#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:58:48 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179402 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/99/4329998.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329998
loop_
_publ_author_name
'Na Zhao'
'Jinyuan Zhang'
'Ying Yang'
'Hongping Zhu'
'Yan Li'
'Gang Fu'
_publ_section_title
;
 β-Diketiminate Germylene-Supported Pentafluorophenylcopper(I) and
 -silver(I) Complexes [LGe(Me)(CuC6F5)n]2 (n = 1, 2),
 LGe[C(SiMe3)N2]AgC6F5, and {LGe[C(SiMe3)N2](AgC6F5)2}2 (L =
 HC[C(Me)N-2,6-iPr2C6H3]2): Synthesis and Structural Characterization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8710
_journal_page_last               8718
_journal_paper_doi               10.1021/ic300216m
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C90 H100 Ag4 F20 Ge2 N8 Si2'
_chemical_formula_weight         2306.62
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.470(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.8783(6)
_cell_length_b                   21.7083(7)
_cell_length_c                   16.1356(8)
_cell_measurement_reflns_used    4418
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.4783
_cell_measurement_theta_min      2.6902
_cell_volume                     4746.6(4)
_computing_cell_refinement       CrysAlisPro
_computing_data_collection       CrysAlisPro
_computing_data_reduction        CrysAlisPro
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       '/w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) x-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0921
_diffrn_reflns_av_sigmaI/netI    0.1999
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            28650
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.75
_exptl_absorpt_coefficient_mu    1.547
_exptl_absorpt_correction_T_max  0.8607
_exptl_absorpt_correction_T_min  0.7473
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   empirical
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_diffrn    1.614
_exptl_crystal_description       block
_exptl_crystal_F_000             2312
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.577
_refine_diff_density_min         -0.404
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.636
_refine_ls_hydrogen_treatment    'refined in riding mode to the carrier atom'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     581
_refine_ls_number_reflns         9310
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.636
_refine_ls_R_factor_all          0.1102
_refine_ls_R_factor_gt           0.0415
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0399
_refine_ls_wR_factor_ref         0.0465
_reflns_number_gt                4537
_reflns_number_total             9310
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300216m_si_002_4.cif
_cod_data_source_block           compound_4
_cod_original_cell_volume        4746.6(3)
_cod_database_code               4329998
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.36332(3) 0.108881(14) 0.20300(2) 0.02512(10) Uani 1 1 d .
Ag2 Ag -0.42311(3) 0.028097(15) 0.07266(2) 0.03043(11) Uani 1 1 d .
Ge1 Ge -0.23098(4) 0.163711(19) 0.29693(3) 0.01865(13) Uani 1 1 d .
Si1 Si -0.09053(10) 0.03574(6) 0.31508(9) 0.0333(4) Uani 1 1 d .
N1 N -0.1603(2) 0.23517(14) 0.2668(2) 0.0170(9) Uani 1 1 d .
N2 N -0.2844(3) 0.20688(14) 0.3810(2) 0.0185(9) Uani 1 1 d .
N3 N -0.0769(3) 0.13066(14) 0.4312(3) 0.0305(11) Uani 1 1 d .
N4 N -0.0375(3) 0.14749(17) 0.4969(3) 0.0569(16) Uani 1 1 d .
F31 F -0.59382(18) 0.12813(10) 0.08027(16) 0.0383(8) Uani 1 1 d .
F32 F -0.7391(2) 0.12817(11) 0.16607(18) 0.0535(9) Uani 1 1 d .
F33 F -0.7291(2) 0.05128(13) 0.3003(2) 0.0695(10) Uani 1 1 d .
F34 F -0.5715(2) -0.02376(13) 0.3486(2) 0.0679(10) Uani 1 1 d .
F35 F -0.42673(18) -0.02378(11) 0.26428(16) 0.0427(8) Uani 1 1 d .
F41 F -0.2387(2) -0.06387(11) 0.08270(18) 0.0516(9) Uani 1 1 d .
F42 F -0.0913(2) -0.06707(13) -0.0007(2) 0.0723(11) Uani 1 1 d .
F43 F -0.0912(3) 0.01126(16) -0.1315(2) 0.0856(12) Uani 1 1 d .
F44 F -0.2408(2) 0.09281(13) -0.1791(2) 0.0725(10) Uani 1 1 d .
F45 F -0.3891(2) 0.09562(11) -0.09813(17) 0.0495(9) Uani 1 1 d .
C1 C -0.0913(3) 0.33983(17) 0.2849(3) 0.0343(13) Uani 1 1 d .
H1A H -0.0760 0.3305 0.2298 0.051 Uiso 1 1 calc R
H1B H -0.0300 0.3482 0.3265 0.051 Uiso 1 1 calc R
H1C H -0.1343 0.3761 0.2796 0.051 Uiso 1 1 calc R
C2 C -0.1426(3) 0.28591(18) 0.3140(3) 0.0232(12) Uani 1 1 d .
C3 C -0.1748(3) 0.29306(18) 0.3896(3) 0.0225(12) Uani 1 1 d .
H3A H -0.1448 0.3257 0.4253 0.027 Uiso 1 1 calc R
C4 C -0.2441(3) 0.25921(19) 0.4195(3) 0.0255(13) Uani 1 1 d .
C5 C -0.2803(3) 0.28232(18) 0.4950(3) 0.0383(15) Uani 1 1 d .
H5A H -0.3411 0.2606 0.4988 0.057 Uiso 1 1 calc R
H5B H -0.2935 0.3266 0.4888 0.057 Uiso 1 1 calc R
H5C H -0.2299 0.2748 0.5468 0.057 Uiso 1 1 calc R
C6 C -0.1244(3) 0.11161(18) 0.3571(3) 0.0238(12) Uani 1 1 d .
C7 C 0.0323(3) 0.01005(18) 0.3769(3) 0.0516(17) Uani 1 1 d .
H7A H 0.0427 -0.0333 0.3642 0.077 Uiso 1 1 calc R
H7B H 0.0345 0.0146 0.4377 0.077 Uiso 1 1 calc R
H7C H 0.0842 0.0353 0.3614 0.077 Uiso 1 1 calc R
C8 C -0.1824(3) -0.02386(19) 0.3238(3) 0.0555(17) Uani 1 1 d .
H8A H -0.2485 -0.0091 0.2967 0.083 Uiso 1 1 calc R
H8B H -0.1799 -0.0326 0.3838 0.083 Uiso 1 1 calc R
H8C H -0.1677 -0.0615 0.2954 0.083 Uiso 1 1 calc R
C9 C -0.0909(3) 0.04612(18) 0.2014(3) 0.0414(15) Uani 1 1 d .
H9A H -0.1569 0.0586 0.1709 0.062 Uiso 1 1 calc R
H9B H -0.0728 0.0072 0.1779 0.062 Uiso 1 1 calc R
H9C H -0.0431 0.0780 0.1950 0.062 Uiso 1 1 calc R
C11 C -0.1203(3) 0.22576(17) 0.1920(3) 0.0204(12) Uani 1 1 d .
C12 C -0.0200(4) 0.21449(19) 0.1998(3) 0.0227(12) Uani 1 1 d .
C13 C 0.0120(4) 0.1964(2) 0.1275(3) 0.0414(15) Uani 1 1 d .
H13A H 0.0799 0.1876 0.1315 0.050 Uiso 1 1 calc R
C14 C -0.0528(4) 0.1909(2) 0.0504(3) 0.0451(15) Uani 1 1 d .
H14A H -0.0301 0.1769 0.0022 0.054 Uiso 1 1 calc R
C15 C -0.1505(4) 0.2056(2) 0.0433(3) 0.0407(15) Uani 1 1 d .
H15A H -0.1940 0.2034 -0.0109 0.049 Uiso 1 1 calc R
C16 C -0.1871(4) 0.22354(18) 0.1122(3) 0.0250(13) Uani 1 1 d .
C21 C -0.3804(3) 0.18734(19) 0.3927(3) 0.0209(12) Uani 1 1 d .
C22 C -0.3879(4) 0.1402(2) 0.4479(3) 0.0280(13) Uani 1 1 d .
C23 C -0.4810(4) 0.1246(2) 0.4604(3) 0.0447(16) Uani 1 1 d .
H23A H -0.4874 0.0932 0.4998 0.054 Uiso 1 1 calc R
C24 C -0.5639(4) 0.1546(2) 0.4160(3) 0.0432(15) Uani 1 1 d .
H24A H -0.6272 0.1434 0.4246 0.052 Uiso 1 1 calc R
C25 C -0.5555(4) 0.2001(2) 0.3601(3) 0.0376(15) Uani 1 1 d .
H25A H -0.6133 0.2202 0.3300 0.045 Uiso 1 1 calc R
C26 C -0.4638(4) 0.21787(19) 0.3459(3) 0.0251(13) Uani 1 1 d .
C30 C -0.5032(3) 0.05239(19) 0.1684(3) 0.0244(12) Uani 1 1 d .
C31 C -0.5857(4) 0.08997(19) 0.1479(3) 0.0242(12) Uani 1 1 d .
C32 C -0.6615(4) 0.0901(2) 0.1900(3) 0.0314(14) Uani 1 1 d .
C33 C -0.6561(4) 0.0514(2) 0.2569(4) 0.0415(15) Uani 1 1 d .
C34 C -0.5757(4) 0.0134(2) 0.2823(4) 0.0366(14) Uani 1 1 d .
C35 C -0.5030(4) 0.0143(2) 0.2371(3) 0.0269(13) Uani 1 1 d .
C40 C -0.3207(3) 0.0162(2) -0.0039(3) 0.0299(14) Uani 1 1 d .
C41 C -0.2428(4) -0.0233(2) 0.0172(3) 0.0311(13) Uani 1 1 d .
C42 C -0.1655(4) -0.0264(2) -0.0235(4) 0.0415(16) Uani 1 1 d .
C43 C -0.1632(4) 0.0138(3) -0.0885(4) 0.0497(17) Uani 1 1 d .
C44 C -0.2401(4) 0.0544(2) -0.1130(4) 0.0406(15) Uani 1 1 d .
C45 C -0.3143(4) 0.0548(2) -0.0696(4) 0.0315(14) Uani 1 1 d .
C121 C 0.0579(3) 0.22247(19) 0.2810(3) 0.0315(13) Uani 1 1 d .
H12A H 0.0242 0.2376 0.3260 0.038 Uiso 1 1 calc R
C122 C 0.1351(3) 0.2707(2) 0.2700(3) 0.0490(16) Uani 1 1 d .
H12B H 0.1775 0.2802 0.3254 0.074 Uiso 1 1 calc R
H12C H 0.1017 0.3083 0.2453 0.074 Uiso 1 1 calc R
H12D H 0.1756 0.2544 0.2322 0.074 Uiso 1 1 calc R
C123 C 0.1099(3) 0.16271(19) 0.3119(3) 0.0398(14) Uani 1 1 d .
H12E H 0.1584 0.1702 0.3649 0.060 Uiso 1 1 calc R
H12F H 0.1437 0.1469 0.2689 0.060 Uiso 1 1 calc R
H12G H 0.0614 0.1324 0.3221 0.060 Uiso 1 1 calc R
C161 C -0.2916(3) 0.24768(18) 0.1010(3) 0.0298(13) Uani 1 1 d .
H16A H -0.3121 0.2415 0.1562 0.036 Uiso 1 1 calc R
C162 C -0.2929(4) 0.31697(18) 0.0841(3) 0.0568(19) Uani 1 1 d .
H16B H -0.2424 0.3372 0.1274 0.085 Uiso 1 1 calc R
H16C H -0.3579 0.3337 0.0861 0.085 Uiso 1 1 calc R
H16D H -0.2792 0.3245 0.0278 0.085 Uiso 1 1 calc R
C163 C -0.3676(3) 0.21533(18) 0.0326(3) 0.0382(14) Uani 1 1 d .
H16E H -0.3673 0.1711 0.0449 0.057 Uiso 1 1 calc R
H16F H -0.3512 0.2219 -0.0228 0.057 Uiso 1 1 calc R
H16G H -0.4333 0.2322 0.0319 0.057 Uiso 1 1 calc R
C221 C -0.2988(4) 0.1065(2) 0.4995(3) 0.0478(15) Uani 1 1 d .
H22A H -0.2403 0.1189 0.4765 0.057 Uiso 1 1 calc R
C222 C -0.3102(4) 0.0366(2) 0.4887(3) 0.0655(19) Uani 1 1 d .
H22B H -0.2512 0.0162 0.5216 0.098 Uiso 1 1 calc R
H22C H -0.3183 0.0259 0.4286 0.098 Uiso 1 1 calc R
H22D H -0.3682 0.0229 0.5091 0.098 Uiso 1 1 calc R
C223 C -0.2771(4) 0.1236(2) 0.5916(3) 0.064(2) Uani 1 1 d .
H22E H -0.2190 0.1009 0.6217 0.096 Uiso 1 1 calc R
H22F H -0.3339 0.1132 0.6160 0.096 Uiso 1 1 calc R
H22G H -0.2643 0.1680 0.5976 0.096 Uiso 1 1 calc R
C261 C -0.4586(3) 0.26931(19) 0.2829(3) 0.0345(14) Uani 1 1 d .
H26A H -0.3885 0.2727 0.2771 0.041 Uiso 1 1 calc R
C262 C -0.5213(3) 0.2557(2) 0.1959(3) 0.0488(16) Uani 1 1 d .
H26B H -0.4989 0.2173 0.1743 0.073 Uiso 1 1 calc R
H26C H -0.5151 0.2895 0.1572 0.073 Uiso 1 1 calc R
H26D H -0.5904 0.2514 0.1999 0.073 Uiso 1 1 calc R
C263 C -0.4890(4) 0.3321(2) 0.3139(3) 0.0639(19) Uani 1 1 d .
H26E H -0.4461 0.3420 0.3689 0.096 Uiso 1 1 calc R
H26F H -0.5577 0.3301 0.3200 0.096 Uiso 1 1 calc R
H26G H -0.4826 0.3641 0.2726 0.096 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C30 Ag1 Ge1 156.04(12) .
C30 Ag1 Ag2 50.13(12) .
Ge1 Ag1 Ag2 149.41(2) .
C40 Ag2 C30 167.32(15) .
C40 Ag2 Ag1 113.73(11) .
C30 Ag2 Ag1 53.66(10) .
C40 Ag2 Ag2 87.07(11) 3_455
C30 Ag2 Ag2 105.35(11) 3_455
Ag1 Ag2 Ag2 153.19(2) 3_455
N2 Ge1 C6 107.34(17) .
N2 Ge1 N1 94.57(15) .
C6 Ge1 N1 102.55(15) .
N2 Ge1 Ag1 108.95(10) .
C6 Ge1 Ag1 114.70(12) .
N1 Ge1 Ag1 125.98(10) .
C8 Si1 C9 107.9(2) .
C8 Si1 C7 108.5(2) .
C9 Si1 C7 112.0(2) .
C8 Si1 C6 110.9(2) .
C9 Si1 C6 107.71(19) .
C7 Si1 C6 109.87(19) .
C2 N1 C11 122.5(4) .
C2 N1 Ge1 123.7(3) .
C11 N1 Ge1 113.5(2) .
C4 N2 C21 119.0(4) .
C4 N2 Ge1 123.2(3) .
C21 N2 Ge1 117.0(2) .
N4 N3 C6 178.2(6) .
C2 C1 H1A 109.5 .
C2 C1 H1B 109.5 .
H1A C1 H1B 109.5 .
C2 C1 H1C 109.5 .
H1A C1 H1C 109.5 .
H1B C1 H1C 109.5 .
N1 C2 C3 122.6(4) .
N1 C2 C1 120.6(4) .
C3 C2 C1 116.8(4) .
C4 C3 C2 128.8(4) .
C4 C3 H3A 115.6 .
C2 C3 H3A 115.6 .
N2 C4 C3 122.4(5) .
N2 C4 C5 118.3(4) .
C3 C4 C5 119.2(4) .
C4 C5 H5A 109.5 .
C4 C5 H5B 109.5 .
H5A C5 H5B 109.5 .
C4 C5 H5C 109.5 .
H5A C5 H5C 109.5 .
H5B C5 H5C 109.5 .
N3 C6 Si1 119.6(3) .
N3 C6 Ge1 116.9(3) .
Si1 C6 Ge1 123.5(2) .
Si1 C7 H7A 109.5 .
Si1 C7 H7B 109.5 .
H7A C7 H7B 109.5 .
Si1 C7 H7C 109.5 .
H7A C7 H7C 109.5 .
H7B C7 H7C 109.5 .
Si1 C8 H8A 109.5 .
Si1 C8 H8B 109.5 .
H8A C8 H8B 109.5 .
Si1 C8 H8C 109.5 .
H8A C8 H8C 109.5 .
H8B C8 H8C 109.5 .
Si1 C9 H9A 109.5 .
Si1 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
Si1 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
C12 C11 C16 121.4(5) .
C12 C11 N1 120.4(4) .
C16 C11 N1 118.0(4) .
C13 C12 C11 117.9(4) .
C13 C12 C121 117.3(5) .
C11 C12 C121 124.7(5) .
C14 C13 C12 121.2(5) .
C14 C13 H13A 119.4 .
C12 C13 H13A 119.4 .
C15 C14 C13 119.8(5) .
C15 C14 H14A 120.1 .
C13 C14 H14A 120.1 .
C14 C15 C16 121.9(5) .
C14 C15 H15A 119.0 .
C16 C15 H15A 119.0 .
C15 C16 C11 117.5(5) .
C15 C16 C161 120.9(4) .
C11 C16 C161 121.2(4) .
C22 C21 C26 122.0(4) .
C22 C21 N2 120.1(4) .
C26 C21 N2 117.8(4) .
C21 C22 C23 118.6(5) .
C21 C22 C221 123.1(4) .
C23 C22 C221 118.2(5) .
C24 C23 C22 120.4(5) .
C24 C23 H23A 119.8 .
C22 C23 H23A 119.8 .
C25 C24 C23 120.3(5) .
C25 C24 H24A 119.8 .
C23 C24 H24A 119.8 .
C24 C25 C26 121.5(5) .
C24 C25 H25A 119.3 .
C26 C25 H25A 119.3 .
C25 C26 C21 117.2(5) .
C25 C26 C261 119.3(4) .
C21 C26 C261 123.6(5) .
C35 C30 C31 113.7(4) .
C35 C30 Ag2 121.1(3) .
C31 C30 Ag2 120.0(3) .
C35 C30 Ag1 105.9(3) .
C31 C30 Ag1 111.1(3) .
Ag2 C30 Ag1 76.21(15) .
F31 C31 C32 117.3(4) .
F31 C31 C30 118.2(5) .
C32 C31 C30 124.5(5) .
F32 C32 C33 120.8(5) .
F32 C32 C31 120.7(5) .
C33 C32 C31 118.5(5) .
F33 C33 C32 119.7(5) .
F33 C33 C34 119.7(5) .
C32 C33 C34 120.7(5) .
F34 C34 C35 121.8(5) .
F34 C34 C33 119.7(5) .
C35 C34 C33 118.5(5) .
F35 C35 C34 116.0(5) .
F35 C35 C30 119.8(5) .
C34 C35 C30 124.2(5) .
C41 C40 C45 113.5(5) .
C41 C40 Ag2 122.2(4) .
C45 C40 Ag2 123.2(4) .
C40 C41 F41 119.8(5) .
C40 C41 C42 124.7(5) .
F41 C41 C42 115.5(5) .
F42 C42 C43 119.0(6) .
F42 C42 C41 122.1(6) .
C43 C42 C41 118.9(5) .
F43 C43 C42 121.0(6) .
F43 C43 C44 119.9(6) .
C42 C43 C44 119.0(5) .
F44 C44 C45 121.6(5) .
F44 C44 C43 119.6(5) .
C45 C44 C43 118.7(5) .
C44 C45 F45 115.7(5) .
C44 C45 C40 125.2(5) .
F45 C45 C40 119.1(5) .
C123 C121 C12 112.7(4) .
C123 C121 C122 109.0(4) .
C12 C121 C122 111.2(4) .
C123 C121 H12A 107.9 .
C12 C121 H12A 107.9 .
C122 C121 H12A 107.9 .
C121 C122 H12B 109.5 .
C121 C122 H12C 109.5 .
H12B C122 H12C 109.5 .
C121 C122 H12D 109.5 .
H12B C122 H12D 109.5 .
H12C C122 H12D 109.5 .
C121 C123 H12E 109.5 .
C121 C123 H12F 109.5 .
H12E C123 H12F 109.5 .
C121 C123 H12G 109.5 .
H12E C123 H12G 109.5 .
H12F C123 H12G 109.5 .
C16 C161 C163 115.0(4) .
C16 C161 C162 109.6(4) .
C163 C161 C162 110.1(3) .
C16 C161 H16A 107.3 .
C163 C161 H16A 107.3 .
C162 C161 H16A 107.3 .
C161 C162 H16B 109.5 .
C161 C162 H16C 109.5 .
H16B C162 H16C 109.5 .
C161 C162 H16D 109.5 .
H16B C162 H16D 109.5 .
H16C C162 H16D 109.5 .
C161 C163 H16E 109.5 .
C161 C163 H16F 109.5 .
H16E C163 H16F 109.5 .
C161 C163 H16G 109.5 .
H16E C163 H16G 109.5 .
H16F C163 H16G 109.5 .
C223 C221 C22 113.0(5) .
C223 C221 C222 110.6(4) .
C22 C221 C222 111.3(4) .
C223 C221 H22A 107.2 .
C22 C221 H22A 107.2 .
C222 C221 H22A 107.2 .
C221 C222 H22B 109.5 .
C221 C222 H22C 109.5 .
H22B C222 H22C 109.5 .
C221 C222 H22D 109.5 .
H22B C222 H22D 109.5 .
H22C C222 H22D 109.5 .
C221 C223 H22E 109.5 .
C221 C223 H22F 109.5 .
H22E C223 H22F 109.5 .
C221 C223 H22G 109.5 .
H22E C223 H22G 109.5 .
H22F C223 H22G 109.5 .
C262 C261 C26 112.1(4) .
C262 C261 C263 109.4(4) .
C26 C261 C263 112.0(4) .
C262 C261 H26A 107.7 .
C26 C261 H26A 107.7 .
C263 C261 H26A 107.7 .
C261 C262 H26B 109.5 .
C261 C262 H26C 109.5 .
H26B C262 H26C 109.5 .
C261 C262 H26D 109.5 .
H26B C262 H26D 109.5 .
H26C C262 H26D 109.5 .
C261 C263 H26E 109.5 .
C261 C263 H26F 109.5 .
H26E C263 H26F 109.5 .
C261 C263 H26G 109.5 .
H26E C263 H26G 109.5 .
H26F C263 H26G 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C30 2.261(4) .
Ag1 Ge1 2.4258(5) .
Ag1 Ag2 2.7264(5) .
Ag2 C40 2.091(5) .
Ag2 C30 2.155(5) .
Ag2 Ag2 3.0627(7) 3_455
Ge1 N2 1.924(4) .
Ge1 C6 1.947(4) .
Ge1 N1 1.953(3) .
Si1 C8 1.843(4) .
Si1 C9 1.847(5) .
Si1 C7 1.865(4) .
Si1 C6 1.879(4) .
N1 C2 1.332(5) .
N1 C11 1.446(5) .
N2 C4 1.356(5) .
N2 C21 1.449(5) .
N3 N4 1.142(5) .
N3 C6 1.301(5) .
F31 C31 1.356(5) .
F32 C32 1.346(5) .
F33 C33 1.350(6) .
F34 C34 1.331(5) .
F35 C35 1.340(4) .
F41 C41 1.368(5) .
F42 C42 1.346(5) .
F43 C43 1.335(6) .
F44 C44 1.351(6) .
F45 C45 1.366(5) .
C1 C2 1.497(5) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
C2 C3 1.396(6) .
C3 C4 1.378(6) .
C3 H3A 0.9500 .
C4 C5 1.501(6) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C11 C12 1.392(6) .
C11 C16 1.416(5) .
C12 C13 1.392(6) .
C12 C121 1.518(5) .
C13 C14 1.374(6) .
C13 H13A 0.9500 .
C14 C15 1.373(6) .
C14 H14A 0.9500 .
C15 C16 1.375(6) .
C15 H15A 0.9500 .
C16 C161 1.515(6) .
C21 C22 1.374(6) .
C21 C26 1.404(5) .
C22 C23 1.392(6) .
C22 C221 1.521(6) .
C23 C24 1.380(6) .
C23 H23A 0.9500 .
C24 C25 1.359(6) .
C24 H24A 0.9500 .
C25 C26 1.395(6) .
C25 H25A 0.9500 .
C26 C261 1.523(6) .
C30 C35 1.382(6) .
C30 C31 1.386(6) .
C31 C32 1.371(6) .
C32 C33 1.356(7) .
C33 C34 1.377(6) .
C34 C35 1.367(7) .
C40 C41 1.364(6) .
C40 C45 1.369(6) .
C41 C42 1.375(7) .
C42 C43 1.370(7) .
C43 C44 1.375(7) .
C44 C45 1.365(7) .
C121 C123 1.516(5) .
C121 C122 1.537(5) .
C121 H12A 1.0000 .
C122 H12B 0.9800 .
C122 H12C 0.9800 .
C122 H12D 0.9800 .
C123 H12E 0.9800 .
C123 H12F 0.9800 .
C123 H12G 0.9800 .
C161 C163 1.524(5) .
C161 C162 1.528(5) .
C161 H16A 1.0000 .
C162 H16B 0.9800 .
C162 H16C 0.9800 .
C162 H16D 0.9800 .
C163 H16E 0.9800 .
C163 H16F 0.9800 .
C163 H16G 0.9800 .
C221 C223 1.498(6) .
C221 C222 1.533(6) .
C221 H22A 1.0000 .
C222 H22B 0.9800 .
C222 H22C 0.9800 .
C222 H22D 0.9800 .
C223 H22E 0.9800 .
C223 H22F 0.9800 .
C223 H22G 0.9800 .
C261 C262 1.511(5) .
C261 C263 1.542(6) .
C261 H26A 1.0000 .
C262 H26B 0.9800 .
C262 H26C 0.9800 .
C262 H26D 0.9800 .
C263 H26E 0.9800 .
C263 H26F 0.9800 .
C263 H26G 0.9800 .
