#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342574.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342574
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Sm4 Ru2 In Ge4'
_chemical_formula_sum            'Ge4 In Ru2 Sm4'
_chemical_formula_weight         1208.72
_chemical_name_common
'samarium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'samarium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.517(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.877(3)
_cell_length_b                   4.3178(7)
_cell_length_c                   7.0936(12)
_cell_measurement_reflns_used    1891
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.45
_cell_measurement_theta_min      3.00
_cell_volume                     466.23(14)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0340
_diffrn_reflns_av_unetI/netI     0.0310
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3389
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.225
_diffrn_reflns_theta_min         2.676
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    42.910
_exptl_absorpt_correction_T_max  0.5728
_exptl_absorpt_correction_T_min  0.1100
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.610
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1026
_exptl_crystal_size_max          0.091
_exptl_crystal_size_mid          0.021
_exptl_crystal_size_min          0.019
_refine_diff_density_max         2.114
_refine_diff_density_min         -2.113
_refine_diff_density_rms         0.437
_refine_ls_extinction_coef       0.00087(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         988
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0290
_refine_ls_R_factor_gt           0.0221
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0181P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0422
_refine_ls_wR_factor_ref         0.0439
_reflns_Friedel_coverage         0.000
_reflns_number_gt                849
_reflns_number_total             988
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Sm4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_original_cell_volume        466.23(13)
_cod_database_code               4342574
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.112
_shelx_estimated_absorpt_t_max   0.496
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Sm1 Sm 0.34901(2) 0.0000 0.06477(5) 0.00638(9) Uani 1 2 d S T P
Sm2 Sm 0.58809(2) 0.0000 0.38265(5) 0.00604(9) Uani 1 2 d S T P
Ru Ru 0.21920(3) 0.0000 0.62921(8) 0.00540(11) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0082(2) Uani 0.965(3) 4 d S T .
Ge1 Ge 0.06489(5) 0.0000 0.65616(11) 0.00613(14) Uani 1 2 d S T P
Ge2 Ge 0.20642(5) 0.0000 0.26868(11) 0.00675(14) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Sm1 Ge1 92.65(2) 7_556 7_546
Ge1 Sm1 Ge2 86.94(2) 7_556 .
Ge1 Sm1 Ge2 86.94(2) 7_546 .
Ge1 Sm1 Ge2 167.15(2) 7_556 7_545
Ge1 Sm1 Ge2 88.840(19) 7_546 7_545
Ge2 Sm1 Ge2 105.891(18) . 7_545
Ge1 Sm1 Ge2 88.840(19) 7_556 7
Ge1 Sm1 Ge2 167.15(2) 7_546 7
Ge2 Sm1 Ge2 105.891(18) . 7
Ge2 Sm1 Ge2 86.94(2) 7_545 7
Ge1 Sm1 Ru 133.663(13) 7_556 1_554
Ge1 Sm1 Ru 133.663(13) 7_546 1_554
Ge2 Sm1 Ru 95.64(2) . 1_554
Ge2 Sm1 Ru 45.915(13) 7_545 1_554
Ge2 Sm1 Ru 45.915(13) 7 1_554
Ge1 Sm1 In 54.182(16) 7_556 3
Ge1 Sm1 In 110.247(19) 7_546 3
Ge2 Sm1 In 136.861(9) . 3
Ge2 Sm1 In 113.449(17) 7_545 3
Ge2 Sm1 In 60.795(15) 7 3
Ru Sm1 In 99.064(14) 1_554 3
Ge1 Sm1 In 110.247(19) 7_556 3_545
Ge1 Sm1 In 54.182(16) 7_546 3_545
Ge2 Sm1 In 136.861(9) . 3_545
Ge2 Sm1 In 60.795(15) 7_545 3_545
Ge2 Sm1 In 113.449(17) 7 3_545
Ru Sm1 In 99.064(14) 1_554 3_545
In Sm1 In 80.152(15) 3 3_545
Ge1 Sm1 Ru 45.253(18) 7_556 7_556
Ge1 Sm1 Ru 101.65(2) 7_546 7_556
Ge2 Sm1 Ru 44.295(11) . 7_556
Ge2 Sm1 Ru 146.567(19) 7_545 7_556
Ge2 Sm1 Ru 88.441(18) 7 7_556
Ru Sm1 Ru 112.199(16) 1_554 7_556
In Sm1 Ru 92.746(12) 3 7_556
In Sm1 Ru 148.683(14) 3_545 7_556
Ge1 Sm1 Ru 101.65(2) 7_556 7_546
Ge1 Sm1 Ru 45.253(18) 7_546 7_546
Ge2 Sm1 Ru 44.295(11) . 7_546
Ge2 Sm1 Ru 88.441(18) 7_545 7_546
Ge2 Sm1 Ru 146.567(19) 7 7_546
Ru Sm1 Ru 112.199(16) 1_554 7_546
In Sm1 Ru 148.683(14) 3 7_546
In Sm1 Ru 92.746(12) 3_545 7_546
Ru Sm1 Ru 77.551(18) 7_556 7_546
Ge1 Sm1 Sm2 113.361(18) 7_556 5_655
Ge1 Sm1 Sm2 113.361(18) 7_546 5_655
Ge2 Sm1 Sm2 149.396(19) . 5_655
Ge2 Sm1 Sm2 54.702(15) 7_545 5_655
Ge2 Sm1 Sm2 54.702(15) 7 5_655
Ru Sm1 Sm2 53.759(17) 1_554 5_655
In Sm1 Sm2 59.282(7) 3 5_655
In Sm1 Sm2 59.282(7) 3_545 5_655
Ru Sm1 Sm2 140.657(9) 7_556 5_655
Ru Sm1 Sm2 140.657(9) 7_546 5_655
Ge1 Sm1 Sm1 141.41(2) 7_556 7_545
Ge1 Sm1 Sm1 86.527(16) 7_546 7_545
Ge2 Sm1 Sm1 54.483(15) . 7_545
Ge2 Sm1 Sm1 51.408(15) 7_545 7_545
Ge2 Sm1 Sm1 100.218(19) 7 7_545
Ru Sm1 Sm1 59.406(13) 1_554 7_545
In Sm1 Sm1 158.399(17) 3 7_545
In Sm1 Sm1 100.373(13) 3_545 7_545
Ru Sm1 Sm1 97.158(17) 7_556 7_545
Ru Sm1 Sm1 52.793(13) 7_546 7_545
Sm2 Sm1 Sm1 102.150(14) 5_655 7_545
Ge1 Sm2 Ge1 92.26(3) 3 3_545
Ge1 Sm2 Ru 108.866(17) 3 5_656
Ge1 Sm2 Ru 108.866(17) 3_545 5_656
Ge1 Sm2 Ge2 82.120(18) 3 3
Ge1 Sm2 Ge2 149.54(2) 3_545 3
Ru Sm2 Ge2 46.918(13) 5_656 3
Ge1 Sm2 Ge2 149.54(2) 3 3_545
Ge1 Sm2 Ge2 82.120(18) 3_545 3_545
Ru Sm2 Ge2 46.918(13) 5_656 3_545
Ge2 Sm2 Ge2 87.72(2) 3 3_545
Ge1 Sm2 Ru 48.071(18) 3 3
Ge1 Sm2 Ru 108.48(2) 3_545 3
Ru Sm2 Ru 60.829(15) 5_656 3
Ge2 Sm2 Ru 47.093(19) 3 3
Ge2 Sm2 Ru 105.43(2) 3_545 3
Ge1 Sm2 Ru 108.48(2) 3 3_545
Ge1 Sm2 Ru 48.071(18) 3_545 3_545
Ru Sm2 Ru 60.829(15) 5_656 3_545
Ge2 Sm2 Ru 105.43(2) 3 3_545
Ge2 Sm2 Ru 47.093(19) 3_545 3_545
Ru Sm2 Ru 86.203(19) 3 3_545
Ge1 Sm2 Ge1 108.161(15) 3 7_546
Ge1 Sm2 Ge1 48.67(2) 3_545 7_546
Ru Sm2 Ge1 137.021(12) 5_656 7_546
Ge2 Sm2 Ge1 160.62(2) 3 7_546
Ge2 Sm2 Ge1 90.525(18) 3_545 7_546
Ru Sm2 Ge1 150.74(2) 3 7_546
Ru Sm2 Ge1 87.202(17) 3_545 7_546
Ge1 Sm2 Ge1 48.67(2) 3 7_556
Ge1 Sm2 Ge1 108.161(15) 3_545 7_556
Ru Sm2 Ge1 137.021(12) 5_656 7_556
Ge2 Sm2 Ge1 90.525(18) 3 7_556
Ge2 Sm2 Ge1 160.62(2) 3_545 7_556
Ru Sm2 Ge1 87.202(17) 3 7_556
Ru Sm2 Ge1 150.74(2) 3_545 7_556
Ge1 Sm2 Ge1 84.77(2) 7_546 7_556
Ge1 Sm2 In 150.071(19) 3 3_545
Ge1 Sm2 In 87.790(17) 3_545 3_545
Ru Sm2 In 99.351(13) 5_656 3_545
Ge2 Sm2 In 111.724(19) 3 3_545
Ge2 Sm2 In 60.011(16) 3_545 3_545
Ru Sm2 In 157.218(15) 3 3_545
Ru Sm2 In 93.673(13) 3_545 3_545
Ge1 Sm2 In 51.729(14) 7_546 3_545
Ge1 Sm2 In 103.122(16) 7_556 3_545
Ge1 Sm2 In 87.790(17) 3 3
Ge1 Sm2 In 150.071(19) 3_545 3
Ru Sm2 In 99.351(12) 5_656 3
Ge2 Sm2 In 60.011(16) 3 3
Ge2 Sm2 In 111.724(19) 3_545 3
Ru Sm2 In 93.673(13) 3 3
Ru Sm2 In 157.218(15) 3_545 3
Ge1 Sm2 In 103.122(16) 7_546 3
Ge1 Sm2 In 51.729(14) 7_556 3
In Sm2 In 77.774(15) 3_545 3
Ge1 Sm2 Ge2 78.650(19) 3 5_656
Ge1 Sm2 Ge2 78.650(19) 3_545 5_656
Ru Sm2 Ge2 44.313(19) 5_656 5_656
Ge2 Sm2 Ge2 70.89(2) 3 5_656
Ge2 Sm2 Ge2 70.89(2) 3_545 5_656
Ru Sm2 Ge2 43.236(10) 3 5_656
Ru Sm2 Ge2 43.236(9) 3_545 5_656
Ge1 Sm2 Ge2 126.472(16) 7_546 5_656
Ge1 Sm2 Ge2 126.472(16) 7_556 5_656
In Sm2 Ge2 130.394(11) 3_545 5_656
In Sm2 Ge2 130.394(11) 3 5_656
Ge2 Ru Ge2 121.99(4) 7_556 7_546
Ge2 Ru Ge2 101.10(2) 7_556 .
Ge2 Ru Ge2 101.10(2) 7_546 .
Ge2 Ru Ge1 111.92(2) 7_556 .
Ge2 Ru Ge1 111.92(2) 7_546 .
Ge2 Ru Ge1 106.25(3) . .
Ge2 Ru Sm2 67.205(19) 7_556 5_656
Ge2 Ru Sm2 67.205(19) 7_546 5_656
Ge2 Ru Sm2 76.43(2) . 5_656
Ge1 Ru Sm2 177.31(3) . 5_656
Ge2 Ru Sm2 160.90(2) 7_556 3_445
Ge2 Ru Sm2 75.508(19) 7_546 3_445
Ge2 Ru Sm2 65.535(17) . 3_445
Ge1 Ru Sm2 62.523(17) . 3_445
Sm2 Ru Sm2 119.172(15) 5_656 3_445
Ge2 Ru Sm2 75.508(19) 7_556 3_455
Ge2 Ru Sm2 160.90(2) 7_546 3_455
Ge2 Ru Sm2 65.535(17) . 3_455
Ge1 Ru Sm2 62.523(17) . 3_455
Sm2 Ru Sm2 119.172(15) 5_656 3_455
Sm2 Ru Sm2 86.201(19) 3_445 3_455
Ge2 Ru Sm1 65.940(19) 7_556 1_556
Ge2 Ru Sm1 65.940(19) 7_546 1_556
Ge2 Ru Sm1 146.17(3) . 1_556
Ge1 Ru Sm1 107.58(3) . 1_556
Sm2 Ru Sm1 69.733(16) 5_656 1_556
Sm2 Ru Sm1 132.752(12) 3_445 1_556
Sm2 Ru Sm1 132.752(12) 3_455 1_556
Ge2 Ru Sm1 58.48(2) 7_556 7_556
Ge2 Ru Sm1 124.94(3) 7_546 7_556
Ge2 Ru Sm1 133.910(15) . 7_556
Ge1 Ru Sm1 57.590(15) . 7_556
Sm2 Ru Sm1 120.586(14) 5_656 7_556
Sm2 Ru Sm1 120.07(2) 3_445 7_556
Sm2 Ru Sm1 69.216(15) 3_455 7_556
Sm1 Ru Sm1 67.801(16) 1_556 7_556
Ge2 Ru Sm1 124.94(3) 7_556 7_546
Ge2 Ru Sm1 58.48(2) 7_546 7_546
Ge2 Ru Sm1 133.910(16) . 7_546
Ge1 Ru Sm1 57.590(15) . 7_546
Sm2 Ru Sm1 120.586(14) 5_656 7_546
Sm2 Ru Sm1 69.216(15) 3_445 7_546
Sm2 Ru Sm1 120.066(19) 3_455 7_546
Sm1 Ru Sm1 67.801(16) 1_556 7_546
Sm1 Ru Sm1 77.551(18) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Sm1 56.426(11) 5_556 3_445
Ge1 In Sm1 123.574(11) 1_554 3_445
Ge1 In Sm1 123.574(11) 5_556 7
Ge1 In Sm1 56.426(11) 1_554 7
Sm1 In Sm1 180.0 3_445 7
Ge1 In Sm1 123.574(11) 5_556 7_545
Ge1 In Sm1 56.426(11) 1_554 7_545
Sm1 In Sm1 99.848(15) 3_445 7_545
Sm1 In Sm1 80.152(15) 7 7_545
Ge1 In Sm1 56.426(11) 5_556 3_455
Ge1 In Sm1 123.574(11) 1_554 3_455
Sm1 In Sm1 80.152(15) 3_445 3_455
Sm1 In Sm1 99.848(15) 7 3_455
Sm1 In Sm1 180.0 7_545 3_455
Ge1 In Sm2 59.936(14) 5_556 3_455
Ge1 In Sm2 120.064(14) 1_554 3_455
Sm1 In Sm2 116.244(12) 3_445 3_455
Sm1 In Sm2 63.756(11) 7 3_455
Sm1 In Sm2 111.478(11) 7_545 3_455
Sm1 In Sm2 68.522(11) 3_455 3_455
Ge1 In Sm2 120.064(14) 5_556 7_545
Ge1 In Sm2 59.936(14) 1_554 7_545
Sm1 In Sm2 63.756(11) 3_445 7_545
Sm1 In Sm2 116.244(12) 7 7_545
Sm1 In Sm2 68.522(11) 7_545 7_545
Sm1 In Sm2 111.478(11) 3_455 7_545
Sm2 In Sm2 180.0 3_455 7_545
Ge1 In Sm2 59.936(14) 5_556 3_445
Ge1 In Sm2 120.064(14) 1_554 3_445
Sm1 In Sm2 68.522(11) 3_445 3_445
Sm1 In Sm2 111.478(11) 7 3_445
Sm1 In Sm2 63.756(11) 7_545 3_445
Sm1 In Sm2 116.244(11) 3_455 3_445
Sm2 In Sm2 77.775(15) 3_455 3_445
Sm2 In Sm2 102.225(15) 7_545 3_445
Ge1 In Sm2 120.064(14) 5_556 7
Ge1 In Sm2 59.936(14) 1_554 7
Sm1 In Sm2 111.478(11) 3_445 7
Sm1 In Sm2 68.522(11) 7 7
Sm1 In Sm2 116.244(11) 7_545 7
Sm1 In Sm2 63.756(11) 3_455 7
Sm2 In Sm2 102.225(15) 3_455 7
Sm2 In Sm2 77.775(15) 7_545 7
Sm2 In Sm2 180.0 3_445 7
Ru Ge1 Ge1 119.78(5) . 5_556
Ru Ge1 In 130.58(3) . 1_556
Ge1 Ge1 In 109.64(4) 5_556 1_556
Ru Ge1 Sm1 77.16(2) . 7_556
Ge1 Ge1 Sm1 132.679(14) 5_556 7_556
In Ge1 Sm1 69.392(18) 1_556 7_556
Ru Ge1 Sm1 77.16(2) . 7_546
Ge1 Ge1 Sm1 132.679(14) 5_556 7_546
In Ge1 Sm1 69.392(18) 1_556 7_546
Sm1 Ge1 Sm1 92.65(2) 7_556 7_546
Ru Ge1 Sm2 69.406(18) . 3_445
Ge1 Ge1 Sm2 69.90(2) 5_556 3_445
In Ge1 Sm2 133.024(13) 1_556 3_445
Sm1 Ge1 Sm2 146.47(3) 7_556 3_445
Sm1 Ge1 Sm2 77.922(16) 7_546 3_445
Ru Ge1 Sm2 69.406(18) . 3_455
Ge1 Ge1 Sm2 69.90(2) 5_556 3_455
In Ge1 Sm2 133.024(13) 1_556 3_455
Sm1 Ge1 Sm2 77.922(16) 7_556 3_455
Sm1 Ge1 Sm2 146.47(3) 7_546 3_455
Sm2 Ge1 Sm2 92.26(3) 3_445 3_455
Ru Ge1 Sm2 136.554(13) . 7_546
Ge1 Ge1 Sm2 61.42(2) 5_556 7_546
In Ge1 Sm2 68.335(16) 1_556 7_546
Sm1 Ge1 Sm2 137.54(3) 7_556 7_546
Sm1 Ge1 Sm2 76.265(15) 7_546 7_546
Sm2 Ge1 Sm2 71.838(15) 3_445 7_546
Sm2 Ge1 Sm2 131.32(2) 3_455 7_546
Ru Ge1 Sm2 136.554(13) . 7_556
Ge1 Ge1 Sm2 61.42(2) 5_556 7_556
In Ge1 Sm2 68.335(16) 1_556 7_556
Sm1 Ge1 Sm2 76.265(15) 7_556 7_556
Sm1 Ge1 Sm2 137.54(3) 7_546 7_556
Sm2 Ge1 Sm2 131.32(2) 3_445 7_556
Sm2 Ge1 Sm2 71.838(15) 3_455 7_556
Sm2 Ge1 Sm2 84.77(2) 7_546 7_556
Ru Ge2 Ru 121.99(4) 7_556 7_546
Ru Ge2 Ru 78.90(2) 7_556 .
Ru Ge2 Ru 78.90(2) 7_546 .
Ru Ge2 Sm1 77.22(2) 7_556 .
Ru Ge2 Sm1 77.22(2) 7_546 .
Ru Ge2 Sm1 129.47(3) . .
Ru Ge2 Sm2 143.45(3) 7_556 3_445
Ru Ge2 Sm2 65.879(18) 7_546 3_445
Ru Ge2 Sm2 67.372(18) . 3_445
Sm1 Ge2 Sm2 135.670(12) . 3_445
Ru Ge2 Sm2 65.879(18) 7_556 3_455
Ru Ge2 Sm2 143.45(3) 7_546 3_455
Ru Ge2 Sm2 67.372(18) . 3_455
Sm1 Ge2 Sm2 135.670(12) . 3_455
Sm2 Ge2 Sm2 87.72(2) 3_445 3_455
Ru Ge2 Sm1 146.22(3) 7_556 7_545
Ru Ge2 Sm1 68.146(17) 7_546 7_545
Ru Ge2 Sm1 133.858(15) . 7_545
Sm1 Ge2 Sm1 74.108(18) . 7_545
Sm2 Ge2 Sm1 70.017(15) 3_445 7_545
Sm2 Ge2 Sm1 127.71(3) 3_455 7_545
Ru Ge2 Sm1 68.146(17) 7_556 7
Ru Ge2 Sm1 146.22(3) 7_546 7
Ru Ge2 Sm1 133.858(15) . 7
Sm1 Ge2 Sm1 74.108(18) . 7
Sm2 Ge2 Sm1 127.71(3) 3_445 7
Sm2 Ge2 Sm1 70.017(15) 3_455 7
Sm1 Ge2 Sm1 86.94(2) 7_545 7
Ru Ge2 Sm2 61.255(18) 7_556 5_656
Ru Ge2 Sm2 61.255(18) 7_546 5_656
Ru Ge2 Sm2 59.25(2) . 5_656
Sm1 Ge2 Sm2 70.22(2) . 5_656
Sm2 Ge2 Sm2 109.11(2) 3_445 5_656
Sm2 Ge2 Sm2 109.11(2) 3_455 5_656
Sm1 Ge2 Sm2 122.665(17) 7_545 5_656
Sm1 Ge2 Sm2 122.665(17) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sm1 Ge1 2.9849(6) 7_556
Sm1 Ge1 2.9849(6) 7_546
Sm1 Ge2 3.0133(9) .
Sm1 Ge2 3.1380(7) 7_545
Sm1 Ge2 3.1380(7) 7
Sm1 Ru 3.1896(8) 1_554
Sm1 In 3.3533(5) 3
Sm1 In 3.3533(5) 3_545
Sm1 Ru 3.4472(6) 7_556
Sm1 Ru 3.4472(6) 7_546
Sm1 Sm2 3.5878(7) 5_655
Sm1 Sm1 3.7079(7) 7_545
Sm2 Ge1 2.9945(7) 3
Sm2 Ge1 2.9945(7) 3_545
Sm2 Ru 3.0846(8) 5_656
Sm2 Ge2 3.1158(6) 3
Sm2 Ge2 3.1158(6) 3_545
Sm2 Ru 3.1596(5) 3
Sm2 Ru 3.1596(5) 3_545
Sm2 Ge1 3.2025(7) 7_546
Sm2 Ge1 3.2025(7) 7_556
Sm2 In 3.4389(5) 3_545
Sm2 In 3.4389(5) 3
Sm2 Ge2 3.4890(9) 5_656
Ru Ge2 2.4685(5) 7_556
Ru Ge2 2.4685(5) 7_546
Ru Ge2 2.5073(10) .
Ru Ge1 2.5112(9) .
Ru Sm2 3.0847(8) 5_656
Ru Sm2 3.1596(5) 3_445
Ru Sm2 3.1596(5) 3_455
Ru Sm1 3.1895(8) 1_556
Ru Sm1 3.4472(6) 7_556
Ru Sm1 3.4472(6) 7_546
In Ge1 2.9051(8) 5_556
In Ge1 2.9051(8) 1_554
In Sm1 3.3534(5) 3_445
In Sm1 3.3534(5) 7
In Sm1 3.3534(5) 7_545
In Sm1 3.3534(5) 3_455
In Sm2 3.4389(5) 3_455
In Sm2 3.4389(5) 7_545
In Sm2 3.4389(5) 3_445
In Sm2 3.4389(5) 7
Ge1 Ge1 2.5609(15) 5_556
Ge1 In 2.9050(8) 1_556
Ge1 Sm1 2.9849(6) 7_556
Ge1 Sm1 2.9849(6) 7_546
Ge1 Sm2 2.9946(7) 3_445
Ge1 Sm2 2.9946(7) 3_455
Ge1 Sm2 3.2025(7) 7_546
Ge1 Sm2 3.2025(7) 7_556
Ge2 Ru 2.4685(5) 7_556
Ge2 Ru 2.4685(5) 7_546
Ge2 Sm2 3.1158(6) 3_445
Ge2 Sm2 3.1158(6) 3_455
Ge2 Sm1 3.1379(7) 7_545
Ge2 Sm1 3.1379(7) 7
Ge2 Sm2 3.4890(9) 5_656
