#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342588.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342588
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Nd4 Co2 In Ge4'
_chemical_formula_sum            'Co2 Ge4 In Nd4'
_chemical_formula_weight         1100.00
_chemical_name_common            'neodymium cobalt indium germanide (4/2/1/4)'
_chemical_name_systematic        'neodymium cobalt indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 107.5115(8)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.7845(9)
_cell_length_b                   4.3028(3)
_cell_length_c                   7.1824(4)
_cell_measurement_reflns_used    2183
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.39
_cell_measurement_theta_min      4.93
_cell_volume                     465.20(5)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0299
_diffrn_reflns_av_unetI/netI     0.0260
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3306
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.075
_diffrn_reflns_theta_min         2.706
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    40.399
_exptl_absorpt_correction_T_max  0.4400
_exptl_absorpt_correction_T_min  0.1684
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.853
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             942
_exptl_crystal_size_max          0.076
_exptl_crystal_size_mid          0.039
_exptl_crystal_size_min          0.028
_refine_diff_density_max         1.418
_refine_diff_density_min         -1.467
_refine_diff_density_rms         0.312
_refine_ls_extinction_coef       0.00044(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         968
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0244
_refine_ls_R_factor_gt           0.0185
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0140P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0354
_refine_ls_wR_factor_ref         0.0366
_reflns_Friedel_coverage         0.000
_reflns_number_gt                851
_reflns_number_total             968
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_003.cif
_cod_data_source_block           Nd4Co2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342588
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.149
_shelx_estimated_absorpt_t_max   0.398
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Nd1 Nd 0.34651(2) 0.0000 0.05893(4) 0.00722(7) Uani 1 2 d S T P
Nd2 Nd 0.58883(2) 0.0000 0.38109(4) 0.00647(7) Uani 1 2 d S T P
Co Co 0.21867(5) 0.0000 0.62575(10) 0.00773(14) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00910(16) Uani 0.965(2) 4 d S T .
Ge1 Ge 0.06685(4) 0.0000 0.65580(8) 0.00696(11) Uani 1 2 d S T P
Ge2 Ge 0.20966(4) 0.0000 0.27642(8) 0.00715(11) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Nd1 Ge1 91.568(16) 7_556 7_546
Ge1 Nd1 Ge2 84.082(15) 7_556 .
Ge1 Nd1 Ge2 84.082(15) 7_546 .
Ge1 Nd1 Ge2 167.584(18) 7_556 7_545
Ge1 Nd1 Ge2 89.887(11) 7_546 7_545
Ge2 Nd1 Ge2 108.333(13) . 7_545
Ge1 Nd1 Ge2 89.887(11) 7_556 7
Ge1 Nd1 Ge2 167.584(18) 7_546 7
Ge2 Nd1 Ge2 108.333(13) . 7
Ge2 Nd1 Ge2 86.108(16) 7_545 7
Ge1 Nd1 Co 134.207(8) 7_556 1_554
Ge1 Nd1 Co 134.207(8) 7_546 1_554
Ge2 Nd1 Co 99.500(19) . 1_554
Ge2 Nd1 Co 45.379(9) 7_545 1_554
Ge2 Nd1 Co 45.379(9) 7 1_554
Ge1 Nd1 In 55.217(11) 7_556 3
Ge1 Nd1 In 110.312(13) 7_546 3
Ge2 Nd1 In 136.009(7) . 3
Ge2 Nd1 In 112.858(13) 7_545 3
Ge2 Nd1 In 60.948(10) 7 3
Co Nd1 In 98.455(12) 1_554 3
Ge1 Nd1 In 110.312(13) 7_556 3_545
Ge1 Nd1 In 55.217(11) 7_546 3_545
Ge2 Nd1 In 136.009(6) . 3_545
Ge2 Nd1 In 60.948(10) 7_545 3_545
Ge2 Nd1 In 112.858(13) 7 3_545
Co Nd1 In 98.455(12) 1_554 3_545
In Nd1 In 79.605(8) 3 3_545
Ge1 Nd1 Co 43.870(16) 7_556 7_556
Ge1 Nd1 Co 99.285(15) 7_546 7_556
Ge2 Nd1 Co 43.092(11) . 7_556
Ge2 Nd1 Co 147.718(18) 7_545 7_556
Ge2 Nd1 Co 90.290(13) 7 7_556
Co Nd1 Co 114.390(14) 1_554 7_556
In Nd1 Co 92.951(10) 3 7_556
In Nd1 Co 147.086(14) 3_545 7_556
Ge1 Nd1 Co 99.285(15) 7_556 7_546
Ge1 Nd1 Co 43.870(16) 7_546 7_546
Ge2 Nd1 Co 43.092(11) . 7_546
Ge2 Nd1 Co 90.290(13) 7_545 7_546
Ge2 Nd1 Co 147.718(18) 7 7_546
Co Nd1 Co 114.390(14) 1_554 7_546
In Nd1 Co 147.086(14) 3 7_546
In Nd1 Co 92.952(10) 3_545 7_546
Co Nd1 Co 75.974(16) 7_556 7_546
Ge1 Nd1 Nd2 114.064(13) 7_556 5_655
Ge1 Nd1 Nd2 114.064(13) 7_546 5_655
Ge2 Nd1 Nd2 152.719(15) . 5_655
Ge2 Nd1 Nd2 54.419(10) 7_545 5_655
Ge2 Nd1 Nd2 54.419(10) 7 5_655
Co Nd1 Nd2 53.220(15) 1_554 5_655
In Nd1 Nd2 58.941(6) 3 5_655
In Nd1 Nd2 58.941(5) 3_545 5_655
Co Nd1 Nd2 141.714(8) 7_556 5_655
Co Nd1 Nd2 141.714(8) 7_546 5_655
Ge1 Nd1 Nd1 139.903(18) 7_556 7_545
Ge1 Nd1 Nd1 84.956(11) 7_546 7_545
Ge2 Nd1 Nd1 55.821(11) . 7_545
Ge2 Nd1 Nd1 52.512(11) 7_545 7_545
Ge2 Nd1 Nd1 101.758(14) 7 7_545
Co Nd1 Nd1 61.692(12) 1_554 7_545
In Nd1 Nd1 160.040(13) 3 7_545
In Nd1 Nd1 100.264(6) 3_545 7_545
Co Nd1 Nd1 97.261(15) 7_556 7_545
Co Nd1 Nd1 52.698(13) 7_546 7_545
Nd2 Nd1 Nd1 103.641(11) 5_655 7_545
Ge1 Nd2 Ge1 91.286(17) 3 3_545
Ge1 Nd2 Co 108.791(15) 3 5_656
Ge1 Nd2 Co 108.791(15) 3_545 5_656
Ge1 Nd2 Ge2 82.191(13) 3 3
Ge1 Nd2 Ge2 148.454(17) 3_545 3
Co Nd2 Ge2 46.474(10) 5_656 3
Ge1 Nd2 Ge2 148.454(17) 3 3_545
Ge1 Nd2 Ge2 82.191(12) 3_545 3_545
Co Nd2 Ge2 46.474(10) 5_656 3_545
Ge2 Nd2 Ge2 87.414(16) 3 3_545
Ge1 Nd2 Co 47.466(17) 3 3
Ge1 Nd2 Co 108.014(17) 3_545 3
Co Nd2 Co 61.395(18) 5_656 3
Ge2 Nd2 Co 46.666(17) 3 3
Ge2 Nd2 Co 105.422(17) 3_545 3
Ge1 Nd2 Co 108.014(17) 3 3_545
Ge1 Nd2 Co 47.466(16) 3_545 3_545
Co Nd2 Co 61.395(18) 5_656 3_545
Ge2 Nd2 Co 105.422(17) 3 3_545
Ge2 Nd2 Co 46.666(17) 3_545 3_545
Co Nd2 Co 87.103(19) 3 3_545
Ge1 Nd2 Ge1 107.236(11) 3 7_546
Ge1 Nd2 Ge1 48.686(18) 3_545 7_546
Co Nd2 Ge1 137.555(8) 5_656 7_546
Ge2 Nd2 Ge1 161.919(17) 3 7_546
Ge2 Nd2 Ge1 91.506(12) 3_545 7_546
Co Nd2 Ge1 149.661(18) 3 7_546
Co Nd2 Ge1 86.637(14) 3_545 7_546
Ge1 Nd2 Ge1 48.686(18) 3 7_556
Ge1 Nd2 Ge1 107.236(11) 3_545 7_556
Co Nd2 Ge1 137.555(8) 5_656 7_556
Ge2 Nd2 Ge1 91.506(12) 3 7_556
Ge2 Nd2 Ge1 161.919(17) 3_545 7_556
Co Nd2 Ge1 86.637(14) 3 7_556
Co Nd2 Ge1 149.661(18) 3_545 7_556
Ge1 Nd2 Ge1 83.960(16) 7_546 7_556
Ge1 Nd2 Ge2 77.993(13) 3 5_656
Ge1 Nd2 Ge2 77.994(13) 3_545 5_656
Co Nd2 Ge2 44.746(17) 5_656 5_656
Ge2 Nd2 Ge2 70.461(14) 3 5_656
Ge2 Nd2 Ge2 70.461(14) 3_545 5_656
Co Nd2 Ge2 43.692(10) 3 5_656
Co Nd2 Ge2 43.692(10) 3_545 5_656
Ge1 Nd2 Ge2 125.970(11) 7_546 5_656
Ge1 Nd2 Ge2 125.970(11) 7_556 5_656
Ge1 Nd2 In 150.600(14) 3 3_545
Ge1 Nd2 In 88.552(9) 3_545 3_545
Co Nd2 In 99.027(12) 5_656 3_545
Ge2 Nd2 In 111.936(12) 3 3_545
Ge2 Nd2 In 60.475(10) 3_545 3_545
Co Nd2 In 157.263(16) 3 3_545
Co Nd2 In 93.347(11) 3_545 3_545
Ge1 Nd2 In 52.865(10) 7_546 3_545
Ge1 Nd2 In 103.589(11) 7_556 3_545
Ge2 Nd2 In 130.440(8) 5_656 3_545
Ge1 Nd2 In 88.552(10) 3 3
Ge1 Nd2 In 150.600(14) 3_545 3
Co Nd2 In 99.027(12) 5_656 3
Ge2 Nd2 In 60.475(10) 3 3
Ge2 Nd2 In 111.936(12) 3_545 3
Co Nd2 In 93.347(11) 3 3
Co Nd2 In 157.263(16) 3_545 3
Ge1 Nd2 In 103.589(11) 7_546 3
Ge1 Nd2 In 52.865(10) 7_556 3
Ge2 Nd2 In 130.440(8) 5_656 3
In Nd2 In 77.646(7) 3_545 3
Ge2 Co Ge2 124.25(4) 7_556 7_546
Ge2 Co Ge1 110.71(2) 7_556 .
Ge2 Co Ge1 110.71(2) 7_546 .
Ge2 Co Ge2 99.96(2) 7_556 .
Ge2 Co Ge2 99.96(2) 7_546 .
Ge1 Co Ge2 109.15(3) . .
Ge2 Co Nd2 68.06(2) 7_556 5_656
Ge2 Co Nd2 68.06(2) 7_546 5_656
Ge1 Co Nd2 176.10(3) . 5_656
Ge2 Co Nd2 74.76(2) . 5_656
Ge2 Co Nd2 160.20(3) 7_556 3_445
Ge2 Co Nd2 73.905(14) 7_546 3_445
Ge1 Co Nd2 63.857(17) . 3_445
Ge2 Co Nd2 66.479(17) . 3_445
Nd2 Co Nd2 118.604(18) 5_656 3_445
Ge2 Co Nd2 73.905(14) 7_556 3_455
Ge2 Co Nd2 160.20(3) 7_546 3_455
Ge1 Co Nd2 63.857(17) . 3_455
Ge2 Co Nd2 66.479(17) . 3_455
Nd2 Co Nd2 118.604(18) 5_656 3_455
Nd2 Co Nd2 87.105(19) 3_445 3_455
Ge2 Co Nd1 67.163(19) 7_556 1_556
Ge2 Co Nd1 67.163(19) 7_546 1_556
Ge1 Co Nd1 105.25(3) . 1_556
Ge2 Co Nd1 145.61(3) . 1_556
Nd2 Co Nd1 70.850(17) 5_656 1_556
Nd2 Co Nd1 132.148(13) 3_445 1_556
Nd2 Co Nd1 132.148(13) 3_455 1_556
Ge2 Co Nd1 58.043(17) 7_556 7_556
Ge2 Co Nd1 123.98(3) 7_546 7_556
Ge1 Co Nd1 57.380(15) . 7_556
Ge2 Co Nd1 136.051(16) . 7_556
Nd2 Co Nd1 119.913(17) 5_656 7_556
Nd2 Co Nd1 121.16(2) 3_445 7_556
Nd2 Co Nd1 70.685(12) 3_455 7_556
Nd1 Co Nd1 65.609(14) 1_556 7_556
Ge2 Co Nd1 123.98(3) 7_556 7_546
Ge2 Co Nd1 58.043(17) 7_546 7_546
Ge1 Co Nd1 57.380(15) . 7_546
Ge2 Co Nd1 136.051(16) . 7_546
Nd2 Co Nd1 119.913(17) 5_656 7_546
Nd2 Co Nd1 70.685(12) 3_445 7_546
Nd2 Co Nd1 121.16(2) 3_455 7_546
Nd1 Co Nd1 65.609(14) 1_556 7_546
Nd1 Co Nd1 75.975(16) 7_556 7_546
Ge1 In Ge1 180.000(18) 5_556 1_554
Ge1 In Nd1 56.232(8) 5_556 3_445
Ge1 In Nd1 123.768(8) 1_554 3_445
Ge1 In Nd1 123.768(8) 5_556 7
Ge1 In Nd1 56.232(8) 1_554 7
Nd1 In Nd1 180.0 3_445 7
Ge1 In Nd1 123.768(8) 5_556 7_545
Ge1 In Nd1 56.232(8) 1_554 7_545
Nd1 In Nd1 100.395(8) 3_445 7_545
Nd1 In Nd1 79.605(8) 7 7_545
Ge1 In Nd1 56.232(8) 5_556 3_455
Ge1 In Nd1 123.768(8) 1_554 3_455
Nd1 In Nd1 79.605(8) 3_445 3_455
Nd1 In Nd1 100.395(8) 7 3_455
Nd1 In Nd1 180.0 7_545 3_455
Ge1 In Nd2 59.841(9) 5_556 3_455
Ge1 In Nd2 120.159(9) 1_554 3_455
Nd1 In Nd2 115.968(7) 3_445 3_455
Nd1 In Nd2 64.032(7) 7 3_455
Nd1 In Nd2 111.393(7) 7_545 3_455
Nd1 In Nd2 68.607(7) 3_455 3_455
Ge1 In Nd2 120.159(9) 5_556 7_545
Ge1 In Nd2 59.841(9) 1_554 7_545
Nd1 In Nd2 64.032(7) 3_445 7_545
Nd1 In Nd2 115.968(7) 7 7_545
Nd1 In Nd2 68.607(7) 7_545 7_545
Nd1 In Nd2 111.393(7) 3_455 7_545
Nd2 In Nd2 180.0 3_455 7_545
Ge1 In Nd2 59.841(9) 5_556 3_445
Ge1 In Nd2 120.159(9) 1_554 3_445
Nd1 In Nd2 68.607(7) 3_445 3_445
Nd1 In Nd2 111.393(7) 7 3_445
Nd1 In Nd2 64.032(7) 7_545 3_445
Nd1 In Nd2 115.968(7) 3_455 3_445
Nd2 In Nd2 77.646(7) 3_455 3_445
Nd2 In Nd2 102.354(7) 7_545 3_445
Ge1 In Nd2 120.159(9) 5_556 7
Ge1 In Nd2 59.841(9) 1_554 7
Nd1 In Nd2 111.393(7) 3_445 7
Nd1 In Nd2 68.607(7) 7 7
Nd1 In Nd2 115.968(7) 7_545 7
Nd1 In Nd2 64.032(7) 3_455 7
Nd2 In Nd2 102.354(7) 3_455 7
Nd2 In Nd2 77.646(7) 7_545 7
Nd2 In Nd2 180.0 3_445 7
Co Ge1 Ge1 119.17(4) . 5_556
Co Ge1 In 132.13(3) . 1_556
Ge1 Ge1 In 108.70(3) 5_556 1_556
Co Ge1 Nd1 78.750(18) . 7_556
Ge1 Ge1 Nd1 132.820(11) 5_556 7_556
In Ge1 Nd1 68.551(12) 1_556 7_556
Co Ge1 Nd1 78.750(18) . 7_546
Ge1 Ge1 Nd1 132.820(11) 5_556 7_546
In Ge1 Nd1 68.551(12) 1_556 7_546
Nd1 Ge1 Nd1 91.568(17) 7_556 7_546
Co Ge1 Nd2 68.677(16) . 3_445
Ge1 Ge1 Nd2 69.871(17) 5_556 3_445
In Ge1 Nd2 133.375(10) 1_556 3_445
Nd1 Ge1 Nd2 147.28(2) 7_556 3_445
Nd1 Ge1 Nd2 79.420(9) 7_546 3_445
Co Ge1 Nd2 68.677(16) . 3_455
Ge1 Ge1 Nd2 69.871(17) 5_556 3_455
In Ge1 Nd2 133.375(10) 1_556 3_455
Nd1 Ge1 Nd2 79.420(9) 7_556 3_455
Nd1 Ge1 Nd2 147.28(2) 7_546 3_455
Nd2 Ge1 Nd2 91.286(17) 3_445 3_455
Co Ge1 Nd2 136.894(10) . 7_546
Ge1 Ge1 Nd2 61.443(16) 5_556 7_546
In Ge1 Nd2 67.294(11) 1_556 7_546
Nd1 Ge1 Nd2 135.68(2) 7_556 7_546
Nd1 Ge1 Nd2 75.919(10) 7_546 7_546
Nd2 Ge1 Nd2 72.765(11) 3_445 7_546
Nd2 Ge1 Nd2 131.314(18) 3_455 7_546
Co Ge1 Nd2 136.894(10) . 7_556
Ge1 Ge1 Nd2 61.443(16) 5_556 7_556
In Ge1 Nd2 67.294(11) 1_556 7_556
Nd1 Ge1 Nd2 75.919(10) 7_556 7_556
Nd1 Ge1 Nd2 135.68(2) 7_546 7_556
Nd2 Ge1 Nd2 131.314(18) 3_445 7_556
Nd2 Ge1 Nd2 72.765(11) 3_455 7_556
Nd2 Ge1 Nd2 83.960(15) 7_546 7_556
Co Ge2 Co 124.25(4) 7_556 7_546
Co Ge2 Co 80.04(2) 7_556 .
Co Ge2 Co 80.04(2) 7_546 .
Co Ge2 Nd1 78.86(2) 7_556 .
Co Ge2 Nd1 78.86(2) 7_546 .
Co Ge2 Nd1 133.89(3) . .
Co Ge2 Nd2 143.74(3) 7_556 3_445
Co Ge2 Nd2 65.466(18) 7_546 3_445
Co Ge2 Nd2 66.855(16) . 3_445
Nd1 Ge2 Nd2 135.211(9) . 3_445
Co Ge2 Nd2 65.466(18) 7_556 3_455
Co Ge2 Nd2 143.74(3) 7_546 3_455
Co Ge2 Nd2 66.855(16) . 3_455
Nd1 Ge2 Nd2 135.211(9) . 3_455
Nd2 Ge2 Nd2 87.415(16) 3_445 3_455
Co Ge2 Nd1 145.44(3) 7_556 7_545
Co Ge2 Nd1 67.457(17) 7_546 7_545
Co Ge2 Nd1 133.898(12) . 7_545
Nd1 Ge2 Nd1 71.666(13) . 7_545
Nd2 Ge2 Nd1 70.180(10) 3_445 7_545
Nd2 Ge2 Nd1 127.184(19) 3_455 7_545
Co Ge2 Nd1 67.457(17) 7_556 7
Co Ge2 Nd1 145.44(3) 7_546 7
Co Ge2 Nd1 133.898(12) . 7
Nd1 Ge2 Nd1 71.666(13) . 7
Nd2 Ge2 Nd1 127.184(19) 3_445 7
Nd2 Ge2 Nd1 70.180(10) 3_455 7
Nd1 Ge2 Nd1 86.108(16) 7_545 7
Co Ge2 Nd2 62.403(18) 7_556 5_656
Co Ge2 Nd2 62.403(18) 7_546 5_656
Co Ge2 Nd2 60.50(2) . 5_656
Nd1 Ge2 Nd2 73.395(15) . 5_656
Nd2 Ge2 Nd2 109.539(14) 3_445 5_656
Nd2 Ge2 Nd2 109.539(14) 3_455 5_656
Nd1 Ge2 Nd2 122.829(13) 7_545 5_656
Nd1 Ge2 Nd2 122.829(13) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Nd1 Ge1 3.0017(4) 7_556
Nd1 Ge1 3.0017(4) 7_546
Nd1 Ge2 3.0226(6) .
Nd1 Ge2 3.1514(5) 7_545
Nd1 Ge2 3.1514(5) 7
Nd1 Co 3.1581(8) 1_554
Nd1 In 3.3608(3) 3
Nd1 In 3.3608(3) 3_545
Nd1 Co 3.4955(6) 7_556
Nd1 Co 3.4955(6) 7_546
Nd1 Nd2 3.6016(4) 5_655
Nd1 Nd1 3.6159(5) 7_545
Nd2 Ge1 3.0090(4) 3
Nd2 Ge1 3.0090(4) 3_545
Nd2 Co 3.0536(8) 5_656
Nd2 Ge2 3.1136(5) 3
Nd2 Ge2 3.1136(5) 3_545
Nd2 Co 3.1225(6) 3
Nd2 Co 3.1225(6) 3_545
Nd2 Ge1 3.2165(5) 7_546
Nd2 Ge1 3.2165(5) 7_556
Nd2 Ge2 3.3852(6) 5_656
Nd2 In 3.4317(3) 3_545
Nd2 In 3.4317(2) 3
Co Ge2 2.4338(4) 7_556
Co Ge2 2.4338(4) 7_546
Co Ge1 2.4699(9) .
Co Ge2 2.4699(9) .
Co Nd2 3.0537(8) 5_656
Co Nd2 3.1224(6) 3_445
Co Nd2 3.1224(6) 3_455
Co Nd1 3.1582(8) 1_556
Co Nd1 3.4954(6) 7_556
Co Nd1 3.4954(6) 7_546
In Ge1 2.9657(6) 5_556
In Ge1 2.9657(6) 1_554
In Nd1 3.3608(3) 3_445
In Nd1 3.3608(3) 7
In Nd1 3.3608(3) 7_545
In Nd1 3.3608(3) 3_455
In Nd2 3.4317(3) 3_455
In Nd2 3.4317(3) 7_545
In Nd2 3.4317(3) 3_445
In Nd2 3.4317(3) 7
Ge1 Ge1 2.5731(10) 5_556
Ge1 In 2.9657(6) 1_556
Ge1 Nd1 3.0017(4) 7_556
Ge1 Nd1 3.0017(4) 7_546
Ge1 Nd2 3.0090(4) 3_445
Ge1 Nd2 3.0090(4) 3_455
Ge1 Nd2 3.2165(5) 7_546
Ge1 Nd2 3.2165(5) 7_556
Ge2 Co 2.4338(4) 7_556
Ge2 Co 2.4338(4) 7_546
Ge2 Nd2 3.1136(5) 3_445
Ge2 Nd2 3.1136(5) 3_455
Ge2 Nd1 3.1514(5) 7_545
Ge2 Nd1 3.1514(5) 7
Ge2 Nd2 3.3852(6) 5_656
