#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342579.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342579
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Er4 Ru2 In Ge4'
_chemical_formula_sum            'Er4 Ge4 In Ru2'
_chemical_formula_weight         1276.36
_chemical_name_common            'erbium ruthenium indium germanide (4/2/1/4)'
_chemical_name_systematic        'erbium ruthenium indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.850(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.526(5)
_cell_length_b                   4.2254(14)
_cell_length_c                   6.916(2)
_cell_measurement_reflns_used    1363
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.31
_cell_measurement_theta_min      5.02
_cell_volume                     434.2(2)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0496
_diffrn_reflns_av_unetI/netI     0.0442
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3164
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.168
_diffrn_reflns_theta_min         2.742
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    57.681
_exptl_absorpt_correction_T_max  0.5593
_exptl_absorpt_correction_T_min  0.0980
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    9.762
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1074
_exptl_crystal_size_max          0.134
_exptl_crystal_size_mid          0.020
_exptl_crystal_size_min          0.015
_refine_diff_density_max         3.024
_refine_diff_density_min         -2.677
_refine_diff_density_rms         0.611
_refine_ls_extinction_coef       0.00104(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         923
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0329P)²+0.8532P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0657
_refine_ls_wR_factor_ref         0.0689
_reflns_Friedel_coverage         0.000
_reflns_number_gt                758
_reflns_number_total             923
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_004.cif
_cod_data_source_block           Er4Ru2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342579
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.048
_shelx_estimated_absorpt_t_max   0.478
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Er1 Er 0.34794(4) 0.0000 0.06828(8) 0.00911(14) Uani 1 2 d S T P
Er2 Er 0.58744(3) 0.0000 0.38492(8) 0.00865(14) Uani 1 2 d S T P
Ru Ru 0.22059(6) 0.0000 0.63335(13) 0.00852(19) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0106(3) Uani 0.980(5) 4 d S T .
Ge1 Ge 0.06421(8) 0.0000 0.65998(19) 0.0095(2) Uani 1 2 d S T P
Ge2 Ge 0.19976(9) 0.0000 0.25934(19) 0.0100(2) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Er Er -0.2586 4.9576 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Er1 Ge1 93.82(4) 7_556 7_546
Ge1 Er1 Ge2 89.49(4) 7_556 .
Ge1 Er1 Ge2 89.49(4) 7_546 .
Ge1 Er1 Ge2 164.23(4) 7_556 7_545
Ge1 Er1 Ge2 86.77(4) 7_546 7_545
Ge2 Er1 Ge2 106.27(3) . 7_545
Ge1 Er1 Ge2 86.77(4) 7_556 7
Ge1 Er1 Ge2 164.23(4) 7_546 7
Ge2 Er1 Ge2 106.27(3) . 7
Ge2 Er1 Ge2 88.46(4) 7_545 7
Ge1 Er1 Ru 132.99(2) 7_556 1_554
Ge1 Er1 Ru 132.99(2) 7_546 1_554
Ge2 Er1 Ru 94.23(4) . 1_554
Ge2 Er1 Ru 47.29(2) 7_545 1_554
Ge2 Er1 Ru 47.29(2) 7 1_554
Ge1 Er1 In 53.40(3) 7_556 3
Ge1 Er1 In 109.76(3) 7_546 3
Ge2 Er1 In 137.945(16) . 3
Ge2 Er1 In 111.66(3) 7_545 3
Ge2 Er1 In 58.45(3) 7 3
Ru Er1 In 98.24(2) 1_554 3
Ge1 Er1 In 109.76(3) 7_556 3_545
Ge1 Er1 In 53.40(3) 7_546 3_545
Ge2 Er1 In 137.945(16) . 3_545
Ge2 Er1 In 58.45(3) 7_545 3_545
Ge2 Er1 In 111.66(3) 7 3_545
Ru Er1 In 98.24(2) 1_554 3_545
In Er1 In 79.54(3) 3 3_545
Ge1 Er1 Ru 46.41(3) 7_556 7_556
Ge1 Er1 Ru 103.62(4) 7_546 7_556
Ge2 Er1 Ru 45.32(2) . 7_556
Ge2 Er1 Ru 148.43(3) 7_545 7_556
Ge2 Er1 Ru 88.18(3) 7 7_556
Ru Er1 Ru 111.97(3) 1_554 7_556
In Er1 Ru 93.02(2) 3 7_556
In Er1 Ru 149.66(2) 3_545 7_556
Ge1 Er1 Ru 103.62(4) 7_556 7_546
Ge1 Er1 Ru 46.41(3) 7_546 7_546
Ge2 Er1 Ru 45.32(2) . 7_546
Ge2 Er1 Ru 88.18(3) 7_545 7_546
Ge2 Er1 Ru 148.43(3) 7 7_546
Ru Er1 Ru 111.97(3) 1_554 7_546
In Er1 Ru 149.66(2) 3 7_546
In Er1 Ru 93.02(2) 3_545 7_546
Ru Er1 Ru 78.60(3) 7_556 7_546
Ge1 Er1 Er2 111.84(3) 7_556 5_655
Ge1 Er1 Er2 111.84(3) 7_546 5_655
Ge2 Er1 Er2 147.74(3) . 5_655
Ge2 Er1 Er2 53.92(3) 7_545 5_655
Ge2 Er1 Er2 53.92(3) 7 5_655
Ru Er1 Er2 53.52(3) 1_554 5_655
In Er1 Er2 58.540(12) 3 5_655
In Er1 Er2 58.540(12) 3_545 5_655
Ru Er1 Er2 140.092(16) 7_556 5_655
Ru Er1 Er2 140.092(16) 7_546 5_655
Ge1 Er1 Er1 143.42(4) 7_556 7_545
Ge1 Er1 Er1 86.86(3) 7_546 7_545
Ge2 Er1 Er1 53.93(3) . 7_545
Ge2 Er1 Er1 52.34(3) 7_545 7_545
Ge2 Er1 Er1 102.03(3) 7 7_545
Ru Er1 Er1 59.31(2) 1_554 7_545
In Er1 Er1 157.40(3) 3 7_545
In Er1 Er1 99.89(3) 3_545 7_545
Ru Er1 Er1 97.90(3) 7_556 7_545
Ru Er1 Er1 52.66(2) 7_546 7_545
Er2 Er1 Er1 101.63(2) 5_655 7_545
Ge1 Er2 Ge1 92.11(4) 3 3_545
Ge1 Er2 Ru 109.60(3) 3 5_656
Ge1 Er2 Ru 109.60(3) 3_545 5_656
Ge1 Er2 Ge2 82.68(3) 3 3
Ge1 Er2 Ge2 151.53(4) 3_545 3
Ru Er2 Ge2 47.88(2) 5_656 3
Ge1 Er2 Ge2 151.53(4) 3 3_545
Ge1 Er2 Ge2 82.68(3) 3_545 3_545
Ru Er2 Ge2 47.88(2) 5_656 3_545
Ge2 Er2 Ge2 88.68(4) 3 3_545
Ge1 Er2 Ru 48.56(3) 3 3
Ge1 Er2 Ru 108.58(4) 3_545 3
Ru Er2 Ru 61.05(3) 5_656 3
Ge2 Er2 Ru 48.39(3) 3 3
Ge2 Er2 Ru 106.72(4) 3_545 3
Ge1 Er2 Ru 108.58(4) 3 3_545
Ge1 Er2 Ru 48.56(3) 3_545 3_545
Ru Er2 Ru 61.05(3) 5_656 3_545
Ge2 Er2 Ru 106.72(4) 3 3_545
Ge2 Er2 Ru 48.39(3) 3_545 3_545
Ru Er2 Ru 85.81(3) 3 3_545
Ge1 Er2 Ge1 108.78(3) 3 7_546
Ge1 Er2 Ge1 49.01(5) 3_545 7_546
Ru Er2 Ge1 136.34(2) 5_656 7_546
Ge2 Er2 Ge1 158.26(4) 3 7_546
Ge2 Er2 Ge1 88.83(4) 3_545 7_546
Ru Er2 Ge1 151.76(3) 3 7_546
Ru Er2 Ge1 87.50(3) 3_545 7_546
Ge1 Er2 Ge1 49.01(5) 3 7_556
Ge1 Er2 Ge1 108.78(3) 3_545 7_556
Ru Er2 Ge1 136.34(2) 5_656 7_556
Ge2 Er2 Ge1 88.83(4) 3 7_556
Ge2 Er2 Ge1 158.26(4) 3_545 7_556
Ru Er2 Ge1 87.50(3) 3 7_556
Ru Er2 Ge1 151.76(3) 3_545 7_556
Ge1 Er2 Ge1 85.54(4) 7_546 7_556
Ge1 Er2 In 150.30(3) 3 3_545
Ge1 Er2 In 87.91(3) 3_545 3_545
Ru Er2 In 98.27(2) 5_656 3_545
Ge2 Er2 In 110.24(3) 3 3_545
Ge2 Er2 In 57.81(3) 3_545 3_545
Ru Er2 In 156.60(2) 3 3_545
Ru Er2 In 93.55(2) 3_545 3_545
Ge1 Er2 In 51.24(3) 7_546 3_545
Ge1 Er2 In 103.15(3) 7_556 3_545
Ge1 Er2 In 87.91(3) 3 3
Ge1 Er2 In 150.30(3) 3_545 3
Ru Er2 In 98.27(2) 5_656 3
Ge2 Er2 In 57.81(3) 3 3
Ge2 Er2 In 110.24(3) 3_545 3
Ru Er2 In 93.55(2) 3 3
Ru Er2 In 156.60(2) 3_545 3
Ge1 Er2 In 103.15(3) 7_546 3
Ge1 Er2 In 51.24(3) 7_556 3
In Er2 In 77.89(3) 3_545 3
Ge1 Er2 Er2 56.73(3) 3 5_656
Ge1 Er2 Er2 56.73(3) 3_545 5_656
Ru Er2 Er2 156.67(3) 5_656 5_656
Ge2 Er2 Er2 135.58(2) 3 5_656
Ge2 Er2 Er2 135.58(2) 3_545 5_656
Ru Er2 Er2 103.11(3) 3 5_656
Ru Er2 Er2 103.11(3) 3_545 5_656
Ge1 Er2 Er2 52.05(2) 7_546 5_656
Ge1 Er2 Er2 52.05(2) 7_556 5_656
In Er2 Er2 99.82(2) 3_545 5_656
In Er2 Er2 99.82(2) 3 5_656
Ge2 Ru Ge2 119.01(7) 7_556 7_546
Ge2 Ru Ge1 113.27(4) 7_556 .
Ge2 Ru Ge1 113.27(4) 7_546 .
Ge2 Ru Ge2 102.40(4) 7_556 .
Ge2 Ru Ge2 102.40(4) 7_546 .
Ge1 Ru Ge2 103.83(5) . .
Ge2 Ru Er2 66.13(3) 7_556 5_656
Ge2 Ru Er2 66.13(3) 7_546 5_656
Ge1 Ru Er2 178.23(5) . 5_656
Ge2 Ru Er2 77.93(4) . 5_656
Ge2 Ru Er1 65.18(3) 7_556 1_556
Ge2 Ru Er1 65.18(3) 7_546 1_556
Ge1 Ru Er1 106.94(5) . 1_556
Ge2 Ru Er1 149.23(5) . 1_556
Er2 Ru Er1 71.29(3) 5_656 1_556
Ge2 Ru Er2 161.96(4) 7_556 3_445
Ge2 Ru Er2 77.15(4) 7_546 3_445
Ge1 Ru Er2 62.17(3) . 3_445
Ge2 Ru Er2 64.13(3) . 3_445
Er2 Ru Er2 118.95(3) 5_656 3_445
Er1 Ru Er2 132.53(2) 1_556 3_445
Ge2 Ru Er2 77.15(4) 7_556 3_455
Ge2 Ru Er2 161.96(4) 7_546 3_455
Ge1 Ru Er2 62.17(3) . 3_455
Ge2 Ru Er2 64.13(3) . 3_455
Er2 Ru Er2 118.95(3) 5_656 3_455
Er1 Ru Er2 132.53(2) 1_556 3_455
Er2 Ru Er2 85.81(3) 3_445 3_455
Ge2 Ru Ru 123.76(5) 7_556 7_546
Ge2 Ru Ru 52.06(4) 7_546 7_546
Ge1 Ru Ru 120.30(4) . 7_546
Ge2 Ru Ru 50.34(3) . 7_546
Er2 Ru Ru 60.80(3) 5_656 7_546
Er1 Ru Ru 111.28(4) 1_556 7_546
Er2 Ru Ru 58.15(3) 3_445 7_546
Er2 Ru Ru 113.39(5) 3_455 7_546
Ge2 Ru Ru 52.06(4) 7_556 7_556
Ge2 Ru Ru 123.76(5) 7_546 7_556
Ge1 Ru Ru 120.30(4) . 7_556
Ge2 Ru Ru 50.34(3) . 7_556
Er2 Ru Ru 60.80(3) 5_656 7_556
Er1 Ru Ru 111.28(4) 1_556 7_556
Er2 Ru Ru 113.39(5) 3_445 7_556
Er2 Ru Ru 58.15(3) 3_455 7_556
Ru Ru Ru 85.56(5) 7_546 7_556
Ge2 Ru Er1 59.36(3) 7_556 7_556
Ge2 Ru Er1 125.58(5) 7_546 7_556
Ge1 Ru Er1 57.39(3) . 7_556
Ge2 Ru Er1 131.91(3) . 7_556
Er2 Ru Er1 121.44(2) 5_656 7_556
Er1 Ru Er1 68.03(3) 1_556 7_556
Er2 Ru Er1 119.53(4) 3_445 7_556
Er2 Ru Er1 68.32(3) 3_455 7_556
Ru Ru Er1 176.48(3) 7_546 7_556
Ru Ru Er1 97.92(3) 7_556 7_556
Ge2 Ru Er1 125.58(5) 7_556 7_546
Ge2 Ru Er1 59.36(3) 7_546 7_546
Ge1 Ru Er1 57.39(3) . 7_546
Ge2 Ru Er1 131.91(3) . 7_546
Er2 Ru Er1 121.44(2) 5_656 7_546
Er1 Ru Er1 68.03(3) 1_556 7_546
Er2 Ru Er1 68.32(3) 3_445 7_546
Er2 Ru Er1 119.53(4) 3_455 7_546
Ru Ru Er1 97.92(3) 7_546 7_546
Ru Ru Er1 176.48(3) 7_556 7_546
Er1 Ru Er1 78.60(3) 7_556 7_546
Ge1 In Ge1 180.00(4) 5_556 1_554
Ge1 In Ge2 93.09(4) 5_556 .
Ge1 In Ge2 86.91(4) 1_554 .
Ge1 In Ge2 86.91(4) 5_556 5
Ge1 In Ge2 93.09(4) 1_554 5
Ge2 In Ge2 180.0 . 5
Ge1 In Er1 55.815(19) 5_556 3_445
Ge1 In Er1 124.185(19) 1_554 3_445
Ge2 In Er1 123.64(2) . 3_445
Ge2 In Er1 56.36(2) 5 3_445
Ge1 In Er1 124.185(19) 5_556 7
Ge1 In Er1 55.815(19) 1_554 7
Ge2 In Er1 56.36(2) . 7
Ge2 In Er1 123.64(2) 5 7
Er1 In Er1 180.000(12) 3_445 7
Ge1 In Er1 124.185(19) 5_556 7_545
Ge1 In Er1 55.815(19) 1_554 7_545
Ge2 In Er1 56.36(2) . 7_545
Ge2 In Er1 123.64(2) 5 7_545
Er1 In Er1 100.46(3) 3_445 7_545
Er1 In Er1 79.54(3) 7 7_545
Ge1 In Er1 55.815(19) 5_556 3_455
Ge1 In Er1 124.185(19) 1_554 3_455
Ge2 In Er1 123.64(2) . 3_455
Ge2 In Er1 56.36(2) 5 3_455
Er1 In Er1 79.54(3) 3_445 3_455
Er1 In Er1 100.46(3) 7 3_455
Er1 In Er1 180.000(12) 7_545 3_455
Ge1 In Er2 59.78(3) 5_556 3_455
Ge1 In Er2 120.22(3) 1_554 3_455
Ge2 In Er2 55.607(18) . 3_455
Ge2 In Er2 124.393(18) 5 3_455
Er1 In Er2 115.48(2) 3_445 3_455
Er1 In Er2 64.52(2) 7 3_455
Er1 In Er2 111.96(2) 7_545 3_455
Er1 In Er2 68.04(2) 3_455 3_455
Ge1 In Er2 120.22(3) 5_556 7_545
Ge1 In Er2 59.78(3) 1_554 7_545
Ge2 In Er2 124.393(18) . 7_545
Ge2 In Er2 55.607(18) 5 7_545
Er1 In Er2 64.52(2) 3_445 7_545
Er1 In Er2 115.48(2) 7 7_545
Er1 In Er2 68.04(2) 7_545 7_545
Er1 In Er2 111.96(2) 3_455 7_545
Er2 In Er2 180.000(13) 3_455 7_545
Ge1 In Er2 120.22(3) 5_556 7
Ge1 In Er2 59.78(3) 1_554 7
Ge2 In Er2 124.393(18) . 7
Ge2 In Er2 55.607(18) 5 7
Er1 In Er2 111.96(2) 3_445 7
Er1 In Er2 68.04(2) 7 7
Er1 In Er2 115.48(2) 7_545 7
Er1 In Er2 64.52(2) 3_455 7
Er2 In Er2 102.11(3) 3_455 7
Er2 In Er2 77.89(3) 7_545 7
Ge1 In Er2 59.78(3) 5_556 3_445
Ge1 In Er2 120.22(3) 1_554 3_445
Ge2 In Er2 55.607(18) . 3_445
Ge2 In Er2 124.393(18) 5 3_445
Er1 In Er2 68.04(2) 3_445 3_445
Er1 In Er2 111.96(2) 7 3_445
Er1 In Er2 64.52(2) 7_545 3_445
Er1 In Er2 115.48(2) 3_455 3_445
Er2 In Er2 77.89(3) 3_455 3_445
Er2 In Er2 102.11(3) 7_545 3_445
Er2 In Er2 180.000(18) 7 3_445
Ru Ge1 Ge1 118.50(8) . 5_556
Ru Ge1 In 130.78(5) . 1_556
Ge1 Ge1 In 110.72(7) 5_556 1_556
Ru Ge1 Er1 76.21(4) . 7_556
Ge1 Ge1 Er1 132.56(2) 5_556 7_556
In Ge1 Er1 70.79(3) 1_556 7_556
Ru Ge1 Er1 76.21(4) . 7_546
Ge1 Ge1 Er1 132.56(2) 5_556 7_546
In Ge1 Er1 70.79(3) 1_556 7_546
Er1 Ge1 Er1 93.82(4) 7_556 7_546
Ru Ge1 Er2 69.27(3) . 3_445
Ge1 Ge1 Er2 69.17(4) 5_556 3_445
In Ge1 Er2 133.09(2) 1_556 3_445
Er1 Ge1 Er2 145.44(5) 7_556 3_445
Er1 Ge1 Er2 76.82(3) 7_546 3_445
Ru Ge1 Er2 69.27(3) . 3_455
Ge1 Ge1 Er2 69.17(4) 5_556 3_455
In Ge1 Er2 133.09(2) 1_556 3_455
Er1 Ge1 Er2 76.82(3) 7_556 3_455
Er1 Ge1 Er2 145.44(5) 7_546 3_455
Er2 Ge1 Er2 92.11(4) 3_445 3_455
Ru Ge1 Er2 135.99(2) . 7_546
Ge1 Ge1 Er2 61.82(4) 5_556 7_546
In Ge1 Er2 68.99(3) 1_556 7_546
Er1 Ge1 Er2 139.59(5) 7_556 7_546
Er1 Ge1 Er2 76.68(3) 7_546 7_546
Er2 Ge1 Er2 71.22(3) 3_445 7_546
Er2 Ge1 Er2 130.99(5) 3_455 7_546
Ru Ge1 Er2 135.99(2) . 7_556
Ge1 Ge1 Er2 61.82(4) 5_556 7_556
In Ge1 Er2 68.99(3) 1_556 7_556
Er1 Ge1 Er2 76.68(3) 7_556 7_556
Er1 Ge1 Er2 139.59(5) 7_546 7_556
Er2 Ge1 Er2 130.99(5) 3_445 7_556
Er2 Ge1 Er2 71.22(3) 3_455 7_556
Er2 Ge1 Er2 85.54(4) 7_546 7_556
Ru Ge2 Ru 119.01(7) 7_556 7_546
Ru Ge2 Ru 77.60(4) 7_556 .
Ru Ge2 Ru 77.60(4) 7_546 .
Ru Ge2 Er1 75.32(4) 7_556 .
Ru Ge2 Er1 75.32(4) 7_546 .
Ru Ge2 Er1 125.00(5) . .
Ru Ge2 Er2 142.91(5) 7_556 3_445
Ru Ge2 Er2 65.99(3) 7_546 3_445
Ru Ge2 Er2 67.48(3) . 3_445
Er1 Ge2 Er2 135.60(2) . 3_445
Ru Ge2 Er2 65.99(3) 7_556 3_455
Ru Ge2 Er2 142.91(5) 7_546 3_455
Ru Ge2 Er2 67.48(3) . 3_455
Er1 Ge2 Er2 135.60(2) . 3_455
Er2 Ge2 Er2 88.69(4) 3_445 3_455
Ru Ge2 Er1 145.08(5) 7_556 7_545
Ru Ge2 Er1 67.53(3) 7_546 7_545
Ru Ge2 Er1 134.50(2) . 7_545
Er1 Ge2 Er1 73.73(3) . 7_545
Er2 Ge2 Er1 72.01(3) 3_445 7_545
Er2 Ge2 Er1 131.77(5) 3_455 7_545
Ru Ge2 Er1 67.53(3) 7_556 7
Ru Ge2 Er1 145.08(5) 7_546 7
Ru Ge2 Er1 134.50(2) . 7
Er1 Ge2 Er1 73.73(3) . 7
Er2 Ge2 Er1 131.77(5) 3_445 7
Er2 Ge2 Er1 72.01(3) 3_455 7
Er1 Ge2 Er1 88.46(4) 7_545 7
Ru Ge2 In 120.49(3) 7_556 .
Ru Ge2 In 120.49(3) 7_546 .
Ru Ge2 In 113.85(5) . .
Er1 Ge2 In 121.15(5) . .
Er2 Ge2 In 66.58(3) 3_445 .
Er2 Ge2 In 66.58(3) 3_455 .
Er1 Ge2 In 65.20(3) 7_545 .
Er1 Ge2 In 65.20(3) 7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Er1 Ge1 2.8931(11) 7_556
Er1 Ge1 2.8931(11) 7_546
Er1 Ge2 2.9666(15) .
Er1 Ge2 3.0287(12) 7_545
Er1 Ge2 3.0287(12) 7
Er1 Ru 3.0837(13) 1_554
Er1 In 3.3025(8) 3
Er1 In 3.3025(8) 3_545
Er1 Ru 3.3355(10) 7_556
Er1 Ru 3.3355(10) 7_546
Er1 Er2 3.5571(12) 5_655
Er1 Er1 3.5971(12) 7_545
Er2 Ge1 2.9342(11) 3
Er2 Ge1 2.9342(11) 3_545
Er2 Ru 3.0196(14) 5_656
Er2 Ge2 3.0227(11) 3
Er2 Ge2 3.0227(11) 3_545
Er2 Ru 3.1032(10) 3
Er2 Ru 3.1032(10) 3_545
Er2 Ge1 3.1112(12) 7_546
Er2 Ge1 3.1112(12) 7_556
Er2 In 3.3612(8) 3_545
Er2 In 3.3612(8) 3
Er2 Er2 3.5230(13) 5_656
Ru Ge2 2.4518(10) 7_556
Ru Ge2 2.4518(10) 7_546
Ru Ge1 2.4876(17) .
Ru Ge2 2.5120(17) .
Ru Er2 3.0195(14) 5_656
Ru Er1 3.0836(13) 1_556
Ru Er2 3.1032(10) 3_445
Ru Er2 3.1032(10) 3_455
Ru Ru 3.1107(14) 7_546
Ru Ru 3.1107(14) 7_556
Ru Er1 3.3356(10) 7_556
Ru Er1 3.3356(10) 7_546
In Ge1 2.8076(14) 5_556
In Ge1 2.8076(14) 1_554
In Ge2 3.1001(15) .
In Ge2 3.1002(15) 5
In Er1 3.3025(8) 3_445
In Er1 3.3025(8) 7
In Er1 3.3025(8) 7_545
In Er1 3.3025(8) 3_455
In Er2 3.3612(8) 3_455
In Er2 3.3612(8) 7_545
In Er2 3.3612(8) 7
In Er2 3.3612(8) 3_445
Ge1 Ge1 2.513(3) 5_556
Ge1 In 2.8076(14) 1_556
Ge1 Er1 2.8931(11) 7_556
Ge1 Er1 2.8931(11) 7_546
Ge1 Er2 2.9343(11) 3_445
Ge1 Er2 2.9343(11) 3_455
Ge1 Er2 3.1112(12) 7_546
Ge1 Er2 3.1112(12) 7_556
Ge2 Ru 2.4518(10) 7_556
Ge2 Ru 2.4518(10) 7_546
Ge2 Er2 3.0227(11) 3_445
Ge2 Er2 3.0227(11) 3_455
Ge2 Er1 3.0287(12) 7_545
Ge2 Er1 3.0287(12) 7
