#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:12:42 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179527 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/24/4342446.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342446
loop_
_publ_author_name
'Jin-Long, ?'
'Matsuda, Yuki'
'Uemura, Kazuhiro'
'Ebihara, Masahiro'
_publ_section_title
;
 Mixed Valency in Quadruple Hydrogen-Bonded Dimers of
 Bis(biimidazolate)dirhodium Complexes.
;
_journal_issue                   5
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2331
_journal_paper_doi               10.1021/ic502953b
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C58 H58 N8 O4 P2 Rh2'
_chemical_formula_weight         1198.88
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.3171(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   14.7481(2)
_cell_length_b                   42.9551(8)
_cell_length_c                   18.1613(3)
_cell_measurement_temperature    101(2)
_cell_volume                     10718.1(3)
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita,Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      101(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'synchrotron radiation PAL'
_diffrn_radiation_wavelength     1.00002
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_sigmaI/netI    0.0309
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            30660
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.16
_exptl_absorpt_coefficient_mu    1.718
_exptl_absorpt_correction_T_max  0.9665
_exptl_absorpt_correction_T_min  0.8893
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[R. H. Blessing, Acta Cryst. (1995), A51, 33-38]
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.486
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             4912
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.642
_refine_diff_density_min         -0.815
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     736
_refine_ls_number_reflns         4423
_refine_ls_number_restraints     325
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0710
_refine_ls_R_factor_gt           0.0553
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1142P)²+17.4874P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1424
_refine_ls_wR_factor_ref         0.1562
_reflns_number_gt                3448
_reflns_number_total             4423
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic502953b_si_004.cif
_cod_data_source_block           '[1prime(PPh3)2]2'
_cod_depositor_comments
'Adding full bibliography for 4342442--4342446.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4342446
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.01938(5) 0.412147(17) 0.68474(4) 0.0732(4) Uani 1 1 d . . .
N1 N -0.0590(6) 0.37366(18) 0.6432(4) 0.0668(19) Uani 1 1 d . . .
C1 C -0.0104(8) 0.3469(3) 0.6544(5) 0.068(2) Uani 1 1 d . . .
N2 N -0.0663(6) 0.32331(18) 0.6194(4) 0.072(2) Uani 1 1 d . . .
H2N H -0.0486 0.3038 0.6193 0.087 Uiso 1 1 calc R . .
C2 C -0.1578(7) 0.3354(3) 0.5832(5) 0.077(3) Uani 1 1 d . . .
H2 H -0.2145 0.3240 0.5533 0.092 Uiso 1 1 calc R . .
C3 C -0.1530(8) 0.3662(3) 0.5975(5) 0.077(3) Uani 1 1 d . . .
H3 H -0.2059 0.3804 0.5790 0.093 Uiso 1 1 calc R . .
N3 N 0.1249(6) 0.37913(19) 0.7181(4) 0.0683(19) Uani 1 1 d . . .
C4 C 0.0954(8) 0.3494(3) 0.6996(5) 0.072(2) Uani 1 1 d . . .
N4 N 0.1652(7) 0.32836(18) 0.7186(4) 0.072(2) Uani 1 1 d . . .
C5 C 0.2475(7) 0.3460(3) 0.7523(5) 0.078(3) Uani 1 1 d . . .
H5 H 0.3119 0.3379 0.7732 0.094 Uiso 1 1 calc R . .
C6 C 0.2239(8) 0.3767(3) 0.7516(5) 0.074(3) Uani 1 1 d . . .
H6 H 0.2684 0.3934 0.7710 0.089 Uiso 1 1 calc R . .
O1 O 0.1073(5) 0.44992(13) 0.7364(4) 0.0782(17) Uani 1 1 d . . .
O2 O -0.0959(4) 0.44291(14) 0.6446(3) 0.0803(17) Uani 1 1 d . . .
C7 C 0.1287(7) 0.4568(2) 0.8087(7) 0.085(3) Uani 1 1 d DU . .
C8 C 0.1972(10) 0.4839(3) 0.8386(7) 0.130(4) Uani 1 1 d DU . .
H8A H 0.1886 0.4931 0.8857 0.06(4) Uiso 0.546(13) 1 calc PR A 1
H8B H 0.1824 0.5002 0.7973 0.4(2) Uiso 0.546(13) 1 calc PR A 1
H8C H 0.2432 0.4836 0.8102 0.05(5) Uiso 0.454(13) 1 calc PR A 2
H8D H 0.1582 0.5032 0.8226 0.14(11) Uiso 0.454(13) 1 calc PR A 2
C9A C 0.3025(16) 0.4728(6) 0.860(2) 0.195(10) Uani 0.546(13) 1 d PDU A 1
H9A H 0.3214 0.4599 0.9087 0.234 Uiso 0.546(13) 1 calc PR A 1
H9B H 0.3078 0.4599 0.8170 0.234 Uiso 0.546(13) 1 calc PR A 1
C10A C 0.3708(17) 0.5008(8) 0.874(2) 0.264(14) Uani 0.546(13) 1 d PDU A 1
H10A H 0.4367 0.4938 0.8792 0.317 Uiso 0.546(13) 1 calc PR A 1
H10B H 0.3465 0.5155 0.8296 0.317 Uiso 0.546(13) 1 calc PR A 1
C11A C 0.375(3) 0.5166(8) 0.951(2) 0.35(3) Uani 0.546(13) 1 d PDU A 1
H11A H 0.4186 0.5346 0.9612 0.519 Uiso 0.546(13) 1 calc PR A 1
H11B H 0.3988 0.5019 0.9947 0.519 Uiso 0.546(13) 1 calc PR A 1
H11C H 0.3094 0.5236 0.9452 0.519 Uiso 0.546(13) 1 calc PR A 1
C9B C 0.2567(17) 0.4866(6) 0.9255(11) 0.156(9) Uani 0.454(13) 1 d PDU A 2
H9C H 0.2280 0.4735 0.9562 0.188 Uiso 0.454(13) 1 calc PR A 2
H9D H 0.2570 0.5085 0.9428 0.188 Uiso 0.454(13) 1 calc PR A 2
C10B C 0.3613(17) 0.4759(8) 0.940(2) 0.220(13) Uani 0.454(13) 1 d PDU A 2
H10C H 0.3921 0.4900 0.9127 0.264 Uiso 0.454(13) 1 calc PR A 2
H10D H 0.4007 0.4760 0.9970 0.264 Uiso 0.454(13) 1 calc PR A 2
C11B C 0.355(2) 0.4430(8) 0.907(2) 0.222(16) Uani 0.454(13) 1 d PDU A 2
H11D H 0.4013 0.4296 0.9467 0.333 Uiso 0.454(13) 1 calc PR A 2
H11E H 0.3720 0.4434 0.8594 0.333 Uiso 0.454(13) 1 calc PR A 2
H11F H 0.2891 0.4350 0.8935 0.333 Uiso 0.454(13) 1 calc PR A 2
P1 P 0.0568(2) 0.41681(6) 0.56107(15) 0.0841(8) Uani 1 1 d . . .
C12 C 0.1847(8) 0.4238(3) 0.5746(7) 0.099(3) Uani 1 1 d . . .
C13 C 0.2210(13) 0.4159(3) 0.5177(9) 0.161(6) Uani 1 1 d . . .
H13 H 0.1805 0.4056 0.4710 0.193 Uiso 1 1 calc R . .
C14 C 0.3172(16) 0.4228(4) 0.5280(12) 0.213(10) Uani 1 1 d . . .
H14 H 0.3424 0.4169 0.4888 0.256 Uiso 1 1 calc R . .
C15 C 0.3749(14) 0.4379(5) 0.5937(13) 0.204(9) Uani 1 1 d . . .
H15 H 0.4407 0.4423 0.6007 0.245 Uiso 1 1 calc R . .
C16 C 0.3398(10) 0.4469(3) 0.6496(10) 0.152(6) Uani 1 1 d . . .
H16 H 0.3803 0.4581 0.6948 0.182 Uiso 1 1 calc R . .
C17 C 0.2446(10) 0.4399(3) 0.6412(7) 0.106(3) Uani 1 1 d . . .
H17 H 0.2204 0.4460 0.6808 0.128 Uiso 1 1 calc R . .
C18 C -0.0076(11) 0.4455(3) 0.4885(6) 0.097(4) Uani 1 1 d . . .
C19 C -0.1053(13) 0.4483(2) 0.4739(6) 0.107(4) Uani 1 1 d . . .
H19 H -0.1327 0.4359 0.5037 0.129 Uiso 1 1 calc R . .
C20 C -0.1671(11) 0.4688(3) 0.4169(7) 0.126(5) Uani 1 1 d . . .
H20 H -0.2348 0.4701 0.4072 0.152 Uiso 1 1 calc R . .
C21 C -0.1224(18) 0.4870(4) 0.3753(11) 0.162(9) Uani 1 1 d . . .
H21 H -0.1616 0.5003 0.3342 0.194 Uiso 1 1 calc R . .
C22 C -0.0311(19) 0.4861(5) 0.3910(11) 0.178(11) Uani 1 1 d . . .
H22 H -0.0040 0.5002 0.3642 0.214 Uiso 1 1 calc R . .
C23 C 0.0328(12) 0.4652(3) 0.4470(8) 0.138(5) Uani 1 1 d . . .
H23 H 0.1003 0.4646 0.4558 0.165 Uiso 1 1 calc R . .
C24 C 0.0293(8) 0.3808(2) 0.5034(6) 0.079(3) Uani 1 1 d . . .
C25 C -0.0569(8) 0.3767(2) 0.4377(6) 0.081(3) Uani 1 1 d . . .
H25 H -0.1002 0.3937 0.4186 0.098 Uiso 1 1 calc R . .
C26 C -0.0794(9) 0.3486(3) 0.4012(6) 0.097(3) Uani 1 1 d . . .
H26 H -0.1380 0.3463 0.3567 0.116 Uiso 1 1 calc R . .
C27 C -0.0184(10) 0.3231(3) 0.4276(7) 0.093(3) Uani 1 1 d . . .
H27 H -0.0347 0.3035 0.4019 0.111 Uiso 1 1 calc R . .
C28 C 0.0673(9) 0.3269(3) 0.4925(7) 0.086(3) Uani 1 1 d . . .
H28 H 0.1101 0.3098 0.5115 0.103 Uiso 1 1 calc R . .
C29 C 0.0909(8) 0.3554(3) 0.5296(6) 0.088(3) Uani 1 1 d . . .
H29 H 0.1499 0.3576 0.5738 0.106 Uiso 1 1 calc R . .
Rh2 Rh 0.05783(5) 0.178356(17) 0.70979(4) 0.0705(4) Uani 1 1 d . . .
N5 N 0.1292(6) 0.21686(19) 0.7611(5) 0.070(2) Uani 1 1 d . . .
C30 C 0.0999(7) 0.2439(3) 0.7216(6) 0.072(2) Uani 1 1 d . . .
N6 N 0.1558(6) 0.2673(2) 0.7570(5) 0.081(2) Uani 1 1 d . . .
H6N H 0.1502 0.2868 0.7407 0.097 Uiso 1 1 calc R . .
C31 C 0.2251(7) 0.2556(3) 0.8247(6) 0.094(3) Uani 1 1 d . . .
H31 H 0.2752 0.2671 0.8633 0.113 Uiso 1 1 calc R . .
C32 C 0.2082(7) 0.2245(3) 0.8258(6) 0.086(3) Uani 1 1 d . . .
H32 H 0.2456 0.2103 0.8654 0.104 Uiso 1 1 calc R . .
N7 N -0.0141(5) 0.21125(19) 0.6297(4) 0.067(2) Uani 1 1 d . . .
C33 C 0.0172(7) 0.2412(3) 0.6473(6) 0.074(3) Uani 1 1 d . . .
N8 N -0.0303(6) 0.26208(18) 0.5944(5) 0.077(2) Uani 1 1 d . . .
C34 C -0.0975(7) 0.2440(3) 0.5363(5) 0.088(3) Uani 1 1 d . . .
H34 H -0.1440 0.2519 0.4887 0.105 Uiso 1 1 calc R . .
C35 C -0.0873(7) 0.2135(2) 0.5575(5) 0.078(3) Uani 1 1 d . . .
H35 H -0.1244 0.1967 0.5274 0.094 Uiso 1 1 calc R . .
O3 O -0.0249(5) 0.14033(13) 0.6540(3) 0.0729(16) Uani 1 1 d . B .
C36 C -0.1073(8) 0.1347(2) 0.6580(5) 0.080(3) Uani 1 1 d DU . .
C37B C -0.1693(10) 0.1090(3) 0.6105(11) 0.093(4) Uani 0.730(16) 1 d PDU B -1
H37C H -0.2122 0.1176 0.5591 0.111 Uiso 0.730(16) 1 calc PR B -1
H37D H -0.2114 0.1013 0.6383 0.111 Uiso 0.730(16) 1 calc PR B -1
C38B C -0.1141(15) 0.0822(4) 0.5955(13) 0.165(8) Uani 0.730(16) 1 d PDU B -1
H38C H -0.0688 0.0899 0.5706 0.198 Uiso 0.730(16) 1 calc PR B -1
H38D H -0.1604 0.0677 0.5579 0.198 Uiso 0.730(16) 1 calc PR B -1
C39B C -0.0570(18) 0.0647(5) 0.6703(15) 0.229(12) Uani 0.730(16) 1 d PDU B -1
H39C H -0.0052 0.0785 0.7047 0.275 Uiso 0.730(16) 1 calc PR B -1
H39D H -0.1010 0.0597 0.6987 0.275 Uiso 0.730(16) 1 calc PR B -1
C40B C -0.012(2) 0.0355(5) 0.657(2) 0.35(2) Uani 0.730(16) 1 d PDU B -1
H40D H 0.0246 0.0257 0.7076 0.519 Uiso 0.730(16) 1 calc PR B -1
H40E H 0.0327 0.0403 0.6291 0.519 Uiso 0.730(16) 1 calc PR B -1
H40F H -0.0626 0.0213 0.6244 0.519 Uiso 0.730(16) 1 calc PR B -1
C37A C -0.168(2) 0.1108(10) 0.601(3) 0.110(11) Uani 0.270(16) 1 d PDU B -2
H37A H -0.2303 0.1203 0.5683 0.131 Uiso 0.270(16) 1 calc PR B -2
H37B H -0.1817 0.0935 0.6316 0.131 Uiso 0.270(16) 1 calc PR B -2
C38A C -0.119(3) 0.0978(10) 0.5483(18) 0.138(11) Uani 0.270(16) 1 d PDU B -2
H38A H -0.0777 0.1141 0.5376 0.166 Uiso 0.270(16) 1 calc PR B -2
H38B H -0.1689 0.0916 0.4972 0.166 Uiso 0.270(16) 1 calc PR B -2
C39A C -0.056(4) 0.0699(12) 0.586(4) 0.191(14) Uani 0.270(16) 1 d PDU B -2
H39A H -0.0208 0.0740 0.6426 0.230 Uiso 0.270(16) 1 calc PR B -2
H39B H -0.0985 0.0515 0.5812 0.230 Uiso 0.270(16) 1 calc PR B -2
C40A C 0.015(5) 0.0630(19) 0.547(5) 0.31(3) Uani 0.270(16) 1 d PDU B -2
H40A H 0.0562 0.0453 0.5735 0.470 Uiso 0.270(16) 1 calc PR B -2
H40B H 0.0564 0.0813 0.5505 0.470 Uiso 0.270(16) 1 calc PR B -2
H40C H -0.0198 0.0578 0.4911 0.470 Uiso 0.270(16) 1 calc PR B -2
P2 P 0.1651(2) 0.16947(8) 0.63490(15) 0.0939(9) Uani 1 1 d . . .
C41 C 0.2455(8) 0.1355(3) 0.6662(5) 0.096(3) Uani 1 1 d . . .
C42 C 0.2128(10) 0.1097(4) 0.6920(7) 0.113(4) Uani 1 1 d . . .
H42 H 0.1502 0.1101 0.6956 0.135 Uiso 1 1 calc R . .
C43 C 0.2688(13) 0.0828(3) 0.7133(8) 0.133(5) Uani 1 1 d . . .
H43 H 0.2455 0.0648 0.7312 0.160 Uiso 1 1 calc R . .
C44 C 0.3608(15) 0.0833(5) 0.7073(9) 0.164(7) Uani 1 1 d . . .
H44 H 0.4010 0.0653 0.7224 0.196 Uiso 1 1 calc R . .
C45 C 0.3939(12) 0.1085(6) 0.6809(8) 0.186(9) Uani 1 1 d . . .
H45 H 0.4565 0.1081 0.6771 0.224 Uiso 1 1 calc R . .
C46 C 0.3377(10) 0.1346(4) 0.6594(6) 0.143(5) Uani 1 1 d . . .
H46 H 0.3607 0.1523 0.6397 0.172 Uiso 1 1 calc R . .
C47 C 0.1132(9) 0.1624(4) 0.5296(6) 0.126(5) Uani 1 1 d . . .
C48 C 0.0150(11) 0.1493(3) 0.4965(7) 0.125(4) Uani 1 1 d . . .
H48 H -0.0203 0.1461 0.5303 0.150 Uiso 1 1 calc R . .
C49 C -0.0291(10) 0.1412(4) 0.4156(7) 0.168(7) Uani 1 1 d . . .
H49 H -0.0919 0.1320 0.3948 0.202 Uiso 1 1 calc R . .
C50 C 0.0259(13) 0.1476(6) 0.3673(7) 0.240(12) Uani 1 1 d . . .
H50 H -0.0030 0.1456 0.3115 0.288 Uiso 1 1 calc R . .
C51 C 0.1170(12) 0.1563(4) 0.4008(8) 0.157(6) Uani 1 1 d . . .
H51 H 0.1549 0.1582 0.3685 0.189 Uiso 1 1 calc R . .
C52 C 0.1609(9) 0.1628(3) 0.4804(7) 0.129(5) Uani 1 1 d . . .
H52 H 0.2282 0.1678 0.5007 0.155 Uiso 1 1 calc R . .
C53 C 0.2432(11) 0.2031(3) 0.6462(9) 0.127(5) Uani 1 1 d . . .
C54 C 0.3293(13) 0.2051(5) 0.7122(11) 0.196(8) Uani 1 1 d . . .
H54 H 0.3498 0.1882 0.7481 0.236 Uiso 1 1 calc R . .
C55 C 0.3855(15) 0.2325(7) 0.7250(13) 0.266(13) Uani 1 1 d . . .
H55 H 0.4447 0.2352 0.7688 0.320 Uiso 1 1 calc R . .
C56 C 0.346(2) 0.2557(5) 0.6669(16) 0.198(8) Uani 1 1 d . . .
H56 H 0.3821 0.2745 0.6750 0.237 Uiso 1 1 calc R . .
C57 C 0.2666(14) 0.2549(5) 0.6033(12) 0.163(7) Uani 1 1 d . . .
H57 H 0.2465 0.2718 0.5671 0.195 Uiso 1 1 calc R . .
C58 C 0.2132(14) 0.2267(5) 0.5932(12) 0.181(8) Uani 1 1 d . . .
H58 H 0.1550 0.2243 0.5484 0.217 Uiso 1 1 calc R . .
O4 O 0.1430(4) 0.14974(14) 0.7988(3) 0.0747(16) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0074 0.0035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0136 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0227 0.0128 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1747 0.1875 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -0.4229 1.6972 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Rh1 N3 79.1(4) . .
N1 Rh1 O2 96.1(3) . .
N3 Rh1 O2 175.1(3) . .
N1 Rh1 O1 175.1(3) . .
N3 Rh1 O1 97.3(3) . .
O2 Rh1 O1 87.6(2) . .
N1 Rh1 P1 90.76(19) . .
N3 Rh1 P1 85.91(19) . .
O2 Rh1 P1 93.08(19) . .
O1 Rh1 P1 92.17(18) . .
N1 Rh1 Rh1 93.15(18) . 2_556
N3 Rh1 Rh1 97.19(18) . 2_556
O2 Rh1 Rh1 84.12(18) . 2_556
O1 Rh1 Rh1 84.10(17) . 2_556
P1 Rh1 Rh1 175.41(6) . 2_556
C1 N1 C3 105.1(8) . .
C1 N1 Rh1 116.8(7) . .
C3 N1 Rh1 137.7(8) . .
N2 C1 N1 112.6(9) . .
N2 C1 C4 132.3(11) . .
N1 C1 C4 115.1(10) . .
C1 N2 C2 106.0(8) . .
C1 N2 H2N 127.0 . .
C2 N2 H2N 127.0 . .
C3 C2 N2 107.9(9) . .
C3 C2 H2 126.1 . .
N2 C2 H2 126.1 . .
C2 C3 N1 108.5(9) . .
C2 C3 H3 125.8 . .
N1 C3 H3 125.8 . .
C4 N3 C6 103.4(8) . .
C4 N3 Rh1 116.4(7) . .
C6 N3 Rh1 140.0(8) . .
N4 C4 N3 115.6(9) . .
N4 C4 C1 131.5(11) . .
N3 C4 C1 112.6(10) . .
C4 N4 C5 102.7(8) . .
C6 C5 N4 110.3(9) . .
C6 C5 H5 124.8 . .
N4 C5 H5 124.8 . .
C5 C6 N3 107.9(8) . .
C5 C6 H6 126.1 . .
N3 C6 H6 126.1 . .
C7 O1 Rh1 121.9(6) . .
C7 O2 Rh1 122.0(6) 2_556 .
O2 C7 O1 124.9(9) 2_556 .
O2 C7 C8 119.3(10) 2_556 .
O1 C7 C8 115.7(10) . .
C9B C8 C7 119.7(16) . .
C9B C8 C9A 66.7(14) . .
C7 C8 C9A 109.6(13) . .
C9B C8 H8A 43.4 . .
C7 C8 H8A 109.7 . .
C9A C8 H8A 109.7 . .
C9B C8 H8B 128.6 . .
C7 C8 H8B 109.7 . .
C9A C8 H8B 109.7 . .
H8A C8 H8B 108.2 . .
C9B C8 H8C 107.4 . .
C7 C8 H8C 107.4 . .
C9A C8 H8C 46.3 . .
H8A C8 H8C 141.5 . .
H8B C8 H8C 67.5 . .
C9B C8 H8D 107.4 . .
C7 C8 H8D 107.4 . .
C9A C8 H8D 139.6 . .
H8A C8 H8D 71.2 . .
H8B C8 H8D 40.7 . .
H8C C8 H8D 106.9 . .
C10A C9A C8 110.2(17) . .
C10A C9A H9A 109.6 . .
C8 C9A H9A 109.6 . .
C10A C9A H9B 109.6 . .
C8 C9A H9B 109.6 . .
H9A C9A H9B 108.1 . .
C11A C10A C9A 107.9(17) . .
C11A C10A H10A 110.1 . .
C9A C10A H10A 110.1 . .
C11A C10A H10B 110.1 . .
C9A C10A H10B 110.1 . .
H10A C10A H10B 108.4 . .
C10A C11A H11A 109.5 . .
C10A C11A H11B 109.5 . .
H11A C11A H11B 109.5 . .
C10A C11A H11C 109.5 . .
H11A C11A H11C 109.5 . .
H11B C11A H11C 109.5 . .
C8 C9B C10B 108.7(16) . .
C8 C9B H9C 110.0 . .
C10B C9B H9C 110.0 . .
C8 C9B H9D 110.0 . .
C10B C9B H9D 110.0 . .
H9C C9B H9D 108.3 . .
C11B C10B C9B 107.5(17) . .
C11B C10B H10C 110.2 . .
C9B C10B H10C 110.2 . .
C11B C10B H10D 110.2 . .
C9B C10B H10D 110.2 . .
H10C C10B H10D 108.5 . .
C10B C11B H11D 109.5 . .
C10B C11B H11E 109.5 . .
H11D C11B H11E 109.5 . .
C10B C11B H11F 109.5 . .
H11D C11B H11F 109.5 . .
H11E C11B H11F 109.5 . .
C18 P1 C24 102.1(5) . .
C18 P1 C12 103.3(6) . .
C24 P1 C12 102.6(5) . .
C18 P1 Rh1 118.7(4) . .
C24 P1 Rh1 111.7(3) . .
C12 P1 Rh1 116.3(4) . .
C13 C12 C17 118.6(11) . .
C13 C12 P1 121.6(11) . .
C17 C12 P1 119.6(9) . .
C12 C13 C14 120.3(14) . .
C12 C13 H13 119.9 . .
C14 C13 H13 119.9 . .
C15 C14 C13 120.3(14) . .
C15 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
C16 C15 C14 120.6(15) . .
C16 C15 H15 119.7 . .
C14 C15 H15 119.7 . .
C15 C16 C17 120.1(14) . .
C15 C16 H16 119.9 . .
C17 C16 H16 119.9 . .
C16 C17 C12 120.0(11) . .
C16 C17 H17 120.0 . .
C12 C17 H17 120.0 . .
C19 C18 C23 117.6(12) . .
C19 C18 P1 116.1(10) . .
C23 C18 P1 126.3(13) . .
C18 C19 C20 123.4(12) . .
C18 C19 H19 118.3 . .
C20 C19 H19 118.3 . .
C21 C20 C19 115.9(15) . .
C21 C20 H20 122.1 . .
C19 C20 H20 122.1 . .
C22 C21 C20 122(2) . .
C22 C21 H21 119.1 . .
C20 C21 H21 119.1 . .
C21 C22 C23 123(2) . .
C21 C22 H22 118.3 . .
C23 C22 H22 118.3 . .
C18 C23 C22 117.7(16) . .
C18 C23 H23 121.2 . .
C22 C23 H23 121.2 . .
C29 C24 C25 117.9(9) . .
C29 C24 P1 119.2(9) . .
C25 C24 P1 122.6(9) . .
C26 C25 C24 120.8(10) . .
C26 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C25 C26 C27 121.3(10) . .
C25 C26 H26 119.3 . .
C27 C26 H26 119.3 . .
C26 C27 C28 118.3(10) . .
C26 C27 H27 120.8 . .
C28 C27 H27 120.8 . .
C29 C28 C27 120.7(10) . .
C29 C28 H28 119.6 . .
C27 C28 H28 119.6 . .
C28 C29 C24 120.9(10) . .
C28 C29 H29 119.6 . .
C24 C29 H29 119.6 . .
N5 Rh2 N7 78.9(4) . .
N5 Rh2 O4 93.5(3) . .
N7 Rh2 O4 172.3(3) . .
N5 Rh2 O3 176.0(3) . .
N7 Rh2 O3 97.9(3) . .
O4 Rh2 O3 89.8(2) . .
N5 Rh2 P2 92.9(2) . .
N7 Rh2 P2 89.16(19) . .
O4 Rh2 P2 90.57(18) . .
O3 Rh2 P2 89.46(19) . .
N5 Rh2 Rh2 94.58(19) . 2_556
N7 Rh2 Rh2 97.08(18) . 2_556
O4 Rh2 Rh2 84.09(17) . 2_556
O3 Rh2 Rh2 83.40(17) . 2_556
P2 Rh2 Rh2 171.09(8) . 2_556
C30 N5 C32 105.1(8) . .
C30 N5 Rh2 116.8(7) . .
C32 N5 Rh2 137.9(8) . .
N6 C30 N5 112.1(8) . .
N6 C30 C33 133.0(10) . .
N5 C30 C33 114.8(10) . .
C30 N6 C31 106.8(8) . .
C30 N6 H6N 126.6 . .
C31 N6 H6N 126.6 . .
C32 C31 N6 107.0(9) . .
C32 C31 H31 126.5 . .
N6 C31 H31 126.5 . .
N5 C32 C31 109.1(9) . .
N5 C32 H32 125.5 . .
C31 C32 H32 125.5 . .
C33 N7 C35 103.9(8) . .
C33 N7 Rh2 116.4(7) . .
C35 N7 Rh2 139.6(8) . .
N8 C33 N7 115.3(8) . .
N8 C33 C30 131.7(10) . .
N7 C33 C30 113.0(10) . .
C33 N8 C34 102.6(8) . .
C35 C34 N8 110.4(8) . .
C35 C34 H34 124.8 . .
N8 C34 H34 124.8 . .
C34 C35 N7 107.8(9) . .
C34 C35 H35 126.1 . .
N7 C35 H35 126.1 . .
C36 O3 Rh2 122.0(6) . .
O3 C36 O4 124.0(8) . 2_556
O3 C36 C37B 120.5(10) . .
O4 C36 C37B 115.5(11) 2_556 .
O3 C36 C37A 115.7(16) . .
O4 C36 C37A 120.0(16) 2_556 .
C37B C36 C37A 7(3) . .
C36 C37B C38B 114.7(11) . .
C36 C37B H37C 108.6 . .
C38B C37B H37C 108.6 . .
C36 C37B H37D 108.6 . .
C38B C37B H37D 108.6 . .
H37C C37B H37D 107.6 . .
C37B C38B C39B 112.4(14) . .
C37B C38B H38C 109.1 . .
C39B C38B H38C 109.1 . .
C37B C38B H38D 109.1 . .
C39B C38B H38D 109.1 . .
H38C C38B H38D 107.8 . .
C40B C39B C38B 114.1(18) . .
C40B C39B H39C 108.7 . .
C38B C39B H39C 108.7 . .
C40B C39B H39D 108.7 . .
C38B C39B H39D 108.7 . .
H39C C39B H39D 107.6 . .
C39B C40B H40D 109.5 . .
C39B C40B H40E 109.5 . .
H40D C40B H40E 109.5 . .
C39B C40B H40F 109.5 . .
H40D C40B H40F 109.5 . .
H40E C40B H40F 109.5 . .
C36 C37A C38A 113.2(19) . .
C36 C37A H37A 108.9 . .
C38A C37A H37A 108.9 . .
C36 C37A H37B 108.9 . .
C38A C37A H37B 108.9 . .
H37A C37A H37B 107.8 . .
C37A C38A C39A 111(2) . .
C37A C38A H38A 109.4 . .
C39A C38A H38A 109.4 . .
C37A C38A H38B 109.4 . .
C39A C38A H38B 109.4 . .
H38A C38A H38B 108.0 . .
C40A C39A C38A 111(2) . .
C40A C39A H39A 109.4 . .
C38A C39A H39A 109.4 . .
C40A C39A H39B 109.4 . .
C38A C39A H39B 109.4 . .
H39A C39A H39B 108.0 . .
C39A C40A H40A 109.5 . .
C39A C40A H40B 109.5 . .
H40A C40A H40B 109.5 . .
C39A C40A H40C 109.5 . .
H40A C40A H40C 109.5 . .
H40B C40A H40C 109.5 . .
C47 P2 C53 105.1(7) . .
C47 P2 C41 99.9(5) . .
C53 P2 C41 106.6(7) . .
C47 P2 Rh2 120.0(4) . .
C53 P2 Rh2 108.9(4) . .
C41 P2 Rh2 115.1(4) . .
C42 C41 C46 118.9(12) . .
C42 C41 P2 119.0(10) . .
C46 C41 P2 122.0(12) . .
C41 C42 C43 121.7(13) . .
C41 C42 H42 119.2 . .
C43 C42 H42 119.2 . .
C42 C43 C44 117.4(15) . .
C42 C43 H43 121.3 . .
C44 C43 H43 121.3 . .
C45 C44 C43 121.8(16) . .
C45 C44 H44 119.1 . .
C43 C44 H44 119.1 . .
C44 C45 C46 120.1(16) . .
C44 C45 H45 119.9 . .
C46 C45 H45 119.9 . .
C45 C46 C41 120.1(14) . .
C45 C46 H46 119.9 . .
C41 C46 H46 119.9 . .
C52 C47 C48 114.5(11) . .
C52 C47 P2 126.0(11) . .
C48 C47 P2 118.4(9) . .
C49 C48 C47 122.3(12) . .
C49 C48 H48 118.9 . .
C47 C48 H48 118.9 . .
C48 C49 C50 116.2(14) . .
C48 C49 H49 121.9 . .
C50 C49 H49 121.9 . .
C51 C50 C49 119.2(12) . .
C51 C50 H50 120.4 . .
C49 C50 H50 120.4 . .
C50 C51 C52 123.6(13) . .
C50 C51 H51 118.2 . .
C52 C51 H51 118.2 . .
C47 C52 C51 122.9(12) . .
C47 C52 H52 118.5 . .
C51 C52 H52 118.5 . .
C58 C53 C54 121.6(18) . .
C58 C53 P2 119.0(16) . .
C54 C53 P2 119.3(12) . .
C53 C54 C55 119.4(18) . .
C53 C54 H54 120.3 . .
C55 C54 H54 120.3 . .
C54 C55 C56 114.0(18) . .
C54 C55 H55 123.0 . .
C56 C55 H55 123.0 . .
C57 C56 C55 129(2) . .
C57 C56 H56 115.3 . .
C55 C56 H56 115.3 . .
C56 C57 C58 114(2) . .
C56 C57 H57 122.9 . .
C58 C57 H57 122.9 . .
C53 C58 C57 122(2) . .
C53 C58 H58 119.2 . .
C57 C58 H58 119.2 . .
C36 O4 Rh2 121.2(6) 2_556 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 N1 2.001(7) .
Rh1 N3 2.028(7) .
Rh1 O2 2.066(6) .
Rh1 O1 2.076(6) .
Rh1 P1 2.508(3) .
Rh1 Rh1 2.6328(13) 2_556
N1 C1 1.330(10) .
N1 C3 1.369(11) .
C1 N2 1.315(10) .
C1 C4 1.480(14) .
N2 C2 1.369(11) .
N2 H2N 0.8800 .
C2 C3 1.346(12) .
C2 H2 0.9500 .
C3 H3 0.9500 .
N3 C4 1.353(11) .
N3 C6 1.367(11) .
C4 N4 1.317(11) .
N4 C5 1.372(11) .
C5 C6 1.363(12) .
C5 H5 0.9500 .
C6 H6 0.9500 .
O1 C7 1.268(11) .
O2 C7 1.267(11) 2_556
C7 O2 1.267(11) 2_556
C7 C8 1.510(12) .
C8 C9B 1.505(16) .
C8 C9A 1.531(17) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C8 H8C 0.9900 .
C8 H8D 0.9900 .
C9A C10A 1.528(18) .
C9A H9A 0.9900 .
C9A H9B 0.9900 .
C10A C11A 1.525(19) .
C10A H10A 0.9900 .
C10A H10B 0.9900 .
C11A H11A 0.9800 .
C11A H11B 0.9800 .
C11A H11C 0.9800 .
C9B C10B 1.539(18) .
C9B H9C 0.9900 .
C9B H9D 0.9900 .
C10B C11B 1.522(18) .
C10B H10C 0.9900 .
C10B H10D 0.9900 .
C11B H11D 0.9800 .
C11B H11E 0.9800 .
C11B H11F 0.9800 .
P1 C18 1.802(12) .
P1 C24 1.827(10) .
P1 C12 1.835(11) .
C12 C13 1.368(15) .
C12 C17 1.395(14) .
C13 C14 1.39(2) .
C13 H13 0.9500 .
C14 C15 1.35(2) .
C14 H14 0.9500 .
C15 C16 1.353(19) .
C15 H15 0.9500 .
C16 C17 1.389(15) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C18 C19 1.372(15) .
C18 C23 1.402(15) .
C19 C20 1.409(15) .
C19 H19 0.9500 .
C20 C21 1.41(2) .
C20 H20 0.9500 .
C21 C22 1.27(3) .
C21 H21 0.9500 .
C22 C23 1.43(2) .
C22 H22 0.9500 .
C23 H23 0.9500 .
C24 C29 1.390(13) .
C24 C25 1.404(12) .
C25 C26 1.360(12) .
C25 H25 0.9500 .
C26 C27 1.388(13) .
C26 H26 0.9500 .
C27 C28 1.390(14) .
C27 H27 0.9500 .
C28 C29 1.378(13) .
C28 H28 0.9500 .
C29 H29 0.9500 .
Rh2 N5 1.999(7) .
Rh2 N7 2.029(6) .
Rh2 O4 2.056(5) .
Rh2 O3 2.070(6) .
Rh2 P2 2.463(3) .
Rh2 Rh2 2.6180(13) 2_556
N5 C30 1.352(11) .
N5 C32 1.360(11) .
C30 N6 1.311(11) .
C30 C33 1.458(14) .
N6 C31 1.376(11) .
N6 H6N 0.8800 .
C31 C32 1.362(12) .
C31 H31 0.9500 .
C32 H32 0.9500 .
N7 C33 1.364(10) .
N7 C35 1.366(11) .
C33 N8 1.315(11) .
N8 C34 1.390(11) .
C34 C35 1.362(12) .
C34 H34 0.9500 .
C35 H35 0.9500 .
O3 C36 1.267(11) .
C36 O4 1.269(11) 2_556
C36 C37B 1.490(12) .
C36 C37A 1.496(18) .
C37B C38B 1.492(14) .
C37B H37C 0.9900 .
C37B H37D 0.9900 .
C38B C39B 1.511(17) .
C38B H38C 0.9900 .
C38B H38D 0.9900 .
C39B C40B 1.483(17) .
C39B H39C 0.9900 .
C39B H39D 0.9900 .
C40B H40D 0.9800 .
C40B H40E 0.9800 .
C40B H40F 0.9800 .
C37A C38A 1.503(19) .
C37A H37A 0.9900 .
C37A H37B 0.9900 .
C38A C39A 1.514(19) .
C38A H38A 0.9900 .
C38A H38B 0.9900 .
C39A C40A 1.499(19) .
C39A H39A 0.9900 .
C39A H39B 0.9900 .
C40A H40A 0.9800 .
C40A H40B 0.9800 .
C40A H40C 0.9800 .
P2 C47 1.808(12) .
P2 C53 1.812(16) .
P2 C41 1.834(11) .
C41 C42 1.358(15) .
C41 C46 1.410(15) .
C42 C43 1.391(16) .
C42 H42 0.9500 .
C43 C44 1.40(2) .
C43 H43 0.9500 .
C44 C45 1.35(2) .
C44 H44 0.9500 .
C45 C46 1.366(19) .
C45 H45 0.9500 .
C46 H46 0.9500 .
C47 C52 1.323(14) .
C47 C48 1.464(17) .
C48 C49 1.417(16) .
C48 H48 0.9500 .
C49 C50 1.42(2) .
C49 H49 0.9500 .
C50 C51 1.31(2) .
C50 H50 0.9500 .
C51 C52 1.381(16) .
C51 H51 0.9500 .
C52 H52 0.9500 .
C53 C58 1.355(19) .
C53 C54 1.396(19) .
C54 C55 1.41(2) .
C54 H54 0.9500 .
C55 C56 1.41(2) .
C55 H55 0.9500 .
C56 C57 1.31(2) .
C56 H56 0.9500 .
C57 C58 1.42(2) .
C57 H57 0.9500 .
C58 H58 0.9500 .
O4 C36 1.269(11) 2_556
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N2 H2N N8 0.88 1.89 2.754(11) 166.7
N6 H6N N4 0.88 1.86 2.730(11) 168.3
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N3 Rh1 N1 C1 -0.9(6) . .
O2 Rh1 N1 C1 177.9(6) . .
O1 Rh1 N1 C1 -42(4) . .
P1 Rh1 N1 C1 84.8(6) . .
Rh1 Rh1 N1 C1 -97.7(6) 2_556 .
N3 Rh1 N1 C3 -173.2(9) . .
O2 Rh1 N1 C3 5.7(8) . .
O1 Rh1 N1 C3 146(3) . .
P1 Rh1 N1 C3 -87.5(8) . .
Rh1 Rh1 N1 C3 90.1(8) 2_556 .
C3 N1 C1 N2 0.0(9) . .
Rh1 N1 C1 N2 -174.6(5) . .
C3 N1 C1 C4 177.2(7) . .
Rh1 N1 C1 C4 2.6(9) . .
N1 C1 N2 C2 -0.3(9) . .
C4 C1 N2 C2 -176.8(8) . .
C1 N2 C2 C3 0.5(9) . .
N2 C2 C3 N1 -0.5(10) . .
C1 N1 C3 C2 0.3(9) . .
Rh1 N1 C3 C2 173.1(6) . .
N1 Rh1 N3 C4 -1.0(5) . .
O2 Rh1 N3 C4 -14(3) . .
O1 Rh1 N3 C4 175.7(6) . .
P1 Rh1 N3 C4 -92.6(6) . .
Rh1 Rh1 N3 C4 90.8(5) 2_556 .
N1 Rh1 N3 C6 173.7(9) . .
O2 Rh1 N3 C6 160(3) . .
O1 Rh1 N3 C6 -9.6(9) . .
P1 Rh1 N3 C6 82.1(8) . .
Rh1 Rh1 N3 C6 -94.5(8) 2_556 .
C6 N3 C4 N4 0.6(9) . .
Rh1 N3 C4 N4 177.1(6) . .
C6 N3 C4 C1 -173.9(7) . .
Rh1 N3 C4 C1 2.6(9) . .
N2 C1 C4 N4 -0.3(16) . .
N1 C1 C4 N4 -176.8(8) . .
N2 C1 C4 N3 173.1(8) . .
N1 C1 C4 N3 -3.3(10) . .
N3 C4 N4 C5 -0.1(10) . .
C1 C4 N4 C5 173.2(9) . .
C4 N4 C5 C6 -0.5(9) . .
N4 C5 C6 N3 0.9(10) . .
C4 N3 C6 C5 -0.9(9) . .
Rh1 N3 C6 C5 -176.0(6) . .
N1 Rh1 O1 C7 -43(4) . .
N3 Rh1 O1 C7 -83.9(7) . .
O2 Rh1 O1 C7 97.0(7) . .
P1 Rh1 O1 C7 -170.0(7) . .
Rh1 Rh1 O1 C7 12.6(7) 2_556 .
N1 Rh1 O2 C7 109.0(7) . 2_556
N3 Rh1 O2 C7 122(3) . 2_556
O1 Rh1 O2 C7 -67.8(7) . 2_556
P1 Rh1 O2 C7 -159.9(7) . 2_556
Rh1 Rh1 O2 C7 16.5(7) 2_556 2_556
Rh1 O1 C7 O2 -4.0(14) . 2_556
Rh1 O1 C7 C8 177.1(8) . .
O2 C7 C8 C9B 24(2) 2_556 .
O1 C7 C8 C9B -156.8(14) . .
O2 C7 C8 C9A 98.0(19) 2_556 .
O1 C7 C8 C9A -83.0(18) . .
C9B C8 C9A C10A -77(2) . .
C7 C8 C9A C10A 168.5(19) . .
C8 C9A C10A C11A 70(3) . .
C7 C8 C9B C10B 102(3) . .
C9A C8 C9B C10B 2(2) . .
C8 C9B C10B C11B -56(4) . .
N1 Rh1 P1 C18 103.4(5) . .
N3 Rh1 P1 C18 -177.6(5) . .
O2 Rh1 P1 C18 7.2(5) . .
O1 Rh1 P1 C18 -80.5(5) . .
Rh1 Rh1 P1 C18 -45.0(12) 2_556 .
N1 Rh1 P1 C24 -15.1(5) . .
N3 Rh1 P1 C24 63.9(5) . .
O2 Rh1 P1 C24 -111.2(5) . .
O1 Rh1 P1 C24 161.1(5) . .
Rh1 Rh1 P1 C24 -163.5(10) 2_556 .
N1 Rh1 P1 C12 -132.3(5) . .
N3 Rh1 P1 C12 -53.4(5) . .
O2 Rh1 P1 C12 131.5(5) . .
O1 Rh1 P1 C12 43.8(5) . .
Rh1 Rh1 P1 C12 79.2(11) 2_556 .
C18 P1 C12 C13 -72.0(12) . .
C24 P1 C12 C13 33.9(12) . .
Rh1 P1 C12 C13 156.2(10) . .
C18 P1 C12 C17 102.4(10) . .
C24 P1 C12 C17 -151.7(9) . .
Rh1 P1 C12 C17 -29.4(11) . .
C17 C12 C13 C14 2(2) . .
P1 C12 C13 C14 176.9(14) . .
C12 C13 C14 C15 -1(3) . .
C13 C14 C15 C16 -1(3) . .
C14 C15 C16 C17 2(3) . .
C15 C16 C17 C12 -1(2) . .
C13 C12 C17 C16 -1.5(19) . .
P1 C12 C17 C16 -176.1(10) . .
C24 P1 C18 C19 81.7(9) . .
C12 P1 C18 C19 -172.1(8) . .
Rh1 P1 C18 C19 -41.6(9) . .
C24 P1 C18 C23 -99.3(9) . .
C12 P1 C18 C23 6.9(11) . .
Rh1 P1 C18 C23 137.4(8) . .
C23 C18 C19 C20 3.3(16) . .
P1 C18 C19 C20 -177.6(7) . .
C18 C19 C20 C21 -1.0(16) . .
C19 C20 C21 C22 -3(3) . .
C20 C21 C22 C23 5(4) . .
C19 C18 C23 C22 -1.7(16) . .
P1 C18 C23 C22 179.3(10) . .
C21 C22 C23 C18 -3(3) . .
C18 P1 C24 C29 157.9(8) . .
C12 P1 C24 C29 51.2(8) . .
Rh1 P1 C24 C29 -74.1(8) . .
C18 P1 C24 C25 -28.8(9) . .
C12 P1 C24 C25 -135.6(8) . .
Rh1 P1 C24 C25 99.1(7) . .
C29 C24 C25 C26 0.1(13) . .
P1 C24 C25 C26 -173.3(7) . .
C24 C25 C26 C27 0.3(15) . .
C25 C26 C27 C28 -0.4(15) . .
C26 C27 C28 C29 0.0(14) . .
C27 C28 C29 C24 0.4(14) . .
C25 C24 C29 C28 -0.4(13) . .
P1 C24 C29 C28 173.2(7) . .
N7 Rh2 N5 C30 -0.9(6) . .
O4 Rh2 N5 C30 178.4(6) . .
O3 Rh2 N5 C30 -38(4) . .
P2 Rh2 N5 C30 87.7(6) . .
Rh2 Rh2 N5 C30 -97.2(6) 2_556 .
N7 Rh2 N5 C32 -174.9(9) . .
O4 Rh2 N5 C32 4.4(9) . .
O3 Rh2 N5 C32 148(3) . .
P2 Rh2 N5 C32 -86.3(9) . .
Rh2 Rh2 N5 C32 88.8(9) 2_556 .
C32 N5 C30 N6 0.7(10) . .
Rh2 N5 C30 N6 -175.1(6) . .
C32 N5 C30 C33 177.6(8) . .
Rh2 N5 C30 C33 1.8(10) . .
N5 C30 N6 C31 -1.3(10) . .
C33 C30 N6 C31 -177.5(10) . .
C30 N6 C31 C32 1.4(11) . .
C30 N5 C32 C31 0.2(11) . .
Rh2 N5 C32 C31 174.6(7) . .
N6 C31 C32 N5 -1.0(12) . .
N5 Rh2 N7 C33 -0.2(6) . .
O4 Rh2 N7 C33 -5(2) . .
O3 Rh2 N7 C33 177.4(6) . .
P2 Rh2 N7 C33 -93.3(6) . .
Rh2 Rh2 N7 C33 93.1(6) 2_556 .
N5 Rh2 N7 C35 177.2(9) . .
O4 Rh2 N7 C35 172.2(15) . .
O3 Rh2 N7 C35 -5.2(9) . .
P2 Rh2 N7 C35 84.1(9) . .
Rh2 Rh2 N7 C35 -89.5(9) 2_556 .
C35 N7 C33 N8 1.5(10) . .
Rh2 N7 C33 N8 179.8(6) . .
C35 N7 C33 C30 -177.1(7) . .
Rh2 N7 C33 C30 1.2(9) . .
N6 C30 C33 N8 -4.1(17) . .
N5 C30 C33 N8 179.8(9) . .
N6 C30 C33 N7 174.2(9) . .
N5 C30 C33 N7 -2.0(11) . .
N7 C33 N8 C34 -1.1(10) . .
C30 C33 N8 C34 177.1(9) . .
C33 N8 C34 C35 0.3(10) . .
N8 C34 C35 N7 0.5(11) . .
C33 N7 C35 C34 -1.1(10) . .
Rh2 N7 C35 C34 -178.8(7) . .
N5 Rh2 O3 C36 -43(4) . .
N7 Rh2 O3 C36 -79.0(7) . .
O4 Rh2 O3 C36 101.3(7) . .
P2 Rh2 O3 C36 -168.1(6) . .
Rh2 Rh2 O3 C36 17.3(6) 2_556 .
Rh2 O3 C36 O4 -6.3(12) . 2_556
Rh2 O3 C36 C37B 173.7(10) . .
Rh2 O3 C36 C37A 167(3) . .
O3 C36 C37B C38B 30.9(19) . .
O4 C36 C37B C38B -149.1(13) 2_556 .
C37A C36 C37B C38B 82(14) . .
C36 C37B C38B C39B 66(2) . .
C37B C38B C39B C40B 172(2) . .
O3 C36 C37A C38A -1(4) . .
O4 C36 C37A C38A 173(2) 2_556 .
C37B C36 C37A C38A -132(17) . .
C36 C37A C38A C39A 89(5) . .
C37A C38A C39A C40A -162(5) . .
N5 Rh2 P2 C47 -129.9(6) . .
N7 Rh2 P2 C47 -51.1(6) . .
O4 Rh2 P2 C47 136.6(6) . .
O3 Rh2 P2 C47 46.8(6) . .
Rh2 Rh2 P2 C47 83.5(8) 2_556 .
N5 Rh2 P2 C53 -8.9(6) . .
N7 Rh2 P2 C53 70.0(6) . .
O4 Rh2 P2 C53 -102.4(6) . .
O3 Rh2 P2 C53 167.8(6) . .
Rh2 Rh2 P2 C53 -155.5(7) 2_556 .
N5 Rh2 P2 C41 110.7(5) . .
N7 Rh2 P2 C41 -170.4(5) . .
O4 Rh2 P2 C41 17.2(5) . .
O3 Rh2 P2 C41 -72.5(5) . .
Rh2 Rh2 P2 C41 -35.8(7) 2_556 .
C47 P2 C41 C42 -95.1(10) . .
C53 P2 C41 C42 155.7(9) . .
Rh2 P2 C41 C42 34.8(10) . .
C47 P2 C41 C46 80.5(11) . .
C53 P2 C41 C46 -28.7(11) . .
Rh2 P2 C41 C46 -149.5(8) . .
C46 C41 C42 C43 1.4(17) . .
P2 C41 C42 C43 177.2(9) . .
C41 C42 C43 C44 0.2(19) . .
C42 C43 C44 C45 -1(2) . .
C43 C44 C45 C46 0(3) . .
C44 C45 C46 C41 1(2) . .
C42 C41 C46 C45 -2.1(18) . .
P2 C41 C46 C45 -177.7(10) . .
C53 P2 C47 C52 44.4(15) . .
C41 P2 C47 C52 -66.0(15) . .
Rh2 P2 C47 C52 167.2(12) . .
C53 P2 C47 C48 -148.3(11) . .
C41 P2 C47 C48 101.4(11) . .
Rh2 P2 C47 C48 -25.4(13) . .
C52 C47 C48 C49 -7(2) . .
P2 C47 C48 C49 -175.9(11) . .
C47 C48 C49 C50 -2(2) . .
C48 C49 C50 C51 9(3) . .
C49 C50 C51 C52 -7(3) . .
C48 C47 C52 C51 10(2) . .
P2 C47 C52 C51 178.0(12) . .
C50 C51 C52 C47 -4(3) . .
C47 P2 C53 C58 39.1(12) . .
C41 P2 C53 C58 144.6(10) . .
Rh2 P2 C53 C58 -90.6(11) . .
C47 P2 C53 C54 -145.5(13) . .
C41 P2 C53 C54 -40.0(14) . .
Rh2 P2 C53 C54 84.7(13) . .
C58 C53 C54 C55 1(3) . .
P2 C53 C54 C55 -174.1(15) . .
C53 C54 C55 C56 0(3) . .
C54 C55 C56 C57 -1(4) . .
C55 C56 C57 C58 1(3) . .
C54 C53 C58 C57 -2(2) . .
P2 C53 C58 C57 173.7(11) . .
C56 C57 C58 C53 0(2) . .
N5 Rh2 O4 C36 115.7(7) . 2_556
N7 Rh2 O4 C36 120.6(18) . 2_556
O3 Rh2 O4 C36 -62.0(7) . 2_556
P2 Rh2 O4 C36 -151.4(6) . 2_556
Rh2 Rh2 O4 C36 21.4(6) 2_556 2_556
