#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342584.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342584
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Sm4 Fe2 In Ge4'
_chemical_formula_sum            'Fe2 Ge4 In Sm4'
_chemical_formula_weight         1118.28
_chemical_name_common            'samarium iron indium germanide (4/2/1/4)'
_chemical_name_systematic        'samarium iron indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 107.011(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.770(4)
_cell_length_b                   4.2745(11)
_cell_length_c                   7.1211(17)
_cell_measurement_reflns_used    2356
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.90
_cell_measurement_theta_min      4.96
_cell_volume                     459.0(2)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0315
_diffrn_reflns_av_unetI/netI     0.0281
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.972
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3275
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.972
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.264
_diffrn_reflns_theta_min         2.701
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    43.454
_exptl_absorpt_correction_T_max  0.5206
_exptl_absorpt_correction_T_min  0.1503
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.091
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             954
_exptl_crystal_size_max          0.110
_exptl_crystal_size_mid          0.027
_exptl_crystal_size_min          0.024
_refine_diff_density_max         1.545
_refine_diff_density_min         -2.156
_refine_diff_density_rms         0.352
_refine_ls_extinction_coef       0.00104(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         959
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.0254
_refine_ls_R_factor_gt           0.0199
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0168P)²+0.3043P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0396
_refine_ls_wR_factor_ref         0.0412
_reflns_Friedel_coverage         0.000
_reflns_number_gt                842
_reflns_number_total             959
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_002.cif
_cod_data_source_block           Sm4Fe2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342584
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.087
_shelx_estimated_absorpt_t_max   0.422
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Sm1 Sm 0.34772(2) 0.0000 0.06255(4) 0.00629(8) Uani 1 2 d S T P
Sm2 Sm 0.58798(2) 0.0000 0.37920(4) 0.00596(8) Uani 1 2 d S T P
Fe Fe 0.21844(6) 0.0000 0.62850(13) 0.00617(16) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00754(18) Uani 0.964(3) 4 d S T .
Ge1 Ge 0.06620(4) 0.0000 0.65557(9) 0.00613(13) Uani 1 2 d S T P
Ge2 Ge 0.20748(4) 0.0000 0.27217(10) 0.00672(13) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Sm1 Ge1 91.88(3) 7_556 7_546
Ge1 Sm1 Ge2 85.51(2) 7_556 .
Ge1 Sm1 Ge2 85.51(2) 7_546 .
Ge1 Sm1 Ge2 167.213(19) 7_556 7_545
Ge1 Sm1 Ge2 89.64(2) 7_546 7_545
Ge2 Sm1 Ge2 107.269(18) . 7_545
Ge1 Sm1 Ge2 89.64(2) 7_556 7
Ge1 Sm1 Ge2 167.213(19) 7_546 7
Ge2 Sm1 Ge2 107.269(18) . 7
Ge2 Sm1 Ge2 86.15(3) 7_545 7
Ge1 Sm1 Fe 134.054(13) 7_556 1_554
Ge1 Sm1 Fe 134.054(14) 7_546 1_554
Ge2 Sm1 Fe 97.33(3) . 1_554
Ge2 Sm1 Fe 45.588(14) 7_545 1_554
Ge2 Sm1 Fe 45.588(14) 7 1_554
Ge1 Sm1 In 54.989(17) 7_556 3
Ge1 Sm1 In 110.23(2) 7_546 3
Ge2 Sm1 In 136.688(11) . 3
Ge2 Sm1 In 112.709(18) 7_545 3
Ge2 Sm1 In 60.799(16) 7 3
Fe Sm1 In 98.776(18) 1_554 3
Ge1 Sm1 In 110.23(2) 7_556 3_545
Ge1 Sm1 In 54.989(17) 7_546 3_545
Ge2 Sm1 In 136.688(11) . 3_545
Ge2 Sm1 In 60.799(16) 7_545 3_545
Ge2 Sm1 In 112.709(17) 7 3_545
Fe Sm1 In 98.776(18) 1_554 3_545
In Sm1 In 79.56(2) 3 3_545
Ge1 Sm1 Fe 44.44(2) 7_556 7_556
Ge1 Sm1 Fe 100.29(3) 7_546 7_556
Ge2 Sm1 Fe 43.808(14) . 7_556
Ge2 Sm1 Fe 147.39(2) 7_545 7_556
Ge2 Sm1 Fe 89.65(2) 7 7_556
Fe Sm1 Fe 113.27(2) 1_554 7_556
In Sm1 Fe 92.987(19) 3 7_556
In Sm1 Fe 147.879(18) 3_545 7_556
Ge1 Sm1 Fe 100.29(3) 7_556 7_546
Ge1 Sm1 Fe 44.44(2) 7_546 7_546
Ge2 Sm1 Fe 43.808(15) . 7_546
Ge2 Sm1 Fe 89.65(2) 7_545 7_546
Ge2 Sm1 Fe 147.39(2) 7 7_546
Fe Sm1 Fe 113.27(2) 1_554 7_546
In Sm1 Fe 147.879(18) 3 7_546
In Sm1 Fe 92.987(18) 3_545 7_546
Fe Sm1 Fe 76.80(3) 7_556 7_546
Ge1 Sm1 Sm2 113.754(18) 7_556 5_655
Ge1 Sm1 Sm2 113.754(18) 7_546 5_655
Ge2 Sm1 Sm2 151.067(18) . 5_655
Ge2 Sm1 Sm2 54.360(16) 7_545 5_655
Ge2 Sm1 Sm2 54.360(15) 7 5_655
Fe Sm1 Sm2 53.74(2) 1_554 5_655
In Sm1 Sm2 58.860(8) 3 5_655
In Sm1 Sm2 58.860(8) 3_545 5_655
Fe Sm1 Sm2 141.209(13) 7_556 5_655
Fe Sm1 Sm2 141.209(13) 7_546 5_655
Ge1 Sm1 Sm1 140.675(19) 7_556 7_545
Ge1 Sm1 Sm1 85.976(19) 7_546 7_545
Ge2 Sm1 Sm1 55.168(17) . 7_545
Ge2 Sm1 Sm1 52.101(14) 7_545 7_545
Ge2 Sm1 Sm1 100.814(19) 7 7_545
Fe Sm1 Sm1 60.253(16) 1_554 7_545
In Sm1 Sm1 158.928(15) 3 7_545
In Sm1 Sm1 100.48(2) 3_545 7_545
Fe Sm1 Sm1 97.34(2) 7_556 7_545
Fe Sm1 Sm1 53.020(18) 7_546 7_545
Sm2 Sm1 Sm1 102.846(15) 5_655 7_545
Ge1 Sm2 Ge1 91.16(3) 3 3_545
Ge1 Sm2 Fe 108.536(18) 3 5_656
Ge1 Sm2 Fe 108.536(18) 3_545 5_656
Ge1 Sm2 Ge2 82.17(2) 3 3
Ge1 Sm2 Ge2 148.45(2) 3_545 3
Fe Sm2 Ge2 46.668(14) 5_656 3
Ge1 Sm2 Ge2 148.45(2) 3 3_545
Ge1 Sm2 Ge2 82.17(2) 3_545 3_545
Fe Sm2 Ge2 46.668(14) 5_656 3_545
Ge2 Sm2 Ge2 87.57(2) 3 3_545
Ge1 Sm2 Fe 47.37(2) 3 3
Ge1 Sm2 Fe 107.29(3) 3_545 3
Fe Sm2 Fe 61.21(2) 5_656 3
Ge2 Sm2 Fe 47.23(2) 3 3
Ge2 Sm2 Fe 105.37(3) 3_545 3
Ge1 Sm2 Fe 107.29(3) 3 3_545
Ge1 Sm2 Fe 47.37(2) 3_545 3_545
Fe Sm2 Fe 61.21(2) 5_656 3_545
Ge2 Sm2 Fe 105.37(3) 3 3_545
Ge2 Sm2 Fe 47.23(2) 3_545 3_545
Fe Sm2 Fe 86.03(3) 3 3_545
Ge1 Sm2 Ge1 107.328(17) 3 7_546
Ge1 Sm2 Ge1 48.81(2) 3_545 7_546
Fe Sm2 Ge1 137.532(13) 5_656 7_546
Ge2 Sm2 Ge1 161.81(2) 3 7_546
Ge2 Sm2 Ge1 91.34(2) 3_545 7_546
Fe Sm2 Ge1 149.29(2) 3 7_546
Fe Sm2 Ge1 86.91(2) 3_545 7_546
Ge1 Sm2 Ge1 48.81(2) 3 7_556
Ge1 Sm2 Ge1 107.328(17) 3_545 7_556
Fe Sm2 Ge1 137.532(13) 5_656 7_556
Ge2 Sm2 Ge1 91.34(2) 3 7_556
Ge2 Sm2 Ge1 161.81(2) 3_545 7_556
Fe Sm2 Ge1 86.91(2) 3 7_556
Fe Sm2 Ge1 149.29(2) 3_545 7_556
Ge1 Sm2 Ge1 84.07(3) 7_546 7_556
Ge1 Sm2 In 150.620(18) 3 3_545
Ge1 Sm2 In 88.55(2) 3_545 3_545
Fe Sm2 In 99.352(16) 5_656 3_545
Ge2 Sm2 In 112.03(2) 3 3_545
Ge2 Sm2 In 60.424(18) 3_545 3_545
Fe Sm2 In 157.719(18) 3 3_545
Fe Sm2 In 93.95(2) 3_545 3_545
Ge1 Sm2 In 52.682(14) 7_546 3_545
Ge1 Sm2 In 103.554(18) 7_556 3_545
Ge1 Sm2 In 88.55(2) 3 3
Ge1 Sm2 In 150.620(18) 3_545 3
Fe Sm2 In 99.352(16) 5_656 3
Ge2 Sm2 In 60.424(18) 3 3
Ge2 Sm2 In 112.03(2) 3_545 3
Fe Sm2 In 93.95(2) 3 3
Fe Sm2 In 157.719(18) 3_545 3
Ge1 Sm2 In 103.554(18) 7_546 3
Ge1 Sm2 In 52.682(14) 7_556 3
In Sm2 In 77.76(2) 3_545 3
Ge1 Sm2 Ge2 77.854(19) 3 5_656
Ge1 Sm2 Ge2 77.854(19) 3_545 5_656
Fe Sm2 Ge2 44.51(2) 5_656 5_656
Ge2 Sm2 Ge2 70.60(2) 3 5_656
Ge2 Sm2 Ge2 70.60(2) 3_545 5_656
Fe Sm2 Ge2 43.189(14) 3 5_656
Fe Sm2 Ge2 43.189(14) 3_545 5_656
Ge1 Sm2 Ge2 125.937(17) 7_546 5_656
Ge1 Sm2 Ge2 125.937(17) 7_556 5_656
In Sm2 Ge2 130.508(11) 3_545 5_656
In Sm2 Ge2 130.508(11) 3 5_656
Ge2 Fe Ge2 122.38(5) 7_556 7_546
Ge2 Fe Ge1 111.86(2) 7_556 .
Ge2 Fe Ge1 111.86(2) 7_546 .
Ge2 Fe Ge2 100.36(3) 7_556 .
Ge2 Fe Ge2 100.36(3) 7_546 .
Ge1 Fe Ge2 107.50(4) . .
Ge2 Fe Sm2 67.09(2) 7_556 5_656
Ge2 Fe Sm2 67.09(2) 7_546 5_656
Ge1 Fe Sm2 176.69(4) . 5_656
Ge2 Fe Sm2 75.81(3) . 5_656
Ge2 Fe Sm2 160.30(3) 7_556 3_445
Ge2 Fe Sm2 75.28(2) 7_546 3_445
Ge1 Fe Sm2 63.32(2) . 3_445
Ge2 Fe Sm2 65.46(2) . 3_445
Sm2 Fe Sm2 118.79(2) 5_656 3_445
Ge2 Fe Sm2 75.28(2) 7_556 3_455
Ge2 Fe Sm2 160.30(3) 7_546 3_455
Ge1 Fe Sm2 63.32(2) . 3_455
Ge2 Fe Sm2 65.46(2) . 3_455
Sm2 Fe Sm2 118.79(2) 5_656 3_455
Sm2 Fe Sm2 86.03(3) 3_445 3_455
Ge2 Fe Sm1 66.41(2) 7_556 1_556
Ge2 Fe Sm1 66.41(2) 7_546 1_556
Ge1 Fe Sm1 106.71(3) . 1_556
Ge2 Fe Sm1 145.79(4) . 1_556
Sm2 Fe Sm1 69.98(2) 5_656 1_556
Sm2 Fe Sm1 132.984(17) 3_445 1_556
Sm2 Fe Sm1 132.984(17) 3_455 1_556
Ge2 Fe Sm1 58.63(2) 7_556 7_556
Ge2 Fe Sm1 124.61(3) 7_546 7_556
Ge1 Fe Sm1 57.683(18) . 7_556
Ge2 Fe Sm1 135.01(2) . 7_556
Sm2 Fe Sm1 120.04(2) 5_656 7_556
Sm2 Fe Sm1 120.96(3) 3_445 7_556
Sm2 Fe Sm1 70.54(2) 3_455 7_556
Sm1 Fe Sm1 66.72(2) 1_556 7_556
Ge2 Fe Sm1 124.61(3) 7_556 7_546
Ge2 Fe Sm1 58.63(2) 7_546 7_546
Ge1 Fe Sm1 57.683(18) . 7_546
Ge2 Fe Sm1 135.01(2) . 7_546
Sm2 Fe Sm1 120.04(2) 5_656 7_546
Sm2 Fe Sm1 70.54(2) 3_445 7_546
Sm2 Fe Sm1 120.96(3) 3_455 7_546
Sm1 Fe Sm1 66.72(2) 1_556 7_546
Sm1 Fe Sm1 76.80(3) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Sm1 56.146(11) 5_556 3_445
Ge1 In Sm1 123.854(11) 1_554 3_445
Ge1 In Sm1 123.854(11) 5_556 7
Ge1 In Sm1 56.146(11) 1_554 7
Sm1 In Sm1 180.0 3_445 7
Ge1 In Sm1 123.854(11) 5_556 7_545
Ge1 In Sm1 56.146(11) 1_554 7_545
Sm1 In Sm1 100.45(2) 3_445 7_545
Sm1 In Sm1 79.55(2) 7 7_545
Ge1 In Sm1 56.146(11) 5_556 3_455
Ge1 In Sm1 123.854(11) 1_554 3_455
Sm1 In Sm1 79.55(2) 3_445 3_455
Sm1 In Sm1 100.45(2) 7 3_455
Sm1 In Sm1 180.000(10) 7_545 3_455
Ge1 In Sm2 59.931(16) 5_556 3_455
Ge1 In Sm2 120.069(16) 1_554 3_455
Sm1 In Sm2 115.971(14) 3_445 3_455
Sm1 In Sm2 64.029(14) 7 3_455
Sm1 In Sm2 111.427(15) 7_545 3_455
Sm1 In Sm2 68.573(15) 3_455 3_455
Ge1 In Sm2 120.069(16) 5_556 7_545
Ge1 In Sm2 59.931(16) 1_554 7_545
Sm1 In Sm2 64.029(14) 3_445 7_545
Sm1 In Sm2 115.971(14) 7 7_545
Sm1 In Sm2 68.573(15) 7_545 7_545
Sm1 In Sm2 111.427(15) 3_455 7_545
Sm2 In Sm2 180.0 3_455 7_545
Ge1 In Sm2 59.931(16) 5_556 3_445
Ge1 In Sm2 120.069(16) 1_554 3_445
Sm1 In Sm2 68.573(15) 3_445 3_445
Sm1 In Sm2 111.427(15) 7 3_445
Sm1 In Sm2 64.029(14) 7_545 3_445
Sm1 In Sm2 115.971(14) 3_455 3_445
Sm2 In Sm2 77.76(2) 3_455 3_445
Sm2 In Sm2 102.24(2) 7_545 3_445
Ge1 In Sm2 120.069(16) 5_556 7
Ge1 In Sm2 59.931(16) 1_554 7
Sm1 In Sm2 111.427(15) 3_445 7
Sm1 In Sm2 68.573(15) 7 7
Sm1 In Sm2 115.971(14) 7_545 7
Sm1 In Sm2 64.029(14) 3_455 7
Sm2 In Sm2 102.24(2) 3_455 7
Sm2 In Sm2 77.76(2) 7_545 7
Sm2 In Sm2 180.0 3_445 7
Fe Ge1 Ge1 119.91(4) . 5_556
Fe Ge1 In 131.20(3) . 1_556
Ge1 Ge1 In 108.90(4) 5_556 1_556
Fe Ge1 Sm1 77.88(2) . 7_556
Ge1 Ge1 Sm1 132.795(15) 5_556 7_556
In Ge1 Sm1 68.867(19) 1_556 7_556
Fe Ge1 Sm1 77.88(2) . 7_546
Ge1 Ge1 Sm1 132.795(15) 5_556 7_546
In Ge1 Sm1 68.867(19) 1_556 7_546
Sm1 Ge1 Sm1 91.88(3) 7_556 7_546
Fe Ge1 Sm2 69.305(19) . 3_445
Ge1 Ge1 Sm2 69.67(2) 5_556 3_445
In Ge1 Sm2 133.421(14) 1_556 3_445
Sm1 Ge1 Sm2 147.09(3) 7_556 3_445
Sm1 Ge1 Sm2 79.23(2) 7_546 3_445
Fe Ge1 Sm2 69.305(19) . 3_455
Ge1 Ge1 Sm2 69.67(2) 5_556 3_455
In Ge1 Sm2 133.421(14) 1_556 3_455
Sm1 Ge1 Sm2 79.23(2) 7_556 3_455
Sm1 Ge1 Sm2 147.09(3) 7_546 3_455
Sm2 Ge1 Sm2 91.16(3) 3_445 3_455
Fe Ge1 Sm2 137.004(14) . 7_546
Ge1 Ge1 Sm2 61.53(2) 5_556 7_546
In Ge1 Sm2 67.389(15) 1_556 7_546
Sm1 Ge1 Sm2 136.09(2) 7_556 7_546
Sm1 Ge1 Sm2 76.002(18) 7_546 7_546
Sm2 Ge1 Sm2 72.672(17) 3_445 7_546
Sm2 Ge1 Sm2 131.19(2) 3_455 7_546
Fe Ge1 Sm2 137.004(14) . 7_556
Ge1 Ge1 Sm2 61.53(2) 5_556 7_556
In Ge1 Sm2 67.389(15) 1_556 7_556
Sm1 Ge1 Sm2 76.002(18) 7_556 7_556
Sm1 Ge1 Sm2 136.09(2) 7_546 7_556
Sm2 Ge1 Sm2 131.19(2) 3_445 7_556
Sm2 Ge1 Sm2 72.672(17) 3_455 7_556
Sm2 Ge1 Sm2 84.07(3) 7_546 7_556
Fe Ge2 Fe 122.38(5) 7_556 7_546
Fe Ge2 Fe 79.64(3) 7_556 .
Fe Ge2 Fe 79.64(3) 7_546 .
Fe Ge2 Sm1 77.56(3) 7_556 .
Fe Ge2 Sm1 77.56(3) 7_546 .
Fe Ge2 Sm1 131.54(3) . .
Fe Ge2 Sm2 144.07(3) 7_556 3_445
Fe Ge2 Sm2 66.24(3) 7_546 3_445
Fe Ge2 Sm2 67.316(19) . 3_445
Sm1 Ge2 Sm2 135.444(13) . 3_445
Fe Ge2 Sm2 66.24(3) 7_556 3_455
Fe Ge2 Sm2 144.07(3) 7_546 3_455
Fe Ge2 Sm2 67.316(19) . 3_455
Sm1 Ge2 Sm2 135.444(13) . 3_455
Sm2 Ge2 Sm2 87.57(2) 3_445 3_455
Fe Ge2 Sm1 145.31(3) 7_556 7_545
Fe Ge2 Sm1 68.00(2) 7_546 7_545
Fe Ge2 Sm1 134.141(16) . 7_545
Sm1 Ge2 Sm1 72.730(18) . 7_545
Sm2 Ge2 Sm1 70.216(17) 3_445 7_545
Sm2 Ge2 Sm1 127.35(3) 3_455 7_545
Fe Ge2 Sm1 68.00(2) 7_556 7
Fe Ge2 Sm1 145.31(3) 7_546 7
Fe Ge2 Sm1 134.141(16) . 7
Sm1 Ge2 Sm1 72.730(18) . 7
Sm2 Ge2 Sm1 127.35(3) 3_445 7
Sm2 Ge2 Sm1 70.216(17) 3_455 7
Sm1 Ge2 Sm1 86.15(3) 7_545 7
Fe Ge2 Sm2 61.53(2) 7_556 5_656
Fe Ge2 Sm2 61.53(2) 7_546 5_656
Fe Ge2 Sm2 59.68(3) . 5_656
Sm1 Ge2 Sm2 71.85(2) . 5_656
Sm2 Ge2 Sm2 109.40(2) 3_445 5_656
Sm2 Ge2 Sm2 109.40(2) 3_455 5_656
Sm1 Ge2 Sm2 122.803(16) 7_545 5_656
Sm1 Ge2 Sm2 122.803(16) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sm1 Ge1 2.9742(7) 7_556
Sm1 Ge1 2.9742(7) 7_546
Sm1 Ge2 3.0084(9) .
Sm1 Ge2 3.1294(7) 7_545
Sm1 Ge2 3.1294(7) 7
Sm1 Fe 3.1659(11) 1_554
Sm1 In 3.3404(6) 3
Sm1 In 3.3404(6) 3_545
Sm1 Fe 3.4409(9) 7_556
Sm1 Fe 3.4409(9) 7_546
Sm1 Sm2 3.5763(8) 5_655
Sm1 Sm1 3.6406(8) 7_545
Sm2 Ge1 2.9924(7) 3
Sm2 Ge1 2.9924(7) 3_545
Sm2 Fe 3.0692(11) 5_656
Sm2 Ge2 3.0887(7) 3
Sm2 Ge2 3.0887(7) 3_545
Sm2 Fe 3.1329(8) 3
Sm2 Fe 3.1329(8) 3_545
Sm2 Ge1 3.1920(8) 7_546
Sm2 Ge1 3.1920(8) 7_556
Sm2 In 3.4048(6) 3_545
Sm2 In 3.4048(6) 3
Sm2 Ge2 3.4470(9) 5_656
Fe Ge2 2.4392(7) 7_556
Fe Ge2 2.4392(7) 7_546
Fe Ge1 2.4640(12) .
Fe Ge2 2.4924(12) .
Fe Sm2 3.0692(11) 5_656
Fe Sm2 3.1328(8) 3_445
Fe Sm2 3.1328(8) 3_455
Fe Sm1 3.1659(11) 1_556
Fe Sm1 3.4408(9) 7_556
Fe Sm1 3.4408(9) 7_546
In Ge1 2.9333(8) 5_556
In Ge1 2.9333(8) 1_554
In Sm1 3.3405(6) 3_445
In Sm1 3.3405(6) 7
In Sm1 3.3405(6) 7_545
In Sm1 3.3405(6) 3_455
In Sm2 3.4048(6) 3_455
In Sm2 3.4048(6) 7_545
In Sm2 3.4048(6) 3_445
In Sm2 3.4048(6) 7
Ge1 Ge1 2.5615(13) 5_556
Ge1 In 2.9332(8) 1_556
Ge1 Sm1 2.9742(7) 7_556
Ge1 Sm1 2.9742(7) 7_546
Ge1 Sm2 2.9924(7) 3_445
Ge1 Sm2 2.9924(7) 3_455
Ge1 Sm2 3.1919(8) 7_546
Ge1 Sm2 3.1919(8) 7_556
Ge2 Fe 2.4391(7) 7_556
Ge2 Fe 2.4391(7) 7_546
Ge2 Sm2 3.0887(7) 3_445
Ge2 Sm2 3.0887(7) 3_455
Ge2 Sm1 3.1294(7) 7_545
Ge2 Sm1 3.1294(7) 7
Ge2 Sm2 3.4470(9) 5_656
