#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/02/4340267.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4340267
loop_
_publ_author_name
'Wu, Huang-Chun'
'Thanasekaran, P.'
'Tsai, Chi-Hwe'
'Wu, Jing-Yun'
'Huang, Sheng-Ming'
'Wen, Yuh-Sheng'
'Lu, Kuang-Lieh'
_publ_section_title
;
 Self-assembly, reorganization, and photophysical properties of
 silver(I)-Schiff-base molecular rectangle and polymeric array species.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              295
_journal_page_last               303
_journal_paper_doi               10.1021/ic051235k
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C52.25 H48 Ag2 Cl1.5 N8 O8'
_chemical_formula_weight         1184.90
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.258(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   13.4902(4)
_cell_length_b                   27.4260(10)
_cell_length_c                   29.1409(10)
_cell_measurement_reflns_used    1152
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      12.59
_cell_measurement_theta_min      2.71
_cell_volume                     10535.8(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2540
_diffrn_reflns_av_sigmaI/netI    0.9072
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            50840
_diffrn_reflns_theta_full        25.06
_diffrn_reflns_theta_max         25.06
_diffrn_reflns_theta_min         1.43
_exptl_absorpt_coefficient_mu    0.880
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.494
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4808
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.173
_refine_diff_density_min         -0.443
_refine_diff_density_rms         0.141
_refine_ls_extinction_coef       0.00089(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.663
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     642
_refine_ls_number_reflns         9239
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.663
_refine_ls_R_factor_all          0.3308
_refine_ls_R_factor_gt           0.0691
_refine_ls_shift/su_max          1.861
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0842P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1811
_refine_ls_wR_factor_ref         0.2130
_reflns_number_gt                1629
_reflns_number_total             9239
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic051235ksi20050725_062431.cif
_cod_data_source_block           i6423_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C52.25 H48 Ag2 Cl1.50 N8 O8'
_cod_database_code               4340267
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.15785(9) 0.46469(5) 0.16162(5) 0.0765(6) Uani 1 1 d .
Ag2 Ag 0.63614(9) 0.35374(5) 0.01403(5) 0.0779(6) Uani 1 1 d .
Cl1 Cl 0.4815(5) 0.1913(3) 0.0558(3) 0.112(2) Uani 1 1 d .
Cl2 Cl 0.5000 0.5061(4) 0.2500 0.126(3) Uani 1 2 d S
O1 O 0.5692(9) 0.2215(5) 0.0688(5) 0.158(7) Uani 1 1 d .
O2 O 0.5032(9) 0.1434(5) 0.0605(6) 0.152(7) Uani 1 1 d .
O3 O 0.4045(11) 0.2048(5) 0.0783(6) 0.166(7) Uani 1 1 d .
O4 O 0.4420(15) 0.1992(7) 0.0069(10) 0.238(11) Uani 1 1 d .
O5 O 0.5000 0.5554(17) 0.2500 0.132(16) Uiso 0.50 2 d SP
O6 O 0.616(2) 0.5153(10) 0.2683(10) 0.257(13) Uiso 0.75 1 d P
O7 O 0.5000 0.456(2) 0.2500 0.23(3) Uiso 0.50 2 d SP
O8 O 0.5116(16) 0.4919(8) 0.2054(9) 0.185(10) Uiso 0.75 1 d P
O9 O 0.033(2) 0.6255(13) 0.2260(12) 0.229(17) Uiso 0.50 1 d P
O10 O 0.9838(13) 0.2034(4) 0.2552(7) 0.097(5) Uiso 1 1 d .
O11 O 1.0000 0.2420(14) 0.2500 0.108(13) Uiso 0.50 2 d SP
O501 O 0.029(3) 0.6870(19) 0.2083(18) 0.120(17) Uiso 0.25 1 d P
N1 N -0.2262(12) 0.4034(7) 0.1926(7) 0.090(7) Uani 1 1 d .
N2 N -0.0306(14) 0.4012(4) 0.1786(5) 0.083(6) Uani 1 1 d .
N101 N 0.7693(12) 0.2991(6) 0.0509(7) 0.083(6) Uani 1 1 d .
N102 N 0.6226(11) 0.3390(5) 0.0898(4) 0.060(4) Uani 1 1 d .
N201 N -0.2181(12) 0.5402(6) 0.1621(7) 0.085(6) Uani 1 1 d .
N202 N -0.0963(10) 0.5114(6) 0.1063(5) 0.060(4) Uani 1 1 d .
N301 N 0.6674(13) 0.3780(5) -0.0567(5) 0.067(4) Uani 1 1 d .
N302 N 0.4760(10) 0.3938(5) -0.0315(5) 0.066(4) Uani 1 1 d .
C1 C -0.1707(14) 0.3632(9) 0.2099(7) 0.065(6) Uani 1 1 d .
C2 C -0.2062(15) 0.3278(7) 0.2343(7) 0.079(6) Uani 1 1 d .
H2 H -0.1676 0.3002 0.2443 0.094 Uiso 1 1 calc R
C3 C -0.304(2) 0.3340(10) 0.2445(6) 0.120(10) Uani 1 1 d .
H3 H -0.3359 0.3118 0.2607 0.144 Uiso 1 1 calc R
C4 C -0.3471(16) 0.3809(12) 0.2254(10) 0.138(14) Uani 1 1 d .
H4 H -0.4088 0.3912 0.2314 0.166 Uiso 1 1 calc R
C5 C -0.303(3) 0.4068(11) 0.2016(9) 0.155(19) Uani 1 1 d .
H5 H -0.3392 0.4341 0.1888 0.185 Uiso 1 1 calc R
C6 C -0.0692(12) 0.3669(7) 0.1944(6) 0.067(6) Uani 1 1 d .
H6 H -0.0313 0.3383 0.1977 0.080 Uiso 1 1 calc R
C7 C 0.0664(12) 0.3865(11) 0.1618(7) 0.093(8) Uani 1 1 d .
C8 C 0.1358(16) 0.4283(6) 0.1768(5) 0.051(5) Uani 1 1 d .
C9 C 0.2290(12) 0.4224(7) 0.1657(6) 0.052(5) Uani 1 1 d .
H9 H 0.2783 0.4464 0.1738 0.063 Uiso 1 1 calc R
C10 C 0.2494(14) 0.3821(7) 0.1432(7) 0.056(6) Uani 1 1 d .
C11 C 0.1802(15) 0.3473(11) 0.1260(8) 0.124(13) Uani 1 1 d .
H11 H 0.1941 0.3224 0.1067 0.148 Uiso 1 1 calc R
C12 C 0.097(3) 0.3508(6) 0.1377(7) 0.126(13) Uani 1 1 d .
H12 H 0.0509 0.3255 0.1284 0.152 Uiso 1 1 calc R
C13 C 0.1196(10) 0.4756(6) 0.2031(5) 0.078(6) Uani 1 1 d .
H13A H 0.1198 0.4680 0.2353 0.117 Uiso 1 1 calc R
H13B H 0.0557 0.4899 0.1886 0.117 Uiso 1 1 calc R
H13C H 0.1733 0.4981 0.2018 0.117 Uiso 1 1 calc R
C101 C 0.7683(16) 0.2860(8) 0.0949(10) 0.064(7) Uani 1 1 d .
C102 C 0.8331(16) 0.2546(7) 0.1228(7) 0.074(6) Uani 1 1 d .
H102 H 0.8252 0.2449 0.1524 0.089 Uiso 1 1 calc R
C103 C 0.9111(15) 0.2387(6) 0.1030(9) 0.089(7) Uani 1 1 d .
H103 H 0.9616 0.2180 0.1188 0.107 Uiso 1 1 calc R
C104 C 0.910(2) 0.2560(9) 0.0568(10) 0.100(10) Uani 1 1 d .
H104 H 0.9599 0.2458 0.0413 0.120 Uiso 1 1 calc R
C105 C 0.8404(19) 0.2857(8) 0.0362(9) 0.104(11) Uani 1 1 d .
H105 H 0.8465 0.2977 0.0071 0.125 Uiso 1 1 calc R
C106 C 0.6845(15) 0.3052(6) 0.1116(6) 0.068(6) Uani 1 1 d .
H106 H 0.6725 0.2930 0.1397 0.082 Uiso 1 1 calc R
C107 C 0.5301(12) 0.3515(8) 0.1071(5) 0.051(5) Uani 1 1 d .
C108 C 0.4933(16) 0.4000(6) 0.1078(5) 0.056(5) Uani 1 1 d .
C109 C 0.4015(13) 0.4072(7) 0.1209(5) 0.063(6) Uani 1 1 d .
H109 H 0.3796 0.4392 0.1226 0.075 Uiso 1 1 calc R
C110 C 0.3413(17) 0.3712(8) 0.1314(6) 0.061(6) Uani 1 1 d .
C111 C 0.3772(13) 0.3279(8) 0.1310(6) 0.065(6) Uani 1 1 d .
H111 H 0.3391 0.3028 0.1401 0.079 Uiso 1 1 calc R
C112 C 0.4696(16) 0.3143(6) 0.1181(6) 0.075(6) Uani 1 1 d .
H112 H 0.4886 0.2818 0.1171 0.090 Uiso 1 1 calc R
C113 C 0.5640(11) 0.4389(6) 0.0941(5) 0.078(5) Uani 1 1 d .
H11A H 0.5550 0.4399 0.0605 0.118 Uiso 1 1 calc R
H11B H 0.6332 0.4309 0.1078 0.118 Uiso 1 1 calc R
H11C H 0.5480 0.4702 0.1054 0.118 Uiso 1 1 calc R
C201 C -0.1917(14) 0.5716(9) 0.1337(8) 0.065(6) Uani 1 1 d .
C202 C -0.2200(13) 0.6197(10) 0.1263(7) 0.085(7) Uani 1 1 d .
H202 H -0.2013 0.6376 0.1024 0.102 Uiso 1 1 calc R
C203 C -0.2765(16) 0.6402(8) 0.1550(9) 0.097(7) Uani 1 1 d .
H203 H -0.2933 0.6732 0.1539 0.116 Uiso 1 1 calc R
C204 C -0.3067(11) 0.6078(12) 0.1862(8) 0.098(8) Uani 1 1 d .
H204 H -0.3486 0.6185 0.2057 0.117 Uiso 1 1 calc R
C205 C -0.2735(16) 0.5582(9) 0.1884(7) 0.086(6) Uani 1 1 d .
H205 H -0.2935 0.5378 0.2103 0.103 Uiso 1 1 calc R
C206 C -0.1240(14) 0.5548(8) 0.1055(7) 0.074(6) Uani 1 1 d .
H206 H -0.1001 0.5767 0.0860 0.089 Uiso 1 1 calc R
C207 C -0.0224(15) 0.4938(7) 0.0830(7) 0.063(5) Uani 1 1 d .
C208 C -0.0259(12) 0.4500(7) 0.0597(6) 0.058(5) Uani 1 1 d .
C209 C 0.0531(15) 0.4362(5) 0.0401(5) 0.059(5) Uani 1 1 d .
H209 H 0.0476 0.4069 0.0236 0.070 Uiso 1 1 calc R
C210 C 0.1406(12) 0.4631(8) 0.0432(6) 0.054(5) Uani 1 1 d .
C211 C 0.1513(13) 0.5071(6) 0.0673(6) 0.066(6) Uani 1 1 d .
H211 H 0.2099 0.5258 0.0708 0.079 Uiso 1 1 calc R
C212 C 0.0702(16) 0.5215(5) 0.0858(6) 0.067(5) Uani 1 1 d .
H212 H 0.0752 0.5514 0.1013 0.081 Uiso 1 1 calc R
C213 C -0.1188(9) 0.4174(5) 0.0554(5) 0.075(6) Uani 1 1 d .
H21A H -0.1492 0.4224 0.0819 0.112 Uiso 1 1 calc R
H21B H -0.0989 0.3839 0.0543 0.112 Uiso 1 1 calc R
H21C H -0.1670 0.4254 0.0271 0.112 Uiso 1 1 calc R
C301 C 0.5909(13) 0.4013(6) -0.0886(9) 0.061(6) Uani 1 1 d .
C302 C 0.5999(17) 0.4113(7) -0.1325(7) 0.103(8) Uani 1 1 d .
H302 H 0.5491 0.4285 -0.1527 0.123 Uiso 1 1 calc R
C303 C 0.6825(17) 0.3965(8) -0.1471(8) 0.107(9) Uani 1 1 d .
H303 H 0.6868 0.4019 -0.1782 0.128 Uiso 1 1 calc R
C304 C 0.7565(16) 0.3749(8) -0.1190(9) 0.099(8) Uani 1 1 d .
H304 H 0.8148 0.3658 -0.1291 0.119 Uiso 1 1 calc R
C305 C 0.7469(14) 0.3659(7) -0.0742(9) 0.090(7) Uani 1 1 d .
H305 H 0.8003 0.3500 -0.0543 0.108 Uiso 1 1 calc R
C306 C 0.4938(13) 0.4126(6) -0.0701(7) 0.072(6) Uani 1 1 d .
H306 H 0.4460 0.4337 -0.0872 0.087 Uiso 1 1 calc R
C307 C 0.3868(12) 0.4105(9) -0.0144(6) 0.058(5) Uani 1 1 d .
C308 C 0.3225(14) 0.3770(7) -0.0017(6) 0.065(6) Uani 1 1 d .
C309 C 0.2457(13) 0.3942(7) 0.0176(6) 0.062(5) Uani 1 1 d .
H309 H 0.2059 0.3713 0.0288 0.074 Uiso 1 1 calc R
C310 C 0.2220(14) 0.4431(8) 0.0217(6) 0.067(6) Uani 1 1 d .
C311 C 0.2856(14) 0.4746(7) 0.0070(6) 0.078(6) Uani 1 1 d .
H311 H 0.2748 0.5079 0.0093 0.093 Uiso 1 1 calc R
C312 C 0.3676(14) 0.4586(8) -0.0119(6) 0.067(5) Uani 1 1 d .
H312 H 0.4087 0.4812 -0.0227 0.080 Uiso 1 1 calc R
C313 C 0.3427(10) 0.3227(6) -0.0050(6) 0.073(6) Uani 1 1 d .
H31A H 0.2904 0.3046 0.0052 0.110 Uiso 1 1 calc R
H31B H 0.4073 0.3149 0.0146 0.110 Uiso 1 1 calc R
H31C H 0.3432 0.3143 -0.0370 0.110 Uiso 1 1 calc R
C501 C 0.0000 0.698(2) 0.2500 0.15(3) Uiso 0.50 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N201 121.5(7) . .
N1 Ag1 N202 160.0(6) . .
N201 Ag1 N202 71.3(6) . .
N1 Ag1 N2 73.0(6) . .
N201 Ag1 N2 155.8(5) . .
N202 Ag1 N2 101.2(6) . .
N301 Ag2 N102 170.9(4) . .
N301 Ag2 N101 108.7(7) . .
N102 Ag2 N101 70.4(6) . .
N301 Ag2 N302 72.7(6) . .
N102 Ag2 N302 110.3(6) . .
N101 Ag2 N302 167.2(5) . .
O2 Cl1 O3 112.2(10) . .
O2 Cl1 O4 106.2(13) . .
O3 Cl1 O4 105.8(13) . .
O2 Cl1 O1 112.9(9) . .
O3 Cl1 O1 112.3(9) . .
O4 Cl1 O1 106.8(12) . .
O5 Cl2 O7 180.000(16) . .
O5 Cl2 O8 106.2(11) . .
O7 Cl2 O8 73.8(11) . .
O5 Cl2 O8 106.2(11) . 2_655
O7 Cl2 O8 73.8(11) . 2_655
O8 Cl2 O8 148(2) . 2_655
O5 Cl2 O6 80.7(11) . 2_655
O7 Cl2 O6 99.3(11) . 2_655
O8 Cl2 O6 91.6(13) . 2_655
O8 Cl2 O6 93.5(13) 2_655 2_655
O5 Cl2 O6 80.7(11) . .
O7 Cl2 O6 99.3(11) . .
O8 Cl2 O6 93.5(13) . .
O8 Cl2 O6 91.6(13) 2_655 .
O6 Cl2 O6 161(2) 2_655 .
Cl2 O7 O8 54(2) . 2_655
Cl2 O7 O8 54(2) . .
O8 O7 O8 108(4) 2_655 .
Cl2 O8 O7 52(2) . .
O501 O9 O9 103.8(19) . 2
O10 O10 O11 74.6(10) 2_755 .
O10 O11 O10 30.7(19) . 2_755
C501 O501 O9 87(4) . .
C5 N1 C1 116(3) . .
C5 N1 Ag1 121(2) . .
C1 N1 Ag1 121.5(14) . .
C6 N2 C7 112.3(17) . .
C6 N2 Ag1 107.0(14) . .
C7 N2 Ag1 137.3(11) . .
C105 N101 C101 116(2) . .
C105 N101 Ag2 128(2) . .
C101 N101 Ag2 116.0(17) . .
C106 N102 C107 119.5(16) . .
C106 N102 Ag2 114.6(12) . .
C107 N102 Ag2 122.2(11) . .
C205 N201 C201 114(2) . .
C205 N201 Ag1 128.6(18) . .
C201 N201 Ag1 117.6(16) . .
C206 N202 C207 123.9(18) . .
C206 N202 Ag1 112.8(13) . .
C207 N202 Ag1 122.5(12) . .
C305 N301 C301 114.0(16) . .
C305 N301 Ag2 126.4(16) . .
C301 N301 Ag2 118.9(15) . .
C306 N302 C307 118.9(16) . .
C306 N302 Ag2 109.2(11) . .
C307 N302 Ag2 128.8(11) . .
C2 C1 N1 123.2(18) . .
C2 C1 C6 130(2) . .
N1 C1 C6 107(2) . .
C1 C2 C3 118.2(19) . .
C2 C3 C4 109.5(17) . .
C5 C4 C3 121(3) . .
N1 C5 C4 132(4) . .
N2 C6 C1 130.2(19) . .
C12 C7 C8 118.8(18) . .
C12 C7 N2 138(3) . .
C8 C7 N2 103(2) . .
C9 C8 C7 113.1(15) . .
C9 C8 C13 116.6(18) . .
C7 C8 C13 130.3(19) . .
C10 C9 C8 120.3(17) . .
C9 C10 C11 124(2) . .
C9 C10 C110 125.8(18) . .
C11 C10 C110 110(2) . .
C12 C11 C10 116(3) . .
C11 C12 C7 127(3) . .
N101 C101 C102 127.4(18) . .
N101 C101 C106 114(3) . .
C102 C101 C106 119(2) . .
C101 C102 C103 113.6(19) . .
C102 C103 C104 116(2) . .
C105 C104 C103 121(2) . .
N101 C105 C104 126(3) . .
N102 C106 C101 124(2) . .
C112 C107 C108 117.5(15) . .
C112 C107 N102 119.1(19) . .
C108 C107 N102 123.0(18) . .
C109 C108 C107 118.3(14) . .
C109 C108 C113 127.7(19) . .
C107 C108 C113 114.0(18) . .
C110 C109 C108 124.9(18) . .
C111 C110 C109 115(2) . .
C111 C110 C10 124(2) . .
C109 C110 C10 120.6(19) . .
C110 C111 C112 126.7(18) . .
C107 C112 C111 117.2(16) . .
N201 C201 C202 129(2) . .
N201 C201 C206 117(2) . .
C202 C201 C206 114(3) . .
C203 C202 C201 118(2) . .
C202 C203 C204 115(2) . .
C203 C204 C205 120.3(19) . .
N201 C205 C204 124(2) . .
N202 C206 C201 121(2) . .
C208 C207 N202 125.7(19) . .
C208 C207 C212 115.2(18) . .
N202 C207 C212 119.0(18) . .
C209 C208 C207 120.0(16) . .
C209 C208 C213 120.3(18) . .
C207 C208 C213 119.8(18) . .
C208 C209 C210 123.9(16) . .
C209 C210 C211 119.6(16) . .
C209 C210 C310 118(2) . .
C211 C210 C310 122.0(17) . .
C212 C211 C210 116.2(16) . .
C211 C212 C207 125.1(16) . .
C302 C301 N301 121.9(16) . .
C302 C301 C306 123(2) . .
N301 C301 C306 115(2) . .
C303 C302 C301 120(2) . .
C304 C303 C302 121(2) . .
C303 C304 C305 118(2) . .
N301 C305 C304 125(2) . .
N302 C306 C301 123.0(17) . .
C312 C307 C308 120.1(16) . .
C312 C307 N302 120(2) . .
C308 C307 N302 120(2) . .
C309 C308 C307 117.5(18) . .
C309 C308 C313 121.7(17) . .
C307 C308 C313 120.5(18) . .
C308 C309 C310 125.3(17) . .
C311 C310 C309 114.5(18) . .
C311 C310 C210 118(2) . .
C309 C310 C210 126.9(18) . .
C310 C311 C312 122.1(18) . .
C307 C312 C311 120.1(16) . .
O501 C501 O501 155(7) . 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.200(18) .
Ag1 N201 2.226(17) .
Ag1 N202 2.343(14) .
Ag1 N2 2.422(16) .
Ag2 N301 2.289(13) .
Ag2 N102 2.289(13) .
Ag2 N101 2.409(18) .
Ag2 N302 2.534(13) .
Cl1 O2 1.347(13) .
Cl1 O3 1.392(12) .
Cl1 O4 1.43(2) .
Cl1 O1 1.428(12) .
Cl2 O5 1.35(4) .
Cl2 O7 1.37(6) .
Cl2 O8 1.40(3) .
Cl2 O8 1.40(3) 2_655
Cl2 O6 1.56(3) 2_655
Cl2 O6 1.56(3) .
O7 O8 1.66(4) 2_655
O7 O8 1.66(4) .
O9 O501 1.76(5) .
O9 O9 1.81(6) 2
O10 O10 0.58(3) 2_755
O10 O11 1.10(3) .
O11 O10 1.10(3) 2_755
O501 C501 1.39(5) .
N1 C5 1.12(3) .
N1 C1 1.37(2) .
N2 C6 1.213(18) .
N2 C7 1.54(2) .
N101 C105 1.19(2) .
N101 C101 1.33(2) .
N102 C106 1.319(16) .
N102 C107 1.481(16) .
N201 C205 1.28(2) .
N201 C201 1.30(2) .
N202 C206 1.246(17) .
N202 C207 1.41(2) .
N301 C305 1.323(17) .
N301 C301 1.388(19) .
N302 C306 1.304(17) .
N302 C307 1.469(17) .
C1 C2 1.35(2) .
C1 C6 1.53(2) .
C2 C3 1.42(2) .
C3 C4 1.47(3) .
C4 C5 1.23(3) .
C7 C12 1.32(2) .
C7 C8 1.48(2) .
C8 C9 1.373(17) .
C8 C13 1.545(18) .
C9 C10 1.34(2) .
C10 C11 1.35(3) .
C10 C110 1.39(2) .
C11 C12 1.25(3) .
C101 C102 1.36(2) .
C101 C106 1.42(2) .
C102 C103 1.38(2) .
C103 C104 1.42(2) .
C104 C105 1.29(3) .
C107 C112 1.387(18) .
C107 C108 1.420(18) .
C108 C109 1.384(19) .
C108 C113 1.540(18) .
C109 C110 1.355(19) .
C110 C111 1.283(19) .
C111 C112 1.427(19) .
C201 C202 1.38(2) .
C201 C206 1.43(2) .
C202 C203 1.37(2) .
C203 C204 1.39(2) .
C204 C205 1.43(2) .
C207 C208 1.38(2) .
C207 C212 1.449(19) .
C208 C209 1.367(18) .
C208 C213 1.522(17) .
C209 C210 1.378(18) .
C210 C211 1.387(19) .
C210 C310 1.48(2) .
C211 C212 1.376(17) .
C301 C302 1.34(2) .
C301 C306 1.55(2) .
C302 C303 1.34(2) .
C303 C304 1.29(2) .
C304 C305 1.36(2) .
C307 C312 1.348(18) .
C307 C308 1.37(2) .
C308 C309 1.362(18) .
C308 C313 1.522(19) .
C309 C310 1.391(19) .
C310 C311 1.351(19) .
C311 C312 1.406(19) .
C501 O501 1.39(5) 2
