#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:55:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179399 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/96/4329695.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329695
loop_
_publ_author_name
'Yue Liu'
'Zhi Chen'
'Jia Ren'
'Xiao-Qing Zhao'
'Peng Cheng'
'Bin Zhao'
_publ_section_title
;
 Two-Dimensional 3d-4f Networks Containing Planar Co4Ln2 Clusters with
 Single-Molecule-Magnet Behaviors
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7433
_journal_page_last               7435
_journal_paper_doi               10.1021/ic300372v
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C100 H86 Co4 Dy2 N14 O33'
_chemical_formula_weight         2572.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.522(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.2767(6)
_cell_length_b                   25.7524(7)
_cell_length_c                   14.8178(6)
_cell_measurement_reflns_used    16451
_cell_measurement_temperature    394(2)
_cell_measurement_theta_max      29.1175
_cell_measurement_theta_min      2.3678
_cell_volume                     4571.9(4)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug  3 2011,13:03:54)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug  3 2011,13:03:54)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug  3 2011,13:03:54)
;
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      394(2)
_diffrn_detector_area_resol_mean 16.2116
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'SuperNova, Single source at offset), Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) x-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_av_sigmaI/netI    0.0363
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            30316
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.78
_exptl_absorpt_coefficient_mu    2.423
_exptl_absorpt_correction_T_max  0.7905
_exptl_absorpt_correction_T_min  0.5992
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug  3 2011,13:03:54)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            'reddish brown'
_exptl_crystal_density_diffrn    1.864
_exptl_crystal_description       prism
_exptl_crystal_F_000             2564
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         8.194
_refine_diff_density_min         -3.449
_refine_diff_density_rms         0.297
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     687
_refine_ls_number_reflns         8012
_refine_ls_number_restraints     138
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0922
_refine_ls_R_factor_gt           0.0876
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0763P)²+233.9236P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2254
_refine_ls_wR_factor_ref         0.2283
_reflns_number_gt                7384
_reflns_number_total             8012
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300372v_si_001.cif
_cod_data_source_block           P110914I
_cod_original_cell_volume        4571.9(3)
_cod_database_code               4329695
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy -0.50324(4) -0.01049(2) -0.36992(4) 0.01010(19) Uani 1 1 d . . .
Co1 Co -0.74967(13) -0.11511(6) -0.48035(12) 0.0153(4) Uani 1 1 d . . .
Co2 Co -0.73547(14) -0.12335(6) -0.75265(13) 0.0184(4) Uani 1 1 d . . .
O1 O -1.4296(7) -0.4064(3) -0.8966(7) 0.0214(19) Uani 1 1 d . . .
O2 O -1.3255(8) -0.4540(3) -0.7667(7) 0.025(2) Uani 1 1 d . . .
O3 O -1.4020(8) -0.4003(4) -1.2266(7) 0.026(2) Uani 1 1 d . A .
O4 O -1.3597(7) -0.4480(3) -1.0877(6) 0.0185(18) Uani 1 1 d . . .
O5 O -0.6390(7) -0.0668(3) -0.3683(6) 0.0177(18) Uani 1 1 d U A .
O6 O -0.7744(8) -0.1068(4) -0.3500(7) 0.027(2) Uani 1 1 d . A .
O7 O -0.6567(9) -0.0567(4) -0.2248(8) 0.036(2) Uani 1 1 d . . .
O8 O -0.5984(7) -0.0265(3) -0.5408(6) 0.0158(17) Uani 1 1 d . . .
O9 O -0.6193(7) -0.0657(3) -0.6807(6) 0.0150(17) Uani 1 1 d U . .
O10 O -0.7036(7) -0.0994(3) -0.5943(6) 0.0198(18) Uani 1 1 d . A .
O11 O -0.4984(6) 0.0087(3) -0.2102(5) 0.0136(17) Uani 1 1 d U A 1
H11A H -0.5288 -0.0162 -0.1920 0.016 Uiso 1 1 d R A 1
H11B H -0.4304 0.0123 -0.1665 0.016 Uiso 1 1 d R A 1
O17 O -0.8601(6) -0.1160(3) -0.1972(5) 0.058(3) Uani 1 1 d RU . .
H17A H -0.7921 -0.1191 -0.1864 0.070 Uiso 1 1 d R . .
H17B H -0.8895 -0.0910 -0.2375 0.070 Uiso 1 1 d R . .
O12 O -0.7382(16) -0.0676(7) -1.0095(11) 0.078(5) Uani 1 1 d U A .
O13 O -0.7359(9) -0.1176(4) -0.8914(8) 0.036(2) Uani 1 1 d U A .
O14 O -1.2824(10) -0.1753(5) -0.9295(11) 0.054(3) Uani 1 1 d . B 1
O15 O -0.5002(13) 0.0089(6) -0.8578(11) 0.040(3) Uani 0.75 1 d PU C 2
O16 O -0.5044(13) -0.0110(6) -0.9230(11) 0.040(3) Uani 0.75 1 d PU D 3
N1 N -0.9015(9) -0.0739(4) -0.5664(8) 0.018(2) Uani 1 1 d . A .
N2 N -0.8604(8) -0.1722(4) -0.5629(8) 0.017(2) Uani 1 1 d . A .
N3 N -0.6558(8) -0.1863(4) -0.4285(8) 0.021(2) Uani 1 1 d . A .
N4 N -0.8912(9) -0.0808(4) -0.8095(8) 0.023(2) Uani 1 1 d . A .
N5 N -0.8569(8) -0.1801(4) -0.8109(8) 0.019(2) Uani 1 1 d . A .
N6 N -0.6504(8) -0.1943(4) -0.6893(8) 0.019(2) Uani 1 1 d . A .
N7 N -1.3788(12) -0.1009(5) -0.9960(10) 0.042(3) Uani 1 1 d . B 1
C1 C -0.9159(12) -0.0223(5) -0.5638(10) 0.025(3) Uani 1 1 d . . .
H1 H -0.8573 -0.0018 -0.5204 0.030 Uiso 1 1 calc R A .
C2 C -1.0171(12) 0.0010(6) -0.6253(11) 0.029(3) Uani 1 1 d U A .
H2 H -1.0240 0.0369 -0.6235 0.035 Uiso 1 1 calc R . .
C3 C -1.1061(11) -0.0275(6) -0.6880(11) 0.028(3) Uani 1 1 d . . .
H3 H -1.1741 -0.0119 -0.7277 0.034 Uiso 1 1 calc R A .
C4 C -1.0911(11) -0.0816(5) -0.6905(11) 0.026(3) Uani 1 1 d . A .
H4 H -1.1497 -0.1027 -0.7319 0.031 Uiso 1 1 calc R . .
C5 C -0.9863(10) -0.1033(5) -0.6296(10) 0.020(3) Uani 1 1 d . . .
C6 C -0.9658(10) -0.1598(5) -0.6265(9) 0.015(2) Uani 1 1 d . A .
C7 C -1.0421(10) -0.1979(4) -0.6798(9) 0.016(2) Uani 1 1 d . . .
H7 H -1.1139 -0.1889 -0.7256 0.019 Uiso 1 1 calc R A .
C8 C -1.0095(10) -0.2500(4) -0.6635(9) 0.014(2) Uani 1 1 d U A .
C9 C -0.8989(10) -0.2616(5) -0.6004(10) 0.020(3) Uani 1 1 d . . .
H9 H -0.8737 -0.2957 -0.5924 0.024 Uiso 1 1 calc R A .
C10 C -0.8267(10) -0.2218(5) -0.5496(9) 0.016(2) Uani 1 1 d . A .
C11 C -0.7099(10) -0.2299(5) -0.4719(9) 0.016(2) Uani 1 1 d . . .
C12 C -0.6632(10) -0.2783(5) -0.4427(10) 0.020(3) Uani 1 1 d . A .
H12 H -0.7030 -0.3079 -0.4740 0.024 Uiso 1 1 calc R . .
C13 C -0.5564(11) -0.2826(5) -0.3662(10) 0.025(3) Uani 1 1 d . . .
H13 H -0.5232 -0.3148 -0.3448 0.030 Uiso 1 1 calc R A .
C14 C -0.5010(11) -0.2373(5) -0.3228(10) 0.025(3) Uani 1 1 d . A .
H14 H -0.4293 -0.2385 -0.2712 0.030 Uiso 1 1 calc R . .
C15 C -0.5525(11) -0.1909(5) -0.3563(10) 0.025(3) Uani 1 1 d . . .
H15 H -0.5135 -0.1608 -0.3273 0.029 Uiso 1 1 calc R A .
C16 C -1.0946(10) -0.2920(5) -0.7085(10) 0.019(3) Uani 1 1 d . . .
C17 C -1.1939(10) -0.2834(5) -0.7939(9) 0.017(3) Uani 1 1 d . A .
H17 H -1.2073 -0.2514 -0.8260 0.021 Uiso 1 1 calc R . .
C18 C -1.2731(10) -0.3230(5) -0.8309(9) 0.018(3) Uani 1 1 d . . .
H18 H -1.3401 -0.3170 -0.8867 0.021 Uiso 1 1 calc R A .
C19 C -1.2514(10) -0.3730(5) -0.7833(9) 0.016(2) Uani 1 1 d U A .
C20 C -1.1570(10) -0.3790(4) -0.6972(10) 0.017(2) Uani 1 1 d . . .
H20 H -1.1464 -0.4097 -0.6612 0.020 Uiso 1 1 calc R A .
C21 C -1.0756(11) -0.3404(5) -0.6612(10) 0.021(3) Uani 1 1 d . A .
H21 H -1.0086 -0.3469 -0.6057 0.025 Uiso 1 1 calc R . .
C22 C -1.3421(10) -0.4125(5) -0.8190(10) 0.017(3) Uani 1 1 d . . .
C23 C -0.9052(12) -0.0293(5) -0.8060(11) 0.026(3) Uani 1 1 d . . .
H23 H -0.8451 -0.0090 -0.7646 0.032 Uiso 1 1 calc R A .
C24 C -1.0077(12) -0.0055(6) -0.8630(11) 0.029(3) Uani 1 1 d U A .
H24 H -1.0157 0.0301 -0.8579 0.034 Uiso 1 1 calc R . .
C25 C -1.0957(13) -0.0341(5) -0.9259(11) 0.031(3) Uani 1 1 d . . .
H25 H -1.1635 -0.0182 -0.9652 0.037 Uiso 1 1 calc R A .
C26 C -1.0835(12) -0.0876(5) -0.9311(10) 0.026(3) Uani 1 1 d . A .
H26 H -1.1434 -0.1078 -0.9730 0.031 Uiso 1 1 calc R . .
C27 C -0.9807(10) -0.1103(5) -0.8727(10) 0.019(3) Uani 1 1 d . . .
C28 C -0.9613(11) -0.1665(5) -0.8694(9) 0.019(3) Uani 1 1 d . A .
C29 C -1.0418(10) -0.2038(5) -0.9201(9) 0.017(2) Uani 1 1 d . . .
H29 H -1.1153 -0.1941 -0.9594 0.021 Uiso 1 1 calc R A .
C30 C -1.0111(10) -0.2553(5) -0.9112(9) 0.017(3) Uani 1 1 d . A .
C31 C -0.9017(10) -0.2698(5) -0.8486(9) 0.016(2) Uani 1 1 d . . .
H31 H -0.8797 -0.3045 -0.8409 0.019 Uiso 1 1 calc R A .
C32 C -0.8261(11) -0.2300(5) -0.7978(9) 0.020(3) Uani 1 1 d . A .
C33 C -0.7081(10) -0.2382(5) -0.7229(9) 0.016(2) Uani 1 1 d . . .
C34 C -0.6632(11) -0.2867(5) -0.6876(10) 0.023(3) Uani 1 1 d . A .
H34 H -0.7050 -0.3167 -0.7130 0.028 Uiso 1 1 calc R . .
C35 C -0.5554(11) -0.2896(5) -0.6141(10) 0.025(3) Uani 1 1 d . . .
H35 H -0.5231 -0.3216 -0.5888 0.030 Uiso 1 1 calc R A .
C36 C -0.4964(11) -0.2446(5) -0.5788(10) 0.026(3) Uani 1 1 d . A .
H36 H -0.4242 -0.2459 -0.5280 0.031 Uiso 1 1 calc R . .
C37 C -0.5445(10) -0.1972(5) -0.6187(10) 0.021(3) Uani 1 1 d . . .
H37 H -0.5030 -0.1669 -0.5963 0.025 Uiso 1 1 calc R A .
C38 C -1.0965(10) -0.2960(4) -0.9667(9) 0.0143(11) Uani 1 1 d U . .
C39 C -1.1865(9) -0.2820(5) -1.0563(8) 0.0141(11) Uani 1 1 d U A .
H39 H -1.1942 -0.2479 -1.0792 0.017 Uiso 1 1 calc R . .
C40 C -1.2655(10) -0.3198(4) -1.1116(9) 0.0136(11) Uani 1 1 d U . .
H40 H -1.3204 -0.3115 -1.1747 0.016 Uiso 1 1 calc R A .
C41 C -1.2631(9) -0.3698(4) -1.0736(8) 0.0126(11) Uani 1 1 d U A .
C42 C -1.1743(9) -0.3824(4) -0.9831(8) 0.0136(11) Uani 1 1 d U . .
H42 H -1.1703 -0.4155 -0.9569 0.016 Uiso 1 1 calc R A .
C43 C -1.0901(10) -0.3460(4) -0.9302(9) 0.0142(11) Uani 1 1 d U A .
H43 H -1.0303 -0.3556 -0.8707 0.017 Uiso 1 1 calc R . .
C44 C -1.3476(10) -0.4085(5) -1.1352(10) 0.018(3) Uani 1 1 d U . .
C45 C -0.6906(11) -0.0763(5) -0.3105(10) 0.021(3) Uani 1 1 d . A .
C46 C -0.6403(9) -0.0637(4) -0.6034(9) 0.014(2) Uani 1 1 d U . .
C47 C -0.7286(15) -0.0798(8) -0.9269(13) 0.045(4) Uani 1 1 d U . .
H47 H -0.7115 -0.0518 -0.8832 0.053 Uiso 1 1 calc R A .
C48 C -1.3326(13) -0.1366(7) -0.9220(13) 0.040(4) Uani 1 1 d . B 1
H48 H -1.3392 -0.1315 -0.8626 0.048 Uiso 1 1 calc R B 1
C49 C -1.4364(19) -0.0574(9) -0.9816(17) 0.067(6) Uani 1 1 d U B 1
H49A H -1.4293 -0.0576 -0.9143 0.100 Uiso 1 1 calc R B 1
H49B H -1.5139 -0.0593 -1.0276 0.100 Uiso 1 1 calc R B 1
H49C H -1.4049 -0.0260 -0.9931 0.100 Uiso 1 1 calc R B 1
C50 C -1.3701(14) -0.1040(7) -1.0910(12) 0.039(4) Uani 1 1 d . B 1
H50A H -1.3320 -0.1354 -1.0928 0.059 Uiso 1 1 calc R B 1
H50B H -1.3290 -0.0746 -1.0971 0.059 Uiso 1 1 calc R B 1
H50C H -1.4435 -0.1040 -1.1453 0.059 Uiso 1 1 calc R B 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Dy1 O5 85.1(3) 2_353 .
O4 Dy1 O8 80.4(3) 2_353 .
O5 Dy1 O8 80.8(3) . .
O4 Dy1 O2 153.4(3) 2_353 4_656
O5 Dy1 O2 108.3(3) . 4_656
O8 Dy1 O2 123.7(3) . 4_656
O4 Dy1 O11 78.9(3) 2_353 .
O5 Dy1 O11 79.0(3) . .
O8 Dy1 O11 152.1(3) . .
O2 Dy1 O11 81.2(3) 4_656 .
O4 Dy1 O9 82.3(3) 2_353 3_454
O5 Dy1 O9 155.9(3) . 3_454
O8 Dy1 O9 116.9(3) . 3_454
O2 Dy1 O9 76.5(3) 4_656 3_454
O11 Dy1 O9 78.5(3) . 3_454
O4 Dy1 O8 97.7(3) 2_353 3_454
O5 Dy1 O8 149.1(3) . 3_454
O8 Dy1 O8 69.4(3) . 3_454
O2 Dy1 O8 82.7(3) 4_656 3_454
O11 Dy1 O8 131.9(2) . 3_454
O9 Dy1 O8 53.7(3) 3_454 3_454
O4 Dy1 O1 152.6(3) 2_353 4_656
O5 Dy1 O1 79.7(3) . 4_656
O8 Dy1 O1 74.8(3) . 4_656
O2 Dy1 O1 54.1(3) 4_656 4_656
O11 Dy1 O1 119.8(3) . 4_656
O9 Dy1 O1 119.3(3) 3_454 4_656
O8 Dy1 O1 84.4(3) 3_454 4_656
O4 Dy1 C22 178.6(3) 2_353 4_656
O5 Dy1 C22 93.6(3) . 4_656
O8 Dy1 C22 99.4(3) . 4_656
O2 Dy1 C22 27.4(3) 4_656 4_656
O11 Dy1 C22 100.9(3) . 4_656
O9 Dy1 C22 99.0(3) 3_454 4_656
O8 Dy1 C22 83.4(3) 3_454 4_656
O1 Dy1 C22 26.7(3) 4_656 4_656
O4 Dy1 C46 89.5(3) 2_353 3_454
O5 Dy1 C46 172.2(3) . 3_454
O8 Dy1 C46 92.9(3) . 3_454
O2 Dy1 C46 79.0(3) 4_656 3_454
O11 Dy1 C46 105.4(3) . 3_454
O9 Dy1 C46 26.9(3) 3_454 3_454
O8 Dy1 C46 26.7(3) 3_454 3_454
O1 Dy1 C46 103.1(3) 4_656 3_454
C22 Dy1 C46 91.9(3) 4_656 3_454
O4 Dy1 Dy1 89.1(2) 2_353 3_454
O5 Dy1 Dy1 116.2(2) . 3_454
O8 Dy1 Dy1 35.7(2) . 3_454
O2 Dy1 Dy1 104.4(2) 4_656 3_454
O11 Dy1 Dy1 160.03(16) . 3_454
O9 Dy1 Dy1 84.15(19) 3_454 3_454
O8 Dy1 Dy1 33.70(18) 3_454 3_454
O1 Dy1 Dy1 77.5(2) 4_656 3_454
C22 Dy1 Dy1 91.4(3) 4_656 3_454
C46 Dy1 Dy1 58.2(2) 3_454 3_454
N2 Co1 O10 92.3(4) . .
N2 Co1 O5 166.4(4) . .
O10 Co1 O5 100.3(3) . .
N2 Co1 O6 105.2(4) . .
O10 Co1 O6 161.3(4) . .
O5 Co1 O6 62.9(3) . .
N2 Co1 N1 75.7(4) . .
O10 Co1 N1 87.2(4) . .
O5 Co1 N1 109.7(4) . .
O6 Co1 N1 91.0(4) . .
N2 Co1 N3 76.2(4) . .
O10 Co1 N3 97.3(4) . .
O5 Co1 N3 97.0(4) . .
O6 Co1 N3 93.1(4) . .
N1 Co1 N3 151.7(4) . .
N2 Co1 C45 135.7(4) . .
O10 Co1 C45 132.0(4) . .
O5 Co1 C45 32.1(4) . .
O6 Co1 C45 30.8(4) . .
N1 Co1 C45 102.0(4) . .
N3 Co1 C45 95.7(4) . .
O13 Co2 N5 88.1(4) . .
O13 Co2 O9 98.3(4) . .
N5 Co2 O9 173.3(4) . .
O13 Co2 N6 105.8(4) . .
N5 Co2 N6 75.5(4) . .
O9 Co2 N6 104.5(4) . .
O13 Co2 N4 89.1(4) . .
N5 Co2 N4 75.7(4) . .
O9 Co2 N4 102.2(4) . .
N6 Co2 N4 146.9(4) . .
O13 Co2 O10 158.0(4) . .
N5 Co2 O10 112.7(4) . .
O9 Co2 O10 60.7(3) . .
N6 Co2 O10 87.2(4) . .
N4 Co2 O10 89.2(4) . .
C22 O1 Dy1 91.0(7) . 4_455
C22 O2 Dy1 93.9(7) . 4_455
C44 O4 Dy1 132.4(8) . 2_343
C45 O5 Co1 91.3(7) . .
C45 O5 Dy1 137.6(8) . .
Co1 O5 Dy1 130.4(4) . .
C45 O6 Co1 91.9(8) . .
C46 O8 Dy1 141.4(8) . .
C46 O8 Dy1 94.0(7) . 3_454
Dy1 O8 Dy1 110.6(3) . 3_454
C46 O9 Co2 95.0(7) . .
C46 O9 Dy1 93.8(6) . 3_454
Co2 O9 Dy1 168.2(4) . 3_454
C46 O10 Co1 131.2(8) . .
C46 O10 Co2 85.7(7) . .
Co1 O10 Co2 142.9(4) . .
Dy1 O11 H11A 109.9 . .
Dy1 O11 H11B 109.8 . .
H11A O11 H11B 109.2 . .
H17A O17 H17B 109.6 . .
C47 O13 Co2 124.2(12) . .
C5 N1 C1 119.3(12) . .
C5 N1 Co1 115.2(8) . .
C1 N1 Co1 125.4(9) . .
C10 N2 C6 120.6(10) . .
C10 N2 Co1 118.9(8) . .
C6 N2 Co1 120.5(8) . .
C15 N3 C11 117.7(11) . .
C15 N3 Co1 126.6(9) . .
C11 N3 Co1 115.6(8) . .
C23 N4 C27 118.5(12) . .
C23 N4 Co2 127.6(9) . .
C27 N4 Co2 112.5(8) . .
C28 N5 C32 121.1(11) . .
C28 N5 Co2 119.6(8) . .
C32 N5 Co2 118.9(8) . .
C33 N6 C37 118.9(11) . .
C33 N6 Co2 116.7(8) . .
C37 N6 Co2 124.4(8) . .
C48 N7 C49 119.8(16) . .
C48 N7 C50 123.0(14) . .
C49 N7 C50 117.2(15) . .
N1 C1 C2 121.0(13) . .
N1 C1 H1 119.5 . .
C2 C1 H1 119.5 . .
C3 C2 C1 121.5(13) . .
C3 C2 H2 119.2 . .
C1 C2 H2 119.2 . .
C2 C3 C4 117.4(13) . .
C2 C3 H3 121.3 . .
C4 C3 H3 121.3 . .
C5 C4 C3 119.2(13) . .
C5 C4 H4 120.4 . .
C3 C4 H4 120.4 . .
N1 C5 C4 121.5(12) . .
N1 C5 C6 116.5(11) . .
C4 C5 C6 122.0(11) . .
N2 C6 C7 121.1(11) . .
N2 C6 C5 112.1(10) . .
C7 C6 C5 126.8(11) . .
C6 C7 C8 119.0(11) . .
C6 C7 H7 120.5 . .
C8 C7 H7 120.5 . .
C9 C8 C7 118.7(11) . .
C9 C8 C16 121.3(11) . .
C7 C8 C16 119.9(11) . .
C10 C9 C8 119.3(11) . .
C10 C9 H9 120.4 . .
C8 C9 H9 120.4 . .
N2 C10 C9 121.2(11) . .
N2 C10 C11 114.6(10) . .
C9 C10 C11 124.1(11) . .
N3 C11 C12 122.2(11) . .
N3 C11 C10 114.6(10) . .
C12 C11 C10 123.1(11) . .
C11 C12 C13 119.5(12) . .
C11 C12 H12 120.3 . .
C13 C12 H12 120.3 . .
C14 C13 C12 117.8(12) . .
C14 C13 H13 121.1 . .
C12 C13 H13 121.1 . .
C15 C14 C13 119.2(12) . .
C15 C14 H14 120.4 . .
C13 C14 H14 120.4 . .
N3 C15 C14 123.6(13) . .
N3 C15 H15 118.2 . .
C14 C15 H15 118.2 . .
C17 C16 C21 119.4(11) . .
C17 C16 C8 121.7(11) . .
C21 C16 C8 118.8(11) . .
C18 C17 C16 119.9(11) . .
C18 C17 H17 120.1 . .
C16 C17 H17 120.1 . .
C17 C18 C19 120.2(11) . .
C17 C18 H18 119.9 . .
C19 C18 H18 119.9 . .
C20 C19 C18 118.2(11) . .
C20 C19 C22 122.2(11) . .
C18 C19 C22 118.6(11) . .
C19 C20 C21 121.8(11) . .
C19 C20 H20 119.1 . .
C21 C20 H20 119.1 . .
C20 C21 C16 120.1(12) . .
C20 C21 H21 120.0 . .
C16 C21 H21 120.0 . .
O1 C22 O2 121.0(11) . .
O1 C22 C19 122.1(11) . .
O2 C22 C19 116.9(11) . .
O1 C22 Dy1 62.3(6) . 4_455
O2 C22 Dy1 58.7(6) . 4_455
C19 C22 Dy1 175.4(9) . 4_455
N4 C23 C24 121.6(13) . .
N4 C23 H23 119.2 . .
C24 C23 H23 119.2 . .
C25 C24 C23 120.2(13) . .
C25 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
C24 C25 C26 119.3(14) . .
C24 C25 H25 120.3 . .
C26 C25 H25 120.3 . .
C25 C26 C27 119.2(13) . .
C25 C26 H26 120.4 . .
C27 C26 H26 120.4 . .
N4 C27 C26 121.1(12) . .
N4 C27 C28 115.7(11) . .
C26 C27 C28 123.2(12) . .
N5 C28 C29 120.9(12) . .
N5 C28 C27 113.6(10) . .
C29 C28 C27 125.4(12) . .
C30 C29 C28 119.1(12) . .
C30 C29 H29 120.4 . .
C28 C29 H29 120.4 . .
C29 C30 C31 120.1(11) . .
C29 C30 C38 119.9(11) . .
C31 C30 C38 120.0(11) . .
C30 C31 C32 117.3(11) . .
C30 C31 H31 121.4 . .
C32 C31 H31 121.4 . .
N5 C32 C31 121.4(12) . .
N5 C32 C33 113.6(11) . .
C31 C32 C33 125.0(11) . .
N6 C33 C34 122.6(11) . .
N6 C33 C32 114.0(10) . .
C34 C33 C32 123.4(11) . .
C35 C34 C33 118.6(12) . .
C35 C34 H34 120.7 . .
C33 C34 H34 120.7 . .
C36 C35 C34 119.0(12) . .
C36 C35 H35 120.5 . .
C34 C35 H35 120.5 . .
C35 C36 C37 119.9(12) . .
C35 C36 H36 120.0 . .
C37 C36 H36 120.0 . .
N6 C37 C36 121.0(12) . .
N6 C37 H37 119.5 . .
C36 C37 H37 119.5 . .
C43 C38 C39 119.6(11) . .
C43 C38 C30 122.0(11) . .
C39 C38 C30 118.3(11) . .
C38 C39 C40 119.4(11) . .
C38 C39 H39 120.3 . .
C40 C39 H39 120.3 . .
C41 C40 C39 121.4(11) . .
C41 C40 H40 119.3 . .
C39 C40 H40 119.3 . .
C42 C41 C40 117.7(11) . .
C42 C41 C44 122.6(11) . .
C40 C41 C44 119.3(10) . .
C41 C42 C43 121.4(11) . .
C41 C42 H42 119.3 . .
C43 C42 H42 119.3 . .
C38 C43 C42 120.0(11) . .
C38 C43 H43 120.0 . .
C42 C43 H43 120.0 . .
O3 C44 O4 125.2(11) . .
O3 C44 C41 119.0(10) . .
O4 C44 C41 115.7(11) . .
O7 C45 O6 124.8(12) . .
O7 C45 O5 121.3(12) . .
O6 C45 O5 113.9(11) . .
O7 C45 Co1 177.6(10) . .
O6 C45 Co1 57.3(7) . .
O5 C45 Co1 56.6(6) . .
O8 C46 O10 123.8(11) . .
O8 C46 O9 118.5(10) . .
O10 C46 O9 117.6(10) . .
O8 C46 Dy1 59.3(6) . 3_454
O10 C46 Dy1 176.5(9) . 3_454
O9 C46 Dy1 59.3(5) . 3_454
O13 C47 O12 134(2) . .
O13 C47 H47 112.8 . .
O12 C47 H47 112.8 . .
O14 C48 N7 123.3(18) . .
O14 C48 H48 118.3 . .
N7 C48 H48 118.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O4 2.305(8) 2_353
Dy1 O5 2.322(8) .
Dy1 O8 2.329(8) .
Dy1 O2 2.374(8) 4_656
Dy1 O11 2.391(7) .
Dy1 O9 2.451(8) 3_454
Dy1 O8 2.452(8) 3_454
Dy1 O1 2.456(8) 4_656
Dy1 C22 2.772(11) 4_656
Dy1 C46 2.845(11) 3_454
Dy1 Dy1 3.9300(11) 3_454
Co1 N2 2.066(10) .
Co1 O10 2.069(9) .
Co1 O5 2.088(8) .
Co1 O6 2.106(10) .
Co1 N1 2.145(11) .
Co1 N3 2.164(11) .
Co1 C45 2.500(13) .
Co2 O13 2.058(12) .
Co2 N5 2.068(10) .
Co2 O9 2.074(8) .
Co2 N6 2.141(11) .
Co2 N4 2.165(11) .
Co2 O10 2.282(9) .
O1 C22 1.244(15) .
O1 Dy1 2.456(8) 4_455
O2 C22 1.280(15) .
O2 Dy1 2.374(8) 4_455
O3 C44 1.248(16) .
O4 C44 1.286(15) .
O4 Dy1 2.305(8) 2_343
O5 C45 1.330(15) .
O6 C45 1.281(16) .
O7 C45 1.256(17) .
O8 C46 1.282(14) .
O8 Dy1 2.452(8) 3_454
O9 C46 1.292(15) .
O9 Dy1 2.451(8) 3_454
O10 C46 1.291(14) .
O11 H11A 0.8594 .
O11 H11B 0.8603 .
O17 H17A 0.8501 .
O17 H17B 0.8499 .
O12 C47 1.22(2) .
O13 C47 1.13(2) .
O14 C48 1.23(2) .
N1 C5 1.345(16) .
N1 C1 1.347(16) .
N2 C10 1.340(16) .
N2 C6 1.346(16) .
N3 C15 1.332(17) .
N3 C11 1.338(16) .
N4 C23 1.343(17) .
N4 C27 1.381(17) .
N5 C28 1.326(17) .
N5 C32 1.338(16) .
N6 C33 1.334(16) .
N6 C37 1.345(16) .
N7 C48 1.36(2) .
N7 C49 1.42(2) .
N7 C50 1.46(2) .
C1 C2 1.393(19) .
C1 H1 0.9300 .
C2 C3 1.36(2) .
C2 H2 0.9300 .
C3 C4 1.411(19) .
C3 H3 0.9300 .
C4 C5 1.407(18) .
C4 H4 0.9300 .
C5 C6 1.477(17) .
C6 C7 1.386(17) .
C7 C8 1.399(16) .
C7 H7 0.9300 .
C8 C9 1.392(17) .
C8 C16 1.497(16) .
C9 C10 1.384(18) .
C9 H9 0.9300 .
C10 C11 1.495(16) .
C11 C12 1.377(17) .
C12 C13 1.386(18) .
C12 H12 0.9300 .
C13 C14 1.38(2) .
C13 H13 0.9300 .
C14 C15 1.359(19) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.397(17) .
C16 C21 1.398(18) .
C17 C18 1.395(17) .
C17 H17 0.9300 .
C18 C19 1.437(17) .
C18 H18 0.9300 .
C19 C20 1.358(18) .
C19 C22 1.489(16) .
C20 C21 1.394(17) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 Dy1 2.772(11) 4_455
C23 C24 1.397(19) .
C23 H23 0.9300 .
C24 C25 1.36(2) .
C24 H24 0.9300 .
C25 C26 1.391(19) .
C25 H25 0.9300 .
C26 C27 1.392(18) .
C26 H26 0.9300 .
C27 C28 1.467(18) .
C28 C29 1.392(17) .
C29 C30 1.376(17) .
C29 H29 0.9300 .
C30 C31 1.397(17) .
C30 C38 1.502(16) .
C31 C32 1.405(18) .
C31 H31 0.9300 .
C32 C33 1.495(17) .
C33 C34 1.386(18) .
C34 C35 1.378(19) .
C34 H34 0.9300 .
C35 C36 1.369(19) .
C35 H35 0.9300 .
C36 C37 1.387(19) .
C36 H36 0.9300 .
C37 H37 0.9300 .
C38 C43 1.385(16) .
C38 C39 1.398(16) .
C39 C40 1.407(16) .
C39 H39 0.9300 .
C40 C41 1.399(16) .
C40 H40 0.9300 .
C41 C42 1.390(16) .
C41 C44 1.483(16) .
C42 C43 1.409(16) .
C42 H42 0.9300 .
C43 H43 0.9300 .
C46 Dy1 2.845(11) 3_454
C47 H47 0.9300 .
C48 H48 0.9300 .
C49 H49A 0.9600 .
C49 H49B 0.9600 .
C49 H49C 0.9600 .
C50 H50A 0.9600 .
C50 H50B 0.9600 .
C50 H50C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Co1 O5 C45 -30.3(19) . .
O10 Co1 O5 C45 171.7(7) . .
O6 Co1 O5 C45 0.4(7) . .
N1 Co1 O5 C45 81.0(7) . .
N3 Co1 O5 C45 -89.5(7) . .
N2 Co1 O5 Dy1 158.5(14) . .
O10 Co1 O5 Dy1 0.6(6) . .
O6 Co1 O5 Dy1 -170.8(7) . .
N1 Co1 O5 Dy1 -90.2(6) . .
N3 Co1 O5 Dy1 99.3(6) . .
C45 Co1 O5 Dy1 -171.2(10) . .
O4 Dy1 O5 C45 -72.9(12) 2_353 .
O8 Dy1 O5 C45 -153.9(12) . .
O2 Dy1 O5 C45 83.5(12) 4_656 .
O11 Dy1 O5 C45 6.7(11) . .
O9 Dy1 O5 C45 -14.4(16) 3_454 .
O8 Dy1 O5 C45 -169.7(10) 3_454 .
O1 Dy1 O5 C45 130.1(12) 4_656 .
C22 Dy1 O5 C45 107.2(12) 4_656 .
C46 Dy1 O5 C45 -118(2) 3_454 .
Dy1 Dy1 O5 C45 -159.5(11) 3_454 .
O4 Dy1 O5 Co1 94.0(5) 2_353 .
O8 Dy1 O5 Co1 13.0(5) . .
O2 Dy1 O5 Co1 -109.6(5) 4_656 .
O11 Dy1 O5 Co1 173.6(6) . .
O9 Dy1 O5 Co1 152.5(5) 3_454 .
O8 Dy1 O5 Co1 -2.8(9) 3_454 .
O1 Dy1 O5 Co1 -63.1(5) 4_656 .
C22 Dy1 O5 Co1 -86.0(6) 4_656 .
C46 Dy1 O5 Co1 49(3) 3_454 .
Dy1 Dy1 O5 Co1 7.4(6) 3_454 .
N2 Co1 O6 C45 172.4(7) . .
O10 Co1 O6 C45 -28.0(15) . .
O5 Co1 O6 C45 -0.4(7) . .
N1 Co1 O6 C45 -112.1(8) . .
N3 Co1 O6 C45 95.9(8) . .
O4 Dy1 O8 C46 -131.8(12) 2_353 .
O5 Dy1 O8 C46 -45.3(12) . .
O2 Dy1 O8 C46 60.6(13) 4_656 .
O11 Dy1 O8 C46 -89.4(13) . .
O9 Dy1 O8 C46 152.0(11) 3_454 .
O8 Dy1 O8 C46 126.1(13) 3_454 .
O1 Dy1 O8 C46 36.5(12) 4_656 .
C22 Dy1 O8 C46 46.8(12) 4_656 .
C46 Dy1 O8 C46 139.2(11) 3_454 .
Dy1 Dy1 O8 C46 126.1(13) 3_454 .
O4 Dy1 O8 Dy1 102.1(4) 2_353 3_454
O5 Dy1 O8 Dy1 -171.4(4) . 3_454
O2 Dy1 O8 Dy1 -65.5(5) 4_656 3_454
O11 Dy1 O8 Dy1 144.5(4) . 3_454
O9 Dy1 O8 Dy1 25.9(4) 3_454 3_454
O8 Dy1 O8 Dy1 0.0 3_454 3_454
O1 Dy1 O8 Dy1 -89.6(4) 4_656 3_454
C22 Dy1 O8 Dy1 -79.3(4) 4_656 3_454
C46 Dy1 O8 Dy1 13.1(4) 3_454 3_454
O13 Co2 O9 C46 167.2(7) . .
N5 Co2 O9 C46 5(3) . .
N6 Co2 O9 C46 -83.9(7) . .
N4 Co2 O9 C46 76.4(7) . .
O10 Co2 O9 C46 -5.7(6) . .
O13 Co2 O9 Dy1 30(2) . 3_454
N5 Co2 O9 Dy1 -132(3) . 3_454
N6 Co2 O9 Dy1 139(2) . 3_454
N4 Co2 O9 Dy1 -61(2) . 3_454
O10 Co2 O9 Dy1 -143(2) . 3_454
N2 Co1 O10 C46 173.6(10) . .
O5 Co1 O10 C46 -11.5(11) . .
O6 Co1 O10 C46 13.2(18) . .
N1 Co1 O10 C46 98.0(10) . .
N3 Co1 O10 C46 -110.1(10) . .
C45 Co1 O10 C46 -5.6(12) . .
N2 Co1 O10 Co2 -0.1(8) . .
O5 Co1 O10 Co2 174.8(7) . .
O6 Co1 O10 Co2 -160.4(9) . .
N1 Co1 O10 Co2 -75.6(7) . .
N3 Co1 O10 Co2 76.3(7) . .
C45 Co1 O10 Co2 -179.3(6) . .
O13 Co2 O10 C46 -13.2(13) . .
N5 Co2 O10 C46 -173.0(7) . .
O9 Co2 O10 C46 5.7(6) . .
N6 Co2 O10 C46 114.1(7) . .
N4 Co2 O10 C46 -98.8(7) . .
O13 Co2 O10 Co1 162.0(8) . .
N5 Co2 O10 Co1 2.3(8) . .
O9 Co2 O10 Co1 -179.1(9) . .
N6 Co2 O10 Co1 -70.7(7) . .
N4 Co2 O10 Co1 76.4(8) . .
N5 Co2 O13 C47 140.8(14) . .
O9 Co2 O13 C47 -37.2(14) . .
N6 Co2 O13 C47 -144.9(14) . .
N4 Co2 O13 C47 65.0(14) . .
O10 Co2 O13 C47 -21(2) . .
N2 Co1 N1 C5 -2.2(9) . .
O10 Co1 N1 C5 90.9(9) . .
O5 Co1 N1 C5 -169.1(8) . .
O6 Co1 N1 C5 -107.7(9) . .
N3 Co1 N1 C5 -9.3(14) . .
C45 Co1 N1 C5 -136.7(9) . .
N2 Co1 N1 C1 -179.9(11) . .
O10 Co1 N1 C1 -86.7(11) . .
O5 Co1 N1 C1 13.2(12) . .
O6 Co1 N1 C1 74.7(11) . .
N3 Co1 N1 C1 173.0(10) . .
C45 Co1 N1 C1 45.7(11) . .
O10 Co1 N2 C10 95.8(9) . .
O5 Co1 N2 C10 -63(2) . .
O6 Co1 N2 C10 -90.6(9) . .
N1 Co1 N2 C10 -177.7(10) . .
N3 Co1 N2 C10 -1.2(9) . .
C45 Co1 N2 C10 -85.1(10) . .
O10 Co1 N2 C6 -86.3(9) . .
O5 Co1 N2 C6 115.4(16) . .
O6 Co1 N2 C6 87.2(9) . .
N1 Co1 N2 C6 0.2(9) . .
N3 Co1 N2 C6 176.7(10) . .
C45 Co1 N2 C6 92.8(10) . .
N2 Co1 N3 C15 -177.0(12) . .
O10 Co1 N3 C15 92.3(11) . .
O5 Co1 N3 C15 -9.0(12) . .
O6 Co1 N3 C15 -72.1(11) . .
N1 Co1 N3 C15 -169.9(10) . .
C45 Co1 N3 C15 -41.3(12) . .
N2 Co1 N3 C11 0.5(9) . .
O10 Co1 N3 C11 -90.2(9) . .
O5 Co1 N3 C11 168.5(9) . .
O6 Co1 N3 C11 105.4(9) . .
N1 Co1 N3 C11 7.6(15) . .
C45 Co1 N3 C11 136.2(9) . .
O13 Co2 N4 C23 -92.6(12) . .
N5 Co2 N4 C23 179.1(13) . .
O9 Co2 N4 C23 5.6(13) . .
N6 Co2 N4 C23 149.0(11) . .
O10 Co2 N4 C23 65.4(12) . .
O13 Co2 N4 C27 73.4(9) . .
N5 Co2 N4 C27 -14.9(9) . .
O9 Co2 N4 C27 171.6(9) . .
N6 Co2 N4 C27 -45.0(13) . .
O10 Co2 N4 C27 -128.6(9) . .
O13 Co2 N5 C28 -76.2(10) . .
O9 Co2 N5 C28 86(3) . .
N6 Co2 N5 C28 176.9(11) . .
N4 Co2 N5 C28 13.3(10) . .
O10 Co2 N5 C28 96.3(10) . .
O13 Co2 N5 C32 96.5(10) . .
O9 Co2 N5 C32 -101(3) . .
N6 Co2 N5 C32 -10.4(9) . .
N4 Co2 N5 C32 -174.0(11) . .
O10 Co2 N5 C32 -91.0(10) . .
O13 Co2 N6 C33 -77.3(10) . .
N5 Co2 N6 C33 6.4(9) . .
O9 Co2 N6 C33 179.5(9) . .
N4 Co2 N6 C33 36.6(13) . .
O10 Co2 N6 C33 120.8(9) . .
O13 Co2 N6 C37 103.0(11) . .
N5 Co2 N6 C37 -173.2(11) . .
O9 Co2 N6 C37 -0.1(11) . .
N4 Co2 N6 C37 -143.1(10) . .
O10 Co2 N6 C37 -58.9(10) . .
C5 N1 C1 C2 0(2) . .
Co1 N1 C1 C2 177.8(10) . .
N1 C1 C2 C3 2(2) . .
C1 C2 C3 C4 -2(2) . .
C2 C3 C4 C5 0(2) . .
C1 N1 C5 C4 -2.4(19) . .
Co1 N1 C5 C4 179.7(10) . .
C1 N1 C5 C6 -178.4(11) . .
Co1 N1 C5 C6 3.8(14) . .
C3 C4 C5 N1 3(2) . .
C3 C4 C5 C6 178.3(12) . .
C10 N2 C6 C7 0.1(18) . .
Co1 N2 C6 C7 -177.7(9) . .
C10 N2 C6 C5 179.5(11) . .
Co1 N2 C6 C5 1.6(14) . .
N1 C5 C6 N2 -3.6(16) . .
C4 C5 C6 N2 -179.5(12) . .
N1 C5 C6 C7 175.7(12) . .
C4 C5 C6 C7 0(2) . .
N2 C6 C7 C8 2.6(18) . .
C5 C6 C7 C8 -176.6(12) . .
C6 C7 C8 C9 -5.2(18) . .
C6 C7 C8 C16 171.1(11) . .
C7 C8 C9 C10 5.1(18) . .
C16 C8 C9 C10 -171.1(11) . .
C6 N2 C10 C9 -0.2(18) . .
Co1 N2 C10 C9 177.6(9) . .
C6 N2 C10 C11 -176.2(10) . .
Co1 N2 C10 C11 1.7(14) . .
C8 C9 C10 N2 -2.4(18) . .
C8 C9 C10 C11 173.2(11) . .
C15 N3 C11 C12 1.5(19) . .
Co1 N3 C11 C12 -176.2(10) . .
C15 N3 C11 C10 178.0(11) . .
Co1 N3 C11 C10 0.2(14) . .
N2 C10 C11 N3 -1.2(16) . .
C9 C10 C11 N3 -177.0(12) . .
N2 C10 C11 C12 175.2(12) . .
C9 C10 C11 C12 -1(2) . .
N3 C11 C12 C13 0(2) . .
C10 C11 C12 C13 -176.5(12) . .
C11 C12 C13 C14 0(2) . .
C12 C13 C14 C15 0(2) . .
C11 N3 C15 C14 -2(2) . .
Co1 N3 C15 C14 175.5(10) . .
C13 C14 C15 N3 1(2) . .
C9 C8 C16 C17 -159.4(12) . .
C7 C8 C16 C17 24.4(18) . .
C9 C8 C16 C21 23.2(19) . .
C7 C8 C16 C21 -153.0(12) . .
C21 C16 C17 C18 0.1(19) . .
C8 C16 C17 C18 -177.3(11) . .
C16 C17 C18 C19 -1.8(19) . .
C17 C18 C19 C20 5.6(18) . .
C17 C18 C19 C22 174.2(11) . .
C18 C19 C20 C21 -7.8(18) . .
C22 C19 C20 C21 -176.0(12) . .
C19 C20 C21 C16 6(2) . .
C17 C16 C21 C20 -2(2) . .
C8 C16 C21 C20 175.3(12) . .
Dy1 O1 C22 O2 2.6(12) 4_455 .
Dy1 O1 C22 C19 -178.4(11) 4_455 .
Dy1 O2 C22 O1 -2.7(13) 4_455 .
Dy1 O2 C22 C19 178.2(9) 4_455 .
C20 C19 C22 O1 178.3(12) . .
C18 C19 C22 O1 10.1(18) . .
C20 C19 C22 O2 -2.7(18) . .
C18 C19 C22 O2 -170.9(11) . .
C20 C19 C22 Dy1 16(11) . 4_455
C18 C19 C22 Dy1 -152(10) . 4_455
C27 N4 C23 C24 1(2) . .
Co2 N4 C23 C24 166.5(11) . .
N4 C23 C24 C25 -2(2) . .
C23 C24 C25 C26 2(2) . .
C24 C25 C26 C27 -1(2) . .
C23 N4 C27 C26 -1(2) . .
Co2 N4 C27 C26 -168.0(10) . .
C23 N4 C27 C28 -177.2(12) . .
Co2 N4 C27 C28 15.4(14) . .
C25 C26 C27 N4 1(2) . .
C25 C26 C27 C28 176.9(13) . .
C32 N5 C28 C29 -0.9(19) . .
Co2 N5 C28 C29 171.6(9) . .
C32 N5 C28 C27 178.4(11) . .
Co2 N5 C28 C27 -9.1(15) . .
N4 C27 C28 N5 -4.9(17) . .
C26 C27 C28 N5 178.5(13) . .
N4 C27 C28 C29 174.3(12) . .
C26 C27 C28 C29 -2(2) . .
N5 C28 C29 C30 -1.8(19) . .
C27 C28 C29 C30 178.9(12) . .
C28 C29 C30 C31 2.8(19) . .
C28 C29 C30 C38 -179.0(11) . .
C29 C30 C31 C32 -1.0(18) . .
C38 C30 C31 C32 -179.2(11) . .
C28 N5 C32 C31 2.8(19) . .
Co2 N5 C32 C31 -169.8(9) . .
C28 N5 C32 C33 -175.0(11) . .
Co2 N5 C32 C33 12.4(15) . .
C30 C31 C32 N5 -1.8(18) . .
C30 C31 C32 C33 175.8(11) . .
C37 N6 C33 C34 0.2(19) . .
Co2 N6 C33 C34 -179.5(10) . .
C37 N6 C33 C32 177.5(11) . .
Co2 N6 C33 C32 -2.2(14) . .
N5 C32 C33 N6 -6.3(16) . .
C31 C32 C33 N6 176.0(12) . .
N5 C32 C33 C34 171.0(12) . .
C31 C32 C33 C34 -7(2) . .
N6 C33 C34 C35 1(2) . .
C32 C33 C34 C35 -176.2(12) . .
C33 C34 C35 C36 0(2) . .
C34 C35 C36 C37 -2(2) . .
C33 N6 C37 C36 -2.0(19) . .
Co2 N6 C37 C36 177.7(10) . .
C35 C36 C37 N6 3(2) . .
C29 C30 C38 C43 -149.6(12) . .
C31 C30 C38 C43 28.6(18) . .
C29 C30 C38 C39 28.3(17) . .
C31 C30 C38 C39 -153.5(12) . .
C43 C38 C39 C40 -4.3(17) . .
C30 C38 C39 C40 177.7(11) . .
C38 C39 C40 C41 7.3(17) . .
C39 C40 C41 C42 -5.6(17) . .
C39 C40 C41 C44 -179.5(11) . .
C40 C41 C42 C43 1.0(17) . .
C44 C41 C42 C43 174.7(11) . .
C39 C38 C43 C42 -0.2(18) . .
C30 C38 C43 C42 177.7(11) . .
C41 C42 C43 C38 1.9(18) . .
Dy1 O4 C44 O3 -14(2) 2_343 .
Dy1 O4 C44 C41 165.0(8) 2_343 .
C42 C41 C44 O3 -157.2(12) . .
C40 C41 C44 O3 16.4(18) . .
C42 C41 C44 O4 24.1(17) . .
C40 C41 C44 O4 -162.4(11) . .
Co1 O6 C45 O7 -178.6(13) . .
Co1 O6 C45 O5 0.7(11) . .
Co1 O5 C45 O7 178.6(12) . .
Dy1 O5 C45 O7 -11(2) . .
Co1 O5 C45 O6 -0.7(11) . .
Dy1 O5 C45 O6 169.4(8) . .
Dy1 O5 C45 Co1 170.0(12) . .
N2 Co1 C45 O7 140(24) . .
O10 Co1 C45 O7 -41(24) . .
O5 Co1 C45 O7 -30(24) . .
O6 Co1 C45 O7 151(25) . .
N1 Co1 C45 O7 -138(24) . .
N3 Co1 C45 O7 64(24) . .
N2 Co1 C45 O6 -10.5(10) . .
O10 Co1 C45 O6 168.3(7) . .
O5 Co1 C45 O6 179.3(12) . .
N1 Co1 C45 O6 71.2(8) . .
N3 Co1 C45 O6 -86.5(8) . .
N2 Co1 C45 O5 170.2(6) . .
O10 Co1 C45 O5 -11.0(9) . .
O6 Co1 C45 O5 -179.3(12) . .
N1 Co1 C45 O5 -108.1(7) . .
N3 Co1 C45 O5 94.2(7) . .
Dy1 O8 C46 O10 47.4(18) . .
Dy1 O8 C46 O10 178.1(10) 3_454 .
Dy1 O8 C46 O9 -133.1(10) . .
Dy1 O8 C46 O9 -2.5(11) 3_454 .
Dy1 O8 C46 Dy1 -130.7(11) . 3_454
Co1 O10 C46 O8 -5.7(18) . .
Co2 O10 C46 O8 170.4(11) . .
Co1 O10 C46 O9 174.8(7) . .
Co2 O10 C46 O9 -9.0(10) . .
Co1 O10 C46 Dy1 146(14) . 3_454
Co2 O10 C46 Dy1 -37(14) . 3_454
Co2 O9 C46 O8 -169.5(9) . .
Dy1 O9 C46 O8 2.5(11) 3_454 .
Co2 O9 C46 O10 9.9(11) . .
Dy1 O9 C46 O10 -178.0(9) 3_454 .
Co2 O9 C46 Dy1 -172.0(5) . 3_454
Co2 O13 C47 O12 -171.2(19) . .
C49 N7 C48 O14 179.4(18) . .
C50 N7 C48 O14 -2(3) . .
