8436(7) 0.027(3) Uani 0.530(3) 1 d PDU A 1
H16A H 0.9829 -0.4875 0.8324 0.032 Uiso 0.530(3) 1 calc PR A 1
H16B H 0.9291 -0.6017 0.8135 0.032 Uiso 0.530(3) 1 calc PR A 1
F22A F 1.0450(5) -0.6637(8) 0.8973(5) 0.060(2) Uani 0.530(3) 1 d PDU A 1
F23A F 0.9432(7) -0.6619(10) 0.9209(5) 0.071(3) Uani 0.470(3) 1 d PDU A 1
F24A F 1.0178(4) -0.5139(8) 0.9399(3) 0.087(2) Uani 0.530(3) 1 d PDU A 1
C17B C 0.9621(7) -0.6383(10) 0.9022(5) 0.037(3) Uani 0.470(3) 1 d PDU A 2
C16B C 0.9474(13) -0.553(2) 0.8531(8) 0.031(3) Uani 0.470(3) 1 d PDU A 2
H16C H 0.9935 -0.5053 0.8569 0.037 Uiso 0.470(3) 1 calc PR A 2
H16D H 0.9349 -0.5968 0.8165 0.037 Uiso 0.470(3) 1 calc PR A 2
F22B F 1.0227(5) -0.7035(7) 0.9017(5) 0.045(2) Uani 0.470(3) 1 d PDU A 2
F23B F 0.9061(4) -0.7069(6) 0.8980(4) 0.059(2) Uani 0.470(3) 1 d PDU A 2
F24B F 0.9798(4) -0.5837(7) 0.9517(3) 0.0570(16) Uani 0.530(3) 1 d PDU A 2
C7A C 0.8135(9) -0.355(2) 0.5863(7) 0.025(4) Uani 0.530(3) 1 d PDU A 1
H7AA H 0.8541 -0.3714 0.6226 0.029 Uiso 0.530(3) 1 calc PR A 1
H7AB H 0.8164 -0.2714 0.5760 0.029 Uiso 0.530(3) 1 calc PR A 1
C8A C 0.8217(5) -0.4346(9) 0.5395(4) 0.0347(19) Uani 0.530(3) 1 d PDU A 1
F11A F 0.8886(3) -0.4171(7) 0.5313(3) 0.0620(19) Uani 0.530(3) 1 d PDU A 1
F12A F 0.8173(4) -0.5470(5) 0.5531(3) 0.0574(17) Uani 0.530(3) 1 d PDU A 1
F10A F 0.7690(4) -0.4160(8) 0.4906(3) 0.0571(18) Uani 0.530(3) 1 d PDU A 1
C7B C 0.8055(10) -0.343(2) 0.5769(8) 0.025(4) Uani 0.470(3) 1 d PDU A 2
H7BA H 0.8530 -0.3707 0.6053 0.030 Uiso 0.470(3) 1 calc PR A 2
H7BB H 0.8069 -0.2557 0.5749 0.030 Uiso 0.470(3) 1 calc PR A 2
C8B C 0.7958(6) -0.3968(9) 0.5194(5) 0.0292(19) Uani 0.470(3) 1 d PDU A 2
F11B F 0.8546(4) -0.3676(6) 0.5025(3) 0.0409(14) Uani 0.470(3) 1 d PDU A 2
F12B F 0.7922(4) -0.5146(6) 0.5202(3) 0.0446(15) Uani 0.470(3) 1 d PDU A 2
F10B F 0.7326(4) -0.3591(7) 0.4806(2) 0.0472(16) Uani 0.470(3) 1 d PDU A 2
Cl1S Cl 0.93227(7) 0.15310(11) 0.76857(6) 0.0522(3) Uani 1 1 d U . .
C1S C 1.0000 0.2352(7) 0.7500 0.088(4) Uani 1 2 d SU . .
H1SA H 1.0262 0.2868 0.7826 0.106 Uiso 0.50 1 calc PR . .
H1SB H 0.9738 0.2868 0.7174 0.106 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
P1 Pt1 P3 179.43(3) .
P1 Pt1 Cl3 92.88(3) .
P3 Pt1 Cl3 87.68(3) .
P1 Pt1 Cl2 85.68(3) .
P3 Pt1 Cl2 93.76(3) .
Cl3 Pt1 Cl2 176.50(3) .
P1 Pt1 Cl1 92.09(3) .
P3 Pt1 Cl1 87.84(3) .
Cl3 Pt1 Cl1 88.89(3) .
Cl2 Pt1 Cl1 87.97(3) .
P1 Pt1 Rh1 90.62(2) .
P3 Pt1 Rh1 89.42(2) .
Cl3 Pt1 Rh1 93.64(2) .
Cl2 Pt1 Rh1 89.57(2) .
Cl1 Pt1 Rh1 176.193(19) .
C19 Rh1 P2 94.01(11) .
C19 Rh1 P4 84.46(10) .
P2 Rh1 P4 178.20(3) .
C19 Rh1 Cl4 174.76(10) .
P2 Rh1 Cl4 84.56(3) .
P4 Rh1 Cl4 96.88(3) .
C19 Rh1 Cl5 86.62(10) .
P2 Rh1 Cl5 89.57(3) .
P4 Rh1 Cl5 89.40(3) .
Cl4 Rh1 Cl5 88.33(3) .
C19 Rh1 Pt1 91.15(9) .
P2 Rh1 Pt1 89.48(2) .
P4 Rh1 Pt1 91.49(2) .
Cl4 Rh1 Pt1 93.88(2) .
Cl5 Rh1 Pt1 177.51(2) .
O2 P1 O1 99.21(13) .
O2 P1 N1 100.42(14) .
O1 P1 N1 107.69(14) .
O2 P1 Pt1 113.75(9) .
O1 P1 Pt1 118.21(10) .
N1 P1 Pt1 115.08(11) .
O3B P2 O4 92.9(3) .
O4 P2 O3A 99.7(3) .
O3B P2 N1 96.5(3) .
O4 P2 N1 103.15(15) .
O3A P2 N1 111.0(3) .
O3B P2 Rh1 126.2(2) .
O4 P2 Rh1 119.28(10) .
O3A P2 Rh1 108.6(2) .
N1 P2 Rh1 114.15(10) .
O6 P3 O5 98.37(12) .
O6 P3 N2 102.47(13) .
O5 P3 N2 104.91(13) .
O6 P3 Pt1 116.04(9) .
O5 P3 Pt1 117.64(9) .
N2 P3 Pt1 115.03(10) .
O7 P4 O8 98.16(13) .
O7 P4 N2 106.73(14) .
O8 P4 N2 98.01(14) .
O7 P4 Rh1 122.72(10) .
O8 P4 Rh1 113.90(10) .
N2 P4 Rh1 113.63(10) .
C9 N1 P1 118.2(2) .
C9 N1 P2 121.2(2) .
P1 N1 P2 119.87(16) .
C18 N2 P3 119.6(2) .
C18 N2 P4 118.9(2) .
P3 N2 P4 121.02(16) .
C19 N3 C20 177.6(4) .
C1 O1 P1 126.7(2) .
C3 O2 P1 126.0(2) .
C7A O4 P2 127.9(5) .
C7B O4 P2 131.7(6) .
C10 O5 P3 127.8(2) .
C12 O6 P3 121.4(2) .
C14 O7 P4 125.9(2) .
C16B O8 P4 130.3(9) .
C16A O8 P4 120.6(7) .
O1 C1 C2 106.5(3) .
F3 C2 F2 106.9(4) .
F3 C2 F1 108.3(4) .
F2 C2 F1 107.4(4) .
F3 C2 C1 113.7(4) .
F2 C2 C1 111.6(4) .
F1 C2 C1 108.6(4) .
O2 C3 C4 106.9(3) .
F5 C4 F6 107.5(3) .
F5 C4 F4 106.8(3) .
F6 C4 F4 107.5(3) .
F5 C4 C3 112.1(3) .
F6 C4 C3 110.3(3) .
F4 C4 C3 112.4(3) .
F15 C11 F13 107.0(4) .
F15 C11 F14 107.9(3) .
F13 C11 F14 107.7(3) .
F15 C11 C10 113.3(3) .
F13 C11 C10 112.4(3) .
F14 C11 C10 108.3(3) .
O5 C10 C11 107.6(3) .
O6 C12 C13 107.8(3) .
F16 C13 F17 107.1(3) .
F16 C13 F18 108.0(3) .
F17 C13 F18 107.0(3) .
F16 C13 C12 112.8(3) .
F17 C13 C12 112.5(3) .
F18 C13 C12 109.3(3) .
O7 C14 C15 107.9(3) .
F21 C15 F19 107.5(3) .
F21 C15 F20 107.0(3) .
F19 C15 F20 107.5(3) .
F21 C15 C14 112.6(3) .
F19 C15 C14 110.0(3) .
F20 C15 C14 112.0(3) .
N3 C19 Rh1 171.2(3) .
N3 C20 C23B 106.6(5) .
N3 C20 C21A 105.1(4) .
C23B C20 C21A 148.3(6) .
N3 C20 C21B 106.4(5) .
C23B C20 C21B 114.1(8) .
C21A C20 C21B 57.4(6) .
N3 C20 C22B 103.9(5) .
C23B C20 C22B 114.7(9) .
C21A C20 C22B 54.6(7) .
C21B C20 C22B 110.2(9) .
N3 C20 C23A 108.4(4) .
C23B C20 C23A 58.5(6) .
C21A C20 C23A 112.4(5) .
C21B C20 C23A 57.5(6) .
C22B C20 C23A 147.6(6) .
N3 C20 C22A 109.3(4) .
C23B C20 C22A 54.3(6) .
C21A C20 C22A 112.3(5) .
C21B C20 C22A 144.4(5) .
C22B C20 C22A 61.5(7) .
C23A C20 C22A 109.2(5) .
F8A C6A F9A 108.0(9) .
F8A C6A F7A 106.6(11) .
F9A C6A F7A 104.0(13) .
F8A C6A C5A 111.0(10) .
F9A C6A C5A 114.5(9) .
F7A C6A C5A 112.1(10) .
O3A C5A C6A 110.8(8) .
C5A O3A P2 124.9(7) .
F8B C6B F9B 107.5(8) .
F8B C6B F7B 103.8(9) .
F9B C6B F7B 107.7(12) .
F8B C6B C5B 113.5(9) .
F9B C6B C5B 109.4(8) .
F7B C6B C5B 114.5(11) .
O3B C5B C6B 123.0(8) .
C5B O3B P2 144.1(8) .
F23A C17A F22A 108.4(10) .
F23A C17A F24A 107.8(10) .
F22A C17A F24A 105.0(9) .
F23A C17A C16A 115.3(13) .
F22A C17A C16A 109.6(9) .
F24A C17A C16A 110.1(13) .
O8 C16A C17A 103.8(9) .
F23B C17B F24B 109.0(11) .
F23B C17B F22B 108.9(9) .
F24B C17B F22B 107.4(10) .
F23B C17B C16B 112.8(15) .
F24B C17B C16B 111.8(14) .
F22B C17B C16B 106.8(10) .
O8 C16B C17B 109.6(10) .
O4 C7A C8A 105.8(9) .
F10A C8A F12A 107.4(7) .
F10A C8A F11A 107.5(8) .
F12A C8A F11A 108.3(8) .
F10A C8A C7A 112.5(12) .
F12A C8A C7A 110.7(12) .
F11A C8A C7A 110.3(7) .
O4 C7B C8B 104.6(9) .
F11B C8B F10B 108.7(9) .
F11B C8B F12B 107.7(8) .
F10B C8B F12B 107.1(9) .
F11B C8B C7B 108.9(8) .
F10B C8B C7B 111.6(13) .
F12B C8B C7B 112.6(15) .
Cl1S C1S Cl1S 115.1(4) 2_756
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P1 2.3072(8) .
Pt1 P3 2.3073(8) .
Pt1 Cl3 2.3283(7) .
Pt1 Cl2 2.3318(8) .
Pt1 Cl1 2.4955(7) .
Pt1 Rh1 2.7053(3) .
Rh1 C19 1.937(4) .
Rh1 P2 2.2998(9) .
Rh1 P4 2.3040(9) .
Rh1 Cl4 2.3675(8) .
Rh1 Cl5 2.4090(8) .
P1 O2 1.581(2) .
P1 O1 1.591(2) .
P1 N1 1.662(3) .
P2 O3B 1.583(7) .
P2 O4 1.589(2) .
P2 O3A 1.626(6) .
P2 N1 1.678(3) .
P3 O6 1.589(2) .
P3 O5 1.589(2) .
P3 N2 1.659(3) .
P4 O7 1.592(2) .
P4 O8 1.598(3) .
P4 N2 1.683(3) .
N1 C9 1.496(4) .
N2 C18 1.497(4) .
N3 C19 1.161(4) .
N3 C20 1.457(4) .
O1 C1 1.442(4) .
O2 C3 1.432(4) .
O4 C7A 1.426(10) .
O4 C7B 1.426(12) .
O5 C10 1.433(4) .
O6 C12 1.440(4) .
O7 C14 1.439(4) .
O8 C16B 1.443(10) .
O8 C16A 1.451(10) .
F1 C2 1.342(5) .
F2 C2 1.338(5) .
F3 C2 1.300(6) .
F4 C4 1.340(5) .
F5 C4 1.336(5) .
F6 C4 1.339(4) .
F13 C11 1.324(5) .
F14 C11 1.341(5) .
F15 C11 1.324(5) .
F16 C13 1.327(5) .
F17 C13 1.338(4) .
F18 C13 1.348(4) .
F19 C15 1.329(5) .
F20 C15 1.341(5) .
F21 C15 1.326(5) .
C1 C2 1.489(5) .
C3 C4 1.495(5) .
C11 C10 1.501(5) .
C12 C13 1.501(5) .
C14 C15 1.505(5) .
C20 C23B 1.463(9) .
C20 C21A 1.495(8) .
C20 C21B 1.511(10) .
C20 C22B 1.529(11) .
C20 C23A 1.535(8) .
C20 C22A 1.536(8) .
C6A F8A 1.328(13) .
C6A F9A 1.337(12) .
C6A F7A 1.346(11) .
C6A C5A 1.478(12) .
C5A O3A 1.247(8) .
C6B F8B 1.330(10) .
C6B F9B 1.343(11) .
C6B F7B 1.351(11) .
C6B C5B 1.487(11) .
C5B O3B 1.279(9) .
C17A F23A 1.290(14) .
C17A F22A 1.345(10) .
C17A F24A 1.347(12) .
C17A C16A 1.506(12) .
C17B F23B 1.274(14) .
C17B F24B 1.314(13) .
C17B F22B 1.347(11) .
C17B C16B 1.506(14) .
C7A C8A 1.503(12) .
C8A F10A 1.310(11) .
C8A F12A 1.327(11) .
C8A F11A 1.331(8) .
C7B C8B 1.499(12) .
C8B F11B 1.324(9) .
C8B F10B 1.329(13) .
C8B F12B 1.338(11) .
Cl1S C1S 1.733(4) .
C1S Cl1S 1.733(4) 2_756
