#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342578.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342578
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Ho4 Ru2 In Ge4'
_chemical_formula_sum            'Ge4 Ho4 In Ru2'
_chemical_formula_weight         1267.04
_chemical_name_common
'holmium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic
'holmium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.842(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.550(4)
_cell_length_b                   4.2349(12)
_cell_length_c                   6.9425(19)
_cell_measurement_reflns_used    2170
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.11
_cell_measurement_theta_min      5.00
_cell_volume                     437.6(2)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0341
_diffrn_reflns_av_unetI/netI     0.0316
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3120
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.164
_diffrn_reflns_theta_min         2.737
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    55.046
_exptl_absorpt_correction_T_max  0.4103
_exptl_absorpt_correction_T_min  0.0403
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    9.617
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1066
_exptl_crystal_size_max          0.101
_exptl_crystal_size_mid          0.027
_exptl_crystal_size_min          0.023
_refine_diff_density_max         2.164
_refine_diff_density_min         -2.413
_refine_diff_density_rms         0.530
_refine_ls_extinction_coef       0.00184(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         930
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0271
_refine_ls_R_factor_gt           0.0232
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0272P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0528
_refine_ls_wR_factor_ref         0.0543
_reflns_Friedel_coverage         0.000
_reflns_number_gt                842
_reflns_number_total             930
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Ho4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342578
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.072
_shelx_estimated_absorpt_t_max   0.364
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ho1 Ho 0.34818(2) 0.0000 0.06760(5) 0.00653(10) Uani 1 2 d S T P
Ho2 Ho 0.58723(2) 0.0000 0.38370(5) 0.00611(10) Uani 1 2 d S T P
Ru Ru 0.22041(4) 0.0000 0.63283(9) 0.00762(14) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0080(2) Uani 0.962(4) 4 d S T .
Ge1 Ge 0.06444(5) 0.0000 0.66003(13) 0.00689(17) Uani 1 2 d S T P
Ge2 Ge 0.20063(6) 0.0000 0.26062(13) 0.00796(17) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ho Ho -0.2175 4.6783 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Ho1 Ge1 93.75(3) 7_556 7_546
Ge1 Ho1 Ge2 89.03(3) 7_556 .
Ge1 Ho1 Ge2 89.03(3) 7_546 .
Ge1 Ho1 Ge2 164.70(3) 7_556 7_545
Ge1 Ho1 Ge2 87.03(3) 7_546 7_545
Ge2 Ho1 Ge2 106.26(2) . 7_545
Ge1 Ho1 Ge2 87.03(3) 7_556 7
Ge1 Ho1 Ge2 164.70(3) 7_546 7
Ge2 Ho1 Ge2 106.26(2) . 7
Ge2 Ho1 Ge2 88.25(3) 7_545 7
Ge1 Ho1 Ru 133.047(16) 7_556 1_554
Ge1 Ho1 Ru 133.047(16) 7_546 1_554
Ge2 Ho1 Ru 94.50(3) . 1_554
Ge2 Ho1 Ru 47.089(18) 7_545 1_554
Ge2 Ho1 Ru 47.089(18) 7 1_554
Ge1 Ho1 In 53.55(2) 7_556 3
Ge1 Ho1 In 109.96(2) 7_546 3
Ge2 Ho1 In 137.758(13) . 3
Ge2 Ho1 In 111.91(2) 7_545 3
Ge2 Ho1 In 58.73(2) 7 3
Ru Ho1 In 98.315(18) 1_554 3
Ge1 Ho1 In 109.96(2) 7_556 3_545
Ge1 Ho1 In 53.55(2) 7_546 3_545
Ge2 Ho1 In 137.758(13) . 3_545
Ge2 Ho1 In 58.73(2) 7_545 3_545
Ge2 Ho1 In 111.91(2) 7 3_545
Ru Ho1 In 98.315(18) 1_554 3_545
In Ho1 In 79.70(2) 3 3_545
Ge1 Ho1 Ru 46.18(2) 7_556 7_556
Ge1 Ho1 Ru 103.29(3) 7_546 7_556
Ge2 Ho1 Ru 45.128(14) . 7_556
Ge2 Ho1 Ru 148.17(2) 7_545 7_556
Ge2 Ho1 Ru 88.27(3) 7 7_556
Ru Ho1 Ru 112.04(2) 1_554 7_556
In Ho1 Ru 92.992(19) 3 7_556
In Ho1 Ru 149.533(16) 3_545 7_556
Ge1 Ho1 Ru 103.29(3) 7_556 7_546
Ge1 Ho1 Ru 46.18(2) 7_546 7_546
Ge2 Ho1 Ru 45.128(14) . 7_546
Ge2 Ho1 Ru 88.27(3) 7_545 7_546
Ge2 Ho1 Ru 148.17(2) 7 7_546
Ru Ho1 Ru 112.04(2) 1_554 7_546
In Ho1 Ru 149.533(16) 3 7_546
In Ho1 Ru 92.992(19) 3_545 7_546
Ru Ho1 Ru 78.37(2) 7_556 7_546
Ge1 Ho1 Ho2 112.07(2) 7_556 5_655
Ge1 Ho1 Ho2 112.07(2) 7_546 5_655
Ge2 Ho1 Ho2 148.07(2) . 5_655
Ge2 Ho1 Ho2 54.042(19) 7_545 5_655
Ge2 Ho1 Ho2 54.042(19) 7 5_655
Ru Ho1 Ho2 53.58(2) 1_554 5_655
In Ho1 Ho2 58.612(9) 3 5_655
In Ho1 Ho2 58.612(9) 3_545 5_655
Ru Ho1 Ho2 140.225(13) 7_556 5_655
Ru Ho1 Ho2 140.225(13) 7_546 5_655
Ge1 Ho1 Ho1 143.02(2) 7_556 7_545
Ge1 Ho1 Ho1 86.70(2) 7_546 7_545
Ge2 Ho1 Ho1 53.99(2) . 7_545
Ge2 Ho1 Ho1 52.270(19) 7_545 7_545
Ge2 Ho1 Ho1 101.83(2) 7 7_545
Ru Ho1 Ho1 59.392(15) 1_554 7_545
In Ho1 Ho1 157.574(18) 3 7_545
In Ho1 Ho1 99.93(2) 3_545 7_545
Ru Ho1 Ho1 97.74(2) 7_556 7_545
Ru Ho1 Ho1 52.652(17) 7_546 7_545
Ho2 Ho1 Ho1 101.797(17) 5_655 7_545
Ge1 Ho2 Ge1 91.87(3) 3 3_545
Ge1 Ho2 Ru 109.35(2) 3 5_656
Ge1 Ho2 Ru 109.35(2) 3_545 5_656
Ge1 Ho2 Ge2 82.60(3) 3 3
Ge1 Ho2 Ge2 151.00(3) 3_545 3
Ru Ho2 Ge2 47.744(17) 5_656 3
Ge1 Ho2 Ge2 151.00(3) 3 3_545
Ge1 Ho2 Ge2 82.60(3) 3_545 3_545
Ru Ho2 Ge2 47.744(17) 5_656 3_545
Ge2 Ho2 Ge2 88.58(3) 3 3_545
Ge1 Ho2 Ru 48.36(2) 3 3
Ge1 Ho2 Ru 108.25(3) 3_545 3
Ru Ho2 Ru 61.007(19) 5_656 3
Ge2 Ho2 Ru 48.24(2) 3 3
Ge2 Ho2 Ru 106.50(3) 3_545 3
Ge1 Ho2 Ru 108.25(3) 3 3_545
Ge1 Ho2 Ru 48.36(2) 3_545 3_545
Ru Ho2 Ru 61.007(19) 5_656 3_545
Ge2 Ho2 Ru 106.50(3) 3 3_545
Ge2 Ho2 Ru 48.24(2) 3_545 3_545
Ru Ho2 Ru 85.73(3) 3 3_545
Ge1 Ho2 Ge1 108.73(2) 3 7_546
Ge1 Ho2 Ge1 49.10(3) 3_545 7_546
Ru Ho2 Ge1 136.408(16) 5_656 7_546
Ge2 Ho2 Ge1 158.73(3) 3 7_546
Ge2 Ho2 Ge1 89.05(3) 3_545 7_546
Ru Ho2 Ge1 151.49(2) 3 7_546
Ru Ho2 Ge1 87.41(2) 3_545 7_546
Ge1 Ho2 Ge1 49.10(3) 3 7_556
Ge1 Ho2 Ge1 108.73(2) 3_545 7_556
Ru Ho2 Ge1 136.408(16) 5_656 7_556
Ge2 Ho2 Ge1 89.05(3) 3 7_556
Ge2 Ho2 Ge1 158.73(3) 3_545 7_556
Ru Ho2 Ge1 87.41(2) 3 7_556
Ru Ho2 Ge1 151.49(2) 3_545 7_556
Ge1 Ho2 Ge1 85.54(3) 7_546 7_556
Ge1 Ho2 In 150.52(2) 3 3_545
Ge1 Ho2 In 88.07(3) 3_545 3_545
Ru Ho2 In 98.401(15) 5_656 3_545
Ge2 Ho2 In 110.50(2) 3 3_545
Ge2 Ho2 In 58.10(2) 3_545 3_545
Ru Ho2 In 156.717(16) 3 3_545
Ru Ho2 In 93.58(2) 3_545 3_545
Ge1 Ho2 In 51.365(18) 7_546 3_545
Ge1 Ho2 In 103.31(2) 7_556 3_545
Ge1 Ho2 In 88.07(3) 3 3
Ge1 Ho2 In 150.52(2) 3_545 3
Ru Ho2 In 98.401(15) 5_656 3
Ge2 Ho2 In 58.10(2) 3 3
Ge2 Ho2 In 110.50(2) 3_545 3
Ru Ho2 In 93.58(2) 3 3
Ru Ho2 In 156.717(16) 3_545 3
Ge1 Ho2 In 103.31(2) 7_546 3
Ge1 Ho2 In 51.365(18) 7_556 3
In Ho2 In 77.98(2) 3_545 3
Ge1 Ho2 Ho2 56.621(17) 3 5_656
Ge1 Ho2 Ho2 56.621(17) 3_545 5_656
Ru Ho2 Ho2 156.16(2) 5_656 5_656
Ge2 Ho2 Ho2 135.584(15) 3 5_656
Ge2 Ho2 Ho2 135.584(15) 3_545 5_656
Ru Ho2 Ho2 102.78(2) 3 5_656
Ru Ho2 Ho2 102.78(2) 3_545 5_656
Ge1 Ho2 Ho2 52.108(18) 7_546 5_656
Ge1 Ho2 Ho2 52.108(18) 7_556 5_656
In Ho2 Ho2 100.071(19) 3_545 5_656
In Ho2 Ho2 100.071(19) 3 5_656
Ge2 Ru Ge2 119.44(5) 7_556 7_546
Ge2 Ru Ge1 113.03(3) 7_556 .
Ge2 Ru Ge1 113.03(3) 7_546 .
Ge2 Ru Ge2 102.22(3) 7_556 .
Ge2 Ru Ge2 102.22(3) 7_546 .
Ge1 Ru Ge2 104.28(4) . .
Ge2 Ru Ho2 66.26(2) 7_556 5_656
Ge2 Ru Ho2 66.26(2) 7_546 5_656
Ge1 Ru Ho2 177.91(3) . 5_656
Ge2 Ru Ho2 77.81(3) . 5_656
Ge2 Ru Ho1 65.29(2) 7_556 1_556
Ge2 Ru Ho1 65.29(2) 7_546 1_556
Ge1 Ru Ho1 106.89(3) . 1_556
Ge2 Ru Ho1 148.83(3) . 1_556
Ho2 Ru Ho1 71.02(2) 5_656 1_556
Ge2 Ru Ho2 161.72(3) 7_556 3_445
Ge2 Ru Ho2 76.97(3) 7_546 3_445
Ge1 Ru Ho2 62.33(2) . 3_445
Ge2 Ru Ho2 64.21(2) . 3_445
Ho2 Ru Ho2 118.992(19) 5_656 3_445
Ho1 Ru Ho2 132.652(15) 1_556 3_445
Ge2 Ru Ho2 76.97(3) 7_556 3_455
Ge2 Ru Ho2 161.72(3) 7_546 3_455
Ge1 Ru Ho2 62.33(2) . 3_455
Ge2 Ru Ho2 64.21(2) . 3_455
Ho2 Ru Ho2 118.992(19) 5_656 3_455
Ho1 Ru Ho2 132.652(15) 1_556 3_455
Ho2 Ru Ho2 85.73(3) 3_445 3_455
Ge2 Ru Ru 123.87(4) 7_556 7_546
Ge2 Ru Ru 51.97(3) 7_546 7_546
Ge1 Ru Ru 120.44(3) . 7_546
Ge2 Ru Ru 50.25(2) . 7_546
Ho2 Ru Ru 60.86(2) 5_656 7_546
Ho1 Ru Ru 111.15(3) 1_556 7_546
Ho2 Ru Ru 58.13(2) 3_445 7_546
Ho2 Ru Ru 113.34(3) 3_455 7_546
Ge2 Ru Ru 51.97(3) 7_556 7_556
Ge2 Ru Ru 123.87(4) 7_546 7_556
Ge1 Ru Ru 120.44(3) . 7_556
Ge2 Ru Ru 50.25(2) . 7_556
Ho2 Ru Ru 60.86(2) 5_656 7_556
Ho1 Ru Ru 111.15(3) 1_556 7_556
Ho2 Ru Ru 113.34(3) 3_445 7_556
Ho2 Ru Ru 58.13(2) 3_455 7_556
Ru Ru Ru 85.58(4) 7_546 7_556
Ge2 Ru Ho1 59.25(3) 7_556 7_556
Ge2 Ru Ho1 125.45(3) 7_546 7_556
Ge1 Ru Ho1 57.323(18) . 7_556
Ge2 Ru Ho1 132.23(2) . 7_556
Ho2 Ru Ho1 121.284(17) 5_656 7_556
Ho1 Ru Ho1 67.96(2) 1_556 7_556
Ho2 Ru Ho1 119.64(3) 3_445 7_556
Ho2 Ru Ho1 68.59(2) 3_455 7_556
Ru Ru Ho1 176.37(2) 7_546 7_556
Ru Ru Ho1 98.02(2) 7_556 7_556
Ge2 Ru Ho1 125.45(3) 7_556 7_546
Ge2 Ru Ho1 59.25(3) 7_546 7_546
Ge1 Ru Ho1 57.323(18) . 7_546
Ge2 Ru Ho1 132.23(2) . 7_546
Ho2 Ru Ho1 121.284(17) 5_656 7_546
Ho1 Ru Ho1 67.96(2) 1_556 7_546
Ho2 Ru Ho1 68.59(2) 3_445 7_546
Ho2 Ru Ho1 119.64(3) 3_455 7_546
Ru Ru Ho1 98.02(2) 7_546 7_546
Ru Ru Ho1 176.37(2) 7_556 7_546
Ho1 Ru Ho1 78.37(2) 7_556 7_546
Ge1 In Ge1 180.00(3) 5_556 1_554
Ge1 In Ge2 86.98(3) 5_556 5
Ge1 In Ge2 93.02(3) 1_554 5
Ge1 In Ge2 93.02(3) 5_556 .
Ge1 In Ge2 86.98(3) 1_554 .
Ge2 In Ge2 180.0 5 .
Ge1 In Ho1 55.886(13) 5_556 3_445
Ge1 In Ho1 124.114(13) 1_554 3_445
Ge2 In Ho1 56.423(18) 5 3_445
Ge2 In Ho1 123.578(18) . 3_445
Ge1 In Ho1 124.114(13) 5_556 7
Ge1 In Ho1 55.886(13) 1_554 7
Ge2 In Ho1 123.577(18) 5 7
Ge2 In Ho1 56.422(18) . 7
Ho1 In Ho1 180.0 3_445 7
Ge1 In Ho1 55.886(13) 5_556 3_455
Ge1 In Ho1 124.114(13) 1_554 3_455
Ge2 In Ho1 56.423(18) 5 3_455
Ge2 In Ho1 123.578(18) . 3_455
Ho1 In Ho1 79.70(2) 3_445 3_455
Ho1 In Ho1 100.30(2) 7 3_455
Ge1 In Ho1 124.114(13) 5_556 7_545
Ge1 In Ho1 55.886(13) 1_554 7_545
Ge2 In Ho1 123.577(18) 5 7_545
Ge2 In Ho1 56.422(18) . 7_545
Ho1 In Ho1 100.30(2) 3_445 7_545
Ho1 In Ho1 79.70(2) 7 7_545
Ho1 In Ho1 180.000(12) 3_455 7_545
Ge1 In Ho2 59.785(19) 5_556 3_455
Ge1 In Ho2 120.215(19) 1_554 3_455
Ge2 In Ho2 124.402(13) 5 3_455
Ge2 In Ho2 55.598(13) . 3_455
Ho1 In Ho2 115.561(16) 3_445 3_455
Ho1 In Ho2 64.439(16) 7 3_455
Ho1 In Ho2 67.982(16) 3_455 3_455
Ho1 In Ho2 112.018(17) 7_545 3_455
Ge1 In Ho2 120.215(19) 5_556 7_545
Ge1 In Ho2 59.785(19) 1_554 7_545
Ge2 In Ho2 55.598(13) 5 7_545
Ge2 In Ho2 124.402(13) . 7_545
Ho1 In Ho2 64.439(16) 3_445 7_545
Ho1 In Ho2 115.561(16) 7 7_545
Ho1 In Ho2 112.018(17) 3_455 7_545
Ho1 In Ho2 67.982(16) 7_545 7_545
Ho2 In Ho2 180.0 3_455 7_545
Ge1 In Ho2 120.215(19) 5_556 7
Ge1 In Ho2 59.785(19) 1_554 7
Ge2 In Ho2 55.598(13) 5 7
Ge2 In Ho2 124.402(13) . 7
Ho1 In Ho2 112.018(17) 3_445 7
Ho1 In Ho2 67.982(16) 7 7
Ho1 In Ho2 64.439(16) 3_455 7
Ho1 In Ho2 115.561(16) 7_545 7
Ho2 In Ho2 102.02(2) 3_455 7
Ho2 In Ho2 77.98(2) 7_545 7
Ge1 In Ho2 59.785(19) 5_556 3_445
Ge1 In Ho2 120.215(19) 1_554 3_445
Ge2 In Ho2 124.402(13) 5 3_445
Ge2 In Ho2 55.598(13) . 3_445
Ho1 In Ho2 67.982(16) 3_445 3_445
Ho1 In Ho2 112.018(17) 7 3_445
Ho1 In Ho2 115.561(16) 3_455 3_445
Ho1 In Ho2 64.439(16) 7_545 3_445
Ho2 In Ho2 77.98(2) 3_455 3_445
Ho2 In Ho2 102.02(2) 7_545 3_445
Ho2 In Ho2 180.0 7 3_445
Ru Ge1 Ge1 118.43(5) . 5_556
Ru Ge1 In 130.90(4) . 1_556
Ge1 Ge1 In 110.66(5) 5_556 1_556
Ru Ge1 Ho1 76.50(2) . 7_556
Ge1 Ge1 Ho1 132.542(17) 5_556 7_556
In Ge1 Ho1 70.56(2) 1_556 7_556
Ru Ge1 Ho1 76.50(2) . 7_546
Ge1 Ge1 Ho1 132.542(17) 5_556 7_546
In Ge1 Ho1 70.56(2) 1_556 7_546
Ho1 Ge1 Ho1 93.75(3) 7_556 7_546
Ru Ge1 Ho2 69.31(2) . 3_445
Ge1 Ge1 Ho2 68.99(3) 5_556 3_445
In Ge1 Ho2 133.167(17) 1_556 3_445
Ho1 Ge1 Ho2 145.78(3) 7_556 3_445
Ho1 Ge1 Ho2 77.17(2) 7_546 3_445
Ru Ge1 Ho2 69.31(2) . 3_455
Ge1 Ge1 Ho2 68.99(3) 5_556 3_455
In Ge1 Ho2 133.167(17) 1_556 3_455
Ho1 Ge1 Ho2 77.17(2) 7_556 3_455
Ho1 Ge1 Ho2 145.78(3) 7_546 3_455
Ho2 Ge1 Ho2 91.87(3) 3_445 3_455
Ru Ge1 Ho2 136.009(17) . 7_546
Ge1 Ge1 Ho2 61.91(3) 5_556 7_546
In Ge1 Ho2 68.849(19) 1_556 7_546
Ho1 Ge1 Ho2 139.22(3) 7_556 7_546
Ho1 Ge1 Ho2 76.47(2) 7_546 7_546
Ho2 Ge1 Ho2 71.27(2) 3_445 7_546
Ho2 Ge1 Ho2 130.90(3) 3_455 7_546
Ru Ge1 Ho2 136.009(17) . 7_556
Ge1 Ge1 Ho2 61.91(3) 5_556 7_556
In Ge1 Ho2 68.849(19) 1_556 7_556
Ho1 Ge1 Ho2 76.47(2) 7_556 7_556
Ho1 Ge1 Ho2 139.22(3) 7_546 7_556
Ho2 Ge1 Ho2 130.90(3) 3_445 7_556
Ho2 Ge1 Ho2 71.27(2) 3_455 7_556
Ho2 Ge1 Ho2 85.54(3) 7_546 7_556
Ru Ge2 Ru 119.44(5) 7_556 7_546
Ru Ge2 Ru 77.78(3) 7_556 .
Ru Ge2 Ru 77.78(3) 7_546 .
Ru Ge2 Ho1 75.62(3) 7_556 .
Ru Ge2 Ho1 75.62(3) 7_546 .
Ru Ge2 Ho1 125.66(4) . .
Ru Ge2 Ho2 143.06(4) 7_556 3_445
Ru Ge2 Ho2 66.00(2) 7_546 3_445
Ru Ge2 Ho2 67.55(2) . 3_445
Ho1 Ge2 Ho2 135.607(15) . 3_445
Ru Ge2 Ho2 66.00(2) 7_556 3_455
Ru Ge2 Ho2 143.06(4) 7_546 3_455
Ru Ge2 Ho2 67.55(2) . 3_455
Ho1 Ge2 Ho2 135.607(16) . 3_455
Ho2 Ge2 Ho2 88.58(3) 3_445 3_455
Ru Ge2 Ho1 145.26(4) 7_556 7_545
Ru Ge2 Ho1 67.62(2) 7_546 7_545
Ru Ge2 Ho1 134.447(18) . 7_545
Ho1 Ge2 Ho1 73.74(2) . 7_545
Ho2 Ge2 Ho1 71.68(2) 3_445 7_545
Ho2 Ge2 Ho1 131.15(3) 3_455 7_545
Ru Ge2 Ho1 67.62(2) 7_556 7
Ru Ge2 Ho1 145.26(4) 7_546 7
Ru Ge2 Ho1 134.447(18) . 7
Ho1 Ge2 Ho1 73.74(2) . 7
Ho2 Ge2 Ho1 131.15(3) 3_445 7
Ho2 Ge2 Ho1 71.68(2) 3_455 7
Ho1 Ge2 Ho1 88.25(3) 7_545 7
Ru Ge2 In 120.27(2) 7_556 .
Ru Ge2 In 120.27(2) 7_546 .
Ru Ge2 In 113.60(3) . .
Ho1 Ge2 In 120.74(4) . .
Ho2 Ge2 In 66.30(2) 3_445 .
Ho2 Ge2 In 66.30(2) 3_455 .
Ho1 Ge2 In 64.849(19) 7_545 .
Ho1 Ge2 In 64.849(19) 7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ho1 Ge1 2.9011(8) 7_556
Ho1 Ge1 2.9011(8) 7_546
Ho1 Ge2 2.9735(11) .
Ho1 Ge2 3.0413(9) 7_545
Ho1 Ge2 3.0413(9) 7
Ho1 Ru 3.0956(10) 1_554
Ho1 In 3.3044(7) 3
Ho1 In 3.3044(7) 3_545
Ho1 Ru 3.3514(8) 7_556
Ho1 Ru 3.3514(8) 7_546
Ho1 Ho2 3.5564(10) 5_655
Ho1 Ho1 3.6093(9) 7_545
Ho2 Ge1 2.9468(8) 3
Ho2 Ge1 2.9468(8) 3_545
Ho2 Ru 3.0263(11) 5_656
Ho2 Ge2 3.0324(8) 3
Ho2 Ge2 3.0324(8) 3_545
Ho2 Ru 3.1126(7) 3
Ho2 Ru 3.1126(7) 3_545
Ho2 Ge1 3.1181(9) 7_546
Ho2 Ge1 3.1181(9) 7_556
Ho2 In 3.3654(7) 3_545
Ho2 In 3.3654(7) 3
Ho2 Ho2 3.5364(10) 5_656
Ru Ge2 2.4520(8) 7_556
Ru Ge2 2.4520(8) 7_546
Ru Ge1 2.4866(12) .
Ru Ge2 2.5123(13) .
Ru Ho2 3.0263(11) 5_656
Ru Ho1 3.0956(10) 1_556
Ru Ho2 3.1126(7) 3_445
Ru Ho2 3.1126(7) 3_455
Ru Ru 3.1170(10) 7_546
Ru Ru 3.1170(10) 7_556
Ru Ho1 3.3514(8) 7_556
Ru Ho1 3.3514(8) 7_546
In Ge1 2.8187(10) 5_556
In Ge1 2.8187(10) 1_554
In Ge2 3.1201(11) 5
In Ge2 3.1201(11) .
In Ho1 3.3043(7) 3_445
In Ho1 3.3043(7) 7
In Ho1 3.3043(7) 3_455
In Ho1 3.3043(7) 7_545
In Ho2 3.3654(7) 3_455
In Ho2 3.3654(7) 7_545
In Ho2 3.3654(7) 7
In Ho2 3.3654(7) 3_445
Ge1 Ge1 2.5245(17) 5_556
Ge1 In 2.8187(10) 1_556
Ge1 Ho1 2.9011(8) 7_556
Ge1 Ho1 2.9011(8) 7_546
Ge1 Ho2 2.9468(8) 3_445
Ge1 Ho2 2.9468(8) 3_455
Ge1 Ho2 3.1182(9) 7_546
Ge1 Ho2 3.1182(9) 7_556
Ge2 Ru 2.4519(8) 7_556
Ge2 Ru 2.4519(8) 7_546
Ge2 Ho2 3.0324(8) 3_445
Ge2 Ho2 3.0324(8) 3_455
Ge2 Ho1 3.0413(9) 7_545
Ge2 Ho1 3.0413(9) 7
