#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342583.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342583
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Nd4 Fe2 In Ge4'
_chemical_formula_sum            'Fe2 Ge4 In Nd4'
_chemical_formula_weight         1093.84
_chemical_name_common            'neodymium iron indium germanide (4/2/1/4)'
_chemical_name_systematic        'neodymium iron indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 107.0650(9)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.9354(10)
_cell_length_b                   4.3102(3)
_cell_length_c                   7.2004(5)
_cell_measurement_reflns_used    3036
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.58
_cell_measurement_theta_min      4.92
_cell_volume                     472.78(6)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0256
_diffrn_reflns_av_unetI/netI     0.0218
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.978
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3336
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.180
_diffrn_reflns_theta_min         2.674
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    39.312
_exptl_absorpt_correction_T_max  0.4949
_exptl_absorpt_correction_T_min  0.1334
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.684
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             938
_exptl_crystal_size_max          0.074
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.034
_refine_diff_density_max         1.682
_refine_diff_density_min         -0.989
_refine_diff_density_rms         0.274
_refine_ls_extinction_coef       0.00030(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         982
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0217
_refine_ls_R_factor_gt           0.0168
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0175P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0361
_refine_ls_wR_factor_ref         0.0373
_reflns_Friedel_coverage         0.000
_reflns_number_gt                879
_reflns_number_total             982
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_002.cif
_cod_data_source_block           Nd4Fe2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342583
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.159
_shelx_estimated_absorpt_t_max   0.348
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Nd1 Nd 0.34754(2) 0.0000 0.06215(4) 0.00712(7) Uani 1 2 d S T P
Nd2 Nd 0.58823(2) 0.0000 0.37846(4) 0.00687(7) Uani 1 2 d S T P
Fe Fe 0.21763(4) 0.0000 0.62762(10) 0.00743(14) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00872(15) Uani 0.987(2) 4 d S T .
Ge1 Ge 0.06590(3) 0.0000 0.65421(7) 0.00701(11) Uani 1 2 d S T P
Ge2 Ge 0.20913(3) 0.0000 0.27565(7) 0.00746(11) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Nd1 Ge1 91.417(16) 7_556 7_546
Ge1 Nd1 Ge2 84.999(14) 7_556 .
Ge1 Nd1 Ge2 84.999(14) 7_546 .
Ge1 Nd1 Ge2 167.400(16) 7_556 7_545
Ge1 Nd1 Ge2 90.257(11) 7_546 7_545
Ge2 Nd1 Ge2 107.589(12) . 7_545
Ge1 Nd1 Ge2 90.257(11) 7_556 7
Ge1 Nd1 Ge2 167.400(16) 7_546 7
Ge2 Nd1 Ge2 107.589(12) . 7
Ge2 Nd1 Ge2 85.463(15) 7_545 7
Ge1 Nd1 Fe 134.287(8) 7_556 1_554
Ge1 Nd1 Fe 134.287(8) 7_546 1_554
Ge2 Nd1 Fe 97.883(18) . 1_554
Ge2 Nd1 Fe 45.201(9) 7_545 1_554
Ge2 Nd1 Fe 45.201(9) 7 1_554
Ge1 Nd1 In 55.138(10) 7_556 3
Ge1 Nd1 In 110.046(12) 7_546 3
Ge2 Nd1 In 136.508(6) . 3
Ge2 Nd1 In 112.696(12) 7_545 3
Ge2 Nd1 In 61.251(9) 7 3
Fe Nd1 In 98.887(11) 1_554 3
Ge1 Nd1 In 110.046(12) 7_556 3_545
Ge1 Nd1 In 55.138(10) 7_546 3_545
Ge2 Nd1 In 136.508(6) . 3_545
Ge2 Nd1 In 61.251(9) 7_545 3_545
Ge2 Nd1 In 112.696(12) 7 3_545
Fe Nd1 In 98.887(12) 1_554 3_545
In Nd1 In 79.391(8) 3 3_545
Ge1 Nd1 Fe 44.263(15) 7_556 7_556
Ge1 Nd1 Fe 99.888(15) 7_546 7_556
Ge2 Nd1 Fe 43.608(10) . 7_556
Ge2 Nd1 Fe 147.320(16) 7_545 7_556
Ge2 Nd1 Fe 90.001(13) 7 7_556
Fe Nd1 Fe 113.468(14) 1_554 7_556
In Nd1 Fe 92.969(10) 3 7_556
In Nd1 Fe 147.569(14) 3_545 7_556
Ge1 Nd1 Fe 99.888(15) 7_556 7_546
Ge1 Nd1 Fe 44.263(15) 7_546 7_546
Ge2 Nd1 Fe 43.608(10) . 7_546
Ge2 Nd1 Fe 90.001(13) 7_545 7_546
Ge2 Nd1 Fe 147.320(16) 7 7_546
Fe Nd1 Fe 113.468(14) 1_554 7_546
In Nd1 Fe 147.569(14) 3 7_546
In Nd1 Fe 92.969(9) 3_545 7_546
Fe Nd1 Fe 76.661(16) 7_556 7_546
Ge1 Nd1 Nd2 113.876(12) 7_556 5_655
Ge1 Nd1 Nd2 113.876(12) 7_546 5_655
Ge2 Nd1 Nd2 151.747(14) . 5_655
Ge2 Nd1 Nd2 54.330(10) 7_545 5_655
Ge2 Nd1 Nd2 54.330(10) 7 5_655
Fe Nd1 Nd2 53.864(14) 1_554 5_655
In Nd1 Nd2 58.824(5) 3 5_655
In Nd1 Nd2 58.824(5) 3_545 5_655
Fe Nd1 Nd2 141.322(8) 7_556 5_655
Fe Nd1 Nd2 141.322(8) 7_546 5_655
Ge1 Nd1 Nd1 140.552(16) 7_556 7_545
Ge1 Nd1 Nd1 86.089(10) 7_546 7_545
Ge2 Nd1 Nd1 55.555(10) . 7_545
Ge2 Nd1 Nd1 52.034(10) 7_545 7_545
Ge2 Nd1 Nd1 100.457(13) 7 7_545
Fe Nd1 Nd1 60.254(12) 1_554 7_545
In Nd1 Nd1 159.034(12) 3 7_545
In Nd1 Nd1 100.596(6) 3_545 7_545
Fe Nd1 Nd1 97.431(14) 7_556 7_545
Fe Nd1 Nd1 53.214(12) 7_546 7_545
Nd2 Nd1 Nd1 102.947(10) 5_655 7_545
Ge1 Nd2 Ge1 91.008(16) 3 3_545
Ge1 Nd2 Fe 108.608(14) 3 5_656
Ge1 Nd2 Fe 108.608(14) 3_545 5_656
Ge1 Nd2 Ge2 82.143(12) 3 3
Ge1 Nd2 Ge2 148.035(16) 3_545 3
Fe Nd2 Ge2 46.380(9) 5_656 3
Ge1 Nd2 Ge2 148.035(16) 3 3_545
Ge1 Nd2 Ge2 82.143(12) 3_545 3_545
Fe Nd2 Ge2 46.380(9) 5_656 3_545
Ge2 Nd2 Ge2 87.339(15) 3 3_545
Ge1 Nd2 Fe 47.320(15) 3 3
Ge1 Nd2 Fe 107.282(16) 3_545 3
Fe Nd2 Fe 61.342(17) 5_656 3
Ge2 Nd2 Fe 46.917(16) 3 3
Ge2 Nd2 Fe 105.115(16) 3_545 3
Ge1 Nd2 Fe 107.282(16) 3 3_545
Ge1 Nd2 Fe 47.320(15) 3_545 3_545
Fe Nd2 Fe 61.342(17) 5_656 3_545
Ge2 Nd2 Fe 105.115(16) 3 3_545
Ge2 Nd2 Fe 46.917(16) 3_545 3_545
Fe Nd2 Fe 86.224(19) 3 3_545
Ge1 Nd2 Ge1 106.896(10) 3 7_546
Ge1 Nd2 Ge1 48.468(17) 3_545 7_546
Fe Nd2 Ge1 137.683(7) 5_656 7_546
Ge2 Nd2 Ge1 162.624(16) 3 7_546
Ge2 Nd2 Ge1 91.786(11) 3_545 7_546
Fe Nd2 Ge1 148.800(17) 3 7_546
Fe Nd2 Ge1 86.653(13) 3_545 7_546
Ge1 Nd2 Ge1 48.468(17) 3 7_556
Ge1 Nd2 Ge1 106.896(10) 3_545 7_556
Fe Nd2 Ge1 137.683(7) 5_656 7_556
Ge2 Nd2 Ge1 91.786(11) 3 7_556
Ge2 Nd2 Ge1 162.624(16) 3_545 7_556
Fe Nd2 Ge1 86.653(13) 3 7_556
Fe Nd2 Ge1 148.800(17) 3_545 7_556
Ge1 Nd2 Ge1 83.902(14) 7_546 7_556
Ge1 Nd2 In 150.362(13) 3 3_545
Ge1 Nd2 In 88.516(9) 3_545 3_545
Fe Nd2 In 99.572(12) 5_656 3_545
Ge2 Nd2 In 112.489(12) 3 3_545
Ge2 Nd2 In 61.056(10) 3_545 3_545
Fe Nd2 In 158.008(15) 3 3_545
Fe Nd2 In 93.994(11) 3_545 3_545
Ge1 Nd2 In 52.913(9) 7_546 3_545
Ge1 Nd2 In 103.640(11) 7_556 3_545
Ge1 Nd2 In 88.516(10) 3 3
Ge1 Nd2 In 150.362(13) 3_545 3
Fe Nd2 In 99.572(12) 5_656 3
Ge2 Nd2 In 61.056(10) 3 3
Ge2 Nd2 In 112.489(12) 3_545 3
Fe Nd2 In 93.994(11) 3 3
Fe Nd2 In 158.008(15) 3_545 3
Ge1 Nd2 In 103.640(11) 7_546 3
Ge1 Nd2 In 52.913(9) 7_556 3
In Nd2 In 77.719(7) 3_545 3
Ge1 Nd2 Ge2 77.964(13) 3 5_656
Ge1 Nd2 Ge2 77.964(13) 3_545 5_656
Fe Nd2 Ge2 44.393(16) 5_656 5_656
Ge2 Nd2 Ge2 70.074(13) 3 5_656
Ge2 Nd2 Ge2 70.074(14) 3_545 5_656
Fe Nd2 Ge2 43.304(9) 3 5_656
Fe Nd2 Ge2 43.304(9) 3_545 5_656
Ge1 Nd2 Ge2 125.742(11) 7_546 5_656
Ge1 Nd2 Ge2 125.742(11) 7_556 5_656
In Nd2 Ge2 130.618(7) 3_545 5_656
In Nd2 Ge2 130.618(7) 3 5_656
Ge2 Fe Ge2 122.98(3) 7_556 7_546
Ge2 Fe Ge1 111.81(2) 7_556 .
Ge2 Fe Ge1 111.81(2) 7_546 .
Ge2 Fe Ge2 99.66(2) 7_556 .
Ge2 Fe Ge2 99.66(2) 7_546 .
Ge1 Fe Ge2 108.32(3) . .
Ge2 Fe Nd2 67.116(18) 7_556 5_656
Ge2 Fe Nd2 67.116(18) 7_546 5_656
Ge1 Fe Nd2 176.54(3) . 5_656
Ge2 Fe Nd2 75.14(2) . 5_656
Ge2 Fe Nd2 159.95(3) 7_556 3_445
Ge2 Fe Nd2 74.826(13) 7_546 3_445
Ge1 Fe Nd2 63.546(15) . 3_445
Ge2 Fe Nd2 65.861(16) . 3_445
Nd2 Fe Nd2 118.657(17) 5_656 3_445
Ge2 Fe Nd2 74.826(13) 7_556 3_455
Ge2 Fe Nd2 159.95(3) 7_546 3_455
Ge1 Fe Nd2 63.546(15) . 3_455
Ge2 Fe Nd2 65.861(16) . 3_455
Nd2 Fe Nd2 118.657(17) 5_656 3_455
Nd2 Fe Nd2 86.224(19) 3_445 3_455
Ge2 Fe Nd1 66.769(18) 7_556 1_556
Ge2 Fe Nd1 66.769(18) 7_546 1_556
Ge1 Fe Nd1 106.83(3) . 1_556
Ge2 Fe Nd1 144.84(3) . 1_556
Nd2 Fe Nd1 69.706(16) 5_656 1_556
Nd2 Fe Nd1 133.044(13) 3_445 1_556
Nd2 Fe Nd1 133.044(13) 3_455 1_556
Ge2 Fe Nd1 58.636(16) 7_556 7_556
Ge2 Fe Nd1 124.72(3) 7_546 7_556
Ge1 Fe Nd1 57.891(14) . 7_556
Ge2 Fe Nd1 135.624(15) . 7_556
Nd2 Fe Nd1 119.719(17) 5_656 7_556
Nd2 Fe Nd1 121.38(2) 3_445 7_556
Nd2 Fe Nd1 70.913(11) 3_455 7_556
Nd1 Fe Nd1 66.531(14) 1_556 7_556
Ge2 Fe Nd1 124.72(3) 7_556 7_546
Ge2 Fe Nd1 58.636(16) 7_546 7_546
Ge1 Fe Nd1 57.891(14) . 7_546
Ge2 Fe Nd1 135.624(15) . 7_546
Nd2 Fe Nd1 119.719(17) 5_656 7_546
Nd2 Fe Nd1 70.913(11) 3_445 7_546
Nd2 Fe Nd1 121.38(2) 3_455 7_546
Nd1 Fe Nd1 66.531(14) 1_556 7_546
Nd1 Fe Nd1 76.662(16) 7_556 7_546
Ge1 In Ge1 180.000(16) 5_556 1_554
Ge1 In Nd1 56.210(7) 5_556 3_445
Ge1 In Nd1 123.790(7) 1_554 3_445
Ge1 In Nd1 123.790(7) 5_556 7
Ge1 In Nd1 56.210(7) 1_554 7
Nd1 In Nd1 180.0 3_445 7
Ge1 In Nd1 123.790(7) 5_556 7_545
Ge1 In Nd1 56.210(7) 1_554 7_545
Nd1 In Nd1 100.610(8) 3_445 7_545
Nd1 In Nd1 79.390(8) 7 7_545
Ge1 In Nd1 56.210(7) 5_556 3_455
Ge1 In Nd1 123.790(7) 1_554 3_455
Nd1 In Nd1 79.390(8) 3_445 3_455
Nd1 In Nd1 100.610(8) 7 3_455
Nd1 In Nd1 180.0 7_545 3_455
Ge1 In Nd2 59.899(8) 5_556 3_455
Ge1 In Nd2 120.101(8) 1_554 3_455
Nd1 In Nd2 116.012(6) 3_445 3_455
Nd1 In Nd2 63.988(7) 7 3_455
Nd1 In Nd2 111.279(7) 7_545 3_455
Nd1 In Nd2 68.721(6) 3_455 3_455
Ge1 In Nd2 120.101(8) 5_556 7_545
Ge1 In Nd2 59.899(8) 1_554 7_545
Nd1 In Nd2 63.988(7) 3_445 7_545
Nd1 In Nd2 116.012(6) 7 7_545
Nd1 In Nd2 68.721(6) 7_545 7_545
Nd1 In Nd2 111.279(7) 3_455 7_545
Nd2 In Nd2 180.0 3_455 7_545
Ge1 In Nd2 59.899(8) 5_556 3_445
Ge1 In Nd2 120.101(8) 1_554 3_445
Nd1 In Nd2 68.721(6) 3_445 3_445
Nd1 In Nd2 111.279(7) 7 3_445
Nd1 In Nd2 63.989(7) 7_545 3_445
Nd1 In Nd2 116.011(6) 3_455 3_445
Nd2 In Nd2 77.719(7) 3_455 3_445
Nd2 In Nd2 102.281(7) 7_545 3_445
Ge1 In Nd2 120.101(8) 5_556 7
Ge1 In Nd2 59.899(8) 1_554 7
Nd1 In Nd2 111.279(7) 3_445 7
Nd1 In Nd2 68.721(6) 7 7
Nd1 In Nd2 116.011(6) 7_545 7
Nd1 In Nd2 63.989(7) 3_455 7
Nd2 In Nd2 102.281(7) 3_455 7
Nd2 In Nd2 77.719(7) 7_545 7
Nd2 In Nd2 180.0 3_445 7
Fe Ge1 Ge1 120.07(3) . 5_556
Fe Ge1 In 131.03(2) . 1_556
Ge1 Ge1 In 108.89(3) 5_556 1_556
Fe Ge1 Nd1 77.846(16) . 7_556
Ge1 Ge1 Nd1 132.976(10) 5_556 7_556
In Ge1 Nd1 68.653(12) 1_556 7_556
Fe Ge1 Nd1 77.846(16) . 7_546
Ge1 Ge1 Nd1 132.976(10) 5_556 7_546
In Ge1 Nd1 68.653(12) 1_556 7_546
Nd1 Ge1 Nd1 91.417(16) 7_556 7_546
Fe Ge1 Nd2 69.134(15) . 3_445
Ge1 Ge1 Nd2 69.886(16) 5_556 3_445
In Ge1 Nd2 133.563(9) 1_556 3_445
Nd1 Ge1 Nd2 146.87(2) 7_556 3_445
Nd1 Ge1 Nd2 79.417(9) 7_546 3_445
Fe Ge1 Nd2 69.134(15) . 3_455
Ge1 Ge1 Nd2 69.886(16) 5_556 3_455
In Ge1 Nd2 133.563(9) 1_556 3_455
Nd1 Ge1 Nd2 79.417(9) 7_556 3_455
Nd1 Ge1 Nd2 146.87(2) 7_546 3_455
Nd2 Ge1 Nd2 91.007(16) 3_445 3_455
Fe Ge1 Nd2 137.162(8) . 7_546
Ge1 Ge1 Nd2 61.646(15) 5_556 7_546
In Ge1 Nd2 67.188(10) 1_556 7_546
Nd1 Ge1 Nd2 135.691(19) 7_556 7_546
Nd1 Ge1 Nd2 76.030(9) 7_546 7_546
Nd2 Ge1 Nd2 73.105(10) 3_445 7_546
Nd2 Ge1 Nd2 131.532(17) 3_455 7_546
Fe Ge1 Nd2 137.162(8) . 7_556
Ge1 Ge1 Nd2 61.646(15) 5_556 7_556
In Ge1 Nd2 67.188(11) 1_556 7_556
Nd1 Ge1 Nd2 76.030(9) 7_556 7_556
Nd1 Ge1 Nd2 135.690(19) 7_546 7_556
Nd2 Ge1 Nd2 131.532(17) 3_445 7_556
Nd2 Ge1 Nd2 73.105(10) 3_455 7_556
Nd2 Ge1 Nd2 83.900(14) 7_546 7_556
Fe Ge2 Fe 122.98(3) 7_556 7_546
Fe Ge2 Fe 80.34(2) 7_556 .
Fe Ge2 Fe 80.34(2) 7_546 .
Fe Ge2 Nd1 77.75(2) 7_556 .
Fe Ge2 Nd1 77.75(2) 7_546 .
Fe Ge2 Nd1 133.04(3) . .
Fe Ge2 Nd2 144.57(3) 7_556 3_445
Fe Ge2 Nd2 66.503(17) 7_546 3_445
Fe Ge2 Nd2 67.221(15) . 3_445
Nd1 Ge2 Nd2 135.300(8) . 3_445
Fe Ge2 Nd2 66.503(17) 7_556 3_455
Fe Ge2 Nd2 144.57(3) 7_546 3_455
Fe Ge2 Nd2 67.221(15) . 3_455
Nd1 Ge2 Nd2 135.300(8) . 3_455
Nd2 Ge2 Nd2 87.341(15) 3_445 3_455
Fe Ge2 Nd1 144.93(2) 7_556 7_545
Fe Ge2 Nd1 68.031(17) 7_546 7_545
Fe Ge2 Nd1 134.073(11) . 7_545
Nd1 Ge2 Nd1 72.410(12) . 7_545
Nd2 Ge2 Nd1 69.910(9) 3_445 7_545
Nd2 Ge2 Nd1 126.414(18) 3_455 7_545
Fe Ge2 Nd1 68.031(17) 7_556 7
Fe Ge2 Nd1 144.93(2) 7_546 7
Fe Ge2 Nd1 134.072(11) . 7
Nd1 Ge2 Nd1 72.410(12) . 7
Nd2 Ge2 Nd1 126.414(18) 3_445 7
Nd2 Ge2 Nd1 69.910(9) 3_455 7
Nd1 Ge2 Nd1 85.463(15) 7_545 7
Fe Ge2 Nd2 61.869(17) 7_556 5_656
Fe Ge2 Nd2 61.869(17) 7_546 5_656
Fe Ge2 Nd2 60.47(2) . 5_656
Nd1 Ge2 Nd2 72.572(14) . 5_656
Nd2 Ge2 Nd2 109.925(13) 3_445 5_656
Nd2 Ge2 Nd2 109.925(13) 3_455 5_656
Nd1 Ge2 Nd2 123.247(12) 7_545 5_656
Nd1 Ge2 Nd2 123.246(12) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Nd1 Ge1 3.0108(4) 7_556
Nd1 Ge1 3.0108(4) 7_546
Nd1 Ge2 3.0362(6) .
Nd1 Ge2 3.1760(4) 7_545
Nd1 Ge2 3.1760(4) 7
Nd1 Fe 3.2053(7) 1_554
Nd1 In 3.3742(3) 3
Nd1 In 3.3742(3) 3_545
Nd1 Fe 3.4749(6) 7_556
Nd1 Fe 3.4749(6) 7_546
Nd1 Nd2 3.6080(4) 5_655
Nd1 Nd1 3.6711(5) 7_545
Nd2 Ge1 3.0213(4) 3
Nd2 Ge1 3.0213(4) 3_545
Nd2 Fe 3.1068(7) 5_656
Nd2 Ge2 3.1211(4) 3
Nd2 Ge2 3.1211(4) 3_545
Nd2 Fe 3.1534(5) 3
Nd2 Fe 3.1534(5) 3_545
Nd2 Ge1 3.2238(4) 7_546
Nd2 Ge1 3.2238(4) 7_556
Nd2 In 3.4349(3) 3_545
Nd2 In 3.4349(3) 3
Nd2 Ge2 3.4511(6) 5_656
Fe Ge2 2.4525(4) 7_556
Fe Ge2 2.4525(4) 7_546
Fe Ge1 2.4809(8) .
Fe Ge2 2.4980(9) .
Fe Nd2 3.1068(7) 5_656
Fe Nd2 3.1534(5) 3_445
Fe Nd2 3.1534(5) 3_455
Fe Nd1 3.2052(7) 1_556
Fe Nd1 3.4748(6) 7_556
Fe Nd1 3.4748(6) 7_546
In Ge1 2.9726(5) 5_556
In Ge1 2.9726(5) 1_554
In Nd1 3.3742(3) 3_445
In Nd1 3.3742(3) 7
In Nd1 3.3742(3) 7_545
In Nd1 3.3742(3) 3_455
In Nd2 3.4349(3) 3_455
In Nd2 3.4349(3) 7_545
In Nd2 3.4349(3) 3_445
In Nd2 3.4349(3) 7
Ge1 Ge1 2.5701(10) 5_556
Ge1 In 2.9726(5) 1_556
Ge1 Nd1 3.0108(4) 7_556
Ge1 Nd1 3.0108(4) 7_546
Ge1 Nd2 3.0213(4) 3_445
Ge1 Nd2 3.0213(4) 3_455
Ge1 Nd2 3.2239(4) 7_546
Ge1 Nd2 3.2239(4) 7_556
Ge2 Fe 2.4525(4) 7_556
Ge2 Fe 2.4525(4) 7_546
Ge2 Nd2 3.1210(4) 3_445
Ge2 Nd2 3.1210(4) 3_455
Ge2 Nd1 3.1760(4) 7_545
Ge2 Nd1 3.1760(4) 7
Ge2 Nd2 3.4511(6) 5_656
