#------------------------------------------------------------------------------
#$Date: 2016-03-23 23:59:59 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179520 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/17/4341760.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4341760
loop_
_publ_author_name
'Mednikov, Evgueni G.'
'Dahl, Lawrence F.'
_publ_section_title
;
 Acid/Base-Controlled Au(I)/Au(0) Reductive Transformations of the
 Monogold [(μ14-Au)Pd22(CO)20(PEt3)8](+) Monocation into Three Different
 Neutral Digold Nanoclusters: Au2Pd21(CO)20(PEt3)10,
 Au2Pd28(CO)26(PEt3)10, and New Five-Layer Hexagonal Close-Packed
 (μ12-Au)2Pd42(CO)30(PEt3)12 with a Trigonal-Bipyramidal AuPd3Au Kernel.
;
_journal_issue                   3
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1145
_journal_page_last               1151
_journal_paper_doi               10.1021/ic502470m
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C102 H180 Au2 O30 P12 Pd42'
_chemical_formula_sum            'C102 H180 Au2 O30 P12 Pd42'
_chemical_formula_weight         7120.83
_chemical_name_common            'Gold/Palladium Carbonyl Phosphine Cluster'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           167
_space_group_name_Hall           '-R 3 2"c'
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3 2"c'
_symmetry_space_group_name_H-M   'R -3 c :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   28.2643(10)
_cell_length_b                   28.2643(10)
_cell_length_c                   36.1195(14)
_cell_measurement_temperature    100(2)
_cell_volume                     24989.0(16)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'w and f scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0493
_diffrn_reflns_av_sigmaI/netI    0.0152
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       44
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_number            142041
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.01
_exptl_absorpt_coefficient_mu    6.322
_exptl_absorpt_correction_T_max  0.5791
_exptl_absorpt_correction_T_min  0.4937
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
SADABS  (Bruker-AXS, 2007)
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    2.839
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'block crystal'
_exptl_crystal_F_000             19812
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.274
_refine_diff_density_min         -2.667
_refine_diff_density_rms         0.260
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     276
_refine_ls_number_reflns         5437
_refine_ls_number_restraints     35
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0779
_refine_ls_R_factor_gt           0.0599
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0616P)²+2566.1482P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1572
_refine_ls_wR_factor_ref         0.1696
_reflns_number_gt                4525
_reflns_number_total             5437
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic502470m_si_001.cif
_cod_data_source_block           dahl374
_cod_depositor_comments          'Adding full bibliography for 4341760.cif.'
_cod_original_sg_symbol_H-M      R-3c
_cod_database_code               4341760
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+5/6'
'x-y+2/3, -y+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+7/6'
'x-y+1/3, -y+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z-1/6'
'-x+y+2/3, y+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+1/6'
'-x+y+1/3, y+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.6667 0.3333 1.019652(18) 0.02495(19) Uani 1 3 d S . .
Pd1 Pd 0.6667 0.38815(4) 1.0833 0.0214(2) Uani 1 2 d S . .
Pd2 Pd 0.72000(3) 0.44842(3) 1.02014(2) 0.0274(2) Uani 1 1 d . . .
Pd3 Pd 0.78161(4) 0.44827(4) 1.0833 0.0294(3) Uani 1 2 d SD . .
Pd4 Pd 0.60523(3) 0.38561(3) 1.01808(2) 0.0277(2) Uani 1 1 d D . .
Pd5 Pd 0.66611(3) 0.38988(3) 0.95711(2) 0.0290(2) Uani 1 1 d . . .
Pd6 Pd 0.72291(4) 0.50080(4) 1.08574(2) 0.0335(2) Uani 1 1 d . . .
Pd7 Pd 0.77705(4) 0.44715(4) 0.95258(3) 0.0376(2) Uani 1 1 d . . .
Pd8 Pd 0.66785(4) 0.50938(4) 1.02249(3) 0.0408(3) Uani 1 1 d D . .
P1 P 0.8403(2) 0.51571(17) 0.91442(12) 0.0694(13) Uani 1 1 d D A .
O1 O 0.5574(13) 0.4338(11) 0.9722(8) 0.071(8) Uiso 0.42 1 d PD A 1
C1 C 0.5696(13) 0.4002(12) 0.9741(7) 0.040(7) Uiso 0.42 1 d PD A 1
O1A O 0.5294(10) 0.4132(9) 0.9897(7) 0.080(6) Uiso 0.58 1 d PD A 2
C1A C 0.5482(9) 0.3853(10) 0.9859(6) 0.048(6) Uiso 0.58 1 d PD A 2
O2 O 0.7811(6) 0.5566(5) 0.9907(4) 0.081(4) Uani 1 1 d . A .
C2 C 0.7412(6) 0.5212(5) 1.0042(4) 0.051(3) Uani 1 1 d . . .
O3 O 0.9050(9) 0.5100(9) 1.0864(8) 0.089(8) Uiso 0.51 1 d PD B 3
C3 C 0.8618(6) 0.4720(10) 1.0831(7) 0.045(6) Uiso 0.51 1 d PD B 3
O3A O 0.8885(12) 0.5018(12) 1.0482(9) 0.098(9) Uiso 0.49 1 d PD B 4
C3A C 0.8492(11) 0.4612(14) 1.0561(11) 0.082(11) Uiso 0.49 1 d PD . 4
O4 O 0.7057(4) 0.4453(5) 0.8885(3) 0.060(3) Uani 1 1 d . . .
O5 O 0.7475(6) 0.6111(5) 1.1044(3) 0.081(4) Uani 1 1 d . B .
C4 C 0.7132(6) 0.4348(6) 0.9181(3) 0.048(3) Uani 1 1 d . A .
C5 C 0.7237(7) 0.5658(7) 1.1119(4) 0.057(4) Uani 1 1 d . . .
C11 C 0.829(2) 0.551(2) 0.8760(13) 0.099(19) Uiso 0.36 1 d PD A 5
H11A H 0.8266 0.5307 0.8530 0.119 Uiso 0.36 1 calc PR A 5
H11B H 0.7923 0.5472 0.8797 0.119 Uiso 0.36 1 calc PR A 5
C12 C 0.8814(17) 0.488(2) 0.8946(15) 0.085(16) Uiso 0.36 1 d PD A 5
H12A H 0.9124 0.5172 0.8806 0.101 Uiso 0.36 1 calc PR A 5
H12B H 0.8968 0.4763 0.9150 0.101 Uiso 0.36 1 calc PR A 5
C13 C 0.9031(8) 0.5668(10) 0.9376(8) 0.029(6) Uiso 0.36 1 d PD A 5
H13A H 0.9236 0.5482 0.9447 0.035 Uiso 0.36 1 calc PR A 5
H13B H 0.9254 0.5946 0.9189 0.035 Uiso 0.36 1 calc PR A 5
C14 C 0.870(3) 0.611(2) 0.870(2) 0.110(12) Uiso 0.36 1 d PD A 5
H14A H 0.8522 0.6289 0.8582 0.166 Uiso 0.36 1 calc PR A 5
H14B H 0.8998 0.6142 0.8542 0.166 Uiso 0.36 1 calc PR A 5
H14C H 0.8852 0.6282 0.8940 0.166 Uiso 0.36 1 calc PR A 5
C15 C 0.848(3) 0.439(2) 0.8689(18) 0.050(18) Uiso 0.36 1 d PD A 5
H15A H 0.8720 0.4269 0.8584 0.075 Uiso 0.36 1 calc PR A 5
H15B H 0.8325 0.4505 0.8488 0.075 Uiso 0.36 1 calc PR A 5
H15C H 0.8187 0.4095 0.8830 0.075 Uiso 0.36 1 calc PR A 5
C16 C 0.901(4) 0.597(3) 0.9718(15) 0.11(2) Uiso 0.36 1 d PD A 5
H16A H 0.9378 0.6226 0.9805 0.169 Uiso 0.36 1 calc PR A 5
H16B H 0.8801 0.5710 0.9915 0.169 Uiso 0.36 1 calc PR A 5
H16C H 0.8824 0.6180 0.9655 0.169 Uiso 0.36 1 calc PR A 5
C11A C 0.8179(9) 0.5647(8) 0.8997(6) 0.052(5) Uiso 0.64 1 d PD A 6
H11C H 0.7817 0.5425 0.8879 0.063 Uiso 0.64 1 calc PR A 6
H11D H 0.8116 0.5797 0.9228 0.063 Uiso 0.64 1 calc PR A 6
C12A C 0.8418(11) 0.4889(10) 0.8684(4) 0.063(6) Uiso 0.64 1 d PD A 6
H12C H 0.8058 0.4748 0.8562 0.076 Uiso 0.64 1 calc PR A 6
H12D H 0.8698 0.5185 0.8528 0.076 Uiso 0.64 1 calc PR A 6
C13A C 0.9135(5) 0.5567(16) 0.9236(11) 0.118(14) Uiso 0.64 1 d PD A 6
H13C H 0.9302 0.5337 0.9283 0.142 Uiso 0.64 1 calc PR A 6
H13D H 0.9333 0.5827 0.9033 0.142 Uiso 0.64 1 calc PR A 6
C14A C 0.8507(16) 0.6133(14) 0.8742(11) 0.110(12) Uiso 0.64 1 d PD A 6
H14D H 0.8307 0.6330 0.8703 0.166 Uiso 0.64 1 calc PR A 6
H14E H 0.8563 0.6003 0.8503 0.166 Uiso 0.64 1 calc PR A 6
H14F H 0.8863 0.6379 0.8855 0.166 Uiso 0.64 1 calc PR A 6
C15A C 0.855(2) 0.4428(18) 0.8723(16) 0.10(2) Uiso 0.64 1 d PD A 6
H15D H 0.8554 0.4282 0.8477 0.145 Uiso 0.64 1 calc PR A 6
H15E H 0.8273 0.4137 0.8878 0.145 Uiso 0.64 1 calc PR A 6
H15F H 0.8911 0.4572 0.8838 0.145 Uiso 0.64 1 calc PR A 6
C16A C 0.9111(18) 0.5856(18) 0.9586(11) 0.107(12) Uiso 0.64 1 d PD A 6
H16D H 0.9483 0.6104 0.9674 0.161 Uiso 0.64 1 calc PR A 6
H16E H 0.8907 0.5584 0.9778 0.161 Uiso 0.64 1 calc PR A 6
H16F H 0.8928 0.6065 0.9531 0.161 Uiso 0.64 1 calc PR A 6
P2 P 0.6654(3) 0.5628(3) 0.97515(18) 0.0578(17) Uani 0.68 1 d PD C 7
C21 C 0.6540(14) 0.5285(10) 0.9302(4) 0.081(8) Uiso 0.68 1 d PD C 7
H21A H 0.6802 0.5149 0.9283 0.097 Uiso 0.68 1 calc PR C 7
H21B H 0.6169 0.4960 0.9307 0.097 Uiso 0.68 1 calc PR C 7
C22 C 0.7292(8) 0.6281(7) 0.9693(7) 0.074(6) Uiso 0.68 1 d PD C 7
H22A H 0.7586 0.6208 0.9614 0.089 Uiso 0.68 1 calc PR C 7
H22B H 0.7243 0.6494 0.9494 0.089 Uiso 0.68 1 calc PR C 7
C23 C 0.6162(8) 0.5868(9) 0.9803(9) 0.067(8) Uiso 0.68 1 d PD C 7
H23A H 0.6166 0.5982 1.0063 0.081 Uiso 0.68 1 calc PR C 7
H23B H 0.6272 0.6190 0.9643 0.081 Uiso 0.68 1 calc PR C 7
C24 C 0.6589(13) 0.5601(12) 0.8948(7) 0.084(7) Uiso 0.68 1 d PD C 7
H24A H 0.6515 0.5361 0.8733 0.126 Uiso 0.68 1 calc PR C 7
H24B H 0.6959 0.5916 0.8929 0.126 Uiso 0.68 1 calc PR C 7
H24C H 0.6324 0.5728 0.8954 0.126 Uiso 0.68 1 calc PR C 7
C25 C 0.7469(16) 0.6620(13) 1.0048(7) 0.094(10) Uiso 0.68 1 d PD C 7
H25A H 0.7811 0.6962 1.0004 0.141 Uiso 0.68 1 calc PR C 7
H25B H 0.7524 0.6413 1.0245 0.141 Uiso 0.68 1 calc PR C 7
H25C H 0.7184 0.6702 1.0124 0.141 Uiso 0.68 1 calc PR C 7
C26 C 0.5581(7) 0.5423(15) 0.9701(13) 0.145(17) Uiso 0.68 1 d PD C 7
H26A H 0.5330 0.5564 0.9733 0.217 Uiso 0.68 1 calc PR C 7
H26B H 0.5468 0.5105 0.9862 0.217 Uiso 0.68 1 calc PR C 7
H26C H 0.5574 0.5314 0.9442 0.217 Uiso 0.68 1 calc PR C 7
P2A P 0.6754(7) 0.5853(6) 0.9900(4) 0.062(4) Uani 0.32 1 d PD D 8
C21A C 0.7179(18) 0.6518(13) 1.0122(16) 0.069(15) Uiso 0.32 1 d PD D 8
H21C H 0.7199 0.6812 0.9962 0.083 Uiso 0.32 1 calc PR D 8
H21D H 0.7014 0.6529 1.0361 0.083 Uiso 0.32 1 calc PR D 8
C22A C 0.702(2) 0.5946(17) 0.9426(7) 0.074(6) Uiso 0.32 1 d PD D 8
H22C H 0.6961 0.6218 0.9297 0.089 Uiso 0.32 1 calc PR D 8
H22D H 0.7422 0.6090 0.9437 0.089 Uiso 0.32 1 calc PR D 8
C23A C 0.6118(17) 0.575(2) 0.969(2) 0.10(3) Uiso 0.32 1 d PD D 8
H23C H 0.6034 0.5518 0.9470 0.114 Uiso 0.32 1 calc PR D 8
H23D H 0.5817 0.5559 0.9870 0.114 Uiso 0.32 1 calc PR D 8
C24A C 0.775(2) 0.661(3) 1.0187(19) 0.084(7) Uiso 0.32 1 d PD D 8
H24D H 0.7980 0.6963 1.0306 0.126 Uiso 0.32 1 calc PR D 8
H24E H 0.7916 0.6599 0.9950 0.126 Uiso 0.32 1 calc PR D 8
H24F H 0.7731 0.6318 1.0348 0.126 Uiso 0.32 1 calc PR D 8
C25A C 0.675(3) 0.541(2) 0.9206(10) 0.09(2) Uiso 0.32 1 d PD D 8
H25D H 0.6908 0.5479 0.8956 0.128 Uiso 0.32 1 calc PR D 8
H25E H 0.6360 0.5271 0.9191 0.128 Uiso 0.32 1 calc PR D 8
H25F H 0.6822 0.5143 0.9331 0.128 Uiso 0.32 1 calc PR D 8
C26A C 0.613(3) 0.628(2) 0.9575(19) 0.09(2) Uiso 0.32 1 d PD D 8
H26D H 0.5778 0.6195 0.9471 0.142 Uiso 0.32 1 calc PR D 8
H26E H 0.6418 0.6473 0.9389 0.142 Uiso 0.32 1 calc PR D 8
H26F H 0.6210 0.6519 0.9792 0.142 Uiso 0.32 1 calc PR D 8
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Pd5 Au1 Pd5 60.25(3) 3_665 2_655
Pd5 Au1 Pd5 60.25(3) 3_665 .
Pd5 Au1 Pd5 60.25(3) 2_655 .
Pd5 Au1 Pd1 146.657(19) 3_665 .
Pd5 Au1 Pd1 147.159(19) 2_655 .
Pd5 Au1 Pd1 110.62(3) . .
Pd5 Au1 Pd1 110.62(3) 3_665 3_665
Pd5 Au1 Pd1 146.659(19) 2_655 3_665
Pd5 Au1 Pd1 147.16(2) . 3_665
Pd1 Au1 Pd1 57.87(3) . 3_665
Pd5 Au1 Pd1 147.159(19) 3_665 2_655
Pd5 Au1 Pd1 110.62(3) 2_655 2_655
Pd5 Au1 Pd1 146.659(19) . 2_655
Pd1 Au1 Pd1 57.87(3) . 2_655
Pd1 Au1 Pd1 57.87(3) 3_665 2_655
Pd5 Au1 Pd4 87.79(3) 3_665 2_655
Pd5 Au1 Pd4 59.53(2) 2_655 2_655
Pd5 Au1 Pd4 119.72(3) . 2_655
Pd1 Au1 Pd4 120.87(3) . 2_655
Pd1 Au1 Pd4 89.487(19) 3_665 2_655
Pd1 Au1 Pd4 63.04(2) 2_655 2_655
Pd5 Au1 Pd4 59.53(2) 3_665 3_665
Pd5 Au1 Pd4 119.72(3) 2_655 3_665
Pd5 Au1 Pd4 87.79(3) . 3_665
Pd1 Au1 Pd4 89.485(19) . 3_665
Pd1 Au1 Pd4 63.04(2) 3_665 3_665
Pd1 Au1 Pd4 120.87(3) 2_655 3_665
Pd4 Au1 Pd4 119.959(2) 2_655 3_665
Pd5 Au1 Pd4 119.72(3) 3_665 .
Pd5 Au1 Pd4 87.79(3) 2_655 .
Pd5 Au1 Pd4 59.53(2) . .
Pd1 Au1 Pd4 63.04(2) . .
Pd1 Au1 Pd4 120.87(3) 3_665 .
Pd1 Au1 Pd4 89.484(19) 2_655 .
Pd4 Au1 Pd4 119.957(2) 2_655 .
Pd4 Au1 Pd4 119.960(2) 3_665 .
Pd5 Au1 Pd2 91.41(3) 3_665 .
Pd5 Au1 Pd2 119.79(3) 2_655 .
Pd5 Au1 Pd2 59.59(2) . .
Pd1 Au1 Pd2 91.05(2) 3_665 .
Pd1 Au1 Pd2 117.80(3) 2_655 .
Pd4 Au1 Pd2 179.15(3) 2_655 .
Pd4 Au1 Pd2 59.77(2) 3_665 .
Pd4 Au1 Pd2 60.26(2) . .
Pd5 Au1 Pd2 59.59(2) 3_665 3_665
Pd5 Au1 Pd2 91.41(3) 2_655 3_665
Pd5 Au1 Pd2 119.80(3) . 3_665
Pd1 Au1 Pd2 117.80(3) . 3_665
Pd1 Au1 Pd2 59.98(2) 3_665 3_665
Pd1 Au1 Pd2 91.05(2) 2_655 3_665
Pd4 Au1 Pd2 59.77(2) 2_655 3_665
Pd4 Au1 Pd2 60.26(2) 3_665 3_665
Pd4 Au1 Pd2 179.15(3) . 3_665
Pd2 Au1 Pd2 119.996(1) . 3_665
Pd5 Au1 Pd2 119.80(3) 3_665 2_655
Pd5 Au1 Pd2 59.59(2) 2_655 2_655
Pd5 Au1 Pd2 91.41(3) . 2_655
Pd1 Au1 Pd2 91.05(2) . 2_655
Pd1 Au1 Pd2 117.80(3) 3_665 2_655
Pd1 Au1 Pd2 59.98(2) 2_655 2_655
Pd4 Au1 Pd2 60.26(2) 2_655 2_655
Pd4 Au1 Pd2 179.15(3) 3_665 2_655
Pd4 Au1 Pd2 59.77(2) . 2_655
Pd2 Au1 Pd2 119.997(1) . 2_655
Pd2 Au1 Pd2 119.996(1) 3_665 2_655
Pd1 Pd1 Pd1 60.0 3_665 2_655
Pd1 Pd1 Pd6 178.189(18) 3_665 18_656
Pd1 Pd1 Pd6 120.03(2) 2_655 18_656
Pd1 Pd1 Pd6 120.03(2) 3_665 .
Pd1 Pd1 Pd6 178.189(18) 2_655 .
Pd6 Pd1 Pd6 60.01(4) 18_656 .
Pd1 Pd1 Au1 61.065(16) 3_665 .
Pd1 Pd1 Au1 61.064(16) 2_655 .
Pd6 Pd1 Au1 117.23(2) 18_656 .
Pd6 Pd1 Au1 120.66(2) . .
Pd1 Pd1 Au1 61.055(16) 3_665 16_546
Pd1 Pd1 Au1 61.057(16) 2_655 16_546
Pd6 Pd1 Au1 120.67(2) 18_656 16_546
Pd6 Pd1 Au1 117.24(2) . 16_546
Au1 Pd1 Au1 112.06(4) . 16_546
Pd1 Pd1 Pd2 93.48(2) 3_665 .
Pd1 Pd1 Pd2 121.85(2) 2_655 .
Pd6 Pd1 Pd2 85.01(3) 18_656 .
Pd6 Pd1 Pd2 59.90(3) . .
Au1 Pd1 Pd2 60.835(19) . .
Au1 Pd1 Pd2 150.10(3) 16_546 .
Pd1 Pd1 Pd2 121.84(2) 3_665 18_656
Pd1 Pd1 Pd2 93.48(3) 2_655 18_656
Pd6 Pd1 Pd2 59.91(3) 18_656 18_656
Pd6 Pd1 Pd2 85.02(3) . 18_656
Au1 Pd1 Pd2 150.10(3) . 18_656
Au1 Pd1 Pd2 60.839(19) 16_546 18_656
Pd2 Pd1 Pd2 140.28(5) . 18_656
Pd1 Pd1 Pd3 61.52(2) 3_665 .
Pd1 Pd1 Pd3 121.52(2) 2_655 .
Pd6 Pd1 Pd3 118.42(4) 18_656 .
Pd6 Pd1 Pd3 58.54(3) . .
Au1 Pd1 Pd3 90.852(13) . .
Au1 Pd1 Pd3 90.849(13) 16_546 .
Pd2 Pd1 Pd3 61.588(19) . .
Pd2 Pd1 Pd3 117.24(2) 18_656 .
Pd1 Pd1 Pd3 121.53(2) 3_665 2_655
Pd1 Pd1 Pd3 61.53(2) 2_655 2_655
Pd6 Pd1 Pd3 58.54(3) 18_656 2_655
Pd6 Pd1 Pd3 118.41(4) . 2_655
Au1 Pd1 Pd3 90.854(13) . 2_655
Au1 Pd1 Pd3 90.853(13) 16_546 2_655
Pd2 Pd1 Pd3 117.24(2) . 2_655
Pd2 Pd1 Pd3 61.587(19) 18_656 2_655
Pd3 Pd1 Pd3 176.95(5) . 2_655
Pd1 Pd1 Pd4 88.77(2) 3_665 18_656
Pd1 Pd1 Pd4 119.72(2) 2_655 18_656
Pd6 Pd1 Pd4 92.67(3) 18_656 18_656
Pd6 Pd1 Pd4 58.61(3) . 18_656
Au1 Pd1 Pd4 145.64(3) . 18_656
Au1 Pd1 Pd4 58.710(18) 16_546 18_656
Pd2 Pd1 Pd4 109.11(3) . 18_656
Pd2 Pd1 Pd4 59.10(2) 18_656 18_656
Pd3 Pd1 Pd4 58.372(17) . 18_656
Pd3 Pd1 Pd4 120.65(2) 2_655 18_656
Pd1 Pd1 Pd4 119.73(2) 3_665 .
Pd1 Pd1 Pd4 88.77(2) 2_655 .
Pd6 Pd1 Pd4 58.60(3) 18_656 .
Pd6 Pd1 Pd4 92.67(3) . .
Au1 Pd1 Pd4 58.708(18) . .
Au1 Pd1 Pd4 145.64(3) 16_546 .
Pd2 Pd1 Pd4 59.11(2) . .
Pd2 Pd1 Pd4 109.11(3) 18_656 .
Pd3 Pd1 Pd4 120.65(2) . .
Pd3 Pd1 Pd4 58.373(17) 2_655 .
Pd4 Pd1 Pd4 148.21(5) 18_656 .
C2 Pd2 Pd8 47.3(4) . .
C2 Pd2 Pd6 77.0(5) . .
Pd8 Pd2 Pd6 61.65(3) . .
C2 Pd2 Pd5 100.2(5) . .
Pd8 Pd2 Pd5 95.26(4) . .
Pd6 Pd2 Pd5 151.53(4) . .
C2 Pd2 Pd4 128.7(4) . 3_665
Pd8 Pd2 Pd4 175.47(4) . 3_665
Pd6 Pd2 Pd4 116.70(4) . 3_665
Pd5 Pd2 Pd4 87.52(3) . 3_665
C2 Pd2 Pd1 133.0(4) . .
Pd8 Pd2 Pd1 93.52(4) . .
Pd6 Pd2 Pd1 59.38(3) . .
Pd5 Pd2 Pd1 109.76(3) . .
Pd4 Pd2 Pd1 88.89(3) 3_665 .
C2 Pd2 Pd4 108.1(5) . .
Pd8 Pd2 Pd4 65.77(3) . .
Pd6 Pd2 Pd4 94.39(3) . .
Pd5 Pd2 Pd4 59.13(3) . .
Pd4 Pd2 Pd4 118.76(4) 3_665 .
Pd1 Pd2 Pd4 62.42(2) . .
C2 Pd2 Au1 159.1(5) . .
Pd8 Pd2 Au1 124.99(4) . .
Pd6 Pd2 Au1 118.50(3) . .
Pd5 Pd2 Au1 59.35(3) . .
Pd4 Pd2 Au1 59.53(2) 3_665 .
Pd1 Pd2 Au1 59.19(3) . .
Pd4 Pd2 Au1 59.30(2) . .
C2 Pd2 Pd3 112.1(5) . .
Pd8 Pd2 Pd3 119.18(3) . .
Pd6 Pd2 Pd3 57.69(3) . .
Pd5 Pd2 Pd3 143.37(4) . .
Pd4 Pd2 Pd3 59.01(2) 3_665 .
Pd1 Pd2 Pd3 59.53(3) . .
Pd4 Pd2 Pd3 121.90(4) . .
Au1 Pd2 Pd3 88.74(3) . .
C2 Pd2 Pd7 83.4(4) . .
Pd8 Pd2 Pd7 119.94(4) . .
Pd6 Pd2 Pd7 147.89(4) . .
Pd5 Pd2 Pd7 56.80(3) . .
Pd4 Pd2 Pd7 58.85(3) 3_665 .
Pd1 Pd2 Pd7 143.47(4) . .
Pd4 Pd2 Pd7 115.93(4) . .
Au1 Pd2 Pd7 87.75(3) . .
Pd3 Pd2 Pd7 108.88(3) . .
C3A Pd3 C3A 111(2) 16_546 .
C3A Pd3 C3 29.6(13) 16_546 16_546
C3A Pd3 C3 92.6(12) . 16_546
C3A Pd3 C3 92.6(12) 16_546 .
C3A Pd3 C3 29.6(13) . .
C3 Pd3 C3 86.4(15) 16_546 .
C3A Pd3 Pd6 48.6(11) 16_546 .
C3A Pd3 Pd6 134.3(11) . .
C3 Pd3 Pd6 48.6(7) 16_546 .
C3 Pd3 Pd6 135.0(7) . .
C3A Pd3 Pd6 134.3(11) 16_546 16_546
C3A Pd3 Pd6 48.6(11) . 16_546
C3 Pd3 Pd6 135.0(7) 16_546 16_546
C3 Pd3 Pd6 48.6(7) . 16_546
Pd6 Pd3 Pd6 176.33(6) . 16_546
C3A Pd3 Pd4 55.9(12) 16_546 18_656
C3A Pd3 Pd4 150.9(13) . 18_656
C3 Pd3 Pd4 83.3(7) 16_546 18_656
C3 Pd3 Pd4 121.3(8) . 18_656
Pd6 Pd3 Pd4 60.41(3) . 18_656
Pd6 Pd3 Pd4 118.43(3) 16_546 18_656
C3A Pd3 Pd4 150.9(13) 16_546 3_665
C3A Pd3 Pd4 55.9(12) . 3_665
C3 Pd3 Pd4 121.3(8) 16_546 3_665
C3 Pd3 Pd4 83.3(7) . 3_665
Pd6 Pd3 Pd4 118.43(3) . 3_665
Pd6 Pd3 Pd4 60.41(3) 16_546 3_665
Pd4 Pd3 Pd4 147.83(6) 18_656 3_665
C3A Pd3 Pd1 144.5(12) 16_546 3_665
C3A Pd3 Pd1 100.4(10) . 3_665
C3 Pd3 Pd1 165.3(7) 16_546 3_665
C3 Pd3 Pd1 108.3(7) . 3_665
Pd6 Pd3 Pd1 116.63(5) . 3_665
Pd6 Pd3 Pd1 59.71(3) 16_546 3_665
Pd4 Pd3 Pd1 88.56(3) 18_656 3_665
Pd4 Pd3 Pd1 62.48(3) 3_665 3_665
C3A Pd3 Pd1 100.4(10) 16_546 .
C3A Pd3 Pd1 144.5(12) . .
C3 Pd3 Pd1 108.3(7) 16_546 .
C3 Pd3 Pd1 165.2(7) . .
Pd6 Pd3 Pd1 59.71(3) . .
Pd6 Pd3 Pd1 116.63(5) 16_546 .
Pd4 Pd3 Pd1 62.47(3) 18_656 .
Pd4 Pd3 Pd1 88.57(3) 3_665 .
Pd1 Pd3 Pd1 56.95(5) 3_665 .
C3A Pd3 Pd2 102.1(12) 16_546 .
C3A Pd3 Pd2 97.6(13) . .
C3 Pd3 Pd2 82.2(8) 16_546 .
C3 Pd3 Pd2 125.2(8) . .
Pd6 Pd3 Pd2 59.33(2) . .
Pd6 Pd3 Pd2 119.38(3) 16_546 .
Pd4 Pd3 Pd2 110.24(3) 18_656 .
Pd4 Pd3 Pd2 59.10(3) 3_665 .
Pd1 Pd3 Pd2 89.15(3) 3_665 .
Pd1 Pd3 Pd2 58.89(2) . .
C3A Pd3 Pd2 97.6(13) 16_546 16_546
C3A Pd3 Pd2 102.1(12) . 16_546
C3 Pd3 Pd2 125.2(8) 16_546 16_546
C3 Pd3 Pd2 82.2(8) . 16_546
Pd6 Pd3 Pd2 119.39(3) . 16_546
Pd6 Pd3 Pd2 59.33(2) 16_546 16_546
Pd4 Pd3 Pd2 59.10(3) 18_656 16_546
Pd4 Pd3 Pd2 110.24(3) 3_665 16_546
Pd1 Pd3 Pd2 58.88(2) 3_665 16_546
Pd1 Pd3 Pd2 89.15(3) . 16_546
Pd2 Pd3 Pd2 144.80(6) . 16_546
C1A Pd4 C1 19.6(10) . .
C1A Pd4 C3A 71.6(11) . 2_655
C1 Pd4 C3A 88.1(11) . 2_655
C1A Pd4 Pd5 91.1(8) . .
C1 Pd4 Pd5 74.2(9) . .
C3A Pd4 Pd5 162.3(6) 2_655 .
C1A Pd4 Pd6 106.3(6) . 18_656
C1 Pd4 Pd6 113.7(7) . 18_656
C3A Pd4 Pd6 46.3(10) 2_655 18_656
Pd5 Pd4 Pd6 141.40(4) . 18_656
C1A Pd4 Au1 136.9(6) . .
C1 Pd4 Au1 128.8(8) . .
C3A Pd4 Au1 136.1(5) 2_655 .
Pd5 Pd4 Au1 59.96(3) . .
Pd6 Pd4 Au1 116.20(4) 18_656 .
C1A Pd4 Pd3 105.6(8) . 2_655
C1 Pd4 Pd3 125.2(10) . 2_655
C3A Pd4 Pd3 45.1(5) 2_655 2_655
Pd5 Pd4 Pd3 149.08(4) . 2_655
Pd6 Pd4 Pd3 58.62(2) 18_656 2_655
Au1 Pd4 Pd3 91.05(3) . 2_655
C1A Pd4 Pd2 92.3(7) . 2_655
C1 Pd4 Pd2 102.5(9) . 2_655
C3A Pd4 Pd2 92.1(8) 2_655 2_655
Pd5 Pd4 Pd2 92.22(3) . 2_655
Pd6 Pd4 Pd2 120.39(4) 18_656 2_655
Au1 Pd4 Pd2 60.70(2) . 2_655
Pd3 Pd4 Pd2 61.90(2) 2_655 2_655
C1A Pd4 Pd2 134.1(8) . .
C1 Pd4 Pd2 115.1(10) . .
C3A Pd4 Pd2 130.6(10) 2_655 .
Pd5 Pd4 Pd2 59.79(3) . .
Pd6 Pd4 Pd2 84.34(3) 18_656 .
Au1 Pd4 Pd2 60.45(2) . .
Pd3 Pd4 Pd2 117.39(4) 2_655 .
Pd2 Pd4 Pd2 121.10(4) 2_655 .
C1A Pd4 Pd7 46.1(6) . 2_655
C1 Pd4 Pd7 44.0(8) . 2_655
C3A Pd4 Pd7 107.6(9) 2_655 2_655
Pd5 Pd4 Pd7 59.75(3) . 2_655
Pd6 Pd4 Pd7 151.34(4) 18_656 2_655
Au1 Pd4 Pd7 90.77(3) . 2_655
Pd3 Pd4 Pd7 114.78(4) 2_655 2_655
Pd2 Pd4 Pd7 63.08(3) 2_655 2_655
Pd2 Pd4 Pd7 119.51(4) . 2_655
C1A Pd4 Pd1 161.7(7) . .
C1 Pd4 Pd1 168.6(8) . .
C3A Pd4 Pd1 90.1(8) 2_655 .
Pd5 Pd4 Pd1 107.11(3) . .
Pd6 Pd4 Pd1 58.02(3) 18_656 .
Au1 Pd4 Pd1 58.25(3) . .
Pd3 Pd4 Pd1 59.15(3) 2_655 .
Pd2 Pd4 Pd1 88.85(3) 2_655 .
Pd2 Pd4 Pd1 58.48(2) . .
Pd7 Pd4 Pd1 146.63(4) 2_655 .
C1A Pd4 Pd8 92.3(7) . .
C1 Pd4 Pd8 82.5(9) . .
C3A Pd4 Pd8 87.1(8) 2_655 .
Pd5 Pd4 Pd8 90.00(3) . .
Pd6 Pd4 Pd8 55.92(3) 18_656 .
Au1 Pd4 Pd8 116.83(4) . .
Pd3 Pd4 Pd8 114.54(3) 2_655 .
Pd2 Pd4 Pd8 174.89(4) 2_655 .
Pd2 Pd4 Pd8 56.45(3) . .
Pd7 Pd4 Pd8 121.95(4) 2_655 .
Pd1 Pd4 Pd8 86.10(3) . .
C4 Pd5 Pd7 49.5(4) . .
C4 Pd5 Pd4 145.7(5) . .
Pd7 Pd5 Pd4 125.58(4) . .
C4 Pd5 Au1 141.1(5) . .
Pd7 Pd5 Au1 93.15(3) . .
Pd4 Pd5 Au1 60.50(2) . .
C4 Pd5 Pd2 102.4(4) . .
Pd7 Pd5 Pd2 64.50(3) . .
Pd4 Pd5 Pd2 61.08(3) . .
Au1 Pd5 Pd2 61.06(2) . .
C4 Pd5 Pd7 124.5(4) . 2_655
Pd7 Pd5 Pd7 173.12(5) . 2_655
Pd4 Pd5 Pd7 61.15(3) . 2_655
Au1 Pd5 Pd7 91.90(3) . 2_655
Pd2 Pd5 Pd7 122.20(4) . 2_655
C4 Pd5 Pd5 124.8(4) . 2_655
Pd7 Pd5 Pd5 120.52(4) . 2_655
Pd4 Pd5 Pd5 88.12(4) . 2_655
Au1 Pd5 Pd5 59.877(16) . 2_655
Pd2 Pd5 Pd5 120.90(2) . 2_655
Pd7 Pd5 Pd5 58.59(4) 2_655 2_655
C4 Pd5 Pd5 88.1(5) . 3_665
Pd7 Pd5 Pd5 60.64(4) . 3_665
Pd4 Pd5 Pd5 120.32(2) . 3_665
Au1 Pd5 Pd5 59.877(16) . 3_665
Pd2 Pd5 Pd5 92.07(3) . 3_665
Pd7 Pd5 Pd5 118.47(4) 2_655 3_665
Pd5 Pd5 Pd5 60.0 2_655 3_665
C3A Pd6 C5 92.6(7) 16_546 .
C3A Pd6 C3 29.0(12) 16_546 16_546
C5 Pd6 C3 100.0(7) . 16_546
C3A Pd6 Pd3 47.3(5) 16_546 .
C5 Pd6 Pd3 139.8(5) . .
C3 Pd6 Pd3 47.4(4) 16_546 .
C3A Pd6 Pd8 102.0(10) 16_546 18_656
C5 Pd6 Pd8 47.1(5) . 18_656
C3 Pd6 Pd8 127.1(7) 16_546 18_656
Pd3 Pd6 Pd8 127.79(4) . 18_656
C3A Pd6 Pd1 101.1(8) 16_546 .
C5 Pd6 Pd1 142.1(5) . .
C3 Pd6 Pd1 109.1(4) 16_546 .
Pd3 Pd6 Pd1 61.75(3) . .
Pd8 Pd6 Pd1 95.22(4) 18_656 .
C3A Pd6 Pd6 151.5(12) 16_546 18_656
C5 Pd6 Pd6 92.2(5) . 18_656
C3 Pd6 Pd6 167.8(5) 16_546 18_656
Pd3 Pd6 Pd6 121.60(3) . 18_656
Pd8 Pd6 Pd6 62.33(4) 18_656 18_656
Pd1 Pd6 Pd6 59.99(2) . 18_656
C3A Pd6 Pd2 104.3(7) 16_546 .
C5 Pd6 Pd2 148.6(4) . .
C3 Pd6 Pd2 84.0(7) 16_546 .
Pd3 Pd6 Pd2 62.97(3) . .
Pd8 Pd6 Pd2 147.16(5) 18_656 .
Pd1 Pd6 Pd2 60.71(2) . .
Pd6 Pd6 Pd2 85.43(4) 18_656 .
C3A Pd6 Pd4 56.0(12) 16_546 18_656
C5 Pd6 Pd4 97.7(4) . 18_656
C3 Pd6 Pd4 83.0(7) 16_546 18_656
Pd3 Pd6 Pd4 60.97(3) . 18_656
Pd8 Pd6 Pd4 66.82(3) 18_656 18_656
Pd1 Pd6 Pd4 63.37(3) . 18_656
Pd6 Pd6 Pd4 95.58(4) 18_656 18_656
Pd2 Pd6 Pd4 113.71(4) . 18_656
C3A Pd6 Pd8 149.1(12) 16_546 .
C5 Pd6 Pd8 93.1(5) . .
C3 Pd6 Pd8 120.1(7) 16_546 .
Pd3 Pd6 Pd8 121.95(4) . .
Pd8 Pd6 Pd8 104.05(4) 18_656 .
Pd1 Pd6 Pd8 92.81(3) . .
Pd6 Pd6 Pd8 58.40(4) 18_656 .
Pd2 Pd6 Pd8 59.16(3) . .
Pd4 Pd6 Pd8 152.26(5) 18_656 .
C1 Pd7 C1A 19.7(10) 3_665 3_665
C1 Pd7 C4 155.6(11) 3_665 .
C1A Pd7 C4 174.7(8) 3_665 .
C1 Pd7 P1 94.1(6) 3_665 .
C1A Pd7 P1 91.6(5) 3_665 .
C4 Pd7 P1 91.5(4) . .
C1 Pd7 Pd5 129.2(7) 3_665 .
C1A Pd7 Pd5 132.9(4) 3_665 .
C4 Pd7 Pd5 44.7(4) . .
P1 Pd7 Pd5 135.25(15) . .
C1 Pd7 Pd5 74.8(9) 3_665 3_665
C1A Pd7 Pd5 89.6(6) 3_665 3_665
C4 Pd7 Pd5 85.2(4) . 3_665
P1 Pd7 Pd5 138.09(12) . 3_665
Pd5 Pd7 Pd5 60.77(4) . 3_665
C1 Pd7 Pd4 46.1(5) 3_665 3_665
C1A Pd7 Pd4 44.8(4) 3_665 3_665
C4 Pd7 Pd4 132.1(4) . 3_665
P1 Pd7 Pd4 136.30(15) . 3_665
Pd5 Pd7 Pd4 88.18(3) . 3_665
Pd5 Pd7 Pd4 59.09(3) 3_665 3_665
C1 Pd7 Pd2 99.7(6) 3_665 .
C1A Pd7 Pd2 87.3(6) 3_665 .
C4 Pd7 Pd2 93.7(4) . .
P1 Pd7 Pd2 133.02(12) . .
Pd5 Pd7 Pd2 58.70(3) . .
Pd5 Pd7 Pd2 88.89(3) 3_665 .
Pd4 Pd7 Pd2 58.07(3) 3_665 .
C5 Pd8 C2 162.0(7) 18_656 .
C5 Pd8 P2 98.3(4) 18_656 .
C2 Pd8 P2 90.7(4) . .
C5 Pd8 P2A 89.9(6) 18_656 .
C2 Pd8 P2A 93.8(6) . .
P2 Pd8 P2A 18.9(4) . .
C5 Pd8 Pd6 48.5(4) 18_656 18_656
C2 Pd8 Pd6 125.1(4) . 18_656
P2 Pd8 Pd6 144.1(2) . 18_656
P2A Pd8 Pd6 138.4(4) . 18_656
C5 Pd8 Pd2 134.4(4) 18_656 .
C2 Pd8 Pd2 43.9(4) . .
P2 Pd8 Pd2 125.69(18) . .
P2A Pd8 Pd2 135.6(4) . .
Pd6 Pd8 Pd2 85.93(4) 18_656 .
C5 Pd8 Pd6 90.8(4) 18_656 .
C2 Pd8 Pd6 73.7(4) . .
P2 Pd8 Pd6 148.1(2) . .
P2A Pd8 Pd6 132.3(5) . .
Pd6 Pd8 Pd6 59.28(4) 18_656 .
Pd2 Pd8 Pd6 59.19(3) . .
C5 Pd8 Pd4 91.0(5) 18_656 .
C2 Pd8 Pd4 97.6(4) . .
P2 Pd8 Pd4 121.7(2) . .
P2A Pd8 Pd4 139.2(4) . .
Pd6 Pd8 Pd4 57.25(3) 18_656 .
Pd2 Pd8 Pd4 57.78(3) . .
Pd6 Pd8 Pd4 88.43(3) . .
C11 P1 C13A 105(2) . .
C11 P1 C13 107(2) . .
C13A P1 C13 22.4(12) . .
C11 P1 C12A 65(2) . .
C13A P1 C12A 100.1(15) . .
C13 P1 C12A 121.7(14) . .
C11 P1 C12 105(3) . .
C13A P1 C12 65.5(19) . .
C13 P1 C12 86.8(18) . .
C12A P1 C12 47.4(18) . .
C11 P1 C11A 33(2) . .
C13A P1 C11A 106.2(16) . .
C13 P1 C11A 95.7(13) . .
C12A P1 C11A 97.7(11) . .
C12 P1 C11A 137(2) . .
C11 P1 Pd7 129(2) . .
C13A P1 Pd7 125.3(14) . .
C13 P1 Pd7 115.1(10) . .
C12A P1 Pd7 111.1(9) . .
C12 P1 Pd7 105.2(19) . .
C11A P1 Pd7 112.5(7) . .
O1 C1 Pd7 142(2) . 2_655
O1 C1 Pd4 126(2) . .
Pd7 C1 Pd4 89.9(9) 2_655 .
O1A C1A Pd4 125.1(19) . .
O1A C1A Pd7 145.5(18) . 2_655
Pd4 C1A Pd7 89.1(7) . 2_655
O2 C2 Pd2 133.4(13) . .
O2 C2 Pd8 137.7(12) . .
Pd2 C2 Pd8 88.9(5) . .
O3 C3 Pd3 143(2) . .
O3 C3 Pd6 133(2) . 16_546
Pd3 C3 Pd6 84.0(7) . 16_546
O3A C3A Pd3 130(3) . .
O3A C3A Pd6 135(3) . 16_546
Pd3 C3A Pd6 84.1(10) . 16_546
O3A C3A Pd4 130(3) . 3_665
Pd3 C3A Pd4 79.0(10) . 3_665
Pd6 C3A Pd4 77.7(12) 16_546 3_665
O4 C4 Pd5 133.9(12) . .
O4 C4 Pd7 140.1(11) . .
Pd5 C4 Pd7 85.9(5) . .
O5 C5 Pd8 146.1(12) . 18_656
O5 C5 Pd6 129.1(12) . .
Pd8 C5 Pd6 84.5(6) 18_656 .
C14 C11 P1 118(4) . .
C14 C11 H11A 107.9 . .
P1 C11 H11A 107.9 . .
C14 C11 H11B 107.9 . .
P1 C11 H11B 107.9 . .
H11A C11 H11B 107.2 . .
C15 C12 P1 113(3) . .
C15 C12 H12A 109.1 . .
P1 C12 H12A 109.1 . .
C15 C12 H12B 109.1 . .
P1 C12 H12B 109.1 . .
H12A C12 H12B 107.8 . .
C16 C13 P1 121(4) . .
C16 C13 H13A 107.1 . .
P1 C13 H13A 107.1 . .
C16 C13 H13B 107.1 . .
P1 C13 H13B 107.1 . .
H13A C13 H13B 106.8 . .
C11 C14 H14A 109.5 . .
C11 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C11 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C12 C15 H15A 109.5 . .
C12 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C12 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C13 C16 H16A 109.5 . .
C13 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C13 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C14A C11A P1 124(2) . .
C14A C11A H11C 106.3 . .
P1 C11A H11C 106.3 . .
C14A C11A H11D 106.3 . .
P1 C11A H11D 106.3 . .
H11C C11A H11D 106.4 . .
C15A C12A P1 109(2) . .
C15A C12A H12C 109.8 . .
P1 C12A H12C 109.8 . .
C15A C12A H12D 109.8 . .
P1 C12A H12D 109.8 . .
H12C C12A H12D 108.2 . .
C16A C13A P1 99(2) . .
C16A C13A H13C 112.0 . .
P1 C13A H13C 112.0 . .
C16A C13A H13D 112.0 . .
P1 C13A H13D 112.0 . .
H13C C13A H13D 109.7 . .
C11A C14A H14D 109.5 . .
C11A C14A H14E 109.5 . .
H14D C14A H14E 109.5 . .
C11A C14A H14F 109.5 . .
H14D C14A H14F 109.5 . .
H14E C14A H14F 109.5 . .
C12A C15A H15D 109.5 . .
C12A C15A H15E 109.5 . .
H15D C15A H15E 109.5 . .
C12A C15A H15F 109.5 . .
H15D C15A H15F 109.5 . .
H15E C15A H15F 109.5 . .
C13A C16A H16D 109.5 . .
C13A C16A H16E 109.5 . .
H16D C16A H16E 109.5 . .
C13A C16A H16F 109.5 . .
H16D C16A H16F 109.5 . .
H16E C16A H16F 109.5 . .
C21 P2 C22 104.7(13) . .
C21 P2 C23 108.7(14) . .
C22 P2 C23 100.7(12) . .
C21 P2 Pd8 111.4(8) . .
C22 P2 Pd8 114.1(9) . .
C23 P2 Pd8 116.2(10) . .
C24 C21 P2 119.4(18) . .
C24 C21 H21A 107.5 . .
P2 C21 H21A 107.5 . .
C24 C21 H21B 107.5 . .
P2 C21 H21B 107.5 . .
H21A C21 H21B 107.0 . .
C25 C22 P2 112.4(19) . .
C25 C22 H22A 109.1 . .
P2 C22 H22A 109.1 . .
C25 C22 H22B 109.1 . .
P2 C22 H22B 109.1 . .
H22A C22 H22B 107.9 . .
C26 C23 P2 111.7(9) . .
C26 C23 H23A 109.3 . .
P2 C23 H23A 109.3 . .
C26 C23 H23B 109.3 . .
P2 C23 H23B 109.3 . .
H23A C23 H23B 107.9 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C22 C25 H25A 109.5 . .
C22 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C22 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C23 C26 H26A 109.5 . .
C23 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C23 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C21A P2A C22A 104(2) . .
C21A P2A C23A 115(3) . .
C22A P2A C23A 87(3) . .
C21A P2A Pd8 115(2) . .
C22A P2A Pd8 115.8(18) . .
C23A P2A Pd8 115(2) . .
C24A C21A P2A 110(3) . .
C24A C21A H21C 109.8 . .
P2A C21A H21C 109.8 . .
C24A C21A H21D 109.8 . .
P2A C21A H21D 109.8 . .
H21C C21A H21D 108.2 . .
C25A C22A P2A 112.2(10) . .
C25A C22A H22C 109.2 . .
P2A C22A H22C 109.2 . .
C25A C22A H22D 109.2 . .
P2A C22A H22D 109.2 . .
H22C C22A H22D 107.9 . .
C26A C23A P2A 115(4) . .
C26A C23A H23C 108.6 . .
P2A C23A H23C 108.6 . .
C26A C23A H23D 108.6 . .
P2A C23A H23D 108.6 . .
H23C C23A H23D 107.6 . .
C21A C24A H24D 109.5 . .
C21A C24A H24E 109.5 . .
H24D C24A H24E 109.5 . .
C21A C24A H24F 109.5 . .
H24D C24A H24F 109.5 . .
C22A C25A H25D 109.5 . .
C22A C25A H25E 109.5 . .
H25D C25A H25E 109.5 . .
C22A C25A H25F 109.5 . .
H25D C25A H25F 109.5 . .
H25E C25A H25F 109.5 . .
C23A C26A H26D 109.5 . .
C23A C26A H26E 109.5 . .
H26D C26A H26E 109.5 . .
C23A C26A H26F 109.5 . .
H26D C26A H26F 109.5 . .
H26E C26A H26F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 Pd5 2.7720(10) 3_665
Au1 Pd5 2.7720(10) 2_655
Au1 Pd5 2.7720(10) .
Au1 Pd1 2.7734(8) .
Au1 Pd1 2.7734(8) 3_665
Au1 Pd1 2.7734(8) 2_655
Au1 Pd4 2.7870(8) 2_655
Au1 Pd4 2.7870(8) 3_665
Au1 Pd4 2.7870(8) .
Au1 Pd2 2.8197(8) .
Au1 Pd2 2.8197(8) 3_665
Au1 Pd2 2.8197(8) 2_655
Pd1 Pd1 2.6837(18) 3_665
Pd1 Pd1 2.6838(18) 2_655
Pd1 Pd6 2.7584(13) 18_656
Pd1 Pd6 2.7587(13) .
Pd1 Au1 2.7734(8) 16_546
Pd1 Pd2 2.7958(9) .
Pd1 Pd2 2.7958(8) 18_656
Pd1 Pd3 2.8145(11) .
Pd1 Pd3 2.8144(11) 2_655
Pd1 Pd4 2.9071(9) 18_656
Pd1 Pd4 2.9071(9) .
Pd2 C2 1.922(13) .
Pd2 Pd8 2.7726(13) .
Pd2 Pd6 2.7734(12) .
Pd2 Pd5 2.7786(12) .
Pd2 Pd4 2.7939(12) 3_665
Pd2 Pd4 2.8145(12) .
Pd2 Pd3 2.8722(9) .
Pd2 Pd7 2.9350(12) .
Pd3 C3A 2.014(18) 16_546
Pd3 C3A 2.014(18) .
Pd3 C3 2.016(16) 16_546
Pd3 C3 2.016(16) .
Pd3 Pd6 2.7252(9) .
Pd3 Pd6 2.7254(9) 16_546
Pd3 Pd4 2.7912(9) 18_656
Pd3 Pd4 2.7914(8) 3_665
Pd3 Pd1 2.8144(11) 3_665
Pd3 Pd2 2.8723(9) 16_546
Pd4 C1A 1.984(15) .
Pd4 C1 2.031(17) .
Pd4 C3A 2.35(4) 2_655
Pd4 Pd5 2.7599(11) .
Pd4 Pd6 2.7756(12) 18_656
Pd4 Pd3 2.7913(8) 2_655
Pd4 Pd2 2.7939(12) 2_655
Pd4 Pd7 2.8174(12) 2_655
Pd4 Pd8 3.0339(13) .
Pd5 C4 1.918(14) .
Pd5 Pd7 2.7211(12) .
Pd5 Pd7 2.7787(13) 2_655
Pd5 Pd5 2.7823(14) 2_655
Pd5 Pd5 2.7823(14) 3_665
Pd6 C3A 2.05(4) 16_546
Pd6 C5 2.056(14) .
Pd6 C3 2.06(3) 16_546
Pd6 Pd8 2.7334(13) 18_656
Pd6 Pd6 2.7589(19) 18_656
Pd6 Pd4 2.7760(12) 18_656
Pd6 Pd8 2.8420(13) .
Pd7 C1 1.96(3) 3_665
Pd7 C1A 2.03(2) 3_665
Pd7 C4 2.074(14) .
Pd7 P1 2.321(4) .
Pd7 Pd5 2.7788(13) 3_665
Pd7 Pd4 2.8172(12) 3_665
Pd8 C5 2.011(16) 18_656
Pd8 C2 2.037(15) .
Pd8 P2 2.305(6) .
Pd8 P2A 2.361(11) .
Pd8 Pd6 2.7334(13) 18_656
P1 C11 1.825(10) .
P1 C13A 1.826(10) .
P1 C13 1.835(10) .
P1 C12A 1.836(10) .
P1 C12 1.840(10) .
P1 C11A 1.866(9) .
O1 C1 1.164(10) .
C1 Pd7 1.96(3) 2_655
O1A C1A 1.160(10) .
C1A Pd7 2.03(2) 2_655
O2 C2 1.176(17) .
O3 C3 1.161(10) .
C3 Pd6 2.06(3) 16_546
O3A C3A 1.164(10) .
C3A Pd6 2.05(4) 16_546
C3A Pd4 2.35(4) 3_665
O4 C4 1.159(16) .
O5 C5 1.141(18) .
C5 Pd8 2.011(16) 18_656
C11 C14 1.527(10) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C15 1.532(10) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C16 1.530(10) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C11A C14A 1.525(10) .
C11A H11C 0.9900 .
C11A H11D 0.9900 .
C12A C15A 1.532(10) .
C12A H12C 0.9900 .
C12A H12D 0.9900 .
C13A C16A 1.525(10) .
C13A H13C 0.9900 .
C13A H13D 0.9900 .
C14A H14D 0.9800 .
C14A H14E 0.9800 .
C14A H14F 0.9800 .
C15A H15D 0.9800 .
C15A H15E 0.9800 .
C15A H15F 0.9800 .
C16A H16D 0.9800 .
C16A H16E 0.9800 .
C16A H16F 0.9800 .
P2 C21 1.835(10) .
P2 C22 1.837(10) .
P2 C23 1.838(10) .
C21 C24 1.527(10) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C25 1.530(10) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C26 1.532(10) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
P2A C21A 1.833(10) .
P2A C22A 1.835(10) .
P2A C23A 1.838(10) .
C21A C24A 1.531(10) .
C21A H21C 0.9900 .
C21A H21D 0.9900 .
C22A C25A 1.530(10) .
C22A H22C 0.9900 .
C22A H22D 0.9900 .
C23A C26A 1.531(10) .
C23A H23C 0.9900 .
C23A H23D 0.9900 .
C24A H24D 0.9800 .
C24A H24E 0.9800 .
C24A H24F 0.9800 .
C25A H25D 0.9800 .
C25A H25E 0.9800 .
C25A H25F 0.9800 .
C26A H26D 0.9800 .
C26A H26E 0.9800 .
C26A H26F 0.9800 .
