#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:57:32 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179401 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/98/4329833.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329833
loop_
_publ_author_name
'Christian Hering'
'Mathias Lehmann'
'Axel Schulz'
'Alexander Villinger'
_publ_contact_author_address
;
Universität Rostock
Institut für Chemie
Abteilung für Anorganische Chemie
Albert-Einstein-Strasse 3a 
18059 Rostock
Bundesrepublik Deutschland
;
_publ_contact_author_email
;
axel.schulz@uni-rostock.de, alexander.villinger@uni-rostock.de'
;
_publ_contact_author_fax         '+49 (0)381/498-6382'
_publ_contact_author_name        'Axel Schulz'
_publ_contact_author_phone       '+49 (0)381/498-6400 or 6403'
_publ_section_title
;
 Chlorine/Methyl Exchange Reactions in Silylated Aminostibanes: A New
 Route To Stibinostibonium Cations
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8212
_journal_page_last               8224
_journal_paper_doi               10.1021/ic300770b
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C27 H34 Cl2 N Sb Si , 0.5(C6 H6)'
_chemical_formula_sum            'C30 H37 Cl2 N Sb Si'
_chemical_formula_weight         632.35
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_author_name               'Villinger, A.'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.728(2)
_cell_angle_beta                 103.704(2)
_cell_angle_gamma                97.391(2)
_cell_formula_units_Z            8
_cell_length_a                   16.8761(6)
_cell_length_b                   19.0256(6)
_cell_length_c                   19.5410(6)
_cell_measurement_reflns_used    9861
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      46.456
_cell_measurement_theta_min      4.322
_cell_volume                     6038.9(3)
_computing_cell_refinement       'Bruker Apex v2.0-2'
_computing_data_collection       'Bruker Apex v2.0-2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker Apex Kappa II-CCD-diffractometer'
_diffrn_measurement_method       'phi and psi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0954
_diffrn_reflns_av_sigmaI/netI    0.1075
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            137362
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    1.149
_exptl_absorpt_correction_T_max  0.9555
_exptl_absorpt_correction_T_min  0.6440
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.391
_exptl_crystal_description       block
_exptl_crystal_F_000             2584
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.891
_refine_diff_density_min         -0.879
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1323
_refine_ls_number_reflns         28661
_refine_ls_number_restraints     17
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.1334
_refine_ls_R_factor_gt           0.0443
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0342P)²+6.8072P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0802
_refine_ls_wR_factor_ref         0.1125
_reflns_number_gt                14754
_reflns_number_total             28661
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic300770b_si_001_05.cif
_cod_data_source_block           is_ch11b
_cod_database_code               4329833
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.64288(2) 0.713410(17) 0.763676(17) 0.02901(9) Uani 1 1 d . . .
Cl1 Cl 0.72367(9) 0.70765(8) 0.88174(7) 0.0444(4) Uani 1 1 d . . .
Cl2A Cl 0.8825(6) 0.6800(5) 0.6595(4) 0.0506(10) Uani 0.553(6) 1 d PD A 1
C26A C 0.859(3) 0.7920(10) 0.765(3) 0.0637(14) Uani 0.553(6) 1 d PD A 1
H26A H 0.8371 0.8189 0.7235 0.096 Uiso 0.553(6) 1 calc PR A 1
H26B H 0.9190 0.8039 0.7788 0.096 Uiso 0.553(6) 1 calc PR A 1
H26C H 0.8352 0.8040 0.8035 0.096 Uiso 0.553(6) 1 calc PR A 1
Cl2B Cl 0.8656(8) 0.8018(3) 0.7650(8) 0.0637(14) Uani 0.447(6) 1 d PD A 2
C26B C 0.877(3) 0.685(3) 0.666(2) 0.0506(10) Uani 0.447(6) 1 d PD A 2
H26D H 0.8484 0.7098 0.6256 0.076 Uiso 0.447(6) 1 calc PR A 2
H26E H 0.8709 0.6341 0.6524 0.076 Uiso 0.447(6) 1 calc PR A 2
H26F H 0.9356 0.7039 0.6782 0.076 Uiso 0.447(6) 1 calc PR A 2
Si1 Si 0.83223(9) 0.69656(8) 0.74149(9) 0.0381(4) Uani 1 1 d D . .
N1 N 0.7261(2) 0.67693(19) 0.7138(2) 0.0258(9) Uani 1 1 d . A .
C1 C 0.6852(3) 0.6301(2) 0.6542(3) 0.0275(11) Uani 1 1 d . . .
C2 C 0.7005(3) 0.5594(2) 0.6483(3) 0.0301(12) Uani 1 1 d . A .
C3 C 0.6609(3) 0.5188(3) 0.5870(3) 0.0394(14) Uani 1 1 d . . .
H3 H 0.6722 0.4716 0.5829 0.047 Uiso 1 1 calc R A .
C4 C 0.6064(4) 0.5440(3) 0.5326(3) 0.0445(14) Uani 1 1 d . A .
H4 H 0.5818 0.5153 0.4910 0.053 Uiso 1 1 calc R . .
C5 C 0.5879(3) 0.6117(3) 0.5395(3) 0.0405(14) Uani 1 1 d . . .
H5 H 0.5485 0.6290 0.5027 0.049 Uiso 1 1 calc R A .
C6 C 0.6250(3) 0.6550(2) 0.5984(3) 0.0295(12) Uani 1 1 d . A .
C7 C 0.5972(3) 0.7265(3) 0.6023(2) 0.0297(12) Uani 1 1 d . . .
C8 C 0.5187(3) 0.7305(3) 0.6137(3) 0.0335(12) Uani 1 1 d . A .
C9 C 0.4908(3) 0.7964(3) 0.6139(3) 0.0372(13) Uani 1 1 d . . .
H9 H 0.4389 0.7992 0.6241 0.045 Uiso 1 1 calc R A .
C10 C 0.5367(3) 0.8575(3) 0.5998(3) 0.0366(13) Uani 1 1 d . A .
C11 C 0.6127(3) 0.8524(3) 0.5860(3) 0.0346(13) Uani 1 1 d . . .
H11 H 0.6447 0.8939 0.5758 0.042 Uiso 1 1 calc R A .
C12 C 0.6433(3) 0.7881(3) 0.5869(3) 0.0315(12) Uani 1 1 d . A .
C13 C 0.7532(3) 0.5240(2) 0.7061(3) 0.0298(12) Uani 1 1 d . . .
C14 C 0.7278(3) 0.5103(2) 0.7690(3) 0.0354(13) Uani 1 1 d . A .
C15 C 0.7763(3) 0.4750(3) 0.8215(3) 0.0377(13) Uani 1 1 d . . .
H15 H 0.7587 0.4658 0.8637 0.045 Uiso 1 1 calc R A .
C16 C 0.8484(3) 0.4529(3) 0.8149(3) 0.0402(14) Uani 1 1 d . A .
C17 C 0.8706(3) 0.4631(3) 0.7517(3) 0.0394(14) Uani 1 1 d . . .
H17 H 0.9192 0.4463 0.7455 0.047 Uiso 1 1 calc R A .
C18 C 0.8241(3) 0.4971(3) 0.6966(3) 0.0341(12) Uani 1 1 d . A .
C19 C 0.4619(3) 0.6656(3) 0.6250(3) 0.0474(15) Uani 1 1 d . . .
H19A H 0.4947 0.6307 0.6500 0.071 Uiso 1 1 calc R A .
H19B H 0.4294 0.6447 0.5792 0.071 Uiso 1 1 calc R . .
H19C H 0.4248 0.6793 0.6530 0.071 Uiso 1 1 calc R . .
C20 C 0.5043(4) 0.9285(3) 0.5979(3) 0.0511(16) Uani 1 1 d . . .
H20A H 0.4595 0.9257 0.6222 0.077 Uiso 1 1 calc R A .
H20B H 0.4836 0.9403 0.5488 0.077 Uiso 1 1 calc R . .
H20C H 0.5488 0.9654 0.6214 0.077 Uiso 1 1 calc R . .
C21 C 0.7252(3) 0.7861(3) 0.5699(3) 0.0472(15) Uani 1 1 d . . .
H21A H 0.7672 0.7826 0.6135 0.071 Uiso 1 1 calc R A .
H21B H 0.7401 0.8296 0.5468 0.071 Uiso 1 1 calc R . .
H21C H 0.7219 0.7449 0.5382 0.071 Uiso 1 1 calc R . .
C22 C 0.6487(3) 0.5292(3) 0.7812(3) 0.0398(14) Uani 1 1 d . . .
H22A H 0.6146 0.5431 0.7368 0.060 Uiso 1 1 calc R A .
H22B H 0.6604 0.5687 0.8163 0.060 Uiso 1 1 calc R . .
H22C H 0.6191 0.4880 0.7984 0.060 Uiso 1 1 calc R . .
C23 C 0.9011(4) 0.4172(3) 0.8743(3) 0.0550(17) Uani 1 1 d . . .
H23A H 0.9524 0.4094 0.8619 0.083 Uiso 1 1 calc R A .
H23B H 0.8712 0.3716 0.8821 0.083 Uiso 1 1 calc R . .
H23C H 0.9140 0.4476 0.9175 0.083 Uiso 1 1 calc R . .
C24 C 0.8517(4) 0.5021(3) 0.6286(3) 0.0463(15) Uani 1 1 d . . .
H24A H 0.9118 0.5135 0.6392 0.069 Uiso 1 1 calc R A .
H24B H 0.8265 0.5395 0.6008 0.069 Uiso 1 1 calc R . .
H24C H 0.8348 0.4567 0.6017 0.069 Uiso 1 1 calc R . .
C25 C 0.6724(3) 0.8263(2) 0.7682(3) 0.0355(13) Uani 1 1 d . . .
H25A H 0.6446 0.8472 0.8006 0.053 Uiso 1 1 calc R . .
H25B H 0.6541 0.8442 0.7211 0.053 Uiso 1 1 calc R . .
H25C H 0.7321 0.8392 0.7851 0.053 Uiso 1 1 calc R . .
C27 C 0.8848(3) 0.6501(3) 0.8183(3) 0.0397(14) Uani 1 1 d D A .
H27A H 0.8844 0.6004 0.8045 0.060 Uiso 1 1 calc R . .
H27B H 0.8561 0.6525 0.8562 0.060 Uiso 1 1 calc R . .
H27C H 0.9418 0.6729 0.8350 0.060 Uiso 1 1 calc R . .
Sb2 Sb 0.33685(2) 0.671033(18) 0.952108(17) 0.02923(9) Uani 1 1 d . . .
Cl3 Cl 0.25649(9) 0.66302(7) 1.03895(7) 0.0419(3) Uani 1 1 d . . .
Cl4A Cl 0.1242(6) 0.7178(3) 0.8648(5) 0.0530(12) Uani 0.539(6) 1 d PD B 1
C54A C 0.097(3) 0.587(2) 0.7615(11) 0.0510(12) Uani 0.539(6) 1 d PD B 1
H54A H 0.1405 0.5774 0.7382 0.076 Uiso 0.539(6) 1 calc PR B 1
H54B H 0.0686 0.6249 0.7376 0.076 Uiso 0.539(6) 1 calc PR B 1
H54C H 0.0581 0.5440 0.7593 0.076 Uiso 0.539(6) 1 calc PR B 1
Cl4B Cl 0.0926(7) 0.5895(6) 0.7513(3) 0.0510(12) Uani 0.461(6) 1 d PD B 2
C54B C 0.128(3) 0.7088(12) 0.857(2) 0.0530(12) Uani 0.461(6) 1 d PD B 2
H54D H 0.1583 0.7357 0.8270 0.080 Uiso 0.461(6) 1 calc PR B 2
H54E H 0.1468 0.7285 0.9057 0.080 Uiso 0.461(6) 1 calc PR B 2
H54F H 0.0688 0.7121 0.8400 0.080 Uiso 0.461(6) 1 calc PR B 2
Si2 Si 0.14423(9) 0.61540(8) 0.85449(8) 0.0351(4) Uani 1 1 d D . .
N2 N 0.2495(2) 0.61303(19) 0.8721(2) 0.0262(9) Uani 1 1 d . B .
C28 C 0.2876(3) 0.5680(3) 0.8322(3) 0.0292(12) Uani 1 1 d . . .
C29 C 0.2623(3) 0.4938(3) 0.8232(3) 0.0292(11) Uani 1 1 d . B .
C30 C 0.2978(3) 0.4554(3) 0.7798(3) 0.0379(13) Uani 1 1 d . . .
H30 H 0.2800 0.4059 0.7721 0.045 Uiso 1 1 calc R B .
C31 C 0.3568(4) 0.4857(3) 0.7480(3) 0.0424(14) Uani 1 1 d . B .
H31 H 0.3779 0.4582 0.7173 0.051 Uiso 1 1 calc R . .
C32 C 0.3849(3) 0.5563(3) 0.7614(3) 0.0361(13) Uani 1 1 d . . .
H32 H 0.4280 0.5772 0.7414 0.043 Uiso 1 1 calc R B .
C33 C 0.3520(3) 0.5983(3) 0.8034(3) 0.0298(12) Uani 1 1 d . B .
C34 C 0.2045(3) 0.4500(2) 0.8590(3) 0.0308(12) Uani 1 1 d . . .
C35 C 0.2259(3) 0.4430(3) 0.9327(3) 0.0357(13) Uani 1 1 d . B .
C36 C 0.1763(4) 0.3955(3) 0.9624(3) 0.0456(15) Uani 1 1 d . . .
H36 H 0.1900 0.3916 1.0121 0.055 Uiso 1 1 calc R B .
C37 C 0.1071(4) 0.3533(3) 0.9227(4) 0.0508(16) Uani 1 1 d . B .
C38 C 0.0884(4) 0.3601(3) 0.8511(3) 0.0479(15) Uani 1 1 d . . .
H38 H 0.0413 0.3316 0.8231 0.057 Uiso 1 1 calc R B .
C39 C 0.1358(3) 0.4071(3) 0.8180(3) 0.0365(13) Uani 1 1 d . B .
C40 C 0.3894(3) 0.6746(3) 0.8148(3) 0.0300(12) Uani 1 1 d . . .
C41 C 0.3509(3) 0.7281(3) 0.7756(3) 0.0336(12) Uani 1 1 d . B .
C42 C 0.3907(3) 0.7963(3) 0.7838(3) 0.0393(14) Uani 1 1 d . . .
H42 H 0.3651 0.8319 0.7565 0.047 Uiso 1 1 calc R B .
C43 C 0.4660(3) 0.8155(3) 0.8299(3) 0.0373(13) Uani 1 1 d . B .
C44 C 0.5045(3) 0.7630(3) 0.8670(3) 0.0345(12) Uani 1 1 d . . .
H44 H 0.5569 0.7754 0.8987 0.041 Uiso 1 1 calc R B .
C45 C 0.4687(3) 0.6921(3) 0.8592(3) 0.0309(12) Uani 1 1 d . B .
C46 C 0.3020(3) 0.4831(3) 0.9793(3) 0.0417(14) Uani 1 1 d . . .
H46A H 0.3426 0.4963 0.9516 0.063 Uiso 1 1 calc R B .
H46B H 0.3250 0.4532 1.0175 0.063 Uiso 1 1 calc R . .
H46C H 0.2882 0.5261 0.9995 0.063 Uiso 1 1 calc R . .
C47 C 0.0554(4) 0.2997(4) 0.9573(4) 0.082(2) Uani 1 1 d . . .
H47A H 0.0916 0.2717 0.9893 0.124 Uiso 1 1 calc R B .
H47B H 0.0169 0.2682 0.9209 0.124 Uiso 1 1 calc R . .
H47C H 0.0245 0.3249 0.9840 0.124 Uiso 1 1 calc R . .
C48 C 0.1095(4) 0.4078(3) 0.7384(3) 0.0483(15) Uani 1 1 d . . .
H48A H 0.0494 0.4036 0.7235 0.072 Uiso 1 1 calc R B .
H48B H 0.1285 0.3679 0.7176 0.072 Uiso 1 1 calc R . .
H48C H 0.1337 0.4525 0.7226 0.072 Uiso 1 1 calc R . .
C49 C 0.2685(3) 0.7104(3) 0.7246(3) 0.0466(15) Uani 1 1 d . . .
H49A H 0.2661 0.6648 0.6998 0.070 Uiso 1 1 calc R B .
H49B H 0.2606 0.7476 0.6903 0.070 Uiso 1 1 calc R . .
H49C H 0.2250 0.7074 0.7504 0.070 Uiso 1 1 calc R . .
C50 C 0.5048(4) 0.8923(3) 0.8397(3) 0.0472(15) Uani 1 1 d . . .
H50A H 0.5091 0.9106 0.7939 0.071 Uiso 1 1 calc R B .
H50B H 0.5599 0.8958 0.8713 0.071 Uiso 1 1 calc R . .
H50C H 0.4706 0.9202 0.8603 0.071 Uiso 1 1 calc R . .
C51 C 0.5163(3) 0.6362(3) 0.8977(3) 0.0363(13) Uani 1 1 d . . .
H51A H 0.5612 0.6591 0.9359 0.054 Uiso 1 1 calc R B .
H51B H 0.5391 0.6106 0.8647 0.054 Uiso 1 1 calc R . .
H51C H 0.4793 0.6027 0.9174 0.054 Uiso 1 1 calc R . .
C52 C 0.3198(3) 0.7805(2) 0.9360(3) 0.0373(13) Uani 1 1 d . . .
H52A H 0.3727 0.8108 0.9524 0.056 Uiso 1 1 calc R . .
H52B H 0.2810 0.7937 0.9626 0.056 Uiso 1 1 calc R . .
H52C H 0.2978 0.7869 0.8857 0.056 Uiso 1 1 calc R . .
C53 C 0.0868(3) 0.5646(3) 0.9110(3) 0.0453(15) Uani 1 1 d D B .
H53A H 0.1125 0.5782 0.9606 0.068 Uiso 1 1 calc R . .
H53B H 0.0875 0.5137 0.9029 0.068 Uiso 1 1 calc R . .
H53C H 0.0297 0.5746 0.8995 0.068 Uiso 1 1 calc R . .
Sb3 Sb 0.66827(2) 0.206921(17) 0.544212(17) 0.02779(9) Uani 1 1 d . . .
Cl5 Cl 0.74773(9) 0.21813(7) 0.45661(7) 0.0420(3) Uani 1 1 d . . .
Cl6A Cl 0.9145(4) 0.1826(4) 0.74101(16) 0.0421(7) Uani 0.721(5) 1 d PD C 1
C80A C 0.879(2) 0.2960(8) 0.6308(18) 0.0459(16) Uani 0.721(5) 1 d PD C 1
H80A H 0.8537 0.3191 0.6636 0.069 Uiso 0.721(5) 1 calc PR C 1
H80B H 0.8545 0.3080 0.5825 0.069 Uiso 0.721(5) 1 calc PR C 1
H80C H 0.9384 0.3125 0.6423 0.069 Uiso 0.721(5) 1 calc PR C 1
Cl6B Cl 0.8843(14) 0.3053(6) 0.6352(12) 0.0459(16) Uani 0.279(5) 1 d PD C 2
C80B C 0.908(4) 0.182(4) 0.7313(16) 0.0421(7) Uani 0.279(5) 1 d PD C 2
H80D H 0.8782 0.2023 0.7620 0.063 Uiso 0.279(5) 1 calc PR C 2
H80E H 0.9661 0.2037 0.7439 0.063 Uiso 0.279(5) 1 calc PR C 2
H80F H 0.9056 0.1306 0.7372 0.063 Uiso 0.279(5) 1 calc PR C 2
Si3 Si 0.86183(9) 0.19866(7) 0.63842(8) 0.0301(3) Uani 1 1 d D . .
N3 N 0.7569(2) 0.17017(19) 0.62223(19) 0.0224(9) Uani 1 1 d . C .
C55 C 0.7210(3) 0.1161(2) 0.6608(2) 0.0222(10) Uani 1 1 d . . .
C56 C 0.6580(3) 0.1301(2) 0.6928(2) 0.0261(11) Uani 1 1 d . C .
C57 C 0.6272(3) 0.0808(3) 0.7347(3) 0.0336(12) Uani 1 1 d . . .
H57 H 0.5850 0.0915 0.7563 0.040 Uiso 1 1 calc R C .
C58 C 0.6565(3) 0.0168(3) 0.7458(3) 0.0353(13) Uani 1 1 d . C .
H58 H 0.6371 -0.0156 0.7767 0.042 Uiso 1 1 calc R . .
C59 C 0.7144(3) 0.0004(3) 0.7112(2) 0.0297(12) Uani 1 1 d . . .
H59 H 0.7329 -0.0447 0.7170 0.036 Uiso 1 1 calc R C .
C60 C 0.7470(3) 0.0481(2) 0.6678(2) 0.0242(11) Uani 1 1 d . C .
C61 C 0.6191(3) 0.1972(2) 0.6834(2) 0.0278(11) Uani 1 1 d . . .
C62 C 0.6573(3) 0.2601(3) 0.7229(2) 0.0306(12) Uani 1 1 d . C .
C63 C 0.6165(3) 0.3200(3) 0.7145(3) 0.0361(13) Uani 1 1 d . . .
H63 H 0.6424 0.3624 0.7410 0.043 Uiso 1 1 calc R C .
C64 C 0.5402(3) 0.3198(3) 0.6693(3) 0.0364(13) Uani 1 1 d . C .
C65 C 0.5022(3) 0.2569(3) 0.6316(3) 0.0330(12) Uani 1 1 d . . .
H65 H 0.4498 0.2559 0.6000 0.040 Uiso 1 1 calc R C .
C66 C 0.5397(3) 0.1951(2) 0.6395(3) 0.0303(12) Uani 1 1 d . C .
C67 C 0.8029(3) 0.0188(2) 0.6285(2) 0.0235(10) Uani 1 1 d . . .
C68 C 0.8739(3) -0.0076(2) 0.6660(3) 0.0281(11) Uani 1 1 d . C .
C69 C 0.9211(3) -0.0403(2) 0.6296(3) 0.0324(12) Uani 1 1 d . . .
H69 H 0.9692 -0.0576 0.6554 0.039 Uiso 1 1 calc R C .
C70 C 0.9001(3) -0.0487(3) 0.5563(3) 0.0346(13) Uani 1 1 d . C .
C71 C 0.8286(3) -0.0243(2) 0.5205(3) 0.0320(12) Uani 1 1 d . . .
H71 H 0.8127 -0.0301 0.4705 0.038 Uiso 1 1 calc R C .
C72 C 0.7792(3) 0.0084(2) 0.5551(2) 0.0240(11) Uani 1 1 d . C .
C73 C 0.7400(3) 0.2635(3) 0.7738(3) 0.0405(14) Uani 1 1 d . . .
H73A H 0.7487 0.2158 0.7896 0.061 Uiso 1 1 calc R C .
H73B H 0.7421 0.2949 0.8145 0.061 Uiso 1 1 calc R . .
H73C H 0.7831 0.2819 0.7503 0.061 Uiso 1 1 calc R . .
C74 C 0.5003(4) 0.3870(3) 0.6594(3) 0.0478(15) Uani 1 1 d . . .
H74A H 0.5005 0.4078 0.7055 0.072 Uiso 1 1 calc R C .
H74B H 0.4435 0.3758 0.6315 0.072 Uiso 1 1 calc R . .
H74C H 0.5312 0.4209 0.6347 0.072 Uiso 1 1 calc R . .
C75 C 0.4915(3) 0.1272(3) 0.6013(3) 0.0367(13) Uani 1 1 d . . .
H75A H 0.4503 0.1390 0.5601 0.055 Uiso 1 1 calc R C .
H75B H 0.4639 0.0999 0.6332 0.055 Uiso 1 1 calc R . .
H75C H 0.5292 0.0989 0.5858 0.055 Uiso 1 1 calc R . .
C76 C 0.9031(3) -0.0015(3) 0.7455(3) 0.0376(13) Uani 1 1 d . . .
H76A H 0.9634 0.0077 0.7590 0.056 Uiso 1 1 calc R C .
H76B H 0.8846 -0.0460 0.7653 0.056 Uiso 1 1 calc R . .
H76C H 0.8803 0.0376 0.7638 0.056 Uiso 1 1 calc R . .
C77 C 0.9510(4) -0.0866(3) 0.5175(3) 0.0533(17) Uani 1 1 d . . .
H77A H 1.0058 -0.0880 0.5483 0.080 Uiso 1 1 calc R C .
H77B H 0.9563 -0.0613 0.4751 0.080 Uiso 1 1 calc R . .
H77C H 0.9239 -0.1352 0.5040 0.080 Uiso 1 1 calc R . .
C78 C 0.7002(3) 0.0283(3) 0.5107(2) 0.0309(12) Uani 1 1 d . . .
H78A H 0.6619 0.0334 0.5405 0.046 Uiso 1 1 calc R C .
H78B H 0.6757 -0.0089 0.4739 0.046 Uiso 1 1 calc R . .
H78C H 0.7117 0.0733 0.4889 0.046 Uiso 1 1 calc R . .
C79 C 0.6863(3) 0.3206(2) 0.5634(3) 0.0350(13) Uani 1 1 d . . .
H79A H 0.6327 0.3380 0.5530 0.053 Uiso 1 1 calc R . .
H79B H 0.7198 0.3430 0.5329 0.053 Uiso 1 1 calc R . .
H79C H 0.7145 0.3322 0.6129 0.053 Uiso 1 1 calc R . .
C81 C 0.9202(3) 0.1594(3) 0.5826(3) 0.0352(13) Uani 1 1 d D C .
H81A H 0.9224 0.1093 0.5930 0.053 Uiso 1 1 calc R . .
H81B H 0.9763 0.1848 0.5923 0.053 Uiso 1 1 calc R . .
H81C H 0.8930 0.1631 0.5328 0.053 Uiso 1 1 calc R . .
Sb4 Sb 0.36348(2) 0.175300(17) 0.736462(17) 0.02769(9) Uani 1 1 d . . .
Cl7 Cl 0.28097(8) 0.15284(7) 0.61807(7) 0.0397(3) Uani 1 1 d . . .
Cl8A Cl 0.1234(2) 0.10398(17) 0.84446(16) 0.0432(7) Uani 0.808(6) 1 d PD D 1
C107 C 0.148(2) 0.2132(9) 0.7309(17) 0.050(3) Uani 0.808(6) 1 d PD D 1
H10V H 0.1747 0.2493 0.7683 0.075 Uiso 0.808(6) 1 calc PR D 1
H10W H 0.0881 0.2128 0.7206 0.075 Uiso 0.808(6) 1 calc PR D 1
H10X H 0.1673 0.2241 0.6883 0.075 Uiso 0.808(6) 1 calc PR D 1
Cl8B Cl 0.149(2) 0.2248(10) 0.7366(18) 0.050(3) Uani 0.192(6) 1 d PD D 2
C139 C 0.122(4) 0.117(4) 0.833(3) 0.0432(7) Uani 0.192(6) 1 d PD D 2
H11A H 0.1525 0.1502 0.8725 0.065 Uiso 0.192(6) 1 calc PR D 2
H11B H 0.1211 0.0684 0.8495 0.065 Uiso 0.192(6) 1 calc PR D 2
H11C H 0.0657 0.1280 0.8175 0.065 Uiso 0.192(6) 1 calc PR D 2
Si4 Si 0.17336(9) 0.12573(7) 0.75999(8) 0.0316(3) Uani 1 1 d D . .
N4 N 0.2790(2) 0.12540(19) 0.78695(19) 0.0249(9) Uani 1 1 d . D .
C82 C 0.3192(3) 0.0871(2) 0.8462(2) 0.0256(11) Uani 1 1 d . . .
C83 C 0.2990(3) 0.0139(2) 0.8520(2) 0.0278(11) Uani 1 1 d . D .
C84 C 0.3385(3) -0.0180(3) 0.9117(3) 0.0369(13) Uani 1 1 d . . .
H84 H 0.3245 -0.0675 0.9159 0.044 Uiso 1 1 calc R D .
C85 C 0.3974(3) 0.0198(3) 0.9649(3) 0.0412(14) Uani 1 1 d . D .
H85 H 0.4219 -0.0031 1.0060 0.049 Uiso 1 1 calc R . .
C86 C 0.4203(3) 0.0906(3) 0.9583(3) 0.0370(13) Uani 1 1 d . . .
H86 H 0.4627 0.1162 0.9941 0.044 Uiso 1 1 calc R D .
C87 C 0.3822(3) 0.1256(3) 0.8996(2) 0.0267(11) Uani 1 1 d . D .
C88 C 0.2391(3) -0.0352(2) 0.7971(3) 0.0297(12) Uani 1 1 d . . .
C89 C 0.1693(3) -0.0734(3) 0.8129(3) 0.0329(12) Uani 1 1 d . D .
C90 C 0.1184(3) -0.1225(3) 0.7637(3) 0.0388(14) Uani 1 1 d . . .
H90 H 0.0700 -0.1463 0.7743 0.047 Uiso 1 1 calc R D .
C91 C 0.1351(3) -0.1381(3) 0.6996(3) 0.0361(13) Uani 1 1 d . D .
C92 C 0.2046(3) -0.1009(3) 0.6856(3) 0.0373(13) Uani 1 1 d . . .
H92 H 0.2168 -0.1104 0.6416 0.045 Uiso 1 1 calc R D .
C93 C 0.2577(3) -0.0504(2) 0.7320(3) 0.0301(12) Uani 1 1 d . D .
C94 C 0.4124(3) 0.2026(3) 0.8970(2) 0.0283(11) Uani 1 1 d . . .
C95 C 0.3669(3) 0.2547(3) 0.9139(3) 0.0335(12) Uani 1 1 d . D .
C96 C 0.3986(3) 0.3258(3) 0.9144(3) 0.0373(13) Uani 1 1 d . . .
H96 H 0.3679 0.3608 0.9257 0.045 Uiso 1 1 calc R D .
C97 C 0.4738(4) 0.3472(3) 0.8989(3) 0.0418(14) Uani 1 1 d . D .
C98 C 0.5178(3) 0.2962(3) 0.8831(3) 0.0410(14) Uani 1 1 d . . .
H98 H 0.5689 0.3105 0.8715 0.049 Uiso 1 1 calc R D .
C99 C 0.4898(3) 0.2234(3) 0.8836(3) 0.0339(12) Uani 1 1 d . D .
C100 C 0.1474(4) -0.0653(3) 0.8832(3) 0.0467(15) Uani 1 1 d . . .
H10A H 0.1748 -0.0197 0.9066 0.070 Uiso 1 1 calc R D .
H10B H 0.1656 -0.1040 0.9131 0.070 Uiso 1 1 calc R . .
H10C H 0.0876 -0.0669 0.8755 0.070 Uiso 1 1 calc R . .
C101 C 0.0811(4) -0.1943(3) 0.6491(3) 0.0521(16) Uani 1 1 d . . .
H10D H 0.0924 -0.1887 0.6024 0.078 Uiso 1 1 calc R D .
H10E H 0.0233 -0.1896 0.6461 0.078 Uiso 1 1 calc R . .
H10F H 0.0924 -0.2412 0.6657 0.078 Uiso 1 1 calc R . .
C102 C 0.3335(3) -0.0160(3) 0.7129(3) 0.0356(13) Uani 1 1 d . . .
H10G H 0.3729 0.0055 0.7555 0.053 Uiso 1 1 calc R D .
H10H H 0.3192 0.0209 0.6793 0.053 Uiso 1 1 calc R . .
H10I H 0.3582 -0.0516 0.6914 0.053 Uiso 1 1 calc R . .
C103 C 0.2870(3) 0.2355(3) 0.9337(3) 0.0465(15) Uani 1 1 d . . .
H10J H 0.2518 0.1997 0.8995 0.070 Uiso 1 1 calc R D .
H10K H 0.2595 0.2779 0.9336 0.070 Uiso 1 1 calc R . .
H10L H 0.2971 0.2164 0.9808 0.070 Uiso 1 1 calc R . .
C104 C 0.5061(4) 0.4252(3) 0.9005(3) 0.0586(18) Uani 1 1 d . . .
H10M H 0.5646 0.4307 0.9004 0.088 Uiso 1 1 calc R D .
H10N H 0.4992 0.4487 0.9432 0.088 Uiso 1 1 calc R . .
H10O H 0.4755 0.4466 0.8588 0.088 Uiso 1 1 calc R . .
C105 C 0.5448(3) 0.1706(3) 0.8713(3) 0.0476(15) Uani 1 1 d . . .
H10P H 0.5809 0.1913 0.8421 0.071 Uiso 1 1 calc R D .
H10Q H 0.5110 0.1276 0.8471 0.071 Uiso 1 1 calc R . .
H10R H 0.5784 0.1585 0.9166 0.071 Uiso 1 1 calc R . .
C106 C 0.3401(3) 0.2835(2) 0.7342(3) 0.0342(13) Uani 1 1 d . . .
H10S H 0.3880 0.3141 0.7259 0.051 Uiso 1 1 calc R . .
H10T H 0.3300 0.2977 0.7794 0.051 Uiso 1 1 calc R . .
H10U H 0.2917 0.2882 0.6961 0.051 Uiso 1 1 calc R . .
C108 C 0.1161(3) 0.0630(3) 0.6868(3) 0.0331(12) Uani 1 1 d D D .
H10Y H 0.1153 0.0144 0.7031 0.050 Uiso 1 1 calc R . .
H10Z H 0.1432 0.0675 0.6476 0.050 Uiso 1 1 calc R . .
H10 H 0.0596 0.0737 0.6711 0.050 Uiso 1 1 calc R . .
C109 C 0.9418(8) 0.5906(13) 0.4578(7) 0.179(10) Uani 0.785(11) 1 d PG E 1
H109 H 0.9960 0.5791 0.4631 0.214 Uiso 0.785(11) 1 calc PR E 1
C110 C 0.8747(15) 0.5375(7) 0.4397(7) 0.176(10) Uani 0.785(11) 1 d PG E 1
H110 H 0.8831 0.4898 0.4326 0.211 Uiso 0.785(11) 1 calc PR E 1
C111 C 0.7954(11) 0.5543(11) 0.4319(5) 0.184(11) Uani 0.785(11) 1 d PG E 1
H111 H 0.7496 0.5181 0.4195 0.220 Uiso 0.785(11) 1 calc PR E 1
C112 C 0.7832(7) 0.6241(13) 0.4422(6) 0.168(9) Uani 0.785(11) 1 d PG E 1
H112 H 0.7289 0.6356 0.4369 0.202 Uiso 0.785(11) 1 calc PR E 1
C113 C 0.8502(14) 0.6772(8) 0.4603(6) 0.137(6) Uani 0.785(11) 1 d PG E 1
H113 H 0.8419 0.7249 0.4674 0.164 Uiso 0.785(11) 1 calc PR E 1
C114 C 0.9296(10) 0.6604(10) 0.4681(6) 0.152(7) Uani 0.785(11) 1 d PG E 1
H114 H 0.9754 0.6966 0.4805 0.182 Uiso 0.785(11) 1 calc PR E 1
C115 C 0.794(4) 0.588(3) 0.449(2) 0.179(10) Uani 0.215(11) 1 d PG E 2
H115 H 0.7618 0.6233 0.4573 0.214 Uiso 0.215(11) 1 calc PR E 2
C116 C 0.756(2) 0.518(3) 0.432(2) 0.152(7) Uani 0.215(11) 1 d PG E 2
H116 H 0.6992 0.5061 0.4295 0.182 Uiso 0.215(11) 1 calc PR E 2
C117 C 0.803(3) 0.466(2) 0.4201(17) 0.137(6) Uani 0.215(11) 1 d PG E 2
H117 H 0.7774 0.4186 0.4088 0.164 Uiso 0.215(11) 1 calc PR E 2
C118 C 0.886(3) 0.484(3) 0.424(2) 0.168(9) Uani 0.215(11) 1 d PG E 2
H118 H 0.9181 0.4483 0.4159 0.202 Uiso 0.215(11) 1 calc PR E 2
C119 C 0.924(2) 0.553(4) 0.441(2) 0.184(11) Uani 0.215(11) 1 d PG E 2
H119 H 0.9807 0.5655 0.4437 0.220 Uiso 0.215(11) 1 calc PR E 2
C120 C 0.877(4) 0.605(2) 0.453(2) 0.176(10) Uani 0.215(11) 1 d PG E 2
H120 H 0.9026 0.6530 0.4644 0.211 Uiso 0.215(11) 1 calc PR E 2
C121 C 0.8927(17) 1.080(3) 0.9138(13) 0.142(12) Uani 0.334(4) 1 d PG F 1
H121 H 0.9378 1.1133 0.9085 0.171 Uiso 0.334(4) 1 calc PR F 1
C122 C 0.818(2) 1.103(2) 0.9136(14) 0.141(9) Uani 0.334(4) 1 d PG F 1
H122 H 0.8113 1.1515 0.9081 0.169 Uiso 0.334(4) 1 calc PR F 1
C123 C 0.7517(17) 1.054(3) 0.9214(17) 0.172(15) Uani 0.334(4) 1 d PG F 1
H123 H 0.7003 1.0699 0.9212 0.206 Uiso 0.334(4) 1 calc PR F 1
C124 C 0.761(3) 0.983(3) 0.9295(19) 0.21(3) Uani 0.334(4) 1 d PG F 1
H124 H 0.7159 0.9500 0.9348 0.248 Uiso 0.334(4) 1 calc PR F 1
C125 C 0.836(3) 0.960(2) 0.9297(17) 0.159(15) Uani 0.334(4) 1 d PG F 1
H125 H 0.8423 0.9118 0.9352 0.190 Uiso 0.334(4) 1 calc PR F 1
C126 C 0.902(2) 1.009(3) 0.9219(15) 0.168(16) Uani 0.334(4) 1 d PG F 1
H126 H 0.9533 0.9935 0.9221 0.202 Uiso 0.334(4) 1 calc PR F 1
C127 C 0.813(4) 0.9991(18) 0.930(2) 0.159(15) Uani 0.251(11) 1 d PG G 2
H127 H 0.7964 0.9495 0.9303 0.190 Uiso 0.251(11) 1 calc PR G 2
C128 C 0.895(3) 1.024(3) 0.9345(17) 0.168(16) Uani 0.251(11) 1 d PG G 2
H128 H 0.9348 0.9923 0.9382 0.202 Uiso 0.251(11) 1 calc PR G 2
C129 C 0.9202(18) 1.097(3) 0.9339(13) 0.142(12) Uani 0.251(11) 1 d PG G 2
H129 H 0.9764 1.1143 0.9371 0.171 Uiso 0.251(11) 1 calc PR G 2
C130 C 0.863(3) 1.1441(18) 0.9285(14) 0.141(9) Uani 0.251(11) 1 d PG G 2
H130 H 0.8797 1.1936 0.9280 0.169 Uiso 0.251(11) 1 calc PR G 2
C131 C 0.781(2) 1.119(3) 0.9238(19) 0.172(15) Uani 0.251(11) 1 d PG G 2
H131 H 0.7413 1.1509 0.9201 0.206 Uiso 0.251(11) 1 calc PR G 2
C132 C 0.756(2) 1.046(3) 0.924(2) 0.21(3) Uani 0.251(11) 1 d PG G 2
H132 H 0.6997 1.0288 0.9212 0.248 Uiso 0.251(11) 1 calc PR G 2
C133 C 0.7668(13) 0.9365(18) 0.9480(9) 0.142(12) Uani 0.415(11) 1 d PG H 3
H133 H 0.7169 0.9137 0.9567 0.171 Uiso 0.415(11) 1 calc PR H 3
C134 C 0.7724(18) 1.0067(17) 0.9285(11) 0.168(16) Uani 0.415(11) 1 d PG H 3
H134 H 0.7263 1.0317 0.9238 0.202 Uiso 0.415(11) 1 calc PR H 3
C135 C 0.845(2) 1.0401(13) 0.9157(13) 0.159(15) Uani 0.415(11) 1 d PG H 3
H135 H 0.8492 1.0880 0.9024 0.190 Uiso 0.415(11) 1 calc PR H 3
C136 C 0.9128(15) 1.0034(19) 0.9225(12) 0.21(3) Uani 0.415(11) 1 d PG H 3
H136 H 0.9627 1.0263 0.9138 0.248 Uiso 0.415(11) 1 calc PR H 3
C137 C 0.9071(14) 0.9333(19) 0.9421(10) 0.172(15) Uani 0.415(11) 1 d PG H 3
H137 H 0.9532 0.9082 0.9467 0.206 Uiso 0.415(11) 1 calc PR H 3
C138 C 0.8342(19) 0.8999(13) 0.9548(9) 0.141(9) Uani 0.415(11) 1 d PG H 3
H138 H 0.8303 0.8519 0.9682 0.169 Uiso 0.415(11) 1 calc PR H 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N1 Sb1 C25 104.48(18)
N1 Sb1 Cl1 96.38(11)
C25 Sb1 Cl1 90.93(14)
Si1 C26A H26A 109.5
Si1 C26A H26B 109.5
Si1 C26A H26C 109.5
Si1 C26B H26D 109.5
Si1 C26B H26E 109.5
H26D C26B H26E 109.5
Si1 C26B H26F 109.5
H26D C26B H26F 109.5
H26E C26B H26F 109.5
N1 Si1 C26A 108.8(15)
N1 Si1 C26B 108.7(17)
C26A Si1 C26B 103(2)
N1 Si1 C27 117.5(2)
C26A Si1 C27 106.5(15)
C26B Si1 C27 110.9(17)
N1 Si1 Cl2A 109.1(3)
C26A Si1 Cl2A 105.1(15)
C26B Si1 Cl2A 2.1(19)
C27 Si1 Cl2A 109.0(3)
N1 Si1 Cl2B 110.6(4)
C26A Si1 Cl2B 2.3(19)
C26B Si1 Cl2B 101.3(17)
C27 Si1 Cl2B 106.7(5)
Cl2A Si1 Cl2B 103.0(5)
C1 N1 Si1 123.4(3)
C1 N1 Sb1 111.5(3)
Si1 N1 Sb1 125.1(2)
C2 C1 N1 122.8(4)
C2 C1 C6 117.8(4)
N1 C1 C6 119.4(4)
C3 C2 C1 118.9(5)
C3 C2 C13 117.7(4)
C1 C2 C13 123.3(4)
C4 C3 C2 123.0(5)
C4 C3 H3 118.5
C2 C3 H3 118.5
C3 C4 C5 118.6(5)
C3 C4 H4 120.7
C5 C4 H4 120.7
C4 C5 C6 121.7(5)
C4 C5 H5 119.2
C6 C5 H5 119.2
C5 C6 C1 120.0(4)
C5 C6 C7 117.4(5)
C1 C6 C7 122.6(4)
C12 C7 C8 119.0(5)
C12 C7 C6 121.5(5)
C8 C7 C6 119.1(4)
C9 C8 C7 119.5(5)
C9 C8 C19 118.0(5)
C7 C8 C19 122.5(5)
C10 C9 C8 121.6(5)
C10 C9 H9 119.2
C8 C9 H9 119.2
C9 C10 C11 118.3(5)
C9 C10 C20 121.1(5)
C11 C10 C20 120.6(5)
C12 C11 C10 121.7(5)
C12 C11 H11 119.1
C10 C11 H11 119.1
C11 C12 C7 119.8(5)
C11 C12 C21 118.8(5)
C7 C12 C21 121.4(5)
C18 C13 C14 118.8(5)
C18 C13 C2 121.1(4)
C14 C13 C2 119.8(4)
C15 C14 C13 119.1(5)
C15 C14 C22 117.6(5)
C13 C14 C22 123.2(5)
C16 C15 C14 122.7(5)
C16 C15 H15 118.7
C14 C15 H15 118.7
C15 C16 C17 117.8(5)
C15 C16 C23 121.1(5)
C17 C16 C23 121.1(5)
C16 C17 C18 122.3(5)
C16 C17 H17 118.8
C18 C17 H17 118.8
C17 C18 C13 119.1(5)
C17 C18 C24 117.8(5)
C13 C18 C24 123.0(5)
C8 C19 H19A 109.5
C8 C19 H19B 109.5
H19A C19 H19B 109.5
C8 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C10 C20 H20A 109.5
C10 C20 H20B 109.5
H20A C20 H20B 109.5
C10 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C12 C21 H21A 109.5
C12 C21 H21B 109.5
H21A C21 H21B 109.5
C12 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C14 C22 H22A 109.5
C14 C22 H22B 109.5
H22A C22 H22B 109.5
C14 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C16 C23 H23A 109.5
C16 C23 H23B 109.5
H23A C23 H23B 109.5
C16 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C18 C24 H24A 109.5
C18 C24 H24B 109.5
H24A C24 H24B 109.5
C18 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
Sb1 C25 H25A 109.5
Sb1 C25 H25B 109.5
H25A C25 H25B 109.5
Sb1 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
Si1 C27 H27A 109.5
Si1 C27 H27B 109.5
H27A C27 H27B 109.5
Si1 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
N2 Sb2 C52 105.72(18)
N2 Sb2 Cl3 96.86(11)
C52 Sb2 Cl3 91.47(14)
Si2 C54A H54A 109.5
Si2 C54A H54B 109.5
Si2 C54A H54C 109.5
Si2 C54B H54D 109.5
Si2 C54B H54E 109.5
H54D C54B H54E 109.5
Si2 C54B H54F 109.5
H54D C54B H54F 109.5
H54E C54B H54F 109.5
N2 Si2 C54B 107.8(15)
N2 Si2 C53 117.3(2)
C54B Si2 C53 109.8(14)
N2 Si2 C54A 109.3(14)
C54B Si2 C54A 103(2)
C53 Si2 C54A 109.1(15)
N2 Si2 Cl4B 109.9(4)
C54B Si2 Cl4B 99.7(15)
C53 Si2 Cl4B 110.8(4)
C54A Si2 Cl4B 2.9(17)
N2 Si2 Cl4A 108.7(3)
C54B Si2 Cl4A 4.4(17)
C53 Si2 Cl4A 105.9(3)
C54A Si2 Cl4A 106.0(14)
Cl4B Si2 Cl4A 103.2(4)
C28 N2 Si2 123.4(3)
C28 N2 Sb2 111.1(3)
Si2 N2 Sb2 125.5(2)
C33 C28 C29 119.3(4)
C33 C28 N2 119.4(4)
C29 C28 N2 121.3(4)
C30 C29 C28 117.6(5)
C30 C29 C34 115.1(4)
C28 C29 C34 127.2(4)
C31 C30 C29 123.0(5)
C31 C30 H30 118.5
C29 C30 H30 118.5
C32 C31 C30 118.6(5)
C32 C31 H31 120.7
C30 C31 H31 120.7
C31 C32 C33 121.7(5)
C31 C32 H32 119.2
C33 C32 H32 119.2
C32 C33 C28 119.4(5)
C32 C33 C40 116.2(5)
C28 C33 C40 124.3(4)
C39 C34 C35 119.4(5)
C39 C34 C29 119.4(5)
C35 C34 C29 120.5(5)
C36 C35 C34 118.7(5)
C36 C35 C46 118.9(5)
C34 C35 C46 122.4(5)
C35 C36 C37 122.8(6)
C35 C36 H36 118.6
C37 C36 H36 118.6
C38 C37 C36 117.5(6)
C38 C37 C47 121.3(6)
C36 C37 C47 121.2(6)
C37 C38 C39 122.6(6)
C37 C38 H38 118.7
C39 C38 H38 118.7
C38 C39 C34 119.1(5)
C38 C39 C48 117.1(5)
C34 C39 C48 123.8(5)
C45 C40 C41 119.3(5)
C45 C40 C33 119.2(4)
C41 C40 C33 121.1(5)
C42 C41 C40 119.0(5)
C42 C41 C49 120.3(5)
C40 C41 C49 120.7(5)
C41 C42 C43 122.7(5)
C41 C42 H42 118.7
C43 C42 H42 118.7
C42 C43 C44 118.3(5)
C42 C43 C50 120.4(5)
C44 C43 C50 121.3(5)
C43 C44 C45 121.8(5)
C43 C44 H44 119.1
C45 C44 H44 119.1
C44 C45 C40 118.7(5)
C44 C45 C51 119.4(5)
C40 C45 C51 121.9(5)
C35 C46 H46A 109.5
C35 C46 H46B 109.5
H46A C46 H46B 109.5
C35 C46 H46C 109.5
H46A C46 H46C 109.5
H46B C46 H46C 109.5
C37 C47 H47A 109.5
C37 C47 H47B 109.5
H47A C47 H47B 109.5
C37 C47 H47C 109.5
H47A C47 H47C 109.5
H47B C47 H47C 109.5
C39 C48 H48A 109.5
C39 C48 H48B 109.5
H48A C48 H48B 109.5
C39 C48 H48C 109.5
H48A C48 H48C 109.5
H48B C48 H48C 109.5
C41 C49 H49A 109.5
C41 C49 H49B 109.5
H49A C49 H49B 109.5
C41 C49 H49C 109.5
H49A C49 H49C 109.5
H49B C49 H49C 109.5
C43 C50 H50A 109.5
C43 C50 H50B 109.5
H50A C50 H50B 109.5
C43 C50 H50C 109.5
H50A C50 H50C 109.5
H50B C50 H50C 109.5
C45 C51 H51A 109.5
C45 C51 H51B 109.5
H51A C51 H51B 109.5
C45 C51 H51C 109.5
H51A C51 H51C 109.5
H51B C51 H51C 109.5
Sb2 C52 H52A 109.5
Sb2 C52 H52B 109.5
H52A C52 H52B 109.5
Sb2 C52 H52C 109.5
H52A C52 H52C 109.5
H52B C52 H52C 109.5
Si2 C53 H53A 109.5
Si2 C53 H53B 109.5
H53A C53 H53B 109.5
Si2 C53 H53C 109.5
H53A C53 H53C 109.5
H53B C53 H53C 109.5
N3 Sb3 C79 105.03(17)
N3 Sb3 Cl5 96.58(10)
C79 Sb3 Cl5 91.14(14)
Si3 C80A H80A 109.5
Si3 C80A H80B 109.5
Si3 C80A H80C 109.5
Si3 C80B H80D 109.5
Si3 C80B H80E 109.5
H80D C80B H80E 109.5
Si3 C80B H80F 109.5
H80D C80B H80F 109.5
H80E C80B H80F 109.5
N3 Si3 C81 117.8(2)
N3 Si3 C80B 108(2)
C81 Si3 C80B 108(2)
N3 Si3 C80A 109.4(11)
C81 Si3 C80A 107.1(11)
C80B Si3 C80A 106(3)
N3 Si3 Cl6B 110.9(7)
C81 Si3 Cl6B 108.1(7)
C80B Si3 Cl6B 103(3)
C80A Si3 Cl6B 2.9(17)
N3 Si3 Cl6A 108.7(2)
C81 Si3 Cl6A 108.3(3)
C80B Si3 Cl6A 1(3)
C80A Si3 Cl6A 104.8(11)
Cl6B Si3 Cl6A 101.9(7)
C55 N3 Si3 123.8(3)
C55 N3 Sb3 111.4(3)
Si3 N3 Sb3 124.8(2)
C56 C55 C60 118.1(4)
C56 C55 N3 119.8(4)
C60 C55 N3 122.0(4)
C57 C56 C55 120.7(4)
C57 C56 C61 115.9(4)
C55 C56 C61 123.4(4)
C58 C57 C56 121.2(5)
C58 C57 H57 119.4
C56 C57 H57 119.4
C57 C58 C59 118.8(5)
C57 C58 H58 120.6
C59 C58 H58 120.6
C58 C59 C60 122.2(5)
C58 C59 H59 118.9
C60 C59 H59 118.9
C59 C60 C55 118.7(4)
C59 C60 C67 115.0(4)
C55 C60 C67 126.2(4)
C66 C61 C62 119.6(4)
C66 C61 C56 119.0(4)
C62 C61 C56 121.2(4)
C63 C62 C61 118.7(5)
C63 C62 C73 119.9(4)
C61 C62 C73 121.3(4)
C64 C63 C62 122.5(5)
C64 C63 H63 118.7
C62 C63 H63 118.7
C63 C64 C65 118.3(5)
C63 C64 C74 120.5(5)
C65 C64 C74 121.2(5)
C64 C65 C66 121.4(5)
C64 C65 H65 119.3
C66 C65 H65 119.3
C65 C66 C61 119.4(5)
C65 C66 C75 118.2(5)
C61 C66 C75 122.3(4)
C72 C67 C68 119.1(4)
C72 C67 C60 120.5(4)
C68 C67 C60 119.9(4)
C69 C68 C67 119.6(5)
C69 C68 C76 117.1(4)
C67 C68 C76 123.3(4)
C68 C69 C70 122.0(5)
C68 C69 H69 119.0
C70 C69 H69 119.0
C71 C70 C69 117.6(5)
C71 C70 C77 121.1(5)
C69 C70 C77 121.3(5)
C70 C71 C72 122.1(5)
C70 C71 H71 118.9
C72 C71 H71 118.9
C71 C72 C67 119.5(4)
C71 C72 C78 117.1(4)
C67 C72 C78 123.3(4)
C62 C73 H73A 109.5
C62 C73 H73B 109.5
H73A C73 H73B 109.5
C62 C73 H73C 109.5
H73A C73 H73C 109.5
H73B C73 H73C 109.5
C64 C74 H74A 109.5
C64 C74 H74B 109.5
H74A C74 H74B 109.5
C64 C74 H74C 109.5
H74A C74 H74C 109.5
H74B C74 H74C 109.5
C66 C75 H75A 109.5
C66 C75 H75B 109.5
H75A C75 H75B 109.5
C66 C75 H75C 109.5
H75A C75 H75C 109.5
H75B C75 H75C 109.5
C68 C76 H76A 109.5
C68 C76 H76B 109.5
H76A C76 H76B 109.5
C68 C76 H76C 109.5
H76A C76 H76C 109.5
H76B C76 H76C 109.5
C70 C77 H77A 109.5
C70 C77 H77B 109.5
H77A C77 H77B 109.5
C70 C77 H77C 109.5
H77A C77 H77C 109.5
H77B C77 H77C 109.5
C72 C78 H78A 109.5
C72 C78 H78B 109.5
H78A C78 H78B 109.5
C72 C78 H78C 109.5
H78A C78 H78C 109.5
H78B C78 H78C 109.5
Sb3 C79 H79A 109.5
Sb3 C79 H79B 109.5
H79A C79 H79B 109.5
Sb3 C79 H79C 109.5
H79A C79 H79C 109.5
H79B C79 H79C 109.5
Si3 C81 H81A 109.5
Si3 C81 H81B 109.5
H81A C81 H81B 109.5
Si3 C81 H81C 109.5
H81A C81 H81C 109.5
H81B C81 H81C 109.5
N4 Sb4 C106 103.82(17)
N4 Sb4 Cl7 97.18(11)
C106 Sb4 Cl7 90.56(14)
Si4 C107 H10V 109.5
Si4 C107 H10W 109.5
Si4 C107 H10X 109.5
Si4 C139 H11A 109.5
Si4 C139 H11B 109.5
H11A C139 H11B 109.5
Si4 C139 H11C 109.5
H11A C139 H11C 109.5
H11B C139 H11C 109.5
N4 Si4 C107 111.7(11)
N4 Si4 C139 113(2)
C107 Si4 C139 99(2)
N4 Si4 C108 117.1(2)
C107 Si4 C108 104.9(10)
C139 Si4 C108 109(3)
N4 Si4 Cl8B 109.8(10)
C107 Si4 Cl8B 5(2)
C139 Si4 Cl8B 96(2)
C108 Si4 Cl8B 109.6(10)
N4 Si4 Cl8A 108.46(18)
C107 Si4 Cl8A 106.9(10)
C139 Si4 Cl8A 8(2)
C108 Si4 Cl8A 107.3(2)
Cl8B Si4 Cl8A 103.7(10)
C82 N4 Si4 124.4(3)
C82 N4 Sb4 111.0(3)
Si4 N4 Sb4 124.6(2)
C83 C82 C87 119.1(4)
C83 C82 N4 122.7(4)
C87 C82 N4 118.2(4)
C84 C83 C82 118.9(4)
C84 C83 C88 115.6(4)
C82 C83 C88 125.5(4)
C85 C84 C83 122.0(5)
C85 C84 H84 119.0
C83 C84 H84 119.0
C86 C85 C84 119.5(5)
C86 C85 H85 120.2
C84 C85 H85 120.2
C85 C86 C87 120.9(5)
C85 C86 H86 119.6
C87 C86 H86 119.6
C86 C87 C82 119.5(5)
C86 C87 C94 116.7(4)
C82 C87 C94 123.8(4)
C89 C88 C93 118.8(5)
C89 C88 C83 120.4(4)
C93 C88 C83 120.3(5)
C90 C89 C88 119.7(5)
C90 C89 C100 117.3(5)
C88 C89 C100 123.0(5)
C89 C90 C91 122.5(5)
C89 C90 H90 118.7
C91 C90 H90 118.7
C92 C91 C90 116.8(5)
C92 C91 C101 121.9(5)
C90 C91 C101 121.2(5)
C91 C92 C93 123.7(5)
C91 C92 H92 118.2
C93 C92 H92 118.2
C92 C93 C88 118.5(5)
C92 C93 C102 119.1(5)
C88 C93 C102 122.4(5)
C99 C94 C95 119.4(5)
C99 C94 C87 119.8(4)
C95 C94 C87 120.5(5)
C96 C95 C94 119.1(5)
C96 C95 C103 119.0(5)
C94 C95 C103 121.8(5)
C97 C96 C95 122.0(5)
C97 C96 H96 119.0
C95 C96 H96 119.0
C98 C97 C96 118.5(5)
C98 C97 C104 121.3(6)
C96 C97 C104 120.2(5)
C97 C98 C99 122.0(5)
C97 C98 H98 119.0
C99 C98 H98 119.0
C94 C99 C98 118.8(5)
C94 C99 C105 122.3(5)
C98 C99 C105 118.9(5)
C89 C100 H10A 109.5
C89 C100 H10B 109.5
H10A C100 H10B 109.5
C89 C100 H10C 109.5
H10A C100 H10C 109.5
H10B C100 H10C 109.5
C91 C101 H10D 109.5
C91 C101 H10E 109.5
H10D C101 H10E 109.5
C91 C101 H10F 109.5
H10D C101 H10F 109.5
H10E C101 H10F 109.5
C93 C102 H10G 109.5
C93 C102 H10H 109.5
H10G C102 H10H 109.5
C93 C102 H10I 109.5
H10G C102 H10I 109.5
H10H C102 H10I 109.5
C95 C103 H10J 109.5
C95 C103 H10K 109.5
H10J C103 H10K 109.5
C95 C103 H10L 109.5
H10J C103 H10L 109.5
H10K C103 H10L 109.5
C97 C104 H10M 109.5
C97 C104 H10N 109.5
H10M C104 H10N 109.5
C97 C104 H10O 109.5
H10M C104 H10O 109.5
H10N C104 H10O 109.5
C99 C105 H10P 109.5
C99 C105 H10Q 109.5
H10P C105 H10Q 109.5
C99 C105 H10R 109.5
H10P C105 H10R 109.5
H10Q C105 H10R 109.5
Sb4 C106 H10S 109.5
Sb4 C106 H10T 109.5
H10S C106 H10T 109.5
Sb4 C106 H10U 109.5
H10S C106 H10U 109.5
H10T C106 H10U 109.5
Si4 C108 H10Y 109.5
Si4 C108 H10Z 109.5
H10Y C108 H10Z 109.5
Si4 C108 H10 109.5
H10Y C108 H10 109.5
H10Z C108 H10 109.5
C110 C109 C114 120.0
C110 C109 H109 120.0
C114 C109 H109 120.0
C109 C110 C111 120.0
C109 C110 H110 120.0
C111 C110 H110 120.0
C112 C111 C110 120.0
C112 C111 H111 120.0
C110 C111 H111 120.0
C113 C112 C111 120.0
C113 C112 H112 120.0
C111 C112 H112 120.0
C112 C113 C114 120.0
C112 C113 H113 120.0
C114 C113 H113 120.0
C113 C114 C109 120.0
C113 C114 H114 120.0
C109 C114 H114 120.0
C116 C115 C120 120.0
C116 C115 H115 120.0
C120 C115 H115 120.0
C115 C116 C117 120.0
C115 C116 H116 120.0
C117 C116 H116 120.0
C118 C117 C116 120.0
C118 C117 H117 120.0
C116 C117 H117 120.0
C117 C118 C119 120.0
C117 C118 H118 120.0
C119 C118 H118 120.0
C120 C119 C118 120.0
C120 C119 H119 120.0
C118 C119 H119 120.0
C119 C120 C115 120.0
C119 C120 H120 120.0
C115 C120 H120 120.0
C122 C121 C126 120.00(6)
C122 C121 H121 120.0
C126 C121 H121 120.0
C123 C122 C121 120.0
C123 C122 H122 120.0
C121 C122 H122 120.0
C124 C123 C122 120.0
C124 C123 H123 120.0
C122 C123 H123 120.0
C123 C124 C125 120.00(6)
C123 C124 H124 120.0
C125 C124 H124 120.0
C126 C125 C124 120.0
C126 C125 H125 120.0
C124 C125 H125 120.0
C125 C126 C121 120.0
C125 C126 H126 120.0
C121 C126 H126 120.0
C128 C127 C132 120.0
C128 C127 H127 120.0
C132 C127 H127 120.0
C129 C128 C127 120.0
C129 C128 H128 120.0
C127 C128 H128 120.0
C128 C129 C130 120.0
C128 C129 H129 120.0
C130 C129 H129 120.0
C131 C130 C129 120.0
C131 C130 H130 120.0
C129 C130 H130 120.0
C132 C131 C130 120.0
C132 C131 H131 120.0
C130 C131 H131 120.0
C131 C132 C127 120.0
C131 C132 H132 120.0
C127 C132 H132 120.0
C134 C133 C138 120.0
C134 C133 H133 120.0
C138 C133 H133 120.0
C133 C134 C135 120.0
C133 C134 H134 120.0
C135 C134 H134 120.0
C136 C135 C134 120.0
C136 C135 H135 120.0
C134 C135 H135 120.0
C135 C136 C137 120.0
C135 C136 H136 120.0
C137 C136 H136 120.0
C138 C137 C136 120.0
C138 C137 H137 120.0
C136 C137 H137 120.0
C137 C138 C133 120.0
C137 C138 H138 120.0
C133 C138 H138 120.0
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Sb1 N1 2.071(4)
Sb1 C25 2.137(5)
Sb1 Cl1 2.3975(13)
Cl2A Si1 2.022(5)
C26A Si1 1.838(17)
C26A H26A 0.9800
C26A H26B 0.9800
C26A H26C 0.9800
Cl2B Si1 2.025(6)
C26B Si1 1.842(18)
C26B H26D 0.9800
C26B H26E 0.9800
C26B H26F 0.9800
Si1 N1 1.733(4)
Si1 C27 1.851(5)
N1 C1 1.435(6)
C1 C2 1.410(6)
C1 C6 1.435(7)
C2 C3 1.393(7)
C2 C13 1.490(7)
C3 C4 1.366(7)
C3 H3 0.9500
C4 C5 1.376(7)
C4 H4 0.9500
C5 C6 1.378(7)
C5 H5 0.9500
C6 C7 1.500(7)
C7 C12 1.399(7)
C7 C8 1.405(7)
C8 C9 1.394(7)
C8 C19 1.516(7)
C9 C10 1.381(7)
C9 H9 0.9500
C10 C11 1.387(7)
C10 C20 1.519(7)
C11 C12 1.387(7)
C11 H11 0.9500
C12 C21 1.501(7)
C13 C18 1.410(7)
C13 C14 1.411(7)
C14 C15 1.392(7)
C14 C22 1.496(7)
C15 C16 1.371(7)
C15 H15 0.9500
C16 C17 1.383(7)
C16 C23 1.511(7)
C17 C18 1.393(7)
C17 H17 0.9500
C18 C24 1.508(7)
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
C21 H21A 0.9800
C21 H21B 0.9800
C21 H21C 0.9800
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 H23A 0.9800
C23 H23B 0.9800
C23 H23C 0.9800
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 H25A 0.9800
C25 H25B 0.9800
C25 H25C 0.9800
C27 H27A 0.9800
C27 H27B 0.9800
C27 H27C 0.9800
Sb2 N2 2.068(4)
Sb2 C52 2.156(5)
Sb2 Cl3 2.4054(13)
Cl4A Si2 2.036(4)
C54A Si2 1.845(17)
C54A H54A 0.9800
C54A H54B 0.9800
C54A H54C 0.9800
Cl4B Si2 2.024(6)
C54B Si2 1.837(17)
C54B H54D 0.9800
C54B H54E 0.9800
C54B H54F 0.9800
Si2 N2 1.734(4)
Si2 C53 1.840(5)
N2 C28 1.456(6)
C28 C33 1.402(7)
C28 C29 1.417(7)
C29 C30 1.396(7)
C29 C34 1.504(7)
C30 C31 1.366(7)
C30 H30 0.9500
C31 C32 1.366(7)
C31 H31 0.9500
C32 C33 1.392(7)
C32 H32 0.9500
C33 C40 1.497(7)
C34 C39 1.397(7)
C34 C35 1.412(7)
C35 C36 1.379(7)
C35 C46 1.496(7)
C36 C37 1.386(8)
C36 H36 0.9500
C37 C38 1.371(8)
C37 C47 1.525(8)
C38 C39 1.390(7)
C38 H38 0.9500
C39 C48 1.514(7)
C40 C45 1.407(7)
C40 C41 1.415(6)
C41 C42 1.372(7)
C41 C49 1.502(7)
C42 C43 1.375(7)
C42 H42 0.9500
C43 C44 1.381(7)
C43 C50 1.513(7)
C44 C45 1.396(7)
C44 H44 0.9500
C45 C51 1.515(6)
C46 H46A 0.9800
C46 H46B 0.9800
C46 H46C 0.9800
C47 H47A 0.9800
C47 H47B 0.9800
C47 H47C 0.9800
C48 H48A 0.9800
C48 H48B 0.9800
C48 H48C 0.9800
C49 H49A 0.9800
C49 H49B 0.9800
C49 H49C 0.9800
C50 H50A 0.9800
C50 H50B 0.9800
C50 H50C 0.9800
C51 H51A 0.9800
C51 H51B 0.9800
C51 H51C 0.9800
C52 H52A 0.9800
C52 H52B 0.9800
C52 H52C 0.9800
C53 H53A 0.9800
C53 H53B 0.9800
C53 H53C 0.9800
Sb3 N3 2.066(4)
Sb3 C79 2.160(5)
Sb3 Cl5 2.4078(13)
Cl6A Si3 2.036(3)
C80A Si3 1.851(15)
C80A H80A 0.9800
C80A H80B 0.9800
C80A H80C 0.9800
Cl6B Si3 2.020(10)
C80B Si3 1.848(19)
C80B H80D 0.9800
C80B H80E 0.9800
C80B H80F 0.9800
Si3 N3 1.736(4)
Si3 C81 1.844(5)
N3 C55 1.439(6)
C55 C56 1.406(6)
C55 C60 1.417(6)
C56 C57 1.385(7)
C56 C61 1.503(6)
C57 C58 1.374(7)
C57 H57 0.9500
C58 C59 1.376(7)
C58 H58 0.9500
C59 C60 1.399(6)
C59 H59 0.9500
C60 C67 1.501(6)
C61 C66 1.405(7)
C61 C62 1.408(6)
C62 C63 1.397(7)
C62 C73 1.502(7)
C63 C64 1.378(7)
C63 H63 0.9500
C64 C65 1.393(7)
C64 C74 1.514(7)
C65 C66 1.398(6)
C65 H65 0.9500
C66 C75 1.518(7)
C67 C72 1.400(6)
C67 C68 1.404(6)
C68 C69 1.383(7)
C68 C76 1.513(7)
C69 C70 1.393(7)
C69 H69 0.9500
C70 C71 1.384(7)
C70 C77 1.513(7)
C71 C72 1.388(6)
C71 H71 0.9500
C72 C78 1.504(6)
C73 H73A 0.9800
C73 H73B 0.9800
C73 H73C 0.9800
C74 H74A 0.9800
C74 H74B 0.9800
C74 H74C 0.9800
C75 H75A 0.9800
C75 H75B 0.9800
C75 H75C 0.9800
C76 H76A 0.9800
C76 H76B 0.9800
C76 H76C 0.9800
C77 H77A 0.9800
C77 H77B 0.9800
C77 H77C 0.9800
C78 H78A 0.9800
C78 H78B 0.9800
C78 H78C 0.9800
C79 H79A 0.9800
C79 H79B 0.9800
C79 H79C 0.9800
C81 H81A 0.9800
C81 H81B 0.9800
C81 H81C 0.9800
Sb4 N4 2.061(4)
Sb4 C106 2.144(4)
Sb4 Cl7 2.4020(13)
Cl8A Si4 2.048(2)
C107 Si4 1.835(13)
C107 H10V 0.9800
C107 H10W 0.9800
C107 H10X 0.9800
Cl8B Si4 2.015(15)
C139 Si4 1.842(18)
C139 H11A 0.9800
C139 H11B 0.9800
C139 H11C 0.9800
Si4 N4 1.736(4)
Si4 C108 1.846(5)
N4 C82 1.452(6)
C82 C83 1.404(6)
C82 C87 1.417(6)
C83 C84 1.389(6)
C83 C88 1.505(7)
C84 C85 1.376(7)
C84 H84 0.9500
C85 C86 1.369(7)
C85 H85 0.9500
C86 C87 1.397(6)
C86 H86 0.9500
C87 C94 1.494(7)
C88 C89 1.404(7)
C88 C93 1.415(7)
C89 C90 1.382(7)
C89 C100 1.517(7)
C90 C91 1.386(7)
C90 H90 0.9500
C91 C92 1.376(7)
C91 C101 1.497(7)
C92 C93 1.386(7)
C92 H92 0.9500
C93 C102 1.490(7)
C94 C99 1.402(7)
C94 C95 1.411(7)
C95 C96 1.388(7)
C95 C103 1.492(7)
C96 C97 1.384(7)
C96 H96 0.9500
C97 C98 1.370(8)
C97 C104 1.511(7)
C98 C99 1.405(7)
C98 H98 0.9500
C99 C105 1.506(7)
C100 H10A 0.9800
C100 H10B 0.9800
C100 H10C 0.9800
C101 H10D 0.9800
C101 H10E 0.9800
C101 H10F 0.9800
C102 H10G 0.9800
C102 H10H 0.9800
C102 H10I 0.9800
C103 H10J 0.9800
C103 H10K 0.9800
C103 H10L 0.9800
C104 H10M 0.9800
C104 H10N 0.9800
C104 H10O 0.9800
C105 H10P 0.9800
C105 H10Q 0.9800
C105 H10R 0.9800
C106 H10S 0.9800
C106 H10T 0.9800
C106 H10U 0.9800
C108 H10Y 0.9800
C108 H10Z 0.9800
C108 H10 0.9800
C109 C110 1.3900
C109 C114 1.3900
C109 H109 0.9500
C110 C111 1.3900
C110 H110 0.9500
C111 C112 1.3900
C111 H111 0.9500
C112 C113 1.3900
C112 H112 0.9500
C113 C114 1.3900
C113 H113 0.9500
C114 H114 0.9500
C115 C116 1.3900
C115 C120 1.3900
C115 H115 0.9500
C116 C117 1.3900
C116 H116 0.9500
C117 C118 1.3900
C117 H117 0.9500
C118 C119 1.3900
C118 H118 0.9500
C119 C120 1.3900
C119 H119 0.9500
C120 H120 0.9500
C121 C122 1.3900
C121 C126 1.3900
C121 H121 0.9500
C122 C123 1.3900
C122 H122 0.9500
C123 C124 1.3900
C123 H123 0.9500
C124 C125 1.3900
C124 H124 0.9500
C125 C126 1.3900
C125 H125 0.9500
C126 H126 0.9500
C127 C128 1.3900
C127 C132 1.3900
C127 H127 0.9500
C128 C129 1.3900
C128 H128 0.9500
C129 C130 1.3900
C129 H129 0.9500
C130 C131 1.3900
C130 H130 0.9500
C131 C132 1.3900
C131 H131 0.9500
C132 H132 0.9500
C133 C134 1.3900
C133 C138 1.3900
C133 H133 0.9500
C134 C135 1.3900
C134 H134 0.9500
C135 C136 1.3900
C135 H135 0.9500
C136 C137 1.3900
C136 H136 0.9500
C137 C138 1.3900
C137 H137 0.9500
C138 H138 0.9500
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C26A Si1 N1 C1 137.7(17)
C26B Si1 N1 C1 25.8(18)
C27 Si1 N1 C1 -101.1(4)
Cl2A Si1 N1 C1 23.5(5)
Cl2B Si1 N1 C1 136.1(6)
C26A Si1 N1 Sb1 -45.2(16)
C26B Si1 N1 Sb1 -157.2(17)
C27 Si1 N1 Sb1 75.9(3)
Cl2A Si1 N1 Sb1 -159.4(3)
Cl2B Si1 N1 Sb1 -46.8(5)
C25 Sb1 N1 C1 -126.6(3)
Cl1 Sb1 N1 C1 140.8(3)
C25 Sb1 N1 Si1 56.0(3)
Cl1 Sb1 N1 Si1 -36.6(2)
Si1 N1 C1 C2 56.4(6)
Sb1 N1 C1 C2 -121.0(4)
Si1 N1 C1 C6 -124.7(4)
Sb1 N1 C1 C6 57.9(5)
N1 C1 C2 C3 -177.0(4)
C6 C1 C2 C3 4.2(7)
N1 C1 C2 C13 6.9(7)
C6 C1 C2 C13 -172.0(4)
C1 C2 C3 C4 -1.3(8)
C13 C2 C3 C4 175.1(5)
C2 C3 C4 C5 -2.0(9)
C3 C4 C5 C6 2.3(8)
C4 C5 C6 C1 0.7(8)
C4 C5 C6 C7 -176.9(5)
C2 C1 C6 C5 -3.9(7)
N1 C1 C6 C5 177.1(4)
C2 C1 C6 C7 173.5(4)
N1 C1 C6 C7 -5.4(7)
C5 C6 C7 C12 -101.3(6)
C1 C6 C7 C12 81.2(6)
C5 C6 C7 C8 71.2(6)
C1 C6 C7 C8 -106.3(6)
C12 C7 C8 C9 -4.2(7)
C6 C7 C8 C9 -176.9(4)
C12 C7 C8 C19 175.1(5)
C6 C7 C8 C19 2.5(7)
C7 C8 C9 C10 3.3(8)
C19 C8 C9 C10 -176.0(5)
C8 C9 C10 C11 -0.9(8)
C8 C9 C10 C20 177.9(5)
C9 C10 C11 C12 -0.6(7)
C20 C10 C11 C12 -179.5(5)
C10 C11 C12 C7 -0.3(8)
C10 C11 C12 C21 178.6(5)
C8 C7 C12 C11 2.7(7)
C6 C7 C12 C11 175.2(4)
C8 C7 C12 C21 -176.1(5)
C6 C7 C12 C21 -3.6(7)
C3 C2 C13 C18 63.5(7)
C1 C2 C13 C18 -120.3(5)
C3 C2 C13 C14 -109.8(5)
C1 C2 C13 C14 66.4(7)
C18 C13 C14 C15 4.4(7)
C2 C13 C14 C15 177.8(4)
C18 C13 C14 C22 -172.9(5)
C2 C13 C14 C22 0.5(7)
C13 C14 C15 C16 0.2(8)
C22 C14 C15 C16 177.6(5)
C14 C15 C16 C17 -3.6(8)
C14 C15 C16 C23 177.6(5)
C15 C16 C17 C18 2.6(8)
C23 C16 C17 C18 -178.6(5)
C16 C17 C18 C13 1.9(8)
C16 C17 C18 C24 -177.1(5)
C14 C13 C18 C17 -5.3(7)
C2 C13 C18 C17 -178.7(4)
C14 C13 C18 C24 173.5(5)
C2 C13 C18 C24 0.2(8)
C54B Si2 N2 C28 -135.3(15)
C53 Si2 N2 C28 100.2(4)
C54A Si2 N2 C28 -24.6(15)
Cl4B Si2 N2 C28 -27.5(5)
Cl4A Si2 N2 C28 -139.8(4)
C54B Si2 N2 Sb2 45.7(15)
C53 Si2 N2 Sb2 -78.7(3)
C54A Si2 N2 Sb2 156.5(15)
Cl4B Si2 N2 Sb2 153.5(4)
Cl4A Si2 N2 Sb2 41.2(4)
C52 Sb2 N2 C28 124.8(3)
Cl3 Sb2 N2 C28 -141.7(3)
C52 Sb2 N2 Si2 -56.1(3)
Cl3 Sb2 N2 Si2 37.4(2)
Si2 N2 C28 C33 127.4(4)
Sb2 N2 C28 C33 -53.6(5)
Si2 N2 C28 C29 -54.3(6)
Sb2 N2 C28 C29 124.8(4)
C33 C28 C29 C30 -6.3(7)
N2 C28 C29 C30 175.4(4)
C33 C28 C29 C34 169.7(5)
N2 C28 C29 C34 -8.6(7)
C28 C29 C30 C31 2.2(8)
C34 C29 C30 C31 -174.3(5)
C29 C30 C31 C32 2.6(8)
C30 C31 C32 C33 -3.3(8)
C31 C32 C33 C28 -0.9(8)
C31 C32 C33 C40 178.9(5)
C29 C28 C33 C32 5.7(7)
N2 C28 C33 C32 -175.9(4)
C29 C28 C33 C40 -174.1(4)
N2 C28 C33 C40 4.3(7)
C30 C29 C34 C39 -58.3(6)
C28 C29 C34 C39 125.5(5)
C30 C29 C34 C35 111.4(5)
C28 C29 C34 C35 -64.7(7)
C39 C34 C35 C36 -2.3(7)
C29 C34 C35 C36 -172.0(4)
C39 C34 C35 C46 175.3(5)
C29 C34 C35 C46 5.5(7)
C34 C35 C36 C37 1.3(8)
C46 C35 C36 C37 -176.3(5)
C35 C36 C37 C38 -0.2(9)
C35 C36 C37 C47 178.0(6)
C36 C37 C38 C39 0.1(9)
C47 C37 C38 C39 -178.2(6)
C37 C38 C39 C34 -1.1(8)
C37 C38 C39 C48 178.4(5)
C35 C34 C39 C38 2.2(7)
C29 C34 C39 C38 172.0(4)
C35 C34 C39 C48 -177.3(5)
C29 C34 C39 C48 -7.4(7)
C32 C33 C40 C45 -72.6(6)
C28 C33 C40 C45 107.2(6)
C32 C33 C40 C41 99.8(6)
C28 C33 C40 C41 -80.3(6)
C45 C40 C41 C42 -2.4(7)
C33 C40 C41 C42 -174.9(5)
C45 C40 C41 C49 176.4(5)
C33 C40 C41 C49 4.0(7)
C40 C41 C42 C43 -1.4(8)
C49 C41 C42 C43 179.7(5)
C41 C42 C43 C44 3.0(8)
C41 C42 C43 C50 -176.7(5)
C42 C43 C44 C45 -0.7(8)
C50 C43 C44 C45 179.0(5)
C43 C44 C45 C40 -3.1(7)
C43 C44 C45 C51 176.1(5)
C41 C40 C45 C44 4.6(7)
C33 C40 C45 C44 177.2(4)
C41 C40 C45 C51 -174.6(4)
C33 C40 C45 C51 -2.1(7)
C81 Si3 N3 C55 96.8(4)
C80B Si3 N3 C55 -26(3)
C80A Si3 N3 C55 -140.6(12)
Cl6B Si3 N3 C55 -138.0(8)
Cl6A Si3 N3 C55 -26.8(4)
C81 Si3 N3 Sb3 -81.4(3)
C80B Si3 N3 Sb3 156(3)
C80A Si3 N3 Sb3 41.1(12)
Cl6B Si3 N3 Sb3 43.8(7)
Cl6A Si3 N3 Sb3 155.0(3)
C79 Sb3 N3 C55 125.9(3)
Cl5 Sb3 N3 C55 -141.1(3)
C79 Sb3 N3 Si3 -55.6(3)
Cl5 Sb3 N3 Si3 37.4(2)
Si3 N3 C55 C56 126.2(4)
Sb3 N3 C55 C56 -55.3(5)
Si3 N3 C55 C60 -53.9(5)
Sb3 N3 C55 C60 124.6(4)
C60 C55 C56 C57 5.3(7)
N3 C55 C56 C57 -174.9(4)
C60 C55 C56 C61 -173.7(4)
N3 C55 C56 C61 6.1(7)
C55 C56 C57 C58 -0.7(8)
C61 C56 C57 C58 178.4(5)
C56 C57 C58 C59 -3.5(8)
C57 C58 C59 C60 2.9(8)
C58 C59 C60 C55 1.7(7)
C58 C59 C60 C67 -174.1(4)
C56 C55 C60 C59 -5.7(6)
N3 C55 C60 C59 174.4(4)
C56 C55 C60 C67 169.6(4)
N3 C55 C60 C67 -10.3(7)
C57 C56 C61 C66 -74.0(6)
C55 C56 C61 C66 105.1(5)
C57 C56 C61 C62 99.9(5)
C55 C56 C61 C62 -81.0(6)
C66 C61 C62 C63 -3.1(7)
C56 C61 C62 C63 -177.0(4)
C66 C61 C62 C73 176.4(5)
C56 C61 C62 C73 2.6(7)
C61 C62 C63 C64 0.3(8)
C73 C62 C63 C64 -179.3(5)
C62 C63 C64 C65 1.1(8)
C62 C63 C64 C74 -177.1(5)
C63 C64 C65 C66 0.4(7)
C74 C64 C65 C66 178.5(5)
C64 C65 C66 C61 -3.2(7)
C64 C65 C66 C75 175.0(5)
C62 C61 C66 C65 4.6(7)
C56 C61 C66 C65 178.6(4)
C62 C61 C66 C75 -173.6(4)
C56 C61 C66 C75 0.4(7)
C59 C60 C67 C72 112.2(5)
C55 C60 C67 C72 -63.2(6)
C59 C60 C67 C68 -58.7(6)
C55 C60 C67 C68 125.9(5)
C72 C67 C68 C69 3.0(7)
C60 C67 C68 C69 174.1(4)
C72 C67 C68 C76 -177.6(4)
C60 C67 C68 C76 -6.6(7)
C67 C68 C69 C70 -0.5(7)
C76 C68 C69 C70 -179.9(5)
C68 C69 C70 C71 -1.4(8)
C68 C69 C70 C77 -178.1(5)
C69 C70 C71 C72 0.9(8)
C77 C70 C71 C72 177.6(5)
C70 C71 C72 C67 1.6(8)
C70 C71 C72 C78 -176.1(5)
C68 C67 C72 C71 -3.5(7)
C60 C67 C72 C71 -174.5(4)
C68 C67 C72 C78 174.0(4)
C60 C67 C72 C78 3.0(7)
C107 Si4 N4 C82 142.1(11)
C139 Si4 N4 C82 31(2)
C108 Si4 N4 C82 -96.9(4)
Cl8B Si4 N4 C82 137.3(11)
Cl8A Si4 N4 C82 24.6(4)
C107 Si4 N4 Sb4 -40.9(11)
C139 Si4 N4 Sb4 -152(2)
C108 Si4 N4 Sb4 80.1(3)
Cl8B Si4 N4 Sb4 -45.7(11)
Cl8A Si4 N4 Sb4 -158.4(2)
C106 Sb4 N4 C82 -126.6(3)
Cl7 Sb4 N4 C82 141.0(3)
C106 Sb4 N4 Si4 56.0(3)
Cl7 Sb4 N4 Si4 -36.3(2)
Si4 N4 C82 C83 55.5(6)
Sb4 N4 C82 C83 -121.8(4)
Si4 N4 C82 C87 -125.5(4)
Sb4 N4 C82 C87 57.2(5)
C87 C82 C83 C84 3.2(7)
N4 C82 C83 C84 -177.8(4)
C87 C82 C83 C88 -174.4(4)
N4 C82 C83 C88 4.6(7)
C82 C83 C84 C85 -0.6(8)
C88 C83 C84 C85 177.2(5)
C83 C84 C85 C86 -2.4(8)
C84 C85 C86 C87 2.8(8)
C85 C86 C87 C82 -0.2(7)
C85 C86 C87 C94 -179.2(5)
C83 C82 C87 C86 -2.8(7)
N4 C82 C87 C86 178.2(4)
C83 C82 C87 C94 176.1(4)
N4 C82 C87 C94 -2.9(7)
C84 C83 C88 C89 62.4(6)
C82 C83 C88 C89 -119.9(5)
C84 C83 C88 C93 -109.5(5)
C82 C83 C88 C93 68.2(6)
C93 C88 C89 C90 -2.9(7)
C83 C88 C89 C90 -175.0(4)
C93 C88 C89 C100 175.3(5)
C83 C88 C89 C100 3.2(7)
C88 C89 C90 C91 2.8(8)
C100 C89 C90 C91 -175.5(5)
C89 C90 C91 C92 -1.7(8)
C89 C90 C91 C101 176.7(5)
C90 C91 C92 C93 0.8(8)
C101 C91 C92 C93 -177.6(5)
C91 C92 C93 C88 -1.1(7)
C91 C92 C93 C102 176.9(5)
C89 C88 C93 C92 2.0(7)
C83 C88 C93 C92 174.1(4)
C89 C88 C93 C102 -175.9(4)
C83 C88 C93 C102 -3.8(7)
C86 C87 C94 C99 72.0(6)
C82 C87 C94 C99 -107.0(5)
C86 C87 C94 C95 -102.4(5)
C82 C87 C94 C95 78.6(6)
C99 C94 C95 C96 2.4(7)
C87 C94 C95 C96 176.7(4)
C99 C94 C95 C103 -175.6(5)
C87 C94 C95 C103 -1.2(7)
C94 C95 C96 C97 -0.2(8)
C103 C95 C96 C97 177.8(5)
C95 C96 C97 C98 -0.4(8)
C95 C96 C97 C104 -179.7(5)
C96 C97 C98 C99 -1.3(8)
C104 C97 C98 C99 178.0(5)
C95 C94 C99 C98 -3.9(7)
C87 C94 C99 C98 -178.3(4)
C95 C94 C99 C105 174.6(5)
C87 C94 C99 C105 0.2(7)
C97 C98 C99 C94 3.4(8)
C97 C98 C99 C105 -175.2(5)
C114 C109 C110 C111 0.0
C109 C110 C111 C112 0.0
C110 C111 C112 C113 0.0
C111 C112 C113 C114 0.0
C112 C113 C114 C109 0.0
C110 C109 C114 C113 0.0
C120 C115 C116 C117 0.0
C115 C116 C117 C118 0.0
C116 C117 C118 C119 0.0
C117 C118 C119 C120 0.0
C118 C119 C120 C115 0.0
C116 C115 C120 C119 0.0
C126 C121 C122 C123 0.0
C121 C122 C123 C124 0.0
C122 C123 C124 C125 0.0
C123 C124 C125 C126 0.0
C124 C125 C126 C121 0.0
C122 C121 C126 C125 0.0
C132 C127 C128 C129 0.0
C127 C128 C129 C130 0.0
C128 C129 C130 C131 0.0
C129 C130 C131 C132 0.0
C130 C131 C132 C127 0.0
C128 C127 C132 C131 0.0
C138 C133 C134 C135 0.0
C133 C134 C135 C136 0.0
C134 C135 C136 C137 0.0
C135 C136 C137 C138 0.0
C136 C137 C138 C133 0.0
C134 C133 C138 C137 0.0
