#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342571.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342571
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Ce4 Ru2 In Ge4'
_chemical_formula_sum            'Ce4 Ge4 In Ru2'
_chemical_formula_weight         1167.80
_chemical_name_common            'cerium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic        'cerium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.144(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.174(4)
_cell_length_b                   4.3794(10)
_cell_length_c                   7.2321(17)
_cell_measurement_reflns_used    2578
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.15
_cell_measurement_theta_min      2.62
_cell_volume                     492.1(2)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_unetI/netI     0.0272
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.973
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            3534
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.973
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.284
_diffrn_reflns_theta_min         2.622
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    35.293
_exptl_absorpt_correction_T_max  0.6524
_exptl_absorpt_correction_T_min  0.1382
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.882
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             994
_exptl_crystal_size_max          0.189
_exptl_crystal_size_mid          0.041
_exptl_crystal_size_min          0.019
_refine_diff_density_max         1.603
_refine_diff_density_min         -1.687
_refine_diff_density_rms         0.370
_refine_ls_extinction_coef       0.00053(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         1025
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0294
_refine_ls_R_factor_gt           0.0218
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0261P)²+0.2084P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0493
_refine_ls_wR_factor_ref         0.0513
_reflns_Friedel_coverage         0.000
_reflns_number_gt                878
_reflns_number_total             1025
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Ce4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342571
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.057
_shelx_estimated_absorpt_t_max   0.554
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ce1 Ce 0.34953(2) 0.0000 0.06118(5) 0.00783(9) Uani 1 2 d S T P
Ce2 Ce 0.58842(2) 0.0000 0.37852(5) 0.00739(9) Uani 1 2 d S T P
Ru Ru 0.21781(3) 0.0000 0.62602(7) 0.00745(11) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00931(19) Uani 0.962(3) 4 d S T .
Ge1 Ge 0.06541(4) 0.0000 0.65348(10) 0.00776(14) Uani 1 2 d S T P
Ge2 Ge 0.21169(4) 0.0000 0.27628(10) 0.00821(14) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge2 Ce1 Ge1 84.92(2) . 7_556
Ge2 Ce1 Ge1 84.92(2) . 7_546
Ge1 Ce1 Ge1 91.36(3) 7_556 7_546
Ge2 Ce1 Ge2 105.77(2) . 7_545
Ge1 Ce1 Ge2 169.27(2) 7_556 7_545
Ge1 Ce1 Ge2 90.59(2) 7_546 7_545
Ge2 Ce1 Ge2 105.77(2) . 7
Ge1 Ce1 Ge2 90.59(2) 7_556 7
Ge1 Ce1 Ge2 169.27(2) 7_546 7
Ge2 Ce1 Ge2 85.59(3) 7_545 7
Ge2 Ce1 Ru 96.75(3) . 1_554
Ge1 Ce1 Ru 134.317(13) 7_556 1_554
Ge1 Ce1 Ru 134.317(13) 7_546 1_554
Ge2 Ce1 Ru 44.860(14) 7_545 1_554
Ge2 Ce1 Ru 44.860(14) 7 1_554
Ge2 Ce1 In 135.922(11) . 3
Ge1 Ce1 In 54.687(17) 7_556 3
Ge1 Ce1 In 110.21(2) 7_546 3
Ge2 Ce1 In 114.848(19) 7_545 3
Ge2 Ce1 In 62.824(16) 7 3
Ru Ce1 In 99.981(16) 1_554 3
Ge2 Ce1 In 135.922(12) . 3_545
Ge1 Ce1 In 110.21(2) 7_556 3_545
Ge1 Ce1 In 54.687(17) 7_546 3_545
Ge2 Ce1 In 62.824(16) 7_545 3_545
Ge2 Ce1 In 114.848(19) 7 3_545
Ru Ce1 In 99.981(16) 1_554 3_545
In Ce1 In 80.388(19) 3 3_545
Ge2 Ce1 Ru 43.488(12) . 7_556
Ge1 Ce1 Ru 44.378(19) 7_556 7_556
Ge1 Ce1 Ru 99.94(2) 7_546 7_556
Ge2 Ce1 Ru 145.27(2) 7_545 7_556
Ge2 Ce1 Ru 88.81(2) 7 7_556
Ru Ce1 Ru 112.439(18) 1_554 7_556
In Ce1 Ru 92.494(15) 3 7_556
In Ce1 Ru 147.560(14) 3_545 7_556
Ge2 Ce1 Ru 43.488(12) . 7_546
Ge1 Ce1 Ru 99.94(2) 7_556 7_546
Ge1 Ce1 Ru 44.378(19) 7_546 7_546
Ge2 Ce1 Ru 88.81(2) 7_545 7_546
Ge2 Ce1 Ru 145.27(2) 7 7_546
Ru Ce1 Ru 112.439(18) 1_554 7_546
In Ce1 Ru 147.560(14) 3 7_546
In Ce1 Ru 92.494(15) 3_545 7_546
Ru Ce1 Ru 76.65(2) 7_556 7_546
Ge2 Ce1 Ce2 151.021(18) . 5_655
Ge1 Ce1 Ce2 114.407(19) 7_556 5_655
Ge1 Ce1 Ce2 114.407(19) 7_546 5_655
Ge2 Ce1 Ce2 55.395(16) 7_545 5_655
Ge2 Ce1 Ce2 55.395(16) 7 5_655
Ru Ce1 Ce2 54.27(2) 1_554 5_655
In Ce1 Ce2 59.822(8) 3 5_655
In Ce1 Ce2 59.822(8) 3_545 5_655
Ru Ce1 Ce2 141.194(11) 7_556 5_655
Ru Ce1 Ce2 141.194(11) 7_546 5_655
Ge2 Ce1 Ce1 54.938(17) . 7_545
Ge1 Ce1 Ce1 139.85(2) 7_556 7_545
Ge1 Ce1 Ce1 86.415(18) 7_546 7_545
Ge2 Ce1 Ce1 50.828(15) 7_545 7_545
Ge2 Ce1 Ce1 98.83(2) 7 7_545
Ru Ce1 Ce1 59.459(14) 1_554 7_545
In Ce1 Ce1 159.410(17) 3 7_545
In Ce1 Ce1 100.968(19) 3_545 7_545
Ru Ce1 Ce1 96.58(2) 7_556 7_545
Ru Ce1 Ce1 52.979(14) 7_546 7_545
Ce2 Ce1 Ce1 102.807(16) 5_655 7_545
Ge1 Ce2 Ge1 91.79(3) 3 3_545
Ge1 Ce2 Ru 108.039(17) 3 5_656
Ge1 Ce2 Ru 108.039(17) 3_545 5_656
Ge1 Ce2 Ge2 81.69(2) 3 3
Ge1 Ce2 Ge2 147.48(2) 3_545 3
Ru Ce2 Ge2 46.132(13) 5_656 3
Ge1 Ce2 Ge2 147.48(2) 3 3_545
Ge1 Ce2 Ge2 81.69(2) 3_545 3_545
Ru Ce2 Ge2 46.132(13) 5_656 3_545
Ge2 Ce2 Ge2 86.91(3) 3 3_545
Ge1 Ce2 Ru 47.553(18) 3 3
Ge1 Ce2 Ru 107.77(2) 3_545 3
Ru Ce2 Ru 60.550(16) 5_656 3
Ge2 Ce2 Ru 46.116(19) 3 3
Ge2 Ce2 Ru 104.21(2) 3_545 3
Ge1 Ce2 Ru 107.77(2) 3 3_545
Ge1 Ce2 Ru 47.553(18) 3_545 3_545
Ru Ce2 Ru 60.550(16) 5_656 3_545
Ge2 Ce2 Ru 104.21(2) 3 3_545
Ge2 Ce2 Ru 46.12(2) 3_545 3_545
Ru Ce2 Ru 86.07(2) 3 3_545
Ge1 Ce2 Ge1 107.350(18) 3 7_546
Ge1 Ce2 Ge1 48.52(2) 3_545 7_546
Ru Ce2 Ge1 137.696(13) 5_656 7_546
Ge2 Ce2 Ge1 162.99(2) 3 7_546
Ge2 Ce2 Ge1 92.08(2) 3_545 7_546
Ru Ce2 Ge1 149.41(2) 3 7_546
Ru Ce2 Ge1 87.01(2) 3_545 7_546
Ge1 Ce2 Ge1 48.52(2) 3 7_556
Ge1 Ce2 Ge1 107.350(18) 3_545 7_556
Ru Ce2 Ge1 137.696(13) 5_656 7_556
Ge2 Ce2 Ge1 92.08(2) 3 7_556
Ge2 Ce2 Ge1 162.99(2) 3_545 7_556
Ru Ce2 Ge1 87.01(2) 3 7_556
Ru Ce2 Ge1 149.41(2) 3_545 7_556
Ge1 Ce2 Ge1 83.95(3) 7_546 7_556
Ge1 Ce2 In 149.899(19) 3 3_545
Ge1 Ce2 In 87.89(2) 3_545 3_545
Ru Ce2 In 100.619(13) 5_656 3_545
Ge2 Ce2 In 113.34(2) 3 3_545
Ge2 Ce2 In 62.118(18) 3_545 3_545
Ru Ce2 In 158.142(15) 3 3_545
Ru Ce2 In 94.066(17) 3_545 3_545
Ge1 Ce2 In 52.172(15) 7_546 3_545
Ge1 Ce2 In 103.109(19) 7_556 3_545
Ge1 Ce2 In 87.89(2) 3 3
Ge1 Ce2 In 149.899(19) 3_545 3
Ru Ce2 In 100.619(13) 5_656 3
Ge2 Ce2 In 62.118(18) 3 3
Ge2 Ce2 In 113.34(2) 3_545 3
Ru Ce2 In 94.066(17) 3 3
Ru Ce2 In 158.142(15) 3_545 3
Ge1 Ce2 In 103.109(19) 7_546 3
Ge1 Ce2 In 52.172(15) 7_556 3
In Ce2 In 77.809(19) 3_545 3
Ge1 Ce2 Ge2 77.90(2) 3 5_656
Ge1 Ce2 Ge2 77.90(2) 3_545 5_656
Ru Ce2 Ge2 43.94(2) 5_656 5_656
Ge2 Ce2 Ge2 69.58(2) 3 5_656
Ge2 Ce2 Ge2 69.58(2) 3_545 5_656
Ru Ce2 Ge2 43.170(11) 3 5_656
Ru Ce2 Ge2 43.170(11) 3_545 5_656
Ge1 Ce2 Ge2 125.788(18) 7_546 5_656
Ge1 Ce2 Ge2 125.788(18) 7_556 5_656
In Ce2 Ge2 131.099(12) 3_545 5_656
In Ce2 Ge2 131.099(12) 3 5_656
Ge2 Ru Ge2 124.07(4) 7_556 7_546
Ge2 Ru Ge2 100.01(2) 7_556 .
Ge2 Ru Ge2 100.01(2) 7_546 .
Ge2 Ru Ge1 111.04(2) 7_556 .
Ge2 Ru Ge1 111.04(2) 7_546 .
Ge2 Ru Ge1 108.30(3) . .
Ge2 Ru Ce2 67.795(19) 7_556 5_656
Ge2 Ru Ce2 67.79(2) 7_546 5_656
Ge2 Ru Ce2 75.45(2) . 5_656
Ge1 Ru Ce2 176.25(3) . 5_656
Ge2 Ru Ce2 159.84(2) 7_556 3_445
Ge2 Ru Ce2 74.52(2) 7_546 3_445
Ge2 Ru Ce2 66.421(17) . 3_445
Ge1 Ru Ce2 62.921(18) . 3_445
Ce2 Ru Ce2 119.450(16) 5_656 3_445
Ge2 Ru Ce2 74.52(2) 7_556 3_455
Ge2 Ru Ce2 159.84(2) 7_546 3_455
Ge2 Ru Ce2 66.421(17) . 3_455
Ge1 Ru Ce2 62.921(18) . 3_455
Ce2 Ru Ce2 119.450(16) 5_656 3_455
Ce2 Ru Ce2 86.07(2) 3_445 3_455
Ge2 Ru Ce1 66.494(19) 7_556 1_556
Ge2 Ru Ce1 66.494(19) 7_546 1_556
Ge2 Ru Ce1 143.48(3) . 1_556
Ge1 Ru Ce1 108.22(3) . 1_556
Ce2 Ru Ce1 68.023(18) 5_656 1_556
Ce2 Ru Ce1 133.277(12) 3_445 1_556
Ce2 Ru Ce1 133.277(12) 3_455 1_556
Ge2 Ru Ce1 57.93(2) 7_556 7_556
Ge2 Ru Ce1 124.37(3) 7_546 7_556
Ge2 Ru Ce1 135.614(15) . 7_556
Ge1 Ru Ce1 57.885(15) . 7_556
Ce2 Ru Ce1 119.520(14) 5_656 7_556
Ce2 Ru Ce1 120.74(2) 3_445 7_556
Ce2 Ru Ce1 70.408(18) 3_455 7_556
Ce1 Ru Ce1 67.561(18) 1_556 7_556
Ge2 Ru Ce1 124.37(3) 7_556 7_546
Ge2 Ru Ce1 57.93(2) 7_546 7_546
Ge2 Ru Ce1 135.614(15) . 7_546
Ge1 Ru Ce1 57.885(15) . 7_546
Ce2 Ru Ce1 119.520(14) 5_656 7_546
Ce2 Ru Ce1 70.408(18) 3_445 7_546
Ce2 Ru Ce1 120.74(2) 3_455 7_546
Ce1 Ru Ce1 67.561(18) 1_556 7_546
Ce1 Ru Ce1 76.65(2) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Ce1 56.968(11) 5_556 3_445
Ge1 In Ce1 123.032(11) 1_554 3_445
Ge1 In Ce1 123.032(11) 5_556 7
Ge1 In Ce1 56.968(11) 1_554 7
Ce1 In Ce1 180.0 3_445 7
Ge1 In Ce1 123.032(11) 5_556 7_545
Ge1 In Ce1 56.968(11) 1_554 7_545
Ce1 In Ce1 99.61(2) 3_445 7_545
Ce1 In Ce1 80.39(2) 7 7_545
Ge1 In Ce1 56.968(11) 5_556 3_455
Ge1 In Ce1 123.032(11) 1_554 3_455
Ce1 In Ce1 80.39(2) 3_445 3_455
Ce1 In Ce1 99.61(2) 7 3_455
Ce1 In Ce1 180.0 7_545 3_455
Ge1 In Ce2 60.236(16) 5_556 3_455
Ge1 In Ce2 119.764(16) 1_554 3_455
Ce1 In Ce2 117.091(14) 3_445 3_455
Ce1 In Ce2 62.909(14) 7 3_455
Ce1 In Ce2 110.806(14) 7_545 3_455
Ce1 In Ce2 69.194(14) 3_455 3_455
Ge1 In Ce2 119.764(16) 5_556 7_545
Ge1 In Ce2 60.236(16) 1_554 7_545
Ce1 In Ce2 62.909(14) 3_445 7_545
Ce1 In Ce2 117.091(14) 7 7_545
Ce1 In Ce2 69.194(14) 7_545 7_545
Ce1 In Ce2 110.806(14) 3_455 7_545
Ce2 In Ce2 180.0 3_455 7_545
Ge1 In Ce2 60.236(16) 5_556 3_445
Ge1 In Ce2 119.764(16) 1_554 3_445
Ce1 In Ce2 69.194(14) 3_445 3_445
Ce1 In Ce2 110.806(15) 7 3_445
Ce1 In Ce2 62.909(14) 7_545 3_445
Ce1 In Ce2 117.091(14) 3_455 3_445
Ce2 In Ce2 77.808(19) 3_455 3_445
Ce2 In Ce2 102.192(19) 7_545 3_445
Ge1 In Ce2 119.764(16) 5_556 7
Ge1 In Ce2 60.236(16) 1_554 7
Ce1 In Ce2 110.806(15) 3_445 7
Ce1 In Ce2 69.194(14) 7 7
Ce1 In Ce2 117.091(14) 7_545 7
Ce1 In Ce2 62.909(14) 3_455 7
Ce2 In Ce2 102.192(19) 3_455 7
Ce2 In Ce2 77.808(19) 7_545 7
Ce2 In Ce2 180.0 3_445 7
Ru Ge1 Ge1 120.77(4) . 5_556
Ru Ge1 In 130.42(3) . 1_556
Ge1 Ge1 In 108.81(4) 5_556 1_556
Ru Ge1 Ce2 69.525(17) . 3_445
Ge1 Ge1 Ce2 70.24(2) 5_556 3_445
In Ge1 Ce2 133.226(14) 1_556 3_445
Ru Ge1 Ce2 69.525(17) . 3_455
Ge1 Ge1 Ce2 70.24(2) 5_556 3_455
In Ge1 Ce2 133.226(14) 1_556 3_455
Ce2 Ge1 Ce2 91.79(3) 3_445 3_455
Ru Ge1 Ce1 77.74(2) . 7_556
Ge1 Ge1 Ce1 132.887(16) 5_556 7_556
In Ge1 Ce1 68.344(19) 1_556 7_556
Ce2 Ge1 Ce1 147.13(3) 3_445 7_556
Ce2 Ge1 Ce1 79.19(2) 3_455 7_556
Ru Ge1 Ce1 77.74(2) . 7_546
Ge1 Ge1 Ce1 132.887(16) 5_556 7_546
In Ge1 Ce1 68.344(19) 1_556 7_546
Ce2 Ge1 Ce1 79.19(2) 3_445 7_546
Ce2 Ge1 Ce1 147.13(3) 3_455 7_546
Ce1 Ge1 Ce1 91.36(3) 7_556 7_546
Ru Ge1 Ce2 137.144(14) . 7_546
Ge1 Ge1 Ce2 61.24(2) 5_556 7_546
In Ge1 Ce2 67.592(16) 1_556 7_546
Ce2 Ge1 Ce2 72.651(18) 3_445 7_546
Ce2 Ge1 Ce2 131.48(2) 3_455 7_546
Ce1 Ge1 Ce2 135.76(3) 7_556 7_546
Ce1 Ge1 Ce2 76.080(18) 7_546 7_546
Ru Ge1 Ce2 137.144(14) . 7_556
Ge1 Ge1 Ce2 61.24(2) 5_556 7_556
In Ge1 Ce2 67.592(16) 1_556 7_556
Ce2 Ge1 Ce2 131.48(2) 3_445 7_556
Ce2 Ge1 Ce2 72.651(17) 3_455 7_556
Ce1 Ge1 Ce2 76.080(18) 7_556 7_556
Ce1 Ge1 Ce2 135.76(3) 7_546 7_556
Ce2 Ge1 Ce2 83.95(3) 7_546 7_556
Ru Ge2 Ru 124.07(4) 7_556 7_546
Ru Ge2 Ru 79.99(2) 7_556 .
Ru Ge2 Ru 79.99(2) 7_546 .
Ru Ge2 Ce1 78.58(2) 7_556 .
Ru Ge2 Ce1 78.58(2) 7_546 .
Ru Ge2 Ce1 133.28(3) . .
Ru Ge2 Ce2 144.04(3) 7_556 3_445
Ru Ge2 Ce2 66.07(2) 7_546 3_445
Ru Ge2 Ce2 67.464(17) . 3_445
Ce1 Ge2 Ce2 135.364(14) . 3_445
Ru Ge2 Ce2 66.07(2) 7_556 3_455
Ru Ge2 Ce2 144.04(3) 7_546 3_455
Ru Ge2 Ce2 67.464(17) . 3_455
Ce1 Ge2 Ce2 135.364(14) . 3_455
Ce2 Ge2 Ce2 86.91(3) 3_445 3_455
Ru Ge2 Ce1 146.72(3) 7_556 7_545
Ru Ge2 Ce1 68.646(19) 7_546 7_545
Ru Ge2 Ce1 133.041(17) . 7_545
Ce1 Ge2 Ce1 74.23(2) . 7_545
Ce2 Ge2 Ce1 68.175(18) 3_445 7_545
Ce2 Ge2 Ce1 124.25(3) 3_455 7_545
Ru Ge2 Ce1 68.646(19) 7_556 7
Ru Ge2 Ce1 146.72(3) 7_546 7
Ru Ge2 Ce1 133.041(17) . 7
Ce1 Ge2 Ce1 74.23(2) . 7
Ce2 Ge2 Ce1 124.25(3) 3_445 7
Ce2 Ge2 Ce1 68.175(17) 3_455 7
Ce1 Ge2 Ce1 85.59(3) 7_545 7
Ru Ge2 Ce2 62.306(19) 7_556 5_656
Ru Ge2 Ce2 62.306(19) 7_546 5_656
Ru Ge2 Ce2 60.60(2) . 5_656
Ce1 Ge2 Ce2 72.68(3) . 5_656
Ce2 Ge2 Ce2 110.42(2) 3_445 5_656
Ce2 Ge2 Ce2 110.42(2) 3_455 5_656
Ce1 Ge2 Ce2 124.733(18) 7_545 5_656
Ce1 Ge2 Ce2 124.733(18) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 Ge2 3.0527(10) .
Ce1 Ge1 3.0605(7) 7_556
Ce1 Ge1 3.0605(7) 7_546
Ce1 Ge2 3.2230(8) 7_545
Ce1 Ge2 3.2230(8) 7
Ce1 Ru 3.2734(9) 1_554
Ce1 In 3.3929(6) 3
Ce1 In 3.3929(6) 3_545
Ce1 Ru 3.5311(7) 7_556
Ce1 Ru 3.5311(7) 7_546
Ce1 Ce2 3.5908(9) 5_655
Ce1 Ce1 3.7894(9) 7_545
Ce2 Ge1 3.0495(7) 3
Ce2 Ge1 3.0495(7) 3_545
Ce2 Ru 3.1433(9) 5_656
Ce2 Ge2 3.1838(7) 3
Ce2 Ge2 3.1838(7) 3_545
Ce2 Ru 3.2085(6) 3
Ce2 Ru 3.2085(6) 3_545
Ce2 Ge1 3.2739(8) 7_546
Ce2 Ge1 3.2739(8) 7_556
Ce2 In 3.4867(6) 3_545
Ce2 In 3.4867(6) 3
Ce2 Ge2 3.4922(10) 5_656
Ru Ge2 2.4792(6) 7_556
Ru Ge2 2.4792(6) 7_546
Ru Ge2 2.5037(11) .
Ru Ge1 2.5273(10) .
Ru Ce2 3.1433(9) 5_656
Ru Ce2 3.2085(6) 3_445
Ru Ce2 3.2085(6) 3_455
Ru Ce1 3.2734(9) 1_556
Ru Ce1 3.5310(7) 7_556
Ru Ce1 3.5310(7) 7_546
In Ge1 2.9789(9) 5_556
In Ge1 2.9789(9) 1_554
In Ce1 3.3929(6) 3_445
In Ce1 3.3929(6) 7
In Ce1 3.3929(6) 7_545
In Ce1 3.3929(6) 3_455
In Ce2 3.4867(6) 3_455
In Ce2 3.4867(6) 7_545
In Ce2 3.4867(6) 3_445
In Ce2 3.4867(6) 7
Ge1 Ge1 2.6063(14) 5_556
Ge1 In 2.9789(9) 1_556
Ge1 Ce2 3.0494(7) 3_445
Ge1 Ce2 3.0494(7) 3_455
Ge1 Ce1 3.0606(7) 7_556
Ge1 Ce1 3.0606(7) 7_546
Ge1 Ce2 3.2739(8) 7_546
Ge1 Ce2 3.2739(8) 7_556
Ge2 Ru 2.4792(6) 7_556
Ge2 Ru 2.4792(6) 7_546
Ge2 Ce2 3.1837(7) 3_445
Ge2 Ce2 3.1837(7) 3_455
Ge2 Ce1 3.2230(8) 7_545
Ge2 Ce1 3.2230(8) 7
Ge2 Ce2 3.4922(10) 5_656
