#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342572.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342572
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Pr4 Ru2 In Ge4'
_chemical_formula_sum            'Ge4 In Pr4 Ru2'
_chemical_formula_weight         1170.96
_chemical_name_common
'praseodymium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'praseodymium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.254(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.083(5)
_cell_length_b                   4.3605(13)
_cell_length_c                   7.190(2)
_cell_measurement_reflns_used    806
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.27
_cell_measurement_theta_min      6.13
_cell_volume                     484.1(2)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0609
_diffrn_reflns_av_unetI/netI     0.0513
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            3430
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.075
_diffrn_reflns_theta_min         2.638
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    37.195
_exptl_absorpt_correction_T_max  0.6326
_exptl_absorpt_correction_T_min  0.0590
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.033
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1002
_exptl_crystal_size_max          0.118
_exptl_crystal_size_mid          0.026
_exptl_crystal_size_min          0.020
_refine_diff_density_max         3.714
_refine_diff_density_min         -2.322
_refine_diff_density_rms         0.646
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     36
_refine_ls_number_reflns         996
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0510
_refine_ls_R_factor_gt           0.0349
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0388P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0749
_refine_ls_wR_factor_ref         0.0812
_reflns_Friedel_coverage         0.000
_reflns_number_gt                783
_reflns_number_total             996
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Pr4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342572
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.097
_shelx_estimated_absorpt_t_max   0.523
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pr1 Pr 0.34947(4) 0.0000 0.06241(9) 0.00806(15) Uani 1 2 d S T P
Pr2 Pr 0.58830(4) 0.0000 0.38007(9) 0.00748(15) Uani 1 2 d S T P
Ru Ru 0.21833(5) 0.0000 0.62714(13) 0.00719(19) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0095(3) Uani 0.959(5) 4 d S T .
Ge1 Ge 0.06523(7) 0.0000 0.65444(18) 0.0079(2) Uani 1 2 d S T P
Ge2 Ge 0.21014(8) 0.0000 0.27471(18) 0.0087(2) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Pr1 Ge1 91.80(4) 7_556 7_546
Ge1 Pr1 Ge2 85.51(4) 7_556 .
Ge1 Pr1 Ge2 85.51(4) 7_546 .
Ge1 Pr1 Ge2 168.59(4) 7_556 7_545
Ge1 Pr1 Ge2 90.11(3) 7_546 7_545
Ge2 Pr1 Ge2 105.86(3) . 7_545
Ge1 Pr1 Ge2 90.11(3) 7_556 7
Ge1 Pr1 Ge2 168.59(4) 7_546 7
Ge2 Pr1 Ge2 105.86(3) . 7
Ge2 Pr1 Ge2 85.86(4) 7_545 7
Ge1 Pr1 Ru 134.10(2) 7_556 1_554
Ge1 Pr1 Ru 134.10(2) 7_546 1_554
Ge2 Pr1 Ru 96.46(4) . 1_554
Ge2 Pr1 Ru 45.11(2) 7_545 1_554
Ge2 Pr1 Ru 45.11(2) 7 1_554
Ge1 Pr1 In 54.53(3) 7_556 3
Ge1 Pr1 In 110.26(3) 7_546 3
Ge2 Pr1 In 136.199(17) . 3
Ge2 Pr1 In 114.37(3) 7_545 3
Ge2 Pr1 In 62.22(3) 7 3
Ru Pr1 In 99.68(2) 1_554 3
Ge1 Pr1 In 110.26(3) 7_556 3_545
Ge1 Pr1 In 54.53(3) 7_546 3_545
Ge2 Pr1 In 136.199(17) . 3_545
Ge2 Pr1 In 62.22(3) 7_545 3_545
Ge2 Pr1 In 114.37(3) 7 3_545
Ru Pr1 In 99.68(2) 1_554 3_545
In Pr1 In 80.34(3) 3 3_545
Ge1 Pr1 Ru 44.69(3) 7_556 7_556
Ge1 Pr1 Ru 100.51(4) 7_546 7_556
Ge2 Pr1 Ru 43.683(19) . 7_556
Ge2 Pr1 Ru 145.61(3) 7_545 7_556
Ge2 Pr1 Ru 88.74(3) 7 7_556
Ru Pr1 Ru 112.32(3) 1_554 7_556
In Pr1 Ru 92.60(2) 3 7_556
In Pr1 Ru 147.97(3) 3_545 7_556
Ge1 Pr1 Ru 100.51(4) 7_556 7_546
Ge1 Pr1 Ru 44.69(3) 7_546 7_546
Ge2 Pr1 Ru 43.683(19) . 7_546
Ge2 Pr1 Ru 88.74(3) 7_545 7_546
Ge2 Pr1 Ru 145.61(3) 7 7_546
Ru Pr1 Ru 112.32(3) 1_554 7_546
In Pr1 Ru 147.97(3) 3 7_546
In Pr1 Ru 92.60(2) 3_545 7_546
Ru Pr1 Ru 76.92(3) 7_556 7_546
Ge1 Pr1 Pr2 114.10(3) 7_556 5_655
Ge1 Pr1 Pr2 114.10(3) 7_546 5_655
Ge2 Pr1 Pr2 150.54(3) . 5_655
Ge2 Pr1 Pr2 55.11(3) 7_545 5_655
Ge2 Pr1 Pr2 55.11(3) 7 5_655
Ru Pr1 Pr2 54.08(3) 1_554 5_655
In Pr1 Pr2 59.668(13) 3 5_655
In Pr1 Pr2 59.668(13) 3_545 5_655
Ru Pr1 Pr2 141.019(16) 7_556 5_655
Ru Pr1 Pr2 141.019(16) 7_546 5_655
Ge1 Pr1 Pr1 140.33(4) 7_556 7_545
Ge1 Pr1 Pr1 86.47(3) 7_546 7_545
Ge2 Pr1 Pr1 54.83(3) . 7_545
Ge2 Pr1 Pr1 51.02(3) 7_545 7_545
Ge2 Pr1 Pr1 99.18(3) 7 7_545
Ru Pr1 Pr1 59.42(2) 1_554 7_545
In Pr1 Pr1 159.06(3) 3 7_545
In Pr1 Pr1 100.79(2) 3_545 7_545
Ru Pr1 Pr1 96.71(3) 7_556 7_545
Ru Pr1 Pr1 52.90(2) 7_546 7_545
Pr2 Pr1 Pr1 102.57(3) 5_655 7_545
Ge1 Pr2 Ge1 91.96(4) 3 3_545
Ge1 Pr2 Ru 108.32(3) 3 5_656
Ge1 Pr2 Ru 108.32(3) 3_545 5_656
Ge1 Pr2 Ge2 81.78(3) 3 3
Ge1 Pr2 Ge2 148.06(4) 3_545 3
Ru Pr2 Ge2 46.34(2) 5_656 3
Ge1 Pr2 Ge2 148.06(4) 3 3_545
Ge1 Pr2 Ge2 81.78(3) 3_545 3_545
Ru Pr2 Ge2 46.34(2) 5_656 3_545
Ge2 Pr2 Ge2 87.18(4) 3 3_545
Ge1 Pr2 Ru 47.75(3) 3 3
Ge1 Pr2 Ru 108.01(4) 3_545 3
Ru Pr2 Ru 60.63(3) 5_656 3
Ge2 Pr2 Ru 46.33(3) 3 3
Ge2 Pr2 Ru 104.52(4) 3_545 3
Ge1 Pr2 Ru 108.01(4) 3 3_545
Ge1 Pr2 Ru 47.75(3) 3_545 3_545
Ru Pr2 Ru 60.63(3) 5_656 3_545
Ge2 Pr2 Ru 104.52(4) 3 3_545
Ge2 Pr2 Ru 46.33(3) 3_545 3_545
Ru Pr2 Ru 86.09(3) 3 3_545
Ge1 Pr2 Ge1 107.65(3) 3 7_546
Ge1 Pr2 Ge1 48.61(4) 3_545 7_546
Ru Pr2 Ge1 137.47(2) 5_656 7_546
Ge2 Pr2 Ge1 162.27(4) 3 7_546
Ge2 Pr2 Ge1 91.59(3) 3_545 7_546
Ru Pr2 Ge1 149.91(3) 3 7_546
Ru Pr2 Ge1 87.12(3) 3_545 7_546
Ge1 Pr2 Ge1 48.61(4) 3 7_556
Ge1 Pr2 Ge1 107.65(3) 3_545 7_556
Ru Pr2 Ge1 137.47(2) 5_656 7_556
Ge2 Pr2 Ge1 91.59(3) 3 7_556
Ge2 Pr2 Ge1 162.27(4) 3_545 7_556
Ru Pr2 Ge1 87.12(3) 3 7_556
Ru Pr2 Ge1 149.91(3) 3_545 7_556
Ge1 Pr2 Ge1 84.23(4) 7_546 7_556
Ge1 Pr2 In 149.96(3) 3 3_545
Ge1 Pr2 In 87.88(3) 3_545 3_545
Ru Pr2 In 100.17(2) 5_656 3_545
Ge2 Pr2 In 112.87(3) 3 3_545
Ge2 Pr2 In 61.51(3) 3_545 3_545
Ru Pr2 In 157.79(3) 3 3_545
Ru Pr2 In 93.96(2) 3_545 3_545
Ge1 Pr2 In 52.01(2) 7_546 3_545
Ge1 Pr2 In 103.08(3) 7_556 3_545
Ge1 Pr2 In 87.88(3) 3 3
Ge1 Pr2 In 149.96(3) 3_545 3
Ru Pr2 In 100.17(2) 5_656 3
Ge2 Pr2 In 61.51(3) 3 3
Ge2 Pr2 In 112.87(3) 3_545 3
Ru Pr2 In 93.96(2) 3 3
Ru Pr2 In 157.79(3) 3_545 3
Ge1 Pr2 In 103.08(3) 7_546 3
Ge1 Pr2 In 52.01(2) 7_556 3
In Pr2 In 77.76(3) 3_545 3
Ge1 Pr2 Ge2 78.20(3) 3 5_656
Ge1 Pr2 Ge2 78.20(3) 3_545 5_656
Ru Pr2 Ge2 44.01(3) 5_656 5_656
Ge2 Pr2 Ge2 69.86(4) 3 5_656
Ge2 Pr2 Ge2 69.86(4) 3_545 5_656
Ru Pr2 Ge2 43.181(17) 3 5_656
Ru Pr2 Ge2 43.181(17) 3_545 5_656
Ge1 Pr2 Ge2 126.09(3) 7_546 5_656
Ge1 Pr2 Ge2 126.09(3) 7_556 5_656
In Pr2 Ge2 130.826(19) 3_545 5_656
In Pr2 Ge2 130.826(19) 3 5_656
Ge2 Ru Ge2 123.59(6) 7_556 7_546
Ge2 Ru Ge2 100.22(4) 7_556 .
Ge2 Ru Ge2 100.22(4) 7_546 .
Ge2 Ru Ge1 111.33(4) 7_556 .
Ge2 Ru Ge1 111.33(4) 7_546 .
Ge2 Ru Ge1 107.63(5) . .
Ge2 Ru Pr2 67.62(3) 7_556 5_656
Ge2 Ru Pr2 67.62(3) 7_546 5_656
Ge2 Ru Pr2 75.73(4) . 5_656
Ge1 Ru Pr2 176.63(5) . 5_656
Ge2 Ru Pr2 160.05(4) 7_556 3_445
Ge2 Ru Pr2 74.75(3) 7_546 3_445
Ge2 Ru Pr2 66.16(3) . 3_445
Ge1 Ru Pr2 62.76(3) . 3_445
Pr2 Ru Pr2 119.37(3) 5_656 3_445
Ge2 Ru Pr2 74.75(3) 7_556 3_455
Ge2 Ru Pr2 160.05(4) 7_546 3_455
Ge2 Ru Pr2 66.16(3) . 3_455
Ge1 Ru Pr2 62.76(3) . 3_455
Pr2 Ru Pr2 119.37(3) 5_656 3_455
Pr2 Ru Pr2 86.09(3) 3_445 3_455
Ge2 Ru Pr1 66.45(3) 7_556 1_556
Ge2 Ru Pr1 66.45(3) 7_546 1_556
Ge2 Ru Pr1 144.33(5) . 1_556
Ge1 Ru Pr1 108.03(4) . 1_556
Pr2 Ru Pr1 68.60(3) 5_656 1_556
Pr2 Ru Pr1 133.11(2) 3_445 1_556
Pr2 Ru Pr1 133.11(2) 3_455 1_556
Ge2 Ru Pr1 58.19(3) 7_556 7_556
Ge2 Ru Pr1 124.69(5) 7_546 7_556
Ge2 Ru Pr1 135.06(3) . 7_556
Ge1 Ru Pr1 57.75(3) . 7_556
Pr2 Ru Pr1 119.93(2) 5_656 7_556
Pr2 Ru Pr1 120.45(3) 3_445 7_556
Pr2 Ru Pr1 69.98(3) 3_455 7_556
Pr1 Ru Pr1 67.68(3) 1_556 7_556
Ge2 Ru Pr1 124.69(5) 7_556 7_546
Ge2 Ru Pr1 58.19(3) 7_546 7_546
Ge2 Ru Pr1 135.06(3) . 7_546
Ge1 Ru Pr1 57.75(3) . 7_546
Pr2 Ru Pr1 119.93(2) 5_656 7_546
Pr2 Ru Pr1 69.98(3) 3_445 7_546
Pr2 Ru Pr1 120.45(3) 3_455 7_546
Pr1 Ru Pr1 67.68(3) 1_556 7_546
Pr1 Ru Pr1 76.92(3) 7_556 7_546
Ge1 In Ge1 180.00(4) 5_556 1_554
Ge1 In Pr1 56.793(19) 5_556 3_445
Ge1 In Pr1 123.207(19) 1_554 3_445
Ge1 In Pr1 123.207(19) 5_556 7
Ge1 In Pr1 56.793(19) 1_554 7
Pr1 In Pr1 180.000(14) 3_445 7
Ge1 In Pr1 123.207(19) 5_556 7_545
Ge1 In Pr1 56.793(19) 1_554 7_545
Pr1 In Pr1 99.66(3) 3_445 7_545
Pr1 In Pr1 80.34(3) 7 7_545
Ge1 In Pr1 56.793(19) 5_556 3_455
Ge1 In Pr1 123.207(19) 1_554 3_455
Pr1 In Pr1 80.34(3) 3_445 3_455
Pr1 In Pr1 99.66(3) 7 3_455
Pr1 In Pr1 180.000(14) 7_545 3_455
Ge1 In Pr2 60.12(2) 5_556 3_455
Ge1 In Pr2 119.88(2) 1_554 3_455
Pr1 In Pr2 116.79(2) 3_445 3_455
Pr1 In Pr2 63.21(2) 7 3_455
Pr1 In Pr2 111.04(2) 7_545 3_455
Pr1 In Pr2 68.96(2) 3_455 3_455
Ge1 In Pr2 119.88(2) 5_556 7_545
Ge1 In Pr2 60.12(2) 1_554 7_545
Pr1 In Pr2 63.21(2) 3_445 7_545
Pr1 In Pr2 116.79(2) 7 7_545
Pr1 In Pr2 68.96(2) 7_545 7_545
Pr1 In Pr2 111.04(2) 3_455 7_545
Pr2 In Pr2 180.000(16) 3_455 7_545
Ge1 In Pr2 60.12(2) 5_556 3_445
Ge1 In Pr2 119.88(2) 1_554 3_445
Pr1 In Pr2 68.96(2) 3_445 3_445
Pr1 In Pr2 111.04(2) 7 3_445
Pr1 In Pr2 63.21(2) 7_545 3_445
Pr1 In Pr2 116.79(2) 3_455 3_445
Pr2 In Pr2 77.76(3) 3_455 3_445
Pr2 In Pr2 102.24(3) 7_545 3_445
Ge1 In Pr2 119.88(2) 5_556 7
Ge1 In Pr2 60.12(2) 1_554 7
Pr1 In Pr2 111.04(2) 3_445 7
Pr1 In Pr2 68.96(2) 7 7
Pr1 In Pr2 116.79(2) 7_545 7
Pr1 In Pr2 63.21(2) 3_455 7
Pr2 In Pr2 102.24(3) 3_455 7
Pr2 In Pr2 77.76(3) 7_545 7
Pr2 In Pr2 180.0 3_445 7
Ru Ge1 Ge1 120.42(8) . 5_556
Ru Ge1 In 130.46(5) . 1_556
Ge1 Ge1 In 109.12(7) 5_556 1_556
Ru Ge1 Pr2 69.50(3) . 3_445
Ge1 Ge1 Pr2 70.11(4) 5_556 3_445
In Ge1 Pr2 133.15(2) 1_556 3_445
Ru Ge1 Pr2 69.49(3) . 3_455
Ge1 Ge1 Pr2 70.11(4) 5_556 3_455
In Ge1 Pr2 133.15(2) 1_556 3_455
Pr2 Ge1 Pr2 91.96(4) 3_445 3_455
Ru Ge1 Pr1 77.56(3) . 7_556
Ge1 Ge1 Pr1 132.82(2) 5_556 7_556
In Ge1 Pr1 68.67(3) 1_556 7_556
Pr2 Ge1 Pr1 146.94(5) 3_445 7_556
Pr2 Ge1 Pr1 78.77(3) 3_455 7_556
Ru Ge1 Pr1 77.56(3) . 7_546
Ge1 Ge1 Pr1 132.82(3) 5_556 7_546
In Ge1 Pr1 68.67(3) 1_556 7_546
Pr2 Ge1 Pr1 78.77(3) 3_445 7_546
Pr2 Ge1 Pr1 146.94(5) 3_455 7_546
Pr1 Ge1 Pr1 91.80(4) 7_556 7_546
Ru Ge1 Pr2 136.94(2) . 7_546
Ge1 Ge1 Pr2 61.28(4) 5_556 7_546
In Ge1 Pr2 67.88(3) 1_556 7_546
Pr2 Ge1 Pr2 72.35(3) 3_445 7_546
Pr2 Ge1 Pr2 131.40(4) 3_455 7_546
Pr1 Ge1 Pr2 136.37(5) 7_556 7_546
Pr1 Ge1 Pr2 76.15(3) 7_546 7_546
Ru Ge1 Pr2 136.94(2) . 7_556
Ge1 Ge1 Pr2 61.28(4) 5_556 7_556
In Ge1 Pr2 67.88(3) 1_556 7_556
Pr2 Ge1 Pr2 131.40(4) 3_445 7_556
Pr2 Ge1 Pr2 72.35(3) 3_455 7_556
Pr1 Ge1 Pr2 76.15(3) 7_556 7_556
Pr1 Ge1 Pr2 136.37(5) 7_546 7_556
Pr2 Ge1 Pr2 84.23(4) 7_546 7_556
Ru Ge2 Ru 123.59(6) 7_556 7_546
Ru Ge2 Ru 79.78(4) 7_556 .
Ru Ge2 Ru 79.78(4) 7_546 .
Ru Ge2 Pr1 78.12(4) 7_556 .
Ru Ge2 Pr1 78.12(4) 7_546 .
Ru Ge2 Pr1 132.13(5) . .
Ru Ge2 Pr2 144.02(5) 7_556 3_445
Ru Ge2 Pr2 66.04(3) 7_546 3_445
Ru Ge2 Pr2 67.52(3) . 3_445
Pr1 Ge2 Pr2 135.45(2) . 3_445
Ru Ge2 Pr2 66.04(3) 7_556 3_455
Ru Ge2 Pr2 144.02(5) 7_546 3_455
Ru Ge2 Pr2 67.52(3) . 3_455
Pr1 Ge2 Pr2 135.45(2) . 3_455
Pr2 Ge2 Pr2 87.19(4) 3_445 3_455
Ru Ge2 Pr1 146.41(5) 7_556 7_545
Ru Ge2 Pr1 68.44(3) 7_546 7_545
Ru Ge2 Pr1 133.40(3) . 7_545
Pr1 Ge2 Pr1 74.14(3) . 7_545
Pr2 Ge2 Pr1 68.74(3) 3_445 7_545
Pr2 Ge2 Pr1 125.22(4) 3_455 7_545
Ru Ge2 Pr1 68.44(3) 7_556 7
Ru Ge2 Pr1 146.41(5) 7_546 7
Ru Ge2 Pr1 133.40(3) . 7
Pr1 Ge2 Pr1 74.14(3) . 7
Pr2 Ge2 Pr1 125.22(4) 3_445 7
Pr2 Ge2 Pr1 68.74(3) 3_455 7
Pr1 Ge2 Pr1 85.86(4) 7_545 7
Ru Ge2 Pr2 62.07(3) 7_556 5_656
Ru Ge2 Pr2 62.07(3) 7_546 5_656
Ru Ge2 Pr2 60.26(4) . 5_656
Pr1 Ge2 Pr2 71.87(4) . 5_656
Pr2 Ge2 Pr2 110.14(4) 3_445 5_656
Pr2 Ge2 Pr2 110.14(4) 3_455 5_656
Pr1 Ge2 Pr2 124.09(3) 7_545 5_656
Pr1 Ge2 Pr2 124.09(3) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pr1 Ge1 3.0360(11) 7_556
Pr1 Ge1 3.0360(11) 7_546
Pr1 Ge2 3.0441(15) .
Pr1 Ge2 3.2011(12) 7_545
Pr1 Ge2 3.2011(12) 7
Pr1 Ru 3.2477(13) 1_554
Pr1 In 3.3800(8) 3
Pr1 In 3.3800(8) 3_545
Pr1 Ru 3.5054(11) 7_556
Pr1 Ru 3.5054(11) 7_546
Pr1 Pr2 3.5925(13) 5_655
Pr1 Pr1 3.7667(13) 7_545
Pr2 Ge1 3.0319(12) 3
Pr2 Ge1 3.0319(11) 3_545
Pr2 Ru 3.1249(14) 5_656
Pr2 Ge2 3.1620(11) 3
Pr2 Ge2 3.1620(11) 3_545
Pr2 Ru 3.1942(10) 3
Pr2 Ru 3.1942(10) 3_545
Pr2 Ge1 3.2511(11) 7_546
Pr2 Ge1 3.2511(12) 7_556
Pr2 In 3.4736(8) 3_545
Pr2 In 3.4736(8) 3
Pr2 Ge2 3.4880(16) 5_656
Ru Ge2 2.4740(9) 7_556
Ru Ge2 2.4740(9) 7_546
Ru Ge2 2.5004(17) .
Ru Ge1 2.5243(16) .
Ru Pr2 3.1249(14) 5_656
Ru Pr2 3.1942(10) 3_445
Ru Pr2 3.1942(10) 3_455
Ru Pr1 3.2477(13) 1_556
Ru Pr1 3.5053(11) 7_556
Ru Pr1 3.5053(11) 7_546
In Ge1 2.9552(14) 5_556
In Ge1 2.9552(14) 1_554
In Pr1 3.3800(8) 3_445
In Pr1 3.3800(8) 7
In Pr1 3.3800(8) 7_545
In Pr1 3.3800(8) 3_455
In Pr2 3.4736(8) 3_455
In Pr2 3.4736(8) 7_545
In Pr2 3.4736(8) 3_445
In Pr2 3.4736(8) 7
Ge1 Ge1 2.594(2) 5_556
Ge1 In 2.9552(14) 1_556
Ge1 Pr2 3.0319(11) 3_445
Ge1 Pr2 3.0319(11) 3_455
Ge1 Pr1 3.0360(11) 7_556
Ge1 Pr1 3.0360(11) 7_546
Ge1 Pr2 3.2511(12) 7_546
Ge1 Pr2 3.2511(12) 7_556
Ge2 Ru 2.4740(9) 7_556
Ge2 Ru 2.4740(9) 7_546
Ge2 Pr2 3.1619(11) 3_445
Ge2 Pr2 3.1619(11) 3_455
Ge2 Pr1 3.2011(12) 7_545
Ge2 Pr1 3.2011(12) 7
Ge2 Pr2 3.4879(16) 5_656
