#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:53:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179398 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/95/4329503.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329503
loop_
_publ_author_name
'Sheng-Ping Guo'
'Tae-Soo You'
'Ya-Ho Jung'
'Svilen Bobev'
_publ_section_title
;
 Synthesis, Crystal Chemistry, and Magnetic Properties of RE7Li8Ge10 and
 RE11Li12Ge16 (RE= La-Nd, Sm): New Members of the [REGe2]n[RELi2Ge]m
 Homologous Series
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6821
_journal_page_last               6829
_journal_paper_doi               10.1021/ic300566x
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         Pr11Li12Ge16
_chemical_formula_sum            'Ge16 Li12 Pr11'
_chemical_formula_weight         2794.73
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           71
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-I 2 2'
_symmetry_space_group_name_H-M   'I m m m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   4.4389(17)
_cell_length_b                   6.899(3)
_cell_length_c                   52.23(2)
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      28.3
_cell_measurement_theta_min      0.8
_cell_volume                     1599.5(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0524
_diffrn_reflns_av_sigmaI/netI    0.0264
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       69
_diffrn_reflns_limit_l_min       -69
_diffrn_reflns_number            10681
_diffrn_reflns_theta_full        28.24
_diffrn_reflns_theta_max         28.24
_diffrn_reflns_theta_min         0.78
_exptl_absorpt_coefficient_mu    31.132
_exptl_absorpt_correction_T_max  0.3842
_exptl_absorpt_correction_T_min  0.2793
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    5.802
_exptl_crystal_description       irregular
_exptl_crystal_F_000             2394
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.758
_refine_diff_density_min         -1.353
_refine_diff_density_rms         0.319
_refine_ls_extinction_coef       0.000244(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_matrix_type           full
_refine_ls_number_parameters     63
_refine_ls_number_reflns         1208
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.100
_refine_ls_R_factor_all          0.0376
_refine_ls_R_factor_gt           0.0245
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0143P)²+23.1197P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0477
_refine_ls_wR_factor_ref         0.0598
_reflns_number_gt                930
_reflns_number_total             1208
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300566x_si_002_7.cif
_cod_data_source_block           VII
_cod_original_cell_volume        1599.7(11)
_cod_database_code               4329503
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pr1 Pr 0.5000 0.0000 0.102857(13) 0.00857(17) Uani 1 4 d S
Pr2 Pr 0.5000 0.0000 0.178712(12) 0.00718(16) Uani 1 4 d S
Pr3 Pr 0.5000 0.0000 0.463032(12) 0.00805(16) Uani 1 4 d S
Pr4 Pr 0.0000 0.0000 0.282725(12) 0.00806(17) Uani 1 4 d S
Pr5 Pr 0.0000 0.0000 0.358490(12) 0.00735(16) Uani 1 4 d S
Pr6 Pr 0.0000 0.0000 0.0000 0.0077(2) Uani 1 8 d S
Ge1 Ge 0.0000 0.18158(14) 0.138190(17) 0.0087(2) Uani 1 2 d S
Ge2 Ge 0.0000 0.31813(13) 0.182185(16) 0.0081(2) Uani 1 2 d S
Ge3 Ge 0.5000 0.0000 0.23920(2) 0.0092(3) Uani 1 4 d S
Ge4 Ge 0.0000 0.0000 0.06019(2) 0.0100(3) Uani 1 4 d S
Ge5 Ge 0.0000 0.0000 0.41867(2) 0.0099(3) Uani 1 4 d S
Ge6 Ge 0.0000 0.18345(19) 0.5000 0.0084(3) Uani 1 4 d S
Li1 Li 0.0000 0.189(2) 0.2285(3) 0.011(3) Uiso 1 2 d S
Li2 Li 0.0000 0.311(2) 0.0918(3) 0.010(3) Uiso 1 2 d S
Li3 Li 0.0000 0.313(2) 0.4526(3) 0.039(5) Uiso 0.955(5) 2 d SP
Ge3* Ge 0.0000 0.313(2) 0.4526(3) 0.039(5) Uiso 0.045(5) 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Li2 Pr1 Li2 86.1(4) . 2
Li2 Pr1 Li2 90.0(4) . 1_655
Li2 Pr1 Li2 158.8(5) 2 1_655
Li2 Pr1 Li2 158.8(5) . 2_655
Li2 Pr1 Li2 90.0(4) 2 2_655
Li2 Pr1 Li2 86.1(4) 1_655 2_655
Li2 Pr1 Ge4 111.6(2) . 1_655
Li2 Pr1 Ge4 111.6(2) 2 1_655
Li2 Pr1 Ge4 51.0(2) 1_655 1_655
Li2 Pr1 Ge4 51.0(2) 2_655 1_655
Li2 Pr1 Ge4 51.0(2) . .
Li2 Pr1 Ge4 51.0(2) 2 .
Li2 Pr1 Ge4 111.6(2) 1_655 .
Li2 Pr1 Ge4 111.6(2) 2_655 .
Ge4 Pr1 Ge4 89.77(5) 1_655 .
Li2 Pr1 Ge1 48.5(2) . .
Li2 Pr1 Ge1 83.2(2) 2 .
Li2 Pr1 Ge1 109.6(2) 1_655 .
Li2 Pr1 Ge1 151.4(3) 2_655 .
Ge4 Pr1 Ge1 155.97(2) 1_655 .
Ge4 Pr1 Ge1 85.29(3) . .
Li2 Pr1 Ge1 109.6(2) . 1_655
Li2 Pr1 Ge1 151.4(3) 2 1_655
Li2 Pr1 Ge1 48.5(2) 1_655 1_655
Li2 Pr1 Ge1 83.2(2) 2_655 1_655
Ge4 Pr1 Ge1 85.28(3) 1_655 1_655
Ge4 Pr1 Ge1 155.97(2) . 1_655
Ge1 Pr1 Ge1 89.71(4) . 1_655
Li2 Pr1 Ge1 151.4(3) . 2_655
Li2 Pr1 Ge1 109.6(2) 2 2_655
Li2 Pr1 Ge1 83.2(2) 1_655 2_655
Li2 Pr1 Ge1 48.5(2) 2_655 2_655
Ge4 Pr1 Ge1 85.28(3) 1_655 2_655
Ge4 Pr1 Ge1 155.97(2) . 2_655
Ge1 Pr1 Ge1 108.18(4) . 2_655
Ge1 Pr1 Ge1 46.92(4) 1_655 2_655
Li2 Pr1 Ge1 83.2(2) . 2
Li2 Pr1 Ge1 48.5(2) 2 2
Li2 Pr1 Ge1 151.4(3) 1_655 2
Li2 Pr1 Ge1 109.6(2) 2_655 2
Ge4 Pr1 Ge1 155.97(2) 1_655 2
Ge4 Pr1 Ge1 85.29(3) . 2
Ge1 Pr1 Ge1 46.92(4) . 2
Ge1 Pr1 Ge1 108.18(4) 1_655 2
Ge1 Pr1 Ge1 89.71(4) 2_655 2
Li2 Pr1 Ge3* 96.4(3) . 14_545
Li2 Pr1 Ge3* 63.5(3) 2 14_545
Li2 Pr1 Ge3* 96.4(3) 1_655 14_545
Li2 Pr1 Ge3* 63.5(3) 2_655 14_545
Ge4 Pr1 Ge3* 49.69(10) 1_655 14_545
Ge4 Pr1 Ge3* 49.69(10) . 14_545
Ge1 Pr1 Ge3* 134.26(5) . 14_545
Ge1 Pr1 Ge3* 134.26(5) 1_655 14_545
Ge1 Pr1 Ge3* 111.91(17) 2_655 14_545
Ge1 Pr1 Ge3* 111.91(17) 2 14_545
Li2 Pr1 Li3 96.4(3) . 14_545
Li2 Pr1 Li3 63.5(3) 2 14_545
Li2 Pr1 Li3 96.4(3) 1_655 14_545
Li2 Pr1 Li3 63.5(3) 2_655 14_545
Ge4 Pr1 Li3 49.69(10) 1_655 14_545
Ge4 Pr1 Li3 49.69(10) . 14_545
Ge1 Pr1 Li3 134.26(5) . 14_545
Ge1 Pr1 Li3 134.26(5) 1_655 14_545
Ge1 Pr1 Li3 111.91(17) 2_655 14_545
Ge1 Pr1 Li3 111.91(17) 2 14_545
Ge3* Pr1 Li3 0.0(5) 14_545 14_545
Ge2 Pr2 Ge2 90.44(4) . 1_655
Ge2 Pr2 Ge2 89.17(4) . 2
Ge2 Pr2 Ge2 173.35(4) 1_655 2
Ge2 Pr2 Ge2 173.35(4) . 2_655
Ge2 Pr2 Ge2 89.17(4) 1_655 2_655
Ge2 Pr2 Ge2 90.44(4) 2 2_655
Ge2 Pr2 Ge3 86.67(2) . .
Ge2 Pr2 Ge3 86.67(2) 1_655 .
Ge2 Pr2 Ge3 86.67(2) 2 .
Ge2 Pr2 Ge3 86.67(2) 2_655 .
Ge2 Pr2 Ge1 45.26(3) . .
Ge2 Pr2 Ge1 104.31(3) 1_655 .
Ge2 Pr2 Ge1 80.04(3) 2 .
Ge2 Pr2 Ge1 141.09(3) 2_655 .
Ge3 Pr2 Ge1 129.71(2) . .
Ge2 Pr2 Ge1 80.04(3) . 2
Ge2 Pr2 Ge1 141.09(3) 1_655 2
Ge2 Pr2 Ge1 45.26(3) 2 2
Ge2 Pr2 Ge1 104.31(3) 2_655 2
Ge3 Pr2 Ge1 129.71(2) . 2
Ge1 Pr2 Ge1 44.44(4) . 2
Ge2 Pr2 Ge1 104.31(3) . 1_655
Ge2 Pr2 Ge1 45.26(3) 1_655 1_655
Ge2 Pr2 Ge1 141.09(3) 2 1_655
Ge2 Pr2 Ge1 80.04(3) 2_655 1_655
Ge3 Pr2 Ge1 129.71(2) . 1_655
Ge1 Pr2 Ge1 84.13(4) . 1_655
Ge1 Pr2 Ge1 100.58(4) 2 1_655
Ge2 Pr2 Ge1 141.08(3) . 2_655
Ge2 Pr2 Ge1 80.04(3) 1_655 2_655
Ge2 Pr2 Ge1 104.31(3) 2 2_655
Ge2 Pr2 Ge1 45.26(3) 2_655 2_655
Ge3 Pr2 Ge1 129.71(2) . 2_655
Ge1 Pr2 Ge1 100.58(4) . 2_655
Ge1 Pr2 Ge1 84.13(4) 2 2_655
Ge1 Pr2 Ge1 44.44(4) 1_655 2_655
Ge2 Pr2 Li1 43.7(2) . .
Ge2 Pr2 Li1 97.98(18) 1_655 .
Ge2 Pr2 Li1 77.22(19) 2 .
Ge2 Pr2 Li1 129.8(2) 2_655 .
Ge3 Pr2 Li1 44.74(18) . .
Ge1 Pr2 Li1 84.97(18) . .
Ge1 Pr2 Li1 100.51(14) 2 .
Ge1 Pr2 Li1 136.5(2) 1_655 .
Ge1 Pr2 Li1 174.40(17) 2_655 .
Ge2 Pr2 Li1 97.98(18) . 1_655
Ge2 Pr2 Li1 43.7(2) 1_655 1_655
Ge2 Pr2 Li1 129.8(2) 2 1_655
Ge2 Pr2 Li1 77.22(19) 2_655 1_655
Ge3 Pr2 Li1 44.74(18) . 1_655
Ge1 Pr2 Li1 136.5(2) . 1_655
Ge1 Pr2 Li1 174.40(17) 2 1_655
Ge1 Pr2 Li1 84.97(18) 1_655 1_655
Ge1 Pr2 Li1 100.51(14) 2_655 1_655
Li1 Pr2 Li1 74.7(3) . 1_655
Ge2 Pr2 Li1 129.8(2) . 2_655
Ge2 Pr2 Li1 77.22(19) 1_655 2_655
Ge2 Pr2 Li1 97.98(18) 2 2_655
Ge2 Pr2 Li1 43.7(2) 2_655 2_655
Ge3 Pr2 Li1 44.74(18) . 2_655
Ge1 Pr2 Li1 174.40(17) . 2_655
Ge1 Pr2 Li1 136.5(2) 2 2_655
Ge1 Pr2 Li1 100.51(14) 1_655 2_655
Ge1 Pr2 Li1 84.97(18) 2_655 2_655
Li1 Pr2 Li1 89.5(4) . 2_655
Li1 Pr2 Li1 41.8(4) 1_655 2_655
Ge3* Pr3 Li3 0.0(6) 2 2
Ge3* Pr3 Ge3* 160.0(5) 2 1_655
Li3 Pr3 Ge3* 160.0(5) 2 1_655
Ge3* Pr3 Li3 160.0(5) 2 1_655
Li3 Pr3 Li3 160.0(5) 2 1_655
Ge3* Pr3 Li3 0.0(6) 1_655 1_655
Ge3* Pr3 Ge3* 89.9(4) 2 2_655
Li3 Pr3 Ge3* 89.9(4) 2 2_655
Ge3* Pr3 Ge3* 86.7(4) 1_655 2_655
Li3 Pr3 Ge3* 86.7(4) 1_655 2_655
Ge3* Pr3 Li3 89.9(4) 2 2_655
Li3 Pr3 Li3 89.9(4) 2 2_655
Ge3* Pr3 Li3 86.7(4) 1_655 2_655
Li3 Pr3 Li3 86.7(4) 1_655 2_655
Ge3* Pr3 Li3 0.0(6) 2_655 2_655
Ge3* Pr3 Li3 86.7(4) 2 .
Li3 Pr3 Li3 86.7(4) 2 .
Ge3* Pr3 Li3 89.9(4) 1_655 .
Li3 Pr3 Li3 89.9(4) 1_655 .
Ge3* Pr3 Li3 160.0(5) 2_655 .
Li3 Pr3 Li3 160.0(5) 2_655 .
Ge3* Pr3 Li2 63.7(3) 2 14_545
Li3 Pr3 Li2 63.7(3) 2 14_545
Ge3* Pr3 Li2 97.3(3) 1_655 14_545
Li3 Pr3 Li2 97.3(3) 1_655 14_545
Ge3* Pr3 Li2 63.7(3) 2_655 14_545
Li3 Pr3 Li2 63.7(3) 2_655 14_545
Li3 Pr3 Li2 97.3(3) . 14_545
Ge3* Pr3 Li2 97.3(3) 2 13
Li3 Pr3 Li2 97.3(3) 2 13
Ge3* Pr3 Li2 63.7(3) 1_655 13
Li3 Pr3 Li2 63.7(3) 1_655 13
Ge3* Pr3 Li2 97.3(3) 2_655 13
Li3 Pr3 Li2 97.3(3) 2_655 13
Li3 Pr3 Li2 63.7(3) . 13
Li2 Pr3 Li2 49.0(5) 14_545 13
Ge3* Pr3 Ge6 149.9(2) 2 1_655
Li3 Pr3 Ge6 149.9(2) 2 1_655
Ge3* Pr3 Ge6 49.0(2) 1_655 1_655
Li3 Pr3 Ge6 49.0(2) 1_655 1_655
Ge3* Pr3 Ge6 83.5(2) 2_655 1_655
Li3 Pr3 Ge6 83.5(2) 2_655 1_655
Li3 Pr3 Ge6 108.8(2) . 1_655
Li2 Pr3 Ge6 135.44(5) 14_545 1_655
Li2 Pr3 Ge6 112.62(18) 13 1_655
Ge3* Pr3 Ge6 108.8(2) 2 9_656
Li3 Pr3 Ge6 108.8(2) 2 9_656
Ge3* Pr3 Ge6 83.5(2) 1_655 9_656
Li3 Pr3 Ge6 83.5(2) 1_655 9_656
Ge3* Pr3 Ge6 49.0(2) 2_655 9_656
Li3 Pr3 Ge6 49.0(2) 2_655 9_656
Li3 Pr3 Ge6 149.9(2) . 9_656
Li2 Pr3 Ge6 112.62(18) 14_545 9_656
Li2 Pr3 Ge6 135.44(5) 13 9_656
Ge6 Pr3 Ge6 46.56(5) 1_655 9_656
Li1 Pr4 Li1 49.5(5) 2 .
Li1 Pr4 Ge2 134.22(5) 2 13
Li1 Pr4 Ge2 111.28(18) . 13
Li1 Pr4 Ge2 111.27(18) 2 14_545
Li1 Pr4 Ge2 134.22(5) . 14_545
Ge2 Pr4 Ge2 47.11(4) 13 14_545
Li1 Pr4 Ge2 111.27(18) 2 14_445
Li1 Pr4 Ge2 134.22(5) . 14_445
Ge2 Pr4 Ge2 108.58(4) 13 14_445
Ge2 Pr4 Ge2 89.96(4) 14_545 14_445
Li1 Pr4 Ge2 134.22(5) 2 13_455
Li1 Pr4 Ge2 111.28(18) . 13_455
Ge2 Pr4 Ge2 89.96(4) 13 13_455
Ge2 Pr4 Ge2 108.58(4) 14_545 13_455
Ge2 Pr4 Ge2 47.11(4) 14_445 13_455
Li1 Pr4 Li1 63.0(3) 2 14_445
Li1 Pr4 Li1 96.70(19) . 14_445
Ge2 Pr4 Li1 151.8(3) 13 14_445
Ge2 Pr4 Li1 109.6(2) 14_545 14_445
Ge2 Pr4 Li1 48.4(3) 14_445 14_445
Ge2 Pr4 Li1 83.2(2) 13_455 14_445
Li1 Pr4 Li1 96.70(19) 2 13
Li1 Pr4 Li1 63.0(3) . 13
Ge2 Pr4 Li1 48.4(3) 13 13
Ge2 Pr4 Li1 83.2(2) 14_545 13
Ge2 Pr4 Li1 151.8(3) 14_445 13
Ge2 Pr4 Li1 109.6(2) 13_455 13
Li1 Pr4 Li1 158.5(5) 14_445 13
Li1 Pr4 Li1 96.70(19) 2 13_455
Li1 Pr4 Li1 63.0(3) . 13_455
Ge2 Pr4 Li1 109.6(2) 13 13_455
Ge2 Pr4 Li1 151.8(3) 14_545 13_455
Ge2 Pr4 Li1 83.2(2) 14_445 13_455
Ge2 Pr4 Li1 48.4(3) 13_455 13_455
Li1 Pr4 Li1 86.1(4) 14_445 13_455
Li1 Pr4 Li1 89.9(4) 13 13_455
Li1 Pr4 Li1 63.0(3) 2 14_545
Li1 Pr4 Li1 96.70(19) . 14_545
Ge2 Pr4 Li1 83.2(2) 13 14_545
Ge2 Pr4 Li1 48.4(3) 14_545 14_545
Ge2 Pr4 Li1 109.6(2) 14_445 14_545
Ge2 Pr4 Li1 151.8(3) 13_455 14_545
Li1 Pr4 Li1 89.9(4) 14_445 14_545
Li1 Pr4 Li1 86.1(4) 13 14_545
Li1 Pr4 Li1 158.5(5) 13_455 14_545
Li1 Pr4 Ge3 49.47(11) 2 1_455
Li1 Pr4 Ge3 49.47(11) . 1_455
Ge2 Pr4 Ge3 155.70(2) 13 1_455
Ge2 Pr4 Ge3 155.70(2) 14_545 1_455
Ge2 Pr4 Ge3 85.64(3) 14_445 1_455
Ge2 Pr4 Ge3 85.64(3) 13_455 1_455
Li1 Pr4 Ge3 51.2(3) 14_445 1_455
Li1 Pr4 Ge3 111.1(2) 13 1_455
Li1 Pr4 Ge3 51.2(3) 13_455 1_455
Li1 Pr4 Ge3 111.1(2) 14_545 1_455
Li1 Pr4 Ge3 49.47(11) 2 .
Li1 Pr4 Ge3 49.47(11) . .
Ge2 Pr4 Ge3 85.64(3) 13 .
Ge2 Pr4 Ge3 85.64(3) 14_545 .
Ge2 Pr4 Ge3 155.70(2) 14_445 .
Ge2 Pr4 Ge3 155.70(2) 13_455 .
Li1 Pr4 Ge3 111.1(2) 14_445 .
Li1 Pr4 Ge3 51.2(3) 13 .
Li1 Pr4 Ge3 111.1(2) 13_455 .
Li1 Pr4 Ge3 51.2(3) 14_545 .
Ge3 Pr4 Ge3 88.62(5) 1_455 .
Ge1 Pr5 Ge1 173.64(4) 13 14_445
Ge1 Pr5 Ge1 89.24(4) 13 14_545
Ge1 Pr5 Ge1 90.41(4) 14_445 14_545
Ge1 Pr5 Ge1 90.41(4) 13 13_455
Ge1 Pr5 Ge1 89.24(4) 14_445 13_455
Ge1 Pr5 Ge1 173.64(4) 14_545 13_455
Ge1 Pr5 Ge5 86.82(2) 13 .
Ge1 Pr5 Ge5 86.82(2) 14_445 .
Ge1 Pr5 Ge5 86.82(2) 14_545 .
Ge1 Pr5 Ge5 86.82(2) 13_455 .
Ge1 Pr5 Ge2 140.86(3) 13 14_445
Ge1 Pr5 Ge2 45.20(3) 14_445 14_445
Ge1 Pr5 Ge2 104.15(3) 14_545 14_445
Ge1 Pr5 Ge2 80.01(3) 13_455 14_445
Ge5 Pr5 Ge2 129.80(2) . 14_445
Ge1 Pr5 Ge2 104.15(3) 13 13_455
Ge1 Pr5 Ge2 80.01(3) 14_445 13_455
Ge1 Pr5 Ge2 140.86(3) 14_545 13_455
Ge1 Pr5 Ge2 45.20(3) 13_455 13_455
Ge5 Pr5 Ge2 129.80(2) . 13_455
Ge2 Pr5 Ge2 44.43(4) 14_445 13_455
Ge1 Pr5 Ge2 80.01(3) 13 14_545
Ge1 Pr5 Ge2 104.15(3) 14_445 14_545
Ge1 Pr5 Ge2 45.20(3) 14_545 14_545
Ge1 Pr5 Ge2 140.86(3) 13_455 14_545
Ge5 Pr5 Ge2 129.80(2) . 14_545
Ge2 Pr5 Ge2 83.94(4) 14_445 14_545
Ge2 Pr5 Ge2 100.39(4) 13_455 14_545
Ge1 Pr5 Ge2 45.20(3) 13 13
Ge1 Pr5 Ge2 140.86(3) 14_445 13
Ge1 Pr5 Ge2 80.01(3) 14_545 13
Ge1 Pr5 Ge2 104.15(3) 13_455 13
Ge5 Pr5 Ge2 129.80(2) . 13
Ge2 Pr5 Ge2 100.39(4) 14_445 13
Ge2 Pr5 Ge2 83.94(4) 13_455 13
Ge2 Pr5 Ge2 44.43(4) 14_545 13
Ge1 Pr5 Li2 43.9(2) 13 13
Ge1 Pr5 Li2 130.0(2) 14_445 13
Ge1 Pr5 Li2 77.35(19) 14_545 13
Ge1 Pr5 Li2 98.07(19) 13_455 13
Ge5 Pr5 Li2 44.78(18) . 13
Ge2 Pr5 Li2 174.53(17) 14_445 13
Ge2 Pr5 Li2 136.5(2) 13_455 13
Ge2 Pr5 Li2 100.58(14) 14_545 13
Ge2 Pr5 Li2 85.03(18) 13 13
Ge1 Pr5 Li2 77.35(19) 13 14_545
Ge1 Pr5 Li2 98.07(19) 14_445 14_545
Ge1 Pr5 Li2 43.9(2) 14_545 14_545
Ge1 Pr5 Li2 130.0(2) 13_455 14_545
Ge5 Pr5 Li2 44.78(18) . 14_545
Ge2 Pr5 Li2 136.5(2) 14_445 14_545
Ge2 Pr5 Li2 174.53(17) 13_455 14_545
Ge2 Pr5 Li2 85.03(18) 14_545 14_545
Ge2 Pr5 Li2 100.58(14) 13 14_545
Li2 Pr5 Li2 41.9(5) 13 14_545
Ge1 Pr5 Li2 98.07(19) 13 13_455
Ge1 Pr5 Li2 77.35(19) 14_445 13_455
Ge1 Pr5 Li2 130.0(2) 14_545 13_455
Ge1 Pr5 Li2 43.9(2) 13_455 13_455
Ge5 Pr5 Li2 44.78(18) . 13_455
Ge2 Pr5 Li2 100.58(14) 14_445 13_455
Ge2 Pr5 Li2 85.03(18) 13_455 13_455
Ge2 Pr5 Li2 174.53(17) 14_545 13_455
Ge2 Pr5 Li2 136.5(2) 13 13_455
Li2 Pr5 Li2 74.7(3) 13 13_455
Li2 Pr5 Li2 89.6(4) 14_545 13_455
Ge6 Pr6 Ge6 180.00(3) 13 5_444
Ge6 Pr6 Ge6 90.92(5) 13 13_455
Ge6 Pr6 Ge6 89.08(5) 5_444 13_455
Ge6 Pr6 Ge6 89.08(5) 13 5_544
Ge6 Pr6 Ge6 90.92(5) 5_444 5_544
Ge6 Pr6 Ge6 180.0 13_455 5_544
Ge6 Pr6 Ge4 90.0 13 .
Ge6 Pr6 Ge4 90.0 5_444 .
Ge6 Pr6 Ge4 90.0 13_455 .
Ge6 Pr6 Ge4 90.0 5_544 .
Ge6 Pr6 Ge4 90.0 13 9
Ge6 Pr6 Ge4 90.0 5_444 9
Ge6 Pr6 Ge4 90.0 13_455 9
Ge6 Pr6 Ge4 90.0 5_544 9
Ge4 Pr6 Ge4 180.0 . 9
Ge6 Pr6 Li3 45.8(2) 13 13
Ge6 Pr6 Li3 134.2(2) 5_444 13
Ge6 Pr6 Li3 100.91(18) 13_455 13
Ge6 Pr6 Li3 79.09(18) 5_544 13
Ge4 Pr6 Li3 46.03(17) . 13
Ge4 Pr6 Li3 133.97(17) 9 13
Ge6 Pr6 Li3 134.2(2) 13 5_444
Ge6 Pr6 Li3 45.8(2) 5_444 5_444
Ge6 Pr6 Li3 79.09(18) 13_455 5_444
Ge6 Pr6 Li3 100.91(18) 5_544 5_444
Ge4 Pr6 Li3 133.97(17) . 5_444
Ge4 Pr6 Li3 46.03(17) 9 5_444
Li3 Pr6 Li3 180.0(3) 13 5_444
Ge6 Pr6 Li3 79.09(18) 13 14_545
Ge6 Pr6 Li3 100.91(18) 5_444 14_545
Ge6 Pr6 Li3 134.2(2) 13_455 14_545
Ge6 Pr6 Li3 45.8(2) 5_544 14_545
Ge4 Pr6 Li3 46.03(17) . 14_545
Ge4 Pr6 Li3 133.97(17) 9 14_545
Li3 Pr6 Li3 42.5(4) 13 14_545
Li3 Pr6 Li3 137.5(4) 5_444 14_545
Ge6 Pr6 Li3 100.91(18) 13 6_454
Ge6 Pr6 Li3 79.09(18) 5_444 6_454
Ge6 Pr6 Li3 45.8(2) 13_455 6_454
Ge6 Pr6 Li3 134.2(2) 5_544 6_454
Ge4 Pr6 Li3 133.97(17) . 6_454
Ge4 Pr6 Li3 46.03(17) 9 6_454
Li3 Pr6 Li3 137.5(4) 13 6_454
Li3 Pr6 Li3 42.5(4) 5_444 6_454
Li3 Pr6 Li3 180.0(3) 14_545 6_454
Ge6 Pr6 Li3 100.91(18) 13 13_455
Ge6 Pr6 Li3 79.09(18) 5_444 13_455
Ge6 Pr6 Li3 45.8(2) 13_455 13_455
Ge6 Pr6 Li3 134.2(2) 5_544 13_455
Ge4 Pr6 Li3 46.03(17) . 13_455
Ge4 Pr6 Li3 133.97(17) 9 13_455
Li3 Pr6 Li3 76.9(3) 13 13_455
Li3 Pr6 Li3 103.1(3) 5_444 13_455
Li3 Pr6 Li3 92.1(3) 14_545 13_455
Li3 Pr6 Li3 87.9(3) 6_454 13_455
Ge6 Pr6 Li3 79.09(18) 13 5_544
Ge6 Pr6 Li3 100.91(18) 5_444 5_544
Ge6 Pr6 Li3 134.2(2) 13_455 5_544
Ge6 Pr6 Li3 45.8(2) 5_544 5_544
Ge4 Pr6 Li3 133.97(17) . 5_544
Ge4 Pr6 Li3 46.03(17) 9 5_544
Li3 Pr6 Li3 103.1(3) 13 5_544
Li3 Pr6 Li3 76.9(3) 5_444 5_544
Li3 Pr6 Li3 87.9(3) 14_545 5_544
Li3 Pr6 Li3 92.1(3) 6_454 5_544
Li3 Pr6 Li3 180.0(3) 13_455 5_544
Ge2 Ge1 Ge1 112.29(3) . 2
Ge2 Ge1 Li2 137.5(3) . .
Ge1 Ge1 Li2 110.2(3) 2 .
Ge2 Ge1 Pr5 71.47(3) . 13
Ge1 Ge1 Pr5 134.621(19) 2 13
Li2 Ge1 Pr5 79.0(2) . 13
Ge2 Ge1 Pr5 71.47(3) . 13_455
Ge1 Ge1 Pr5 134.62(2) 2 13_455
Li2 Ge1 Pr5 79.0(2) . 13_455
Pr5 Ge1 Pr5 90.41(4) 13 13_455
Ge2 Ge1 Pr1 133.92(2) . .
Ge1 Ge1 Pr1 66.539(19) 2 .
Li2 Ge1 Pr1 65.6(2) . .
Pr5 Ge1 Pr1 79.14(3) 13 .
Pr5 Ge1 Pr1 144.36(4) 13_455 .
Ge2 Ge1 Pr1 133.93(2) . 1_455
Ge1 Ge1 Pr1 66.54(2) 2 1_455
Li2 Ge1 Pr1 65.6(2) . 1_455
Pr5 Ge1 Pr1 144.36(4) 13 1_455
Pr5 Ge1 Pr1 79.14(3) 13_455 1_455
Pr1 Ge1 Pr1 89.71(4) . 1_455
Ge2 Ge1 Pr2 63.41(3) . 1_455
Ge1 Ge1 Pr2 67.780(18) 2 1_455
Li2 Ge1 Pr2 136.90(7) . 1_455
Pr5 Ge1 Pr2 134.88(4) 13 1_455
Pr5 Ge1 Pr2 75.81(3) 13_455 1_455
Pr1 Ge1 Pr2 134.16(4) . 1_455
Pr1 Ge1 Pr2 75.62(3) 1_455 1_455
Ge2 Ge1 Pr2 63.41(3) . .
Ge1 Ge1 Pr2 67.781(18) 2 .
Li2 Ge1 Pr2 136.90(7) . .
Pr5 Ge1 Pr2 75.81(3) 13 .
Pr5 Ge1 Pr2 134.88(4) 13_455 .
Pr1 Ge1 Pr2 75.62(3) . .
Pr1 Ge1 Pr2 134.16(4) 1_455 .
Pr2 Ge1 Pr2 84.13(4) 1_455 .
Ge1 Ge2 Ge2 112.29(3) . 2_565
Ge1 Ge2 Li1 137.5(3) . .
Ge2 Ge2 Li1 110.2(3) 2_565 .
Ge1 Ge2 Pr2 71.34(3) . .
Ge2 Ge2 Pr2 134.59(2) 2_565 .
Li1 Ge2 Pr2 79.2(2) . .
Ge1 Ge2 Pr2 71.34(3) . 1_455
Ge2 Ge2 Pr2 134.586(19) 2_565 1_455
Li1 Ge2 Pr2 79.2(2) . 1_455
Pr2 Ge2 Pr2 90.44(4) . 1_455
Ge1 Ge2 Pr4 133.76(2) . 13
Ge2 Ge2 Pr4 66.446(19) 2_565 13
Li1 Ge2 Pr4 65.8(2) . 13
Pr2 Ge2 Pr4 79.20(3) . 13
Pr2 Ge2 Pr4 144.70(4) 1_455 13
Ge1 Ge2 Pr4 133.76(2) . 13_455
Ge2 Ge2 Pr4 66.446(19) 2_565 13_455
Li1 Ge2 Pr4 65.8(2) . 13_455
Pr2 Ge2 Pr4 144.70(4) . 13_455
Pr2 Ge2 Pr4 79.20(3) 1_455 13_455
Pr4 Ge2 Pr4 89.95(4) 13 13_455
Ge1 Ge2 Pr5 63.33(3) . 13_455
Ge2 Ge2 Pr5 67.785(18) 2_565 13_455
Li1 Ge2 Pr5 137.00(7) . 13_455
Pr2 Ge2 Pr5 134.67(4) . 13_455
Pr2 Ge2 Pr5 75.73(3) 1_455 13_455
Pr4 Ge2 Pr5 134.05(4) 13 13_455
Pr4 Ge2 Pr5 75.52(3) 13_455 13_455
Ge1 Ge2 Pr5 63.33(3) . 13
Ge2 Ge2 Pr5 67.785(18) 2_565 13
Li1 Ge2 Pr5 137.00(7) . 13
Pr2 Ge2 Pr5 75.73(3) . 13
Pr2 Ge2 Pr5 134.67(4) 1_455 13
Pr4 Ge2 Pr5 75.52(3) 13 13
Pr4 Ge2 Pr5 134.05(4) 13_455 13
Pr5 Ge2 Pr5 83.94(4) 13_455 13
Li1 Ge3 Li1 155.4(6) 2 1_655
Li1 Ge3 Li1 114.7(5) 2 2_655
Li1 Ge3 Li1 59.4(6) 1_655 2_655
Li1 Ge3 Li1 59.4(6) 2 .
Li1 Ge3 Li1 114.7(5) 1_655 .
Li1 Ge3 Li1 155.4(6) 2_655 .
Li1 Ge3 Li1 121.4(2) 2 13
Li1 Ge3 Li1 75.1(4) 1_655 13
Li1 Ge3 Li1 121.4(2) 2_655 13
Li1 Ge3 Li1 75.1(4) . 13
Li1 Ge3 Li1 75.1(4) 2 14_545
Li1 Ge3 Li1 121.4(2) 1_655 14_545
Li1 Ge3 Li1 75.1(4) 2_655 14_545
Li1 Ge3 Li1 121.4(2) . 14_545
Li1 Ge3 Li1 103.5(6) 13 14_545
Li1 Ge3 Pr2 77.7(3) 2 .
Li1 Ge3 Pr2 77.7(3) 1_655 .
Li1 Ge3 Pr2 77.7(3) 2_655 .
Li1 Ge3 Pr2 77.7(3) . .
Li1 Ge3 Pr2 128.2(3) 13 .
Li1 Ge3 Pr2 128.2(3) 14_545 .
Li1 Ge3 Pr4 137.8(3) 2 1_655
Li1 Ge3 Pr4 64.1(3) 1_655 1_655
Li1 Ge3 Pr4 64.1(3) 2_655 1_655
Li1 Ge3 Pr4 137.8(3) . 1_655
Li1 Ge3 Pr4 63.71(19) 13 1_655
Li1 Ge3 Pr4 63.7(2) 14_545 1_655
Pr2 Ge3 Pr4 135.69(2) . 1_655
Li1 Ge3 Pr4 64.1(3) 2 .
Li1 Ge3 Pr4 137.8(3) 1_655 .
Li1 Ge3 Pr4 137.8(3) 2_655 .
Li1 Ge3 Pr4 64.1(3) . .
Li1 Ge3 Pr4 63.7(2) 13 .
Li1 Ge3 Pr4 63.71(19) 14_545 .
Pr2 Ge3 Pr4 135.69(2) . .
Pr4 Ge3 Pr4 88.62(5) 1_655 .
Ge3* Ge4 Li3 0.0(8) 14_445 14_445
Ge3* Ge4 Ge3* 150.9(6) 14_445 13
Li3 Ge4 Ge3* 150.9(6) 14_445 13
Ge3* Ge4 Li3 150.9(6) 14_445 13
Li3 Ge4 Li3 150.9(6) 14_445 13
Ge3* Ge4 Li3 0.0(6) 13 13
Ge3* Ge4 Ge3* 58.3(5) 14_445 13_455
Li3 Ge4 Ge3* 58.3(5) 14_445 13_455
Ge3* Ge4 Ge3* 113.5(5) 13 13_455
Li3 Ge4 Ge3* 113.5(5) 13 13_455
Ge3* Ge4 Li3 58.3(5) 14_445 13_455
Li3 Ge4 Li3 58.3(5) 14_445 13_455
Ge3* Ge4 Li3 113.5(5) 13 13_455
Li3 Ge4 Li3 113.5(5) 13 13_455
Ge3* Ge4 Li3 0.0(6) 13_455 13_455
Ge3* Ge4 Ge3* 113.5(5) 14_445 14_545
Li3 Ge4 Ge3* 113.5(5) 14_445 14_545
Ge3* Ge4 Ge3* 58.3(5) 13 14_545
Li3 Ge4 Ge3* 58.3(5) 13 14_545
Ge3* Ge4 Ge3* 150.9(6) 13_455 14_545
Li3 Ge4 Ge3* 150.9(6) 13_455 14_545
Ge3* Ge4 Li3 113.5(5) 14_445 14_545
Li3 Ge4 Li3 113.5(5) 14_445 14_545
Ge3* Ge4 Li3 58.3(5) 13 14_545
Li3 Ge4 Li3 58.3(5) 13 14_545
Ge3* Ge4 Li3 150.9(6) 13_455 14_545
Li3 Ge4 Li3 150.9(6) 13_455 14_545
Ge3* Ge4 Li3 0.0(8) 14_545 14_545
Ge3* Ge4 Li2 122.6(3) 14_445 .
Li3 Ge4 Li2 122.6(3) 14_445 .
Ge3* Ge4 Li2 76.6(3) 13 .
Li3 Ge4 Li2 76.6(3) 13 .
Ge3* Ge4 Li2 76.6(3) 13_455 .
Li3 Ge4 Li2 76.6(3) 13_455 .
Ge3* Ge4 Li2 122.6(3) 14_545 .
Li3 Ge4 Li2 122.6(3) 14_545 .
Ge3* Ge4 Li2 76.6(3) 14_445 2
Li3 Ge4 Li2 76.6(3) 14_445 2
Ge3* Ge4 Li2 122.6(3) 13 2
Li3 Ge4 Li2 122.6(3) 13 2
Ge3* Ge4 Li2 122.6(3) 13_455 2
Li3 Ge4 Li2 122.6(3) 13_455 2
Ge3* Ge4 Li2 76.6(3) 14_545 2
Li3 Ge4 Li2 76.6(3) 14_545 2
Li2 Ge4 Li2 104.7(6) . 2
Ge3* Ge4 Pr6 75.5(3) 14_445 .
Li3 Ge4 Pr6 75.5(3) 14_445 .
Ge3* Ge4 Pr6 75.5(3) 13 .
Li3 Ge4 Pr6 75.5(3) 13 .
Ge3* Ge4 Pr6 75.5(3) 13_455 .
Li3 Ge4 Pr6 75.5(3) 13_455 .
Ge3* Ge4 Pr6 75.5(3) 14_545 .
Li3 Ge4 Pr6 75.5(3) 14_545 .
Li2 Ge4 Pr6 127.6(3) . .
Li2 Ge4 Pr6 127.6(3) 2 .
Ge3* Ge4 Pr1 65.7(3) 14_445 1_455
Li3 Ge4 Pr1 65.7(3) 14_445 1_455
Ge3* Ge4 Pr1 140.2(3) 13 1_455
Li3 Ge4 Pr1 140.2(3) 13 1_455
Ge3* Ge4 Pr1 65.7(3) 13_455 1_455
Li3 Ge4 Pr1 65.7(3) 13_455 1_455
Ge3* Ge4 Pr1 140.2(3) 14_545 1_455
Li3 Ge4 Pr1 140.2(3) 14_545 1_455
Li2 Ge4 Pr1 64.37(19) . 1_455
Li2 Ge4 Pr1 64.37(19) 2 1_455
Pr6 Ge4 Pr1 135.12(2) . 1_455
Li2 Ge5 Li2 156.0(6) 14_445 13
Li2 Ge5 Li2 59.5(6) 14_445 13_455
Li2 Ge5 Li2 114.9(5) 13 13_455
Li2 Ge5 Li2 114.9(6) 14_445 14_545
Li2 Ge5 Li2 59.5(6) 13 14_545
Li2 Ge5 Li2 156.0(6) 13_455 14_545
Li2 Ge5 Li3 121.0(3) 14_445 .
Li2 Ge5 Li3 75.4(3) 13 .
Li2 Ge5 Li3 75.4(3) 13_455 .
Li2 Ge5 Li3 121.0(3) 14_545 .
Li2 Ge5 Ge3* 75.4(3) 14_445 2
Li2 Ge5 Ge3* 121.0(3) 13 2
Li2 Ge5 Ge3* 121.0(3) 13_455 2
Li2 Ge5 Ge3* 75.4(3) 14_545 2
Li3 Ge5 Ge3* 101.2(6) . 2
Li2 Ge5 Li3 75.4(3) 14_445 2
Li2 Ge5 Li3 121.0(3) 13 2
Li2 Ge5 Li3 121.0(3) 13_455 2
Li2 Ge5 Li3 75.4(3) 14_545 2
Li3 Ge5 Li3 101.2(6) . 2
Ge3* Ge5 Li3 0.0(6) 2 2
Li2 Ge5 Pr5 78.0(3) 14_445 .
Li2 Ge5 Pr5 78.0(3) 13 .
Li2 Ge5 Pr5 78.0(3) 13_455 .
Li2 Ge5 Pr5 78.0(3) 14_545 .
Li3 Ge5 Pr5 129.4(3) . .
Ge3* Ge5 Pr5 129.4(3) 2 .
Li3 Ge5 Pr5 129.4(3) 2 .
Li2 Ge5 Pr3 137.2(3) 14_445 .
Li2 Ge5 Pr3 64.4(3) 13 .
Li2 Ge5 Pr3 137.2(3) 13_455 .
Li2 Ge5 Pr3 64.4(3) 14_545 .
Li3 Ge5 Pr3 62.72(18) . .
Ge3* Ge5 Pr3 62.72(18) 2 .
Li3 Ge5 Pr3 62.72(18) 2 .
Pr5 Ge5 Pr3 136.24(2) . .
Li2 Ge5 Pr3 64.4(3) 14_445 1_455
Li2 Ge5 Pr3 137.2(3) 13 1_455
Li2 Ge5 Pr3 64.4(3) 13_455 1_455
Li2 Ge5 Pr3 137.2(3) 14_545 1_455
Li3 Ge5 Pr3 62.72(18) . 1_455
Ge3* Ge5 Pr3 62.72(18) 2 1_455
Li3 Ge5 Pr3 62.72(18) 2 1_455
Pr5 Ge5 Pr3 136.24(2) . 1_455
Pr3 Ge5 Pr3 87.53(5) . 1_455
Ge6 Ge6 Ge3* 109.8(3) 9_556 10_556
Ge6 Ge6 Li3 109.8(3) 9_556 10_556
Ge3* Ge6 Li3 0.0(6) 10_556 10_556
Ge6 Ge6 Li3 109.8(3) 9_556 .
Ge3* Ge6 Li3 140.4(6) 10_556 .
Li3 Ge6 Li3 140.4(6) 10_556 .
Ge6 Ge6 Pr6 134.54(2) 9_556 5
Ge3* Ge6 Pr6 76.3(2) 10_556 5
Li3 Ge6 Pr6 76.3(2) 10_556 5
Li3 Ge6 Pr6 76.3(2) . 5
Ge6 Ge6 Pr6 134.54(2) 9_556 5_455
Ge3* Ge6 Pr6 76.3(2) 10_556 5_455
Li3 Ge6 Pr6 76.3(2) 10_556 5_455
Li3 Ge6 Pr6 76.3(2) . 5_455
Pr6 Ge6 Pr6 90.92(5) 5 5_455
Ge6 Ge6 Pr3 66.72(2) 9_556 1_455
Ge3* Ge6 Pr3 134.52(8) 10_556 1_455
Li3 Ge6 Pr3 134.52(8) 10_556 1_455
Li3 Ge6 Pr3 64.3(2) . 1_455
Pr6 Ge6 Pr3 140.46(3) 5 1_455
Pr6 Ge6 Pr3 77.48(2) 5_455 1_455
Ge6 Ge6 Pr3 66.72(2) 9_556 9_656
Ge3* Ge6 Pr3 64.31(19) 10_556 9_656
Li3 Ge6 Pr3 64.31(19) 10_556 9_656
Li3 Ge6 Pr3 134.52(8) . 9_656
Pr6 Ge6 Pr3 77.48(2) 5 9_656
Pr6 Ge6 Pr3 140.46(3) 5_455 9_656
Pr3 Ge6 Pr3 133.44(5) 1_455 9_656
Ge6 Ge6 Pr3 66.72(2) 9_556 9_556
Ge3* Ge6 Pr3 64.3(2) 10_556 9_556
Li3 Ge6 Pr3 64.3(2) 10_556 9_556
Li3 Ge6 Pr3 134.52(8) . 9_556
Pr6 Ge6 Pr3 140.46(3) 5 9_556
Pr6 Ge6 Pr3 77.48(2) 5_455 9_556
Pr3 Ge6 Pr3 74.16(4) 1_455 9_556
Pr3 Ge6 Pr3 87.74(4) 9_656 9_556
Ge6 Ge6 Pr3 66.72(2) 9_556 .
Ge3* Ge6 Pr3 134.52(8) 10_556 .
Li3 Ge6 Pr3 134.52(8) 10_556 .
Li3 Ge6 Pr3 64.3(2) . .
Pr6 Ge6 Pr3 77.48(2) 5 .
Pr6 Ge6 Pr3 140.46(3) 5_455 .
Pr3 Ge6 Pr3 87.74(4) 1_455 .
Pr3 Ge6 Pr3 74.16(4) 9_656 .
Pr3 Ge6 Pr3 133.44(5) 9_556 .
Ge2 Li1 Li1 110.2(3) . 2
Ge2 Li1 Ge3 111.8(3) . 1_455
Li1 Li1 Ge3 60.3(3) 2 1_455
Ge2 Li1 Ge3 111.8(3) . .
Li1 Li1 Ge3 60.3(3) 2 .
Ge3 Li1 Ge3 114.7(5) 1_455 .
Ge2 Li1 Ge3 108.1(5) . 13
Li1 Li1 Ge3 141.8(3) 2 13
Ge3 Li1 Ge3 104.9(4) 1_455 13
Ge3 Li1 Ge3 104.9(4) . 13
Ge2 Li1 Pr4 175.4(6) . .
Li1 Li1 Pr4 65.3(3) 2 .
Ge3 Li1 Pr4 66.4(3) 1_455 .
Ge3 Li1 Pr4 66.4(3) . .
Ge3 Li1 Pr4 76.5(4) 13 .
Ge2 Li1 Pr4 65.8(3) . 13
Li1 Li1 Pr4 133.0(2) 2 13
Ge3 Li1 Pr4 166.7(5) 1_455 13
Ge3 Li1 Pr4 77.45(9) . 13
Ge3 Li1 Pr4 65.1(3) 13 13
Pr4 Li1 Pr4 117.0(3) . 13
Ge2 Li1 Pr4 65.8(3) . 13_455
Li1 Li1 Pr4 133.0(2) 2 13_455
Ge3 Li1 Pr4 77.45(9) 1_455 13_455
Ge3 Li1 Pr4 166.7(5) . 13_455
Ge3 Li1 Pr4 65.1(3) 13 13_455
Pr4 Li1 Pr4 117.0(3) . 13_455
Pr4 Li1 Pr4 89.9(4) 13 13_455
Ge2 Li1 Li1 123.9(6) . 13
Li1 Li1 Li1 104.8(5) 2 13
Ge3 Li1 Li1 123.5(7) 1_455 13
Ge3 Li1 Li1 53.8(2) . 13
Ge3 Li1 Li1 51.2(4) 13 13
Pr4 Li1 Li1 58.8(4) . 13
Pr4 Li1 Li1 58.2(3) 13 13
Pr4 Li1 Li1 115.7(7) 13_455 13
Ge2 Li1 Li1 123.9(6) . 13_455
Li1 Li1 Li1 104.8(5) 2 13_455
Ge3 Li1 Li1 53.8(2) 1_455 13_455
Ge3 Li1 Li1 123.5(7) . 13_455
Ge3 Li1 Li1 51.2(4) 13 13_455
Pr4 Li1 Li1 58.8(4) . 13_455
Pr4 Li1 Li1 115.7(7) 13 13_455
Pr4 Li1 Li1 58.2(3) 13_455 13_455
Li1 Li1 Li1 85.5(7) 13 13_455
Ge2 Li1 Pr2 57.1(2) . .
Li1 Li1 Pr2 69.1(2) 2 .
Ge3 Li1 Pr2 119.0(5) 1_455 .
Ge3 Li1 Pr2 57.54(19) . .
Ge3 Li1 Pr2 136.1(3) 13 .
Pr4 Li1 Pr2 119.7(3) . .
Pr4 Li1 Pr2 71.51(18) 13 .
Pr4 Li1 Pr2 122.7(4) 13_455 .
Li1 Li1 Pr2 99.7(2) 13 .
Li1 Li1 Pr2 172.8(6) 13_455 .
Ge2 Li1 Pr2 57.1(2) . 1_455
Li1 Li1 Pr2 69.1(2) 2 1_455
Ge3 Li1 Pr2 57.54(19) 1_455 1_455
Ge3 Li1 Pr2 119.0(5) . 1_455
Ge3 Li1 Pr2 136.1(3) 13 1_455
Pr4 Li1 Pr2 119.7(3) . 1_455
Pr4 Li1 Pr2 122.7(4) 13 1_455
Pr4 Li1 Pr2 71.51(18) 13_455 1_455
Li1 Li1 Pr2 172.8(6) 13 1_455
Li1 Li1 Pr2 99.7(2) 13_455 1_455
Pr2 Li1 Pr2 74.7(3) . 1_455
Ge1 Li2 Li2 110.2(3) . 2_565
Ge1 Li2 Ge5 111.5(3) . 13
Li2 Li2 Ge5 60.2(3) 2_565 13
Ge1 Li2 Ge5 111.5(3) . 13_455
Li2 Li2 Ge5 60.2(3) 2_565 13_455
Ge5 Li2 Ge5 114.9(5) 13 13_455
Ge1 Li2 Ge4 107.4(5) . .
Li2 Li2 Ge4 142.4(3) 2_565 .
Ge5 Li2 Ge4 105.4(3) 13 .
Ge5 Li2 Ge4 105.4(3) 13_455 .
Ge1 Li2 Pr1 65.9(3) . 1_455
Li2 Li2 Pr1 133.1(2) 2_565 1_455
Ge5 Li2 Pr1 166.7(5) 13 1_455
Ge5 Li2 Pr1 77.35(9) 13_455 1_455
Ge4 Li2 Pr1 64.6(3) . 1_455
Ge1 Li2 Pr1 65.9(3) . .
Li2 Li2 Pr1 133.1(2) 2_565 .
Ge5 Li2 Pr1 77.35(9) 13 .
Ge5 Li2 Pr1 166.7(5) 13_455 .
Ge4 Li2 Pr1 64.6(3) . .
Pr1 Li2 Pr1 90.0(4) 1_455 .
Ge1 Li2 Pr3 175.7(6) . 13
Li2 Li2 Pr3 65.5(3) 2_565 13
Ge5 Li2 Pr3 66.7(3) 13 13
Ge5 Li2 Pr3 66.7(3) 13_455 13
Ge4 Li2 Pr3 76.9(3) . 13
Pr1 Li2 Pr3 116.8(3) 1_455 13
Pr1 Li2 Pr3 116.8(3) . 13
Ge1 Li2 Li3 124.5(4) . 13_455
Li2 Li2 Li3 104.8(3) 2_565 13_455
Ge5 Li2 Li3 123.0(5) 13 13_455
Ge5 Li2 Li3 54.4(3) 13_455 13_455
Ge4 Li2 Li3 51.0(3) . 13_455
Pr1 Li2 Li3 58.7(3) 1_455 13_455
Pr1 Li2 Li3 115.2(5) . 13_455
Pr3 Li2 Li3 58.1(3) 13 13_455
Ge1 Li2 Li3 124.5(4) . 13
Li2 Li2 Li3 104.8(3) 2_565 13
Ge5 Li2 Li3 54.4(3) 13 13
Ge5 Li2 Li3 123.0(5) 13_455 13
Ge4 Li2 Li3 51.0(3) . 13
Pr1 Li2 Li3 115.2(5) 1_455 13
Pr1 Li2 Li3 58.7(3) . 13
Pr3 Li2 Li3 58.1(3) 13 13
Li3 Li2 Li3 83.9(5) 13_455 13
Ge1 Li2 Pr5 57.1(2) . 13
Li2 Li2 Pr5 69.1(2) 2_565 13
Ge5 Li2 Pr5 57.23(19) 13 13
Ge5 Li2 Pr5 118.8(5) 13_455 13
Ge4 Li2 Pr5 135.8(3) . 13
Pr1 Li2 Pr5 122.9(4) 1_455 13
Pr1 Li2 Pr5 71.60(17) . 13
Pr3 Li2 Pr5 119.8(3) 13 13
Li3 Li2 Pr5 173.2(5) 13_455 13
Li3 Li2 Pr5 100.45(16) 13 13
Ge1 Li2 Pr5 57.1(2) . 13_455
Li2 Li2 Pr5 69.1(2) 2_565 13_455
Ge5 Li2 Pr5 118.8(5) 13 13_455
Ge5 Li2 Pr5 57.23(19) 13_455 13_455
Ge4 Li2 Pr5 135.8(3) . 13_455
Pr1 Li2 Pr5 71.60(17) 1_455 13_455
Pr1 Li2 Pr5 122.9(4) . 13_455
Pr3 Li2 Pr5 119.8(3) 13 13_455
Li3 Li2 Pr5 100.45(16) 13_455 13_455
Li3 Li2 Pr5 173.2(5) 13 13_455
Pr5 Li2 Pr5 74.7(3) 13 13_455
Ge3* Li3 Li3 0.0(6) 2_565 2_565
Ge3* Li3 Ge6 109.8(3) 2_565 .
Li3 Li3 Ge6 109.8(3) 2_565 .
Ge3* Li3 Ge4 60.8(3) 2_565 13
Li3 Li3 Ge4 60.8(3) 2_565 13
Ge6 Li3 Ge4 113.7(3) . 13
Ge3* Li3 Ge4 60.8(3) 2_565 13_455
Li3 Li3 Ge4 60.8(3) 2_565 13_455
Ge6 Li3 Ge4 113.7(3) . 13_455
Ge4 Li3 Ge4 113.5(5) 13 13_455
Ge3* Li3 Ge5 140.6(3) 2_565 .
Li3 Li3 Ge5 140.6(3) 2_565 .
Ge6 Li3 Ge5 109.6(5) . .
Ge4 Li3 Ge5 102.5(3) 13 .
Ge4 Li3 Ge5 102.5(3) 13_455 .
Ge3* Li3 Pr3 133.34(19) 2_565 .
Li3 Li3 Pr3 133.34(19) 2_565 .
Ge6 Li3 Pr3 66.7(3) . .
Ge4 Li3 Pr3 77.73(8) 13 .
Ge4 Li3 Pr3 165.6(5) 13_455 .
Ge5 Li3 Pr3 65.2(3) . .
Ge3* Li3 Pr3 133.34(19) 2_565 1_455
Li3 Li3 Pr3 133.34(19) 2_565 1_455
Ge6 Li3 Pr3 66.7(3) . 1_455
Ge4 Li3 Pr3 165.6(5) 13 1_455
Ge4 Li3 Pr3 77.73(8) 13_455 1_455
Ge5 Li3 Pr3 65.2(3) . 1_455
Pr3 Li3 Pr3 89.9(4) . 1_455
Ge3* Li3 Pr1 65.9(3) 2_565 13
Li3 Li3 Pr1 65.9(3) 2_565 13
Ge6 Li3 Pr1 175.7(6) . 13
Ge4 Li3 Pr1 64.7(3) 13 13
Ge4 Li3 Pr1 64.7(3) 13_455 13
Ge5 Li3 Pr1 74.7(3) . 13
Pr3 Li3 Pr1 116.0(3) . 13
Pr3 Li3 Pr1 116.0(3) 1_455 13
Ge3* Li3 Li2 104.8(3) 2_565 13_455
Li3 Li3 Li2 104.8(3) 2_565 13_455
Ge6 Li3 Li2 124.8(4) . 13_455
Ge4 Li3 Li2 120.6(5) 13 13_455
Ge4 Li3 Li2 52.4(3) 13_455 13_455
Ge5 Li3 Li2 50.1(3) . 13_455
Pr3 Li3 Li2 114.7(5) . 13_455
Pr3 Li3 Li2 58.2(3) 1_455 13_455
Pr1 Li3 Li2 57.8(3) 13 13_455
Ge3* Li3 Li2 104.8(3) 2_565 13
Li3 Li3 Li2 104.8(3) 2_565 13
Ge6 Li3 Li2 124.8(4) . 13
Ge4 Li3 Li2 52.4(3) 13 13
Ge4 Li3 Li2 120.6(5) 13_455 13
Ge5 Li3 Li2 50.1(3) . 13
Pr3 Li3 Li2 58.2(3) . 13
Pr3 Li3 Li2 114.7(5) 1_455 13
Pr1 Li3 Li2 57.8(3) 13 13
Li2 Li3 Li2 83.9(5) 13_455 13
Ge3* Li3 Pr6 68.8(2) 2_565 5
Li3 Li3 Pr6 68.8(2) 2_565 5
Ge6 Li3 Pr6 58.0(2) . 5
Ge4 Li3 Pr6 58.52(17) 13 5
Ge4 Li3 Pr6 121.2(5) 13_455 5
Ge5 Li3 Pr6 136.1(3) . 5
Pr3 Li3 Pr6 71.86(16) . 5
Pr3 Li3 Pr6 124.5(4) 1_455 5
Pr1 Li3 Pr6 119.1(3) 13 5
Li2 Li3 Pr6 173.3(5) 13_455 5
Li2 Li3 Pr6 99.31(17) 13 5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pr1 Li2 3.139(11) .
Pr1 Li2 3.139(11) 2
Pr1 Li2 3.139(11) 1_655
Pr1 Li2 3.139(11) 2_655
Pr1 Ge4 3.1451(13) 1_655
Pr1 Ge4 3.1452(13) .
Pr1 Ge1 3.1467(11) .
Pr1 Ge1 3.1467(11) 1_655
Pr1 Ge1 3.1467(11) 2_655
Pr1 Ge1 3.1467(11) 2
Pr1 Ge3* 3.171(13) 14_545
Pr1 Li3 3.171(13) 14_545
Pr2 Ge2 3.1268(11) .
Pr2 Ge2 3.1268(11) 1_655
Pr2 Ge2 3.1268(11) 2
Pr2 Ge2 3.1268(11) 2_655
Pr2 Ge3 3.1593(19) .
Pr2 Ge1 3.3129(11) .
Pr2 Ge1 3.3129(11) 2
Pr2 Ge1 3.3129(11) 1_655
Pr2 Ge1 3.3129(11) 2_655
Pr2 Li1 3.659(12) .
Pr2 Li1 3.659(12) 1_655
Pr2 Li1 3.659(12) 2_655
Pr3 Ge3* 3.143(10) 2
Pr3 Li3 3.143(10) 2
Pr3 Ge3* 3.143(10) 1_655
Pr3 Li3 3.143(10) 1_655
Pr3 Ge3* 3.143(10) 2_655
Pr3 Li3 3.143(10) 2_655
Pr3 Li3 3.143(10) .
Pr3 Li2 3.149(14) 14_545
Pr3 Li2 3.149(14) 13
Pr3 Ge6 3.2026(10) 1_655
Pr3 Ge6 3.2026(10) 9_656
Pr4 Li1 3.121(15) 2
Pr4 Li1 3.121(15) .
Pr4 Ge2 3.1400(11) 13
Pr4 Ge2 3.1400(11) 14_545
Pr4 Ge2 3.1400(10) 14_445
Pr4 Ge2 3.1400(11) 13_455
Pr4 Li1 3.140(11) 14_445
Pr4 Li1 3.140(11) 13
Pr4 Li1 3.140(10) 13_455
Pr4 Li1 3.140(10) 14_545
Pr4 Ge3 3.1773(13) 1_455
Pr4 Ge3 3.1773(13) .
Pr5 Ge1 3.1277(11) 13
Pr5 Ge1 3.1277(11) 14_445
Pr5 Ge1 3.1277(11) 14_545
Pr5 Ge1 3.1277(11) 13_455
Pr5 Ge5 3.1432(19) .
Pr5 Ge2 3.3188(11) 14_445
Pr5 Ge2 3.3188(11) 13_455
Pr5 Ge2 3.3188(11) 14_545
Pr5 Ge2 3.3188(11) 13
Pr5 Li2 3.656(11) 13
Pr5 Li2 3.656(11) 14_545
Pr5 Li2 3.656(11) 13_455
Pr6 Ge6 3.1138(13) 13
Pr6 Ge6 3.1138(13) 5_444
Pr6 Ge6 3.1138(13) 13_455
Pr6 Ge6 3.1138(13) 5_544
Pr6 Ge4 3.1440(18) .
Pr6 Ge4 3.1442(18) 9
Pr6 Li3 3.569(11) 13
Pr6 Li3 3.569(11) 5_444
Pr6 Li3 3.569(11) 14_545
Pr6 Li3 3.569(11) 6_454
Pr6 Li3 3.569(11) 13_455
Pr6 Li3 3.569(11) 5_544
Ge1 Ge2 2.4836(15) .
Ge1 Ge1 2.506(2) 2
Ge1 Li2 2.580(14) .
Ge1 Pr5 3.1277(11) 13
Ge1 Pr5 3.1277(11) 13_455
Ge1 Pr1 3.1467(11) 1_455
Ge1 Pr2 3.3128(11) 1_455
Ge2 Ge2 2.510(2) 2_565
Ge2 Li1 2.575(14) .
Ge2 Pr2 3.1268(11) 1_455
Ge2 Pr4 3.1401(10) 13
Ge2 Pr4 3.1401(11) 13_455
Ge2 Pr5 3.3187(11) 13_455
Ge2 Pr5 3.3187(11) 13
Ge3 Li1 2.636(8) 2
Ge3 Li1 2.636(8) 1_655
Ge3 Li1 2.636(8) 2_655
Ge3 Li1 2.636(8) .
Ge3 Li1 2.729(15) 13
Ge3 Li1 2.729(15) 14_545
Ge3 Pr4 3.1772(13) 1_655
Ge4 Ge3* 2.654(8) 14_445
Ge4 Li3 2.654(8) 14_445
Ge4 Ge3* 2.654(8) 13
Ge4 Li3 2.654(8) 13
Ge4 Ge3* 2.654(8) 13_455
Ge4 Li3 2.654(8) 13_455
Ge4 Ge3* 2.654(8) 14_545
Ge4 Li3 2.654(8) 14_545
Ge4 Li2 2.706(15) .
Ge4 Li2 2.706(15) 2
Ge4 Pr1 3.1451(13) 1_455
Ge5 Li2 2.633(8) 14_445
Ge5 Li2 2.633(8) 13
Ge5 Li2 2.633(8) 13_455
Ge5 Li2 2.633(8) 14_545
Ge5 Li3 2.791(14) .
Ge5 Ge3* 2.791(14) 2
Ge5 Li3 2.791(14) 2
Ge5 Pr3 3.2088(14) 1_455
Ge6 Ge6 2.531(3) 9_556
Ge6 Ge3* 2.633(13) 10_556
Ge6 Li3 2.633(13) 10_556
Ge6 Li3 2.633(13) .
Ge6 Pr6 3.1138(13) 5
Ge6 Pr6 3.1138(13) 5_455
Ge6 Pr3 3.2025(10) 1_455
Ge6 Pr3 3.2025(10) 9_656
Ge6 Pr3 3.2025(10) 9_556
Li1 Li1 2.61(3) 2
Li1 Ge3 2.636(8) 1_455
Li1 Ge3 2.729(15) 13
Li1 Pr4 3.140(10) 13
Li1 Pr4 3.140(10) 13_455
Li1 Li1 3.27(2) 13
Li1 Li1 3.27(2) 13_455
Li1 Pr2 3.659(12) 1_455
Li2 Li2 2.61(3) 2_565
Li2 Ge5 2.633(8) 13
Li2 Ge5 2.633(8) 13_455
Li2 Pr1 3.139(11) 1_455
Li2 Pr3 3.149(14) 13
Li2 Li3 3.320(15) 13_455
Li2 Li3 3.320(15) 13
Li2 Pr5 3.657(11) 13
Li2 Pr5 3.657(11) 13_455
Li3 Ge3* 2.59(3) 2_565
Li3 Li3 2.59(3) 2_565
Li3 Ge4 2.654(8) 13
Li3 Ge4 2.654(8) 13_455
Li3 Pr3 3.143(10) 1_455
Li3 Pr1 3.171(13) 13
Li3 Li2 3.320(15) 13_455
Li3 Li2 3.320(15) 13
Li3 Pr6 3.569(11) 5
