#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:53:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179398 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/95/4329502.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329502
loop_
_publ_author_name
'Sheng-Ping Guo'
'Tae-Soo You'
'Ya-Ho Jung'
'Svilen Bobev'
_publ_section_title
;
 Synthesis, Crystal Chemistry, and Magnetic Properties of RE7Li8Ge10 and
 RE11Li12Ge16 (RE= La-Nd, Sm): New Members of the [REGe2]n[RELi2Ge]m
 Homologous Series
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6821
_journal_page_last               6829
_journal_paper_doi               10.1021/ic300566x
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         Ce11Li12Ge16
_chemical_formula_sum            'Ce11 Ge16 Li12'
_chemical_formula_weight         2786.04
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           71
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-I 2 2'
_symmetry_space_group_name_H-M   'I m m m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   4.4681(4)
_cell_length_b                   6.9249(6)
_cell_length_c                   52.492(5)
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      28.2
_cell_measurement_theta_min      0.8
_cell_volume                     1624.2(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0481
_diffrn_reflns_av_sigmaI/netI    0.0247
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       70
_diffrn_reflns_limit_l_min       -70
_diffrn_reflns_number            10921
_diffrn_reflns_theta_full        28.30
_diffrn_reflns_theta_max         28.30
_diffrn_reflns_theta_min         0.78
_exptl_absorpt_coefficient_mu    29.579
_exptl_absorpt_correction_T_max  0.4608
_exptl_absorpt_correction_T_min  0.3432
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    5.697
_exptl_crystal_description       irregular
_exptl_crystal_F_000             2372
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.431
_refine_diff_density_min         -1.614
_refine_diff_density_rms         0.334
_refine_ls_extinction_coef       0.00179(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.130
_refine_ls_matrix_type           full
_refine_ls_number_parameters     63
_refine_ls_number_reflns         1231
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.130
_refine_ls_R_factor_all          0.0361
_refine_ls_R_factor_gt           0.0245
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0244P)²+34.4070P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0548
_refine_ls_wR_factor_ref         0.0750
_reflns_number_gt                984
_reflns_number_total             1231
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300566x_si_002_6.cif
_cod_data_source_block           VI
_cod_original_cell_volume        1624.2(2)
_cod_database_code               4329502
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ce1 Ce 0.5000 0.0000 0.102819(14) 0.0084(2) Uani 1 4 d S
Ce2 Ce 0.5000 0.0000 0.178723(13) 0.00702(18) Uani 1 4 d S
Ce3 Ce 0.5000 0.0000 0.462905(13) 0.00808(19) Uani 1 4 d S
Ce4 Ce 0.0000 0.0000 0.282623(13) 0.00795(19) Uani 1 4 d S
Ce5 Ce 0.0000 0.0000 0.358427(13) 0.00722(19) Uani 1 4 d S
Ce6 Ce 0.0000 0.0000 0.0000 0.0076(2) Uani 1 8 d S
Ge1 Ge 0.0000 0.18130(14) 0.138322(18) 0.0083(2) Uani 1 2 d S
Ge2 Ge 0.0000 0.31882(14) 0.182111(17) 0.0081(2) Uani 1 2 d S
Ge3 Ge 0.5000 0.0000 0.23916(3) 0.0091(3) Uani 1 4 d S
Ge4 Ge 0.0000 0.0000 0.06021(3) 0.0098(3) Uani 1 4 d S
Ge5 Ge 0.0000 0.0000 0.41863(3) 0.0097(3) Uani 1 4 d S
Ge6 Ge 0.0000 0.1833(2) 0.5000 0.0082(3) Uani 1 4 d S
Li1 Li 0.0000 0.187(2) 0.2285(3) 0.014(3) Uiso 1 2 d S
Li2 Li 0.0000 0.313(2) 0.0915(3) 0.008(3) Uiso 1 2 d S
Li3 Li 0.0000 0.310(2) 0.4526(3) 0.045(5) Uiso 0.952(6) 2 d SP
Ge3* Ge 0.0000 0.310(2) 0.4526(3) 0.045(5) Uiso 0.048(6) 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge4 Ce1 Ge4 89.93(4) 1_655 .
Ge4 Ce1 Ge1 85.29(2) 1_655 1_655
Ge4 Ce1 Ge1 156.117(19) . 1_655
Ge4 Ce1 Ge1 85.29(2) 1_655 2_655
Ge4 Ce1 Ge1 156.117(19) . 2_655
Ge1 Ce1 Ge1 46.68(3) 1_655 2_655
Ge4 Ce1 Ge1 156.117(19) 1_655 2
Ge4 Ce1 Ge1 85.29(2) . 2
Ge1 Ce1 Ge1 107.95(4) 1_655 2
Ge1 Ce1 Ge1 89.67(3) 2_655 2
Ge4 Ce1 Ge1 156.118(19) 1_655 .
Ge4 Ce1 Ge1 85.29(2) . .
Ge1 Ce1 Ge1 89.67(3) 1_655 .
Ge1 Ce1 Ge1 107.95(4) 2_655 .
Ge1 Ce1 Ge1 46.68(3) 2 .
Ge4 Ce1 Li2 111.5(2) 1_655 .
Ge4 Ce1 Li2 51.0(3) . .
Ge1 Ce1 Li2 109.6(2) 1_655 .
Ge1 Ce1 Li2 151.4(3) 2_655 .
Ge1 Ce1 Li2 83.4(2) 2 .
Ge1 Ce1 Li2 48.8(2) . .
Ge4 Ce1 Li2 111.5(2) 1_655 2
Ge4 Ce1 Li2 51.0(3) . 2
Ge1 Ce1 Li2 151.4(3) 1_655 2
Ge1 Ce1 Li2 109.6(2) 2_655 2
Ge1 Ce1 Li2 48.8(2) 2 2
Ge1 Ce1 Li2 83.4(2) . 2
Li2 Ce1 Li2 86.4(4) . 2
Ge4 Ce1 Li2 50.9(3) 1_655 1_655
Ge4 Ce1 Li2 111.5(2) . 1_655
Ge1 Ce1 Li2 48.8(2) 1_655 1_655
Ge1 Ce1 Li2 83.4(2) 2_655 1_655
Ge1 Ce1 Li2 151.4(3) 2 1_655
Ge1 Ce1 Li2 109.6(2) . 1_655
Li2 Ce1 Li2 89.6(4) . 1_655
Li2 Ce1 Li2 158.5(5) 2 1_655
Ge4 Ce1 Li2 50.9(3) 1_655 2_655
Ge4 Ce1 Li2 111.5(2) . 2_655
Ge1 Ce1 Li2 83.4(2) 1_655 2_655
Ge1 Ce1 Li2 48.8(2) 2_655 2_655
Ge1 Ce1 Li2 109.6(2) 2 2_655
Ge1 Ce1 Li2 151.4(3) . 2_655
Li2 Ce1 Li2 158.5(5) . 2_655
Li2 Ce1 Li2 89.6(4) 2 2_655
Li2 Ce1 Li2 86.4(4) 1_655 2_655
Ge4 Ce1 Ge3* 49.85(11) 1_655 14_545
Ge4 Ce1 Ge3* 49.85(11) . 14_545
Ge1 Ce1 Ge3* 134.35(5) 1_655 14_545
Ge1 Ce1 Ge3* 111.90(19) 2_655 14_545
Ge1 Ce1 Ge3* 111.90(19) 2 14_545
Ge1 Ce1 Ge3* 134.35(5) . 14_545
Li2 Ce1 Ge3* 96.4(3) . 14_545
Li2 Ce1 Ge3* 63.1(3) 2 14_545
Li2 Ce1 Ge3* 96.4(3) 1_655 14_545
Li2 Ce1 Ge3* 63.1(3) 2_655 14_545
Ge4 Ce1 Li3 49.85(11) 1_655 14_545
Ge4 Ce1 Li3 49.85(11) . 14_545
Ge1 Ce1 Li3 134.35(5) 1_655 14_545
Ge1 Ce1 Li3 111.90(19) 2_655 14_545
Ge1 Ce1 Li3 111.90(19) 2 14_545
Ge1 Ce1 Li3 134.35(5) . 14_545
Li2 Ce1 Li3 96.4(3) . 14_545
Li2 Ce1 Li3 63.1(3) 2 14_545
Li2 Ce1 Li3 96.4(3) 1_655 14_545
Li2 Ce1 Li3 63.1(3) 2_655 14_545
Ge3* Ce1 Li3 0.0(6) 14_545 14_545
Ge2 Ce2 Ge2 90.49(3) . 1_655
Ge2 Ce2 Ge2 89.14(3) . 2
Ge2 Ce2 Ge2 173.51(4) 1_655 2
Ge2 Ce2 Ge2 173.51(4) . 2_655
Ge2 Ce2 Ge2 89.14(3) 1_655 2_655
Ge2 Ce2 Ge2 90.49(3) 2 2_655
Ge2 Ce2 Ge3 86.76(2) . .
Ge2 Ce2 Ge3 86.76(2) 1_655 .
Ge2 Ce2 Ge3 86.76(2) 2 .
Ge2 Ce2 Ge3 86.76(2) 2_655 .
Ge2 Ce2 Ge1 45.11(2) . .
Ge2 Ce2 Ge1 104.37(2) 1_655 .
Ge2 Ce2 Ge1 79.86(2) 2 .
Ge2 Ce2 Ge1 141.07(3) 2_655 .
Ge3 Ce2 Ge1 129.609(17) . .
Ge2 Ce2 Ge1 79.86(2) . 2
Ge2 Ce2 Ge1 141.07(3) 1_655 2
Ge2 Ce2 Ge1 45.11(2) 2 2
Ge2 Ce2 Ge1 104.37(2) 2_655 2
Ge3 Ce2 Ge1 129.610(17) . 2
Ge1 Ce2 Ge1 44.35(3) . 2
Ge2 Ce2 Ge1 104.37(2) . 1_655
Ge2 Ce2 Ge1 45.11(2) 1_655 1_655
Ge2 Ce2 Ge1 141.07(3) 2 1_655
Ge2 Ce2 Ge1 79.86(2) 2_655 1_655
Ge3 Ce2 Ge1 129.610(17) . 1_655
Ge1 Ce2 Ge1 84.38(3) . 1_655
Ge1 Ce2 Ge1 100.78(3) 2 1_655
Ge2 Ce2 Ge1 141.07(3) . 2_655
Ge2 Ce2 Ge1 79.86(2) 1_655 2_655
Ge2 Ce2 Ge1 104.37(2) 2 2_655
Ge2 Ce2 Ge1 45.11(2) 2_655 2_655
Ge3 Ce2 Ge1 129.610(17) . 2_655
Ge1 Ce2 Ge1 100.78(3) . 2_655
Ge1 Ce2 Ge1 84.38(3) 2 2_655
Ge1 Ce2 Ge1 44.35(3) 1_655 2_655
Ge2 Ce2 Li1 98.3(2) . 1_655
Ge2 Ce2 Li1 43.9(2) 1_655 1_655
Ge2 Ce2 Li1 129.8(2) 2 1_655
Ge2 Ce2 Li1 77.0(2) 2_655 1_655
Ge3 Ce2 Li1 44.7(2) . 1_655
Ge1 Ce2 Li1 136.8(2) . 1_655
Ge1 Ce2 Li1 174.27(19) 2 1_655
Ge1 Ce2 Li1 84.9(2) 1_655 1_655
Ge1 Ce2 Li1 100.26(16) 2_655 1_655
Ge2 Ce2 Li1 129.8(2) . 2_655
Ge2 Ce2 Li1 77.0(2) 1_655 2_655
Ge2 Ce2 Li1 98.3(2) 2 2_655
Ge2 Ce2 Li1 43.9(2) 2_655 2_655
Ge3 Ce2 Li1 44.7(2) . 2_655
Ge1 Ce2 Li1 174.27(19) . 2_655
Ge1 Ce2 Li1 136.8(2) 2 2_655
Ge1 Ce2 Li1 100.26(16) 1_655 2_655
Ge1 Ce2 Li1 84.9(2) 2_655 2_655
Li1 Ce2 Li1 41.4(5) 1_655 2_655
Ge2 Ce2 Li1 77.0(2) . 2
Ge2 Ce2 Li1 129.8(2) 1_655 2
Ge2 Ce2 Li1 43.9(2) 2 2
Ge2 Ce2 Li1 98.3(2) 2_655 2
Ge3 Ce2 Li1 44.7(2) . 2
Ge1 Ce2 Li1 100.26(16) . 2
Ge1 Ce2 Li1 84.9(2) 2 2
Ge1 Ce2 Li1 174.27(19) 1_655 2
Ge1 Ce2 Li1 136.8(2) 2_655 2
Li1 Ce2 Li1 89.4(4) 1_655 2
Li1 Ce2 Li1 74.9(3) 2_655 2
Li2 Ce3 Li2 48.6(6) 14_545 13
Li2 Ce3 Ge3* 64.0(3) 14_545 2
Li2 Ce3 Ge3* 97.1(3) 13 2
Li2 Ce3 Li3 64.0(3) 14_545 2
Li2 Ce3 Li3 97.1(3) 13 2
Ge3* Ce3 Li3 0.0(7) 2 2
Li2 Ce3 Ge3* 97.1(3) 14_545 1_655
Li2 Ce3 Ge3* 64.0(3) 13 1_655
Ge3* Ce3 Ge3* 160.2(5) 2 1_655
Li3 Ce3 Ge3* 160.2(5) 2 1_655
Li2 Ce3 Li3 97.1(3) 14_545 1_655
Li2 Ce3 Li3 64.0(3) 13 1_655
Ge3* Ce3 Li3 160.2(5) 2 1_655
Li3 Ce3 Li3 160.2(5) 2 1_655
Ge3* Ce3 Li3 0.0(7) 1_655 1_655
Li2 Ce3 Ge3* 64.0(3) 14_545 2_655
Li2 Ce3 Ge3* 97.1(3) 13 2_655
Ge3* Ce3 Ge3* 90.5(4) 2 2_655
Li3 Ce3 Ge3* 90.5(4) 2 2_655
Ge3* Ce3 Ge3* 86.1(4) 1_655 2_655
Li3 Ce3 Ge3* 86.1(4) 1_655 2_655
Li2 Ce3 Li3 64.0(3) 14_545 2_655
Li2 Ce3 Li3 97.1(3) 13 2_655
Ge3* Ce3 Li3 90.5(4) 2 2_655
Li3 Ce3 Li3 90.5(4) 2 2_655
Ge3* Ce3 Li3 86.1(4) 1_655 2_655
Li3 Ce3 Li3 86.1(4) 1_655 2_655
Ge3* Ce3 Li3 0.0(7) 2_655 2_655
Li2 Ce3 Li3 97.1(3) 14_545 .
Li2 Ce3 Li3 64.0(3) 13 .
Ge3* Ce3 Li3 86.1(4) 2 .
Li3 Ce3 Li3 86.1(4) 2 .
Ge3* Ce3 Li3 90.5(4) 1_655 .
Li3 Ce3 Li3 90.5(4) 1_655 .
Ge3* Ce3 Li3 160.2(5) 2_655 .
Li3 Ce3 Li3 160.2(5) 2_655 .
Li2 Ce3 Ge5 48.93(11) 14_545 .
Li2 Ce3 Ge5 48.93(12) 13 .
Ge3* Ce3 Ge5 52.0(3) 2 .
Li3 Ce3 Ge5 52.0(3) 2 .
Ge3* Ce3 Ge5 111.6(2) 1_655 .
Li3 Ce3 Ge5 111.6(2) 1_655 .
Ge3* Ce3 Ge5 111.6(2) 2_655 .
Li3 Ce3 Ge5 111.6(2) 2_655 .
Li3 Ce3 Ge5 52.0(3) . .
Li2 Ce3 Ge5 48.93(11) 14_545 1_655
Li2 Ce3 Ge5 48.93(11) 13 1_655
Ge3* Ce3 Ge5 111.6(2) 2 1_655
Li3 Ce3 Ge5 111.6(2) 2 1_655
Ge3* Ce3 Ge5 52.0(3) 1_655 1_655
Li3 Ce3 Ge5 52.0(3) 1_655 1_655
Ge3* Ce3 Ge5 52.0(3) 2_655 1_655
Li3 Ce3 Ge5 52.0(3) 2_655 1_655
Li3 Ce3 Ge5 111.6(2) . 1_655
Ge5 Ce3 Ge5 87.73(4) . 1_655
Li1 Ce4 Li1 49.1(6) . 2
Li1 Ce4 Ge2 111.6(2) . 13
Li1 Ce4 Ge2 134.23(5) 2 13
Li1 Ce4 Ge2 134.23(5) . 14_545
Li1 Ce4 Ge2 111.6(2) 2 14_545
Ge2 Ce4 Ge2 46.77(4) 13 14_545
Li1 Ce4 Ge2 134.23(5) . 14_445
Li1 Ce4 Ge2 111.6(2) 2 14_445
Ge2 Ce4 Ge2 108.31(4) 13 14_445
Ge2 Ce4 Ge2 89.95(3) 14_545 14_445
Li1 Ce4 Ge2 111.6(2) . 13_455
Li1 Ce4 Ge2 134.23(5) 2 13_455
Ge2 Ce4 Ge2 89.95(3) 13 13_455
Ge2 Ce4 Ge2 108.31(4) 14_545 13_455
Ge2 Ce4 Ge2 46.77(4) 14_445 13_455
Li1 Ce4 Li1 96.7(2) . 14_445
Li1 Ce4 Li1 63.2(4) 2 14_445
Ge2 Ce4 Li1 151.4(3) 13 14_445
Ge2 Ce4 Li1 109.6(3) 14_545 14_445
Ge2 Ce4 Li1 48.5(3) 14_445 14_445
Ge2 Ce4 Li1 83.1(2) 13_455 14_445
Li1 Ce4 Li1 63.2(4) . 13
Li1 Ce4 Li1 96.7(2) 2 13
Ge2 Ce4 Li1 48.5(3) 13 13
Ge2 Ce4 Li1 83.1(2) 14_545 13
Ge2 Ce4 Li1 151.4(3) 14_445 13
Ge2 Ce4 Li1 109.6(3) 13_455 13
Li1 Ce4 Li1 158.8(6) 14_445 13
Li1 Ce4 Li1 63.2(4) . 13_455
Li1 Ce4 Li1 96.7(2) 2 13_455
Ge2 Ce4 Li1 109.6(3) 13 13_455
Ge2 Ce4 Li1 151.4(3) 14_545 13_455
Ge2 Ce4 Li1 83.1(2) 14_445 13_455
Ge2 Ce4 Li1 48.5(3) 13_455 13_455
Li1 Ce4 Li1 86.3(5) 14_445 13_455
Li1 Ce4 Li1 89.8(4) 13 13_455
Li1 Ce4 Li1 96.7(2) . 14_545
Li1 Ce4 Li1 63.2(4) 2 14_545
Ge2 Ce4 Li1 83.1(2) 13 14_545
Ge2 Ce4 Li1 48.5(3) 14_545 14_545
Ge2 Ce4 Li1 109.6(3) 14_445 14_545
Ge2 Ce4 Li1 151.4(3) 13_455 14_545
Li1 Ce4 Li1 89.8(4) 14_445 14_545
Li1 Ce4 Li1 86.3(5) 13 14_545
Li1 Ce4 Li1 158.8(6) 13_455 14_545
Li1 Ce4 Ge3 49.46(12) . 1_455
Li1 Ce4 Ge3 49.46(12) 2 1_455
Ge2 Ce4 Ge3 155.91(2) 13 1_455
Ge2 Ce4 Ge3 155.91(2) 14_545 1_455
Ge2 Ce4 Ge3 85.64(2) 14_445 1_455
Ge2 Ce4 Ge3 85.64(2) 13_455 1_455
Li1 Ce4 Ge3 51.3(3) 14_445 1_455
Li1 Ce4 Ge3 111.2(3) 13 1_455
Li1 Ce4 Ge3 51.3(3) 13_455 1_455
Li1 Ce4 Ge3 111.2(3) 14_545 1_455
Li1 Ce4 Ge3 49.46(12) . .
Li1 Ce4 Ge3 49.46(12) 2 .
Ge2 Ce4 Ge3 85.64(2) 13 .
Ge2 Ce4 Ge3 85.64(2) 14_545 .
Ge2 Ce4 Ge3 155.91(2) 14_445 .
Ge2 Ce4 Ge3 155.91(2) 13_455 .
Li1 Ce4 Ge3 111.2(3) 14_445 .
Li1 Ce4 Ge3 51.3(3) 13 .
Li1 Ce4 Ge3 111.2(3) 13_455 .
Li1 Ce4 Ge3 51.3(3) 14_545 .
Ge3 Ce4 Ge3 88.79(4) 1_455 .
Ge1 Ce5 Ge1 173.78(4) 13 14_445
Ge1 Ce5 Ge1 89.13(3) 13 14_545
Ge1 Ce5 Ge1 90.53(3) 14_445 14_545
Ge1 Ce5 Ge1 90.53(3) 13 13_455
Ge1 Ce5 Ge1 89.13(3) 14_445 13_455
Ge1 Ce5 Ge1 173.78(4) 14_545 13_455
Ge1 Ce5 Ge5 86.89(2) 13 .
Ge1 Ce5 Ge5 86.89(2) 14_445 .
Ge1 Ce5 Ge5 86.89(2) 14_545 .
Ge1 Ce5 Ge5 86.89(2) 13_455 .
Ge1 Ce5 Ge2 140.85(3) 13 14_445
Ge1 Ce5 Ge2 45.08(2) 14_445 14_445
Ge1 Ce5 Ge2 104.29(2) 14_545 14_445
Ge1 Ce5 Ge2 79.78(2) 13_455 14_445
Ge5 Ce5 Ge2 129.711(16) . 14_445
Ge1 Ce5 Ge2 104.29(2) 13 13_455
Ge1 Ce5 Ge2 79.78(2) 14_445 13_455
Ge1 Ce5 Ge2 140.85(3) 14_545 13_455
Ge1 Ce5 Ge2 45.08(2) 13_455 13_455
Ge5 Ce5 Ge2 129.711(16) . 13_455
Ge2 Ce5 Ge2 44.26(3) 14_445 13_455
Ge1 Ce5 Ge2 45.08(2) 13 13
Ge1 Ce5 Ge2 140.85(3) 14_445 13
Ge1 Ce5 Ge2 79.78(2) 14_545 13
Ge1 Ce5 Ge2 104.29(2) 13_455 13
Ge5 Ce5 Ge2 129.711(16) . 13
Ge2 Ce5 Ge2 100.58(3) 14_445 13
Ge2 Ce5 Ge2 84.25(3) 13_455 13
Ge1 Ce5 Ge2 79.78(2) 13 14_545
Ge1 Ce5 Ge2 104.29(2) 14_445 14_545
Ge1 Ce5 Ge2 45.08(2) 14_545 14_545
Ge1 Ce5 Ge2 140.85(3) 13_455 14_545
Ge5 Ce5 Ge2 129.711(16) . 14_545
Ge2 Ce5 Ge2 84.25(3) 14_445 14_545
Ge2 Ce5 Ge2 100.58(3) 13_455 14_545
Ge2 Ce5 Ge2 44.26(3) 13 14_545
Ge1 Ce5 Li2 44.3(2) 13 13
Ge1 Ce5 Li2 129.7(2) 14_445 13
Ge1 Ce5 Li2 77.1(2) 14_545 13
Ge1 Ce5 Li2 98.40(19) 13_455 13
Ge5 Ce5 Li2 44.50(18) . 13
Ge2 Ce5 Li2 174.19(18) 14_445 13
Ge2 Ce5 Li2 136.9(2) 13_455 13
Ge2 Ce5 Li2 85.22(18) 13 13
Ge2 Ce5 Li2 100.42(14) 14_545 13
Ge1 Ce5 Li2 77.1(2) 13 14_545
Ge1 Ce5 Li2 98.40(19) 14_445 14_545
Ge1 Ce5 Li2 44.3(2) 14_545 14_545
Ge1 Ce5 Li2 129.7(2) 13_455 14_545
Ge5 Ce5 Li2 44.50(18) . 14_545
Ge2 Ce5 Li2 136.9(2) 14_445 14_545
Ge2 Ce5 Li2 174.19(17) 13_455 14_545
Ge2 Ce5 Li2 100.42(14) 13 14_545
Ge2 Ce5 Li2 85.22(18) 14_545 14_545
Li2 Ce5 Li2 41.1(5) 13 14_545
Ge1 Ce5 Li2 98.40(19) 13 13_455
Ge1 Ce5 Li2 77.1(2) 14_445 13_455
Ge1 Ce5 Li2 129.7(2) 14_545 13_455
Ge1 Ce5 Li2 44.3(2) 13_455 13_455
Ge5 Ce5 Li2 44.50(18) . 13_455
Ge2 Ce5 Li2 100.42(14) 14_445 13_455
Ge2 Ce5 Li2 85.22(18) 13_455 13_455
Ge2 Ce5 Li2 136.9(2) 13 13_455
Ge2 Ce5 Li2 174.19(17) 14_545 13_455
Li2 Ce5 Li2 74.7(3) 13 13_455
Li2 Ce5 Li2 89.0(4) 14_545 13_455
Ge6 Ce6 Ge6 180.00(4) 13 5_444
Ge6 Ce6 Ge6 91.07(4) 13 13_455
Ge6 Ce6 Ge6 88.93(4) 5_444 13_455
Ge6 Ce6 Ge6 88.93(4) 13 5_544
Ge6 Ce6 Ge6 91.07(4) 5_444 5_544
Ge6 Ce6 Ge6 180.0 13_455 5_544
Ge6 Ce6 Ge4 90.0 13 .
Ge6 Ce6 Ge4 90.0 5_444 .
Ge6 Ce6 Ge4 90.0 13_455 .
Ge6 Ce6 Ge4 90.0 5_544 .
Ge6 Ce6 Ge4 90.0 13 9
Ge6 Ce6 Ge4 90.0 5_444 9
Ge6 Ce6 Ge4 90.0 13_455 9
Ge6 Ce6 Ge4 90.0 5_544 9
Ge4 Ce6 Ge4 180.0 . 9
Ge6 Ce6 Li3 45.6(2) 13 13
Ge6 Ce6 Li3 134.4(2) 5_444 13
Ge6 Ce6 Li3 100.8(2) 13_455 13
Ge6 Ce6 Li3 79.2(2) 5_544 13
Ge4 Ce6 Li3 46.16(19) . 13
Ge4 Ce6 Li3 133.84(19) 9 13
Ge6 Ce6 Li3 134.4(2) 13 5_444
Ge6 Ce6 Li3 45.6(2) 5_444 5_444
Ge6 Ce6 Li3 79.2(2) 13_455 5_444
Ge6 Ce6 Li3 100.8(2) 5_544 5_444
Ge4 Ce6 Li3 133.84(19) . 5_444
Ge4 Ce6 Li3 46.16(19) 9 5_444
Li3 Ce6 Li3 180.0(3) 13 5_444
Ge6 Ce6 Li3 79.2(2) 13 14_545
Ge6 Ce6 Li3 100.8(2) 5_444 14_545
Ge6 Ce6 Li3 134.4(2) 13_455 14_545
Ge6 Ce6 Li3 45.6(2) 5_544 14_545
Ge4 Ce6 Li3 46.16(19) . 14_545
Ge4 Ce6 Li3 133.84(19) 9 14_545
Li3 Ce6 Li3 42.9(5) 13 14_545
Li3 Ce6 Li3 137.1(5) 5_444 14_545
Ge6 Ce6 Li3 100.8(2) 13 6_454
Ge6 Ce6 Li3 79.2(2) 5_444 6_454
Ge6 Ce6 Li3 45.6(2) 13_455 6_454
Ge6 Ce6 Li3 134.4(2) 5_544 6_454
Ge4 Ce6 Li3 133.84(19) . 6_454
Ge4 Ce6 Li3 46.16(19) 9 6_454
Li3 Ce6 Li3 137.1(5) 13 6_454
Li3 Ce6 Li3 42.9(5) 5_444 6_454
Li3 Ce6 Li3 180.0(3) 14_545 6_454
Ge6 Ce6 Li3 134.4(2) 13 14_445
Ge6 Ce6 Li3 45.6(2) 5_444 14_445
Ge6 Ce6 Li3 79.2(2) 13_455 14_445
Ge6 Ce6 Li3 100.8(2) 5_544 14_445
Ge4 Ce6 Li3 46.16(19) . 14_445
Ge4 Ce6 Li3 133.84(19) 9 14_445
Li3 Ce6 Li3 92.3(4) 13 14_445
Li3 Ce6 Li3 87.7(4) 5_444 14_445
Li3 Ce6 Li3 76.9(3) 14_545 14_445
Li3 Ce6 Li3 103.1(3) 6_454 14_445
Ge6 Ce6 Li3 45.6(2) 13 6_554
Ge6 Ce6 Li3 134.4(2) 5_444 6_554
Ge6 Ce6 Li3 100.8(2) 13_455 6_554
Ge6 Ce6 Li3 79.2(2) 5_544 6_554
Ge4 Ce6 Li3 133.84(19) . 6_554
Ge4 Ce6 Li3 46.16(19) 9 6_554
Li3 Ce6 Li3 87.7(4) 13 6_554
Li3 Ce6 Li3 92.3(4) 5_444 6_554
Li3 Ce6 Li3 103.1(3) 14_545 6_554
Li3 Ce6 Li3 76.9(3) 6_454 6_554
Li3 Ce6 Li3 180.0(3) 14_445 6_554
Ge2 Ge1 Ge1 112.51(3) . 2
Ge2 Ge1 Li2 137.1(3) . .
Ge1 Ge1 Li2 110.4(3) 2 .
Ge2 Ge1 Ce5 71.42(3) . 13
Ge1 Ge1 Ce5 134.568(13) 2 13
Li2 Ge1 Ce5 78.8(2) . 13
Ge2 Ge1 Ce5 71.42(3) . 13_455
Ge1 Ge1 Ce5 134.568(13) 2 13_455
Li2 Ge1 Ce5 78.8(2) . 13_455
Ce5 Ge1 Ce5 90.53(3) 13 13_455
Ge2 Ge1 Ce1 134.027(18) . 1_455
Ge1 Ge1 Ce1 66.657(17) 2 1_455
Li2 Ge1 Ce1 65.6(2) . 1_455
Ce5 Ge1 Ce1 144.17(4) 13 1_455
Ce5 Ge1 Ce1 78.995(13) 13_455 1_455
Ge2 Ge1 Ce1 134.028(18) . .
Ge1 Ge1 Ce1 66.657(17) 2 .
Li2 Ge1 Ce1 65.6(2) . .
Ce5 Ge1 Ce1 78.995(13) 13 .
Ce5 Ge1 Ce1 144.17(4) 13_455 .
Ce1 Ge1 Ce1 89.67(3) 1_455 .
Ge2 Ge1 Ce2 63.61(3) . .
Ge1 Ge1 Ce2 67.826(17) 2 .
Li2 Ge1 Ce2 136.82(7) . .
Ce5 Ge1 Ce2 75.711(14) 13 .
Ce5 Ge1 Ce2 135.02(4) 13_455 .
Ce1 Ge1 Ce2 134.34(3) 1_455 .
Ce1 Ge1 Ce2 75.635(19) . .
Ge2 Ge1 Ce2 63.60(3) . 1_455
Ge1 Ge1 Ce2 67.827(17) 2 1_455
Li2 Ge1 Ce2 136.82(7) . 1_455
Ce5 Ge1 Ce2 135.02(4) 13 1_455
Ce5 Ge1 Ce2 75.712(14) 13_455 1_455
Ce1 Ge1 Ce2 75.635(18) 1_455 1_455
Ce1 Ge1 Ce2 134.34(3) . 1_455
Ce2 Ge1 Ce2 84.38(3) . 1_455
Ge1 Ge2 Ge2 112.51(3) . 2_565
Ge1 Ge2 Li1 137.0(4) . .
Ge2 Ge2 Li1 110.5(4) 2_565 .
Ge1 Ge2 Ce2 71.29(3) . 1_455
Ge2 Ge2 Ce2 134.571(13) 2_565 1_455
Li1 Ge2 Ce2 78.9(3) . 1_455
Ge1 Ge2 Ce2 71.29(3) . .
Ge2 Ge2 Ce2 134.571(14) 2_565 .
Li1 Ge2 Ce2 78.9(3) . .
Ce2 Ge2 Ce2 90.49(3) 1_455 .
Ge1 Ge2 Ce4 133.864(17) . 13
Ge2 Ge2 Ce4 66.612(18) 2_565 13
Li1 Ge2 Ce4 65.8(2) . 13
Ce2 Ge2 Ce4 144.44(4) 1_455 13
Ce2 Ge2 Ce4 79.034(13) . 13
Ge1 Ge2 Ce4 133.864(17) . 13_455
Ge2 Ge2 Ce4 66.612(17) 2_565 13_455
Li1 Ge2 Ce4 65.8(2) . 13_455
Ce2 Ge2 Ce4 79.032(13) 1_455 13_455
Ce2 Ge2 Ce4 144.45(4) . 13_455
Ce4 Ge2 Ce4 89.94(3) 13 13_455
Ge1 Ge2 Ce5 63.51(2) . 13_455
Ge2 Ge2 Ce5 67.874(17) 2_565 13_455
Li1 Ge2 Ce5 136.92(7) . 13_455
Ce2 Ge2 Ce5 75.638(14) 1_455 13_455
Ce2 Ge2 Ce5 134.79(3) . 13_455
Ce4 Ge2 Ce5 134.32(3) 13 13_455
Ce4 Ge2 Ce5 75.557(19) 13_455 13_455
Ge1 Ge2 Ce5 63.51(2) . 13
Ge2 Ge2 Ce5 67.874(17) 2_565 13
Li1 Ge2 Ce5 136.92(7) . 13
Ce2 Ge2 Ce5 134.80(3) 1_455 13
Ce2 Ge2 Ce5 75.636(14) . 13
Ce4 Ge2 Ce5 75.557(19) 13 13
Ce4 Ge2 Ce5 134.32(3) 13_455 13
Ce5 Ge2 Ce5 84.25(3) 13_455 13
Li1 Ge3 Li1 58.8(6) . 2
Li1 Ge3 Li1 115.4(6) . 1_655
Li1 Ge3 Li1 155.5(7) 2 1_655
Li1 Ge3 Li1 155.5(7) . 2_655
Li1 Ge3 Li1 115.4(6) 2 2_655
Li1 Ge3 Li1 58.8(6) 1_655 2_655
Li1 Ge3 Li1 75.2(4) . 13
Li1 Ge3 Li1 121.1(3) 2 13
Li1 Ge3 Li1 75.2(4) 1_655 13
Li1 Ge3 Li1 121.1(3) 2_655 13
Li1 Ge3 Li1 121.1(3) . 14_545
Li1 Ge3 Li1 75.2(4) 2 14_545
Li1 Ge3 Li1 121.1(3) 1_655 14_545
Li1 Ge3 Li1 75.2(4) 2_655 14_545
Li1 Ge3 Li1 103.8(7) 13 14_545
Li1 Ge3 Ce2 77.8(3) . .
Li1 Ge3 Ce2 77.8(3) 2 .
Li1 Ge3 Ce2 77.8(3) 1_655 .
Li1 Ge3 Ce2 77.8(3) 2_655 .
Li1 Ge3 Ce2 128.1(3) 13 .
Li1 Ge3 Ce2 128.1(3) 14_545 .
Li1 Ge3 Ce4 63.9(3) . .
Li1 Ge3 Ce4 63.9(3) 2 .
Li1 Ge3 Ce4 138.0(4) 1_655 .
Li1 Ge3 Ce4 138.0(4) 2_655 .
Li1 Ge3 Ce4 63.8(2) 13 .
Li1 Ge3 Ce4 63.8(2) 14_545 .
Ce2 Ge3 Ce4 135.604(19) . .
Li1 Ge3 Ce4 138.0(4) . 1_655
Li1 Ge3 Ce4 138.0(4) 2 1_655
Li1 Ge3 Ce4 63.9(3) 1_655 1_655
Li1 Ge3 Ce4 63.9(3) 2_655 1_655
Li1 Ge3 Ce4 63.8(2) 13 1_655
Li1 Ge3 Ce4 63.8(2) 14_545 1_655
Ce2 Ge3 Ce4 135.605(19) . 1_655
Ce4 Ge3 Ce4 88.79(4) . 1_655
Ge3* Ge4 Li3 0.0(9) 14_445 14_445
Ge3* Ge4 Ge3* 150.9(6) 14_445 13
Li3 Ge4 Ge3* 150.9(6) 14_445 13
Ge3* Ge4 Li3 150.9(6) 14_445 13
Li3 Ge4 Li3 150.9(6) 14_445 13
Ge3* Ge4 Li3 0.0(9) 13 13
Ge3* Ge4 Ge3* 58.8(6) 14_445 13_455
Li3 Ge4 Ge3* 58.8(6) 14_445 13_455
Ge3* Ge4 Ge3* 113.1(6) 13 13_455
Li3 Ge4 Ge3* 113.1(6) 13 13_455
Ge3* Ge4 Li3 58.8(6) 14_445 13_455
Li3 Ge4 Li3 58.8(6) 14_445 13_455
Ge3* Ge4 Li3 113.1(6) 13 13_455
Li3 Ge4 Li3 113.1(6) 13 13_455
Ge3* Ge4 Li3 0.0(6) 13_455 13_455
Ge3* Ge4 Ge3* 113.1(6) 14_445 14_545
Li3 Ge4 Ge3* 113.1(6) 14_445 14_545
Ge3* Ge4 Ge3* 58.8(6) 13 14_545
Li3 Ge4 Ge3* 58.8(6) 13 14_545
Ge3* Ge4 Ge3* 150.9(6) 13_455 14_545
Li3 Ge4 Ge3* 150.9(6) 13_455 14_545
Ge3* Ge4 Li3 113.1(6) 14_445 14_545
Li3 Ge4 Li3 113.1(6) 14_445 14_545
Ge3* Ge4 Li3 58.8(6) 13 14_545
Li3 Ge4 Li3 58.8(6) 13 14_545
Ge3* Ge4 Li3 150.9(6) 13_455 14_545
Li3 Ge4 Li3 150.9(6) 13_455 14_545
Ge3* Ge4 Li3 0.0(9) 14_545 14_545
Ge3* Ge4 Li2 76.1(4) 14_445 2
Li3 Ge4 Li2 76.1(4) 14_445 2
Ge3* Ge4 Li2 122.9(3) 13 2
Li3 Ge4 Li2 122.9(3) 13 2
Ge3* Ge4 Li2 122.9(3) 13_455 2
Li3 Ge4 Li2 122.9(3) 13_455 2
Ge3* Ge4 Li2 76.1(4) 14_545 2
Li3 Ge4 Li2 76.1(4) 14_545 2
Ge3* Ge4 Li2 122.9(3) 14_445 .
Li3 Ge4 Li2 122.9(3) 14_445 .
Ge3* Ge4 Li2 76.1(4) 13 .
Li3 Ge4 Li2 76.1(4) 13 .
Ge3* Ge4 Li2 76.1(4) 13_455 .
Li3 Ge4 Li2 76.1(4) 13_455 .
Ge3* Ge4 Li2 122.9(3) 14_545 .
Li3 Ge4 Li2 122.9(3) 14_545 .
Li2 Ge4 Li2 105.7(6) 2 .
Ge3* Ge4 Ce6 75.5(3) 14_445 .
Li3 Ge4 Ce6 75.5(3) 14_445 .
Ge3* Ge4 Ce6 75.5(3) 13 .
Li3 Ge4 Ce6 75.5(3) 13 .
Ge3* Ge4 Ce6 75.5(3) 13_455 .
Li3 Ge4 Ce6 75.5(3) 13_455 .
Ge3* Ge4 Ce6 75.5(3) 14_545 .
Li3 Ge4 Ce6 75.5(3) 14_545 .
Li2 Ge4 Ce6 127.2(3) 2 .
Li2 Ge4 Ce6 127.2(3) . .
Ge3* Ge4 Ce1 140.1(3) 14_445 .
Li3 Ge4 Ce1 140.1(3) 14_445 .
Ge3* Ge4 Ce1 65.7(3) 13 .
Li3 Ge4 Ce1 65.7(3) 13 .
Ge3* Ge4 Ce1 140.1(3) 13_455 .
Li3 Ge4 Ce1 140.1(3) 13_455 .
Ge3* Ge4 Ce1 65.7(3) 14_545 .
Li3 Ge4 Ce1 65.7(3) 14_545 .
Li2 Ge4 Ce1 64.7(2) 2 .
Li2 Ge4 Ce1 64.7(2) . .
Ce6 Ge4 Ce1 135.035(19) . .
Li2 Ge5 Li2 156.6(6) 14_445 13
Li2 Ge5 Li2 58.7(6) 14_445 13_455
Li2 Ge5 Li2 115.9(6) 13 13_455
Li2 Ge5 Li2 115.9(6) 14_445 14_545
Li2 Ge5 Li2 58.7(6) 13 14_545
Li2 Ge5 Li2 156.6(6) 13_455 14_545
Li2 Ge5 Li3 120.4(3) 14_445 .
Li2 Ge5 Li3 75.6(4) 13 .
Li2 Ge5 Li3 75.6(4) 13_455 .
Li2 Ge5 Li3 120.4(3) 14_545 .
Li2 Ge5 Ge3* 75.6(4) 14_445 2
Li2 Ge5 Ge3* 120.4(3) 13 2
Li2 Ge5 Ge3* 120.4(3) 13_455 2
Li2 Ge5 Ge3* 75.6(4) 14_545 2
Li3 Ge5 Ge3* 100.6(6) . 2
Li2 Ge5 Li3 75.6(4) 14_445 2
Li2 Ge5 Li3 120.4(3) 13 2
Li2 Ge5 Li3 120.4(3) 13_455 2
Li2 Ge5 Li3 75.6(4) 14_545 2
Li3 Ge5 Li3 100.6(6) . 2
Ge3* Ge5 Li3 0.0(6) 2 2
Li2 Ge5 Ce5 78.3(3) 14_445 .
Li2 Ge5 Ce5 78.3(3) 13 .
Li2 Ge5 Ce5 78.3(3) 13_455 .
Li2 Ge5 Ce5 78.3(3) 14_545 .
Li3 Ge5 Ce5 129.7(3) . .
Ge3* Ge5 Ce5 129.7(3) 2 .
Li3 Ge5 Ce5 129.7(3) 2 .
Li2 Ge5 Ce3 137.2(3) 14_445 .
Li2 Ge5 Ce3 63.8(3) 13 .
Li2 Ge5 Ce3 137.2(3) 13_455 .
Li2 Ge5 Ce3 63.8(3) 14_545 .
Li3 Ge5 Ce3 62.6(2) . .
Ge3* Ge5 Ce3 62.6(2) 2 .
Li3 Ge5 Ce3 62.6(2) 2 .
Ce5 Ge5 Ce3 136.134(19) . .
Li2 Ge5 Ce3 63.8(3) 14_445 1_455
Li2 Ge5 Ce3 137.2(3) 13 1_455
Li2 Ge5 Ce3 63.8(3) 13_455 1_455
Li2 Ge5 Ce3 137.2(3) 14_545 1_455
Li3 Ge5 Ce3 62.6(2) . 1_455
Ge3* Ge5 Ce3 62.6(2) 2 1_455
Li3 Ge5 Ce3 62.6(2) 2 1_455
Ce5 Ge5 Ce3 136.135(19) . 1_455
Ce3 Ge5 Ce3 87.73(4) . 1_455
Ge6 Ge6 Ge3* 109.5(3) 9_556 10_556
Ge6 Ge6 Li3 109.5(3) 9_556 10_556
Ge3* Ge6 Li3 0.0(7) 10_556 10_556
Ge6 Ge6 Li3 109.5(3) 9_556 .
Ge3* Ge6 Li3 141.1(7) 10_556 .
Li3 Ge6 Li3 141.1(7) 10_556 .
Ge6 Ge6 Ce6 134.467(18) 9_556 5
Ge3* Ge6 Ce6 76.5(2) 10_556 5
Li3 Ge6 Ce6 76.5(2) 10_556 5
Li3 Ge6 Ce6 76.5(2) . 5
Ge6 Ge6 Ce6 134.467(19) 9_556 5_455
Ge3* Ge6 Ce6 76.5(2) 10_556 5_455
Li3 Ge6 Ce6 76.5(2) 10_556 5_455
Li3 Ge6 Ce6 76.5(2) . 5_455
Ce6 Ge6 Ce6 91.07(4) 5 5_455
Ge6 Ge6 Ce3 66.81(2) 9_556 1_455
Ge3* Ge6 Ce3 134.48(9) 10_556 1_455
Li3 Ge6 Ce3 134.48(9) 10_556 1_455
Li3 Ge6 Ce3 64.0(2) . 1_455
Ce6 Ge6 Ce3 140.39(2) 5 1_455
Ce6 Ge6 Ce3 77.369(8) 5_455 1_455
Ge6 Ge6 Ce3 66.81(2) 9_556 9_656
Ge3* Ge6 Ce3 64.0(2) 10_556 9_656
Li3 Ge6 Ce3 64.0(2) 10_556 9_656
Li3 Ge6 Ce3 134.48(9) . 9_656
Ce6 Ge6 Ce3 77.369(8) 5 9_656
Ce6 Ge6 Ce3 140.39(2) 5_455 9_656
Ce3 Ge6 Ce3 133.62(5) 1_455 9_656
Ge6 Ge6 Ce3 66.81(2) 9_556 9_556
Ge3* Ge6 Ce3 64.0(2) 10_556 9_556
Li3 Ge6 Ce3 64.0(2) 10_556 9_556
Li3 Ge6 Ce3 134.48(9) . 9_556
Ce6 Ge6 Ce3 140.39(2) 5 9_556
Ce6 Ge6 Ce3 77.369(8) 5_455 9_556
Ce3 Ge6 Ce3 74.31(3) 1_455 9_556
Ce3 Ge6 Ce3 87.73(2) 9_656 9_556
Ge6 Ge6 Ce3 66.81(2) 9_556 .
Ge3* Ge6 Ce3 134.48(9) 10_556 .
Li3 Ge6 Ce3 134.48(9) 10_556 .
Li3 Ge6 Ce3 64.0(2) . .
Ce6 Ge6 Ce3 77.369(8) 5 .
Ce6 Ge6 Ce3 140.39(2) 5_455 .
Ce3 Ge6 Ce3 87.73(2) 1_455 .
Ce3 Ge6 Ce3 74.31(3) 9_656 .
Ce3 Ge6 Ce3 133.62(5) 9_556 .
Li1 Li1 Ge2 110.5(4) 2 .
Li1 Li1 Ge3 60.6(3) 2 .
Ge2 Li1 Ge3 111.8(4) . .
Li1 Li1 Ge3 60.6(3) 2 1_455
Ge2 Li1 Ge3 111.8(4) . 1_455
Ge3 Li1 Ge3 115.4(6) . 1_455
Li1 Li1 Ge3 141.9(3) 2 13
Ge2 Li1 Ge3 107.6(6) . 13
Ge3 Li1 Ge3 104.8(4) . 13
Ge3 Li1 Ge3 104.8(4) 1_455 13
Li1 Li1 Ce4 65.5(3) 2 .
Ge2 Li1 Ce4 176.0(7) . .
Ge3 Li1 Ce4 66.6(3) . .
Ge3 Li1 Ce4 66.6(3) 1_455 .
Ge3 Li1 Ce4 76.4(4) 13 .
Li1 Li1 Ce4 133.2(2) 2 13
Ge2 Li1 Ce4 65.7(3) . 13
Ge3 Li1 Ce4 77.19(10) . 13
Ge3 Li1 Ce4 166.2(5) 1_455 13
Ge3 Li1 Ce4 64.9(3) 13 13
Ce4 Li1 Ce4 116.8(4) . 13
Li1 Li1 Ce4 133.2(2) 2 13_455
Ge2 Li1 Ce4 65.7(3) . 13_455
Ge3 Li1 Ce4 166.2(5) . 13_455
Ge3 Li1 Ce4 77.19(10) 1_455 13_455
Ge3 Li1 Ce4 64.9(3) 13 13_455
Ce4 Li1 Ce4 116.8(4) . 13_455
Ce4 Li1 Ce4 89.8(4) 13 13_455
Li1 Li1 Li1 105.3(6) 2 13
Ge2 Li1 Li1 123.4(6) . 13
Ge3 Li1 Li1 53.9(2) . 13
Ge3 Li1 Li1 123.8(8) 1_455 13
Ge3 Li1 Li1 50.9(4) 13 13
Ce4 Li1 Li1 59.0(5) . 13
Ce4 Li1 Li1 57.8(4) 13 13
Ce4 Li1 Li1 115.1(7) 13_455 13
Li1 Li1 Li1 105.3(6) 2 13_455
Ge2 Li1 Li1 123.4(6) . 13_455
Ge3 Li1 Li1 123.8(8) . 13_455
Ge3 Li1 Li1 53.9(2) 1_455 13_455
Ge3 Li1 Li1 50.9(4) 13 13_455
Ce4 Li1 Li1 59.0(5) . 13_455
Ce4 Li1 Li1 115.1(7) 13 13_455
Ce4 Li1 Li1 57.8(4) 13_455 13_455
Li1 Li1 Li1 85.4(8) 13 13_455
Li1 Li1 Ce2 69.3(3) 2 1_455
Ge2 Li1 Ce2 57.2(3) . 1_455
Ge3 Li1 Ce2 119.4(5) . 1_455
Ge3 Li1 Ce2 57.6(2) 1_455 1_455
Ge3 Li1 Ce2 135.8(3) 13 1_455
Ce4 Li1 Ce2 120.0(4) . 1_455
Ce4 Li1 Ce2 122.7(5) 13 1_455
Ce4 Li1 Ce2 71.43(19) 13_455 1_455
Li1 Li1 Ce2 173.3(7) 13 1_455
Li1 Li1 Ce2 99.7(2) 13_455 1_455
Li1 Li1 Ce2 69.3(3) 2 .
Ge2 Li1 Ce2 57.2(3) . .
Ge3 Li1 Ce2 57.6(2) . .
Ge3 Li1 Ce2 119.4(5) 1_455 .
Ge3 Li1 Ce2 135.8(3) 13 .
Ce4 Li1 Ce2 120.0(4) . .
Ce4 Li1 Ce2 71.43(19) 13 .
Ce4 Li1 Ce2 122.7(5) 13_455 .
Li1 Li1 Ce2 99.7(2) 13 .
Li1 Li1 Ce2 173.3(7) 13_455 .
Ce2 Li1 Ce2 74.9(3) 1_455 .
Li2 Li2 Ge1 110.4(3) 2_565 .
Li2 Li2 Ge5 60.6(3) 2_565 13
Ge1 Li2 Ge5 111.2(3) . 13
Li2 Li2 Ge5 60.6(3) 2_565 13_455
Ge1 Li2 Ge5 111.2(3) . 13_455
Ge5 Li2 Ge5 115.9(6) 13 13_455
Li2 Li2 Ge4 142.8(3) 2_565 .
Ge1 Li2 Ge4 106.7(5) . .
Ge5 Li2 Ge4 105.6(4) 13 .
Ge5 Li2 Ge4 105.6(4) 13_455 .
Li2 Li2 Ce3 65.7(3) 2_565 13
Ge1 Li2 Ce3 176.1(6) . 13
Ge5 Li2 Ce3 67.3(3) 13 13
Ge5 Li2 Ce3 67.3(3) 13_455 13
Ge4 Li2 Ce3 77.2(4) . 13
Li2 Li2 Ce1 133.2(2) 2_565 .
Ge1 Li2 Ce1 65.5(3) . .
Ge5 Li2 Ce1 77.06(9) 13 .
Ge5 Li2 Ce1 166.1(5) 13_455 .
Ge4 Li2 Ce1 64.3(3) . .
Ce3 Li2 Ce1 116.9(3) 13 .
Li2 Li2 Ce1 133.2(2) 2_565 1_455
Ge1 Li2 Ce1 65.5(3) . 1_455
Ge5 Li2 Ce1 166.1(5) 13 1_455
Ge5 Li2 Ce1 77.06(9) 13_455 1_455
Ge4 Li2 Ce1 64.3(3) . 1_455
Ce3 Li2 Ce1 116.9(3) 13 1_455
Ce1 Li2 Ce1 89.6(4) . 1_455
Li2 Li2 Li3 104.9(4) 2_565 13_455
Ge1 Li2 Li3 124.2(4) . 13_455
Ge5 Li2 Li3 123.6(6) 13 13_455
Ge5 Li2 Li3 54.3(3) 13_455 13_455
Ge4 Li2 Li3 51.3(3) . 13_455
Ce3 Li2 Li3 58.1(3) 13 13_455
Ce1 Li2 Li3 115.2(5) . 13_455
Ce1 Li2 Li3 58.7(3) 1_455 13_455
Li2 Li2 Li3 104.9(4) 2_565 13
Ge1 Li2 Li3 124.2(4) . 13
Ge5 Li2 Li3 54.3(3) 13 13
Ge5 Li2 Li3 123.6(6) 13_455 13
Ge4 Li2 Li3 51.3(3) . 13
Ce3 Li2 Li3 58.1(3) 13 13
Ce1 Li2 Li3 58.7(3) . 13
Ce1 Li2 Li3 115.2(5) 1_455 13
Li3 Li2 Li3 84.2(5) 13_455 13
Li2 Li2 Ce5 69.5(2) 2_565 13
Ge1 Li2 Ce5 56.9(2) . 13
Ge5 Li2 Ce5 57.2(2) 13 13
Ge5 Li2 Ce5 119.1(5) 13_455 13
Ge4 Li2 Ce5 135.3(3) . 13
Ce3 Li2 Ce5 120.4(4) 13 13
Ce1 Li2 Ce5 71.31(17) . 13
Ce1 Li2 Ce5 122.3(4) 1_455 13
Li3 Li2 Ce5 173.4(5) 13_455 13
Li3 Li2 Ce5 100.34(18) 13 13
Li2 Li2 Ce5 69.5(2) 2_565 13_455
Ge1 Li2 Ce5 56.9(2) . 13_455
Ge5 Li2 Ce5 119.1(5) 13 13_455
Ge5 Li2 Ce5 57.2(2) 13_455 13_455
Ge4 Li2 Ce5 135.3(3) . 13_455
Ce3 Li2 Ce5 120.4(4) 13 13_455
Ce1 Li2 Ce5 122.3(4) . 13_455
Ce1 Li2 Ce5 71.31(17) 1_455 13_455
Li3 Li2 Ce5 100.34(18) 13_455 13_455
Li3 Li2 Ce5 173.4(5) 13 13_455
Ce5 Li2 Ce5 74.7(3) 13 13_455
Ge3* Li3 Li3 0.0(7) 2_565 2_565
Ge3* Li3 Ge6 109.5(3) 2_565 .
Li3 Li3 Ge6 109.5(3) 2_565 .
Ge3* Li3 Ge4 60.6(3) 2_565 13
Li3 Li3 Ge4 60.6(3) 2_565 13
Ge6 Li3 Ge4 113.6(4) . 13
Ge3* Li3 Ge4 60.6(3) 2_565 13_455
Li3 Li3 Ge4 60.6(3) 2_565 13_455
Ge6 Li3 Ge4 113.6(4) . 13_455
Ge4 Li3 Ge4 113.1(6) 13 13_455
Ge3* Li3 Ge5 140.3(3) 2_565 .
Li3 Li3 Ge5 140.3(3) 2_565 .
Ge6 Li3 Ge5 110.2(5) . .
Ge4 Li3 Ge5 102.6(4) 13 .
Ge4 Li3 Ge5 102.6(4) 13_455 .
Ge3* Li3 Ce3 133.1(2) 2_565 .
Li3 Li3 Ce3 133.1(2) 2_565 .
Ge6 Li3 Ce3 67.1(3) . .
Ge4 Li3 Ce3 77.63(9) 13 .
Ge4 Li3 Ce3 166.1(5) 13_455 .
Ge5 Li3 Ce3 65.4(3) . .
Ge3* Li3 Ce3 133.1(2) 2_565 1_455
Li3 Li3 Ce3 133.1(2) 2_565 1_455
Ge6 Li3 Ce3 67.1(3) . 1_455
Ge4 Li3 Ce3 166.1(5) 13 1_455
Ge4 Li3 Ce3 77.63(9) 13_455 1_455
Ge5 Li3 Ce3 65.4(3) . 1_455
Ce3 Li3 Ce3 90.5(4) . 1_455
Ge3* Li3 Ce1 65.7(3) 2_565 13
Li3 Li3 Ce1 65.7(3) 2_565 13
Ge6 Li3 Ce1 175.2(6) . 13
Ge4 Li3 Ce1 64.5(3) 13 13
Ge4 Li3 Ce1 64.5(3) 13_455 13
Ge5 Li3 Ce1 74.6(4) . 13
Ce3 Li3 Ce1 116.0(3) . 13
Ce3 Li3 Ce1 116.0(3) 1_455 13
Ge3* Li3 Li2 104.9(4) 2_565 13_455
Li3 Li3 Li2 104.9(4) 2_565 13_455
Ge6 Li3 Li2 124.8(4) . 13_455
Ge4 Li3 Li2 120.8(6) 13 13_455
Ge4 Li3 Li2 52.6(3) 13_455 13_455
Ge5 Li3 Li2 50.0(3) . 13_455
Ce3 Li3 Li2 114.8(5) . 13_455
Ce3 Li3 Li2 57.8(3) 1_455 13_455
Ce1 Li3 Li2 58.1(3) 13 13_455
Ge3* Li3 Li2 104.9(4) 2_565 13
Li3 Li3 Li2 104.9(4) 2_565 13
Ge6 Li3 Li2 124.8(4) . 13
Ge4 Li3 Li2 52.6(3) 13 13
Ge4 Li3 Li2 120.8(6) 13_455 13
Ge5 Li3 Li2 50.0(3) . 13
Ce3 Li3 Li2 57.8(3) . 13
Ce3 Li3 Li2 114.8(5) 1_455 13
Ce1 Li3 Li2 58.1(3) 13 13
Li2 Li3 Li2 84.3(5) 13_455 13
Ge3* Li3 Ce6 68.6(2) 2_565 5
Li3 Li3 Ce6 68.6(2) 2_565 5
Ge6 Li3 Ce6 57.9(2) . 5
Ge4 Li3 Ce6 58.4(2) 13 5
Ge4 Li3 Ce6 120.9(5) 13_455 5
Ge5 Li3 Ce6 136.4(3) . 5
Ce3 Li3 Ce6 71.88(18) . 5
Ce3 Li3 Ce6 124.9(5) 1_455 5
Ce1 Li3 Ce6 118.7(4) 13 5
Li2 Li3 Ce6 173.2(5) 13_455 5
Li2 Li3 Ce6 99.14(18) 13 5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 Ge4 3.1612(11) 1_655
Ce1 Ge4 3.1613(11) .
Ce1 Ge1 3.1686(8) 1_655
Ce1 Ge1 3.1686(8) 2_655
Ce1 Ge1 3.1686(8) 2
Ce1 Ge1 3.1686(8) .
Ce1 Li2 3.171(11) .
Ce1 Li2 3.171(11) 2
Ce1 Li2 3.171(11) 1_655
Ce1 Li2 3.171(11) 2_655
Ce1 Ge3* 3.191(15) 14_545
Ce1 Li3 3.191(15) 14_545
Ce2 Ge2 3.1460(7) .
Ce2 Ge2 3.1460(7) 1_655
Ce2 Ge2 3.1460(7) 2
Ce2 Ge2 3.1460(7) 2_655
Ce2 Ge3 3.1723(15) .
Ce2 Ge1 3.3263(9) .
Ce2 Ge1 3.3264(9) 2
Ce2 Ge1 3.3264(9) 1_655
Ce2 Ge1 3.3264(9) 2_655
Ce2 Li1 3.673(13) 1_655
Ce2 Li1 3.673(13) 2_655
Ce2 Li1 3.673(13) 2
Ce3 Li2 3.136(15) 14_545
Ce3 Li2 3.136(15) 13
Ce3 Ge3* 3.147(11) 2
Ce3 Li3 3.147(11) 2
Ce3 Ge3* 3.147(11) 1_655
Ce3 Li3 3.147(11) 1_655
Ce3 Ge3* 3.147(11) 2_655
Ce3 Li3 3.147(11) 2_655
Ce3 Li3 3.147(11) .
Ce3 Ge5 3.2239(11) .
Ce3 Ge5 3.2239(11) 1_655
Ce4 Li1 3.125(16) .
Ce4 Li1 3.125(16) 2
Ce4 Ge2 3.1609(8) 13
Ce4 Ge2 3.1609(8) 14_545
Ce4 Ge2 3.1609(8) 14_445
Ce4 Ge2 3.1609(8) 13_455
Ce4 Li1 3.165(12) 14_445
Ce4 Li1 3.165(12) 13
Ce4 Li1 3.165(12) 13_455
Ce4 Li1 3.165(12) 14_545
Ce4 Ge3 3.1932(11) 1_455
Ce4 Ge3 3.1933(11) .
Ce5 Ge1 3.1450(7) 13
Ce5 Ge1 3.1450(7) 14_445
Ce5 Ge1 3.1450(7) 14_545
Ce5 Ge1 3.1450(7) 13_455
Ce5 Ge5 3.1600(16) .
Ce5 Ge2 3.3307(8) 14_445
Ce5 Ge2 3.3307(8) 13_455
Ce5 Ge2 3.3307(8) 13
Ce5 Ge2 3.3307(8) 14_545
Ce5 Li2 3.682(12) 13
Ce5 Li2 3.682(12) 14_545
Ce5 Li2 3.682(12) 13_455
Ce6 Ge6 3.1304(10) 13
Ce6 Ge6 3.1304(10) 5_444
Ce6 Ge6 3.1304(10) 13_455
Ce6 Ge6 3.1304(10) 5_544
Ce6 Ge4 3.1605(14) .
Ce6 Ge4 3.1607(14) 9
Ce6 Li3 3.593(12) 13
Ce6 Li3 3.593(12) 5_444
Ce6 Li3 3.593(12) 14_545
Ce6 Li3 3.593(12) 6_454
Ce6 Li3 3.593(12) 14_445
Ce6 Li3 3.593(12) 6_554
Ge1 Ge2 2.4881(14) .
Ge1 Ge1 2.511(2) 2
Ge1 Li2 2.620(15) .
Ge1 Ce5 3.1450(7) 13
Ge1 Ce5 3.1450(7) 13_455
Ge1 Ce1 3.1686(8) 1_455
Ge1 Ce2 3.3265(9) 1_455
Ge2 Ge2 2.509(2) 2_565
Ge2 Li1 2.598(16) .
Ge2 Ce2 3.1459(7) 1_455
Ge2 Ce4 3.1610(8) 13
Ge2 Ce4 3.1610(8) 13_455
Ge2 Ce5 3.3307(8) 13_455
Ge2 Ce5 3.3307(8) 13
Ge3 Li1 2.644(9) .
Ge3 Li1 2.644(9) 2
Ge3 Li1 2.644(9) 1_655
Ge3 Li1 2.644(9) 2_655
Ge3 Li1 2.752(17) 13
Ge3 Li1 2.752(17) 14_545
Ge3 Ce4 3.1933(11) 1_655
Ge4 Ge3* 2.677(9) 14_445
Ge4 Li3 2.677(9) 14_445
Ge4 Ge3* 2.677(9) 13
Ge4 Li3 2.677(9) 13
Ge4 Ge3* 2.677(9) 13_455
Ge4 Li3 2.677(9) 13_455
Ge4 Ge3* 2.677(9) 14_545
Ge4 Li3 2.677(9) 14_545
Ge4 Li2 2.724(15) 2
Ge4 Li2 2.724(15) .
Ge5 Li2 2.635(8) 14_445
Ge5 Li2 2.635(8) 13
Ge5 Li2 2.635(8) 13_455
Ge5 Li2 2.635(8) 14_545
Ge5 Li3 2.792(16) .
Ge5 Ge3* 2.792(16) 2
Ge5 Li3 2.792(16) 2
Ge5 Ce3 3.2239(11) 1_455
Ge6 Ge6 2.539(3) 9_556
Ge6 Ge3* 2.639(15) 10_556
Ge6 Li3 2.639(15) 10_556
Ge6 Li3 2.640(15) .
Ge6 Ce6 3.1304(10) 5
Ge6 Ce6 3.1304(10) 5_455
Ge6 Ce3 3.2240(7) 1_455
Ge6 Ce3 3.2240(7) 9_656
Ge6 Ce3 3.2240(7) 9_556
Li1 Li1 2.59(3) 2
Li1 Ge3 2.644(9) 1_455
Li1 Ge3 2.752(17) 13
Li1 Ce4 3.165(12) 13
Li1 Ce4 3.165(12) 13_455
Li1 Li1 3.29(2) 13
Li1 Li1 3.29(2) 13_455
Li1 Ce2 3.673(13) 1_455
Li2 Li2 2.58(3) 2_565
Li2 Ge5 2.635(8) 13
Li2 Ge5 2.635(8) 13_455
Li2 Ce3 3.137(15) 13
Li2 Ce1 3.171(11) 1_455
Li2 Li3 3.331(16) 13_455
Li2 Li3 3.331(16) 13
Li2 Ce5 3.682(12) 13
Li2 Ce5 3.682(12) 13_455
Li3 Ge3* 2.63(3) 2_565
Li3 Li3 2.63(3) 2_565
Li3 Ge4 2.677(9) 13
Li3 Ge4 2.677(9) 13_455
Li3 Ce3 3.147(11) 1_455
Li3 Ce1 3.191(15) 13
Li3 Li2 3.330(16) 13_455
Li3 Li2 3.330(16) 13
Li3 Ce6 3.593(12) 5
