#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342573.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342573
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Nd4 Ru2 In Ge4'
_chemical_formula_sum            'Ge4 In Nd4 Ru2'
_chemical_formula_weight         1184.28
_chemical_name_common
'neodymium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'neodymium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.353(5)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.014(6)
_cell_length_b                   4.3463(16)
_cell_length_c                   7.160(3)
_cell_measurement_reflns_used    1854
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.17
_cell_measurement_theta_min      2.96
_cell_volume                     478.2(3)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0384
_diffrn_reflns_av_unetI/netI     0.0338
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3457
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.226
_diffrn_reflns_theta_min         2.651
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    38.991
_exptl_absorpt_correction_T_max  0.5830
_exptl_absorpt_correction_T_min  0.1094
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.225
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1010
_exptl_crystal_size_max          0.092
_exptl_crystal_size_mid          0.021
_exptl_crystal_size_min          0.021
_refine_diff_density_max         2.299
_refine_diff_density_min         -2.258
_refine_diff_density_rms         0.432
_refine_ls_extinction_coef       0.00086(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         994
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0350
_refine_ls_R_factor_gt           0.0244
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0247P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0498
_refine_ls_wR_factor_ref         0.0529
_reflns_Friedel_coverage         0.000
_reflns_number_gt                833
_reflns_number_total             994
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Nd4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342573
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.124
_shelx_estimated_absorpt_t_max   0.495
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Nd1 Nd 0.34959(3) 0.0000 0.06348(6) 0.00763(10) Uani 1 2 d S T P
Nd2 Nd 0.58818(3) 0.0000 0.38076(6) 0.00719(10) Uani 1 2 d S T P
Ru Ru 0.21848(4) 0.0000 0.62778(9) 0.00664(13) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0088(2) Uani 0.954(3) 4 d S T .
Ge1 Ge 0.06505(5) 0.0000 0.65481(12) 0.00723(16) Uani 1 2 d S T P
Ge2 Ge 0.20896(5) 0.0000 0.27264(12) 0.00785(16) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Nd1 Ge1 92.13(4) 7_556 7_546
Ge1 Nd1 Ge2 85.96(3) 7_556 .
Ge1 Nd1 Ge2 85.96(3) 7_546 .
Ge1 Nd1 Ge2 168.23(3) 7_556 7_545
Ge1 Nd1 Ge2 89.73(3) 7_546 7_545
Ge2 Nd1 Ge2 105.76(3) . 7_545
Ge1 Nd1 Ge2 89.73(3) 7_556 7
Ge1 Nd1 Ge2 168.23(3) 7_546 7
Ge2 Nd1 Ge2 105.76(3) . 7
Ge2 Nd1 Ge2 86.16(4) 7_545 7
Ge1 Nd1 Ru 133.937(18) 7_556 1_554
Ge1 Nd1 Ru 133.937(18) 7_546 1_554
Ge2 Nd1 Ru 96.06(3) . 1_554
Ge2 Nd1 Ru 45.340(19) 7_545 1_554
Ge2 Nd1 Ru 45.340(19) 7 1_554
Ge1 Nd1 In 54.49(2) 7_556 3
Ge1 Nd1 In 110.38(3) 7_546 3
Ge2 Nd1 In 136.436(16) . 3
Ge2 Nd1 In 114.09(2) 7_545 3
Ge2 Nd1 In 61.76(2) 7 3
Ru Nd1 In 99.47(2) 1_554 3
Ge1 Nd1 In 110.38(3) 7_556 3_545
Ge1 Nd1 In 54.49(2) 7_546 3_545
Ge2 Nd1 In 136.436(16) . 3_545
Ge2 Nd1 In 61.76(2) 7_545 3_545
Ge2 Nd1 In 114.09(2) 7 3_545
Ru Nd1 In 99.47(2) 1_554 3_545
In Nd1 In 80.35(3) 3 3_545
Ge1 Nd1 Ru 44.84(2) 7_556 7_556
Ge1 Nd1 Ru 100.88(3) 7_546 7_556
Ge2 Nd1 Ru 43.889(16) . 7_556
Ge2 Nd1 Ru 145.82(3) 7_545 7_556
Ge2 Nd1 Ru 88.61(3) 7 7_556
Ru Nd1 Ru 112.20(3) 1_554 7_556
In Nd1 Ru 92.67(2) 3 7_556
In Nd1 Ru 148.296(17) 3_545 7_556
Ge1 Nd1 Ru 100.88(3) 7_556 7_546
Ge1 Nd1 Ru 44.84(2) 7_546 7_546
Ge2 Nd1 Ru 43.889(15) . 7_546
Ge2 Nd1 Ru 88.61(3) 7_545 7_546
Ge2 Nd1 Ru 145.82(3) 7 7_546
Ru Nd1 Ru 112.20(3) 1_554 7_546
In Nd1 Ru 148.296(17) 3 7_546
In Nd1 Ru 92.67(2) 3_545 7_546
Ru Nd1 Ru 77.12(3) 7_556 7_546
Ge1 Nd1 Nd2 113.93(3) 7_556 5_655
Ge1 Nd1 Nd2 113.93(2) 7_546 5_655
Ge2 Nd1 Nd2 150.05(2) . 5_655
Ge2 Nd1 Nd2 54.98(2) 7_545 5_655
Ge2 Nd1 Nd2 54.98(2) 7 5_655
Ru Nd1 Nd2 53.99(3) 1_554 5_655
In Nd1 Nd2 59.546(11) 3 5_655
In Nd1 Nd2 59.546(11) 3_545 5_655
Ru Nd1 Nd2 140.890(15) 7_556 5_655
Ru Nd1 Nd2 140.890(15) 7_546 5_655
Ge1 Nd1 Nd1 140.62(3) 7_556 7_545
Ge1 Nd1 Nd1 86.51(3) 7_546 7_545
Ge2 Nd1 Nd1 54.66(2) . 7_545
Ge2 Nd1 Nd1 51.102(19) 7_545 7_545
Ge2 Nd1 Nd1 99.38(3) 7 7_545
Ru Nd1 Nd1 59.309(17) 1_554 7_545
In Nd1 Nd1 158.74(2) 3 7_545
In Nd1 Nd1 100.66(3) 3_545 7_545
Ru Nd1 Nd1 96.80(3) 7_556 7_545
Ru Nd1 Nd1 52.890(19) 7_546 7_545
Nd2 Nd1 Nd1 102.37(2) 5_655 7_545
Ge1 Nd2 Ge1 92.05(4) 3 3_545
Ge1 Nd2 Ru 108.50(2) 3 5_656
Ge1 Nd2 Ru 108.50(2) 3_545 5_656
Ge1 Nd2 Ge2 81.91(3) 3 3
Ge1 Nd2 Ge2 148.54(3) 3_545 3
Ru Nd2 Ge2 46.519(18) 5_656 3
Ge1 Nd2 Ge2 148.54(3) 3 3_545
Ge1 Nd2 Ge2 81.91(3) 3_545 3_545
Ru Nd2 Ge2 46.519(18) 5_656 3_545
Ge2 Nd2 Ge2 87.33(3) 3 3_545
Ge1 Nd2 Ru 47.83(2) 3 3
Ge1 Nd2 Ru 108.15(3) 3_545 3
Ru Nd2 Ru 60.72(2) 5_656 3
Ge2 Nd2 Ru 46.61(3) 3 3
Ge2 Nd2 Ru 104.83(3) 3_545 3
Ge1 Nd2 Ru 108.15(3) 3 3_545
Ge1 Nd2 Ru 47.83(2) 3_545 3_545
Ru Nd2 Ru 60.72(2) 5_656 3_545
Ge2 Nd2 Ru 104.83(3) 3 3_545
Ge2 Nd2 Ru 46.61(3) 3_545 3_545
Ru Nd2 Ru 86.14(3) 3 3_545
Ge1 Nd2 Ge1 107.80(2) 3 7_546
Ge1 Nd2 Ge1 48.58(3) 3_545 7_546
Ru Nd2 Ge1 137.315(18) 5_656 7_546
Ge2 Nd2 Ge1 161.78(3) 3 7_546
Ge2 Nd2 Ge1 91.25(3) 3_545 7_546
Ru Nd2 Ge1 150.11(2) 3 7_546
Ru Nd2 Ge1 87.08(3) 3_545 7_546
Ge1 Nd2 Ge1 48.58(3) 3 7_556
Ge1 Nd2 Ge1 107.80(2) 3_545 7_556
Ru Nd2 Ge1 137.315(18) 5_656 7_556
Ge2 Nd2 Ge1 91.25(3) 3 7_556
Ge2 Nd2 Ge1 161.78(3) 3_545 7_556
Ru Nd2 Ge1 87.08(3) 3 7_556
Ru Nd2 Ge1 150.11(2) 3_545 7_556
Ge1 Nd2 Ge1 84.45(4) 7_546 7_556
Ge1 Nd2 In 150.01(2) 3 3_545
Ge1 Nd2 In 87.85(3) 3_545 3_545
Ru Nd2 In 99.899(17) 5_656 3_545
Ge2 Nd2 In 112.48(3) 3 3_545
Ge2 Nd2 In 61.02(2) 3_545 3_545
Ru Nd2 In 157.629(18) 3 3_545
Ru Nd2 In 93.86(3) 3_545 3_545
Ge1 Nd2 In 51.96(2) 7_546 3_545
Ge1 Nd2 In 103.16(2) 7_556 3_545
Ge1 Nd2 In 87.85(3) 3 3
Ge1 Nd2 In 150.01(2) 3_545 3
Ru Nd2 In 99.899(17) 5_656 3
Ge2 Nd2 In 61.02(2) 3 3
Ge2 Nd2 In 112.48(3) 3_545 3
Ru Nd2 In 93.86(3) 3 3
Ru Nd2 In 157.629(18) 3_545 3
Ge1 Nd2 In 103.16(3) 7_546 3
Ge1 Nd2 In 51.96(2) 7_556 3
In Nd2 In 77.78(3) 3_545 3
Ge1 Nd2 Ge2 78.34(3) 3 5_656
Ge1 Nd2 Ge2 78.34(3) 3_545 5_656
Ru Nd2 Ge2 44.12(3) 5_656 5_656
Ge2 Nd2 Ge2 70.20(3) 3 5_656
Ge2 Nd2 Ge2 70.20(3) 3_545 5_656
Ru Nd2 Ge2 43.209(16) 3 5_656
Ru Nd2 Ge2 43.209(15) 3_545 5_656
Ge1 Nd2 Ge2 126.16(2) 7_546 5_656
Ge1 Nd2 Ge2 126.16(2) 7_556 5_656
In Nd2 Ge2 130.684(15) 3_545 5_656
In Nd2 Ge2 130.684(15) 3 5_656
Ge2 Ru Ge2 123.00(5) 7_556 7_546
Ge2 Ru Ge2 100.49(3) 7_556 .
Ge2 Ru Ge2 100.49(3) 7_546 .
Ge2 Ru Ge1 111.55(3) 7_556 .
Ge2 Ru Ge1 111.55(3) 7_546 .
Ge2 Ru Ge1 107.23(3) . .
Ge2 Ru Nd2 67.45(2) 7_556 5_656
Ge2 Ru Nd2 67.45(2) 7_546 5_656
Ge2 Ru Nd2 75.92(3) . 5_656
Ge1 Ru Nd2 176.85(3) . 5_656
Ge2 Ru Nd2 160.35(3) 7_556 3_445
Ge2 Ru Nd2 75.02(3) 7_546 3_445
Ge2 Ru Nd2 65.97(2) . 3_445
Ge1 Ru Nd2 62.71(2) . 3_445
Nd2 Ru Nd2 119.28(2) 5_656 3_445
Ge2 Ru Nd2 75.02(3) 7_556 3_455
Ge2 Ru Nd2 160.35(3) 7_546 3_455
Ge2 Ru Nd2 65.97(2) . 3_455
Ge1 Ru Nd2 62.71(2) . 3_455
Nd2 Ru Nd2 119.28(2) 5_656 3_455
Nd2 Ru Nd2 86.14(3) 3_445 3_455
Ge2 Ru Nd1 66.23(2) 7_556 1_556
Ge2 Ru Nd1 66.23(2) 7_546 1_556
Ge2 Ru Nd1 144.80(3) . 1_556
Ge1 Ru Nd1 107.96(3) . 1_556
Nd2 Ru Nd1 68.89(2) 5_656 1_556
Nd2 Ru Nd1 133.030(16) 3_445 1_556
Nd2 Ru Nd1 133.030(16) 3_455 1_556
Ge2 Ru Nd1 58.32(3) 7_556 7_556
Ge2 Ru Nd1 124.78(3) 7_546 7_556
Ge2 Ru Nd1 134.70(2) . 7_556
Ge1 Ru Nd1 57.676(18) . 7_556
Nd2 Ru Nd1 120.168(17) 5_656 7_556
Nd2 Ru Nd1 120.33(3) 3_445 7_556
Nd2 Ru Nd1 69.73(3) 3_455 7_556
Nd1 Ru Nd1 67.80(3) 1_556 7_556
Ge2 Ru Nd1 124.78(3) 7_556 7_546
Ge2 Ru Nd1 58.32(3) 7_546 7_546
Ge2 Ru Nd1 134.70(2) . 7_546
Ge1 Ru Nd1 57.676(18) . 7_546
Nd2 Ru Nd1 120.168(17) 5_656 7_546
Nd2 Ru Nd1 69.73(3) 3_445 7_546
Nd2 Ru Nd1 120.33(3) 3_455 7_546
Nd1 Ru Nd1 67.80(3) 1_556 7_546
Nd1 Ru Nd1 77.12(3) 7_556 7_546
Ge1 In Ge1 180.00(3) 5_556 1_554
Ge1 In Nd1 56.668(15) 5_556 3_445
Ge1 In Nd1 123.332(15) 1_554 3_445
Ge1 In Nd1 123.332(15) 5_556 7
Ge1 In Nd1 56.668(15) 1_554 7
Nd1 In Nd1 180.0 3_445 7
Ge1 In Nd1 123.332(15) 5_556 7_545
Ge1 In Nd1 56.668(15) 1_554 7_545
Nd1 In Nd1 99.65(3) 3_445 7_545
Nd1 In Nd1 80.35(3) 7 7_545
Ge1 In Nd1 56.668(15) 5_556 3_455
Ge1 In Nd1 123.332(15) 1_554 3_455
Nd1 In Nd1 80.35(3) 3_445 3_455
Nd1 In Nd1 99.65(3) 7 3_455
Nd1 In Nd1 180.000(14) 7_545 3_455
Ge1 In Nd2 60.02(2) 5_556 3_455
Ge1 In Nd2 119.98(2) 1_554 3_455
Nd1 In Nd2 116.57(2) 3_445 3_455
Nd1 In Nd2 63.43(2) 7 3_455
Nd1 In Nd2 111.26(2) 7_545 3_455
Nd1 In Nd2 68.74(2) 3_455 3_455
Ge1 In Nd2 119.98(2) 5_556 7_545
Ge1 In Nd2 60.02(2) 1_554 7_545
Nd1 In Nd2 63.43(2) 3_445 7_545
Nd1 In Nd2 116.57(2) 7 7_545
Nd1 In Nd2 68.74(2) 7_545 7_545
Nd1 In Nd2 111.26(2) 3_455 7_545
Nd2 In Nd2 180.000(10) 3_455 7_545
Ge1 In Nd2 60.02(2) 5_556 3_445
Ge1 In Nd2 119.98(2) 1_554 3_445
Nd1 In Nd2 68.74(2) 3_445 3_445
Nd1 In Nd2 111.26(2) 7 3_445
Nd1 In Nd2 63.43(2) 7_545 3_445
Nd1 In Nd2 116.57(2) 3_455 3_445
Nd2 In Nd2 77.78(3) 3_455 3_445
Nd2 In Nd2 102.22(3) 7_545 3_445
Ge1 In Nd2 119.98(2) 5_556 7
Ge1 In Nd2 60.02(2) 1_554 7
Nd1 In Nd2 111.26(2) 3_445 7
Nd1 In Nd2 68.74(2) 7 7
Nd1 In Nd2 116.57(2) 7_545 7
Nd1 In Nd2 63.43(2) 3_455 7
Nd2 In Nd2 102.22(3) 3_455 7
Nd2 In Nd2 77.78(3) 7_545 7
Nd2 In Nd2 180.0 3_445 7
Ru Ge1 Ge1 120.22(5) . 5_556
Ru Ge1 In 130.46(3) . 1_556
Ge1 Ge1 In 109.32(5) 5_556 1_556
Ru Ge1 Nd1 77.48(2) . 7_556
Ge1 Ge1 Nd1 132.74(2) 5_556 7_556
In Ge1 Nd1 68.85(3) 1_556 7_556
Ru Ge1 Nd1 77.48(2) . 7_546
Ge1 Ge1 Nd1 132.74(2) 5_556 7_546
In Ge1 Nd1 68.85(3) 1_556 7_546
Nd1 Ge1 Nd1 92.13(4) 7_556 7_546
Ru Ge1 Nd2 69.47(2) . 3_445
Ge1 Ge1 Nd2 70.04(3) 5_556 3_445
In Ge1 Nd2 133.122(19) 1_556 3_445
Nd1 Ge1 Nd2 146.84(3) 7_556 3_445
Nd1 Ge1 Nd2 78.51(3) 7_546 3_445
Ru Ge1 Nd2 69.47(2) . 3_455
Ge1 Ge1 Nd2 70.04(3) 5_556 3_455
In Ge1 Nd2 133.122(19) 1_556 3_455
Nd1 Ge1 Nd2 78.51(3) 7_556 3_455
Nd1 Ge1 Nd2 146.84(3) 7_546 3_455
Nd2 Ge1 Nd2 92.05(4) 3_445 3_455
Ru Ge1 Nd2 136.808(19) . 7_546
Ge1 Ge1 Nd2 61.38(3) 5_556 7_546
In Ge1 Nd2 68.01(2) 1_556 7_546
Nd1 Ge1 Nd2 136.68(3) 7_556 7_546
Nd1 Ge1 Nd2 76.09(3) 7_546 7_546
Nd2 Ge1 Nd2 72.20(2) 3_445 7_546
Nd2 Ge1 Nd2 131.42(3) 3_455 7_546
Ru Ge1 Nd2 136.808(19) . 7_556
Ge1 Ge1 Nd2 61.38(3) 5_556 7_556
In Ge1 Nd2 68.01(2) 1_556 7_556
Nd1 Ge1 Nd2 76.09(3) 7_556 7_556
Nd1 Ge1 Nd2 136.68(3) 7_546 7_556
Nd2 Ge1 Nd2 131.42(3) 3_445 7_556
Nd2 Ge1 Nd2 72.20(2) 3_455 7_556
Nd2 Ge1 Nd2 84.45(4) 7_546 7_556
Ru Ge2 Ru 123.00(5) 7_556 7_546
Ru Ge2 Ru 79.51(3) 7_556 .
Ru Ge2 Ru 79.51(3) 7_546 .
Ru Ge2 Nd1 77.79(3) 7_556 .
Ru Ge2 Nd1 77.79(3) 7_546 .
Ru Ge2 Nd1 131.26(4) . .
Ru Ge2 Nd2 143.83(4) 7_556 3_445
Ru Ge2 Nd2 66.03(3) 7_546 3_445
Ru Ge2 Nd2 67.43(2) . 3_445
Nd1 Ge2 Nd2 135.565(18) . 3_445
Ru Ge2 Nd2 66.03(3) 7_556 3_455
Ru Ge2 Nd2 143.83(4) 7_546 3_455
Ru Ge2 Nd2 67.43(2) . 3_455
Nd1 Ge2 Nd2 135.565(18) . 3_455
Nd2 Ge2 Nd2 87.33(3) 3_445 3_455
Ru Ge2 Nd1 146.39(3) 7_556 7_545
Ru Ge2 Nd1 68.43(3) 7_546 7_545
Ru Ge2 Nd1 133.54(2) . 7_545
Nd1 Ge2 Nd1 74.24(3) . 7_545
Nd2 Ge2 Nd1 69.14(2) 3_445 7_545
Nd2 Ge2 Nd1 125.95(3) 3_455 7_545
Ru Ge2 Nd1 68.43(3) 7_556 7
Ru Ge2 Nd1 146.39(3) 7_546 7
Ru Ge2 Nd1 133.54(2) . 7
Nd1 Ge2 Nd1 74.24(3) . 7
Nd2 Ge2 Nd1 125.95(3) 3_445 7
Nd2 Ge2 Nd1 69.14(2) 3_455 7
Nd1 Ge2 Nd1 86.16(4) 7_545 7
Ru Ge2 Nd2 61.77(2) 7_556 5_656
Ru Ge2 Nd2 61.77(2) 7_546 5_656
Ru Ge2 Nd2 59.96(3) . 5_656
Nd1 Ge2 Nd2 71.30(3) . 5_656
Nd2 Ge2 Nd2 109.80(3) 3_445 5_656
Nd2 Ge2 Nd2 109.80(3) 3_455 5_656
Nd1 Ge2 Nd2 123.72(2) 7_545 5_656
Nd1 Ge2 Nd2 123.72(2) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Nd1 Ge1 3.0178(9) 7_556
Nd1 Ge1 3.0178(9) 7_546
Nd1 Ge2 3.0355(12) .
Nd1 Ge2 3.1817(10) 7_545
Nd1 Ge2 3.1817(10) 7
Nd1 Ru 3.2331(12) 1_554
Nd1 In 3.3686(9) 3
Nd1 In 3.3686(9) 3_545
Nd1 Ru 3.4863(10) 7_556
Nd1 Ru 3.4863(10) 7_546
Nd1 Nd2 3.5912(12) 5_655
Nd1 Nd1 3.7536(12) 7_545
Nd2 Ge1 3.0198(10) 3
Nd2 Ge1 3.0198(10) 3_545
Nd2 Ru 3.1141(13) 5_656
Nd2 Ge2 3.1474(10) 3
Nd2 Ge2 3.1474(10) 3_545
Nd2 Ru 3.1822(9) 3
Nd2 Ru 3.1822(9) 3_545
Nd2 Ge1 3.2336(11) 7_546
Nd2 Ge1 3.2336(10) 7_556
Nd2 In 3.4614(9) 3_545
Nd2 In 3.4614(9) 3
Nd2 Ge2 3.4890(13) 5_656
Ru Ge2 2.4728(9) 7_556
Ru Ge2 2.4728(9) 7_546
Ru Ge2 2.5042(14) .
Ru Ge1 2.5184(13) .
Ru Nd2 3.1141(13) 5_656
Ru Nd2 3.1823(9) 3_445
Ru Nd2 3.1823(9) 3_455
Ru Nd1 3.2331(12) 1_556
Ru Nd1 3.4863(10) 7_556
Ru Nd1 3.4863(10) 7_546
In Ge1 2.9401(12) 5_556
In Ge1 2.9401(12) 1_554
In Nd1 3.3687(9) 3_445
In Nd1 3.3687(9) 7
In Nd1 3.3687(9) 7_545
In Nd1 3.3687(9) 3_455
In Nd2 3.4614(9) 3_455
In Nd2 3.4614(9) 7_545
In Nd2 3.4614(9) 3_445
In Nd2 3.4614(9) 7
Ge1 Ge1 2.5796(17) 5_556
Ge1 In 2.9401(12) 1_556
Ge1 Nd1 3.0179(9) 7_556
Ge1 Nd1 3.0179(9) 7_546
Ge1 Nd2 3.0198(10) 3_445
Ge1 Nd2 3.0198(10) 3_455
Ge1 Nd2 3.2336(10) 7_546
Ge1 Nd2 3.2336(10) 7_556
Ge2 Ru 2.4728(9) 7_556
Ge2 Ru 2.4728(9) 7_546
Ge2 Nd2 3.1474(10) 3_445
Ge2 Nd2 3.1474(10) 3_455
Ge2 Nd1 3.1817(10) 7_545
Ge2 Nd1 3.1817(10) 7
Ge2 Nd2 3.4891(13) 5_656
