#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342580.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342580
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Tb4 Rh In Ge4'
_chemical_formula_sum            'Ge4 In Rh Tb4'
_chemical_formula_weight         1143.77
_chemical_name_common            'terbium rhodium indium germanide (4/1/1/4)'
_chemical_name_systematic        'terbium rhodium indium germanide (4/1/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 104.9984(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   20.2575(12)
_cell_length_b                   4.2641(3)
_cell_length_c                   10.2434(6)
_cell_measurement_reflns_used    3819
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.52
_cell_measurement_theta_min      4.89
_cell_volume                     854.68(9)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_unetI/netI     0.0303
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6268
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.116
_diffrn_reflns_theta_min         2.058
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    50.891
_exptl_absorpt_correction_T_max  0.2616
_exptl_absorpt_correction_T_min  0.1148
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.889
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1928
_exptl_crystal_size_max          0.075
_exptl_crystal_size_mid          0.055
_exptl_crystal_size_min          0.036
_refine_diff_density_max         3.029
_refine_diff_density_min         -1.811
_refine_diff_density_rms         0.450
_refine_ls_extinction_coef       0.00025(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     64
_refine_ls_number_reflns         1802
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0307
_refine_ls_R_factor_gt           0.0244
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0276P)²+1.9080P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0553
_refine_ls_wR_factor_ref         0.0576
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1539
_reflns_number_total             1802
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_006.cif
_cod_data_source_block           Tb4RhInGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342580
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.115
_shelx_estimated_absorpt_t_max   0.262
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Tb1 Tb 0.27830(2) 0.0000 0.65591(4) 0.00787(9) Uani 1 2 d S T P
Tb2 Tb 0.37132(2) 0.0000 0.00695(3) 0.00703(9) Uani 1 2 d S T P
Tb3 Tb 0.37279(2) 0.0000 0.35947(4) 0.00842(9) Uani 1 2 d S T P
Tb4 Tb 0.54120(2) 0.0000 0.27206(4) 0.00884(9) Uani 1 2 d S T P
Rh Rh 0.24058(3) 0.0000 0.10680(6) 0.00787(12) Uani 1 2 d S T P
In1 In 0.0000 0.0000 0.5000 0.01127(15) Uani 1 4 d S T P
In2 In 0.0000 0.0000 0.0000 0.01258(16) Uani 1 4 d S T P
Ge1 Ge 0.06320(4) 0.0000 0.78519(9) 0.00996(16) Uani 1 2 d S T P
Ge2 Ge 0.13207(5) 0.0000 0.18953(8) 0.00944(16) Uani 1 2 d S T P
Ge3 Ge 0.14302(4) 0.0000 0.44998(8) 0.00876(16) Uani 1 2 d S T P
Ge4 Ge 0.80414(4) 0.0000 0.14907(8) 0.00778(16) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge4 Tb1 Ge2 90.82(2) 5_656 7_556
Ge4 Tb1 Ge2 90.82(2) 5_656 7_546
Ge2 Tb1 Ge2 91.49(3) 7_556 7_546
Ge4 Tb1 Ge3 84.30(2) 5_656 .
Ge2 Tb1 Ge3 134.083(14) 7_556 .
Ge2 Tb1 Ge3 134.083(14) 7_546 .
Ge4 Tb1 Ge3 133.915(13) 5_656 7_556
Ge2 Tb1 Ge3 51.73(2) 7_556 7_556
Ge2 Tb1 Ge3 112.95(2) 7_546 7_556
Ge3 Tb1 Ge3 102.61(2) . 7_556
Ge4 Tb1 Ge3 133.915(13) 5_656 7_546
Ge2 Tb1 Ge3 112.95(2) 7_556 7_546
Ge2 Tb1 Ge3 51.73(2) 7_546 7_546
Ge3 Tb1 Ge3 102.61(2) . 7_546
Ge3 Tb1 Ge3 89.59(2) 7_556 7_546
Ge4 Tb1 Rh 46.014(12) 5_656 7_556
Ge2 Tb1 Rh 47.350(18) 7_556 7_556
Ge2 Tb1 Rh 103.883(19) 7_546 7_556
Ge3 Tb1 Rh 104.905(18) . 7_556
Ge3 Tb1 Rh 88.922(15) 7_556 7_556
Ge3 Tb1 Rh 152.09(2) 7_546 7_556
Ge4 Tb1 Rh 46.014(12) 5_656 7_546
Ge2 Tb1 Rh 103.883(19) 7_556 7_546
Ge2 Tb1 Rh 47.350(18) 7_546 7_546
Ge3 Tb1 Rh 104.905(18) . 7_546
Ge3 Tb1 Rh 152.09(2) 7_556 7_546
Ge3 Tb1 Rh 88.922(15) 7_546 7_546
Rh Tb1 Rh 79.656(15) 7_556 7_546
Ge4 Tb1 Tb4 126.96(2) 5_656 5_656
Ge2 Tb1 Tb4 55.518(16) 7_556 5_656
Ge2 Tb1 Tb4 55.518(16) 7_546 5_656
Ge3 Tb1 Tb4 148.74(2) . 5_656
Ge3 Tb1 Tb4 57.519(16) 7_556 5_656
Ge3 Tb1 Tb4 57.519(16) 7_546 5_656
Rh Tb1 Tb4 98.951(14) 7_556 5_656
Rh Tb1 Tb4 98.951(14) 7_546 5_656
Ge4 Tb1 Tb2 63.937(19) 5_656 1_556
Ge2 Tb1 Tb2 51.649(15) 7_556 1_556
Ge2 Tb1 Tb2 51.649(15) 7_546 1_556
Ge3 Tb1 Tb2 148.23(2) . 1_556
Ge3 Tb1 Tb2 99.778(18) 7_556 1_556
Ge3 Tb1 Tb2 99.778(18) 7_546 1_556
Rh Tb1 Tb2 53.157(11) 7_556 1_556
Rh Tb1 Tb2 53.157(11) 7_546 1_556
Tb4 Tb1 Tb2 63.022(10) 5_656 1_556
Ge4 Tb1 Tb3 54.206(14) 5_656 7_546
Ge2 Tb1 Tb3 145.02(2) 7_556 7_546
Ge2 Tb1 Tb3 89.654(16) 7_546 7_546
Ge3 Tb1 Tb3 51.235(13) . 7_546
Ge3 Tb1 Tb3 153.82(2) 7_556 7_546
Ge3 Tb1 Tb3 94.899(14) 7_546 7_546
Rh Tb1 Tb3 98.629(13) 7_556 7_546
Rh Tb1 Tb3 53.977(12) 7_546 7_546
Tb4 Tb1 Tb3 143.881(6) 5_656 7_546
Tb2 Tb1 Tb3 104.823(11) 1_556 7_546
Ge4 Tb1 Tb3 54.206(14) 5_656 7_556
Ge2 Tb1 Tb3 89.654(16) 7_556 7_556
Ge2 Tb1 Tb3 145.02(2) 7_546 7_556
Ge3 Tb1 Tb3 51.235(13) . 7_556
Ge3 Tb1 Tb3 94.899(14) 7_556 7_556
Ge3 Tb1 Tb3 153.82(2) 7_546 7_556
Rh Tb1 Tb3 53.977(12) 7_556 7_556
Rh Tb1 Tb3 98.629(13) 7_546 7_556
Tb4 Tb1 Tb3 143.881(6) 5_656 7_556
Tb2 Tb1 Tb3 104.823(11) 1_556 7_556
Tb3 Tb1 Tb3 70.374(11) 7_546 7_556
Ge2 Tb2 Ge2 93.78(2) 7_545 7
Ge2 Tb2 Ge1 156.37(3) 7_545 7_556
Ge2 Tb2 Ge1 84.237(19) 7 7_556
Ge2 Tb2 Ge1 84.237(19) 7_545 7_546
Ge2 Tb2 Ge1 156.37(3) 7 7_546
Ge1 Tb2 Ge1 88.25(2) 7_556 7_546
Ge2 Tb2 Rh 111.13(2) 7_545 .
Ge2 Tb2 Rh 111.13(2) 7 .
Ge1 Tb2 Rh 91.38(2) 7_556 .
Ge1 Tb2 Rh 91.38(2) 7_546 .
Ge2 Tb2 Ge4 153.38(3) 7_545 3_455
Ge2 Tb2 Ge4 83.469(17) 7 3_455
Ge1 Tb2 Ge4 49.92(2) 7_556 3_455
Ge1 Tb2 Ge4 108.49(2) 7_546 3_455
Rh Tb2 Ge4 47.242(13) . 3_455
Ge2 Tb2 Ge4 83.469(17) 7_545 3_445
Ge2 Tb2 Ge4 153.38(3) 7 3_445
Ge1 Tb2 Ge4 108.49(2) 7_556 3_445
Ge1 Tb2 Ge4 49.92(2) 7_546 3_445
Rh Tb2 Ge4 47.242(13) . 3_445
Ge4 Tb2 Ge4 87.29(2) 3_455 3_445
Ge2 Tb2 Rh 49.955(19) 7_545 7_545
Ge2 Tb2 Rh 110.94(2) 7 7_545
Ge1 Tb2 Rh 151.67(2) 7_556 7_545
Ge1 Tb2 Rh 85.744(16) 7_546 7_545
Rh Tb2 Rh 61.173(15) . 7_545
Ge4 Tb2 Rh 106.40(2) 3_455 7_545
Ge4 Tb2 Rh 48.411(18) 3_445 7_545
Ge2 Tb2 Rh 110.94(2) 7_545 7
Ge2 Tb2 Rh 49.955(19) 7 7
Ge1 Tb2 Rh 85.744(16) 7_556 7
Ge1 Tb2 Rh 151.67(2) 7_546 7
Rh Tb2 Rh 61.173(15) . 7
Ge4 Tb2 Rh 48.411(18) 3_455 7
Ge4 Tb2 Rh 106.40(2) 3_445 7
Rh Tb2 Rh 86.540(19) 7_545 7
Ge2 Tb2 In2 109.053(18) 7_545 3
Ge2 Tb2 In2 53.570(18) 7 3
Ge1 Tb2 In2 51.558(16) 7_556 3
Ge1 Tb2 In2 104.832(18) 7_546 3
Rh Tb2 In2 137.858(7) . 3
Ge4 Tb2 In2 90.616(13) 3_455 3
Ge4 Tb2 In2 151.74(2) 3_445 3
Rh Tb2 In2 156.214(16) 7_545 3
Rh Tb2 In2 92.923(10) 7 3
Ge2 Tb2 In2 53.570(18) 7_545 3_545
Ge2 Tb2 In2 109.053(18) 7 3_545
Ge1 Tb2 In2 104.832(18) 7_556 3_545
Ge1 Tb2 In2 51.559(16) 7_546 3_545
Rh Tb2 In2 137.858(7) . 3_545
Ge4 Tb2 In2 151.74(2) 3_455 3_545
Ge4 Tb2 In2 90.616(13) 3_445 3_545
Rh Tb2 In2 92.923(10) 7_545 3_545
Rh Tb2 In2 156.214(16) 7 3_545
In2 Tb2 In2 78.146(9) 3 3_545
Ge2 Tb2 Tb1 53.068(16) 7_545 1_554
Ge2 Tb2 Tb1 53.068(16) 7 1_554
Ge1 Tb2 Tb1 135.621(12) 7_556 1_554
Ge1 Tb2 Tb1 135.621(12) 7_546 1_554
Rh Tb2 Tb1 93.378(16) . 1_554
Ge4 Tb2 Tb1 106.859(18) 3_455 1_554
Ge4 Tb2 Tb1 106.859(18) 3_445 1_554
Rh Tb2 Tb1 58.919(12) 7_545 1_554
Rh Tb2 Tb1 58.919(12) 7 1_554
In2 Tb2 Tb1 100.716(9) 3 1_554
In2 Tb2 Tb1 100.716(9) 3_545 1_554
Ge3 Tb3 Ge3 92.02(2) 7_556 7_546
Ge3 Tb3 Ge1 161.64(3) 7_556 7_546
Ge3 Tb3 Ge1 87.099(16) 7_546 7_546
Ge3 Tb3 Ge1 87.099(17) 7_556 7_556
Ge3 Tb3 Ge1 161.64(3) 7_546 7_556
Ge1 Tb3 Ge1 88.02(2) 7_546 7_556
Ge3 Tb3 Ge4 148.09(3) 7_556 3_445
Ge3 Tb3 Ge4 81.797(18) 7_546 3_445
Ge1 Tb3 Ge4 49.82(2) 7_546 3_445
Ge1 Tb3 Ge4 108.20(2) 7_556 3_445
Ge3 Tb3 Ge4 81.797(18) 7_556 3_455
Ge3 Tb3 Ge4 148.09(3) 7_546 3_455
Ge1 Tb3 Ge4 108.20(2) 7_546 3_455
Ge1 Tb3 Ge4 49.82(2) 7_556 3_455
Ge4 Tb3 Ge4 87.12(2) 3_445 3_455
Ge3 Tb3 Rh 108.76(2) 7_556 .
Ge3 Tb3 Rh 108.76(2) 7_546 .
Ge1 Tb3 Rh 88.81(2) 7_546 .
Ge1 Tb3 Rh 88.81(2) 7_556 .
Ge4 Tb3 Rh 46.123(13) 3_445 .
Ge4 Tb3 Rh 46.123(13) 3_455 .
Ge3 Tb3 In1 57.594(17) 7_556 3
Ge3 Tb3 In1 112.035(19) 7_546 3
Ge1 Tb3 In1 105.909(18) 7_546 3
Ge1 Tb3 In1 52.719(16) 7_556 3
Ge4 Tb3 In1 152.921(19) 3_445 3
Ge4 Tb3 In1 91.017(13) 3_455 3
Rh Tb3 In1 137.049(7) . 3
Ge3 Tb3 In1 112.035(19) 7_556 3_545
Ge3 Tb3 In1 57.594(17) 7_546 3_545
Ge1 Tb3 In1 52.719(16) 7_546 3_545
Ge1 Tb3 In1 105.909(18) 7_556 3_545
Ge4 Tb3 In1 91.017(13) 3_445 3_545
Ge4 Tb3 In1 152.921(19) 3_455 3_545
Rh Tb3 In1 137.049(7) . 3_545
In1 Tb3 In1 78.569(10) 3 3_545
Ge3 Tb3 Tb2 133.298(13) 7_556 .
Ge3 Tb3 Tb2 133.297(13) 7_546 .
Ge1 Tb3 Tb2 53.919(15) 7_546 .
Ge1 Tb3 Tb2 53.919(15) 7_556 .
Ge4 Tb3 Tb2 54.289(14) 3_445 .
Ge4 Tb3 Tb2 54.289(14) 3_455 .
Rh Tb3 Tb2 53.319(13) . .
In1 Tb3 Tb2 103.613(9) 3 .
In1 Tb3 Tb2 103.613(9) 3_545 .
Ge3 Tb3 Tb1 102.322(18) 7_556 7_546
Ge3 Tb3 Tb1 51.991(18) 7_546 7_546
Ge1 Tb3 Tb1 91.566(15) 7_546 7_546
Ge1 Tb3 Tb1 145.90(2) 7_556 7_546
Ge4 Tb3 Tb1 49.873(16) 3_445 7_546
Ge4 Tb3 Tb1 98.609(17) 3_455 7_546
Rh Tb3 Tb1 57.093(11) . 7_546
In1 Tb3 Tb1 156.377(12) 3 7_546
In1 Tb3 Tb1 100.746(7) 3_545 7_546
Tb2 Tb3 Tb1 99.504(11) . 7_546
Ge3 Tb3 Tb1 51.991(18) 7_556 7_556
Ge3 Tb3 Tb1 102.321(19) 7_546 7_556
Ge1 Tb3 Tb1 145.90(2) 7_546 7_556
Ge1 Tb3 Tb1 91.566(15) 7_556 7_556
Ge4 Tb3 Tb1 98.609(17) 3_445 7_556
Ge4 Tb3 Tb1 49.873(16) 3_455 7_556
Rh Tb3 Tb1 57.093(11) . 7_556
In1 Tb3 Tb1 100.746(7) 3 7_556
In1 Tb3 Tb1 156.377(12) 3_545 7_556
Tb2 Tb3 Tb1 99.504(11) . 7_556
Tb1 Tb3 Tb1 70.375(11) 7_546 7_556
Ge1 Tb4 Ge1 92.44(3) 7_546 7_556
Ge1 Tb4 Ge2 153.51(3) 7_546 3
Ge1 Tb4 Ge2 83.899(19) 7_556 3
Ge1 Tb4 Ge2 83.899(19) 7_546 3_545
Ge1 Tb4 Ge2 153.51(3) 7_556 3_545
Ge2 Tb4 Ge2 87.80(2) 3 3_545
Ge1 Tb4 Ge3 156.92(2) 7_546 3
Ge1 Tb4 Ge3 87.413(18) 7_556 3
Ge2 Tb4 Ge3 49.39(2) 3 3
Ge2 Tb4 Ge3 106.02(2) 3_545 3
Ge1 Tb4 Ge3 87.413(18) 7_546 3_545
Ge1 Tb4 Ge3 156.92(2) 7_556 3_545
Ge2 Tb4 Ge3 106.02(2) 3 3_545
Ge2 Tb4 Ge3 49.39(2) 3_545 3_545
Ge3 Tb4 Ge3 83.88(2) 3 3_545
Ge1 Tb4 In1 107.265(19) 7_546 3
Ge1 Tb4 In1 52.905(17) 7_556 3
Ge2 Tb4 In1 91.413(12) 3 3
Ge2 Tb4 In1 152.75(2) 3_545 3
Ge3 Tb4 In1 55.207(15) 3 3
Ge3 Tb4 In1 105.218(16) 3_545 3
Ge1 Tb4 In1 52.905(17) 7_546 3_545
Ge1 Tb4 In1 107.265(19) 7_556 3_545
Ge2 Tb4 In1 152.75(2) 3 3_545
Ge2 Tb4 In1 91.413(12) 3_545 3_545
Ge3 Tb4 In1 105.218(16) 3 3_545
Ge3 Tb4 In1 55.207(15) 3_545 3_545
In1 Tb4 In1 77.106(9) 3 3_545
Ge1 Tb4 In2 51.666(17) 7_546 3_545
Ge1 Tb4 In2 106.009(19) 7_556 3_545
Ge2 Tb4 In2 104.142(17) 3 3_545
Ge2 Tb4 In2 51.957(17) 3_545 3_545
Ge3 Tb4 In2 149.722(18) 3 3_545
Ge3 Tb4 In2 91.954(12) 3_545 3_545
In1 Tb4 In2 152.797(12) 3 3_545
In1 Tb4 In2 96.655(6) 3_545 3_545
Ge1 Tb4 In2 106.009(19) 7_546 3
Ge1 Tb4 In2 51.666(17) 7_556 3
Ge2 Tb4 In2 51.957(17) 3 3
Ge2 Tb4 In2 104.142(17) 3_545 3
Ge3 Tb4 In2 91.954(12) 3 3
Ge3 Tb4 In2 149.722(18) 3_545 3
In1 Tb4 In2 96.655(6) 3 3
In1 Tb4 In2 152.797(12) 3_545 3
In2 Tb4 In2 76.711(9) 3_545 3
Ge1 Tb4 Tb1 133.615(14) 7_546 5_656
Ge1 Tb4 Tb1 133.615(13) 7_556 5_656
Ge2 Tb4 Tb1 52.945(16) 3 5_656
Ge2 Tb4 Tb1 52.945(16) 3_545 5_656
Ge3 Tb4 Tb1 53.154(14) 3 5_656
Ge3 Tb4 Tb1 53.154(14) 3_545 5_656
In1 Tb4 Tb1 106.213(10) 3 5_656
In1 Tb4 Tb1 106.213(10) 3_545 5_656
In2 Tb4 Tb1 100.962(9) 3_545 5_656
In2 Tb4 Tb1 100.962(9) 3 5_656
Ge1 Tb4 Tb3 108.924(18) 7_546 5_656
Ge1 Tb4 Tb3 108.924(18) 7_556 5_656
Ge2 Tb4 Tb3 97.025(19) 3 5_656
Ge2 Tb4 Tb3 97.025(19) 3_545 5_656
Ge3 Tb4 Tb3 50.017(13) 3 5_656
Ge3 Tb4 Tb3 50.017(13) 3_545 5_656
In1 Tb4 Tb3 56.028(7) 3 5_656
In1 Tb4 Tb3 56.028(7) 3_545 5_656
In2 Tb4 Tb3 140.674(5) 3_545 5_656
In2 Tb4 Tb3 140.674(5) 3 5_656
Tb1 Tb4 Tb3 66.523(11) 5_656 5_656
Ge4 Rh Ge4 119.32(4) 3_455 3_445
Ge4 Rh Ge4 102.20(2) 3_455 5_655
Ge4 Rh Ge4 102.20(2) 3_445 5_655
Ge4 Rh Ge2 113.36(2) 3_455 .
Ge4 Rh Ge2 113.36(2) 3_445 .
Ge4 Rh Ge2 103.56(3) 5_655 .
Ge4 Rh Tb2 66.65(2) 3_455 .
Ge4 Rh Tb2 66.65(2) 3_445 .
Ge4 Rh Tb2 76.41(2) 5_655 .
Ge2 Rh Tb2 179.97(3) . .
Ge4 Rh Tb2 162.46(3) 3_455 7_545
Ge4 Rh Tb2 76.724(19) 3_445 7_545
Ge4 Rh Tb2 65.355(18) 5_655 7_545
Ge2 Rh Tb2 61.154(17) . 7_545
Tb2 Rh Tb2 118.827(15) . 7_545
Ge4 Rh Tb2 76.724(19) 3_455 7
Ge4 Rh Tb2 162.46(3) 3_445 7
Ge4 Rh Tb2 65.355(18) 5_655 7
Ge2 Rh Tb2 61.154(17) . 7
Tb2 Rh Tb2 118.827(15) . 7
Tb2 Rh Tb2 86.541(19) 7_545 7
Ge4 Rh Rh 123.70(3) 3_455 7_545
Ge4 Rh Rh 52.11(2) 3_445 7_545
Ge4 Rh Rh 50.083(19) 5_655 7_545
Ge2 Rh Rh 120.03(3) . 7_545
Tb2 Rh Rh 59.952(19) . 7_545
Tb2 Rh Rh 58.875(16) 7_545 7_545
Tb2 Rh Rh 114.30(3) 7 7_545
Ge4 Rh Rh 52.11(2) 3_455 7
Ge4 Rh Rh 123.70(3) 3_445 7
Ge4 Rh Rh 50.083(19) 5_655 7
Ge2 Rh Rh 120.03(3) . 7
Tb2 Rh Rh 59.952(19) . 7
Tb2 Rh Rh 114.30(3) 7_545 7
Tb2 Rh Rh 58.875(16) 7 7
Rh Rh Rh 85.26(3) 7_545 7
Ge4 Rh Tb3 64.53(2) 3_455 .
Ge4 Rh Tb3 64.53(2) 3_445 .
Ge4 Rh Tb3 146.36(3) 5_655 .
Ge2 Rh Tb3 110.07(3) . .
Tb2 Rh Tb3 69.957(17) . .
Tb2 Rh Tb3 132.673(12) 7_545 .
Tb2 Rh Tb3 132.673(12) 7 .
Rh Rh Tb3 109.56(3) 7_545 .
Rh Rh Tb3 109.56(3) 7 .
Ge4 Rh Tb1 58.16(2) 3_455 7_556
Ge4 Rh Tb1 125.31(3) 3_445 7_556
Ge4 Rh Tb1 132.472(16) 5_655 7_556
Ge2 Rh Tb1 59.070(17) . 7_556
Tb2 Rh Tb1 120.950(16) . 7_556
Tb2 Rh Tb1 120.15(2) 7_545 7_556
Tb2 Rh Tb1 67.925(11) 7 7_556
Rh Rh Tb1 177.13(2) 7_545 7_556
Rh Rh Tb1 97.540(10) 7 7_556
Tb3 Rh Tb1 68.929(13) . 7_556
Ge4 Rh Tb1 125.31(3) 3_455 7_546
Ge4 Rh Tb1 58.16(2) 3_445 7_546
Ge4 Rh Tb1 132.472(16) 5_655 7_546
Ge2 Rh Tb1 59.070(17) . 7_546
Tb2 Rh Tb1 120.950(16) . 7_546
Tb2 Rh Tb1 67.925(11) 7_545 7_546
Tb2 Rh Tb1 120.15(2) 7 7_546
Rh Rh Tb1 97.540(10) 7_545 7_546
Rh Rh Tb1 177.13(2) 7 7_546
Tb3 Rh Tb1 68.929(13) . 7_546
Tb1 Rh Tb1 79.657(15) 7_556 7_546
Ge1 In1 Ge1 180.0 5_556 .
Ge1 In1 Ge3 88.75(2) 5_556 5_556
Ge1 In1 Ge3 91.25(2) . 5_556
Ge1 In1 Ge3 91.25(2) 5_556 .
Ge1 In1 Ge3 88.75(2) . .
Ge3 In1 Ge3 180.0 5_556 .
Ge1 In1 Tb3 58.292(13) 5_556 3_445
Ge1 In1 Tb3 121.708(13) . 3_445
Ge3 In1 Tb3 54.584(11) 5_556 3_445
Ge3 In1 Tb3 125.416(11) . 3_445
Ge1 In1 Tb3 121.708(13) 5_556 7_556
Ge1 In1 Tb3 58.292(13) . 7_556
Ge3 In1 Tb3 125.416(11) 5_556 7_556
Ge3 In1 Tb3 54.584(11) . 7_556
Tb3 In1 Tb3 180.000(18) 3_445 7_556
Ge1 In1 Tb3 121.708(13) 5_556 7_546
Ge1 In1 Tb3 58.292(13) . 7_546
Ge3 In1 Tb3 125.416(11) 5_556 7_546
Ge3 In1 Tb3 54.584(11) . 7_546
Tb3 In1 Tb3 101.430(10) 3_445 7_546
Tb3 In1 Tb3 78.570(9) 7_556 7_546
Ge1 In1 Tb3 58.292(13) 5_556 3_455
Ge1 In1 Tb3 121.708(13) . 3_455
Ge3 In1 Tb3 54.584(11) 5_556 3_455
Ge3 In1 Tb3 125.416(11) . 3_455
Tb3 In1 Tb3 78.570(9) 3_445 3_455
Tb3 In1 Tb3 101.430(9) 7_556 3_455
Tb3 In1 Tb3 180.0 7_546 3_455
Ge1 In1 Tb4 55.155(13) 5_556 3_445
Ge1 In1 Tb4 124.845(13) . 3_445
Ge3 In1 Tb4 121.425(12) 5_556 3_445
Ge3 In1 Tb4 58.575(12) . 3_445
Tb3 In1 Tb4 66.950(9) 3_445 3_445
Tb3 In1 Tb4 113.050(9) 7_556 3_445
Tb3 In1 Tb4 66.565(9) 7_546 3_445
Tb3 In1 Tb4 113.435(9) 3_455 3_445
Ge1 In1 Tb4 124.845(13) 5_556 7_556
Ge1 In1 Tb4 55.155(13) . 7_556
Ge3 In1 Tb4 58.575(12) 5_556 7_556
Ge3 In1 Tb4 121.425(12) . 7_556
Tb3 In1 Tb4 113.050(9) 3_445 7_556
Tb3 In1 Tb4 66.950(9) 7_556 7_556
Tb3 In1 Tb4 113.435(9) 7_546 7_556
Tb3 In1 Tb4 66.565(9) 3_455 7_556
Tb4 In1 Tb4 180.000(12) 3_445 7_556
Ge1 In1 Tb4 124.845(13) 5_556 7_546
Ge1 In1 Tb4 55.155(13) . 7_546
Ge3 In1 Tb4 58.575(12) 5_556 7_546
Ge3 In1 Tb4 121.425(12) . 7_546
Tb3 In1 Tb4 66.565(9) 3_445 7_546
Tb3 In1 Tb4 113.435(9) 7_556 7_546
Tb3 In1 Tb4 66.950(9) 7_546 7_546
Tb3 In1 Tb4 113.050(9) 3_455 7_546
Tb4 In1 Tb4 102.894(9) 3_445 7_546
Tb4 In1 Tb4 77.106(9) 7_556 7_546
Ge1 In1 Tb4 55.155(13) 5_556 3_455
Ge1 In1 Tb4 124.845(13) . 3_455
Ge3 In1 Tb4 121.425(12) 5_556 3_455
Ge3 In1 Tb4 58.575(12) . 3_455
Tb3 In1 Tb4 113.435(9) 3_445 3_455
Tb3 In1 Tb4 66.565(9) 7_556 3_455
Tb3 In1 Tb4 113.050(9) 7_546 3_455
Tb3 In1 Tb4 66.950(9) 3_455 3_455
Tb4 In1 Tb4 77.106(9) 3_445 3_455
Tb4 In1 Tb4 102.894(9) 7_556 3_455
Tb4 In1 Tb4 180.0 7_546 3_455
Ge1 In2 Ge1 180.00(3) 5_556 1_554
Ge1 In2 Ge2 89.76(2) 5_556 5
Ge1 In2 Ge2 90.24(2) 1_554 5
Ge1 In2 Ge2 90.24(2) 5_556 .
Ge1 In2 Ge2 89.76(2) 1_554 .
Ge2 In2 Ge2 180.0 5 .
Ge1 In2 Tb2 58.345(13) 5_556 3_445
Ge1 In2 Tb2 121.655(13) 1_554 3_445
Ge2 In2 Tb2 54.952(12) 5 3_445
Ge2 In2 Tb2 125.048(12) . 3_445
Ge1 In2 Tb2 121.655(13) 5_556 7
Ge1 In2 Tb2 58.345(13) 1_554 7
Ge2 In2 Tb2 125.048(12) 5 7
Ge2 In2 Tb2 54.952(12) . 7
Tb2 In2 Tb2 180.0 3_445 7
Ge1 In2 Tb2 58.345(13) 5_556 3_455
Ge1 In2 Tb2 121.655(13) 1_554 3_455
Ge2 In2 Tb2 54.953(12) 5 3_455
Ge2 In2 Tb2 125.048(12) . 3_455
Tb2 In2 Tb2 78.147(9) 3_445 3_455
Tb2 In2 Tb2 101.853(9) 7 3_455
Ge1 In2 Tb2 121.655(13) 5_556 7_545
Ge1 In2 Tb2 58.345(13) 1_554 7_545
Ge2 In2 Tb2 125.047(12) 5 7_545
Ge2 In2 Tb2 54.952(12) . 7_545
Tb2 In2 Tb2 101.853(9) 3_445 7_545
Tb2 In2 Tb2 78.147(9) 7 7_545
Tb2 In2 Tb2 180.000(12) 3_455 7_545
Ge1 In2 Tb4 55.296(13) 5_556 3_455
Ge1 In2 Tb4 124.704(13) 1_554 3_455
Ge2 In2 Tb4 122.471(12) 5 3_455
Ge2 In2 Tb4 57.529(12) . 3_455
Tb2 In2 Tb4 113.631(8) 3_445 3_455
Tb2 In2 Tb4 66.369(8) 7 3_455
Tb2 In2 Tb4 67.577(8) 3_455 3_455
Tb2 In2 Tb4 112.423(9) 7_545 3_455
Ge1 In2 Tb4 124.704(13) 5_556 7_545
Ge1 In2 Tb4 55.296(13) 1_554 7_545
Ge2 In2 Tb4 57.529(12) 5 7_545
Ge2 In2 Tb4 122.471(12) . 7_545
Tb2 In2 Tb4 66.369(8) 3_445 7_545
Tb2 In2 Tb4 113.631(8) 7 7_545
Tb2 In2 Tb4 112.423(9) 3_455 7_545
Tb2 In2 Tb4 67.577(8) 7_545 7_545
Tb4 In2 Tb4 180.0 3_455 7_545
Ge1 In2 Tb4 124.704(13) 5_556 7
Ge1 In2 Tb4 55.296(13) 1_554 7
Ge2 In2 Tb4 57.529(12) 5 7
Ge2 In2 Tb4 122.471(12) . 7
Tb2 In2 Tb4 112.423(9) 3_445 7
Tb2 In2 Tb4 67.577(8) 7 7
Tb2 In2 Tb4 66.369(8) 3_455 7
Tb2 In2 Tb4 113.631(8) 7_545 7
Tb4 In2 Tb4 103.288(9) 3_455 7
Tb4 In2 Tb4 76.712(9) 7_545 7
Ge1 In2 Tb4 55.296(13) 5_556 3_445
Ge1 In2 Tb4 124.704(13) 1_554 3_445
Ge2 In2 Tb4 122.471(12) 5 3_445
Ge2 In2 Tb4 57.529(12) . 3_445
Tb2 In2 Tb4 67.577(8) 3_445 3_445
Tb2 In2 Tb4 112.423(9) 7 3_445
Tb2 In2 Tb4 113.631(8) 3_455 3_445
Tb2 In2 Tb4 66.369(8) 7_545 3_445
Tb4 In2 Tb4 76.712(9) 3_455 3_445
Tb4 In2 Tb4 103.288(9) 7_545 3_445
Tb4 In2 Tb4 180.0 7 3_445
Ge4 Ge1 In2 116.52(4) 5_656 1_556
Ge4 Ge1 In1 115.04(4) 5_656 .
In2 Ge1 In1 128.44(3) 1_556 .
Ge4 Ge1 Tb4 133.760(13) 5_656 7_546
In2 Ge1 Tb4 73.038(19) 1_556 7_546
In1 Ge1 Tb4 71.939(19) . 7_546
Ge4 Ge1 Tb4 133.760(14) 5_656 7_556
In2 Ge1 Tb4 73.038(19) 1_556 7_556
In1 Ge1 Tb4 71.939(19) . 7_556
Tb4 Ge1 Tb4 92.44(3) 7_546 7_556
Ge4 Ge1 Tb2 65.58(2) 5_656 7_556
In2 Ge1 Tb2 70.097(18) 1_556 7_556
In1 Ge1 Tb2 134.960(13) . 7_556
Tb4 Ge1 Tb2 143.11(3) 7_546 7_556
Tb4 Ge1 Tb2 78.139(13) 7_556 7_556
Ge4 Ge1 Tb2 65.58(2) 5_656 7_546
In2 Ge1 Tb2 70.097(18) 1_556 7_546
In1 Ge1 Tb2 134.960(13) . 7_546
Tb4 Ge1 Tb2 78.139(13) 7_546 7_546
Tb4 Ge1 Tb2 143.11(3) 7_556 7_546
Tb2 Ge1 Tb2 88.25(2) 7_556 7_546
Ge4 Ge1 Tb3 65.60(2) 5_656 7_546
In2 Ge1 Tb3 135.337(13) 1_556 7_546
In1 Ge1 Tb3 68.988(18) . 7_546
Tb4 Ge1 Tb3 76.872(13) 7_546 7_546
Tb4 Ge1 Tb3 140.91(3) 7_556 7_546
Tb2 Ge1 Tb3 131.18(3) 7_556 7_546
Tb2 Ge1 Tb3 71.996(13) 7_546 7_546
Ge4 Ge1 Tb3 65.60(2) 5_656 7_556
In2 Ge1 Tb3 135.337(13) 1_556 7_556
In1 Ge1 Tb3 68.988(18) . 7_556
Tb4 Ge1 Tb3 140.91(3) 7_546 7_556
Tb4 Ge1 Tb3 76.872(13) 7_556 7_556
Tb2 Ge1 Tb3 71.996(13) 7_556 7_556
Tb2 Ge1 Tb3 131.18(3) 7_546 7_556
Tb3 Ge1 Tb3 88.02(2) 7_546 7_556
Rh Ge2 Ge3 119.01(4) . .
Rh Ge2 In2 120.50(3) . .
Ge3 Ge2 In2 120.49(4) . .
Rh Ge2 Tb2 68.893(19) . 7_545
Ge3 Ge2 Tb2 133.047(13) . 7_545
In2 Ge2 Tb2 71.477(19) . 7_545
Rh Ge2 Tb2 68.893(19) . 7
Ge3 Ge2 Tb2 133.047(13) . 7
In2 Ge2 Tb2 71.477(19) . 7
Tb2 Ge2 Tb2 93.78(2) 7_545 7
Rh Ge2 Tb1 73.58(2) . 7_556
Ge3 Ge2 Tb1 65.10(2) . 7_556
In2 Ge2 Tb1 133.887(15) . 7_556
Tb2 Ge2 Tb1 142.34(3) 7_545 7_556
Tb2 Ge2 Tb1 75.283(12) 7 7_556
Rh Ge2 Tb1 73.58(2) . 7_546
Ge3 Ge2 Tb1 65.10(2) . 7_546
In2 Ge2 Tb1 133.887(14) . 7_546
Tb2 Ge2 Tb1 75.283(12) 7_545 7_546
Tb2 Ge2 Tb1 142.34(3) 7 7_546
Tb1 Ge2 Tb1 91.49(3) 7_556 7_546
Rh Ge2 Tb4 136.023(12) . 3_445
Ge3 Ge2 Tb4 67.60(2) . 3_445
In2 Ge2 Tb4 70.51(2) . 3_445
Tb2 Ge2 Tb4 76.954(13) 7_545 3_445
Tb2 Ge2 Tb4 141.88(3) 7 3_445
Tb1 Ge2 Tb4 132.58(3) 7_556 3_445
Tb1 Ge2 Tb4 71.538(13) 7_546 3_445
Rh Ge2 Tb4 136.023(12) . 3_455
Ge3 Ge2 Tb4 67.60(2) . 3_455
In2 Ge2 Tb4 70.51(2) . 3_455
Tb2 Ge2 Tb4 141.88(3) 7_545 3_455
Tb2 Ge2 Tb4 76.954(13) 7 3_455
Tb1 Ge2 Tb4 71.538(13) 7_556 3_455
Tb1 Ge2 Tb4 132.58(3) 7_546 3_455
Tb4 Ge2 Tb4 87.80(2) 3_445 3_455
Ge2 Ge3 Tb3 132.516(15) . 7_556
Ge2 Ge3 Tb3 132.516(15) . 7_546
Tb3 Ge3 Tb3 92.02(2) 7_556 7_546
Ge2 Ge3 Tb1 122.57(4) . .
Tb3 Ge3 Tb1 76.78(2) 7_556 .
Tb3 Ge3 Tb1 76.78(2) 7_546 .
Ge2 Ge3 Tb1 63.16(2) . 7_556
Tb3 Ge3 Tb1 83.453(11) 7_556 7_556
Tb3 Ge3 Tb1 154.12(3) 7_546 7_556
Tb1 Ge3 Tb1 77.39(2) . 7_556
Ge2 Ge3 Tb1 63.16(2) . 7_546
Tb3 Ge3 Tb1 154.12(3) 7_556 7_546
Tb3 Ge3 Tb1 83.453(11) 7_546 7_546
Tb1 Ge3 Tb1 77.39(2) . 7_546
Tb1 Ge3 Tb1 89.59(2) 7_556 7_546
Ge2 Ge3 In1 109.58(4) . .
Tb3 Ge3 In1 67.820(17) 7_556 .
Tb3 Ge3 In1 67.820(17) 7_546 .
Tb1 Ge3 In1 127.84(3) . .
Tb1 Ge3 In1 131.849(16) 7_556 .
Tb1 Ge3 In1 131.849(16) 7_546 .
Ge2 Ge3 Tb4 63.02(2) . 3_445
Tb3 Ge3 Tb4 133.87(3) 7_556 3_445
Tb3 Ge3 Tb4 74.414(13) 7_546 3_445
Tb1 Ge3 Tb4 137.817(12) . 3_445
Tb1 Ge3 Tb4 126.07(3) 7_556 3_445
Tb1 Ge3 Tb4 69.329(13) 7_546 3_445
In1 Ge3 Tb4 66.217(17) . 3_445
Ge2 Ge3 Tb4 63.02(2) . 3_455
Tb3 Ge3 Tb4 74.414(13) 7_556 3_455
Tb3 Ge3 Tb4 133.87(3) 7_546 3_455
Tb1 Ge3 Tb4 137.817(12) . 3_455
Tb1 Ge3 Tb4 69.329(13) 7_556 3_455
Tb1 Ge3 Tb4 126.07(3) 7_546 3_455
In1 Ge3 Tb4 66.217(17) . 3_455
Tb4 Ge3 Tb4 83.88(2) 3_445 3_455
Rh Ge4 Rh 119.33(4) 3_545 3
Rh Ge4 Rh 77.80(2) 3_545 5_655
Rh Ge4 Rh 77.80(2) 3 5_655
Rh Ge4 Ge1 120.20(2) 3_545 5_656
Rh Ge4 Ge1 120.20(2) 3 5_656
Rh Ge4 Ge1 109.65(4) 5_655 5_656
Rh Ge4 Tb1 75.83(2) 3_545 5_656
Rh Ge4 Tb1 75.83(2) 3 5_656
Rh Ge4 Tb1 126.28(3) 5_655 5_656
Ge1 Ge4 Tb1 124.07(4) 5_656 5_656
Rh Ge4 Tb2 66.104(16) 3_545 3_545
Rh Ge4 Tb2 141.84(3) 3 3_545
Rh Ge4 Tb2 66.235(18) 5_655 3_545
Ge1 Ge4 Tb2 64.50(2) 5_656 3_545
Tb1 Ge4 Tb2 136.301(11) 5_656 3_545
Rh Ge4 Tb2 141.84(3) 3_545 3
Rh Ge4 Tb2 66.104(16) 3 3
Rh Ge4 Tb2 66.235(18) 5_655 3
Ge1 Ge4 Tb2 64.50(2) 5_656 3
Tb1 Ge4 Tb2 136.301(11) 5_656 3
Tb2 Ge4 Tb2 87.29(2) 3_545 3
Rh Ge4 Tb3 146.80(3) 3_545 3
Rh Ge4 Tb3 69.346(17) 3 3
Rh Ge4 Tb3 133.967(14) 5_655 3
Ge1 Ge4 Tb3 64.58(2) 5_656 3
Tb1 Ge4 Tb3 75.921(18) 5_656 3
Tb2 Ge4 Tb3 129.08(3) 3_545 3
Tb2 Ge4 Tb3 71.293(13) 3 3
Rh Ge4 Tb3 69.346(17) 3_545 3_545
Rh Ge4 Tb3 146.80(3) 3 3_545
Rh Ge4 Tb3 133.967(14) 5_655 3_545
Ge1 Ge4 Tb3 64.58(2) 5_656 3_545
Tb1 Ge4 Tb3 75.921(18) 5_656 3_545
Tb2 Ge4 Tb3 71.293(13) 3_545 3_545
Tb2 Ge4 Tb3 129.08(3) 3 3_545
Tb3 Ge4 Tb3 87.11(2) 3 3_545
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 Ge4 2.9166(9) 5_656
Tb1 Ge2 2.9768(7) 7_556
Tb1 Ge2 2.9768(7) 7_546
Tb1 Ge3 2.9946(10) .
Tb1 Ge3 3.0261(6) 7_556
Tb1 Ge3 3.0261(6) 7_546
Tb1 Rh 3.3288(5) 7_556
Tb1 Rh 3.3288(5) 7_546
Tb1 Tb4 3.5381(6) 5_656
Tb1 Tb2 3.6018(5) 1_556
Tb1 Tb3 3.6999(5) 7_546
Tb1 Tb3 3.6999(5) 7_556
Tb2 Ge2 2.9205(6) 7_545
Tb2 Ge2 2.9205(6) 7
Tb2 Ge1 3.0622(7) 7_556
Tb2 Ge1 3.0622(7) 7_546
Tb2 Rh 3.0761(7) .
Tb2 Ge4 3.0891(6) 3_455
Tb2 Ge4 3.0891(6) 3_445
Tb2 Rh 3.1105(5) 7_545
Tb2 Rh 3.1105(5) 7
Tb2 In2 3.3826(3) 3
Tb2 In2 3.3826(3) 3_545
Tb2 Tb1 3.6019(5) 1_554
Tb3 Ge3 2.9634(6) 7_556
Tb3 Ge3 2.9634(6) 7_546
Tb3 Ge1 3.0687(7) 7_546
Tb3 Ge1 3.0687(7) 7_556
Tb3 Ge4 3.0940(6) 3_445
Tb3 Ge4 3.0940(6) 3_455
Tb3 Rh 3.2068(7) .
Tb3 In1 3.3673(3) 3
Tb3 In1 3.3673(3) 3_545
Tb3 Tb1 3.6998(5) 7_546
Tb3 Tb1 3.6998(5) 7_556
Tb4 Ge1 2.9531(7) 7_546
Tb4 Ge1 2.9531(7) 7_556
Tb4 Ge2 3.0747(7) 3
Tb4 Ge2 3.0747(7) 3_545
Tb4 Ge3 3.1900(7) 3
Tb4 Ge3 3.1900(7) 3_545
Tb4 In1 3.4209(3) 3
Tb4 In1 3.4209(3) 3_545
Tb4 In2 3.4358(3) 3_545
Tb4 In2 3.4358(3) 3
Tb4 Tb1 3.5381(6) 5_656
Tb4 Tb3 3.7253(5) 5_656
Rh Ge4 2.4703(5) 3_455
Rh Ge4 2.4703(5) 3_445
Rh Ge4 2.5419(10) 5_655
Rh Ge2 2.5524(10) .
Rh Tb2 3.1105(5) 7_545
Rh Tb2 3.1105(5) 7
Rh Rh 3.1481(8) 7_545
Rh Rh 3.1481(8) 7
Rh Tb1 3.3288(5) 7_556
Rh Tb1 3.3288(5) 7_546
In1 Ge1 2.8701(9) 5_556
In1 Ge1 2.8701(9) .
In1 Ge3 3.0700(9) 5_556
In1 Ge3 3.0701(9) .
In1 Tb3 3.3672(3) 3_445
In1 Tb3 3.3672(3) 7_556
In1 Tb3 3.3672(3) 7_546
In1 Tb3 3.3672(3) 3_455
In1 Tb4 3.4209(3) 3_445
In1 Tb4 3.4209(3) 7_556
In1 Tb4 3.4209(3) 7_546
In1 Tb4 3.4209(3) 3_455
In2 Ge1 2.8177(9) 5_556
In2 Ge1 2.8177(9) 1_554
In2 Ge2 2.8702(9) 5
In2 Ge2 2.8703(9) .
In2 Tb2 3.3825(3) 3_445
In2 Tb2 3.3825(3) 7
In2 Tb2 3.3825(3) 3_455
In2 Tb2 3.3825(3) 7_545
In2 Tb4 3.4358(3) 3_455
In2 Tb4 3.4358(3) 7_545
In2 Tb4 3.4358(3) 7
In2 Tb4 3.4358(3) 3_445
Ge1 Ge4 2.5958(12) 5_656
Ge1 In2 2.8176(9) 1_556
Ge1 Tb4 2.9530(7) 7_546
Ge1 Tb4 2.9530(7) 7_556
Ge1 Tb2 3.0622(7) 7_556
Ge1 Tb2 3.0622(7) 7_546
Ge1 Tb3 3.0687(7) 7_546
Ge1 Tb3 3.0687(7) 7_556
Ge2 Ge3 2.6192(12) .
Ge2 Tb2 2.9205(6) 7_545
Ge2 Tb2 2.9205(6) 7
Ge2 Tb1 2.9768(7) 7_556
Ge2 Tb1 2.9768(7) 7_546
Ge2 Tb4 3.0748(7) 3_445
Ge2 Tb4 3.0748(7) 3_455
Ge3 Tb3 2.9635(6) 7_556
Ge3 Tb3 2.9635(6) 7_546
Ge3 Tb1 3.0261(6) 7_556
Ge3 Tb1 3.0261(6) 7_546
Ge3 Tb4 3.1900(7) 3_445
Ge3 Tb4 3.1900(7) 3_455
Ge4 Rh 2.4703(5) 3_545
Ge4 Rh 2.4703(5) 3
Ge4 Rh 2.5420(10) 5_655
Ge4 Ge1 2.5958(12) 5_656
Ge4 Tb1 2.9166(9) 5_656
Ge4 Tb2 3.0891(6) 3_545
Ge4 Tb2 3.0891(6) 3
Ge4 Tb3 3.0941(6) 3
Ge4 Tb3 3.0941(6) 3_545
