#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342582.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342582
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Pr4 Fe2 In Ge4'
_chemical_formula_sum            'Fe2 Ge4 In Pr4'
_chemical_formula_weight         1080.52
_chemical_name_common
'praseodymium iron indium germanide (4/2/1/4)'
_chemical_name_systematic
'praseodymium iron indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 106.8770(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.0089(12)
_cell_length_b                   4.3242(3)
_cell_length_c                   7.2282(5)
_cell_measurement_reflns_used    1984
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.03
_cell_measurement_theta_min      4.90
_cell_volume                     478.83(6)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0344
_diffrn_reflns_av_unetI/netI     0.0304
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.977
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3440
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.977
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.240
_diffrn_reflns_theta_min         2.659
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    37.479
_exptl_absorpt_correction_T_max  0.4345
_exptl_absorpt_correction_T_min  0.2636
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.494
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             930
_exptl_crystal_size_max          0.056
_exptl_crystal_size_mid          0.033
_exptl_crystal_size_min          0.030
_refine_diff_density_max         2.188
_refine_diff_density_min         -1.698
_refine_diff_density_rms         0.345
_refine_ls_extinction_coef       0.00078(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         1000
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.006
_refine_ls_R_factor_all          0.0282
_refine_ls_R_factor_gt           0.0202
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0154P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0370
_refine_ls_wR_factor_ref         0.0390
_reflns_Friedel_coverage         0.000
_reflns_number_gt                847
_reflns_number_total             1000
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_002.cif
_cod_data_source_block           Pr4Fe2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342582
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.228
_shelx_estimated_absorpt_t_max   0.399
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pr1 Pr 0.34777(2) 0.0000 0.06093(4) 0.00669(8) Uani 1 2 d S T P
Pr2 Pr 0.58812(2) 0.0000 0.37653(4) 0.00636(8) Uani 1 2 d S T P
Fe Fe 0.21719(5) 0.0000 0.62709(11) 0.00670(16) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00862(17) Uani 0.974(3) 4 d S T .
Ge1 Ge 0.06585(4) 0.0000 0.65361(8) 0.00653(12) Uani 1 2 d S T P
Ge2 Ge 0.21072(4) 0.0000 0.27811(9) 0.00749(13) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Pr1 Ge1 91.007(18) 7_556 7_546
Ge1 Pr1 Ge2 84.474(16) 7_556 .
Ge1 Pr1 Ge2 84.474(16) 7_546 .
Ge1 Pr1 Ge2 168.021(19) 7_556 7_545
Ge1 Pr1 Ge2 90.781(12) 7_546 7_545
Ge2 Pr1 Ge2 107.489(14) . 7_545
Ge1 Pr1 Ge2 90.781(12) 7_556 7
Ge1 Pr1 Ge2 168.021(19) 7_546 7
Ge2 Pr1 Ge2 107.489(14) . 7
Ge2 Pr1 Ge2 85.088(17) 7_545 7
Ge1 Pr1 Fe 134.496(9) 7_556 1_554
Ge1 Pr1 Fe 134.496(9) 7_546 1_554
Ge2 Pr1 Fe 98.08(2) . 1_554
Ge2 Pr1 Fe 44.907(10) 7_545 1_554
Ge2 Pr1 Fe 44.907(10) 7 1_554
Ge1 Pr1 In 55.170(12) 7_556 3
Ge1 Pr1 In 109.946(15) 7_546 3
Ge2 Pr1 In 136.172(7) . 3
Ge2 Pr1 In 113.224(13) 7_545 3
Ge2 Pr1 In 61.936(11) 7 3
Fe Pr1 In 99.301(13) 1_554 3
Ge1 Pr1 In 109.946(15) 7_556 3_545
Ge1 Pr1 In 55.170(12) 7_546 3_545
Ge2 Pr1 In 136.172(7) . 3_545
Ge2 Pr1 In 61.936(11) 7_545 3_545
Ge2 Pr1 In 113.224(13) 7 3_545
Fe Pr1 In 99.301(13) 1_554 3_545
In Pr1 In 79.506(9) 3 3_545
Ge1 Pr1 Fe 44.074(17) 7_556 7_556
Ge1 Pr1 Fe 99.470(17) 7_546 7_556
Ge2 Pr1 Fe 43.393(12) . 7_556
Ge2 Pr1 Fe 146.87(2) 7_545 7_556
Ge2 Pr1 Fe 90.026(14) 7 7_556
Fe Pr1 Fe 113.415(16) 1_554 7_556
In Pr1 Fe 92.820(11) 3 7_556
In Pr1 Fe 147.224(16) 3_545 7_556
Ge1 Pr1 Fe 99.470(17) 7_556 7_546
Ge1 Pr1 Fe 44.074(17) 7_546 7_546
Ge2 Pr1 Fe 43.393(12) . 7_546
Ge2 Pr1 Fe 90.026(14) 7_545 7_546
Ge2 Pr1 Fe 146.87(2) 7 7_546
Fe Pr1 Fe 113.415(16) 1_554 7_546
In Pr1 Fe 147.224(16) 3 7_546
In Pr1 Fe 92.820(11) 3_545 7_546
Fe Pr1 Fe 76.477(18) 7_556 7_546
Ge1 Pr1 Pr2 114.093(14) 7_556 5_655
Ge1 Pr1 Pr2 114.093(14) 7_546 5_655
Ge2 Pr1 Pr2 152.274(17) . 5_655
Ge2 Pr1 Pr2 54.621(11) 7_545 5_655
Ge2 Pr1 Pr2 54.621(11) 7 5_655
Fe Pr1 Pr2 54.189(17) 1_554 5_655
In Pr1 Pr2 59.005(6) 3 5_655
In Pr1 Pr2 59.005(6) 3_545 5_655
Fe Pr1 Pr2 141.438(9) 7_556 5_655
Fe Pr1 Pr2 141.438(9) 7_546 5_655
Ge1 Pr1 Pr1 140.113(18) 7_556 7_545
Ge1 Pr1 Pr1 86.123(12) 7_546 7_545
Ge2 Pr1 Pr1 55.643(12) . 7_545
Ge2 Pr1 Pr1 51.846(12) 7_545 7_545
Ge2 Pr1 Pr1 100.002(15) 7 7_545
Fe Pr1 Pr1 60.193(14) 1_554 7_545
In Pr1 Pr1 159.407(14) 3 7_545
In Pr1 Pr1 100.812(7) 3_545 7_545
Fe Pr1 Pr1 97.224(16) 7_556 7_545
Fe Pr1 Pr1 53.222(14) 7_546 7_545
Pr2 Pr1 Pr1 103.219(12) 5_655 7_545
Ge1 Pr2 Ge1 90.755(18) 3 3_545
Ge1 Pr2 Fe 108.291(17) 3 5_656
Ge1 Pr2 Fe 108.291(17) 3_545 5_656
Ge1 Pr2 Ge2 81.946(13) 3 3
Ge1 Pr2 Ge2 147.23(2) 3_545 3
Fe Pr2 Ge2 46.124(11) 5_656 3
Ge1 Pr2 Ge2 147.23(2) 3 3_545
Ge1 Pr2 Ge2 81.946(13) 3_545 3_545
Fe Pr2 Ge2 46.124(11) 5_656 3_545
Ge2 Pr2 Ge2 87.123(17) 3 3_545
Ge1 Pr2 Fe 47.136(18) 3 3
Ge1 Pr2 Fe 106.891(19) 3_545 3
Fe Pr2 Fe 61.218(19) 5_656 3
Ge2 Pr2 Fe 46.583(18) 3 3
Ge2 Pr2 Fe 104.635(19) 3_545 3
Ge1 Pr2 Fe 106.891(19) 3 3_545
Ge1 Pr2 Fe 47.136(18) 3_545 3_545
Fe Pr2 Fe 61.218(19) 5_656 3_545
Ge2 Pr2 Fe 104.635(19) 3 3_545
Ge2 Pr2 Fe 46.583(18) 3_545 3_545
Fe Pr2 Fe 86.00(2) 3 3_545
Ge1 Pr2 Ge1 106.666(12) 3 7_546
Ge1 Pr2 Ge1 48.42(2) 3_545 7_546
Fe Pr2 Ge1 137.828(9) 5_656 7_546
Ge2 Pr2 Ge1 163.522(18) 3 7_546
Ge2 Pr2 Ge1 92.218(12) 3_545 7_546
Fe Pr2 Ge1 148.308(19) 3 7_546
Fe Pr2 Ge1 86.571(15) 3_545 7_546
Ge1 Pr2 Ge1 48.42(2) 3 7_556
Ge1 Pr2 Ge1 106.666(12) 3_545 7_556
Fe Pr2 Ge1 137.828(9) 5_656 7_556
Ge2 Pr2 Ge1 92.218(12) 3 7_556
Ge2 Pr2 Ge1 163.522(18) 3_545 7_556
Fe Pr2 Ge1 86.571(15) 3 7_556
Fe Pr2 Ge1 148.308(19) 3_545 7_556
Ge1 Pr2 Ge1 83.776(17) 7_546 7_556
Ge1 Pr2 In 150.338(16) 3 3_545
Ge1 Pr2 In 88.545(11) 3_545 3_545
Fe Pr2 In 100.038(14) 5_656 3_545
Ge2 Pr2 In 113.170(14) 3 3_545
Ge2 Pr2 In 61.805(12) 3_545 3_545
Fe Pr2 In 158.405(17) 3 3_545
Fe Pr2 In 94.178(12) 3_545 3_545
Ge1 Pr2 In 52.990(11) 7_546 3_545
Ge1 Pr2 In 103.710(13) 7_556 3_545
Ge1 Pr2 In 88.545(11) 3 3
Ge1 Pr2 In 150.338(16) 3_545 3
Fe Pr2 In 100.038(14) 5_656 3
Ge2 Pr2 In 61.805(12) 3 3
Ge2 Pr2 In 113.170(14) 3_545 3
Fe Pr2 In 94.178(12) 3 3
Fe Pr2 In 158.405(17) 3_545 3
Ge1 Pr2 In 103.710(13) 7_546 3
Ge1 Pr2 In 52.990(11) 7_556 3
In Pr2 In 77.846(8) 3_545 3
Ge1 Pr2 Ge2 77.690(15) 3 5_656
Ge1 Pr2 Ge2 77.690(15) 3_545 5_656
Fe Pr2 Ge2 44.207(18) 5_656 5_656
Ge2 Pr2 Ge2 69.548(16) 3 5_656
Ge2 Pr2 Ge2 69.548(16) 3_545 5_656
Fe Pr2 Ge2 43.198(11) 3 5_656
Fe Pr2 Ge2 43.198(11) 3_545 5_656
Ge1 Pr2 Ge2 125.470(13) 7_546 5_656
Ge1 Pr2 Ge2 125.470(13) 7_556 5_656
In Pr2 Ge2 130.814(9) 3_545 5_656
In Pr2 Ge2 130.814(9) 3 5_656
Ge2 Fe Ge2 123.63(4) 7_556 7_546
Ge2 Fe Ge1 111.63(2) 7_556 .
Ge2 Fe Ge1 111.63(2) 7_546 .
Ge2 Fe Ge2 99.24(3) 7_556 .
Ge2 Fe Ge2 99.24(3) 7_546 .
Ge1 Fe Ge2 108.83(4) . .
Ge2 Fe Pr2 67.22(2) 7_556 5_656
Ge2 Fe Pr2 67.22(2) 7_546 5_656
Ge1 Fe Pr2 176.22(4) . 5_656
Ge2 Fe Pr2 74.94(3) . 5_656
Ge2 Fe Pr2 159.46(3) 7_556 3_445
Ge2 Fe Pr2 74.585(16) 7_546 3_445
Ge1 Fe Pr2 63.629(18) . 3_445
Ge2 Fe Pr2 66.013(19) . 3_445
Pr2 Fe Pr2 118.782(19) 5_656 3_445
Ge2 Fe Pr2 74.585(16) 7_556 3_455
Ge2 Fe Pr2 159.46(3) 7_546 3_455
Ge1 Fe Pr2 63.629(18) . 3_455
Ge2 Fe Pr2 66.013(19) . 3_455
Pr2 Fe Pr2 118.782(19) 5_656 3_455
Pr2 Fe Pr2 86.00(2) 3_445 3_455
Ge2 Fe Pr1 66.97(2) 7_556 1_556
Ge2 Fe Pr1 66.97(2) 7_546 1_556
Ge1 Fe Pr1 107.23(3) . 1_556
Ge2 Fe Pr1 143.93(4) . 1_556
Pr2 Fe Pr1 68.993(19) 5_656 1_556
Pr2 Fe Pr1 133.357(14) 3_445 1_556
Pr2 Fe Pr1 133.357(14) 3_455 1_556
Ge2 Fe Pr1 58.546(18) 7_556 7_556
Ge2 Fe Pr1 124.70(3) 7_546 7_556
Ge1 Fe Pr1 58.039(17) . 7_556
Ge2 Fe Pr1 136.062(18) . 7_556
Pr2 Fe Pr1 119.34(2) 5_656 7_556
Pr2 Fe Pr1 121.61(3) 3_445 7_556
Pr2 Fe Pr1 71.332(13) 3_455 7_556
Pr1 Fe Pr1 66.584(16) 1_556 7_556
Ge2 Fe Pr1 124.70(3) 7_556 7_546
Ge2 Fe Pr1 58.546(18) 7_546 7_546
Ge1 Fe Pr1 58.039(17) . 7_546
Ge2 Fe Pr1 136.062(18) . 7_546
Pr2 Fe Pr1 119.34(2) 5_656 7_546
Pr2 Fe Pr1 71.332(13) 3_445 7_546
Pr2 Fe Pr1 121.61(3) 3_455 7_546
Pr1 Fe Pr1 66.584(16) 1_556 7_546
Pr1 Fe Pr1 76.477(18) 7_556 7_546
Ge1 In Ge1 180.000(19) 5_556 1_554
Ge1 In Pr1 56.452(9) 5_556 3_445
Ge1 In Pr1 123.548(9) 1_554 3_445
Ge1 In Pr1 123.548(9) 5_556 7
Ge1 In Pr1 56.452(9) 1_554 7
Pr1 In Pr1 180.0 3_445 7
Ge1 In Pr1 123.548(9) 5_556 7_545
Ge1 In Pr1 56.452(9) 1_554 7_545
Pr1 In Pr1 100.495(9) 3_445 7_545
Pr1 In Pr1 79.505(9) 7 7_545
Ge1 In Pr1 56.452(9) 5_556 3_455
Ge1 In Pr1 123.548(9) 1_554 3_455
Pr1 In Pr1 79.505(9) 3_445 3_455
Pr1 In Pr1 100.495(9) 7 3_455
Pr1 In Pr1 180.000(10) 7_545 3_455
Ge1 In Pr2 60.016(10) 5_556 3_455
Ge1 In Pr2 119.984(10) 1_554 3_455
Pr1 In Pr2 116.376(7) 3_445 3_455
Pr1 In Pr2 63.624(7) 7 3_455
Pr1 In Pr2 111.055(8) 7_545 3_455
Pr1 In Pr2 68.945(8) 3_455 3_455
Ge1 In Pr2 119.984(10) 5_556 7_545
Ge1 In Pr2 60.016(10) 1_554 7_545
Pr1 In Pr2 63.624(7) 3_445 7_545
Pr1 In Pr2 116.376(7) 7 7_545
Pr1 In Pr2 68.945(8) 7_545 7_545
Pr1 In Pr2 111.055(8) 3_455 7_545
Pr2 In Pr2 180.0 3_455 7_545
Ge1 In Pr2 60.016(10) 5_556 3_445
Ge1 In Pr2 119.984(10) 1_554 3_445
Pr1 In Pr2 68.945(8) 3_445 3_445
Pr1 In Pr2 111.055(8) 7 3_445
Pr1 In Pr2 63.624(7) 7_545 3_445
Pr1 In Pr2 116.376(7) 3_455 3_445
Pr2 In Pr2 77.846(8) 3_455 3_445
Pr2 In Pr2 102.154(8) 7_545 3_445
Ge1 In Pr2 119.984(10) 5_556 7
Ge1 In Pr2 60.016(10) 1_554 7
Pr1 In Pr2 111.055(8) 3_445 7
Pr1 In Pr2 68.945(8) 7 7
Pr1 In Pr2 116.376(7) 7_545 7
Pr1 In Pr2 63.624(7) 3_455 7
Pr2 In Pr2 102.154(8) 3_455 7
Pr2 In Pr2 77.846(8) 7_545 7
Pr2 In Pr2 180.0 3_445 7
Fe Ge1 Ge1 120.33(4) . 5_556
Fe Ge1 In 130.86(3) . 1_556
Ge1 Ge1 In 108.81(3) 5_556 1_556
Fe Ge1 Pr1 77.888(19) . 7_556
Ge1 Ge1 Pr1 133.091(12) 5_556 7_556
In Ge1 Pr1 68.377(13) 1_556 7_556
Fe Ge1 Pr1 77.888(19) . 7_546
Ge1 Ge1 Pr1 133.091(12) 5_556 7_546
In Ge1 Pr1 68.377(13) 1_556 7_546
Pr1 Ge1 Pr1 91.007(18) 7_556 7_546
Fe Ge1 Pr2 69.235(18) . 3_445
Ge1 Ge1 Pr2 69.854(19) 5_556 3_445
In Ge1 Pr2 133.675(10) 1_556 3_445
Pr1 Ge1 Pr2 147.01(2) 7_556 3_445
Pr1 Ge1 Pr2 79.830(10) 7_546 3_445
Fe Ge1 Pr2 69.235(18) . 3_455
Ge1 Ge1 Pr2 69.854(19) 5_556 3_455
In Ge1 Pr2 133.675(10) 1_556 3_455
Pr1 Ge1 Pr2 79.830(10) 7_556 3_455
Pr1 Ge1 Pr2 147.01(2) 7_546 3_455
Pr2 Ge1 Pr2 90.755(18) 3_445 3_455
Fe Ge1 Pr2 137.299(10) . 7_546
Ge1 Ge1 Pr2 61.724(18) 5_556 7_546
In Ge1 Pr2 66.994(12) 1_556 7_546
Pr1 Ge1 Pr2 135.23(2) 7_556 7_546
Pr1 Ge1 Pr2 75.966(10) 7_546 7_546
Pr2 Ge1 Pr2 73.334(12) 3_445 7_546
Pr2 Ge1 Pr2 131.58(2) 3_455 7_546
Fe Ge1 Pr2 137.299(10) . 7_556
Ge1 Ge1 Pr2 61.724(18) 5_556 7_556
In Ge1 Pr2 66.994(12) 1_556 7_556
Pr1 Ge1 Pr2 75.966(10) 7_556 7_556
Pr1 Ge1 Pr2 135.23(2) 7_546 7_556
Pr2 Ge1 Pr2 131.58(2) 3_445 7_556
Pr2 Ge1 Pr2 73.334(12) 3_455 7_556
Pr2 Ge1 Pr2 83.774(17) 7_546 7_556
Fe Ge2 Fe 123.63(4) 7_556 7_546
Fe Ge2 Fe 80.76(3) 7_556 .
Fe Ge2 Fe 80.76(3) 7_546 .
Fe Ge2 Pr1 78.06(2) 7_556 .
Fe Ge2 Pr1 78.06(2) 7_546 .
Fe Ge2 Pr1 134.15(3) . .
Fe Ge2 Pr2 144.95(3) 7_556 3_445
Fe Ge2 Pr2 66.66(2) 7_546 3_445
Fe Ge2 Pr2 67.402(18) . 3_445
Pr1 Ge2 Pr2 135.109(10) . 3_445
Fe Ge2 Pr2 66.66(2) 7_556 3_455
Fe Ge2 Pr2 144.95(3) 7_546 3_455
Fe Ge2 Pr2 67.402(18) . 3_455
Pr1 Ge2 Pr2 135.109(10) . 3_455
Pr2 Ge2 Pr2 87.124(17) 3_445 3_455
Fe Ge2 Pr1 145.03(3) 7_556 7_545
Fe Ge2 Pr1 68.127(19) 7_546 7_545
Fe Ge2 Pr1 133.787(13) . 7_545
Pr1 Ge2 Pr1 72.510(14) . 7_545
Pr2 Ge2 Pr1 69.179(11) 3_445 7_545
Pr2 Ge2 Pr1 125.20(2) 3_455 7_545
Fe Ge2 Pr1 68.127(19) 7_556 7
Fe Ge2 Pr1 145.03(3) 7_546 7
Fe Ge2 Pr1 133.787(13) . 7
Pr1 Ge2 Pr1 72.510(14) . 7
Pr2 Ge2 Pr1 125.20(2) 3_445 7
Pr2 Ge2 Pr1 69.179(11) 3_455 7
Pr1 Ge2 Pr1 85.089(17) 7_545 7
Fe Ge2 Pr2 62.22(2) 7_556 5_656
Fe Ge2 Pr2 62.22(2) 7_546 5_656
Fe Ge2 Pr2 60.85(2) . 5_656
Pr1 Ge2 Pr2 73.300(17) . 5_656
Pr2 Ge2 Pr2 110.451(16) 3_445 5_656
Pr2 Ge2 Pr2 110.451(16) 3_455 5_656
Pr1 Ge2 Pr2 123.913(14) 7_545 5_656
Pr1 Ge2 Pr2 123.913(14) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pr1 Ge1 3.0311(5) 7_556
Pr1 Ge1 3.0311(5) 7_546
Pr1 Ge2 3.0459(7) .
Pr1 Ge2 3.1976(5) 7_545
Pr1 Ge2 3.1976(5) 7
Pr1 Fe 3.2245(9) 1_554
Pr1 In 3.3810(3) 3
Pr1 In 3.3810(3) 3_545
Pr1 Fe 3.4933(7) 7_556
Pr1 Fe 3.4933(7) 7_546
Pr1 Pr2 3.5966(5) 5_655
Pr1 Pr1 3.6943(6) 7_545
Pr2 Ge1 3.0377(5) 3
Pr2 Ge1 3.0377(5) 3_545
Pr2 Fe 3.1244(9) 5_656
Pr2 Ge2 3.1374(5) 3
Pr2 Ge2 3.1374(5) 3_545
Pr2 Fe 3.1703(7) 3
Pr2 Fe 3.1703(7) 3_545
Pr2 Ge1 3.2383(5) 7_546
Pr2 Ge1 3.2383(5) 7_556
Pr2 In 3.4413(3) 3_545
Pr2 In 3.4413(3) 3
Pr2 Ge2 3.4545(7) 5_656
Fe Ge2 2.4529(5) 7_556
Fe Ge2 2.4529(5) 7_546
Fe Ge1 2.4852(10) .
Fe Ge2 2.4944(10) .
Fe Pr2 3.1244(9) 5_656
Fe Pr2 3.1703(7) 3_445
Fe Pr2 3.1703(7) 3_455
Fe Pr1 3.2245(9) 1_556
Fe Pr1 3.4932(7) 7_556
Fe Pr1 3.4932(7) 7_546
In Ge1 2.9854(6) 5_556
In Ge1 2.9854(6) 1_554
In Pr1 3.3811(3) 3_445
In Pr1 3.3811(3) 7
In Pr1 3.3811(3) 7_545
In Pr1 3.3811(3) 3_455
In Pr2 3.4413(3) 3_455
In Pr2 3.4413(3) 7_545
In Pr2 3.4413(3) 3_445
In Pr2 3.4413(3) 7
Ge1 Ge1 2.5803(12) 5_556
Ge1 In 2.9855(6) 1_556
Ge1 Pr1 3.0312(5) 7_556
Ge1 Pr1 3.0312(5) 7_546
Ge1 Pr2 3.0377(5) 3_445
Ge1 Pr2 3.0377(5) 3_455
Ge1 Pr2 3.2383(5) 7_546
Ge1 Pr2 3.2383(5) 7_556
Ge2 Fe 2.4530(5) 7_556
Ge2 Fe 2.4530(5) 7_546
Ge2 Pr2 3.1374(5) 3_445
Ge2 Pr2 3.1374(5) 3_455
Ge2 Pr1 3.1976(5) 7_545
Ge2 Pr1 3.1976(5) 7
Ge2 Pr2 3.4545(7) 5_656
