#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342570.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342570
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Sm4 Rh2 In Ge4'
_chemical_formula_sum            'Ge4 In Rh2 Sm4'
_chemical_formula_weight         1212.40
_chemical_name_common            'samarium rhodium indium germanide (4/2/1/4)'
_chemical_name_systematic        'samarium rhodium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.878(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.857(3)
_cell_length_b                   4.3147(8)
_cell_length_c                   7.0971(14)
_cell_measurement_reflns_used    2271
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.57
_cell_measurement_theta_min      2.68
_cell_volume                     464.65(15)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_av_unetI/netI     0.0290
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3381
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.233
_diffrn_reflns_theta_min         2.685
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    43.358
_exptl_absorpt_correction_T_max  0.6771
_exptl_absorpt_correction_T_min  0.0952
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.666
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1030
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.018
_exptl_crystal_size_min          0.014
_refine_diff_density_max         1.655
_refine_diff_density_min         -1.750
_refine_diff_density_rms         0.397
_refine_ls_extinction_coef       0.00190(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         977
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0251
_refine_ls_R_factor_gt           0.0196
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0161P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0379
_refine_ls_wR_factor_ref         0.0393
_reflns_Friedel_coverage         0.000
_reflns_number_gt                852
_reflns_number_total             977
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_005.cif
_cod_data_source_block           Sm4Rh2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_original_cell_volume        464.65(16)
_cod_database_code               4342570
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.098
_shelx_estimated_absorpt_t_max   0.582
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Sm1 Sm 0.34640(2) 0.0000 0.06704(4) 0.00599(8) Uani 1 2 d S T P
Sm2 Sm 0.58692(2) 0.0000 0.38125(4) 0.00557(8) Uani 1 2 d S T P
Rh Rh 0.21977(3) 0.0000 0.62518(7) 0.00583(10) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00730(18) Uani 0.973(3) 4 d S T .
Ge1 Ge 0.06472(4) 0.0000 0.65732(9) 0.00574(13) Uani 1 2 d S T P
Ge2 Ge 0.20301(4) 0.0000 0.26094(9) 0.00617(13) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Sm1 Ge1 92.86(2) 7_556 7_546
Ge1 Sm1 Ge2 88.61(2) 7_556 .
Ge1 Sm1 Ge2 88.61(2) 7_546 .
Ge1 Sm1 Ge2 164.77(2) 7_556 7_545
Ge1 Sm1 Ge2 87.557(19) 7_546 7_545
Ge2 Sm1 Ge2 106.626(17) . 7_545
Ge1 Sm1 Ge2 87.557(19) 7_556 7
Ge1 Sm1 Ge2 164.77(2) 7_546 7
Ge2 Sm1 Ge2 106.626(17) . 7
Ge2 Sm1 Ge2 88.10(2) 7_545 7
Ge1 Sm1 Rh 133.432(12) 7_556 1_554
Ge1 Sm1 Rh 133.432(12) 7_546 1_554
Ge2 Sm1 Rh 96.14(2) . 1_554
Ge2 Sm1 Rh 46.676(13) 7_545 1_554
Ge2 Sm1 Rh 46.676(13) 7 1_554
Ge1 Sm1 In 53.748(16) 7_556 3
Ge1 Sm1 In 109.333(19) 7_546 3
Ge2 Sm1 In 137.784(9) . 3
Ge2 Sm1 In 111.870(17) 7_545 3
Ge2 Sm1 In 59.156(15) 7 3
Rh Sm1 In 97.740(13) 1_554 3
Ge1 Sm1 In 109.333(19) 7_556 3_545
Ge1 Sm1 In 53.748(15) 7_546 3_545
Ge2 Sm1 In 137.784(9) . 3_545
Ge2 Sm1 In 59.156(15) 7_545 3_545
Ge2 Sm1 In 111.870(17) 7 3_545
Rh Sm1 In 97.740(13) 1_554 3_545
In Sm1 In 79.072(16) 3 3_545
Ge1 Sm1 Rh 45.780(18) 7_556 7_556
Ge1 Sm1 Rh 102.15(2) 7_546 7_556
Ge2 Sm1 Rh 45.026(11) . 7_556
Ge2 Sm1 Rh 148.698(19) 7_545 7_556
Ge2 Sm1 Rh 89.038(18) 7 7_556
Rh Sm1 Rh 113.715(16) 1_554 7_556
In Sm1 Rh 93.095(13) 3 7_556
In Sm1 Rh 148.389(13) 3_545 7_556
Ge1 Sm1 Rh 102.15(2) 7_556 7_546
Ge1 Sm1 Rh 45.780(17) 7_546 7_546
Ge2 Sm1 Rh 45.026(11) . 7_546
Ge2 Sm1 Rh 89.038(18) 7_545 7_546
Ge2 Sm1 Rh 148.698(19) 7 7_546
Rh Sm1 Rh 113.715(16) 1_554 7_546
In Sm1 Rh 148.389(13) 3 7_546
In Sm1 Rh 93.095(13) 3_545 7_546
Rh Sm1 Rh 77.588(18) 7_556 7_546
Ge1 Sm1 Sm2 111.890(17) 7_556 5_655
Ge1 Sm1 Sm2 111.890(17) 7_546 5_655
Ge2 Sm1 Sm2 149.278(17) . 5_655
Ge2 Sm1 Sm2 54.353(14) 7_545 5_655
Ge2 Sm1 Sm2 54.353(14) 7 5_655
Rh Sm1 Sm2 53.141(17) 1_554 5_655
In Sm1 Sm2 58.211(7) 3 5_655
In Sm1 Sm2 58.211(7) 3_545 5_655
Rh Sm1 Sm2 140.843(9) 7_556 5_655
Rh Sm1 Sm2 140.843(9) 7_546 5_655
Ge1 Sm1 Sm1 143.471(19) 7_556 7_545
Ge1 Sm1 Sm1 86.771(16) 7_546 7_545
Ge2 Sm1 Sm1 54.866(15) . 7_545
Ge2 Sm1 Sm1 51.760(14) 7_545 7_545
Ge2 Sm1 Sm1 101.903(18) 7 7_545
Rh Sm1 Sm1 60.134(12) 1_554 7_545
In Sm1 Sm1 157.670(15) 3 7_545
In Sm1 Sm1 99.759(16) 3_545 7_545
Rh Sm1 Sm1 98.621(17) 7_556 7_545
Rh Sm1 Sm1 53.581(13) 7_546 7_545
Sm2 Sm1 Sm1 101.961(14) 5_655 7_545
Ge1 Sm2 Ge1 91.85(2) 3 3_545
Ge1 Sm2 Rh 108.392(16) 3 5_656
Ge1 Sm2 Rh 108.392(16) 3_545 5_656
Ge1 Sm2 Ge2 82.630(18) 3 3
Ge1 Sm2 Ge2 150.20(2) 3_545 3
Rh Sm2 Ge2 47.559(12) 5_656 3
Ge1 Sm2 Ge2 150.20(2) 3 3_545
Ge1 Sm2 Ge2 82.630(18) 3_545 3_545
Rh Sm2 Ge2 47.559(13) 5_656 3_545
Ge2 Sm2 Ge2 87.78(2) 3 3_545
Ge1 Sm2 Rh 48.499(17) 3 3
Ge1 Sm2 Rh 108.60(2) 3_545 3
Rh Sm2 Rh 59.973(14) 5_656 3
Ge2 Sm2 Rh 47.408(18) 3 3
Ge2 Sm2 Rh 105.69(2) 3_545 3
Ge1 Sm2 Rh 108.60(2) 3 3_545
Ge1 Sm2 Rh 48.499(17) 3_545 3_545
Rh Sm2 Rh 59.973(14) 5_656 3_545
Ge2 Sm2 Rh 105.69(2) 3 3_545
Ge2 Sm2 Rh 47.408(18) 3_545 3_545
Rh Sm2 Rh 86.191(19) 3 3_545
Ge1 Sm2 Ge1 108.319(15) 3 7_546
Ge1 Sm2 Ge1 48.73(2) 3_545 7_546
Rh Sm2 Ge1 136.830(12) 5_656 7_546
Ge2 Sm2 Ge1 159.83(2) 3 7_546
Ge2 Sm2 Ge1 89.932(19) 3_545 7_546
Rh Sm2 Ge1 151.325(18) 3 7_546
Rh Sm2 Ge1 87.198(18) 3_545 7_546
Ge1 Sm2 Ge1 48.73(2) 3 7_556
Ge1 Sm2 Ge1 108.319(15) 3_545 7_556
Rh Sm2 Ge1 136.830(12) 5_656 7_556
Ge2 Sm2 Ge1 89.932(19) 3 7_556
Ge2 Sm2 Ge1 159.83(2) 3_545 7_556
Rh Sm2 Ge1 87.198(18) 3 7_556
Rh Sm2 Ge1 151.325(18) 3_545 7_556
Ge1 Sm2 Ge1 85.35(2) 7_546 7_556
Ge1 Sm2 In 150.718(18) 3 3_545
Ge1 Sm2 In 88.073(18) 3_545 3_545
Rh Sm2 In 99.350(12) 5_656 3_545
Ge2 Sm2 In 110.773(18) 3 3_545
Ge2 Sm2 In 58.704(15) 3_545 3_545
Rh Sm2 In 156.304(13) 3 3_545
Rh Sm2 In 93.108(14) 3_545 3_545
Ge1 Sm2 In 51.963(13) 7_546 3_545
Ge1 Sm2 In 103.801(16) 7_556 3_545
Ge1 Sm2 In 88.073(18) 3 3
Ge1 Sm2 In 150.718(18) 3_545 3
Rh Sm2 In 99.350(11) 5_656 3
Ge2 Sm2 In 58.704(16) 3 3
Ge2 Sm2 In 110.773(18) 3_545 3
Rh Sm2 In 93.108(14) 3 3
Rh Sm2 In 156.304(13) 3_545 3
Ge1 Sm2 In 103.801(16) 7_546 3
Ge1 Sm2 In 51.963(13) 7_556 3
In Sm2 In 78.167(16) 3_545 3
Ge1 Sm2 Sm2 56.462(14) 3 5_656
Ge1 Sm2 Sm2 56.462(14) 3_545 5_656
Rh Sm2 Sm2 154.389(18) 5_656 5_656
Ge2 Sm2 Sm2 135.881(11) 3 5_656
Ge2 Sm2 Sm2 135.881(11) 3_545 5_656
Rh Sm2 Sm2 102.789(17) 3 5_656
Rh Sm2 Sm2 102.789(17) 3_545 5_656
Ge1 Sm2 Sm2 51.857(14) 7_546 5_656
Ge1 Sm2 Sm2 51.857(14) 7_556 5_656
In Sm2 Sm2 100.462(14) 3_545 5_656
In Sm2 Sm2 100.462(14) 3 5_656
Ge2 Rh Ge2 119.58(3) 7_556 7_546
Ge2 Rh Ge2 103.165(19) 7_556 .
Ge2 Rh Ge2 103.165(19) 7_546 .
Ge2 Rh Ge1 111.614(19) 7_556 .
Ge2 Rh Ge1 111.614(19) 7_546 .
Ge2 Rh Ge1 106.03(3) . .
Ge2 Rh Sm2 66.917(18) 7_556 5_656
Ge2 Rh Sm2 66.917(18) 7_546 5_656
Ge2 Rh Sm2 78.10(2) . 5_656
Ge1 Rh Sm2 175.87(2) . 5_656
Ge2 Rh Rh 125.41(3) 7_556 7_546
Ge2 Rh Rh 51.933(19) 7_546 7_546
Ge2 Rh Rh 51.231(16) . 7_546
Ge1 Rh Rh 121.21(2) . 7_546
Sm2 Rh Rh 61.269(16) 5_656 7_546
Ge2 Rh Rh 51.933(19) 7_556 7_556
Ge2 Rh Rh 125.41(3) 7_546 7_556
Ge2 Rh Rh 51.231(16) . 7_556
Ge1 Rh Rh 121.21(2) . 7_556
Sm2 Rh Rh 61.269(16) 5_656 7_556
Rh Rh Rh 87.57(3) 7_546 7_556
Ge2 Rh Sm2 162.62(2) 7_556 3_445
Ge2 Rh Sm2 76.909(19) 7_546 3_445
Ge2 Rh Sm2 65.346(16) . 3_445
Ge1 Rh Sm2 62.558(16) . 3_445
Sm2 Rh Sm2 120.028(14) 5_656 3_445
Rh Rh Sm2 58.760(17) 7_546 3_445
Rh Rh Sm2 115.27(3) 7_556 3_445
Ge2 Rh Sm2 76.909(19) 7_556 3_455
Ge2 Rh Sm2 162.62(2) 7_546 3_455
Ge2 Rh Sm2 65.346(16) . 3_455
Ge1 Rh Sm2 62.558(16) . 3_455
Sm2 Rh Sm2 120.028(14) 5_656 3_455
Rh Rh Sm2 115.27(3) 7_546 3_455
Rh Rh Sm2 58.760(17) 7_556 3_455
Sm2 Rh Sm2 86.189(19) 3_445 3_455
Ge2 Rh Sm1 64.714(17) 7_556 1_556
Ge2 Rh Sm1 64.714(17) 7_546 1_556
Ge2 Rh Sm1 148.82(3) . 1_556
Ge1 Rh Sm1 105.15(2) . 1_556
Sm2 Rh Sm1 70.725(16) 5_656 1_556
Rh Rh Sm1 110.47(2) 7_546 1_556
Rh Rh Sm1 110.47(2) 7_556 1_556
Sm2 Rh Sm1 131.849(11) 3_445 1_556
Sm2 Rh Sm1 131.849(11) 3_455 1_556
Ge2 Rh Sm1 57.612(18) 7_556 7_556
Ge2 Rh Sm1 123.18(2) 7_546 7_556
Ge2 Rh Sm1 133.608(15) . 7_556
Ge1 Rh Sm1 57.362(13) . 7_556
Sm2 Rh Sm1 119.830(14) 5_656 7_556
Rh Rh Sm1 174.767(18) 7_546 7_556
Rh Rh Sm1 97.399(15) 7_556 7_556
Sm2 Rh Sm1 119.88(2) 3_445 7_556
Sm2 Rh Sm1 69.030(15) 3_455 7_556
Sm1 Rh Sm1 66.285(16) 1_556 7_556
Ge2 Rh Sm1 123.18(2) 7_556 7_546
Ge2 Rh Sm1 57.612(18) 7_546 7_546
Ge2 Rh Sm1 133.608(15) . 7_546
Ge1 Rh Sm1 57.362(13) . 7_546
Sm2 Rh Sm1 119.830(13) 5_656 7_546
Rh Rh Sm1 97.399(15) 7_546 7_546
Rh Rh Sm1 174.767(18) 7_556 7_546
Sm2 Rh Sm1 69.030(15) 3_445 7_546
Sm2 Rh Sm1 119.881(19) 3_455 7_546
Sm1 Rh Sm1 66.285(15) 1_556 7_546
Sm1 Rh Sm1 77.587(18) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Sm1 55.859(10) 5_556 3_445
Ge1 In Sm1 124.141(10) 1_554 3_445
Ge1 In Sm1 124.141(10) 5_556 7
Ge1 In Sm1 55.859(10) 1_554 7
Sm1 In Sm1 180.0 3_445 7
Ge1 In Sm1 124.141(10) 5_556 7_545
Ge1 In Sm1 55.859(10) 1_554 7_545
Sm1 In Sm1 100.928(16) 3_445 7_545
Sm1 In Sm1 79.072(16) 7 7_545
Ge1 In Sm1 55.859(10) 5_556 3_455
Ge1 In Sm1 124.141(10) 1_554 3_455
Sm1 In Sm1 79.072(16) 3_445 3_455
Sm1 In Sm1 100.928(16) 7 3_455
Sm1 In Sm1 180.0 7_545 3_455
Ge1 In Sm2 59.766(14) 5_556 3_455
Ge1 In Sm2 120.234(14) 1_554 3_455
Sm1 In Sm2 115.545(12) 3_445 3_455
Sm1 In Sm2 64.455(12) 7 3_455
Sm1 In Sm2 111.804(12) 7_545 3_455
Sm1 In Sm2 68.196(12) 3_455 3_455
Ge1 In Sm2 120.234(14) 5_556 7_545
Ge1 In Sm2 59.766(14) 1_554 7_545
Sm1 In Sm2 64.455(12) 3_445 7_545
Sm1 In Sm2 115.545(12) 7 7_545
Sm1 In Sm2 68.196(12) 7_545 7_545
Sm1 In Sm2 111.804(12) 3_455 7_545
Sm2 In Sm2 180.0 3_455 7_545
Ge1 In Sm2 59.766(14) 5_556 3_445
Ge1 In Sm2 120.234(14) 1_554 3_445
Sm1 In Sm2 68.196(12) 3_445 3_445
Sm1 In Sm2 111.804(12) 7 3_445
Sm1 In Sm2 64.455(12) 7_545 3_445
Sm1 In Sm2 115.545(12) 3_455 3_445
Sm2 In Sm2 78.167(16) 3_455 3_445
Sm2 In Sm2 101.833(16) 7_545 3_445
Ge1 In Sm2 120.234(14) 5_556 7
Ge1 In Sm2 59.766(14) 1_554 7
Sm1 In Sm2 111.804(12) 3_445 7
Sm1 In Sm2 68.196(12) 7 7
Sm1 In Sm2 115.545(12) 7_545 7
Sm1 In Sm2 64.455(12) 3_455 7
Sm2 In Sm2 101.833(16) 3_455 7
Sm2 In Sm2 78.167(16) 7_545 7
Sm2 In Sm2 180.0 3_445 7
Rh Ge1 Ge1 118.37(4) . 5_556
Rh Ge1 In 131.60(3) . 1_556
Ge1 Ge1 In 110.03(4) 5_556 1_556
Rh Ge1 Sm1 76.857(18) . 7_556
Ge1 Ge1 Sm1 132.889(13) 5_556 7_556
In Ge1 Sm1 70.392(17) 1_556 7_556
Rh Ge1 Sm1 76.857(18) . 7_546
Ge1 Ge1 Sm1 132.888(13) 5_556 7_546
In Ge1 Sm1 70.392(17) 1_556 7_546
Sm1 Ge1 Sm1 92.86(2) 7_556 7_546
Rh Ge1 Sm2 68.943(16) . 3_445
Ge1 Ge1 Sm2 69.31(2) 5_556 3_445
In Ge1 Sm2 133.153(13) 1_556 3_445
Sm1 Ge1 Sm2 145.73(3) 7_556 3_445
Sm1 Ge1 Sm2 77.606(17) 7_546 3_445
Rh Ge1 Sm2 68.943(16) . 3_455
Ge1 Ge1 Sm2 69.31(2) 5_556 3_455
In Ge1 Sm2 133.153(13) 1_556 3_455
Sm1 Ge1 Sm2 77.606(17) 7_556 3_455
Sm1 Ge1 Sm2 145.73(3) 7_546 3_455
Sm2 Ge1 Sm2 91.85(2) 3_445 3_455
Rh Ge1 Sm2 136.118(13) . 7_546
Ge1 Ge1 Sm2 61.97(2) 5_556 7_546
In Ge1 Sm2 68.271(15) 1_556 7_546
Sm1 Ge1 Sm2 138.53(2) 7_556 7_546
Sm1 Ge1 Sm2 76.529(15) 7_546 7_546
Sm2 Ge1 Sm2 71.680(15) 3_445 7_546
Sm2 Ge1 Sm2 131.27(2) 3_455 7_546
Rh Ge1 Sm2 136.118(13) . 7_556
Ge1 Ge1 Sm2 61.97(2) 5_556 7_556
In Ge1 Sm2 68.271(15) 1_556 7_556
Sm1 Ge1 Sm2 76.529(15) 7_556 7_556
Sm1 Ge1 Sm2 138.53(2) 7_546 7_556
Sm2 Ge1 Sm2 131.27(2) 3_445 7_556
Sm2 Ge1 Sm2 71.680(15) 3_455 7_556
Sm2 Ge1 Sm2 85.35(2) 7_546 7_556
Rh Ge2 Rh 119.58(3) 7_556 7_546
Rh Ge2 Rh 76.836(19) 7_556 .
Rh Ge2 Rh 76.836(19) 7_546 .
Rh Ge2 Sm1 77.36(2) 7_556 .
Rh Ge2 Sm1 77.36(2) 7_546 .
Rh Ge2 Sm1 127.32(3) . .
Rh Ge2 Sm1 146.83(3) 7_556 7_545
Rh Ge2 Sm1 68.610(16) 7_546 7_545
Rh Ge2 Sm1 134.252(14) . 7_545
Sm1 Ge2 Sm1 73.374(17) . 7_545
Rh Ge2 Sm1 68.610(16) 7_556 7
Rh Ge2 Sm1 146.83(3) 7_546 7
Rh Ge2 Sm1 134.252(14) . 7
Sm1 Ge2 Sm1 73.374(17) . 7
Sm1 Ge2 Sm1 88.10(2) 7_545 7
Rh Ge2 Sm2 141.62(3) 7_556 3_445
Rh Ge2 Sm2 65.526(18) 7_546 3_445
Rh Ge2 Sm2 67.248(16) . 3_445
Sm1 Ge2 Sm2 135.899(11) . 3_445
Sm1 Ge2 Sm2 71.530(15) 7_545 3_445
Sm1 Ge2 Sm2 130.33(2) 7 3_445
Rh Ge2 Sm2 65.526(18) 7_556 3_455
Rh Ge2 Sm2 141.62(3) 7_546 3_455
Rh Ge2 Sm2 67.248(16) . 3_455
Sm1 Ge2 Sm2 135.899(11) . 3_455
Sm1 Ge2 Sm2 130.33(2) 7_545 3_455
Sm1 Ge2 Sm2 71.530(15) 7 3_455
Sm2 Ge2 Sm2 87.77(2) 3_445 3_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sm1 Ge1 2.9777(6) 7_556
Sm1 Ge1 2.9777(6) 7_546
Sm1 Ge2 2.9799(8) .
Sm1 Ge2 3.1028(7) 7_545
Sm1 Ge2 3.1028(7) 7
Sm1 Rh 3.1952(8) 1_554
Sm1 In 3.3891(5) 3
Sm1 In 3.3891(5) 3_545
Sm1 Rh 3.4434(6) 7_556
Sm1 Rh 3.4434(6) 7_546
Sm1 Sm2 3.6323(7) 5_655
Sm1 Sm1 3.6354(7) 7_545
Sm2 Ge1 3.0029(6) 3
Sm2 Ge1 3.0029(6) 3_545
Sm2 Rh 3.0788(8) 5_656
Sm2 Ge2 3.1119(6) 3
Sm2 Ge2 3.1119(6) 3_545
Sm2 Rh 3.1577(5) 3
Sm2 Rh 3.1577(5) 3_545
Sm2 Ge1 3.1826(7) 7_546
Sm2 Ge1 3.1826(7) 7_556
Sm2 In 3.4219(5) 3_545
Sm2 In 3.4219(5) 3
Sm2 Sm2 3.6247(8) 5_656
Rh Ge2 2.4964(5) 7_556
Rh Ge2 2.4964(5) 7_546
Rh Ge2 2.5207(9) .
Rh Ge1 2.5342(9) .
Rh Sm2 3.0788(8) 5_656
Rh Rh 3.1177(8) 7_546
Rh Rh 3.1177(8) 7_556
Rh Sm2 3.1577(5) 3_445
Rh Sm2 3.1577(5) 3_455
Rh Sm1 3.1952(7) 1_556
Rh Sm1 3.4434(6) 7_556
Rh Sm1 3.4434(6) 7_546
In Ge1 2.9013(8) 5_556
In Ge1 2.9013(8) 1_554
In Sm1 3.3891(5) 3_445
In Sm1 3.3891(5) 7
In Sm1 3.3891(5) 7_545
In Sm1 3.3891(5) 3_455
In Sm2 3.4219(5) 3_455
In Sm2 3.4219(5) 7_545
In Sm2 3.4219(5) 3_445
In Sm2 3.4219(5) 7
Ge1 Ge1 2.5569(13) 5_556
Ge1 In 2.9013(8) 1_556
Ge1 Sm1 2.9777(6) 7_556
Ge1 Sm1 2.9777(6) 7_546
Ge1 Sm2 3.0029(6) 3_445
Ge1 Sm2 3.0029(6) 3_455
Ge1 Sm2 3.1826(7) 7_546
Ge1 Sm2 3.1826(7) 7_556
Ge2 Rh 2.4964(5) 7_556
Ge2 Rh 2.4964(5) 7_546
Ge2 Sm1 3.1028(7) 7_545
Ge2 Sm1 3.1028(7) 7
Ge2 Sm2 3.1120(6) 3_445
Ge2 Sm2 3.1120(6) 3_455
