#------------------------------------------------------------------------------
#$Date: 2019-09-23 12:48:42 +0300 (Mon, 23 Sep 2019) $
#$Revision: 218742 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/09/4340970.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4340970
loop_
_publ_author_name
'Zhao, Fang-Hua'
'Li, Hui'
'Che, Yun-Xia'
'Zheng, Ji-Min'
'Vieru, Veacheslav'
'Chibotaru, Liviu F.'
'Grandjean, Fernande'
'Long, Gary J.'
_publ_section_title
;
 Synthesis, structure, and magnetic properties of Dy₂Co₂L₁₀(bipy)₂
 and Ln₂Ni₂L₁₀(bipy)₂, Ln = La, Gd, Tb, Dy, and Ho: slow magnetic
 relaxation in Dy₂Co₂L₁₀(bipy)₂ and Dy₂Ni₂L₁₀(bipy)₂
;
_journal_coden_ASTM              INOCAJ
_journal_issue                   18
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9785
_journal_page_last               9799
_journal_paper_doi               10.1021/ic501374q
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C90 H46 Cl20 Co2 Dy2 N4 O20'
_chemical_formula_weight         2655.17
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 130.742(19)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   18.490(4)
_cell_length_b                   12.979(3)
_cell_length_c                   27.037(8)
_cell_measurement_reflns_used    37527
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.53
_cell_measurement_theta_min      3.03
_cell_volume                     4916(3)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0417
_diffrn_reflns_av_sigmaI/netI    0.0342
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            46888
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.03
_exptl_absorpt_coefficient_mu    2.448
_exptl_absorpt_correction_T_max  0.6402
_exptl_absorpt_correction_T_min  0.6402
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.794
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2600
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.657
_refine_diff_density_min         -0.826
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     622
_refine_ls_number_reflns         11245
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0391
_refine_ls_R_factor_gt           0.0295
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0155P)²+6.1278P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0575
_refine_ls_wR_factor_ref         0.0621
_reflns_number_gt                9558
_reflns_number_total             11245
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic501374q_si_001.cif
_cod_data_source_block           1Dy2Co2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4340970--4340975.cif.

 Updated bibliographic information.

 Antanas Vaitkus,
 2019-09-23
;
_cod_original_cell_volume        4916(2)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4340970
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.062521(9) 0.528994(9) 0.461980(6) 0.02411(4) Uani 1 1 d .
Co1 Co 0.28007(3) 0.57918(3) 0.467929(18) 0.03227(9) Uani 1 1 d .
Cl1 Cl 0.05969(8) 0.95767(8) 0.22259(5) 0.0665(3) Uani 1 1 d .
Cl2 Cl -0.23053(6) 0.84715(7) 0.21268(4) 0.0524(2) Uani 1 1 d .
Cl3 Cl 0.59593(8) 0.38490(11) 0.79907(5) 0.0835(4) Uani 1 1 d .
Cl4 Cl 0.33694(12) 0.60871(14) 0.78138(7) 0.1080(5) Uani 1 1 d .
Cl5 Cl -0.43396(7) 0.76921(10) 0.18043(4) 0.0713(3) Uani 1 1 d .
Cl6 Cl -0.37029(8) 0.80829(8) 0.40368(6) 0.0676(3) Uani 1 1 d .
Cl7 Cl 0.16905(12) 1.05861(9) 0.58207(7) 0.1019(5) Uani 1 1 d .
Cl8 Cl 0.21059(12) 0.86847(11) 0.77580(6) 0.1015(5) Uani 1 1 d .
Cl9 Cl 0.05103(9) 0.00766(9) 0.40118(7) 0.0822(3) Uani 1 1 d .
Cl10 Cl 0.31387(9) 0.08020(9) 0.37926(6) 0.0787(3) Uani 1 1 d .
O1 O 0.17379(15) 0.64293(19) 0.38067(10) 0.0467(6) Uani 1 1 d .
O2 O 0.07607(15) 0.63244(17) 0.40103(10) 0.0391(5) Uani 1 1 d .
O3 O 0.36285(16) 0.54050(19) 0.56379(10) 0.0453(5) Uani 1 1 d .
O4 O 0.22870(14) 0.57961(19) 0.54195(10) 0.0466(6) Uani 1 1 d .
O5 O -0.09476(14) 0.59600(17) 0.37551(10) 0.0396(5) Uani 1 1 d .
O6 O -0.10871(15) 0.55574(16) 0.44823(9) 0.0381(5) Uani 1 1 d .
O7 O 0.06412(15) 0.66845(15) 0.51432(10) 0.0369(5) Uani 1 1 d .
O8 O 0.03487(15) 0.61424(16) 0.57834(10) 0.0379(5) Uani 1 1 d .
O9 O 0.14191(16) 0.40554(17) 0.45057(11) 0.0438(5) Uani 1 1 d .
O10 O 0.24900(16) 0.43117(17) 0.43922(11) 0.0415(5) Uani 1 1 d .
N1 N 0.37497(16) 0.5996(2) 0.45234(11) 0.0347(5) Uani 1 1 d .
N2 N 0.3265(2) 0.7351(2) 0.49912(13) 0.0465(7) Uani 1 1 d .
C1 C 0.3939(2) 0.5279(3) 0.42666(14) 0.0412(7) Uani 1 1 d .
H1 H 0.3627 0.4631 0.4152 0.049 Uiso 1 1 calc R
C2 C 0.4560(2) 0.5437(3) 0.41612(17) 0.0524(9) Uani 1 1 d .
H2 H 0.4669 0.4914 0.3971 0.063 Uiso 1 1 calc R
C3 C 0.5018(3) 0.6360(4) 0.4336(2) 0.0722(12) Uani 1 1 d .
H3 H 0.5470 0.6480 0.4282 0.087 Uiso 1 1 calc R
C4 C 0.4824(3) 0.7117(4) 0.4590(2) 0.0695(12) Uani 1 1 d .
H4 H 0.5133 0.7766 0.4708 0.083 Uiso 1 1 calc R
C5 C 0.4170(2) 0.6922(3) 0.46743(16) 0.0438(8) Uani 1 1 d .
C6 C 0.3887(2) 0.7689(3) 0.49287(16) 0.0461(8) Uani 1 1 d .
C7 C 0.4207(3) 0.8697(3) 0.5078(2) 0.0683(11) Uani 1 1 d .
H7 H 0.4648 0.8933 0.5033 0.082 Uiso 1 1 calc R
C8 C 0.3878(4) 0.9352(3) 0.5292(2) 0.0760(13) Uani 1 1 d .
H8 H 0.4098 1.0044 0.5400 0.091 Uiso 1 1 calc R
C9 C 0.3240(3) 0.9016(3) 0.53505(19) 0.0687(12) Uani 1 1 d .
H9 H 0.3003 0.9467 0.5493 0.082 Uiso 1 1 calc R
C10 C 0.2947(3) 0.8000(3) 0.51967(18) 0.0590(10) Uani 1 1 d .
H10 H 0.2505 0.7755 0.5239 0.071 Uiso 1 1 calc R
C11 C 0.0996(2) 0.6675(2) 0.37005(13) 0.0326(6) Uani 1 1 d .
C12 C 0.0356(2) 0.7457(2) 0.31772(13) 0.0329(6) Uani 1 1 d .
C13 C 0.0710(2) 0.8054(2) 0.29512(14) 0.0382(7) Uani 1 1 d .
H13 H 0.1338 0.7947 0.3111 0.046 Uiso 1 1 calc R
C14 C 0.0135(2) 0.8806(3) 0.24912(15) 0.0431(8) Uani 1 1 d .
C15 C -0.0783(2) 0.8970(3) 0.22423(15) 0.0435(8) Uani 1 1 d .
H15 H -0.1168 0.9497 0.1930 0.052 Uiso 1 1 calc R
C16 C -0.1127(2) 0.8341(2) 0.24612(14) 0.0380(7) Uani 1 1 d .
C17 C -0.0565(2) 0.7596(2) 0.29344(14) 0.0367(7) Uani 1 1 d .
H17 H -0.0809 0.7189 0.3089 0.044 Uiso 1 1 calc R
C18 C 0.3147(2) 0.5534(2) 0.58078(14) 0.0350(7) Uani 1 1 d .
C19 C 0.3654(2) 0.5376(2) 0.65162(14) 0.0346(6) Uani 1 1 d .
C20 C 0.4487(2) 0.4799(3) 0.68899(14) 0.0404(7) Uani 1 1 d .
H20 H 0.4742 0.4538 0.6703 0.049 Uiso 1 1 calc R
C21 C 0.4942(2) 0.4609(3) 0.75378(16) 0.0462(8) Uani 1 1 d .
C22 C 0.4609(3) 0.5000(3) 0.78252(16) 0.0524(9) Uani 1 1 d .
H22 H 0.4932 0.4869 0.8272 0.063 Uiso 1 1 calc R
C23 C 0.3795(3) 0.5590(3) 0.74510(18) 0.0526(9) Uani 1 1 d .
C24 C 0.3298(2) 0.5779(3) 0.67958(15) 0.0430(7) Uani 1 1 d .
H24 H 0.2727 0.6174 0.6544 0.052 Uiso 1 1 calc R
C25 C -0.13750(19) 0.6008(2) 0.39679(13) 0.0311(6) Uani 1 1 d .
C26 C -0.22698(19) 0.6648(2) 0.36082(14) 0.0316(6) Uani 1 1 d .
C27 C -0.2797(2) 0.6875(2) 0.29531(14) 0.0394(7) Uani 1 1 d .
H27 H -0.2599 0.6639 0.2725 0.047 Uiso 1 1 calc R
C28 C -0.3620(2) 0.7456(3) 0.26385(15) 0.0443(8) Uani 1 1 d .
C29 C -0.3909(2) 0.7835(3) 0.29614(17) 0.0464(8) Uani 1 1 d .
H29 H -0.4470 0.8241 0.2740 0.056 Uiso 1 1 calc R
C30 C -0.3361(2) 0.7608(2) 0.36139(16) 0.0417(7) Uani 1 1 d .
C31 C -0.2551(2) 0.7006(2) 0.39428(15) 0.0358(7) Uani 1 1 d .
H31 H -0.2194 0.6840 0.4390 0.043 Uiso 1 1 calc R
C32 C 0.0654(2) 0.6785(2) 0.56120(14) 0.0325(6) Uani 1 1 d .
C33 C 0.1069(2) 0.7759(2) 0.60016(14) 0.0338(6) Uani 1 1 d .
C34 C 0.1183(2) 0.8613(3) 0.57533(17) 0.0442(8) Uani 1 1 d .
H34 H 0.0993 0.8596 0.5331 0.053 Uiso 1 1 calc R
C35 C 0.1580(3) 0.9495(3) 0.61338(19) 0.0544(9) Uani 1 1 d .
C36 C 0.1883(3) 0.9526(3) 0.67495(19) 0.0603(10) Uani 1 1 d .
H36 H 0.2168 1.0131 0.7008 0.072 Uiso 1 1 calc R
C37 C 0.1765(3) 0.8663(3) 0.69871(17) 0.0564(10) Uani 1 1 d .
C38 C 0.1351(2) 0.7779(3) 0.66189(15) 0.0440(8) Uani 1 1 d .
H38 H 0.1259 0.7195 0.6785 0.053 Uiso 1 1 calc R
C39 C 0.1935(2) 0.3755(2) 0.43884(14) 0.0333(6) Uani 1 1 d .
C40 C 0.1890(2) 0.2634(2) 0.42286(14) 0.0338(6) Uani 1 1 d .
C41 C 0.1276(2) 0.1964(3) 0.41936(16) 0.0421(7) Uani 1 1 d .
H41 H 0.0873 0.2205 0.4272 0.050 Uiso 1 1 calc R
C42 C 0.1253(2) 0.0940(3) 0.40433(16) 0.0470(8) Uani 1 1 d .
C43 C 0.1821(3) 0.0578(3) 0.39169(17) 0.0494(8) Uani 1 1 d .
H43 H 0.1794 -0.0124 0.3807 0.059 Uiso 1 1 calc R
C44 C 0.2421(2) 0.1250(3) 0.39531(16) 0.0456(8) Uani 1 1 d .
C45 C 0.2477(2) 0.2274(2) 0.41135(15) 0.0396(7) Uani 1 1 d .
H45 H 0.2909 0.2726 0.4145 0.048 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Dy1 O6 157.75(8) . 3_566
O2 Dy1 O7 91.05(8) . .
O6 Dy1 O7 82.95(8) 3_566 .
O2 Dy1 O8 123.86(8) . 3_566
O6 Dy1 O8 75.36(8) 3_566 3_566
O7 Dy1 O8 128.40(7) . 3_566
O2 Dy1 O9 86.14(8) . .
O6 Dy1 O9 88.77(8) 3_566 .
O7 Dy1 O9 150.86(8) . .
O8 Dy1 O9 75.39(8) 3_566 .
O2 Dy1 O5 73.52(7) . .
O6 Dy1 O5 125.98(7) 3_566 .
O7 Dy1 O5 80.48(8) . .
O8 Dy1 O5 75.92(8) 3_566 .
O9 Dy1 O5 125.92(8) . .
O2 Dy1 O4 79.07(8) . .
O6 Dy1 O4 78.69(8) 3_566 .
O7 Dy1 O4 74.72(8) . .
O8 Dy1 O4 141.61(8) 3_566 .
O9 Dy1 O4 76.27(8) . .
O5 Dy1 O4 142.40(8) . .
O10 Co1 O1 97.23(10) . .
O10 Co1 O3 92.51(10) . .
O1 Co1 O3 160.28(9) . .
O10 Co1 N1 96.34(9) . .
O1 Co1 N1 91.00(9) . .
O3 Co1 N1 104.95(9) . .
O10 Co1 N2 173.68(10) . .
O1 Co1 N2 84.66(11) . .
O3 Co1 N2 87.52(10) . .
N1 Co1 N2 77.57(11) . .
C11 O1 Co1 117.43(18) . .
C11 O2 Dy1 162.4(2) . .
C18 O3 Co1 108.11(19) . .
C18 O4 Dy1 148.3(2) . .
C25 O5 Dy1 107.32(17) . .
C25 O6 Dy1 177.7(2) . 3_566
C32 O7 Dy1 133.61(19) . .
C32 O8 Dy1 139.69(19) . 3_566
C39 O9 Dy1 154.4(2) . .
C39 O10 Co1 125.59(19) . .
C1 N1 C5 119.1(3) . .
C1 N1 Co1 124.0(2) . .
C5 N1 Co1 116.9(2) . .
C10 N2 C6 119.5(3) . .
C10 N2 Co1 125.9(3) . .
C6 N2 Co1 114.5(2) . .
N1 C1 C2 123.0(3) . .
N1 C1 H1 118.5 . .
C2 C1 H1 118.5 . .
C3 C2 C1 118.4(4) . .
C3 C2 H2 120.8 . .
C1 C2 H2 120.8 . .
C2 C3 C4 119.7(4) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C3 C4 C5 119.4(4) . .
C3 C4 H4 120.3 . .
C5 C4 H4 120.3 . .
N1 C5 C4 120.4(3) . .
N1 C5 C6 115.6(3) . .
C4 C5 C6 124.1(3) . .
N2 C6 C7 120.8(4) . .
N2 C6 C5 115.5(3) . .
C7 C6 C5 123.7(4) . .
C8 C7 C6 119.0(4) . .
C8 C7 H7 120.5 . .
C6 C7 H7 120.5 . .
C9 C8 C7 120.5(4) . .
C9 C8 H8 119.8 . .
C7 C8 H8 119.8 . .
C8 C9 C10 118.0(4) . .
C8 C9 H9 121.0 . .
C10 C9 H9 121.0 . .
N2 C10 C9 122.2(4) . .
N2 C10 H10 118.9 . .
C9 C10 H10 118.9 . .
O1 C11 O2 124.3(3) . .
O1 C11 C12 117.6(2) . .
O2 C11 C12 118.2(3) . .
C17 C12 C13 120.5(3) . .
C17 C12 C11 120.4(3) . .
C13 C12 C11 119.1(3) . .
C14 C13 C12 119.0(3) . .
C14 C13 H13 120.5 . .
C12 C13 H13 120.5 . .
C15 C14 C13 122.0(3) . .
C15 C14 Cl1 119.3(2) . .
C13 C14 Cl1 118.7(3) . .
C14 C15 C16 117.8(3) . .
C14 C15 H15 121.1 . .
C16 C15 H15 121.1 . .
C17 C16 C15 122.0(3) . .
C17 C16 Cl2 118.6(2) . .
C15 C16 Cl2 119.4(2) . .
C12 C17 C16 118.7(3) . .
C12 C17 H17 120.7 . .
C16 C17 H17 120.7 . .
O3 C18 O4 123.2(3) . .
O3 C18 C19 116.7(3) . .
O4 C18 C19 120.1(3) . .
C20 C19 C24 120.1(3) . .
C20 C19 C18 118.5(3) . .
C24 C19 C18 121.4(3) . .
C21 C20 C19 119.2(3) . .
C21 C20 H20 120.4 . .
C19 C20 H20 120.4 . .
C22 C21 C20 121.7(3) . .
C22 C21 Cl3 119.6(3) . .
C20 C21 Cl3 118.7(3) . .
C21 C22 C23 118.2(3) . .
C21 C22 H22 120.9 . .
C23 C22 H22 120.9 . .
C22 C23 C24 122.3(3) . .
C22 C23 Cl4 118.3(3) . .
C24 C23 Cl4 119.4(3) . .
C23 C24 C19 118.4(3) . .
C23 C24 H24 120.8 . .
C19 C24 H24 120.8 . .
O5 C25 O6 123.1(3) . .
O5 C25 C26 119.3(2) . .
O6 C25 C26 117.5(3) . .
C27 C26 C31 120.8(3) . .
C27 C26 C25 120.2(3) . .
C31 C26 C25 119.0(3) . .
C28 C27 C26 118.4(3) . .
C28 C27 H27 120.8 . .
C26 C27 H27 120.8 . .
C29 C28 C27 122.0(3) . .
C29 C28 Cl5 118.3(2) . .
C27 C28 Cl5 119.7(3) . .
C30 C29 C28 118.1(3) . .
C30 C29 H29 121.0 . .
C28 C29 H29 121.0 . .
C29 C30 C31 122.0(3) . .
C29 C30 Cl6 119.1(3) . .
C31 C30 Cl6 118.9(3) . .
C30 C31 C26 118.7(3) . .
C30 C31 H31 120.6 . .
C26 C31 H31 120.6 . .
O8 C32 O7 125.9(3) . .
O8 C32 C33 116.8(3) . .
O7 C32 C33 117.4(3) . .
C34 C33 C38 120.9(3) . .
C34 C33 C32 120.4(3) . .
C38 C33 C32 118.6(3) . .
C33 C34 C35 118.5(3) . .
C33 C34 H34 120.8 . .
C35 C34 H34 120.8 . .
C36 C35 C34 121.7(3) . .
C36 C35 Cl7 119.1(3) . .
C34 C35 Cl7 119.2(3) . .
C35 C36 C37 118.7(3) . .
C35 C36 H36 120.7 . .
C37 C36 H36 120.7 . .
C36 C37 C38 121.6(3) . .
C36 C37 Cl8 120.1(3) . .
C38 C37 Cl8 118.3(3) . .
C37 C38 C33 118.6(3) . .
C37 C38 H38 120.7 . .
C33 C38 H38 120.7 . .
O9 C39 O10 125.3(3) . .
O9 C39 C40 117.8(3) . .
O10 C39 C40 117.0(3) . .
C41 C40 C45 120.0(3) . .
C41 C40 C39 121.1(3) . .
C45 C40 C39 118.9(3) . .
C42 C41 C40 119.3(3) . .
C42 C41 H41 120.3 . .
C40 C41 H41 120.3 . .
C43 C42 C41 121.2(3) . .
C43 C42 Cl9 118.3(3) . .
C41 C42 Cl9 120.5(3) . .
C44 C43 C42 118.6(3) . .
C44 C43 H43 120.7 . .
C42 C43 H43 120.7 . .
C43 C44 C45 121.9(3) . .
C43 C44 Cl10 119.0(3) . .
C45 C44 Cl10 119.1(3) . .
C44 C45 C40 118.9(3) . .
C44 C45 H45 120.5 . .
C40 C45 H45 120.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O2 2.263(2) .
Dy1 O6 2.264(2) 3_566
Dy1 O7 2.2858(19) .
Dy1 O8 2.308(2) 3_566
Dy1 O9 2.326(2) .
Dy1 O5 2.409(2) .
Dy1 O4 2.424(2) .
Co1 O10 2.010(2) .
Co1 O1 2.015(2) .
Co1 O3 2.033(2) .
Co1 N1 2.072(2) .
Co1 N2 2.145(3) .
Cl1 C14 1.745(3) .
Cl2 C16 1.738(3) .
Cl3 C21 1.733(4) .
Cl4 C23 1.733(4) .
Cl5 C28 1.742(3) .
Cl6 C30 1.741(3) .
Cl7 C35 1.729(4) .
Cl8 C37 1.740(4) .
Cl9 C42 1.732(4) .
Cl10 C44 1.743(3) .
O1 C11 1.246(3) .
O2 C11 1.254(3) .
O3 C18 1.251(4) .
O4 C18 1.252(4) .
O5 C25 1.246(3) .
O6 C25 1.262(3) .
O6 Dy1 2.264(2) 3_566
O7 C32 1.259(3) .
O8 C32 1.253(3) .
O8 Dy1 2.308(2) 3_566
O9 C39 1.248(3) .
O10 C39 1.249(4) .
N1 C1 1.336(4) .
N1 C5 1.342(4) .
N2 C10 1.337(4) .
N2 C6 1.341(4) .
C1 C2 1.367(4) .
C1 H1 0.9500 .
C2 C3 1.362(6) .
C2 H2 0.9500 .
C3 C4 1.375(6) .
C3 H3 0.9500 .
C4 C5 1.391(5) .
C4 H4 0.9500 .
C5 C6 1.486(5) .
C6 C7 1.383(5) .
C7 C8 1.373(6) .
C7 H7 0.9500 .
C8 C9 1.361(6) .
C8 H8 0.9500 .
C9 C10 1.383(6) .
C9 H9 0.9500 .
C10 H10 0.9500 .
C11 C12 1.499(4) .
C12 C17 1.381(4) .
C12 C13 1.386(4) .
C13 C14 1.380(4) .
C13 H13 0.9500 .
C14 C15 1.373(5) .
C15 C16 1.384(4) .
C15 H15 0.9500 .
C16 C17 1.384(4) .
C17 H17 0.9500 .
C18 C19 1.498(4) .
C19 C20 1.386(4) .
C19 C24 1.389(4) .
C20 C21 1.383(4) .
C20 H20 0.9500 .
C21 C22 1.366(5) .
C22 C23 1.374(5) .
C22 H22 0.9500 .
C23 C24 1.385(5) .
C24 H24 0.9500 .
C25 C26 1.507(4) .
C26 C27 1.386(4) .
C26 C31 1.386(4) .
C27 C28 1.385(4) .
C27 H27 0.9500 .
C28 C29 1.377(5) .
C29 C30 1.376(5) .
C29 H29 0.9500 .
C30 C31 1.380(4) .
C31 H31 0.9500 .
C32 C33 1.497(4) .
C33 C34 1.381(4) .
C33 C38 1.387(4) .
C34 C35 1.386(4) .
C34 H34 0.9500 .
C35 C36 1.368(5) .
C36 C37 1.377(5) .
C36 H36 0.9500 .
C37 C38 1.378(4) .
C38 H38 0.9500 .
C39 C40 1.505(4) .
C40 C41 1.384(4) .
C40 C45 1.390(4) .
C41 C42 1.382(5) .
C41 H41 0.9500 .
C42 C43 1.381(5) .
C43 C44 1.363(5) .
C43 H43 0.9500 .
C44 C45 1.382(4) .
C45 H45 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O10 Co1 O1 C11 96.7(2) .
O3 Co1 O1 C11 -22.3(4) .
N1 Co1 O1 C11 -166.7(2) .
N2 Co1 O1 C11 -89.3(2) .
O6 Dy1 O2 C11 68.3(7) 3_566
O7 Dy1 O2 C11 142.1(7) .
O8 Dy1 O2 C11 -78.4(7) 3_566
O9 Dy1 O2 C11 -8.9(7) .
O5 Dy1 O2 C11 -138.2(7) .
O4 Dy1 O2 C11 67.8(7) .
O10 Co1 O3 C18 -99.9(2) .
O1 Co1 O3 C18 19.8(4) .
N1 Co1 O3 C18 162.8(2) .
N2 Co1 O3 C18 86.4(2) .
O2 Dy1 O4 C18 -119.0(4) .
O6 Dy1 O4 C18 61.2(4) 3_566
O7 Dy1 O4 C18 146.9(4) .
O8 Dy1 O4 C18 13.1(5) 3_566
O9 Dy1 O4 C18 -30.3(4) .
O5 Dy1 O4 C18 -162.6(4) .
O2 Dy1 O5 C25 -150.4(2) .
O6 Dy1 O5 C25 17.6(2) 3_566
O7 Dy1 O5 C25 -56.4(2) .
O8 Dy1 O5 C25 77.32(19) 3_566
O9 Dy1 O5 C25 137.14(19) .
O4 Dy1 O5 C25 -105.5(2) .
O2 Dy1 O7 C32 -174.6(3) .
O6 Dy1 O7 C32 -16.1(3) 3_566
O8 Dy1 O7 C32 48.9(3) 3_566
O9 Dy1 O7 C32 -90.7(3) .
O5 Dy1 O7 C32 112.3(3) .
O4 Dy1 O7 C32 -96.2(3) .
O2 Dy1 O9 C39 19.6(5) .
O6 Dy1 O9 C39 -138.7(5) 3_566
O7 Dy1 O9 C39 -65.6(5) .
O8 Dy1 O9 C39 146.1(5) 3_566
O5 Dy1 O9 C39 86.0(5) .
O4 Dy1 O9 C39 -60.1(5) .
O1 Co1 O10 C39 -89.0(2) .
O3 Co1 O10 C39 73.8(2) .
N1 Co1 O10 C39 179.1(2) .
O10 Co1 N1 C1 3.7(2) .
O1 Co1 N1 C1 -93.7(2) .
O3 Co1 N1 C1 98.0(2) .
N2 Co1 N1 C1 -178.0(2) .
O10 Co1 N1 C5 -178.5(2) .
O1 Co1 N1 C5 84.1(2) .
O3 Co1 N1 C5 -84.1(2) .
N2 Co1 N1 C5 -0.2(2) .
O1 Co1 N2 C10 84.7(3) .
O3 Co1 N2 C10 -77.2(3) .
N1 Co1 N2 C10 176.9(3) .
O1 Co1 N2 C6 -91.2(2) .
O3 Co1 N2 C6 107.0(2) .
N1 Co1 N2 C6 1.1(2) .
C5 N1 C1 C2 1.4(5) .
Co1 N1 C1 C2 179.2(2) .
N1 C1 C2 C3 1.1(5) .
C1 C2 C3 C4 -2.2(6) .
C2 C3 C4 C5 0.9(7) .
C1 N1 C5 C4 -2.7(5) .
Co1 N1 C5 C4 179.3(3) .
C1 N1 C5 C6 177.3(3) .
Co1 N1 C5 C6 -0.7(4) .
C3 C4 C5 N1 1.6(6) .
C3 C4 C5 C6 -178.4(4) .
C10 N2 C6 C7 0.4(5) .
Co1 N2 C6 C7 176.5(3) .
C10 N2 C6 C5 -177.9(3) .
Co1 N2 C6 C5 -1.7(4) .
N1 C5 C6 N2 1.6(4) .
C4 C5 C6 N2 -178.4(3) .
N1 C5 C6 C7 -176.6(3) .
C4 C5 C6 C7 3.5(6) .
N2 C6 C7 C8 0.0(6) .
C5 C6 C7 C8 178.1(4) .
C6 C7 C8 C9 -0.6(7) .
C7 C8 C9 C10 0.8(7) .
C6 N2 C10 C9 -0.1(6) .
Co1 N2 C10 C9 -175.8(3) .
C8 C9 C10 N2 -0.4(6) .
Co1 O1 C11 O2 -19.4(4) .
Co1 O1 C11 C12 159.3(2) .
Dy1 O2 C11 O1 -24.7(9) .
Dy1 O2 C11 C12 156.7(5) .
O1 C11 C12 C17 165.6(3) .
O2 C11 C12 C17 -15.7(4) .
O1 C11 C12 C13 -15.9(4) .
O2 C11 C12 C13 162.9(3) .
C17 C12 C13 C14 1.5(5) .
C11 C12 C13 C14 -177.0(3) .
C12 C13 C14 C15 -1.2(5) .
C12 C13 C14 Cl1 178.3(2) .
C13 C14 C15 C16 -0.9(5) .
Cl1 C14 C15 C16 179.7(2) .
C14 C15 C16 C17 2.6(5) .
C14 C15 C16 Cl2 -176.5(2) .
C13 C12 C17 C16 0.1(4) .
C11 C12 C17 C16 178.7(3) .
C15 C16 C17 C12 -2.3(5) .
Cl2 C16 C17 C12 176.8(2) .
Co1 O3 C18 O4 4.0(4) .
Co1 O3 C18 C19 -175.0(2) .
Dy1 O4 C18 O3 85.1(5) .
Dy1 O4 C18 C19 -96.0(4) .
O3 C18 C19 C20 -20.3(4) .
O4 C18 C19 C20 160.6(3) .
O3 C18 C19 C24 160.8(3) .
O4 C18 C19 C24 -18.2(4) .
C24 C19 C20 C21 1.6(5) .
C18 C19 C20 C21 -177.3(3) .
C19 C20 C21 C22 -2.0(5) .
C19 C20 C21 Cl3 177.8(2) .
C20 C21 C22 C23 0.5(5) .
Cl3 C21 C22 C23 -179.2(3) .
C21 C22 C23 C24 1.3(6) .
C21 C22 C23 Cl4 179.9(3) .
C22 C23 C24 C19 -1.7(5) .
Cl4 C23 C24 C19 179.7(3) .
C20 C19 C24 C23 0.2(5) .
C18 C19 C24 C23 179.0(3) .
Dy1 O5 C25 O6 -14.7(3) .
Dy1 O5 C25 C26 164.1(2) .
O5 C25 C26 C27 22.6(4) .
O6 C25 C26 C27 -158.5(3) .
O5 C25 C26 C31 -157.1(3) .
O6 C25 C26 C31 21.8(4) .
C31 C26 C27 C28 -1.0(5) .
C25 C26 C27 C28 179.3(3) .
C26 C27 C28 C29 2.0(5) .
C26 C27 C28 Cl5 -176.2(2) .
C27 C28 C29 C30 -1.0(5) .
Cl5 C28 C29 C30 177.2(3) .
C28 C29 C30 C31 -1.1(5) .
C28 C29 C30 Cl6 179.6(3) .
C29 C30 C31 C26 2.0(5) .
Cl6 C30 C31 C26 -178.6(2) .
C27 C26 C31 C30 -1.0(4) .
C25 C26 C31 C30 178.7(3) .
Dy1 O8 C32 O7 -16.7(5) 3_566
Dy1 O8 C32 C33 163.3(2) 3_566
Dy1 O7 C32 O8 -25.5(5) .
Dy1 O7 C32 C33 154.5(2) .
O8 C32 C33 C34 -162.4(3) .
O7 C32 C33 C34 17.5(4) .
O8 C32 C33 C38 18.6(4) .
O7 C32 C33 C38 -161.4(3) .
C38 C33 C34 C35 -0.4(5) .
C32 C33 C34 C35 -179.3(3) .
C33 C34 C35 C36 1.8(6) .
C33 C34 C35 Cl7 -177.8(3) .
C34 C35 C36 C37 -1.5(6) .
Cl7 C35 C36 C37 178.1(3) .
C35 C36 C37 C38 -0.2(6) .
C35 C36 C37 Cl8 -178.0(3) .
C36 C37 C38 C33 1.6(6) .
Cl8 C37 C38 C33 179.4(3) .
C34 C33 C38 C37 -1.3(5) .
C32 C33 C38 C37 177.6(3) .
Dy1 O9 C39 O10 18.4(7) .
Dy1 O9 C39 C40 -161.6(3) .
Co1 O10 C39 O9 6.9(4) .
Co1 O10 C39 C40 -173.13(18) .
O9 C39 C40 C41 1.9(4) .
O10 C39 C40 C41 -178.1(3) .
O9 C39 C40 C45 -178.3(3) .
O10 C39 C40 C45 1.8(4) .
C45 C40 C41 C42 0.0(5) .
C39 C40 C41 C42 179.8(3) .
C40 C41 C42 C43 -1.1(5) .
C40 C41 C42 Cl9 178.7(2) .
C41 C42 C43 C44 1.0(5) .
Cl9 C42 C43 C44 -178.8(3) .
C42 C43 C44 C45 0.2(5) .
C42 C43 C44 Cl10 -179.8(3) .
C43 C44 C45 C40 -1.3(5) .
Cl10 C44 C45 C40 178.7(2) .
C41 C40 C45 C44 1.2(5) .
C39 C40 C45 C44 -178.6(3) .
