#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342577.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342577
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Dy4 Ru2 In Ge4'
_chemical_formula_sum            'Dy4 Ge4 In Ru2'
_chemical_formula_weight         1257.32
_chemical_name_common
'dysprosium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'dysprosium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.728(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.612(3)
_cell_length_b                   4.2519(9)
_cell_length_c                   6.9641(15)
_cell_measurement_reflns_used    1834
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.06
_cell_measurement_theta_min      2.72
_cell_volume                     442.72(16)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0414
_diffrn_reflns_av_unetI/netI     0.0368
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3134
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.091
_diffrn_reflns_theta_min         2.725
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    52.416
_exptl_absorpt_correction_T_max  0.4296
_exptl_absorpt_correction_T_min  0.0838
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    9.432
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1058
_exptl_crystal_size_max          0.067
_exptl_crystal_size_mid          0.030
_exptl_crystal_size_min          0.025
_refine_diff_density_max         1.989
_refine_diff_density_min         -2.681
_refine_diff_density_rms         0.472
_refine_ls_extinction_coef       0.00094(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         928
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0294
_refine_ls_R_factor_gt           0.0235
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0201P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0496
_refine_ls_wR_factor_ref         0.0514
_reflns_Friedel_coverage         0.000
_reflns_number_gt                815
_reflns_number_total             928
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Dy4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_original_cell_volume        442.73(16)
_cod_database_code               4342577
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.127
_shelx_estimated_absorpt_t_max   0.354
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Dy1 Dy 0.34834(2) 0.0000 0.06710(6) 0.00655(10) Uani 1 2 d S T P
Dy2 Dy 0.58756(2) 0.0000 0.38425(6) 0.00610(10) Uani 1 2 d S T P
Ru Ru 0.22032(4) 0.0000 0.63215(10) 0.00572(13) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0081(2) Uani 0.961(4) 4 d S T .
Ge1 Ge 0.06451(5) 0.0000 0.65897(14) 0.00663(17) Uani 1 2 d S T P
Ge2 Ge 0.20184(6) 0.0000 0.26189(14) 0.00730(17) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Dy1 Ge1 93.52(3) 7_556 7_546
Ge1 Dy1 Ge2 88.68(3) 7_556 .
Ge1 Dy1 Ge2 88.68(3) 7_546 .
Ge1 Dy1 Ge2 165.25(3) 7_556 7_545
Ge1 Dy1 Ge2 87.36(2) 7_546 7_545
Ge2 Dy1 Ge2 106.07(2) . 7_545
Ge1 Dy1 Ge2 87.36(2) 7_556 7
Ge1 Dy1 Ge2 165.25(3) 7_546 7
Ge2 Dy1 Ge2 106.07(2) . 7
Ge2 Dy1 Ge2 88.10(3) 7_545 7
Ge1 Dy1 Ru 133.177(16) 7_556 1_554
Ge1 Dy1 Ru 133.177(16) 7_546 1_554
Ge2 Dy1 Ru 94.65(3) . 1_554
Ge2 Dy1 Ru 46.875(17) 7_545 1_554
Ge2 Dy1 Ru 46.875(17) 7 1_554
Ge1 Dy1 In 53.64(2) 7_556 3
Ge1 Dy1 In 110.00(2) 7_546 3
Ge2 Dy1 In 137.588(11) . 3
Ge2 Dy1 In 112.32(2) 7_545 3
Ge2 Dy1 In 59.180(19) 7 3
Ru Dy1 In 98.483(16) 1_554 3
Ge1 Dy1 In 110.00(2) 7_556 3_545
Ge1 Dy1 In 53.64(2) 7_546 3_545
Ge2 Dy1 In 137.588(11) . 3_545
Ge2 Dy1 In 59.180(19) 7_545 3_545
Ge2 Dy1 In 112.32(2) 7 3_545
Ru Dy1 In 98.483(16) 1_554 3_545
In Dy1 In 79.814(18) 3 3_545
Ge1 Dy1 Ru 46.03(2) 7_556 7_556
Ge1 Dy1 Ru 103.02(3) 7_546 7_556
Ge2 Dy1 Ru 44.991(14) . 7_556
Ge2 Dy1 Ru 147.77(2) 7_545 7_556
Ge2 Dy1 Ru 88.19(2) 7 7_556
Ru Dy1 Ru 112.026(19) 1_554 7_556
In Dy1 Ru 92.921(15) 3 7_556
In Dy1 Ru 149.395(17) 3_545 7_556
Ge1 Dy1 Ru 103.02(3) 7_556 7_546
Ge1 Dy1 Ru 46.03(2) 7_546 7_546
Ge2 Dy1 Ru 44.991(14) . 7_546
Ge2 Dy1 Ru 88.19(2) 7_545 7_546
Ge2 Dy1 Ru 147.77(2) 7 7_546
Ru Dy1 Ru 112.025(19) 1_554 7_546
In Dy1 Ru 149.395(17) 3 7_546
In Dy1 Ru 92.921(16) 3_545 7_546
Ru Dy1 Ru 78.26(2) 7_556 7_546
Ge1 Dy1 Dy2 112.35(2) 7_556 5_655
Ge1 Dy1 Dy2 112.35(2) 7_546 5_655
Ge2 Dy1 Dy2 148.22(2) . 5_655
Ge2 Dy1 Dy2 54.223(18) 7_545 5_655
Ge2 Dy1 Dy2 54.223(18) 7 5_655
Ru Dy1 Dy2 53.56(2) 1_554 5_655
In Dy1 Dy2 58.803(8) 3 5_655
In Dy1 Dy2 58.803(8) 3_545 5_655
Ru Dy1 Dy2 140.266(11) 7_556 5_655
Ru Dy1 Dy2 140.266(11) 7_546 5_655
Ge1 Dy1 Dy1 142.74(2) 7_556 7_545
Ge1 Dy1 Dy1 86.69(2) 7_546 7_545
Ge2 Dy1 Dy1 54.062(19) . 7_545
Ge2 Dy1 Dy1 52.005(18) 7_545 7_545
Ge2 Dy1 Dy1 101.48(2) 7 7_545
Ru Dy1 Dy1 59.374(15) 1_554 7_545
In Dy1 Dy1 157.739(19) 3 7_545
In Dy1 Dy1 100.010(17) 3_545 7_545
Ru Dy1 Dy1 97.63(2) 7_556 7_545
Ru Dy1 Dy1 52.651(16) 7_546 7_545
Dy2 Dy1 Dy1 101.802(17) 5_655 7_545
Ge1 Dy2 Ge1 92.20(3) 3 3_545
Ge1 Dy2 Ru 109.31(2) 3 5_656
Ge1 Dy2 Ru 109.31(2) 3_545 5_656
Ge1 Dy2 Ge2 82.49(2) 3 3
Ge1 Dy2 Ge2 150.88(3) 3_545 3
Ru Dy2 Ge2 47.580(16) 5_656 3
Ge1 Dy2 Ge2 150.88(3) 3 3_545
Ge1 Dy2 Ge2 82.49(2) 3_545 3_545
Ru Dy2 Ge2 47.580(16) 5_656 3_545
Ge2 Dy2 Ge2 88.37(3) 3 3_545
Ge1 Dy2 Ru 48.39(2) 3 3
Ge1 Dy2 Ru 108.52(3) 3_545 3
Ru Dy2 Ru 60.948(18) 5_656 3
Ge2 Dy2 Ru 48.00(2) 3 3
Ge2 Dy2 Ru 106.29(3) 3_545 3
Ge1 Dy2 Ru 108.52(3) 3 3_545
Ge1 Dy2 Ru 48.39(2) 3_545 3_545
Ru Dy2 Ru 60.948(18) 5_656 3_545
Ge2 Dy2 Ru 106.29(3) 3 3_545
Ge2 Dy2 Ru 48.00(2) 3_545 3_545
Ru Dy2 Ru 85.89(2) 3 3_545
Ge1 Dy2 Ge1 108.691(18) 3 7_546
Ge1 Dy2 Ge1 48.97(3) 3_545 7_546
Ru Dy2 Ge1 136.520(14) 5_656 7_546
Ge2 Dy2 Ge1 158.93(3) 3 7_546
Ge2 Dy2 Ge1 89.33(2) 3_545 7_546
Ru Dy2 Ge1 151.51(2) 3 7_546
Ru Dy2 Ge1 87.43(2) 3_545 7_546
Ge1 Dy2 Ge1 48.97(3) 3 7_556
Ge1 Dy2 Ge1 108.691(18) 3_545 7_556
Ru Dy2 Ge1 136.520(15) 5_656 7_556
Ge2 Dy2 Ge1 89.33(2) 3 7_556
Ge2 Dy2 Ge1 158.93(3) 3_545 7_556
Ru Dy2 Ge1 87.43(2) 3 7_556
Ru Dy2 Ge1 151.51(2) 3_545 7_556
Ge1 Dy2 Ge1 85.36(3) 7_546 7_556
Ge1 Dy2 In 150.32(2) 3 3_545
Ge1 Dy2 In 87.89(2) 3_545 3_545
Ru Dy2 In 98.567(14) 5_656 3_545
Ge2 Dy2 In 110.65(2) 3 3_545
Ge2 Dy2 In 58.45(2) 3_545 3_545
Ru Dy2 In 156.733(17) 3 3_545
Ru Dy2 In 93.572(17) 3_545 3_545
Ge1 Dy2 In 51.367(18) 7_546 3_545
Ge1 Dy2 In 103.16(2) 7_556 3_545
Ge1 Dy2 In 87.89(2) 3 3
Ge1 Dy2 In 150.32(2) 3_545 3
Ru Dy2 In 98.567(14) 5_656 3
Ge2 Dy2 In 58.45(2) 3 3
Ge2 Dy2 In 110.65(2) 3_545 3
Ru Dy2 In 93.572(17) 3 3
Ru Dy2 In 156.733(17) 3_545 3
Ge1 Dy2 In 103.16(2) 7_546 3
Ge1 Dy2 In 51.367(18) 7_556 3
In Dy2 In 77.873(18) 3_545 3
Ge1 Dy2 Dy2 56.780(17) 3 5_656
Ge1 Dy2 Dy2 56.780(17) 3_545 5_656
Ru Dy2 Dy2 156.30(2) 5_656 5_656
Ge2 Dy2 Dy2 135.683(14) 3 5_656
Ge2 Dy2 Dy2 135.683(14) 3_545 5_656
Ru Dy2 Dy2 102.97(2) 3 5_656
Ru Dy2 Dy2 102.97(2) 3_545 5_656
Ge1 Dy2 Dy2 51.911(17) 7_546 5_656
Ge1 Dy2 Dy2 51.911(17) 7_556 5_656
In Dy2 Dy2 99.818(16) 3_545 5_656
In Dy2 Dy2 99.818(16) 3 5_656
Ge2 Ru Ge2 120.03(5) 7_556 7_546
Ge2 Ru Ge1 112.76(2) 7_556 .
Ge2 Ru Ge1 112.76(3) 7_546 .
Ge2 Ru Ge2 102.08(3) 7_556 .
Ge2 Ru Ge2 102.08(3) 7_546 .
Ge1 Ru Ge2 104.53(4) . .
Ge2 Ru Dy2 66.55(2) 7_556 5_656
Ge2 Ru Dy2 66.55(2) 7_546 5_656
Ge1 Ru Dy2 177.95(3) . 5_656
Ge2 Ru Dy2 77.52(3) . 5_656
Ge2 Ru Dy1 65.40(2) 7_556 1_556
Ge2 Ru Dy1 65.40(2) 7_546 1_556
Ge1 Ru Dy1 107.11(3) . 1_556
Ge2 Ru Dy1 148.36(3) . 1_556
Dy2 Ru Dy1 70.84(2) 5_656 1_556
Ge2 Ru Dy2 161.62(3) 7_556 3_445
Ge2 Ru Dy2 76.63(2) 7_546 3_445
Ge1 Ru Dy2 62.24(2) . 3_445
Ge2 Ru Dy2 64.54(2) . 3_445
Dy2 Ru Dy2 119.052(18) 5_656 3_445
Dy1 Ru Dy2 132.591(15) 1_556 3_445
Ge2 Ru Dy2 76.63(2) 7_556 3_455
Ge2 Ru Dy2 161.62(3) 7_546 3_455
Ge1 Ru Dy2 62.24(2) . 3_455
Ge2 Ru Dy2 64.54(2) . 3_455
Dy2 Ru Dy2 119.052(18) 5_656 3_455
Dy1 Ru Dy2 132.591(15) 1_556 3_455
Dy2 Ru Dy2 85.89(2) 3_445 3_455
Ge2 Ru Ru 124.17(4) 7_556 7_546
Ge2 Ru Ru 51.84(3) 7_546 7_546
Ge1 Ru Ru 120.39(3) . 7_546
Ge2 Ru Ru 50.24(2) . 7_546
Dy2 Ru Ru 60.89(2) 5_656 7_546
Dy1 Ru Ru 110.94(3) 1_556 7_546
Dy2 Ru Ru 58.17(2) 3_445 7_546
Dy2 Ru Ru 113.60(3) 3_455 7_546
Ge2 Ru Ru 51.84(3) 7_556 7_556
Ge2 Ru Ru 124.17(4) 7_546 7_556
Ge1 Ru Ru 120.39(3) . 7_556
Ge2 Ru Ru 50.24(2) . 7_556
Dy2 Ru Ru 60.89(2) 5_656 7_556
Dy1 Ru Ru 110.94(3) 1_556 7_556
Dy2 Ru Ru 113.60(3) 3_445 7_556
Dy2 Ru Ru 58.17(2) 3_455 7_556
Ru Ru Ru 85.83(3) 7_546 7_556
Ge2 Ru Dy1 59.01(2) 7_556 7_556
Ge2 Ru Dy1 125.33(3) 7_546 7_556
Ge1 Ru Dy1 57.410(18) . 7_556
Ge2 Ru Dy1 132.491(19) . 7_556
Dy2 Ru Dy1 121.220(17) 5_656 7_556
Dy1 Ru Dy1 67.976(19) 1_556 7_556
Dy2 Ru Dy1 119.63(2) 3_445 7_556
Dy2 Ru Dy1 68.557(18) 3_455 7_556
Ru Ru Dy1 176.21(2) 7_546 7_556
Ru Ru Dy1 97.954(18) 7_556 7_556
Ge2 Ru Dy1 125.33(3) 7_556 7_546
Ge2 Ru Dy1 59.01(2) 7_546 7_546
Ge1 Ru Dy1 57.410(18) . 7_546
Ge2 Ru Dy1 132.491(19) . 7_546
Dy2 Ru Dy1 121.220(17) 5_656 7_546
Dy1 Ru Dy1 67.976(19) 1_556 7_546
Dy2 Ru Dy1 68.557(18) 3_445 7_546
Dy2 Ru Dy1 119.63(2) 3_455 7_546
Ru Ru Dy1 97.954(18) 7_546 7_546
Ru Ru Dy1 176.21(2) 7_556 7_546
Dy1 Ru Dy1 78.26(2) 7_556 7_546
Ge1 In Ge1 180.00(3) 5_556 1_554
Ge1 In Ge2 87.00(3) 5_556 5
Ge1 In Ge2 93.00(3) 1_554 5
Ge1 In Ge2 93.00(3) 5_556 .
Ge1 In Ge2 87.00(3) 1_554 .
Ge2 In Ge2 180.0 5 .
Ge1 In Dy1 56.022(13) 5_556 3_445
Ge1 In Dy1 123.978(13) 1_554 3_445
Ge2 In Dy1 56.361(16) 5 3_445
Ge2 In Dy1 123.639(16) . 3_445
Ge1 In Dy1 123.978(13) 5_556 7
Ge1 In Dy1 56.022(13) 1_554 7
Ge2 In Dy1 123.639(16) 5 7
Ge2 In Dy1 56.361(16) . 7
Dy1 In Dy1 180.0 3_445 7
Ge1 In Dy1 56.022(13) 5_556 3_455
Ge1 In Dy1 123.978(13) 1_554 3_455
Ge2 In Dy1 56.361(16) 5 3_455
Ge2 In Dy1 123.639(16) . 3_455
Dy1 In Dy1 79.815(18) 3_445 3_455
Dy1 In Dy1 100.185(18) 7 3_455
Ge1 In Dy1 123.978(13) 5_556 7_545
Ge1 In Dy1 56.022(13) 1_554 7_545
Ge2 In Dy1 123.639(16) 5 7_545
Ge2 In Dy1 56.361(16) . 7_545
Dy1 In Dy1 100.185(18) 3_445 7_545
Dy1 In Dy1 79.815(18) 7 7_545
Dy1 In Dy1 180.0 3_455 7_545
Ge1 In Dy2 59.818(17) 5_556 3_455
Ge1 In Dy2 120.182(17) 1_554 3_455
Ge2 In Dy2 124.500(13) 5 3_455
Ge2 In Dy2 55.500(13) . 3_455
Dy1 In Dy2 115.726(14) 3_445 3_455
Dy1 In Dy2 64.274(14) 7 3_455
Dy1 In Dy2 68.142(14) 3_455 3_455
Dy1 In Dy2 111.858(14) 7_545 3_455
Ge1 In Dy2 120.182(17) 5_556 7_545
Ge1 In Dy2 59.818(17) 1_554 7_545
Ge2 In Dy2 55.500(13) 5 7_545
Ge2 In Dy2 124.500(13) . 7_545
Dy1 In Dy2 64.274(14) 3_445 7_545
Dy1 In Dy2 115.726(14) 7 7_545
Dy1 In Dy2 111.858(14) 3_455 7_545
Dy1 In Dy2 68.142(14) 7_545 7_545
Dy2 In Dy2 180.000(10) 3_455 7_545
Ge1 In Dy2 120.182(17) 5_556 7
Ge1 In Dy2 59.818(17) 1_554 7
Ge2 In Dy2 55.500(13) 5 7
Ge2 In Dy2 124.500(13) . 7
Dy1 In Dy2 111.858(14) 3_445 7
Dy1 In Dy2 68.142(14) 7 7
Dy1 In Dy2 64.274(14) 3_455 7
Dy1 In Dy2 115.726(14) 7_545 7
Dy2 In Dy2 102.127(18) 3_455 7
Dy2 In Dy2 77.873(18) 7_545 7
Ge1 In Dy2 59.818(17) 5_556 3_445
Ge1 In Dy2 120.182(17) 1_554 3_445
Ge2 In Dy2 124.500(13) 5 3_445
Ge2 In Dy2 55.500(13) . 3_445
Dy1 In Dy2 68.142(14) 3_445 3_445
Dy1 In Dy2 111.858(14) 7 3_445
Dy1 In Dy2 115.726(14) 3_455 3_445
Dy1 In Dy2 64.274(14) 7_545 3_445
Dy2 In Dy2 77.873(18) 3_455 3_445
Dy2 In Dy2 102.127(18) 7_545 3_445
Dy2 In Dy2 180.0 7 3_445
Ru Ge1 Ge1 118.88(6) . 5_556
Ru Ge1 In 130.74(4) . 1_556
Ge1 Ge1 In 110.37(5) 5_556 1_556
Ru Ge1 Dy1 76.56(2) . 7_556
Ge1 Ge1 Dy1 132.571(17) 5_556 7_556
In Ge1 Dy1 70.33(2) 1_556 7_556
Ru Ge1 Dy1 76.56(2) . 7_546
Ge1 Ge1 Dy1 132.571(17) 5_556 7_546
In Ge1 Dy1 70.33(2) 1_556 7_546
Dy1 Ge1 Dy1 93.52(3) 7_556 7_546
Ru Ge1 Dy2 69.37(2) . 3_445
Ge1 Ge1 Dy2 69.35(3) 5_556 3_445
In Ge1 Dy2 133.035(16) 1_556 3_445
Dy1 Ge1 Dy2 145.88(3) 7_556 3_445
Dy1 Ge1 Dy2 77.18(2) 7_546 3_445
Ru Ge1 Dy2 69.37(2) . 3_455
Ge1 Ge1 Dy2 69.35(3) 5_556 3_455
In Ge1 Dy2 133.035(16) 1_556 3_455
Dy1 Ge1 Dy2 77.18(2) 7_556 3_455
Dy1 Ge1 Dy2 145.88(3) 7_546 3_455
Dy2 Ge1 Dy2 92.20(3) 3_445 3_455
Ru Ge1 Dy2 136.130(16) . 7_546
Ge1 Ge1 Dy2 61.68(3) 5_556 7_546
In Ge1 Dy2 68.816(19) 1_556 7_546
Dy1 Ge1 Dy2 138.96(3) 7_556 7_546
Dy1 Ge1 Dy2 76.498(19) 7_546 7_546
Dy2 Ge1 Dy2 71.309(19) 3_445 7_546
Dy2 Ge1 Dy2 131.03(3) 3_455 7_546
Ru Ge1 Dy2 136.130(16) . 7_556
Ge1 Ge1 Dy2 61.68(3) 5_556 7_556
In Ge1 Dy2 68.816(19) 1_556 7_556
Dy1 Ge1 Dy2 76.498(19) 7_556 7_556
Dy1 Ge1 Dy2 138.96(3) 7_546 7_556
Dy2 Ge1 Dy2 131.03(3) 3_445 7_556
Dy2 Ge1 Dy2 71.309(19) 3_455 7_556
Dy2 Ge1 Dy2 85.36(3) 7_546 7_556
Ru Ge2 Ru 120.03(5) 7_556 7_546
Ru Ge2 Ru 77.92(3) 7_556 .
Ru Ge2 Ru 77.92(3) 7_546 .
Ru Ge2 Dy1 76.00(3) 7_556 .
Ru Ge2 Dy1 76.00(3) 7_546 .
Ru Ge2 Dy1 126.29(4) . .
Ru Ge2 Dy2 142.98(4) 7_556 3_445
Ru Ge2 Dy2 65.87(2) 7_546 3_445
Ru Ge2 Dy2 67.46(2) . 3_445
Dy1 Ge2 Dy2 135.676(15) . 3_445
Ru Ge2 Dy2 65.87(2) 7_556 3_455
Ru Ge2 Dy2 142.98(4) 7_546 3_455
Ru Ge2 Dy2 67.46(2) . 3_455
Dy1 Ge2 Dy2 135.676(15) . 3_455
Dy2 Ge2 Dy2 88.36(3) 3_445 3_455
Ru Ge2 Dy1 145.63(4) 7_556 7_545
Ru Ge2 Dy1 67.73(2) 7_546 7_545
Ru Ge2 Dy1 134.302(17) . 7_545
Dy1 Ge2 Dy1 73.93(2) . 7_545
Dy2 Ge2 Dy1 71.362(18) 3_445 7_545
Dy2 Ge2 Dy1 130.51(3) 3_455 7_545
Ru Ge2 Dy1 67.73(2) 7_556 7
Ru Ge2 Dy1 145.63(4) 7_546 7
Ru Ge2 Dy1 134.302(17) . 7
Dy1 Ge2 Dy1 73.93(2) . 7
Dy2 Ge2 Dy1 130.51(3) 3_445 7
Dy2 Ge2 Dy1 71.362(19) 3_455 7
Dy1 Ge2 Dy1 88.10(3) 7_545 7
Ru Ge2 In 119.98(2) 7_556 .
Ru Ge2 In 119.98(2) 7_546 .
Ru Ge2 In 113.22(3) . .
Dy1 Ge2 In 120.49(3) . .
Dy2 Ge2 In 66.05(2) 3_445 .
Dy2 Ge2 In 66.05(2) 3_455 .
Dy1 Ge2 In 64.458(19) 7_545 .
Dy1 Ge2 In 64.458(19) 7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 Ge1 2.9182(8) 7_556
Dy1 Ge1 2.9182(8) 7_546
Dy1 Ge2 2.9761(11) .
Dy1 Ge2 3.0577(9) 7_545
Dy1 Ge2 3.0577(9) 7
Dy1 Ru 3.1120(9) 1_554
Dy1 In 3.3138(6) 3
Dy1 In 3.3138(6) 3_545
Dy1 Ru 3.3687(7) 7_556
Dy1 Ru 3.3687(7) 7_546
Dy1 Dy2 3.5627(9) 5_655
Dy1 Dy1 3.6290(8) 7_545
Dy2 Ge1 2.9505(8) 3
Dy2 Ge1 2.9505(8) 3_545
Dy2 Ru 3.0343(9) 5_656
Dy2 Ge2 3.0504(8) 3
Dy2 Ge2 3.0504(8) 3_545
Dy2 Ru 3.1203(7) 3
Dy2 Ru 3.1203(7) 3_545
Dy2 Ge1 3.1362(8) 7_546
Dy2 Ge1 3.1362(8) 7_556
Dy2 In 3.3828(6) 3_545
Dy2 In 3.3828(6) 3
Dy2 Dy2 3.5511(9) 5_656
Ru Ge2 2.4545(7) 7_556
Ru Ge2 2.4545(7) 7_546
Ru Ge1 2.4927(11) .
Ru Ge2 2.5107(13) .
Ru Dy2 3.0344(10) 5_656
Ru Dy1 3.1121(9) 1_556
Ru Dy2 3.1203(7) 3_445
Ru Dy2 3.1203(7) 3_455
Ru Ru 3.1222(10) 7_546
Ru Ru 3.1222(10) 7_556
Ru Dy1 3.3687(7) 7_556
Ru Dy1 3.3687(7) 7_546
In Ge1 2.8341(10) 5_556
In Ge1 2.8341(10) 1_554
In Ge2 3.1541(11) 5
In Ge2 3.1541(11) .
In Dy1 3.3138(6) 3_445
In Dy1 3.3138(6) 7
In Dy1 3.3138(6) 3_455
In Dy1 3.3138(6) 7_545
In Dy2 3.3828(6) 3_455
In Dy2 3.3828(6) 7_545
In Dy2 3.3828(6) 7
In Dy2 3.3828(6) 3_445
Ge1 Ge1 2.5284(18) 5_556
Ge1 In 2.8340(10) 1_556
Ge1 Dy1 2.9182(8) 7_556
Ge1 Dy1 2.9182(8) 7_546
Ge1 Dy2 2.9505(8) 3_445
Ge1 Dy2 2.9505(8) 3_455
Ge1 Dy2 3.1361(8) 7_546
Ge1 Dy2 3.1361(8) 7_556
Ge2 Ru 2.4545(7) 7_556
Ge2 Ru 2.4545(7) 7_546
Ge2 Dy2 3.0504(8) 3_445
Ge2 Dy2 3.0504(8) 3_455
Ge2 Dy1 3.0577(9) 7_545
Ge2 Dy1 3.0577(9) 7
