#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342585.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342585
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Gd4 Fe2 In Ge4'
_chemical_formula_sum            'Fe2 Gd4 Ge4 In'
_chemical_formula_weight         1145.88
_chemical_name_common            'gadolinium iron indium germanide (4/2/1/4)'
_chemical_name_systematic        'gadolinium iron indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 107.068(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.672(3)
_cell_length_b                   4.2436(8)
_cell_length_c                   7.0643(13)
_cell_measurement_reflns_used    1021
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.64
_cell_measurement_theta_min      4.99
_cell_volume                     449.12(15)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0532
_diffrn_reflns_av_unetI/netI     0.0470
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3133
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.979
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.008
_diffrn_reflns_theta_min         2.719
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    47.796
_exptl_absorpt_correction_T_max  0.4688
_exptl_absorpt_correction_T_min  0.1091
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.473
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             970
_exptl_crystal_size_max          0.074
_exptl_crystal_size_mid          0.036
_exptl_crystal_size_min          0.024
_refine_diff_density_max         3.253
_refine_diff_density_min         -2.951
_refine_diff_density_rms         0.597
_refine_ls_extinction_coef       0.00040(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         929
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0473
_refine_ls_R_factor_gt           0.0314
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0324P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0631
_refine_ls_wR_factor_ref         0.0692
_reflns_Friedel_coverage         0.000
_reflns_number_gt                738
_reflns_number_total             929
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_002.cif
_cod_data_source_block           Gd4Fe2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_original_cell_volume        449.12(14)
_cod_database_code               4342585
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.126
_shelx_estimated_absorpt_t_max   0.393
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Gd1 Gd 0.34742(4) 0.0000 0.06412(8) 0.00805(14) Uani 1 2 d S T P
Gd2 Gd 0.58795(4) 0.0000 0.38067(8) 0.00781(14) Uani 1 2 d S T P
Fe Fe 0.21885(11) 0.0000 0.6287(2) 0.0086(3) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0095(3) Uani 0.983(5) 4 d S T .
Ge1 Ge 0.06630(8) 0.0000 0.65600(17) 0.0078(2) Uani 1 2 d S T P
Ge2 Ge 0.20590(8) 0.0000 0.26973(18) 0.0086(2) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Gd1 Ge1 92.21(4) 7_556 7_546
Ge1 Gd1 Ge2 86.19(3) 7_556 .
Ge1 Gd1 Ge2 86.19(3) 7_546 .
Ge1 Gd1 Ge2 166.51(4) 7_556 7_545
Ge1 Gd1 Ge2 89.18(3) 7_546 7_545
Ge2 Gd1 Ge2 107.29(3) . 7_545
Ge1 Gd1 Ge2 89.18(3) 7_556 7
Ge1 Gd1 Ge2 166.51(4) 7_546 7
Ge2 Gd1 Ge2 107.29(3) . 7
Ge2 Gd1 Ge2 86.41(4) 7_545 7
Ge1 Gd1 Fe 133.878(19) 7_556 1_554
Ge1 Gd1 Fe 133.878(19) 7_546 1_554
Ge2 Gd1 Fe 96.98(4) . 1_554
Ge2 Gd1 Fe 45.83(2) 7_545 1_554
Ge2 Gd1 Fe 45.83(2) 7 1_554
Ge1 Gd1 In 54.89(2) 7_556 3
Ge1 Gd1 In 110.14(3) 7_546 3
Ge2 Gd1 In 137.094(14) . 3
Ge2 Gd1 In 112.16(3) 7_545 3
Ge2 Gd1 In 60.24(2) 7 3
Fe Gd1 In 98.44(3) 1_554 3
Ge1 Gd1 In 110.14(3) 7_556 3_545
Ge1 Gd1 In 54.89(2) 7_546 3_545
Ge2 Gd1 In 137.094(14) . 3_545
Ge2 Gd1 In 60.24(2) 7_545 3_545
Ge2 Gd1 In 112.16(3) 7 3_545
Fe Gd1 In 98.44(3) 1_554 3_545
In Gd1 In 79.285(18) 3 3_545
Ge1 Gd1 Fe 44.72(3) 7_556 7_556
Ge1 Gd1 Fe 100.77(4) 7_546 7_556
Ge2 Gd1 Fe 44.08(2) . 7_556
Ge2 Gd1 Fe 147.81(4) 7_545 7_556
Ge2 Gd1 Fe 89.64(3) 7 7_556
Fe Gd1 Fe 113.29(3) 1_554 7_556
In Gd1 Fe 93.16(2) 3 7_556
In Gd1 Fe 148.18(3) 3_545 7_556
Ge1 Gd1 Fe 100.77(4) 7_556 7_546
Ge1 Gd1 Fe 44.72(4) 7_546 7_546
Ge2 Gd1 Fe 44.08(2) . 7_546
Ge2 Gd1 Fe 89.64(3) 7_545 7_546
Ge2 Gd1 Fe 147.81(4) 7 7_546
Fe Gd1 Fe 113.29(3) 1_554 7_546
In Gd1 Fe 148.18(3) 3 7_546
In Gd1 Fe 93.16(2) 3_545 7_546
Fe Gd1 Fe 77.02(4) 7_556 7_546
Ge1 Gd1 Gd2 113.43(3) 7_556 5_655
Ge1 Gd1 Gd2 113.43(3) 7_546 5_655
Ge2 Gd1 Gd2 150.50(3) . 5_655
Ge2 Gd1 Gd2 54.10(2) 7_545 5_655
Ge2 Gd1 Gd2 54.10(2) 7 5_655
Fe Gd1 Gd2 53.51(3) 1_554 5_655
In Gd1 Gd2 58.636(10) 3 5_655
In Gd1 Gd2 58.636(10) 3_545 5_655
Fe Gd1 Gd2 141.078(19) 7_556 5_655
Fe Gd1 Gd2 141.078(19) 7_546 5_655
Ge1 Gd1 Gd1 141.28(3) 7_556 7_545
Ge1 Gd1 Gd1 86.15(2) 7_546 7_545
Ge2 Gd1 Gd1 55.08(2) . 7_545
Ge2 Gd1 Gd1 52.20(2) 7_545 7_545
Ge2 Gd1 Gd1 101.08(3) 7 7_545
Fe Gd1 Gd1 60.15(3) 1_554 7_545
In Gd1 Gd1 158.46(3) 3 7_545
In Gd1 Gd1 100.366(16) 3_545 7_545
Fe Gd1 Gd1 97.60(3) 7_556 7_545
Fe Gd1 Gd1 53.14(3) 7_546 7_545
Gd2 Gd1 Gd1 102.51(2) 5_655 7_545
Ge1 Gd2 Ge1 91.41(4) 3 3_545
Ge1 Gd2 Fe 108.67(3) 3 5_656
Ge1 Gd2 Fe 108.67(3) 3_545 5_656
Ge1 Gd2 Ge2 82.30(3) 3 3
Ge1 Gd2 Ge2 149.04(4) 3_545 3
Fe Gd2 Ge2 46.88(2) 5_656 3
Ge1 Gd2 Ge2 149.04(4) 3 3_545
Ge1 Gd2 Ge2 82.30(3) 3_545 3_545
Fe Gd2 Ge2 46.88(2) 5_656 3_545
Ge2 Gd2 Ge2 87.68(4) 3 3_545
Ge1 Gd2 Fe 47.59(4) 3 3
Ge1 Gd2 Fe 107.59(4) 3_545 3
Fe Gd2 Fe 61.12(4) 5_656 3
Ge2 Gd2 Fe 47.45(4) 3 3
Ge2 Gd2 Fe 105.60(4) 3_545 3
Ge1 Gd2 Fe 107.59(4) 3 3_545
Ge1 Gd2 Fe 47.59(4) 3_545 3_545
Fe Gd2 Fe 61.12(4) 5_656 3_545
Ge2 Gd2 Fe 105.60(4) 3 3_545
Ge2 Gd2 Fe 47.45(4) 3_545 3_545
Fe Gd2 Fe 86.04(5) 3 3_545
Ge1 Gd2 Ge1 107.54(2) 3 7_546
Ge1 Gd2 Ge1 48.93(4) 3_545 7_546
Fe Gd2 Ge1 137.470(18) 5_656 7_546
Ge2 Gd2 Ge1 161.06(4) 3 7_546
Ge2 Gd2 Ge1 91.06(3) 3_545 7_546
Fe Gd2 Ge1 149.77(4) 3 7_546
Fe Gd2 Ge1 87.16(3) 3_545 7_546
Ge1 Gd2 Ge1 48.93(4) 3 7_556
Ge1 Gd2 Ge1 107.54(2) 3_545 7_556
Fe Gd2 Ge1 137.470(18) 5_656 7_556
Ge2 Gd2 Ge1 91.06(3) 3 7_556
Ge2 Gd2 Ge1 161.06(4) 3_545 7_556
Fe Gd2 Ge1 87.16(3) 3 7_556
Fe Gd2 Ge1 149.77(4) 3_545 7_556
Ge1 Gd2 Ge1 84.05(3) 7_546 7_556
Ge1 Gd2 In 150.65(3) 3 3_545
Ge1 Gd2 In 88.53(2) 3_545 3_545
Fe Gd2 In 99.10(3) 5_656 3_545
Ge2 Gd2 In 111.50(3) 3 3_545
Ge2 Gd2 In 59.88(2) 3_545 3_545
Fe Gd2 In 157.34(3) 3 3_545
Fe Gd2 In 93.87(3) 3_545 3_545
Ge1 Gd2 In 52.59(2) 7_546 3_545
Ge1 Gd2 In 103.40(2) 7_556 3_545
Ge1 Gd2 In 88.53(2) 3 3
Ge1 Gd2 In 150.65(3) 3_545 3
Fe Gd2 In 99.10(3) 5_656 3
Ge2 Gd2 In 59.88(2) 3 3
Ge2 Gd2 In 111.50(3) 3_545 3
Fe Gd2 In 93.87(3) 3 3
Fe Gd2 In 157.34(3) 3_545 3
Ge1 Gd2 In 103.40(2) 7_546 3
Ge1 Gd2 In 52.59(2) 7_556 3
In Gd2 In 77.634(18) 3_545 3
Ge1 Gd2 Ge2 78.07(3) 3 5_656
Ge1 Gd2 Ge2 78.07(3) 3_545 5_656
Fe Gd2 Ge2 44.49(4) 5_656 5_656
Ge2 Gd2 Ge2 70.96(3) 3 5_656
Ge2 Gd2 Ge2 70.96(3) 3_545 5_656
Fe Gd2 Ge2 43.18(2) 3 5_656
Fe Gd2 Ge2 43.18(2) 3_545 5_656
Ge1 Gd2 Ge2 126.25(2) 7_546 5_656
Ge1 Gd2 Ge2 126.25(2) 7_556 5_656
In Gd2 Ge2 130.349(16) 3_545 5_656
In Gd2 Ge2 130.349(16) 3 5_656
Ge2 Fe Ge2 121.56(8) 7_556 7_546
Ge2 Fe Ge1 112.10(5) 7_556 .
Ge2 Fe Ge1 112.10(5) 7_546 .
Ge2 Fe Ge2 100.86(5) 7_556 .
Ge2 Fe Ge2 100.86(5) 7_546 .
Ge1 Fe Ge2 106.89(7) . .
Ge2 Fe Gd2 66.89(4) 7_556 5_656
Ge2 Fe Gd2 66.89(4) 7_546 5_656
Ge1 Fe Gd2 176.89(7) . 5_656
Ge2 Fe Gd2 76.22(5) . 5_656
Ge2 Fe Gd2 160.79(6) 7_556 3_445
Ge2 Fe Gd2 75.73(3) 7_546 3_445
Ge1 Fe Gd2 63.10(4) . 3_445
Ge2 Fe Gd2 65.29(4) . 3_445
Gd2 Fe Gd2 118.88(4) 5_656 3_445
Ge2 Fe Gd2 75.73(3) 7_556 3_455
Ge2 Fe Gd2 160.79(6) 7_546 3_455
Ge1 Fe Gd2 63.10(4) . 3_455
Ge2 Fe Gd2 65.29(4) . 3_455
Gd2 Fe Gd2 118.88(4) 5_656 3_455
Gd2 Fe Gd2 86.04(5) 3_445 3_455
Ge2 Fe Gd1 66.12(4) 7_556 1_556
Ge2 Fe Gd1 66.12(4) 7_546 1_556
Ge1 Fe Gd1 106.42(6) . 1_556
Ge2 Fe Gd1 146.69(7) . 1_556
Gd2 Fe Gd1 70.47(4) 5_656 1_556
Gd2 Fe Gd1 132.74(3) 3_445 1_556
Gd2 Fe Gd1 132.74(3) 3_455 1_556
Ge2 Fe Gd1 58.72(3) 7_556 7_556
Ge2 Fe Gd1 124.59(6) 7_546 7_556
Ge1 Fe Gd1 57.59(3) . 7_556
Ge2 Fe Gd1 134.53(4) . 7_556
Gd2 Fe Gd1 120.28(4) 5_656 7_556
Gd2 Fe Gd1 120.64(5) 3_445 7_556
Gd2 Fe Gd1 70.12(3) 3_455 7_556
Gd1 Fe Gd1 66.71(3) 1_556 7_556
Ge2 Fe Gd1 124.59(6) 7_556 7_546
Ge2 Fe Gd1 58.72(3) 7_546 7_546
Ge1 Fe Gd1 57.59(3) . 7_546
Ge2 Fe Gd1 134.53(4) . 7_546
Gd2 Fe Gd1 120.28(4) 5_656 7_546
Gd2 Fe Gd1 70.12(3) 3_445 7_546
Gd2 Fe Gd1 120.64(5) 3_455 7_546
Gd1 Fe Gd1 66.71(3) 1_556 7_546
Gd1 Fe Gd1 77.02(4) 7_556 7_546
Ge1 In Ge1 180.00(4) 5_556 1_554
Ge1 In Gd1 55.877(17) 5_556 3_445
Ge1 In Gd1 124.123(17) 1_554 3_445
Ge1 In Gd1 124.123(17) 5_556 7
Ge1 In Gd1 55.877(17) 1_554 7
Gd1 In Gd1 180.000(13) 3_445 7
Ge1 In Gd1 124.123(17) 5_556 7_545
Ge1 In Gd1 55.877(17) 1_554 7_545
Gd1 In Gd1 100.714(18) 3_445 7_545
Gd1 In Gd1 79.286(18) 7 7_545
Ge1 In Gd1 55.877(17) 5_556 3_455
Ge1 In Gd1 124.123(17) 1_554 3_455
Gd1 In Gd1 79.286(18) 3_445 3_455
Gd1 In Gd1 100.714(18) 7 3_455
Gd1 In Gd1 180.000(13) 7_545 3_455
Ge1 In Gd2 59.90(2) 5_556 3_455
Ge1 In Gd2 120.10(2) 1_554 3_455
Gd1 In Gd2 115.664(15) 3_445 3_455
Gd1 In Gd2 64.336(15) 7 3_455
Gd1 In Gd2 111.516(15) 7_545 3_455
Gd1 In Gd2 68.484(15) 3_455 3_455
Ge1 In Gd2 120.10(2) 5_556 7_545
Ge1 In Gd2 59.90(2) 1_554 7_545
Gd1 In Gd2 64.336(15) 3_445 7_545
Gd1 In Gd2 115.664(15) 7 7_545
Gd1 In Gd2 68.484(15) 7_545 7_545
Gd1 In Gd2 111.516(15) 3_455 7_545
Gd2 In Gd2 180.000(14) 3_455 7_545
Ge1 In Gd2 59.90(2) 5_556 3_445
Ge1 In Gd2 120.10(2) 1_554 3_445
Gd1 In Gd2 68.484(15) 3_445 3_445
Gd1 In Gd2 111.516(15) 7 3_445
Gd1 In Gd2 64.336(15) 7_545 3_445
Gd1 In Gd2 115.664(15) 3_455 3_445
Gd2 In Gd2 77.634(18) 3_455 3_445
Gd2 In Gd2 102.366(18) 7_545 3_445
Ge1 In Gd2 120.10(2) 5_556 7
Ge1 In Gd2 59.90(2) 1_554 7
Gd1 In Gd2 111.516(15) 3_445 7
Gd1 In Gd2 68.484(15) 7 7
Gd1 In Gd2 115.664(15) 7_545 7
Gd1 In Gd2 64.336(15) 3_455 7
Gd2 In Gd2 102.366(18) 3_455 7
Gd2 In Gd2 77.634(18) 7_545 7
Gd2 In Gd2 180.0 3_445 7
Fe Ge1 Ge1 119.88(8) . 5_556
Fe Ge1 In 131.33(6) . 1_556
Ge1 Ge1 In 108.79(6) 5_556 1_556
Fe Ge1 Gd1 77.69(4) . 7_556
Ge1 Ge1 Gd1 132.71(2) 5_556 7_556
In Ge1 Gd1 69.23(3) 1_556 7_556
Fe Ge1 Gd1 77.69(4) . 7_546
Ge1 Ge1 Gd1 132.71(2) 5_556 7_546
In Ge1 Gd1 69.23(3) 1_556 7_546
Gd1 Ge1 Gd1 92.21(4) 7_556 7_546
Fe Ge1 Gd2 69.32(3) . 3_445
Ge1 Ge1 Gd2 69.74(4) 5_556 3_445
In Ge1 Gd2 133.28(2) 1_556 3_445
Gd1 Ge1 Gd2 146.93(5) 7_556 3_445
Gd1 Ge1 Gd2 78.84(2) 7_546 3_445
Fe Ge1 Gd2 69.32(3) . 3_455
Ge1 Ge1 Gd2 69.74(4) 5_556 3_455
In Ge1 Gd2 133.28(2) 1_556 3_455
Gd1 Ge1 Gd2 78.84(2) 7_556 3_455
Gd1 Ge1 Gd2 146.93(5) 7_546 3_455
Gd2 Ge1 Gd2 91.41(4) 3_445 3_455
Fe Ge1 Gd2 136.95(2) . 7_546
Ge1 Ge1 Gd2 61.33(3) 5_556 7_546
In Ge1 Gd2 67.51(2) 1_556 7_546
Gd1 Ge1 Gd2 136.57(4) 7_556 7_546
Gd1 Ge1 Gd2 76.19(2) 7_546 7_546
Gd2 Ge1 Gd2 72.46(2) 3_445 7_546
Gd2 Ge1 Gd2 131.07(4) 3_455 7_546
Fe Ge1 Gd2 136.95(2) . 7_556
Ge1 Ge1 Gd2 61.33(3) 5_556 7_556
In Ge1 Gd2 67.51(2) 1_556 7_556
Gd1 Ge1 Gd2 76.19(2) 7_556 7_556
Gd1 Ge1 Gd2 136.57(4) 7_546 7_556
Gd2 Ge1 Gd2 131.07(4) 3_445 7_556
Gd2 Ge1 Gd2 72.46(2) 3_455 7_556
Gd2 Ge1 Gd2 84.05(3) 7_546 7_556
Fe Ge2 Fe 121.56(8) 7_556 7_546
Fe Ge2 Fe 79.14(5) 7_556 .
Fe Ge2 Fe 79.14(5) 7_546 .
Fe Ge2 Gd1 77.19(4) 7_556 .
Fe Ge2 Gd1 77.19(4) 7_546 .
Fe Ge2 Gd1 130.29(6) . .
Fe Ge2 Gd2 143.70(6) 7_556 3_445
Fe Ge2 Gd2 66.23(4) 7_546 3_445
Fe Ge2 Gd2 67.26(4) . 3_445
Gd1 Ge2 Gd2 135.599(18) . 3_445
Fe Ge2 Gd2 66.23(4) 7_556 3_455
Fe Ge2 Gd2 143.70(6) 7_546 3_455
Fe Ge2 Gd2 67.26(3) . 3_455
Gd1 Ge2 Gd2 135.599(18) . 3_455
Gd2 Ge2 Gd2 87.68(4) 3_445 3_455
Fe Ge2 Gd1 145.20(6) 7_556 7_545
Fe Ge2 Gd1 68.04(4) 7_546 7_545
Fe Ge2 Gd1 134.42(2) . 7_545
Gd1 Ge2 Gd1 72.71(3) . 7_545
Gd2 Ge2 Gd1 70.87(2) 3_445 7_545
Gd2 Ge2 Gd1 128.37(4) 3_455 7_545
Fe Ge2 Gd1 68.04(4) 7_556 7
Fe Ge2 Gd1 145.20(6) 7_546 7
Fe Ge2 Gd1 134.42(2) . 7
Gd1 Ge2 Gd1 72.71(3) . 7
Gd2 Ge2 Gd1 128.37(4) 3_445 7
Gd2 Ge2 Gd1 70.87(2) 3_455 7
Gd1 Ge2 Gd1 86.41(4) 7_545 7
Fe Ge2 Gd2 61.09(4) 7_556 5_656
Fe Ge2 Gd2 61.09(4) 7_546 5_656
Fe Ge2 Gd2 59.29(5) . 5_656
Gd1 Ge2 Gd2 71.00(3) . 5_656
Gd2 Ge2 Gd2 109.04(3) 3_445 5_656
Gd2 Ge2 Gd2 109.04(3) 3_455 5_656
Gd1 Ge2 Gd2 122.18(3) 7_545 5_656
Gd1 Ge2 Gd2 122.18(3) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 Ge1 2.9445(9) 7_556
Gd1 Ge1 2.9445(9) 7_546
Gd1 Ge2 2.9867(13) .
Gd1 Ge2 3.0993(10) 7_545
Gd1 Ge2 3.0993(10) 7
Gd1 Fe 3.1435(18) 1_554
Gd1 In 3.3257(6) 3
Gd1 In 3.3257(6) 3_545
Gd1 Fe 3.4076(13) 7_556
Gd1 Fe 3.4076(13) 7_546
Gd1 Gd2 3.5731(9) 5_655
Gd1 Gd1 3.6089(10) 7_545
Gd2 Ge1 2.9644(9) 3
Gd2 Ge1 2.9644(9) 3_545
Gd2 Fe 3.0479(18) 5_656
Gd2 Ge2 3.0633(10) 3
Gd2 Ge2 3.0633(10) 3_545
Gd2 Fe 3.1099(13) 3
Gd2 Fe 3.1099(13) 3_545
Gd2 Ge1 3.1694(10) 7_546
Gd2 Ge1 3.1694(10) 7_556
Gd2 In 3.3849(6) 3_545
Gd2 In 3.3849(6) 3
Gd2 Ge2 3.4429(14) 5_656
Fe Ge2 2.4312(11) 7_556
Fe Ge2 2.4312(11) 7_546
Fe Ge1 2.454(2) .
Fe Ge2 2.484(2) .
Fe Gd2 3.0480(18) 5_656
Fe Gd2 3.1099(13) 3_445
Fe Gd2 3.1099(13) 3_455
Fe Gd1 3.1436(18) 1_556
Fe Gd1 3.4076(13) 7_556
Fe Gd1 3.4076(13) 7_546
In Ge1 2.9099(12) 5_556
In Ge1 2.9099(12) 1_554
In Gd1 3.3257(6) 3_445
In Gd1 3.3257(6) 7
In Gd1 3.3257(6) 7_545
In Gd1 3.3257(6) 3_455
In Gd2 3.3849(6) 3_455
In Gd2 3.3849(6) 7_545
In Gd2 3.3849(6) 3_445
In Gd2 3.3849(6) 7
Ge1 Ge1 2.547(2) 5_556
Ge1 In 2.9099(12) 1_556
Ge1 Gd1 2.9445(9) 7_556
Ge1 Gd1 2.9445(9) 7_546
Ge1 Gd2 2.9643(9) 3_445
Ge1 Gd2 2.9643(9) 3_455
Ge1 Gd2 3.1694(10) 7_546
Ge1 Gd2 3.1694(10) 7_556
Ge2 Fe 2.4312(11) 7_556
Ge2 Fe 2.4312(11) 7_546
Ge2 Gd2 3.0633(10) 3_445
Ge2 Gd2 3.0633(10) 3_455
Ge2 Gd1 3.0993(10) 7_545
Ge2 Gd1 3.0993(10) 7
Ge2 Gd2 3.4429(14) 5_656
