#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342575.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342575
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Gd4 Ru2 In Ge4'
_chemical_formula_sum            'Gd4 Ge4 In Ru2'
_chemical_formula_weight         1236.32
_chemical_name_common
'gadolinium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'gadolinium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.635(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.773(4)
_cell_length_b                   4.2875(11)
_cell_length_c                   7.0393(18)
_cell_measurement_reflns_used    1412
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.94
_cell_measurement_theta_min      5.88
_cell_volume                     456.1(2)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0445
_diffrn_reflns_av_unetI/netI     0.0387
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3346
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.305
_diffrn_reflns_theta_min         2.696
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    47.195
_exptl_absorpt_correction_T_max  0.5527
_exptl_absorpt_correction_T_min  0.0636
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    9.002
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1042
_exptl_crystal_size_max          0.126
_exptl_crystal_size_mid          0.024
_exptl_crystal_size_min          0.021
_refine_diff_density_max         2.762
_refine_diff_density_min         -2.500
_refine_diff_density_rms         0.495
_refine_ls_extinction_coef       0.00063(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         972
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0240
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0139P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0406
_refine_ls_wR_factor_ref         0.0437
_reflns_Friedel_coverage         0.000
_reflns_number_gt                800
_reflns_number_total             972
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Gd4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342575
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.066
_shelx_estimated_absorpt_t_max   0.437
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Gd1 Gd 0.34881(3) 0.0000 0.06621(6) 0.00692(10) Uani 1 2 d S T P
Gd2 Gd 0.58772(3) 0.0000 0.38302(6) 0.00642(10) Uani 1 2 d S T P
Ru Ru 0.21954(4) 0.0000 0.63040(9) 0.00622(13) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0089(2) Uani 0.962(3) 4 d S T .
Ge1 Ge 0.06471(6) 0.0000 0.65732(13) 0.00703(17) Uani 1 2 d S T P
Ge2 Ge 0.20446(6) 0.0000 0.26595(13) 0.00734(17) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Gd1 Ge1 93.07(3) 7_556 7_546
Ge1 Gd1 Ge2 87.74(3) 7_556 .
Ge1 Gd1 Ge2 87.74(3) 7_546 .
Ge1 Gd1 Ge2 166.29(3) 7_556 7_545
Ge1 Gd1 Ge2 88.25(3) 7_546 7_545
Ge2 Gd1 Ge2 105.96(2) . 7_545
Ge1 Gd1 Ge2 88.25(3) 7_556 7
Ge1 Gd1 Ge2 166.29(3) 7_546 7
Ge2 Gd1 Ge2 105.96(2) . 7
Ge2 Gd1 Ge2 87.31(3) 7_545 7
Ge1 Gd1 Ru 133.435(16) 7_556 1_554
Ge1 Gd1 Ru 133.435(16) 7_546 1_554
Ge2 Gd1 Ru 95.14(3) . 1_554
Ge2 Gd1 Ru 46.275(17) 7_545 1_554
Ge2 Gd1 Ru 46.275(17) 7 1_554
Ge1 Gd1 In 53.99(2) 7_556 3
Ge1 Gd1 In 110.16(2) 7_546 3
Ge2 Gd1 In 137.246(13) . 3
Ge2 Gd1 In 112.86(2) 7_545 3
Ge2 Gd1 In 60.100(19) 7 3
Ru Gd1 In 98.783(18) 1_554 3
Ge1 Gd1 In 110.16(2) 7_556 3_545
Ge1 Gd1 In 53.99(2) 7_546 3_545
Ge2 Gd1 In 137.246(13) . 3_545
Ge2 Gd1 In 60.100(19) 7_545 3_545
Ge2 Gd1 In 112.86(2) 7 3_545
Ru Gd1 In 98.783(18) 1_554 3_545
In Gd1 In 79.94(2) 3 3_545
Ge1 Gd1 Ru 45.61(2) 7_556 7_556
Ge1 Gd1 Ru 102.28(3) 7_546 7_556
Ge2 Gd1 Ru 44.608(14) . 7_556
Ge2 Gd1 Ru 147.07(2) 7_545 7_556
Ge2 Gd1 Ru 88.38(2) 7 7_556
Ru Gd1 Ru 112.09(2) 1_554 7_556
In Gd1 Ru 92.881(18) 3 7_556
In Gd1 Ru 149.058(17) 3_545 7_556
Ge1 Gd1 Ru 102.28(3) 7_556 7_546
Ge1 Gd1 Ru 45.61(2) 7_546 7_546
Ge2 Gd1 Ru 44.608(14) . 7_546
Ge2 Gd1 Ru 88.38(2) 7_545 7_546
Ge2 Gd1 Ru 147.07(2) 7 7_546
Ru Gd1 Ru 112.09(2) 1_554 7_546
In Gd1 Ru 149.058(17) 3 7_546
In Gd1 Ru 92.881(18) 3_545 7_546
Ru Gd1 Ru 77.87(2) 7_556 7_546
Ge1 Gd1 Gd2 112.88(2) 7_556 5_655
Ge1 Gd1 Gd2 112.88(2) 7_546 5_655
Ge2 Gd1 Gd2 148.87(2) . 5_655
Ge2 Gd1 Gd2 54.458(19) 7_545 5_655
Ge2 Gd1 Gd2 54.458(19) 7 5_655
Ru Gd1 Gd2 53.73(2) 1_554 5_655
In Gd1 Gd2 58.994(9) 3 5_655
In Gd1 Gd2 58.994(9) 3_545 5_655
Ru Gd1 Gd2 140.484(12) 7_556 5_655
Ru Gd1 Gd2 140.484(12) 7_546 5_655
Ge1 Gd1 Gd1 142.03(3) 7_556 7_545
Ge1 Gd1 Gd1 86.67(2) 7_546 7_545
Ge2 Gd1 Gd1 54.30(2) . 7_545
Ge2 Gd1 Gd1 51.654(18) 7_545 7_545
Ge2 Gd1 Gd1 100.64(2) 7 7_545
Ru Gd1 Gd1 59.290(16) 1_554 7_545
In Gd1 Gd1 157.981(19) 3 7_545
In Gd1 Gd1 100.25(2) 3_545 7_545
Ru Gd1 Gd1 97.37(2) 7_556 7_545
Ru Gd1 Gd1 52.797(17) 7_546 7_545
Gd2 Gd1 Gd1 101.961(18) 5_655 7_545
Ge1 Gd2 Ge1 92.16(3) 3 3_545
Ge1 Gd2 Ru 109.02(2) 3 5_656
Ge1 Gd2 Ru 109.02(2) 3_545 5_656
Ge1 Gd2 Ge2 82.29(2) 3 3
Ge1 Gd2 Ge2 150.01(3) 3_545 3
Ru Gd2 Ge2 47.156(17) 5_656 3
Ge1 Gd2 Ge2 150.01(3) 3 3_545
Ge1 Gd2 Ge2 82.29(2) 3_545 3_545
Ru Gd2 Ge2 47.156(17) 5_656 3_545
Ge2 Gd2 Ge2 87.94(3) 3 3_545
Ge1 Gd2 Ru 48.19(2) 3 3
Ge1 Gd2 Ru 108.42(3) 3_545 3
Ru Gd2 Ru 60.854(19) 5_656 3
Ge2 Gd2 Ru 47.46(2) 3 3
Ge2 Gd2 Ru 105.72(3) 3_545 3
Ge1 Gd2 Ru 108.42(3) 3 3_545
Ge1 Gd2 Ru 48.19(2) 3_545 3_545
Ru Gd2 Ru 60.854(19) 5_656 3_545
Ge2 Gd2 Ru 105.72(3) 3 3_545
Ge2 Gd2 Ru 47.46(2) 3_545 3_545
Ru Gd2 Ru 86.01(3) 3 3_545
Ge1 Gd2 Ge1 108.35(2) 3 7_546
Ge1 Gd2 Ge1 48.80(3) 3_545 7_546
Ru Gd2 Ge1 136.828(16) 5_656 7_546
Ge2 Gd2 Ge1 160.01(3) 3 7_546
Ge2 Gd2 Ge1 90.08(3) 3_545 7_546
Ru Gd2 Ge1 151.00(2) 3 7_546
Ru Gd2 Ge1 87.30(2) 3_545 7_546
Ge1 Gd2 Ge1 48.80(3) 3 7_556
Ge1 Gd2 Ge1 108.35(2) 3_545 7_556
Ru Gd2 Ge1 136.828(16) 5_656 7_556
Ge2 Gd2 Ge1 90.08(3) 3 7_556
Ge2 Gd2 Ge1 160.01(3) 3_545 7_556
Ru Gd2 Ge1 87.30(2) 3 7_556
Ru Gd2 Ge1 151.00(2) 3_545 7_556
Ge1 Gd2 Ge1 85.02(3) 7_546 7_556
Ge1 Gd2 In 150.23(2) 3 3_545
Ge1 Gd2 In 87.88(2) 3_545 3_545
Ru Gd2 In 99.023(15) 5_656 3_545
Ge2 Gd2 In 111.30(2) 3 3_545
Ge2 Gd2 In 59.39(2) 3_545 3_545
Ru Gd2 In 157.012(17) 3 3_545
Ru Gd2 In 93.643(19) 3_545 3_545
Ge1 Gd2 In 51.633(18) 7_546 3_545
Ge1 Gd2 In 103.20(2) 7_556 3_545
Ge1 Gd2 In 87.88(2) 3 3
Ge1 Gd2 In 150.23(2) 3_545 3
Ru Gd2 In 99.023(15) 5_656 3
Ge2 Gd2 In 59.39(2) 3 3
Ge2 Gd2 In 111.29(2) 3_545 3
Ru Gd2 In 93.643(19) 3 3
Ru Gd2 In 157.012(17) 3_545 3
Ge1 Gd2 In 103.20(2) 7_546 3
Ge1 Gd2 In 51.633(18) 7_556 3
In Gd2 In 77.84(2) 3_545 3
Ge1 Gd2 Ge2 78.77(2) 3 5_656
Ge1 Gd2 Ge2 78.77(2) 3_545 5_656
Ru Gd2 Ge2 44.34(2) 5_656 5_656
Ge2 Gd2 Ge2 71.24(3) 3 5_656
Ge2 Gd2 Ge2 71.24(3) 3_545 5_656
Ru Gd2 Ge2 43.149(13) 3 5_656
Ru Gd2 Ge2 43.149(13) 3_545 5_656
Ge1 Gd2 Ge2 126.63(2) 7_546 5_656
Ge1 Gd2 Ge2 126.63(2) 7_556 5_656
In Gd2 Ge2 130.146(13) 3_545 5_656
In Gd2 Ge2 130.146(13) 3 5_656
Ge2 Ru Ge2 121.04(5) 7_556 7_546
Ge2 Ru Ge1 112.35(3) 7_556 .
Ge2 Ru Ge1 112.35(3) 7_546 .
Ge2 Ru Ge2 101.46(3) 7_556 .
Ge2 Ru Ge2 101.46(3) 7_546 .
Ge1 Ru Ge2 105.58(4) . .
Ge2 Ru Gd2 66.83(2) 7_556 5_656
Ge2 Ru Gd2 66.83(2) 7_546 5_656
Ge1 Ru Gd2 177.53(3) . 5_656
Ge2 Ru Gd2 76.89(3) . 5_656
Ge2 Ru Gd2 161.20(3) 7_556 3_445
Ge2 Ru Gd2 76.06(3) 7_546 3_445
Ge1 Ru Gd2 62.41(2) . 3_445
Ge2 Ru Gd2 65.12(2) . 3_445
Gd2 Ru Gd2 119.146(19) 5_656 3_445
Ge2 Ru Gd2 76.06(3) 7_556 3_455
Ge2 Ru Gd2 161.20(3) 7_546 3_455
Ge1 Ru Gd2 62.41(2) . 3_455
Ge2 Ru Gd2 65.12(2) . 3_455
Gd2 Ru Gd2 119.146(19) 5_656 3_455
Gd2 Ru Gd2 86.01(3) 3_445 3_455
Ge2 Ru Ru 124.19(4) 7_556 7_546
Ge2 Ru Ru 51.37(3) 7_546 7_546
Ge1 Ru Ru 120.78(3) . 7_546
Ge2 Ru Ru 50.09(2) . 7_546
Gd2 Ru Ru 60.74(2) 5_656 7_546
Gd2 Ru Ru 58.40(2) 3_445 7_546
Gd2 Ru Ru 113.93(3) 3_455 7_546
Ge2 Ru Ru 51.37(3) 7_556 7_556
Ge2 Ru Ru 124.19(4) 7_546 7_556
Ge1 Ru Ru 120.78(3) . 7_556
Ge2 Ru Ru 50.09(2) . 7_556
Gd2 Ru Ru 60.74(2) 5_656 7_556
Gd2 Ru Ru 113.93(3) 3_445 7_556
Gd2 Ru Ru 58.40(2) 3_455 7_556
Ru Ru Ru 85.90(4) 7_546 7_556
Ge2 Ru Gd1 65.69(2) 7_556 1_556
Ge2 Ru Gd1 65.69(2) 7_546 1_556
Ge1 Ru Gd1 107.39(3) . 1_556
Ge2 Ru Gd1 147.03(3) . 1_556
Gd2 Ru Gd1 70.14(2) 5_656 1_556
Gd2 Ru Gd1 132.727(15) 3_445 1_556
Gd2 Ru Gd1 132.727(15) 3_455 1_556
Ru Ru Gd1 110.27(3) 7_546 1_556
Ru Ru Gd1 110.27(3) 7_556 1_556
Ge2 Ru Gd1 58.79(2) 7_556 7_556
Ge2 Ru Gd1 125.16(3) 7_546 7_556
Ge1 Ru Gd1 57.489(18) . 7_556
Ge2 Ru Gd1 133.32(2) . 7_556
Gd2 Ru Gd1 120.846(18) 5_656 7_556
Gd2 Ru Gd1 119.87(3) 3_445 7_556
Gd2 Ru Gd1 68.95(2) 3_455 7_556
Ru Ru Gd1 175.95(2) 7_546 7_556
Ru Ru Gd1 98.12(2) 7_556 7_556
Gd1 Ru Gd1 67.91(2) 1_556 7_556
Ge2 Ru Gd1 125.16(3) 7_556 7_546
Ge2 Ru Gd1 58.79(2) 7_546 7_546
Ge1 Ru Gd1 57.489(18) . 7_546
Ge2 Ru Gd1 133.32(2) . 7_546
Gd2 Ru Gd1 120.846(18) 5_656 7_546
Gd2 Ru Gd1 68.95(2) 3_445 7_546
Gd2 Ru Gd1 119.87(3) 3_455 7_546
Ru Ru Gd1 98.12(2) 7_546 7_546
Ru Ru Gd1 175.95(2) 7_556 7_546
Gd1 Ru Gd1 67.91(2) 1_556 7_546
Gd1 Ru Gd1 77.87(2) 7_556 7_546
Ge1 In Ge1 180.00(3) 5_556 1_554
Ge1 In Gd1 56.183(14) 5_556 3_445
Ge1 In Gd1 123.817(14) 1_554 3_445
Ge1 In Gd1 123.817(14) 5_556 7
Ge1 In Gd1 56.183(14) 1_554 7
Gd1 In Gd1 180.0 3_445 7
Ge1 In Gd1 123.817(14) 5_556 7_545
Ge1 In Gd1 56.183(14) 1_554 7_545
Gd1 In Gd1 100.05(2) 3_445 7_545
Gd1 In Gd1 79.95(2) 7 7_545
Ge1 In Gd1 56.183(14) 5_556 3_455
Ge1 In Gd1 123.817(14) 1_554 3_455
Gd1 In Gd1 79.95(2) 3_445 3_455
Gd1 In Gd1 100.05(2) 7 3_455
Gd1 In Gd1 180.0 7_545 3_455
Ge1 In Gd2 59.880(19) 5_556 3_455
Ge1 In Gd2 120.120(19) 1_554 3_455
Gd1 In Gd2 115.948(15) 3_445 3_455
Gd1 In Gd2 64.052(16) 7 3_455
Gd1 In Gd2 111.694(16) 7_545 3_455
Gd1 In Gd2 68.306(16) 3_455 3_455
Ge1 In Gd2 120.120(19) 5_556 7_545
Ge1 In Gd2 59.880(19) 1_554 7_545
Gd1 In Gd2 64.052(16) 3_445 7_545
Gd1 In Gd2 115.948(15) 7 7_545
Gd1 In Gd2 68.306(16) 7_545 7_545
Gd1 In Gd2 111.694(16) 3_455 7_545
Gd2 In Gd2 180.000(10) 3_455 7_545
Ge1 In Gd2 59.880(19) 5_556 3_445
Ge1 In Gd2 120.120(19) 1_554 3_445
Gd1 In Gd2 68.306(16) 3_445 3_445
Gd1 In Gd2 111.694(16) 7 3_445
Gd1 In Gd2 64.052(16) 7_545 3_445
Gd1 In Gd2 115.948(15) 3_455 3_445
Gd2 In Gd2 77.84(2) 3_455 3_445
Gd2 In Gd2 102.16(2) 7_545 3_445
Ge1 In Gd2 120.120(19) 5_556 7
Ge1 In Gd2 59.880(19) 1_554 7
Gd1 In Gd2 111.694(16) 3_445 7
Gd1 In Gd2 68.306(16) 7 7
Gd1 In Gd2 115.948(15) 7_545 7
Gd1 In Gd2 64.052(16) 3_455 7
Gd2 In Gd2 102.16(2) 3_455 7
Gd2 In Gd2 77.84(2) 7_545 7
Gd2 In Gd2 180.0 3_445 7
Ru Ge1 Ge1 119.38(5) . 5_556
Ru Ge1 In 130.67(4) . 1_556
Ge1 Ge1 In 109.94(5) 5_556 1_556
Ru Ge1 Gd1 76.90(2) . 7_556
Ge1 Ge1 Gd1 132.620(18) 5_556 7_556
In Ge1 Gd1 69.83(2) 1_556 7_556
Ru Ge1 Gd1 76.90(2) . 7_546
Ge1 Ge1 Gd1 132.620(18) 5_556 7_546
In Ge1 Gd1 69.83(2) 1_556 7_546
Gd1 Ge1 Gd1 93.07(3) 7_556 7_546
Ru Ge1 Gd2 69.39(2) . 3_445
Ge1 Ge1 Gd2 69.63(3) 5_556 3_445
In Ge1 Gd2 133.056(17) 1_556 3_445
Gd1 Ge1 Gd2 146.23(3) 7_556 3_445
Gd1 Ge1 Gd2 77.62(2) 7_546 3_445
Ru Ge1 Gd2 69.39(2) . 3_455
Ge1 Ge1 Gd2 69.63(3) 5_556 3_455
In Ge1 Gd2 133.056(17) 1_556 3_455
Gd1 Ge1 Gd2 77.62(2) 7_556 3_455
Gd1 Ge1 Gd2 146.23(3) 7_546 3_455
Gd2 Ge1 Gd2 92.16(3) 3_445 3_455
Ru Ge1 Gd2 136.386(17) . 7_546
Ge1 Ge1 Gd2 61.57(3) 5_556 7_546
In Ge1 Gd2 68.49(2) 1_556 7_546
Gd1 Ge1 Gd2 138.12(3) 7_556 7_546
Gd1 Ge1 Gd2 76.33(2) 7_546 7_546
Gd2 Ge1 Gd2 71.65(2) 3_445 7_546
Gd2 Ge1 Gd2 131.20(3) 3_455 7_546
Ru Ge1 Gd2 136.386(17) . 7_556
Ge1 Ge1 Gd2 61.57(3) 5_556 7_556
In Ge1 Gd2 68.49(2) 1_556 7_556
Gd1 Ge1 Gd2 76.33(2) 7_556 7_556
Gd1 Ge1 Gd2 138.12(3) 7_546 7_556
Gd2 Ge1 Gd2 131.20(3) 3_445 7_556
Gd2 Ge1 Gd2 71.65(2) 3_455 7_556
Gd2 Ge1 Gd2 85.02(3) 7_546 7_556
Ru Ge2 Ru 121.04(5) 7_556 7_546
Ru Ge2 Ru 78.54(3) 7_556 .
Ru Ge2 Ru 78.54(3) 7_546 .
Ru Ge2 Gd1 76.61(3) 7_556 .
Ru Ge2 Gd1 76.61(3) 7_546 .
Ru Ge2 Gd1 128.12(4) . .
Ru Ge2 Gd2 143.34(4) 7_556 3_445
Ru Ge2 Gd2 66.01(2) 7_546 3_445
Ru Ge2 Gd2 67.43(2) . 3_445
Gd1 Ge2 Gd2 135.719(15) . 3_445
Ru Ge2 Gd2 66.01(2) 7_556 3_455
Ru Ge2 Gd2 143.34(4) 7_546 3_455
Ru Ge2 Gd2 67.43(2) . 3_455
Gd1 Ge2 Gd2 135.719(15) . 3_455
Gd2 Ge2 Gd2 87.94(3) 3_445 3_455
Ru Ge2 Gd1 145.88(4) 7_556 7_545
Ru Ge2 Gd1 68.04(2) 7_546 7_545
Ru Ge2 Gd1 134.125(18) . 7_545
Gd1 Ge2 Gd1 74.04(2) . 7_545
Gd2 Ge2 Gd1 70.62(2) 3_445 7_545
Gd2 Ge2 Gd1 128.81(3) 3_455 7_545
Ru Ge2 Gd1 68.04(2) 7_556 7
Ru Ge2 Gd1 145.88(4) 7_546 7
Ru Ge2 Gd1 134.125(18) . 7
Gd1 Ge2 Gd1 74.04(2) . 7
Gd2 Ge2 Gd1 128.81(3) 3_445 7
Gd2 Ge2 Gd1 70.62(2) 3_455 7
Gd1 Ge2 Gd1 87.31(3) 7_545 7
Ru Ge2 Gd2 60.79(2) 7_556 5_656
Ru Ge2 Gd2 60.79(2) 7_546 5_656
Ru Ge2 Gd2 58.78(3) . 5_656
Gd1 Ge2 Gd2 69.34(3) . 5_656
Gd2 Ge2 Gd2 108.76(3) 3_445 5_656
Gd2 Ge2 Gd2 108.76(3) 3_455 5_656
Gd1 Ge2 Gd2 121.95(2) 7_545 5_656
Gd1 Ge2 Gd2 121.95(2) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 Ge1 2.9536(8) 7_556
Gd1 Ge1 2.9536(8) 7_546
Gd1 Ge2 2.9990(11) .
Gd1 Ge2 3.1055(9) 7_545
Gd1 Ge2 3.1055(9) 7
Gd1 Ru 3.1603(10) 1_554
Gd1 In 3.3370(7) 3
Gd1 In 3.3370(7) 3_545
Gd1 Ru 3.4113(8) 7_556
Gd1 Ru 3.4113(8) 7_546
Gd1 Gd2 3.5798(10) 5_655
Gd1 Gd1 3.6766(10) 7_545
Gd2 Ge1 2.9761(8) 3
Gd2 Ge1 2.9761(8) 3_545
Gd2 Ru 3.0685(11) 5_656
Gd2 Ge2 3.0878(8) 3
Gd2 Ge2 3.0878(8) 3_545
Gd2 Ru 3.1429(7) 3
Gd2 Ru 3.1429(7) 3_545
Gd2 Ge1 3.1725(9) 7_546
Gd2 Ge1 3.1725(9) 7_556
Gd2 In 3.4123(7) 3_545
Gd2 In 3.4123(7) 3
Gd2 Ge2 3.4947(12) 5_656
Ru Ge2 2.4626(7) 7_556
Ru Ge2 2.4626(7) 7_546
Ru Ge1 2.5029(12) .
Ru Ge2 2.5078(13) .
Ru Gd2 3.0685(11) 5_656
Ru Gd2 3.1429(7) 3_445
Ru Gd2 3.1429(7) 3_455
Ru Ru 3.1464(10) 7_546
Ru Ru 3.1464(10) 7_556
Ru Gd1 3.1603(10) 1_556
Ru Gd1 3.4113(8) 7_556
Ru Gd1 3.4113(8) 7_546
In Ge1 2.8757(10) 5_556
In Ge1 2.8757(10) 1_554
In Gd1 3.3370(7) 3_445
In Gd1 3.3370(7) 7
In Gd1 3.3370(7) 7_545
In Gd1 3.3370(7) 3_455
In Gd2 3.4122(7) 3_455
In Gd2 3.4122(7) 7_545
In Gd2 3.4122(7) 3_445
In Gd2 3.4122(7) 7
Ge1 Ge1 2.5463(18) 5_556
Ge1 In 2.8757(10) 1_556
Ge1 Gd1 2.9536(8) 7_556
Ge1 Gd1 2.9536(8) 7_546
Ge1 Gd2 2.9761(8) 3_445
Ge1 Gd2 2.9761(8) 3_455
Ge1 Gd2 3.1725(9) 7_546
Ge1 Gd2 3.1725(9) 7_556
Ge2 Ru 2.4626(7) 7_556
Ge2 Ru 2.4626(7) 7_546
Ge2 Gd2 3.0878(8) 3_445
Ge2 Gd2 3.0878(8) 3_455
Ge2 Gd1 3.1055(9) 7_545
Ge2 Gd1 3.1055(9) 7
Ge2 Gd2 3.4947(12) 5_656
