#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:53:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179398 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/95/4329504.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329504
loop_
_publ_author_name
'Sheng-Ping Guo'
'Tae-Soo You'
'Ya-Ho Jung'
'Svilen Bobev'
_publ_section_title
;
 Synthesis, Crystal Chemistry, and Magnetic Properties of RE7Li8Ge10 and
 RE11Li12Ge16 (RE= La-Nd, Sm): New Members of the [REGe2]n[RELi2Ge]m
 Homologous Series
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6821
_journal_page_last               6829
_journal_paper_doi               10.1021/ic300566x
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         Nd11Li12Ge16
_chemical_formula_sum            'Ge16 Li12 Nd11'
_chemical_formula_weight         2831.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           71
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-I 2 2'
_symmetry_space_group_name_H-M   'I m m m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   4.4139(8)
_cell_length_b                   6.8688(13)
_cell_length_c                   51.973(10)
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      28.3
_cell_measurement_theta_min      0.8
_cell_volume                     1575.7(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0615
_diffrn_reflns_av_sigmaI/netI    0.0318
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       69
_diffrn_reflns_limit_l_min       -69
_diffrn_reflns_number            10521
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         0.78
_exptl_absorpt_coefficient_mu    32.722
_exptl_absorpt_correction_T_max  0.5606
_exptl_absorpt_correction_T_min  0.2442
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    5.967
_exptl_crystal_description       block
_exptl_crystal_F_000             2416
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_refine_diff_density_max         2.948
_refine_diff_density_min         -1.810
_refine_diff_density_rms         0.344
_refine_ls_extinction_coef       0.000445(18)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_matrix_type           full
_refine_ls_number_parameters     63
_refine_ls_number_reflns         1196
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0510
_refine_ls_R_factor_gt           0.0285
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0163P)²+27.9459P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0542
_refine_ls_wR_factor_ref         0.0669
_reflns_number_gt                848
_reflns_number_total             1196
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300566x_si_002_8.cif
_cod_data_source_block           VIII
_cod_database_code               4329504
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Nd1 Nd 0.5000 0.0000 0.103031(16) 0.0101(2) Uani 1 4 d S
Nd2 Nd 0.5000 0.0000 0.178735(16) 0.0086(2) Uani 1 4 d S
Nd3 Nd 0.5000 0.0000 0.463191(16) 0.0101(2) Uani 1 4 d S
Nd4 Nd 0.0000 0.0000 0.282874(16) 0.0098(2) Uani 1 4 d S
Nd5 Nd 0.0000 0.0000 0.358489(16) 0.0088(2) Uani 1 4 d S
Nd6 Nd 0.0000 0.0000 0.0000 0.0097(3) Uani 1 8 d S
Ge1 Ge 0.0000 0.18214(17) 0.13803(2) 0.0098(3) Uani 1 2 d S
Ge2 Ge 0.0000 0.31785(17) 0.18230(2) 0.0098(3) Uani 1 2 d S
Ge3 Ge 0.5000 0.0000 0.23926(3) 0.0104(4) Uani 1 4 d S
Ge4 Ge 0.0000 0.0000 0.06026(3) 0.0117(4) Uani 1 4 d S
Ge5 Ge 0.0000 0.0000 0.41874(3) 0.0110(4) Uani 1 4 d S
Ge6 Ge 0.0000 0.1844(2) 0.5000 0.0091(3) Uani 1 4 d S
Li1 Li 0.0000 0.188(3) 0.2287(4) 0.018(4) Uiso 1 2 d S
Li2 Li 0.0000 0.309(3) 0.0918(4) 0.015(4) Uiso 1 2 d S
Li3 Li 0.0000 0.313(3) 0.4521(3) 0.042(6) Uiso 0.955(6) 2 d SP
Ge3* Ge 0.0000 0.313(3) 0.4521(3) 0.042(6) Uiso 0.045(6) 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Li2 Nd1 Li2 158.4(7) 2 1_655
Li2 Nd1 Li2 90.1(5) 2 2_655
Li2 Nd1 Li2 85.9(5) 1_655 2_655
Li2 Nd1 Li2 85.9(5) 2 .
Li2 Nd1 Li2 90.1(5) 1_655 .
Li2 Nd1 Li2 158.4(7) 2_655 .
Li2 Nd1 Ge1 151.9(3) 2 1_655
Li2 Nd1 Ge1 48.4(3) 1_655 1_655
Li2 Nd1 Ge1 83.2(3) 2_655 1_655
Li2 Nd1 Ge1 109.7(3) . 1_655
Li2 Nd1 Ge1 109.7(3) 2 2_655
Li2 Nd1 Ge1 83.2(3) 1_655 2_655
Li2 Nd1 Ge1 48.4(3) 2_655 2_655
Li2 Nd1 Ge1 151.9(3) . 2_655
Ge1 Nd1 Ge1 47.25(4) 1_655 2_655
Li2 Nd1 Ge1 48.4(3) 2 2
Li2 Nd1 Ge1 151.9(3) 1_655 2
Li2 Nd1 Ge1 109.7(3) 2_655 2
Li2 Nd1 Ge1 83.2(3) . 2
Ge1 Nd1 Ge1 108.71(5) 1_655 2
Ge1 Nd1 Ge1 89.98(4) 2_655 2
Li2 Nd1 Ge1 83.2(3) 2 .
Li2 Nd1 Ge1 109.7(3) 1_655 .
Li2 Nd1 Ge1 151.9(3) 2_655 .
Li2 Nd1 Ge1 48.4(3) . .
Ge1 Nd1 Ge1 89.98(4) 1_655 .
Ge1 Nd1 Ge1 108.71(5) 2_655 .
Ge1 Nd1 Ge1 47.25(4) 2 .
Li2 Nd1 Ge4 111.5(3) 2 1_655
Li2 Nd1 Ge4 50.8(3) 1_655 1_655
Li2 Nd1 Ge4 50.8(3) 2_655 1_655
Li2 Nd1 Ge4 111.5(3) . 1_655
Ge1 Nd1 Ge4 85.15(3) 1_655 1_655
Ge1 Nd1 Ge4 85.15(3) 2_655 1_655
Ge1 Nd1 Ge4 155.73(2) 2 1_655
Ge1 Nd1 Ge4 155.73(2) . 1_655
Li2 Nd1 Ge4 50.8(3) 2 .
Li2 Nd1 Ge4 111.5(3) 1_655 .
Li2 Nd1 Ge4 111.5(3) 2_655 .
Li2 Nd1 Ge4 50.8(3) . .
Ge1 Nd1 Ge4 155.73(2) 1_655 .
Ge1 Nd1 Ge4 155.73(2) 2_655 .
Ge1 Nd1 Ge4 85.15(3) 2 .
Ge1 Nd1 Ge4 85.15(3) . .
Ge4 Nd1 Ge4 89.58(5) 1_655 .
Li2 Nd1 Ge3* 63.3(4) 2 14_545
Li2 Nd1 Ge3* 96.2(4) 1_655 14_545
Li2 Nd1 Ge3* 63.3(4) 2_655 14_545
Li2 Nd1 Ge3* 96.2(4) . 14_545
Ge1 Nd1 Ge3* 134.08(6) 1_655 14_545
Ge1 Nd1 Ge3* 111.6(2) 2_655 14_545
Ge1 Nd1 Ge3* 111.6(2) 2 14_545
Ge1 Nd1 Ge3* 134.08(6) . 14_545
Ge4 Nd1 Ge3* 49.64(12) 1_655 14_545
Ge4 Nd1 Ge3* 49.64(12) . 14_545
Li2 Nd1 Li3 63.3(4) 2 14_545
Li2 Nd1 Li3 96.2(4) 1_655 14_545
Li2 Nd1 Li3 63.3(4) 2_655 14_545
Li2 Nd1 Li3 96.2(4) . 14_545
Ge1 Nd1 Li3 134.08(6) 1_655 14_545
Ge1 Nd1 Li3 111.6(2) 2_655 14_545
Ge1 Nd1 Li3 111.6(2) 2 14_545
Ge1 Nd1 Li3 134.08(6) . 14_545
Ge4 Nd1 Li3 49.64(12) 1_655 14_545
Ge4 Nd1 Li3 49.64(12) . 14_545
Ge3* Nd1 Li3 0.0(6) 14_545 14_545
Ge2 Nd2 Ge2 173.18(5) 1_655 2
Ge2 Nd2 Ge2 89.18(3) 1_655 2_655
Ge2 Nd2 Ge2 90.41(3) 2 2_655
Ge2 Nd2 Ge2 90.41(3) 1_655 .
Ge2 Nd2 Ge2 89.18(3) 2 .
Ge2 Nd2 Ge2 173.17(5) 2_655 .
Ge2 Nd2 Ge3 86.59(3) 1_655 .
Ge2 Nd2 Ge3 86.59(3) 2 .
Ge2 Nd2 Ge3 86.59(3) 2_655 .
Ge2 Nd2 Ge3 86.58(3) . .
Ge2 Nd2 Ge1 104.26(3) 1_655 .
Ge2 Nd2 Ge1 80.20(3) 2 .
Ge2 Nd2 Ge1 141.09(4) 2_655 .
Ge2 Nd2 Ge1 45.42(3) . .
Ge3 Nd2 Ge1 129.82(2) . .
Ge2 Nd2 Ge1 141.09(4) 1_655 2
Ge2 Nd2 Ge1 45.42(3) 2 2
Ge2 Nd2 Ge1 104.26(3) 2_655 2
Ge2 Nd2 Ge1 80.21(3) . 2
Ge3 Nd2 Ge1 129.82(2) . 2
Ge1 Nd2 Ge1 44.51(4) . 2
Ge2 Nd2 Ge1 45.42(3) 1_655 1_655
Ge2 Nd2 Ge1 141.09(4) 2 1_655
Ge2 Nd2 Ge1 80.20(3) 2_655 1_655
Ge2 Nd2 Ge1 104.26(3) . 1_655
Ge3 Nd2 Ge1 129.82(2) . 1_655
Ge1 Nd2 Ge1 83.85(3) . 1_655
Ge1 Nd2 Ge1 100.35(4) 2 1_655
Ge2 Nd2 Ge1 80.20(3) 1_655 2_655
Ge2 Nd2 Ge1 104.26(3) 2 2_655
Ge2 Nd2 Ge1 45.42(3) 2_655 2_655
Ge2 Nd2 Ge1 141.09(4) . 2_655
Ge3 Nd2 Ge1 129.82(2) . 2_655
Ge1 Nd2 Ge1 100.35(4) . 2_655
Ge1 Nd2 Ge1 83.85(3) 2 2_655
Ge1 Nd2 Ge1 44.51(4) 1_655 2_655
Ge2 Nd2 Li1 43.9(3) 1_655 1_655
Ge2 Nd2 Li1 129.5(3) 2 1_655
Ge2 Nd2 Li1 77.1(3) 2_655 1_655
Ge2 Nd2 Li1 98.0(2) . 1_655
Ge3 Nd2 Li1 44.5(2) . 1_655
Ge1 Nd2 Li1 136.6(3) . 1_655
Ge1 Nd2 Li1 174.3(2) 2 1_655
Ge1 Nd2 Li1 85.3(2) 1_655 1_655
Ge1 Nd2 Li1 100.72(19) 2_655 1_655
Ge2 Nd2 Li1 77.1(3) 1_655 2_655
Ge2 Nd2 Li1 98.0(2) 2 2_655
Ge2 Nd2 Li1 43.9(3) 2_655 2_655
Ge2 Nd2 Li1 129.5(3) . 2_655
Ge3 Nd2 Li1 44.5(2) . 2_655
Ge1 Nd2 Li1 174.3(2) . 2_655
Ge1 Nd2 Li1 136.6(3) 2 2_655
Ge1 Nd2 Li1 100.72(19) 1_655 2_655
Ge1 Nd2 Li1 85.3(2) 2_655 2_655
Li1 Nd2 Li1 41.4(6) 1_655 2_655
Ge2 Nd2 Li1 129.5(3) 1_655 2
Ge2 Nd2 Li1 43.9(3) 2 2
Ge2 Nd2 Li1 98.0(2) 2_655 2
Ge2 Nd2 Li1 77.1(3) . 2
Ge3 Nd2 Li1 44.5(2) . 2
Ge1 Nd2 Li1 100.72(19) . 2
Ge1 Nd2 Li1 85.3(2) 2 2
Ge1 Nd2 Li1 174.3(2) 1_655 2
Ge1 Nd2 Li1 136.6(3) 2_655 2
Li1 Nd2 Li1 89.1(5) 1_655 2
Li1 Nd2 Li1 74.5(4) 2_655 2
Ge3* Nd3 Li3 0.0(8) 2 2
Ge3* Nd3 Ge3* 158.9(6) 2 1_655
Li3 Nd3 Ge3* 158.9(6) 2 1_655
Ge3* Nd3 Li3 158.9(6) 2 1_655
Li3 Nd3 Li3 158.9(6) 2 1_655
Ge3* Nd3 Li3 0.0(8) 1_655 1_655
Ge3* Nd3 Ge3* 89.6(5) 2 2_655
Li3 Nd3 Ge3* 89.6(5) 2 2_655
Ge3* Nd3 Ge3* 86.6(5) 1_655 2_655
Li3 Nd3 Ge3* 86.6(5) 1_655 2_655
Ge3* Nd3 Li3 89.6(5) 2 2_655
Li3 Nd3 Li3 89.6(5) 2 2_655
Ge3* Nd3 Li3 86.6(5) 1_655 2_655
Li3 Nd3 Li3 86.6(5) 1_655 2_655
Ge3* Nd3 Li3 0.0(8) 2_655 2_655
Ge3* Nd3 Li3 86.6(5) 2 .
Li3 Nd3 Li3 86.6(5) 2 .
Ge3* Nd3 Li3 89.6(5) 1_655 .
Li3 Nd3 Li3 89.6(5) 1_655 .
Ge3* Nd3 Li3 158.9(6) 2_655 .
Li3 Nd3 Li3 158.9(6) 2_655 .
Ge3* Nd3 Li2 63.1(4) 2 14_545
Li3 Nd3 Li2 63.1(4) 2 14_545
Ge3* Nd3 Li2 96.8(4) 1_655 14_545
Li3 Nd3 Li2 96.8(4) 1_655 14_545
Ge3* Nd3 Li2 63.1(4) 2_655 14_545
Li3 Nd3 Li2 63.1(4) 2_655 14_545
Li3 Nd3 Li2 96.8(4) . 14_545
Ge3* Nd3 Li2 96.8(4) 2 13
Li3 Nd3 Li2 96.8(4) 2 13
Ge3* Nd3 Li2 63.1(4) 1_655 13
Li3 Nd3 Li2 63.1(4) 1_655 13
Ge3* Nd3 Li2 96.8(4) 2_655 13
Li3 Nd3 Li2 96.8(4) 2_655 13
Li3 Nd3 Li2 63.1(4) . 13
Li2 Nd3 Li2 49.2(7) 14_545 13
Ge3* Nd3 Ge6 150.6(3) 2 1_655
Li3 Nd3 Ge6 150.6(3) 2 1_655
Ge3* Nd3 Ge6 49.4(3) 1_655 1_655
Li3 Nd3 Ge6 49.4(3) 1_655 1_655
Ge3* Nd3 Ge6 84.0(2) 2_655 1_655
Li3 Nd3 Ge6 84.0(2) 2_655 1_655
Li3 Nd3 Ge6 109.0(3) . 1_655
Li2 Nd3 Ge6 135.40(6) 14_545 1_655
Li2 Nd3 Ge6 112.4(2) 13 1_655
Ge3* Nd3 Ge6 109.0(3) 2 9_656
Li3 Nd3 Ge6 109.0(3) 2 9_656
Ge3* Nd3 Ge6 84.0(2) 1_655 9_656
Li3 Nd3 Ge6 84.0(2) 1_655 9_656
Ge3* Nd3 Ge6 49.4(3) 2_655 9_656
Li3 Nd3 Ge6 49.4(3) 2_655 9_656
Li3 Nd3 Ge6 150.6(3) . 9_656
Li2 Nd3 Ge6 112.4(2) 14_545 9_656
Li2 Nd3 Ge6 135.40(6) 13 9_656
Ge6 Nd3 Ge6 46.90(6) 1_655 9_656
Li1 Nd4 Li1 49.2(7) . 2
Li1 Nd4 Ge2 111.2(2) . 13
Li1 Nd4 Ge2 134.05(7) 2 13
Li1 Nd4 Ge2 134.05(7) . 14_545
Li1 Nd4 Ge2 111.2(2) 2 14_545
Ge2 Nd4 Ge2 47.34(4) 13 14_545
Li1 Nd4 Ge2 134.05(7) . 14_445
Li1 Nd4 Ge2 111.2(2) 2 14_445
Ge2 Nd4 Ge2 108.98(5) 13 14_445
Ge2 Nd4 Ge2 90.17(4) 14_545 14_445
Li1 Nd4 Ge2 111.2(2) . 13_455
Li1 Nd4 Ge2 134.05(7) 2 13_455
Ge2 Nd4 Ge2 90.17(4) 13 13_455
Ge2 Nd4 Ge2 108.98(5) 14_545 13_455
Ge2 Nd4 Ge2 47.34(4) 14_445 13_455
Li1 Nd4 Li1 96.3(3) . 14_445
Li1 Nd4 Li1 62.6(5) 2 14_445
Ge2 Nd4 Li1 152.2(4) 13 14_445
Ge2 Nd4 Li1 109.6(3) 14_545 14_445
Ge2 Nd4 Li1 48.6(3) 14_445 14_445
Ge2 Nd4 Li1 83.6(3) 13_455 14_445
Li1 Nd4 Li1 62.6(5) . 13
Li1 Nd4 Li1 96.3(3) 2 13
Ge2 Nd4 Li1 48.6(3) 13 13
Ge2 Nd4 Li1 83.6(3) 14_545 13
Ge2 Nd4 Li1 152.2(4) 14_445 13
Ge2 Nd4 Li1 109.6(3) 13_455 13
Li1 Nd4 Li1 157.8(7) 14_445 13
Li1 Nd4 Li1 96.3(3) . 14_545
Li1 Nd4 Li1 62.6(5) 2 14_545
Ge2 Nd4 Li1 83.6(3) 13 14_545
Ge2 Nd4 Li1 48.6(3) 14_545 14_545
Ge2 Nd4 Li1 109.6(3) 14_445 14_545
Ge2 Nd4 Li1 152.2(4) 13_455 14_545
Li1 Nd4 Li1 89.4(5) 14_445 14_545
Li1 Nd4 Li1 86.3(5) 13 14_545
Li1 Nd4 Li1 62.6(5) . 13_455
Li1 Nd4 Li1 96.3(3) 2 13_455
Ge2 Nd4 Li1 109.6(3) 13 13_455
Ge2 Nd4 Li1 152.2(4) 14_545 13_455
Ge2 Nd4 Li1 83.6(3) 14_445 13_455
Ge2 Nd4 Li1 48.6(3) 13_455 13_455
Li1 Nd4 Li1 86.3(5) 14_445 13_455
Li1 Nd4 Li1 89.4(5) 13 13_455
Li1 Nd4 Li1 157.8(7) 14_545 13_455
Li1 Nd4 Ge3 49.35(15) . .
Li1 Nd4 Ge3 49.35(15) 2 .
Ge2 Nd4 Ge3 85.54(3) 13 .
Ge2 Nd4 Ge3 85.54(3) 14_545 .
Ge2 Nd4 Ge3 155.53(2) 14_445 .
Ge2 Nd4 Ge3 155.53(2) 13_455 .
Li1 Nd4 Ge3 110.7(3) 14_445 .
Li1 Nd4 Ge3 51.0(3) 13 .
Li1 Nd4 Ge3 51.0(3) 14_545 .
Li1 Nd4 Ge3 110.7(3) 13_455 .
Li1 Nd4 Ge3 49.35(15) . 1_455
Li1 Nd4 Ge3 49.35(15) 2 1_455
Ge2 Nd4 Ge3 155.53(2) 13 1_455
Ge2 Nd4 Ge3 155.53(2) 14_545 1_455
Ge2 Nd4 Ge3 85.54(3) 14_445 1_455
Ge2 Nd4 Ge3 85.54(3) 13_455 1_455
Li1 Nd4 Ge3 51.0(3) 14_445 1_455
Li1 Nd4 Ge3 110.7(3) 13 1_455
Li1 Nd4 Ge3 110.7(3) 14_545 1_455
Li1 Nd4 Ge3 51.0(3) 13_455 1_455
Ge3 Nd4 Ge3 88.47(5) . 1_455
Ge1 Nd5 Ge1 173.33(5) 13 14_445
Ge1 Nd5 Ge1 89.19(3) 13 14_545
Ge1 Nd5 Ge1 90.42(3) 14_445 14_545
Ge1 Nd5 Ge1 90.42(3) 13 13_455
Ge1 Nd5 Ge1 89.19(3) 14_445 13_455
Ge1 Nd5 Ge1 173.33(5) 14_545 13_455
Ge1 Nd5 Ge5 86.67(3) 13 .
Ge1 Nd5 Ge5 86.67(3) 14_445 .
Ge1 Nd5 Ge5 86.67(3) 14_545 .
Ge1 Nd5 Ge5 86.67(3) 13_455 .
Ge1 Nd5 Ge2 140.97(4) 13 14_445
Ge1 Nd5 Ge2 45.40(3) 14_445 14_445
Ge1 Nd5 Ge2 104.20(3) 14_545 14_445
Ge1 Nd5 Ge2 80.17(3) 13_455 14_445
Ge5 Nd5 Ge2 129.88(2) . 14_445
Ge1 Nd5 Ge2 104.20(3) 13 13_455
Ge1 Nd5 Ge2 80.17(3) 14_445 13_455
Ge1 Nd5 Ge2 140.97(4) 14_545 13_455
Ge1 Nd5 Ge2 45.40(3) 13_455 13_455
Ge5 Nd5 Ge2 129.88(2) . 13_455
Ge2 Nd5 Ge2 44.48(4) 14_445 13_455
Ge1 Nd5 Ge2 80.17(3) 13 14_545
Ge1 Nd5 Ge2 104.20(3) 14_445 14_545
Ge1 Nd5 Ge2 45.40(3) 14_545 14_545
Ge1 Nd5 Ge2 140.97(4) 13_455 14_545
Ge5 Nd5 Ge2 129.88(2) . 14_545
Ge2 Nd5 Ge2 83.76(3) 14_445 14_545
Ge2 Nd5 Ge2 100.24(4) 13_455 14_545
Ge1 Nd5 Ge2 45.40(3) 13 13
Ge1 Nd5 Ge2 140.97(4) 14_445 13
Ge1 Nd5 Ge2 80.17(3) 14_545 13
Ge1 Nd5 Ge2 104.20(3) 13_455 13
Ge5 Nd5 Ge2 129.88(2) . 13
Ge2 Nd5 Ge2 100.24(4) 14_445 13
Ge2 Nd5 Ge2 83.76(3) 13_455 13
Ge2 Nd5 Ge2 44.48(4) 14_545 13
Ge1 Nd5 Li2 43.6(3) 13 13
Ge1 Nd5 Li2 129.9(3) 14_445 13
Ge1 Nd5 Li2 77.4(3) 14_545 13
Ge1 Nd5 Li2 97.8(2) 13_455 13
Ge5 Nd5 Li2 44.8(2) . 13
Ge2 Nd5 Li2 174.6(2) 14_445 13
Ge2 Nd5 Li2 136.3(3) 13_455 13
Ge2 Nd5 Li2 100.74(18) 14_545 13
Ge2 Nd5 Li2 85.1(2) 13 13
Ge1 Nd5 Li2 77.4(3) 13 14_545
Ge1 Nd5 Li2 97.8(2) 14_445 14_545
Ge1 Nd5 Li2 43.6(3) 14_545 14_545
Ge1 Nd5 Li2 129.9(3) 13_455 14_545
Ge5 Nd5 Li2 44.8(2) . 14_545
Ge2 Nd5 Li2 136.3(3) 14_445 14_545
Ge2 Nd5 Li2 174.6(2) 13_455 14_545
Ge2 Nd5 Li2 85.1(2) 14_545 14_545
Ge2 Nd5 Li2 100.74(18) 13 14_545
Li2 Nd5 Li2 42.2(6) 13 14_545
Ge1 Nd5 Li2 97.8(2) 13 13_455
Ge1 Nd5 Li2 77.4(3) 14_445 13_455
Ge1 Nd5 Li2 129.9(3) 14_545 13_455
Ge1 Nd5 Li2 43.6(3) 13_455 13_455
Ge5 Nd5 Li2 44.8(2) . 13_455
Ge2 Nd5 Li2 100.74(18) 14_445 13_455
Ge2 Nd5 Li2 85.1(2) 13_455 13_455
Ge2 Nd5 Li2 174.6(2) 14_545 13_455
Ge2 Nd5 Li2 136.3(3) 13 13_455
Li2 Nd5 Li2 74.6(4) 13 13_455
Li2 Nd5 Li2 89.6(5) 14_545 13_455
Ge6 Nd6 Ge6 180.00(4) 13 5_444
Ge6 Nd6 Ge6 91.03(5) 13 13_455
Ge6 Nd6 Ge6 88.97(5) 5_444 13_455
Ge6 Nd6 Ge6 88.97(5) 13 5_544
Ge6 Nd6 Ge6 91.03(5) 5_444 5_544
Ge6 Nd6 Ge6 180.0 13_455 5_544
Ge6 Nd6 Ge4 90.0 13 .
Ge6 Nd6 Ge4 90.0 5_444 .
Ge6 Nd6 Ge4 90.0 13_455 .
Ge6 Nd6 Ge4 90.0 5_544 .
Ge6 Nd6 Ge4 90.0 13 9
Ge6 Nd6 Ge4 90.0 5_444 9
Ge6 Nd6 Ge4 90.0 13_455 9
Ge6 Nd6 Ge4 90.0 5_544 9
Ge4 Nd6 Ge4 180.0 . 9
Ge6 Nd6 Li3 46.0(3) 13 13
Ge6 Nd6 Li3 134.0(3) 5_444 13
Ge6 Nd6 Li3 100.9(2) 13_455 13
Ge6 Nd6 Li3 79.1(2) 5_544 13
Ge4 Nd6 Li3 45.8(2) . 13
Ge4 Nd6 Li3 134.2(2) 9 13
Ge6 Nd6 Li3 134.0(3) 13 5_444
Ge6 Nd6 Li3 46.0(3) 5_444 5_444
Ge6 Nd6 Li3 79.1(2) 13_455 5_444
Ge6 Nd6 Li3 100.9(2) 5_544 5_444
Ge4 Nd6 Li3 134.2(2) . 5_444
Ge4 Nd6 Li3 45.8(2) 9 5_444
Li3 Nd6 Li3 180.0(4) 13 5_444
Ge6 Nd6 Li3 79.1(2) 13 14_545
Ge6 Nd6 Li3 100.9(2) 5_444 14_545
Ge6 Nd6 Li3 134.0(3) 13_455 14_545
Ge6 Nd6 Li3 46.0(3) 5_544 14_545
Ge4 Nd6 Li3 45.8(2) . 14_545
Ge4 Nd6 Li3 134.2(2) 9 14_545
Li3 Nd6 Li3 42.3(5) 13 14_545
Li3 Nd6 Li3 137.7(5) 5_444 14_545
Ge6 Nd6 Li3 100.9(2) 13 6_454
Ge6 Nd6 Li3 79.1(2) 5_444 6_454
Ge6 Nd6 Li3 46.0(3) 13_455 6_454
Ge6 Nd6 Li3 134.0(3) 5_544 6_454
Ge4 Nd6 Li3 134.2(2) . 6_454
Ge4 Nd6 Li3 45.8(2) 9 6_454
Li3 Nd6 Li3 137.7(5) 13 6_454
Li3 Nd6 Li3 42.3(5) 5_444 6_454
Li3 Nd6 Li3 180.0(4) 14_545 6_454
Ge6 Nd6 Li3 100.9(2) 13 13_455
Ge6 Nd6 Li3 79.1(2) 5_444 13_455
Ge6 Nd6 Li3 46.0(3) 13_455 13_455
Ge6 Nd6 Li3 134.0(3) 5_544 13_455
Ge4 Nd6 Li3 45.8(2) . 13_455
Ge4 Nd6 Li3 134.2(2) 9 13_455
Li3 Nd6 Li3 76.5(3) 13 13_455
Li3 Nd6 Li3 103.5(3) 5_444 13_455
Li3 Nd6 Li3 91.5(4) 14_545 13_455
Li3 Nd6 Li3 88.5(4) 6_454 13_455
Ge6 Nd6 Li3 79.1(2) 13 5_544
Ge6 Nd6 Li3 100.9(2) 5_444 5_544
Ge6 Nd6 Li3 134.0(3) 13_455 5_544
Ge6 Nd6 Li3 46.0(3) 5_544 5_544
Ge4 Nd6 Li3 134.2(2) . 5_544
Ge4 Nd6 Li3 45.8(2) 9 5_544
Li3 Nd6 Li3 103.5(3) 13 5_544
Li3 Nd6 Li3 76.5(3) 5_444 5_544
Li3 Nd6 Li3 88.5(4) 14_545 5_544
Li3 Nd6 Li3 91.5(4) 6_454 5_544
Li3 Nd6 Li3 180.0(4) 13_455 5_544
Ge2 Ge1 Ge1 112.06(4) . 2
Ge2 Ge1 Li2 138.0(4) . .
Ge1 Ge1 Li2 110.0(4) 2 .
Ge2 Ge1 Nd5 71.49(3) . 13
Ge1 Ge1 Nd5 134.596(17) 2 13
Li2 Ge1 Nd5 79.3(3) . 13
Ge2 Ge1 Nd5 71.49(3) . 13_455
Ge1 Ge1 Nd5 134.596(17) 2 13_455
Li2 Ge1 Nd5 79.3(3) . 13_455
Nd5 Ge1 Nd5 90.42(3) 13 13_455
Ge2 Ge1 Nd1 133.68(2) . .
Ge1 Ge1 Nd1 66.37(2) 2 .
Li2 Ge1 Nd1 65.7(3) . .
Nd5 Ge1 Nd1 79.252(18) 13 .
Nd5 Ge1 Nd1 144.78(5) 13_455 .
Ge2 Ge1 Nd1 133.68(2) . 1_455
Ge1 Ge1 Nd1 66.37(2) 2 1_455
Li2 Ge1 Nd1 65.7(3) . 1_455
Nd5 Ge1 Nd1 144.78(5) 13 1_455
Nd5 Ge1 Nd1 79.252(18) 13_455 1_455
Nd1 Ge1 Nd1 89.97(4) . 1_455
Ge2 Ge1 Nd2 63.17(3) . 1_455
Ge1 Ge1 Nd2 67.74(2) 2 1_455
Li2 Ge1 Nd2 136.99(9) . 1_455
Nd5 Ge1 Nd2 134.66(4) 13 1_455
Nd5 Ge1 Nd2 75.791(19) 13_455 1_455
Nd1 Ge1 Nd2 133.93(4) . 1_455
Nd1 Ge1 Nd2 75.47(2) 1_455 1_455
Ge2 Ge1 Nd2 63.17(3) . .
Ge1 Ge1 Nd2 67.75(2) 2 .
Li2 Ge1 Nd2 136.99(9) . .
Nd5 Ge1 Nd2 75.79(2) 13 .
Nd5 Ge1 Nd2 134.66(4) 13_455 .
Nd1 Ge1 Nd2 75.47(2) . .
Nd1 Ge1 Nd2 133.93(4) 1_455 .
Nd2 Ge1 Nd2 83.85(3) 1_455 .
Ge1 Ge2 Ge2 112.05(4) . 2_565
Ge1 Ge2 Li1 137.6(5) . .
Ge2 Ge2 Li1 110.3(4) 2_565 .
Ge1 Ge2 Nd2 71.41(3) . .
Ge2 Ge2 Nd2 134.590(17) 2_565 .
Li1 Ge2 Nd2 79.2(3) . .
Ge1 Ge2 Nd2 71.41(3) . 1_455
Ge2 Ge2 Nd2 134.589(17) 2_565 1_455
Li1 Ge2 Nd2 79.2(3) . 1_455
Nd2 Ge2 Nd2 90.41(3) . 1_455
Ge1 Ge2 Nd4 133.55(2) . 13
Ge2 Ge2 Nd4 66.33(2) 2_565 13
Li1 Ge2 Nd4 66.1(3) . 13
Nd2 Ge2 Nd4 79.274(19) . 13
Nd2 Ge2 Nd4 144.99(4) 1_455 13
Ge1 Ge2 Nd4 133.55(2) . 13_455
Ge2 Ge2 Nd4 66.33(2) 2_565 13_455
Li1 Ge2 Nd4 66.1(3) . 13_455
Nd2 Ge2 Nd4 144.98(4) . 13_455
Nd2 Ge2 Nd4 79.275(19) 1_455 13_455
Nd4 Ge2 Nd4 90.17(4) 13 13_455
Ge1 Ge2 Nd5 63.12(3) . 13_455
Ge2 Ge2 Nd5 67.76(2) 2_565 13_455
Li1 Ge2 Nd5 137.12(9) . 13_455
Nd2 Ge2 Nd5 134.52(4) . 13_455
Nd2 Ge2 Nd5 75.744(19) 1_455 13_455
Nd4 Ge2 Nd5 133.89(4) 13 13_455
Nd4 Ge2 Nd5 75.39(2) 13_455 13_455
Ge1 Ge2 Nd5 63.12(3) . 13
Ge2 Ge2 Nd5 67.76(2) 2_565 13
Li1 Ge2 Nd5 137.12(9) . 13
Nd2 Ge2 Nd5 75.745(19) . 13
Nd2 Ge2 Nd5 134.52(4) 1_455 13
Nd4 Ge2 Nd5 75.39(2) 13 13
Nd4 Ge2 Nd5 133.89(4) 13_455 13
Nd5 Ge2 Nd5 83.75(3) 13_455 13
Li1 Ge3 Li1 59.1(8) . 2
Li1 Ge3 Li1 115.2(7) . 1_655
Li1 Ge3 Li1 155.8(9) 2 1_655
Li1 Ge3 Li1 155.8(9) . 2_655
Li1 Ge3 Li1 115.2(7) 2 2_655
Li1 Ge3 Li1 59.1(8) 1_655 2_655
Li1 Ge3 Li1 74.8(5) . 13
Li1 Ge3 Li1 121.2(3) 2 13
Li1 Ge3 Li1 74.8(5) 1_655 13
Li1 Ge3 Li1 121.2(3) 2_655 13
Li1 Ge3 Li1 121.2(3) . 14_545
Li1 Ge3 Li1 74.8(5) 2 14_545
Li1 Ge3 Li1 121.2(3) 1_655 14_545
Li1 Ge3 Li1 74.8(5) 2_655 14_545
Li1 Ge3 Li1 104.4(8) 13 14_545
Li1 Ge3 Nd2 77.9(4) . .
Li1 Ge3 Nd2 77.9(4) 2 .
Li1 Ge3 Nd2 77.9(4) 1_655 .
Li1 Ge3 Nd2 77.9(4) 2_655 .
Li1 Ge3 Nd2 127.8(4) 13 .
Li1 Ge3 Nd2 127.8(4) 14_545 .
Li1 Ge3 Nd4 64.0(4) . .
Li1 Ge3 Nd4 64.0(4) 2 .
Li1 Ge3 Nd4 137.7(4) 1_655 .
Li1 Ge3 Nd4 137.7(4) 2_655 .
Li1 Ge3 Nd4 64.0(3) 13 .
Li1 Ge3 Nd4 64.0(3) 14_545 .
Nd2 Ge3 Nd4 135.77(2) . .
Li1 Ge3 Nd4 137.6(4) . 1_655
Li1 Ge3 Nd4 137.7(4) 2 1_655
Li1 Ge3 Nd4 64.0(4) 1_655 1_655
Li1 Ge3 Nd4 64.0(4) 2_655 1_655
Li1 Ge3 Nd4 64.0(3) 13 1_655
Li1 Ge3 Nd4 64.0(3) 14_545 1_655
Nd2 Ge3 Nd4 135.77(2) . 1_655
Nd4 Ge3 Nd4 88.47(5) . 1_655
Ge3* Ge4 Li3 0.0(10) 14_445 14_445
Ge3* Ge4 Ge3* 151.7(7) 14_445 13
Li3 Ge4 Ge3* 151.7(7) 14_445 13
Ge3* Ge4 Li3 151.7(7) 14_445 13
Li3 Ge4 Li3 151.7(7) 14_445 13
Ge3* Ge4 Li3 0.0(7) 13 13
Ge3* Ge4 Ge3* 58.4(7) 14_445 13_455
Li3 Ge4 Ge3* 58.4(7) 14_445 13_455
Ge3* Ge4 Ge3* 113.8(6) 13 13_455
Li3 Ge4 Ge3* 113.8(6) 13 13_455
Ge3* Ge4 Li3 58.4(7) 14_445 13_455
Li3 Ge4 Li3 58.4(7) 14_445 13_455
Ge3* Ge4 Li3 113.8(6) 13 13_455
Li3 Ge4 Li3 113.8(6) 13 13_455
Ge3* Ge4 Li3 0.0(7) 13_455 13_455
Ge3* Ge4 Ge3* 113.8(6) 14_445 14_545
Li3 Ge4 Ge3* 113.8(6) 14_445 14_545
Ge3* Ge4 Ge3* 58.4(7) 13 14_545
Li3 Ge4 Ge3* 58.4(7) 13 14_545
Ge3* Ge4 Ge3* 151.7(7) 13_455 14_545
Li3 Ge4 Ge3* 151.7(7) 13_455 14_545
Ge3* Ge4 Li3 113.8(6) 14_445 14_545
Li3 Ge4 Li3 113.8(6) 14_445 14_545
Ge3* Ge4 Li3 58.4(7) 13 14_545
Li3 Ge4 Li3 58.4(7) 13 14_545
Ge3* Ge4 Li3 151.7(7) 13_455 14_545
Li3 Ge4 Li3 151.7(7) 13_455 14_545
Ge3* Ge4 Li3 0.0(10) 14_545 14_545
Ge3* Ge4 Li2 122.4(3) 14_445 .
Li3 Ge4 Li2 122.4(3) 14_445 .
Ge3* Ge4 Li2 76.3(4) 13 .
Li3 Ge4 Li2 76.3(4) 13 .
Ge3* Ge4 Li2 76.3(4) 13_455 .
Li3 Ge4 Li2 76.3(4) 13_455 .
Ge3* Ge4 Li2 122.4(3) 14_545 .
Li3 Ge4 Li2 122.4(3) 14_545 .
Ge3* Ge4 Li2 76.3(4) 14_445 2
Li3 Ge4 Li2 76.3(4) 14_445 2
Ge3* Ge4 Li2 122.4(3) 13 2
Li3 Ge4 Li2 122.4(3) 13 2
Ge3* Ge4 Li2 122.4(3) 13_455 2
Li3 Ge4 Li2 122.4(3) 13_455 2
Ge3* Ge4 Li2 76.3(4) 14_545 2
Li3 Ge4 Li2 76.3(4) 14_545 2
Li2 Ge4 Li2 104.7(8) . 2
Ge3* Ge4 Nd6 75.8(4) 14_445 .
Li3 Ge4 Nd6 75.8(4) 14_445 .
Ge3* Ge4 Nd6 75.8(4) 13 .
Li3 Ge4 Nd6 75.8(4) 13 .
Ge3* Ge4 Nd6 75.8(4) 13_455 .
Li3 Ge4 Nd6 75.8(4) 13_455 .
Ge3* Ge4 Nd6 75.8(4) 14_545 .
Li3 Ge4 Nd6 75.8(4) 14_545 .
Li2 Ge4 Nd6 127.7(4) . .
Li2 Ge4 Nd6 127.7(4) 2 .
Ge3* Ge4 Nd1 65.4(3) 14_445 1_455
Li3 Ge4 Nd1 65.4(3) 14_445 1_455
Ge3* Ge4 Nd1 139.8(4) 13 1_455
Li3 Ge4 Nd1 139.8(4) 13 1_455
Ge3* Ge4 Nd1 65.4(3) 13_455 1_455
Li3 Ge4 Nd1 65.4(3) 13_455 1_455
Ge3* Ge4 Nd1 139.8(4) 14_545 1_455
Li3 Ge4 Nd1 139.8(4) 14_545 1_455
Li2 Ge4 Nd1 64.3(3) . 1_455
Li2 Ge4 Nd1 64.3(3) 2 1_455
Nd6 Ge4 Nd1 135.21(2) . 1_455
Li2 Ge5 Li2 155.9(8) 14_445 13
Li2 Ge5 Li2 59.9(7) 14_445 13_455
Li2 Ge5 Li2 114.5(7) 13 13_455
Li2 Ge5 Li2 114.5(7) 14_445 14_545
Li2 Ge5 Li2 59.9(7) 13 14_545
Li2 Ge5 Li2 155.9(8) 13_455 14_545
Li2 Ge5 Li3 121.3(4) 14_445 .
Li2 Ge5 Li3 75.1(5) 13 .
Li2 Ge5 Li3 75.1(5) 13_455 .
Li2 Ge5 Li3 121.3(4) 14_545 .
Li2 Ge5 Ge3* 75.1(5) 14_445 2
Li2 Ge5 Ge3* 121.3(4) 13 2
Li2 Ge5 Ge3* 121.3(4) 13_455 2
Li2 Ge5 Ge3* 75.1(5) 14_545 2
Li3 Ge5 Ge3* 102.1(7) . 2
Li2 Ge5 Li3 75.1(5) 14_445 2
Li2 Ge5 Li3 121.3(4) 13 2
Li2 Ge5 Li3 121.3(4) 13_455 2
Li2 Ge5 Li3 75.1(5) 14_545 2
Li3 Ge5 Li3 102.1(7) . 2
Ge3* Ge5 Li3 0.0(7) 2 2
Li2 Ge5 Nd5 77.9(4) 14_445 .
Li2 Ge5 Nd5 77.9(4) 13 .
Li2 Ge5 Nd5 77.9(4) 13_455 .
Li2 Ge5 Nd5 77.9(4) 14_545 .
Li3 Ge5 Nd5 128.9(4) . .
Ge3* Ge5 Nd5 128.9(4) 2 .
Li3 Ge5 Nd5 128.9(4) 2 .
Li2 Ge5 Nd3 64.5(4) 14_445 1_455
Li2 Ge5 Nd3 137.1(4) 13 1_455
Li2 Ge5 Nd3 64.5(4) 13_455 1_455
Li2 Ge5 Nd3 137.1(4) 14_545 1_455
Li3 Ge5 Nd3 63.0(2) . 1_455
Ge3* Ge5 Nd3 63.0(2) 2 1_455
Li3 Ge5 Nd3 63.0(2) 2 1_455
Nd5 Ge5 Nd3 136.31(2) . 1_455
Li2 Ge5 Nd3 137.1(4) 14_445 .
Li2 Ge5 Nd3 64.5(4) 13 .
Li2 Ge5 Nd3 137.1(4) 13_455 .
Li2 Ge5 Nd3 64.5(4) 14_545 .
Li3 Ge5 Nd3 63.0(2) . .
Ge3* Ge5 Nd3 63.0(2) 2 .
Li3 Ge5 Nd3 63.0(2) 2 .
Nd5 Ge5 Nd3 136.31(2) . .
Nd3 Ge5 Nd3 87.39(5) 1_455 .
Ge6 Ge6 Ge3* 109.5(4) 9_556 10_556
Ge6 Ge6 Li3 109.5(4) 9_556 10_556
Ge3* Ge6 Li3 0.0(8) 10_556 10_556
Ge6 Ge6 Li3 109.5(4) 9_556 .
Ge3* Ge6 Li3 141.0(8) 10_556 .
Li3 Ge6 Li3 141.0(8) 10_556 .
Ge6 Ge6 Nd6 134.48(2) 9_556 5
Ge3* Ge6 Nd6 76.5(3) 10_556 5
Li3 Ge6 Nd6 76.5(3) 10_556 5
Li3 Ge6 Nd6 76.5(3) . 5
Ge6 Ge6 Nd6 134.48(2) 9_556 5_455
Ge3* Ge6 Nd6 76.5(3) 10_556 5_455
Li3 Ge6 Nd6 76.5(3) 10_556 5_455
Li3 Ge6 Nd6 76.5(3) . 5_455
Nd6 Ge6 Nd6 91.03(5) 5 5_455
Ge6 Ge6 Nd3 66.55(3) 9_556 .
Ge3* Ge6 Nd3 134.37(10) 10_556 .
Li3 Ge6 Nd3 134.37(10) 10_556 .
Li3 Ge6 Nd3 64.3(2) . .
Nd6 Ge6 Nd3 77.541(13) 5 .
Nd6 Ge6 Nd3 140.66(3) 5_455 .
Ge6 Ge6 Nd3 66.55(3) 9_556 1_455
Ge3* Ge6 Nd3 134.38(10) 10_556 1_455
Li3 Ge6 Nd3 134.38(10) 10_556 1_455
Li3 Ge6 Nd3 64.3(2) . 1_455
Nd6 Ge6 Nd3 140.66(3) 5 1_455
Nd6 Ge6 Nd3 77.541(13) 5_455 1_455
Nd3 Ge6 Nd3 87.77(3) . 1_455
Ge6 Ge6 Nd3 66.55(3) 9_556 9_656
Ge3* Ge6 Nd3 64.3(2) 10_556 9_656
Li3 Ge6 Nd3 64.3(2) 10_556 9_656
Li3 Ge6 Nd3 134.38(10) . 9_656
Nd6 Ge6 Nd3 77.541(14) 5 9_656
Nd6 Ge6 Nd3 140.66(3) 5_455 9_656
Nd3 Ge6 Nd3 73.87(3) . 9_656
Nd3 Ge6 Nd3 133.10(5) 1_455 9_656
Ge6 Ge6 Nd3 66.55(3) 9_556 9_556
Ge3* Ge6 Nd3 64.3(2) 10_556 9_556
Li3 Ge6 Nd3 64.3(2) 10_556 9_556
Li3 Ge6 Nd3 134.38(10) . 9_556
Nd6 Ge6 Nd3 140.66(3) 5 9_556
Nd6 Ge6 Nd3 77.541(13) 5_455 9_556
Nd3 Ge6 Nd3 133.10(5) . 9_556
Nd3 Ge6 Nd3 73.87(3) 1_455 9_556
Nd3 Ge6 Nd3 87.77(3) 9_656 9_556
Ge2 Li1 Li1 110.3(4) . 2
Ge2 Li1 Ge3 111.6(5) . 1_455
Li1 Li1 Ge3 60.4(4) 2 1_455
Ge2 Li1 Ge3 111.6(5) . .
Li1 Li1 Ge3 60.4(4) 2 .
Ge3 Li1 Ge3 115.2(7) 1_455 .
Ge2 Li1 Ge3 107.5(7) . 13
Li1 Li1 Ge3 142.2(4) 2 13
Ge3 Li1 Ge3 105.2(5) 1_455 13
Ge3 Li1 Ge3 105.2(5) . 13
Ge2 Li1 Nd4 175.7(8) . .
Li1 Li1 Nd4 65.4(4) 2 .
Ge3 Li1 Nd4 66.7(4) 1_455 .
Ge3 Li1 Nd4 66.7(4) . .
Ge3 Li1 Nd4 76.8(5) 13 .
Ge2 Li1 Nd4 65.3(4) . 13
Li1 Li1 Nd4 133.2(3) 2 13
Ge3 Li1 Nd4 166.4(6) 1_455 13
Ge3 Li1 Nd4 77.50(12) . 13
Ge3 Li1 Nd4 65.0(4) 13 13
Nd4 Li1 Nd4 117.4(5) . 13
Ge2 Li1 Nd4 65.3(4) . 13_455
Li1 Li1 Nd4 133.2(3) 2 13_455
Ge3 Li1 Nd4 77.50(12) 1_455 13_455
Ge3 Li1 Nd4 166.4(6) . 13_455
Ge3 Li1 Nd4 65.0(4) 13 13_455
Nd4 Li1 Nd4 117.4(5) . 13_455
Nd4 Li1 Nd4 89.4(5) 13 13_455
Ge2 Li1 Li1 123.3(8) . 13
Li1 Li1 Li1 105.3(7) 2 13
Ge3 Li1 Li1 124.2(10) 1_455 13
Ge3 Li1 Li1 54.0(3) . 13
Ge3 Li1 Li1 51.2(6) 13 13
Nd4 Li1 Li1 59.3(6) . 13
Nd4 Li1 Li1 58.1(4) 13 13
Nd4 Li1 Li1 115.5(9) 13_455 13
Ge2 Li1 Li1 123.3(8) . 13_455
Li1 Li1 Li1 105.3(7) 2 13_455
Ge3 Li1 Li1 54.0(3) 1_455 13_455
Ge3 Li1 Li1 124.2(10) . 13_455
Ge3 Li1 Li1 51.2(5) 13 13_455
Nd4 Li1 Li1 59.3(6) . 13_455
Nd4 Li1 Li1 115.5(9) 13 13_455
Nd4 Li1 Li1 58.1(4) 13_455 13_455
Li1 Li1 Li1 85.9(10) 13 13_455
Ge2 Li1 Nd2 56.9(3) . .
Li1 Li1 Nd2 69.3(3) 2 .
Ge3 Li1 Nd2 119.1(6) 1_455 .
Ge3 Li1 Nd2 57.6(3) . .
Ge3 Li1 Nd2 135.8(4) 13 .
Nd4 Li1 Nd2 120.1(5) . .
Nd4 Li1 Nd2 71.3(2) 13 .
Nd4 Li1 Nd2 122.1(6) 13_455 .
Li1 Li1 Nd2 99.6(3) 13 .
Li1 Li1 Nd2 173.1(8) 13_455 .
Ge2 Li1 Nd2 56.9(3) . 1_455
Li1 Li1 Nd2 69.3(3) 2 1_455
Ge3 Li1 Nd2 57.6(3) 1_455 1_455
Ge3 Li1 Nd2 119.1(6) . 1_455
Ge3 Li1 Nd2 135.8(4) 13 1_455
Nd4 Li1 Nd2 120.1(5) . 1_455
Nd4 Li1 Nd2 122.1(6) 13 1_455
Nd4 Li1 Nd2 71.3(2) 13_455 1_455
Li1 Li1 Nd2 173.1(8) 13 1_455
Li1 Li1 Nd2 99.6(3) 13_455 1_455
Nd2 Li1 Nd2 74.5(4) . 1_455
Ge1 Li2 Li2 110.0(4) . 2_565
Ge1 Li2 Ge5 111.5(5) . 13
Li2 Li2 Ge5 60.1(4) 2_565 13
Ge1 Li2 Ge5 111.5(5) . 13_455
Li2 Li2 Ge5 60.1(4) 2_565 13_455
Ge5 Li2 Ge5 114.5(7) 13 13_455
Ge1 Li2 Ge4 107.7(7) . .
Li2 Li2 Ge4 142.3(4) 2_565 .
Ge5 Li2 Ge4 105.5(5) 13 .
Ge5 Li2 Ge4 105.5(5) 13_455 .
Ge1 Li2 Nd1 65.9(4) . 1_455
Li2 Li2 Nd1 132.9(3) 2_565 1_455
Ge5 Li2 Nd1 167.0(6) 13 1_455
Ge5 Li2 Nd1 77.52(11) 13_455 1_455
Ge4 Li2 Nd1 64.8(4) . 1_455
Ge1 Li2 Nd1 65.9(4) . .
Li2 Li2 Nd1 132.9(3) 2_565 .
Ge5 Li2 Nd1 77.52(11) 13 .
Ge5 Li2 Nd1 167.0(6) 13_455 .
Ge4 Li2 Nd1 64.8(4) . .
Nd1 Li2 Nd1 90.1(5) 1_455 .
Ge1 Li2 Nd3 175.4(8) . 13
Li2 Li2 Nd3 65.4(4) 2_565 13
Ge5 Li2 Nd3 66.6(4) 13 13
Ge5 Li2 Nd3 66.6(4) 13_455 13
Ge4 Li2 Nd3 77.0(5) . 13
Nd1 Li2 Nd3 117.0(4) 1_455 13
Nd1 Li2 Nd3 117.0(4) . 13
Ge1 Li2 Li3 124.5(5) . 13_455
Li2 Li2 Li3 104.8(4) 2_565 13_455
Ge5 Li2 Li3 123.2(7) 13 13_455
Ge5 Li2 Li3 54.4(3) 13_455 13_455
Ge4 Li2 Li3 51.2(4) . 13_455
Nd1 Li2 Li3 58.7(3) 1_455 13_455
Nd1 Li2 Li3 115.6(6) . 13_455
Nd3 Li2 Li3 58.3(4) 13 13_455
Ge1 Li2 Li3 124.5(5) . 13
Li2 Li2 Li3 104.8(4) 2_565 13
Ge5 Li2 Li3 54.4(3) 13 13
Ge5 Li2 Li3 123.2(7) 13_455 13
Ge4 Li2 Li3 51.2(4) . 13
Nd1 Li2 Li3 115.6(6) 1_455 13
Nd1 Li2 Li3 58.7(3) . 13
Nd3 Li2 Li3 58.3(4) 13 13
Li3 Li2 Li3 84.4(6) 13_455 13
Ge1 Li2 Nd5 57.1(3) . 13
Li2 Li2 Nd5 68.9(3) 2_565 13
Ge5 Li2 Nd5 57.3(3) 13 13
Ge5 Li2 Nd5 118.6(6) 13_455 13
Ge4 Li2 Nd5 135.9(4) . 13
Nd1 Li2 Nd5 122.8(6) 1_455 13
Nd1 Li2 Nd5 71.5(2) . 13
Nd3 Li2 Nd5 119.7(5) 13 13
Li3 Li2 Nd5 172.9(6) 13_455 13
Li3 Li2 Nd5 100.3(2) 13 13
Ge1 Li2 Nd5 57.1(3) . 13_455
Li2 Li2 Nd5 68.9(3) 2_565 13_455
Ge5 Li2 Nd5 118.6(6) 13 13_455
Ge5 Li2 Nd5 57.3(3) 13_455 13_455
Ge4 Li2 Nd5 135.9(4) . 13_455
Nd1 Li2 Nd5 71.5(2) 1_455 13_455
Nd1 Li2 Nd5 122.8(6) . 13_455
Nd3 Li2 Nd5 119.7(5) 13 13_455
Li3 Li2 Nd5 100.3(2) 13_455 13_455
Li3 Li2 Nd5 172.9(6) 13 13_455
Nd5 Li2 Nd5 74.6(4) 13 13_455
Ge3* Li3 Li3 0.0(7) 2_565 2_565
Ge3* Li3 Ge4 60.8(3) 2_565 13
Li3 Li3 Ge4 60.8(3) 2_565 13
Ge3* Li3 Ge4 60.8(3) 2_565 13_455
Li3 Li3 Ge4 60.8(3) 2_565 13_455
Ge4 Li3 Ge4 113.8(6) 13 13_455
Ge3* Li3 Ge6 109.5(4) 2_565 .
Li3 Li3 Ge6 109.5(4) 2_565 .
Ge4 Li3 Ge6 113.2(4) 13 .
Ge4 Li3 Ge6 113.2(4) 13_455 .
Ge3* Li3 Ge5 141.1(4) 2_565 .
Li3 Li3 Ge5 141.1(4) 2_565 .
Ge4 Li3 Ge5 103.1(4) 13 .
Ge4 Li3 Ge5 103.1(4) 13_455 .
Ge6 Li3 Ge5 109.4(6) . .
Ge3* Li3 Nd3 133.3(2) 2_565 1_455
Li3 Li3 Nd3 133.3(2) 2_565 1_455
Ge4 Li3 Nd3 165.9(6) 13 1_455
Ge4 Li3 Nd3 77.84(10) 13_455 1_455
Ge6 Li3 Nd3 66.3(3) . 1_455
Ge5 Li3 Nd3 65.3(3) . 1_455
Ge3* Li3 Nd3 133.3(2) 2_565 .
Li3 Li3 Nd3 133.3(2) 2_565 .
Ge4 Li3 Nd3 77.84(10) 13 .
Ge4 Li3 Nd3 165.9(6) 13_455 .
Ge6 Li3 Nd3 66.3(3) . .
Ge5 Li3 Nd3 65.3(3) . .
Nd3 Li3 Nd3 89.6(4) 1_455 .
Ge3* Li3 Nd1 65.9(3) 2_565 13
Li3 Li3 Nd1 65.9(3) 2_565 13
Ge4 Li3 Nd1 65.0(3) 13 13
Ge4 Li3 Nd1 65.0(3) 13_455 13
Ge6 Li3 Nd1 175.4(7) . 13
Ge5 Li3 Nd1 75.2(4) . 13
Nd3 Li3 Nd1 116.6(4) 1_455 13
Nd3 Li3 Nd1 116.6(4) . 13
Ge3* Li3 Li2 104.8(4) 2_565 13_455
Li3 Li3 Li2 104.8(4) 2_565 13_455
Ge4 Li3 Li2 121.1(6) 13 13_455
Ge4 Li3 Li2 52.5(3) 13_455 13_455
Ge6 Li3 Li2 124.8(5) . 13_455
Ge5 Li3 Li2 50.5(4) . 13_455
Nd3 Li3 Li2 58.6(4) 1_455 13_455
Nd3 Li3 Li2 115.2(6) . 13_455
Nd1 Li3 Li2 58.0(4) 13 13_455
Ge3* Li3 Li2 104.8(5) 2_565 13
Li3 Li3 Li2 104.8(5) 2_565 13
Ge4 Li3 Li2 52.5(3) 13 13
Ge4 Li3 Li2 121.1(6) 13_455 13
Ge6 Li3 Li2 124.8(5) . 13
Ge5 Li3 Li2 50.5(4) . 13
Nd3 Li3 Li2 115.2(6) 1_455 13
Nd3 Li3 Li2 58.6(4) . 13
Nd1 Li3 Li2 58.0(4) 13 13
Li2 Li3 Li2 84.4(6) 13_455 13
Ge3* Li3 Nd6 68.9(3) 2_565 5
Li3 Li3 Nd6 68.9(3) 2_565 5
Ge4 Li3 Nd6 58.4(2) 13 5
Ge4 Li3 Nd6 120.9(6) 13_455 5
Ge6 Li3 Nd6 57.5(3) . 5
Ge5 Li3 Nd6 136.0(3) . 5
Nd3 Li3 Nd6 123.8(5) 1_455 5
Nd3 Li3 Nd6 71.5(2) . 5
Nd1 Li3 Nd6 119.3(4) 13 5
Li2 Li3 Nd6 173.2(6) 13_455 5
Li2 Li3 Nd6 99.3(2) 13 5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Nd1 Li2 3.118(14) 2
Nd1 Li2 3.118(14) 1_655
Nd1 Li2 3.118(14) 2_655
Nd1 Li2 3.118(14) .
Nd1 Ge1 3.1217(10) 1_655
Nd1 Ge1 3.1217(10) 2_655
Nd1 Ge1 3.1217(10) 2
Nd1 Ge1 3.1218(10) .
Nd1 Ge4 3.1325(14) 1_655
Nd1 Ge4 3.1326(14) .
Nd1 Ge3* 3.143(17) 14_545
Nd1 Li3 3.143(17) 14_545
Nd2 Ge2 3.1099(9) 1_655
Nd2 Ge2 3.1099(9) 2
Nd2 Ge2 3.1099(9) 2_655
Nd2 Ge2 3.1099(9) .
Nd2 Ge3 3.1458(19) .
Nd2 Ge1 3.3031(11) .
Nd2 Ge1 3.3032(11) 2
Nd2 Ge1 3.3032(11) 1_655
Nd2 Ge1 3.3032(11) 2_655
Nd2 Li1 3.645(16) 1_655
Nd2 Li1 3.645(16) 2_655
Nd2 Li1 3.645(16) 2
Nd3 Ge3* 3.133(13) 2
Nd3 Li3 3.133(13) 2
Nd3 Ge3* 3.133(13) 1_655
Nd3 Li3 3.133(13) 1_655
Nd3 Ge3* 3.133(12) 2_655
Nd3 Li3 3.133(12) 2_655
Nd3 Li3 3.133(12) .
Nd3 Li2 3.144(19) 14_545
Nd3 Li2 3.144(19) 13
Nd3 Ge6 3.1836(9) 1_655
Nd3 Ge6 3.1836(9) 9_656
Nd4 Li1 3.10(2) .
Nd4 Li1 3.10(2) 2
Nd4 Ge2 3.1166(10) 13
Nd4 Ge2 3.1166(10) 14_545
Nd4 Ge2 3.1166(10) 14_445
Nd4 Ge2 3.1166(10) 13_455
Nd4 Li1 3.136(14) 14_445
Nd4 Li1 3.136(14) 13
Nd4 Li1 3.136(14) 14_545
Nd4 Li1 3.136(14) 13_455
Nd4 Ge3 3.1636(14) .
Nd4 Ge3 3.1638(14) 1_455
Nd5 Ge1 3.1097(9) 13
Nd5 Ge1 3.1097(9) 14_445
Nd5 Ge1 3.1097(9) 14_545
Nd5 Ge1 3.1097(9) 13_455
Nd5 Ge5 3.1316(19) .
Nd5 Ge2 3.3060(11) 14_445
Nd5 Ge2 3.3060(11) 13_455
Nd5 Ge2 3.3060(11) 14_545
Nd5 Ge2 3.3060(11) 13
Nd5 Li2 3.641(15) 13
Nd5 Li2 3.641(15) 14_545
Nd5 Li2 3.641(15) 13_455
Nd6 Ge6 3.0934(12) 13
Nd6 Ge6 3.0934(12) 5_444
Nd6 Ge6 3.0934(12) 13_455
Nd6 Ge6 3.0934(12) 5_544
Nd6 Ge4 3.1317(17) .
Nd6 Ge4 3.1317(17) 9
Nd6 Li3 3.565(13) 13
Nd6 Li3 3.565(13) 5_444
Nd6 Li3 3.565(13) 14_545
Nd6 Li3 3.565(13) 6_454
Nd6 Li3 3.565(13) 13_455
Nd6 Li3 3.565(13) 5_544
Ge1 Ge2 2.4823(16) .
Ge1 Ge1 2.502(2) 2
Ge1 Li2 2.556(19) .
Ge1 Nd5 3.1097(9) 13
Ge1 Nd5 3.1097(9) 13_455
Ge1 Nd1 3.1219(10) 1_455
Ge1 Nd2 3.3031(11) 1_455
Ge2 Ge2 2.502(2) 2_565
Ge2 Li1 2.57(2) .
Ge2 Nd2 3.1099(9) 1_455
Ge2 Nd4 3.1164(10) 13
Ge2 Nd4 3.1164(10) 13_455
Ge2 Nd5 3.3061(11) 13_455
Ge2 Nd5 3.3061(11) 13
Ge3 Li1 2.614(11) .
Ge3 Li1 2.614(11) 2
Ge3 Li1 2.614(11) 1_655
Ge3 Li1 2.614(11) 2_655
Ge3 Li1 2.71(2) 13
Ge3 Li1 2.71(2) 14_545
Ge3 Nd4 3.1637(14) 1_655
Ge4 Ge3* 2.634(9) 14_445
Ge4 Li3 2.634(9) 14_445
Ge4 Ge3* 2.634(9) 13
Ge4 Li3 2.634(9) 13
Ge4 Ge3* 2.634(9) 13_455
Ge4 Li3 2.634(9) 13_455
Ge4 Ge3* 2.634(9) 14_545
Ge4 Li3 2.634(9) 14_545
Ge4 Li2 2.684(19) .
Ge4 Li2 2.684(19) 2
Ge4 Nd1 3.1324(14) 1_455
Ge5 Li2 2.624(11) 14_445
Ge5 Li2 2.624(11) 13
Ge5 Li2 2.624(11) 13_455
Ge5 Li2 2.624(11) 14_545
Ge5 Li3 2.762(17) .
Ge5 Ge3* 2.762(17) 2
Ge5 Li3 2.762(17) 2
Ge5 Nd3 3.1947(14) 1_455
Ge6 Ge6 2.534(3) 9_556
Ge6 Ge3* 2.639(17) 10_556
Ge6 Li3 2.639(17) 10_556
Ge6 Li3 2.639(17) .
Ge6 Nd6 3.0934(12) 5
Ge6 Nd6 3.0934(12) 5_455
Ge6 Nd3 3.1837(9) 1_455
Ge6 Nd3 3.1837(9) 9_656
Ge6 Nd3 3.1837(9) 9_556
Li1 Li1 2.58(4) 2
Li1 Ge3 2.614(11) 1_455
Li1 Ge3 2.71(2) 13
Li1 Nd4 3.136(14) 13
Li1 Nd4 3.136(14) 13_455
Li1 Li1 3.24(3) 13
Li1 Li1 3.24(3) 13_455
Li1 Nd2 3.645(16) 1_455
Li2 Li2 2.62(4) 2_565
Li2 Ge5 2.624(11) 13
Li2 Ge5 2.624(11) 13_455
Li2 Nd1 3.118(14) 1_455
Li2 Nd3 3.144(19) 13
Li2 Li3 3.285(19) 13_455
Li2 Li3 3.285(19) 13
Li2 Nd5 3.641(15) 13
Li2 Nd5 3.641(15) 13_455
Li3 Ge3* 2.57(4) 2_565
Li3 Li3 2.57(4) 2_565
Li3 Ge4 2.634(9) 13
Li3 Ge4 2.634(9) 13_455
Li3 Nd3 3.133(12) 1_455
Li3 Nd1 3.143(17) 13
Li3 Li2 3.285(19) 13_455
Li3 Li2 3.285(19) 13
Li3 Nd6 3.565(13) 5
