#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342576.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342576
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Tb4 Ru2 In Ge4'
_chemical_formula_sum            'Ge4 In Ru2 Tb4'
_chemical_formula_weight         1243.00
_chemical_name_common
'terbium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'terbium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.6718(8)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.6651(9)
_cell_length_b                   4.2639(2)
_cell_length_c                   6.9895(4)
_cell_measurement_reflns_used    3267
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.07
_cell_measurement_theta_min      2.71
_cell_volume                     447.23(4)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_unetI/netI     0.0236
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.983
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3193
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.983
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.177
_diffrn_reflns_theta_min         2.715
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    50.099
_exptl_absorpt_correction_T_max  0.3367
_exptl_absorpt_correction_T_min  0.0347
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    9.230
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1050
_exptl_crystal_size_max          0.142
_exptl_crystal_size_mid          0.049
_exptl_crystal_size_min          0.030
_refine_diff_density_max         1.835
_refine_diff_density_min         -1.662
_refine_diff_density_rms         0.355
_refine_ls_extinction_coef       0.00081(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         944
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.099
_refine_ls_R_factor_all          0.0206
_refine_ls_R_factor_gt           0.0188
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0202P)²+1.3526P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0422
_refine_ls_wR_factor_ref         0.0429
_reflns_Friedel_coverage         0.000
_reflns_number_gt                894
_reflns_number_total             944
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Tb4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342576
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.053
_shelx_estimated_absorpt_t_max   0.315
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Tb1 Tb 0.34865(2) 0.0000 0.06664(4) 0.00661(8) Uani 1 2 d S T P
Tb2 Tb 0.58726(2) 0.0000 0.38282(4) 0.00629(8) Uani 1 2 d S T P
Ru Ru 0.22007(3) 0.0000 0.63194(6) 0.00579(10) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00938(19) Uani 0.932(3) 4 d S T .
Ge1 Ge 0.06446(4) 0.0000 0.65897(9) 0.00688(12) Uani 1 2 d S T P
Ge2 Ge 0.20247(4) 0.0000 0.26350(9) 0.00729(12) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Tb1 Ge1 93.422(18) 7_556 7_546
Ge1 Tb1 Ge2 88.402(16) 7_556 .
Ge1 Tb1 Ge2 88.402(16) 7_546 .
Ge1 Tb1 Ge2 165.54(2) 7_556 7_545
Ge1 Tb1 Ge2 87.636(13) 7_546 7_545
Ge2 Tb1 Ge2 106.045(14) . 7_545
Ge1 Tb1 Ge2 87.636(13) 7_556 7
Ge1 Tb1 Ge2 165.54(2) 7_546 7
Ge2 Tb1 Ge2 106.045(14) . 7
Ge2 Tb1 Ge2 87.813(17) 7_545 7
Ge1 Tb1 Ru 133.242(9) 7_556 1_554
Ge1 Tb1 Ru 133.242(9) 7_546 1_554
Ge2 Tb1 Ru 94.719(17) . 1_554
Ge2 Tb1 Ru 46.699(10) 7_545 1_554
Ge2 Tb1 Ru 46.699(10) 7 1_554
Ge1 Tb1 In 53.690(13) 7_556 3
Ge1 Tb1 In 110.054(14) 7_546 3
Ge2 Tb1 In 137.441(6) . 3
Ge2 Tb1 In 112.508(13) 7_545 3
Ge2 Tb1 In 59.467(12) 7 3
Ru Tb1 In 98.660(9) 1_554 3
Ge1 Tb1 In 110.054(14) 7_556 3_545
Ge1 Tb1 In 53.690(13) 7_546 3_545
Ge2 Tb1 In 137.441(6) . 3_545
Ge2 Tb1 In 59.467(12) 7_545 3_545
Ge2 Tb1 In 112.508(13) 7 3_545
Ru Tb1 In 98.660(9) 1_554 3_545
In Tb1 In 79.928(7) 3 3_545
Ge1 Tb1 Ru 45.943(14) 7_556 7_556
Ge1 Tb1 Ru 102.832(14) 7_546 7_556
Ge2 Tb1 Ru 44.850(9) . 7_556
Ge2 Tb1 Ru 147.523(17) 7_545 7_556
Ge2 Tb1 Ru 88.253(12) 7 7_556
Ru Tb1 Ru 111.950(10) 1_554 7_556
In Tb1 Ru 92.886(7) 3 7_556
In Tb1 Ru 149.309(11) 3_545 7_556
Ge1 Tb1 Ru 102.832(14) 7_556 7_546
Ge1 Tb1 Ru 45.943(14) 7_546 7_546
Ge2 Tb1 Ru 44.850(9) . 7_546
Ge2 Tb1 Ru 88.253(12) 7_545 7_546
Ge2 Tb1 Ru 147.523(17) 7 7_546
Ru Tb1 Ru 111.950(10) 1_554 7_546
In Tb1 Ru 149.309(11) 3 7_546
In Tb1 Ru 92.886(7) 3_545 7_546
Ru Tb1 Ru 78.133(11) 7_556 7_546
Ge1 Tb1 Tb2 112.449(14) 7_556 5_655
Ge1 Tb1 Tb2 112.449(14) 7_546 5_655
Ge2 Tb1 Tb2 148.488(15) . 5_655
Ge2 Tb1 Tb2 54.310(11) 7_545 5_655
Ge2 Tb1 Tb2 54.310(11) 7 5_655
Ru Tb1 Tb2 53.769(11) 1_554 5_655
In Tb1 Tb2 58.854(5) 3 5_655
In Tb1 Tb2 58.854(5) 3_545 5_655
Ru Tb1 Tb2 140.341(6) 7_556 5_655
Ru Tb1 Tb2 140.341(6) 7_546 5_655
Ge1 Tb1 Tb1 142.468(18) 7_556 7_545
Ge1 Tb1 Tb1 86.697(11) 7_546 7_545
Ge2 Tb1 Tb1 54.069(11) . 7_545
Ge2 Tb1 Tb1 51.976(13) 7_545 7_545
Ge2 Tb1 Tb1 101.210(15) 7 7_545
Ru Tb1 Tb1 59.309(9) 1_554 7_545
In Tb1 Tb1 157.866(12) 3 7_545
In Tb1 Tb1 100.120(5) 3_545 7_545
Ru Tb1 Tb1 97.450(12) 7_556 7_545
Ru Tb1 Tb1 52.641(9) 7_546 7_545
Tb2 Tb1 Tb1 101.962(10) 5_655 7_545
Ge1 Tb2 Ge1 91.933(19) 3 3_545
Ge1 Tb2 Ru 109.101(14) 3 5_656
Ge1 Tb2 Ru 109.101(14) 3_545 5_656
Ge1 Tb2 Ge2 82.362(14) 3 3
Ge1 Tb2 Ge2 150.339(19) 3_545 3
Ru Tb2 Ge2 47.455(11) 5_656 3
Ge1 Tb2 Ge2 150.339(19) 3 3_545
Ge1 Tb2 Ge2 82.362(14) 3_545 3_545
Ru Tb2 Ge2 47.455(11) 5_656 3_545
Ge2 Tb2 Ge2 88.340(18) 3 3_545
Ge1 Tb2 Ru 48.258(14) 3 3
Ge1 Tb2 Ru 108.186(15) 3_545 3
Ru Tb2 Ru 60.867(12) 5_656 3
Ge2 Tb2 Ru 47.788(14) 3 3
Ge2 Tb2 Ru 106.014(15) 3_545 3
Ge1 Tb2 Ru 108.186(15) 3 3_545
Ge1 Tb2 Ru 48.258(14) 3_545 3_545
Ru Tb2 Ru 60.867(11) 5_656 3_545
Ge2 Tb2 Ru 106.014(15) 3 3_545
Ge2 Tb2 Ru 47.788(14) 3_545 3_545
Ru Tb2 Ru 85.701(13) 3 3_545
Ge1 Tb2 Ge1 108.606(11) 3 7_546
Ge1 Tb2 Ge1 48.99(2) 3_545 7_546
Ru Tb2 Ge1 136.565(9) 5_656 7_546
Ge2 Tb2 Ge1 159.497(19) 3 7_546
Ge2 Tb2 Ge1 89.511(13) 3_545 7_546
Ru Tb2 Ge1 151.224(16) 3 7_546
Ru Tb2 Ge1 87.361(11) 3_545 7_546
Ge1 Tb2 Ge1 48.99(2) 3 7_556
Ge1 Tb2 Ge1 108.606(11) 3_545 7_556
Ru Tb2 Ge1 136.565(9) 5_656 7_556
Ge2 Tb2 Ge1 89.511(13) 3 7_556
Ge2 Tb2 Ge1 159.497(19) 3_545 7_556
Ru Tb2 Ge1 87.361(11) 3 7_556
Ru Tb2 Ge1 151.224(16) 3_545 7_556
Ge1 Tb2 Ge1 85.415(17) 7_546 7_556
Ge1 Tb2 In 150.453(15) 3 3_545
Ge1 Tb2 In 87.994(10) 3_545 3_545
Ru Tb2 In 98.760(9) 5_656 3_545
Ge2 Tb2 In 111.048(13) 3 3_545
Ge2 Tb2 In 58.806(12) 3_545 3_545
Ru Tb2 In 156.909(12) 3 3_545
Ru Tb2 In 93.659(7) 3_545 3_545
Ge1 Tb2 In 51.445(11) 7_546 3_545
Ge1 Tb2 In 103.326(12) 7_556 3_545
Ge1 Tb2 In 87.994(10) 3 3
Ge1 Tb2 In 150.453(15) 3_545 3
Ru Tb2 In 98.760(9) 5_656 3
Ge2 Tb2 In 58.806(12) 3 3
Ge2 Tb2 In 111.048(13) 3_545 3
Ru Tb2 In 93.659(7) 3 3
Ru Tb2 In 156.909(12) 3_545 3
Ge1 Tb2 In 103.326(12) 7_546 3
Ge1 Tb2 In 51.445(11) 7_556 3
In Tb2 In 78.008(7) 3_545 3
Ge1 Tb2 Tb1 133.720(10) 3 5_655
Ge1 Tb2 Tb1 133.720(10) 3_545 5_655
Ru Tb2 Tb1 55.805(10) 5_656 5_655
Ge2 Tb2 Tb1 54.692(11) 3 5_655
Ge2 Tb2 Tb1 54.692(11) 3_545 5_655
Ru Tb2 Tb1 100.357(11) 3 5_655
Ru Tb2 Tb1 100.357(11) 3_545 5_655
Ge1 Tb2 Tb1 108.359(13) 7_546 5_655
Ge1 Tb2 Tb1 108.359(13) 7_556 5_655
In Tb2 Tb1 56.995(5) 3_545 5_655
In Tb2 Tb1 56.995(6) 3 5_655
Ge2 Ru Ge2 120.29(3) 7_556 7_546
Ge2 Ru Ge1 112.745(18) 7_556 .
Ge2 Ru Ge1 112.745(18) 7_546 .
Ge2 Ru Ge2 101.805(18) 7_556 .
Ge2 Ru Ge2 101.805(18) 7_546 .
Ge1 Ru Ge2 104.78(3) . .
Ge2 Ru Tb2 66.492(17) 7_556 5_656
Ge2 Ru Tb2 66.492(17) 7_546 5_656
Ge1 Ru Tb2 177.70(2) . 5_656
Ge2 Ru Tb2 77.51(2) . 5_656
Ge2 Ru Tb1 65.525(16) 7_556 1_556
Ge2 Ru Tb1 65.525(16) 7_546 1_556
Ge1 Ru Tb1 107.28(2) . 1_556
Ge2 Ru Tb1 147.94(2) . 1_556
Tb2 Ru Tb1 70.426(12) 5_656 1_556
Ge2 Ru Ru 124.02(3) 7_556 7_546
Ge2 Ru Ru 51.637(16) 7_546 7_546
Ge1 Ru Ru 120.513(19) . 7_546
Ge2 Ru Ru 50.168(14) . 7_546
Tb2 Ru Ru 60.913(15) 5_656 7_546
Tb1 Ru Ru 110.722(18) 1_556 7_546
Ge2 Ru Ru 51.637(16) 7_556 7_556
Ge2 Ru Ru 124.02(3) 7_546 7_556
Ge1 Ru Ru 120.513(19) . 7_556
Ge2 Ru Ru 50.168(14) . 7_556
Tb2 Ru Ru 60.913(15) 5_656 7_556
Tb1 Ru Ru 110.722(18) 1_556 7_556
Ru Ru Ru 85.75(2) 7_546 7_556
Ge2 Ru Tb2 161.315(19) 7_556 3_445
Ge2 Ru Tb2 76.565(14) 7_546 3_445
Ge1 Ru Tb2 62.324(13) . 3_445
Ge2 Ru Tb2 64.537(13) . 3_445
Tb2 Ru Tb2 119.133(11) 5_656 3_445
Tb1 Ru Tb2 132.811(9) 1_556 3_445
Ru Ru Tb2 58.220(12) 7_546 3_445
Ru Ru Tb2 113.50(2) 7_556 3_445
Ge2 Ru Tb2 76.565(14) 7_556 3_455
Ge2 Ru Tb2 161.315(19) 7_546 3_455
Ge1 Ru Tb2 62.324(13) . 3_455
Ge2 Ru Tb2 64.537(13) . 3_455
Tb2 Ru Tb2 119.133(11) 5_656 3_455
Tb1 Ru Tb2 132.811(9) 1_556 3_455
Ru Ru Tb2 113.50(2) 7_546 3_455
Ru Ru Tb2 58.220(12) 7_556 3_455
Tb2 Ru Tb2 85.701(13) 3_445 3_455
Ge2 Ru Tb1 59.097(16) 7_556 7_556
Ge2 Ru Tb1 125.42(2) 7_546 7_556
Ge1 Ru Tb1 57.398(12) . 7_556
Ge2 Ru Tb1 132.689(13) . 7_556
Tb2 Ru Tb1 121.061(12) 5_656 7_556
Tb1 Ru Tb1 68.050(10) 1_556 7_556
Ru Ru Tb1 176.192(16) 7_546 7_556
Ru Ru Tb1 98.060(8) 7_556 7_556
Tb2 Ru Tb1 119.699(15) 3_445 7_556
Tb2 Ru Tb1 68.792(9) 3_455 7_556
Ge2 Ru Tb1 125.42(2) 7_556 7_546
Ge2 Ru Tb1 59.097(16) 7_546 7_546
Ge1 Ru Tb1 57.398(12) . 7_546
Ge2 Ru Tb1 132.689(13) . 7_546
Tb2 Ru Tb1 121.062(12) 5_656 7_546
Tb1 Ru Tb1 68.050(10) 1_556 7_546
Ru Ru Tb1 98.060(8) 7_546 7_546
Ru Ru Tb1 176.192(16) 7_556 7_546
Tb2 Ru Tb1 68.792(9) 3_445 7_546
Tb2 Ru Tb1 119.699(15) 3_455 7_546
Tb1 Ru Tb1 78.133(11) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Tb1 56.119(8) 5_556 3_445
Ge1 In Tb1 123.881(8) 1_554 3_445
Ge1 In Tb1 123.881(8) 5_556 7
Ge1 In Tb1 56.119(8) 1_554 7
Tb1 In Tb1 180.0 3_445 7
Ge1 In Tb1 123.881(8) 5_556 7_545
Ge1 In Tb1 56.119(8) 1_554 7_545
Tb1 In Tb1 100.072(7) 3_445 7_545
Tb1 In Tb1 79.928(7) 7 7_545
Ge1 In Tb1 56.119(8) 5_556 3_455
Ge1 In Tb1 123.881(8) 1_554 3_455
Tb1 In Tb1 79.928(7) 3_445 3_455
Tb1 In Tb1 100.072(7) 7 3_455
Tb1 In Tb1 180.0 7_545 3_455
Ge1 In Tb2 59.841(9) 5_556 3_455
Ge1 In Tb2 120.159(9) 1_554 3_455
Tb1 In Tb2 115.850(6) 3_445 3_455
Tb1 In Tb2 64.150(6) 7 3_455
Tb1 In Tb2 111.869(6) 7_545 3_455
Tb1 In Tb2 68.131(6) 3_455 3_455
Ge1 In Tb2 120.159(9) 5_556 7_545
Ge1 In Tb2 59.841(9) 1_554 7_545
Tb1 In Tb2 64.150(6) 3_445 7_545
Tb1 In Tb2 115.850(6) 7 7_545
Tb1 In Tb2 68.131(6) 7_545 7_545
Tb1 In Tb2 111.869(6) 3_455 7_545
Tb2 In Tb2 180.0 3_455 7_545
Ge1 In Tb2 59.841(10) 5_556 3_445
Ge1 In Tb2 120.159(10) 1_554 3_445
Tb1 In Tb2 68.131(6) 3_445 3_445
Tb1 In Tb2 111.869(6) 7 3_445
Tb1 In Tb2 64.150(6) 7_545 3_445
Tb1 In Tb2 115.850(6) 3_455 3_445
Tb2 In Tb2 78.008(7) 3_455 3_445
Tb2 In Tb2 101.992(7) 7_545 3_445
Ge1 In Tb2 120.159(10) 5_556 7
Ge1 In Tb2 59.841(10) 1_554 7
Tb1 In Tb2 111.869(6) 3_445 7
Tb1 In Tb2 68.131(6) 7 7
Tb1 In Tb2 115.850(6) 7_545 7
Tb1 In Tb2 64.150(6) 3_455 7
Tb2 In Tb2 101.992(7) 3_455 7
Tb2 In Tb2 78.008(7) 7_545 7
Tb2 In Tb2 180.0 3_445 7
Ru Ge1 Ge1 118.84(4) . 5_556
Ru Ge1 In 130.72(2) . 1_556
Ge1 Ge1 In 110.45(3) 5_556 1_556
Ru Ge1 Tb1 76.660(16) . 7_556
Ge1 Ge1 Tb1 132.603(11) 5_556 7_556
In Ge1 Tb1 70.191(14) 1_556 7_556
Ru Ge1 Tb1 76.660(16) . 7_546
Ge1 Ge1 Tb1 132.603(11) 5_556 7_546
In Ge1 Tb1 70.191(14) 1_556 7_546
Tb1 Ge1 Tb1 93.422(18) 7_556 7_546
Ru Ge1 Tb2 69.419(15) . 3_445
Ge1 Ge1 Tb2 69.161(19) 5_556 3_445
In Ge1 Tb2 133.141(10) 1_556 3_445
Tb1 Ge1 Tb2 146.04(2) 7_556 3_445
Tb1 Ge1 Tb2 77.452(9) 7_546 3_445
Ru Ge1 Tb2 69.419(15) . 3_455
Ge1 Ge1 Tb2 69.161(19) 5_556 3_455
In Ge1 Tb2 133.141(10) 1_556 3_455
Tb1 Ge1 Tb2 77.452(9) 7_556 3_455
Tb1 Ge1 Tb2 146.04(2) 7_546 3_455
Tb2 Ge1 Tb2 91.933(19) 3_445 3_455
Ru Ge1 Tb2 136.142(10) . 7_546
Ge1 Ge1 Tb2 61.847(18) 5_556 7_546
In Ge1 Tb2 68.713(13) 1_556 7_546
Tb1 Ge1 Tb2 138.72(2) 7_556 7_546
Tb1 Ge1 Tb2 76.356(10) 7_546 7_546
Tb2 Ge1 Tb2 71.394(11) 3_445 7_546
Tb2 Ge1 Tb2 131.01(2) 3_455 7_546
Ru Ge1 Tb2 136.142(10) . 7_556
Ge1 Ge1 Tb2 61.848(18) 5_556 7_556
In Ge1 Tb2 68.713(13) 1_556 7_556
Tb1 Ge1 Tb2 76.356(10) 7_556 7_556
Tb1 Ge1 Tb2 138.72(2) 7_546 7_556
Tb2 Ge1 Tb2 131.01(2) 3_445 7_556
Tb2 Ge1 Tb2 71.394(11) 3_455 7_556
Tb2 Ge1 Tb2 85.413(17) 7_546 7_556
Ru Ge2 Ru 120.29(3) 7_556 7_546
Ru Ge2 Ru 78.194(18) 7_556 .
Ru Ge2 Ru 78.194(18) 7_546 .
Ru Ge2 Tb1 76.054(18) 7_556 .
Ru Ge2 Tb1 76.054(18) 7_546 .
Ru Ge2 Tb1 126.78(3) . .
Ru Ge2 Tb2 143.39(3) 7_556 3_445
Ru Ge2 Tb2 66.054(13) 7_546 3_445
Ru Ge2 Tb2 67.674(15) . 3_445
Tb1 Ge2 Tb2 135.623(9) . 3_445
Ru Ge2 Tb2 66.054(13) 7_556 3_455
Ru Ge2 Tb2 143.39(3) 7_546 3_455
Ru Ge2 Tb2 67.674(15) . 3_455
Tb1 Ge2 Tb2 135.623(9) . 3_455
Tb2 Ge2 Tb2 88.340(18) 3_445 3_455
Ru Ge2 Tb1 145.55(3) 7_556 7_545
Ru Ge2 Tb1 67.776(12) 7_546 7_545
Ru Ge2 Tb1 134.298(11) . 7_545
Tb1 Ge2 Tb1 73.955(14) . 7_545
Tb2 Ge2 Tb1 70.997(10) 3_445 7_545
Tb2 Ge2 Tb1 129.85(2) 3_455 7_545
Ru Ge2 Tb1 67.776(12) 7_556 7
Ru Ge2 Tb1 145.55(3) 7_546 7
Ru Ge2 Tb1 134.298(11) . 7
Tb1 Ge2 Tb1 73.955(14) . 7
Tb2 Ge2 Tb1 129.85(2) 3_445 7
Tb2 Ge2 Tb1 70.997(10) 3_455 7
Tb1 Ge2 Tb1 87.814(17) 7_545 7
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 Ge1 2.9289(4) 7_556
Tb1 Ge1 2.9289(4) 7_546
Tb1 Ge2 2.9908(7) .
Tb1 Ge2 3.0743(5) 7_545
Tb1 Ge2 3.0743(5) 7
Tb1 Ru 3.1269(5) 1_554
Tb1 In 3.3192(2) 3
Tb1 In 3.3192(2) 3_545
Tb1 Ru 3.3829(4) 7_556
Tb1 Ru 3.3829(4) 7_546
Tb1 Tb2 3.5619(4) 5_655
Tb1 Tb1 3.6487(5) 7_545
Tb2 Ge1 2.9654(5) 3
Tb2 Ge1 2.9654(5) 3_545
Tb2 Ru 3.0494(6) 5_656
Tb2 Ge2 3.0597(5) 3
Tb2 Ge2 3.0597(5) 3_545
Tb2 Ru 3.1348(4) 3
Tb2 Ru 3.1348(4) 3_545
Tb2 Ge1 3.1433(5) 7_546
Tb2 Ge1 3.1433(5) 7_556
Tb2 In 3.3874(2) 3_545
Tb2 In 3.3874(2) 3
Tb2 Tb1 3.5619(4) 5_655
Ru Ge2 2.4582(4) 7_556
Ru Ge2 2.4582(4) 7_546
Ru Ge1 2.4985(8) .
Ru Ge2 2.5100(8) .
Ru Tb2 3.0494(6) 5_656
Ru Tb1 3.1268(5) 1_556
Ru Ru 3.1334(6) 7_546
Ru Ru 3.1334(6) 7_556
Ru Tb2 3.1348(4) 3_445
Ru Tb2 3.1348(4) 3_455
Ru Tb1 3.3829(4) 7_556
Ru Tb1 3.3829(4) 7_546
In Ge1 2.8429(6) 5_556
In Ge1 2.8429(6) 1_554
In Tb1 3.3192(2) 3_445
In Tb1 3.3192(2) 7
In Tb1 3.3192(2) 7_545
In Tb1 3.3192(2) 3_455
In Tb2 3.3874(2) 3_455
In Tb2 3.3874(2) 7_545
In Tb2 3.3874(2) 3_445
In Tb2 3.3874(2) 7
Ge1 Ge1 2.5380(12) 5_556
Ge1 In 2.8429(6) 1_556
Ge1 Tb1 2.9289(4) 7_556
Ge1 Tb1 2.9289(4) 7_546
Ge1 Tb2 2.9654(5) 3_445
Ge1 Tb2 2.9654(5) 3_455
Ge1 Tb2 3.1433(5) 7_546
Ge1 Tb2 3.1433(5) 7_556
Ge2 Ru 2.4582(4) 7_556
Ge2 Ru 2.4582(4) 7_546
Ge2 Tb2 3.0597(5) 3_445
Ge2 Tb2 3.0597(5) 3_455
Ge2 Tb1 3.0742(5) 7_545
Ge2 Tb1 3.0742(5) 7
