#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342589.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342589
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Sm4 Co2 In Ge4'
_chemical_formula_sum            'Co2 Ge4 In Sm4'
_chemical_formula_weight         1124.44
_chemical_name_common            'samarium cobalt indium germanide (4/2/1/4)'
_chemical_name_systematic        'samarium cobalt indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 107.6415(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.6336(12)
_cell_length_b                   4.2723(3)
_cell_length_c                   7.1131(6)
_cell_measurement_reflns_used    4401
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.08
_cell_measurement_theta_min      2.73
_cell_volume                     452.75(6)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0208
_diffrn_reflns_av_unetI/netI     0.0192
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3307
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.252
_diffrn_reflns_theta_min         2.734
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    44.515
_exptl_absorpt_correction_T_max  0.4767
_exptl_absorpt_correction_T_min  0.0502
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.248
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             958
_exptl_crystal_size_max          0.127
_exptl_crystal_size_mid          0.036
_exptl_crystal_size_min          0.029
_refine_diff_density_max         1.755
_refine_diff_density_min         -1.359
_refine_diff_density_rms         0.270
_refine_ls_extinction_coef       0.00075(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         959
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.104
_refine_ls_R_factor_all          0.0182
_refine_ls_R_factor_gt           0.0158
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0125P)²+2.0446P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0328
_refine_ls_wR_factor_ref         0.0334
_reflns_Friedel_coverage         0.000
_reflns_number_gt                897
_reflns_number_total             959
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_003.cif
_cod_data_source_block           Sm4Co2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342589
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.070
_shelx_estimated_absorpt_t_max   0.358
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Sm1 Sm 0.34636(2) 0.0000 0.05959(3) 0.00607(6) Uani 1 2 d S T P
Sm2 Sm 0.58881(2) 0.0000 0.38273(3) 0.00549(6) Uani 1 2 d S T P
Co Co 0.21945(4) 0.0000 0.62585(9) 0.00655(12) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.00742(14) Uani 0.973(2) 4 d S T .
Ge1 Ge 0.06703(3) 0.0000 0.65687(7) 0.00595(10) Uani 1 2 d S T P
Ge2 Ge 0.20766(3) 0.0000 0.27226(7) 0.00609(10) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Sm1 Ge1 92.066(15) 7_556 7_546
Ge1 Sm1 Ge2 84.712(13) 7_556 .
Ge1 Sm1 Ge2 84.712(13) 7_546 .
Ge1 Sm1 Ge2 167.102(15) 7_556 7_545
Ge1 Sm1 Ge2 89.105(11) 7_546 7_545
Ge2 Sm1 Ge2 108.185(12) . 7_545
Ge1 Sm1 Ge2 89.105(11) 7_556 7
Ge1 Sm1 Ge2 167.102(15) 7_546 7
Ge2 Sm1 Ge2 108.185(12) . 7
Ge2 Sm1 Ge2 86.947(15) 7_545 7
Ge1 Sm1 Co 133.948(8) 7_556 1_554
Ge1 Sm1 Co 133.948(8) 7_546 1_554
Ge2 Sm1 Co 99.117(17) . 1_554
Ge2 Sm1 Co 45.866(9) 7_545 1_554
Ge2 Sm1 Co 45.866(8) 7 1_554
Ge1 Sm1 In 55.091(10) 7_556 3
Ge1 Sm1 In 110.455(12) 7_546 3
Ge2 Sm1 In 136.319(6) . 3
Ge2 Sm1 In 112.606(11) 7_545 3
Ge2 Sm1 In 60.216(9) 7 3
Co Sm1 In 98.100(11) 1_554 3
Ge1 Sm1 In 110.455(12) 7_556 3_545
Ge1 Sm1 In 55.091(10) 7_546 3_545
Ge2 Sm1 In 136.319(6) . 3_545
Ge2 Sm1 In 60.216(9) 7_545 3_545
Ge2 Sm1 In 112.606(11) 7 3_545
Co Sm1 In 98.100(11) 1_554 3_545
In Sm1 In 79.633(8) 3 3_545
Ge1 Sm1 Co 44.075(14) 7_556 7_556
Ge1 Sm1 Co 99.693(14) 7_546 7_556
Ge2 Sm1 Co 43.332(9) . 7_556
Ge2 Sm1 Co 148.093(15) 7_545 7_556
Ge2 Sm1 Co 90.068(12) 7 7_556
Co Sm1 Co 114.438(13) 1_554 7_556
In Sm1 Co 93.058(9) 3 7_556
In Sm1 Co 147.386(12) 3_545 7_556
Ge1 Sm1 Co 99.693(14) 7_556 7_546
Ge1 Sm1 Co 44.075(14) 7_546 7_546
Ge2 Sm1 Co 43.332(9) . 7_546
Ge2 Sm1 Co 90.068(12) 7_545 7_546
Ge2 Sm1 Co 148.093(15) 7 7_546
Co Sm1 Co 114.438(13) 1_554 7_546
In Sm1 Co 147.386(12) 3 7_546
In Sm1 Co 93.058(9) 3_545 7_546
Co Sm1 Co 76.058(14) 7_556 7_546
Ge1 Sm1 Sm1 140.209(14) 7_556 7_545
Ge1 Sm1 Sm1 84.796(10) 7_546 7_545
Ge2 Sm1 Sm1 55.497(10) . 7_545
Ge2 Sm1 Sm1 52.688(10) 7_545 7_545
Ge2 Sm1 Sm1 102.419(12) 7 7_545
Co Sm1 Sm1 61.878(11) 1_554 7_545
In Sm1 Sm1 159.861(11) 3 7_545
In Sm1 Sm1 100.053(7) 3_545 7_545
Co Sm1 Sm1 97.320(13) 7_556 7_545
Co Sm1 Sm1 52.561(11) 7_546 7_545
Ge1 Sm1 Sm1 84.796(10) 7_556 7
Ge1 Sm1 Sm1 140.209(14) 7_546 7
Ge2 Sm1 Sm1 55.497(10) . 7
Ge2 Sm1 Sm1 102.419(12) 7_545 7
Ge2 Sm1 Sm1 52.688(10) 7 7
Co Sm1 Sm1 61.878(11) 1_554 7
In Sm1 Sm1 100.053(6) 3 7
In Sm1 Sm1 159.861(11) 3_545 7
Co Sm1 Sm1 52.561(11) 7_556 7
Co Sm1 Sm1 97.320(13) 7_546 7
Sm1 Sm1 Sm1 73.283(11) 7_545 7
Ge1 Sm2 Ge1 91.563(15) 3 3_545
Ge1 Sm2 Co 108.933(13) 3 5_656
Ge1 Sm2 Co 108.934(13) 3_545 5_656
Ge1 Sm2 Ge2 82.382(11) 3 3
Ge1 Sm2 Ge2 149.306(15) 3_545 3
Co Sm2 Ge2 46.843(9) 5_656 3
Ge1 Sm2 Ge2 149.306(15) 3 3_545
Ge1 Sm2 Ge2 82.382(11) 3_545 3_545
Co Sm2 Ge2 46.843(9) 5_656 3_545
Ge2 Sm2 Ge2 87.642(15) 3 3_545
Ge1 Sm2 Co 47.688(15) 3 3
Ge1 Sm2 Co 108.414(15) 3_545 3
Co Sm2 Co 61.312(16) 5_656 3
Ge2 Sm2 Co 47.019(15) 3 3
Ge2 Sm2 Co 105.890(15) 3_545 3
Ge1 Sm2 Co 108.414(15) 3 3_545
Ge1 Sm2 Co 47.688(14) 3_545 3_545
Co Sm2 Co 61.312(16) 5_656 3_545
Ge2 Sm2 Co 105.890(15) 3 3_545
Ge2 Sm2 Co 47.019(15) 3_545 3_545
Co Sm2 Co 87.263(17) 3 3_545
Ge1 Sm2 Ge1 107.596(9) 3 7_546
Ge1 Sm2 Ge1 48.838(16) 3_545 7_546
Co Sm2 Ge1 137.368(7) 5_656 7_546
Ge2 Sm2 Ge1 160.841(15) 3 7_546
Ge2 Sm2 Ge1 90.954(11) 3_545 7_546
Co Sm2 Ge1 150.328(16) 3 7_546
Co Sm2 Ge1 86.797(12) 3_545 7_546
Ge1 Sm2 Ge1 48.838(16) 3 7_556
Ge1 Sm2 Ge1 107.596(9) 3_545 7_556
Co Sm2 Ge1 137.368(7) 5_656 7_556
Ge2 Sm2 Ge1 90.954(11) 3 7_556
Ge2 Sm2 Ge1 160.841(15) 3_545 7_556
Co Sm2 Ge1 86.797(13) 3 7_556
Co Sm2 Ge1 150.328(16) 3_545 7_556
Ge1 Sm2 Ge1 84.148(14) 7_546 7_556
Ge1 Sm2 Ge2 78.109(12) 3 5_656
Ge1 Sm2 Ge2 78.109(12) 3_545 5_656
Co Sm2 Ge2 44.912(16) 5_656 5_656
Ge2 Sm2 Ge2 71.197(13) 3 5_656
Ge2 Sm2 Ge2 71.197(13) 3_545 5_656
Co Sm2 Ge2 43.746(9) 3 5_656
Co Sm2 Ge2 43.746(9) 3_545 5_656
Ge1 Sm2 Ge2 126.195(10) 7_546 5_656
Ge1 Sm2 Ge2 126.195(10) 7_556 5_656
Ge1 Sm2 In 150.727(12) 3 3_545
Ge1 Sm2 In 88.495(9) 3_545 3_545
Co Sm2 In 98.662(11) 5_656 3_545
Ge2 Sm2 In 111.197(11) 3 3_545
Ge2 Sm2 In 59.566(10) 3_545 3_545
Co Sm2 In 156.772(14) 3 3_545
Co Sm2 In 93.085(10) 3_545 3_545
Ge1 Sm2 In 52.690(9) 7_546 3_545
Ge1 Sm2 In 103.534(10) 7_556 3_545
Ge2 Sm2 In 130.267(7) 5_656 3_545
Ge1 Sm2 In 88.495(10) 3 3
Ge1 Sm2 In 150.727(12) 3_545 3
Co Sm2 In 98.662(11) 5_656 3
Ge2 Sm2 In 59.566(10) 3 3
Ge2 Sm2 In 111.197(11) 3_545 3
Co Sm2 In 93.085(10) 3 3
Co Sm2 In 156.772(14) 3_545 3
Ge1 Sm2 In 103.534(10) 7_546 3
Ge1 Sm2 In 52.690(9) 7_556 3
Ge2 Sm2 In 130.267(7) 5_656 3
In Sm2 In 77.642(8) 3_545 3
Ge2 Co Ge2 123.39(3) 7_556 7_546
Ge2 Co Ge1 110.698(19) 7_556 .
Ge2 Co Ge1 110.698(19) 7_546 .
Ge2 Co Ge2 100.83(2) 7_556 .
Ge2 Co Ge2 100.83(2) 7_546 .
Ge1 Co Ge2 108.46(3) . .
Ge2 Co Sm2 68.061(17) 7_556 5_656
Ge2 Co Sm2 68.061(17) 7_546 5_656
Ge1 Co Sm2 176.20(3) . 5_656
Ge2 Co Sm2 75.34(2) . 5_656
Ge2 Co Sm2 160.91(2) 7_556 3_445
Ge2 Co Sm2 74.335(12) 7_546 3_445
Ge1 Co Sm2 63.698(15) . 3_445
Ge2 Co Sm2 66.264(15) . 3_445
Sm2 Co Sm2 118.690(16) 5_656 3_445
Ge2 Co Sm2 74.335(12) 7_556 3_455
Ge2 Co Sm2 160.91(2) 7_546 3_455
Ge1 Co Sm2 63.698(15) . 3_455
Ge2 Co Sm2 66.264(15) . 3_455
Sm2 Co Sm2 118.690(15) 5_656 3_455
Sm2 Co Sm2 87.261(17) 3_445 3_455
Ge2 Co Sm1 66.699(17) 7_556 1_556
Ge2 Co Sm1 66.699(17) 7_546 1_556
Ge1 Co Sm1 104.73(2) . 1_556
Ge2 Co Sm1 146.81(3) . 1_556
Sm2 Co Sm1 71.468(15) 5_656 1_556
Sm2 Co Sm1 131.773(12) 3_445 1_556
Sm2 Co Sm1 131.773(12) 3_455 1_556
Ge2 Co Sm1 57.940(15) 7_556 7_556
Ge2 Co Sm1 123.64(2) 7_546 7_556
Ge1 Co Sm1 57.109(13) . 7_556
Ge2 Co Sm1 135.496(14) . 7_556
Sm2 Co Sm1 120.267(16) 5_656 7_556
Sm2 Co Sm1 120.73(2) 3_445 7_556
Sm2 Co Sm1 70.175(11) 3_455 7_556
Sm1 Co Sm1 65.560(13) 1_556 7_556
Ge2 Co Sm1 123.64(2) 7_556 7_546
Ge2 Co Sm1 57.940(14) 7_546 7_546
Ge1 Co Sm1 57.109(13) . 7_546
Ge2 Co Sm1 135.496(14) . 7_546
Sm2 Co Sm1 120.267(16) 5_656 7_546
Sm2 Co Sm1 70.175(11) 3_445 7_546
Sm2 Co Sm1 120.73(2) 3_455 7_546
Sm1 Co Sm1 65.560(13) 1_556 7_546
Sm1 Co Sm1 76.057(15) 7_556 7_546
Ge1 In Ge1 180.000(15) 5_556 1_554
Ge1 In Sm1 56.068(7) 5_556 3_445
Ge1 In Sm1 123.932(7) 1_554 3_445
Ge1 In Sm1 123.932(7) 5_556 7
Ge1 In Sm1 56.068(7) 1_554 7
Sm1 In Sm1 180.0 3_445 7
Ge1 In Sm1 123.933(7) 5_556 7_545
Ge1 In Sm1 56.067(7) 1_554 7_545
Sm1 In Sm1 100.368(8) 3_445 7_545
Sm1 In Sm1 79.632(8) 7 7_545
Ge1 In Sm1 56.067(7) 5_556 3_455
Ge1 In Sm1 123.933(7) 1_554 3_455
Sm1 In Sm1 79.632(8) 3_445 3_455
Sm1 In Sm1 100.368(8) 7 3_455
Sm1 In Sm1 180.0 7_545 3_455
Ge1 In Sm2 59.806(8) 5_556 3_455
Ge1 In Sm2 120.194(8) 1_554 3_455
Sm1 In Sm2 115.761(6) 3_445 3_455
Sm1 In Sm2 64.239(6) 7 3_455
Sm1 In Sm2 111.605(6) 7_545 3_455
Sm1 In Sm2 68.395(6) 3_455 3_455
Ge1 In Sm2 120.194(8) 5_556 7_545
Ge1 In Sm2 59.806(8) 1_554 7_545
Sm1 In Sm2 64.239(6) 3_445 7_545
Sm1 In Sm2 115.761(6) 7 7_545
Sm1 In Sm2 68.395(6) 7_545 7_545
Sm1 In Sm2 111.605(6) 3_455 7_545
Sm2 In Sm2 180.0 3_455 7_545
Ge1 In Sm2 59.806(8) 5_556 3_445
Ge1 In Sm2 120.194(8) 1_554 3_445
Sm1 In Sm2 68.395(6) 3_445 3_445
Sm1 In Sm2 111.605(6) 7 3_445
Sm1 In Sm2 64.239(6) 7_545 3_445
Sm1 In Sm2 115.761(6) 3_455 3_445
Sm2 In Sm2 77.642(7) 3_455 3_445
Sm2 In Sm2 102.358(8) 7_545 3_445
Ge1 In Sm2 120.194(8) 5_556 7
Ge1 In Sm2 59.806(8) 1_554 7
Sm1 In Sm2 111.605(6) 3_445 7
Sm1 In Sm2 68.395(6) 7 7
Sm1 In Sm2 115.761(6) 7_545 7
Sm1 In Sm2 64.239(6) 3_455 7
Sm2 In Sm2 102.358(8) 3_455 7
Sm2 In Sm2 77.642(7) 7_545 7
Sm2 In Sm2 180.0 3_445 7
Co Ge1 Ge1 118.82(3) . 5_556
Co Ge1 In 132.45(2) . 1_556
Ge1 Ge1 In 108.73(3) 5_556 1_556
Co Ge1 Sm1 78.817(15) . 7_556
Ge1 Ge1 Sm1 132.652(10) 5_556 7_556
In Ge1 Sm1 68.842(11) 1_556 7_556
Co Ge1 Sm1 78.817(15) . 7_546
Ge1 Ge1 Sm1 132.652(10) 5_556 7_546
In Ge1 Sm1 68.842(11) 1_556 7_546
Sm1 Ge1 Sm1 92.064(15) 7_556 7_546
Co Ge1 Sm2 68.614(14) . 3_445
Ge1 Ge1 Sm2 69.813(15) 5_556 3_445
In Ge1 Sm2 133.215(8) 1_556 3_445
Sm1 Ge1 Sm2 147.286(19) 7_556 3_445
Sm1 Ge1 Sm2 79.031(9) 7_546 3_445
Co Ge1 Sm2 68.614(14) . 3_455
Ge1 Ge1 Sm2 69.813(15) 5_556 3_455
In Ge1 Sm2 133.215(8) 1_556 3_455
Sm1 Ge1 Sm2 79.031(9) 7_556 3_455
Sm1 Ge1 Sm2 147.286(19) 7_546 3_455
Sm2 Ge1 Sm2 91.565(16) 3_445 3_455
Co Ge1 Sm2 136.683(8) . 7_546
Ge1 Ge1 Sm2 61.349(14) 5_556 7_546
In Ge1 Sm2 67.503(10) 1_556 7_546
Sm1 Ge1 Sm2 136.169(18) 7_556 7_546
Sm1 Ge1 Sm2 75.925(9) 7_546 7_546
Sm2 Ge1 Sm2 72.403(9) 3_445 7_546
Sm2 Ge1 Sm2 131.162(16) 3_455 7_546
Co Ge1 Sm2 136.683(9) . 7_556
Ge1 Ge1 Sm2 61.349(14) 5_556 7_556
In Ge1 Sm2 67.503(10) 1_556 7_556
Sm1 Ge1 Sm2 75.925(9) 7_556 7_556
Sm1 Ge1 Sm2 136.169(18) 7_546 7_556
Sm2 Ge1 Sm2 131.162(16) 3_445 7_556
Sm2 Ge1 Sm2 72.403(9) 3_455 7_556
Sm2 Ge1 Sm2 84.149(14) 7_546 7_556
Co Ge2 Co 123.39(3) 7_556 7_546
Co Ge2 Co 79.17(2) 7_556 .
Co Ge2 Co 79.17(2) 7_546 .
Co Ge2 Sm1 78.727(18) 7_556 .
Co Ge2 Sm1 78.727(18) 7_546 .
Co Ge2 Sm1 132.31(2) . .
Co Ge2 Sm2 142.95(2) 7_556 3_445
Co Ge2 Sm2 65.098(16) 7_546 3_445
Co Ge2 Sm2 66.719(14) . 3_445
Sm1 Ge2 Sm2 135.434(8) . 3_445
Co Ge2 Sm2 65.098(16) 7_556 3_455
Co Ge2 Sm2 142.95(2) 7_546 3_455
Co Ge2 Sm2 66.719(14) . 3_455
Sm1 Ge2 Sm2 135.434(8) . 3_455
Sm2 Ge2 Sm2 87.640(15) 3_445 3_455
Co Ge2 Sm1 145.87(2) 7_556 7_545
Co Ge2 Sm1 67.434(15) 7_546 7_545
Co Ge2 Sm1 133.993(10) . 7_545
Sm1 Ge2 Sm1 71.815(12) . 7_545
Sm2 Ge2 Sm1 70.806(9) 3_445 7_545
Sm2 Ge2 Sm1 128.608(18) 3_455 7_545
Co Ge2 Sm1 67.434(15) 7_556 7
Co Ge2 Sm1 145.87(2) 7_546 7
Co Ge2 Sm1 133.993(10) . 7
Sm1 Ge2 Sm1 71.815(12) . 7
Sm2 Ge2 Sm1 128.608(18) 3_445 7
Sm2 Ge2 Sm1 70.806(9) 3_455 7
Sm1 Ge2 Sm1 86.947(15) 7_545 7
Co Ge2 Sm2 61.919(16) 7_556 5_656
Co Ge2 Sm2 61.919(16) 7_546 5_656
Co Ge2 Sm2 59.751(19) . 5_656
Sm1 Ge2 Sm2 72.562(14) . 5_656
Sm2 Ge2 Sm2 108.804(13) 3_445 5_656
Sm2 Ge2 Sm2 108.804(13) 3_455 5_656
Sm1 Ge2 Sm2 122.108(12) 7_545 5_656
Sm1 Ge2 Sm2 122.108(12) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sm1 Ge1 2.9680(4) 7_556
Sm1 Ge1 2.9680(4) 7_546
Sm1 Ge2 2.9965(6) .
Sm1 Ge2 3.1048(4) 7_545
Sm1 Ge2 3.1048(4) 7
Sm1 Co 3.1217(7) 1_554
Sm1 In 3.3360(2) 3
Sm1 In 3.3360(2) 3_545
Sm1 Co 3.4674(5) 7_556
Sm1 Co 3.4674(5) 7_546
Sm1 Sm1 3.5793(4) 7_545
Sm1 Sm1 3.5793(4) 7
Sm2 Ge1 2.9806(4) 3
Sm2 Ge1 2.9806(4) 3_545
Sm2 Co 3.0168(7) 5_656
Sm2 Ge2 3.0851(4) 3
Sm2 Ge2 3.0851(4) 3_545
Sm2 Co 3.0958(5) 3
Sm2 Co 3.0958(5) 3_545
Sm2 Ge1 3.1878(4) 7_546
Sm2 Ge1 3.1878(4) 7_556
Sm2 Ge2 3.3785(6) 5_656
Sm2 In 3.4075(3) 3_545
Sm2 In 3.4075(3) 3
Co Ge2 2.4262(4) 7_556
Co Ge2 2.4262(4) 7_546
Co Ge1 2.4586(8) .
Co Ge2 2.4656(8) .
Co Sm2 3.0168(7) 5_656
Co Sm2 3.0958(5) 3_445
Co Sm2 3.0958(5) 3_455
Co Sm1 3.1217(7) 1_556
Co Sm1 3.4675(5) 7_556
Co Sm1 3.4675(5) 7_546
In Ge1 2.9335(5) 5_556
In Ge1 2.9335(5) 1_554
In Sm1 3.3361(2) 3_445
In Sm1 3.3361(2) 7
In Sm1 3.3361(2) 7_545
In Sm1 3.3361(2) 3_455
In Sm2 3.4075(2) 3_455
In Sm2 3.4075(2) 7_545
In Sm2 3.4075(2) 3_445
In Sm2 3.4075(2) 7
Ge1 Ge1 2.5570(9) 5_556
Ge1 In 2.9335(5) 1_556
Ge1 Sm1 2.9680(4) 7_556
Ge1 Sm1 2.9680(4) 7_546
Ge1 Sm2 2.9805(4) 3_445
Ge1 Sm2 2.9805(4) 3_455
Ge1 Sm2 3.1878(4) 7_546
Ge1 Sm2 3.1878(4) 7_556
Ge2 Co 2.4262(4) 7_556
Ge2 Co 2.4262(4) 7_546
Ge2 Sm2 3.0852(4) 3_445
Ge2 Sm2 3.0852(4) 3_455
Ge2 Sm1 3.1048(4) 7_545
Ge2 Sm1 3.1048(4) 7
Ge2 Sm2 3.3785(6) 5_656
