#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:14:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179528 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/25/4342590.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342590
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Stoyko, Stanislav S.'
'Mar, Arthur'
_publ_section_title
;
 Many Metals Make the Cut: Quaternary Rare-Earth Germanides RE4M2InGe4 (M
 = Fe, Co, Ni, Ru, Rh, Ir) and RE4RhInGe4 Derived from Excision of Slabs
 in RE2InGe2.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2780
_journal_page_last               2792
_journal_paper_doi               10.1021/ic502955h
_journal_volume                  54
_journal_year                    2015
_chemical_formula_structural     'Gd4 Co2 In Ge4'
_chemical_formula_sum            'Co2 Gd4 Ge4 In'
_chemical_formula_weight         1152.04
_chemical_name_common
'gadolinium cobalt indium germanide (4/2/1/4)'
_chemical_name_systematic
'gadolinium cobalt indium germanide (4/2/1/4)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 107.618(5)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.548(6)
_cell_length_b                   4.2483(16)
_cell_length_c                   7.058(3)
_cell_measurement_reflns_used    1299
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.63
_cell_measurement_theta_min      4.99
_cell_volume                     444.3(3)
_computing_cell_refinement       'Bruker SAINT 8.27B (Bruker, 2011)'
_computing_data_collection       'Bruker APEX 2 (Bruker, 2008)'
_computing_data_reduction        'Bruker SAINT 8.27B'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0455
_diffrn_reflns_av_unetI/netI     0.0399
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3157
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.257
_diffrn_reflns_theta_min         2.749
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    48.777
_exptl_absorpt_correction_T_max  0.5325
_exptl_absorpt_correction_T_min  0.1364
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL (Sheldrick, 2013)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.610
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             974
_exptl_crystal_size_max          0.068
_exptl_crystal_size_mid          0.023
_exptl_crystal_size_min          0.016
_refine_diff_density_max         2.045
_refine_diff_density_min         -2.222
_refine_diff_density_rms         0.506
_refine_ls_extinction_coef       0.00136(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         934
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0347
_refine_ls_R_factor_gt           0.0256
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0236P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0506
_refine_ls_wR_factor_ref         0.0540
_reflns_Friedel_coverage         0.000
_reflns_number_gt                771
_reflns_number_total             934
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic502955h_si_003.cif
_cod_data_source_block           Gd4Co2InGe4
_cod_depositor_comments
'Adding full bibliography for 4342570--4342590.cif.'
_cod_database_code               4342590
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.136
_shelx_estimated_absorpt_t_max   0.509
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Gd1 Gd 0.34635(3) 0.0000 0.06106(6) 0.00665(11) Uani 1 2 d S T P
Gd2 Gd 0.58893(3) 0.0000 0.38421(6) 0.00631(11) Uani 1 2 d S T P
Co Co 0.21972(8) 0.0000 0.62681(16) 0.0070(2) Uani 1 2 d S T P
In In 0.0000 0.0000 0.0000 0.0078(2) Uani 0.970(4) 4 d S T .
Ge1 Ge 0.06698(6) 0.0000 0.65795(13) 0.00688(18) Uani 1 2 d S T P
Ge2 Ge 0.20596(6) 0.0000 0.26912(13) 0.00716(18) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Gd1 Ge1 92.52(4) 7_556 7_546
Ge1 Gd1 Ge2 85.53(3) 7_556 .
Ge1 Gd1 Ge2 85.53(3) 7_546 .
Ge1 Gd1 Ge2 166.50(3) 7_556 7_545
Ge1 Gd1 Ge2 88.52(3) 7_546 7_545
Ge2 Gd1 Ge2 107.98(3) . 7_545
Ge1 Gd1 Ge2 88.52(3) 7_556 7
Ge1 Gd1 Ge2 166.50(3) 7_546 7
Ge2 Gd1 Ge2 107.98(3) . 7
Ge2 Gd1 Ge2 87.37(4) 7_545 7
Ge1 Gd1 Co 133.71(2) 7_556 1_554
Ge1 Gd1 Co 133.706(19) 7_546 1_554
Ge2 Gd1 Co 98.43(4) . 1_554
Ge2 Gd1 Co 46.20(2) 7_545 1_554
Ge2 Gd1 Co 46.20(2) 7 1_554
Ge1 Gd1 In 54.87(3) 7_556 3
Ge1 Gd1 In 110.42(3) 7_546 3
Ge2 Gd1 In 136.697(17) . 3
Ge2 Gd1 In 112.28(3) 7_545 3
Ge2 Gd1 In 59.70(2) 7 3
Co Gd1 In 97.94(3) 1_554 3
Ge1 Gd1 In 110.42(3) 7_556 3_545
Ge1 Gd1 In 54.87(3) 7_546 3_545
Ge2 Gd1 In 136.697(17) . 3_545
Ge2 Gd1 In 59.70(2) 7_545 3_545
Ge2 Gd1 In 112.28(3) 7 3_545
Co Gd1 In 97.94(3) 1_554 3_545
In Gd1 In 79.53(3) 3 3_545
Ge1 Gd1 Co 44.38(3) 7_556 7_556
Ge1 Gd1 Co 100.32(4) 7_546 7_556
Ge2 Gd1 Co 43.70(2) . 7_556
Ge2 Gd1 Co 148.39(3) 7_545 7_556
Ge2 Gd1 Co 89.83(3) 7 7_556
Co Gd1 Co 114.23(3) 1_554 7_556
In Gd1 Co 93.11(3) 3 7_556
In Gd1 Co 147.74(2) 3_545 7_556
Ge1 Gd1 Co 100.32(4) 7_556 7_546
Ge1 Gd1 Co 44.38(3) 7_546 7_546
Ge2 Gd1 Co 43.70(2) . 7_546
Ge2 Gd1 Co 89.83(3) 7_545 7_546
Ge2 Gd1 Co 148.39(3) 7 7_546
Co Gd1 Co 114.23(3) 1_554 7_546
In Gd1 Co 147.74(2) 3 7_546
In Gd1 Co 93.11(3) 3_545 7_546
Co Gd1 Co 76.43(4) 7_556 7_546
Ge1 Gd1 Gd1 140.80(3) 7_556 7_545
Ge1 Gd1 Gd1 84.98(3) 7_546 7_545
Ge2 Gd1 Gd1 55.27(2) . 7_545
Ge2 Gd1 Gd1 52.71(2) 7_545 7_545
Ge2 Gd1 Gd1 102.62(3) 7 7_545
Co Gd1 Gd1 61.61(2) 1_554 7_545
In Gd1 Gd1 159.42(2) 3 7_545
In Gd1 Gd1 99.95(3) 3_545 7_545
Co Gd1 Gd1 97.54(3) 7_556 7_545
Co Gd1 Gd1 52.61(3) 7_546 7_545
Ge1 Gd1 Gd1 84.98(3) 7_556 7
Ge1 Gd1 Gd1 140.80(3) 7_546 7
Ge2 Gd1 Gd1 55.27(2) . 7
Ge2 Gd1 Gd1 102.62(3) 7_545 7
Ge2 Gd1 Gd1 52.71(2) 7 7
Co Gd1 Gd1 61.61(2) 1_554 7
In Gd1 Gd1 99.95(3) 3 7
In Gd1 Gd1 159.42(2) 3_545 7
Co Gd1 Gd1 52.61(3) 7_556 7
Co Gd1 Gd1 97.54(3) 7_546 7
Gd1 Gd1 Gd1 73.28(3) 7_545 7
Ge1 Gd2 Ge1 91.72(4) 3 3_545
Ge1 Gd2 Co 109.16(3) 3 5_656
Ge1 Gd2 Co 109.16(3) 3_545 5_656
Ge1 Gd2 Ge2 82.56(3) 3 3
Ge1 Gd2 Ge2 150.01(3) 3_545 3
Co Gd2 Ge2 47.12(2) 5_656 3
Ge1 Gd2 Ge2 150.01(3) 3 3_545
Ge1 Gd2 Ge2 82.56(3) 3_545 3_545
Co Gd2 Ge2 47.12(2) 5_656 3_545
Ge2 Gd2 Ge2 87.84(4) 3 3_545
Ge1 Gd2 Co 47.84(3) 3 3
Ge1 Gd2 Co 108.63(4) 3_545 3
Co Gd2 Co 61.37(3) 5_656 3
Ge2 Gd2 Co 47.41(3) 3 3
Ge2 Gd2 Co 106.30(4) 3_545 3
Ge1 Gd2 Co 108.63(4) 3 3_545
Ge1 Gd2 Co 47.84(3) 3_545 3_545
Co Gd2 Co 61.37(3) 5_656 3_545
Ge2 Gd2 Co 106.30(4) 3 3_545
Ge2 Gd2 Co 47.41(3) 3_545 3_545
Co Gd2 Co 87.29(4) 3 3_545
Ge1 Gd2 Ge1 107.84(3) 3 7_546
Ge1 Gd2 Ge1 49.01(3) 3_545 7_546
Co Gd2 Ge1 137.24(2) 5_656 7_546
Ge2 Gd2 Ge1 159.92(3) 3 7_546
Ge2 Gd2 Ge1 90.53(3) 3_545 7_546
Co Gd2 Ge1 150.79(3) 3 7_546
Co Gd2 Ge1 86.99(3) 3_545 7_546
Ge1 Gd2 Ge1 49.01(3) 3 7_556
Ge1 Gd2 Ge1 107.84(3) 3_545 7_556
Co Gd2 Ge1 137.24(2) 5_656 7_556
Ge2 Gd2 Ge1 90.53(3) 3 7_556
Ge2 Gd2 Ge1 159.92(3) 3_545 7_556
Co Gd2 Ge1 86.99(3) 3 7_556
Co Gd2 Ge1 150.79(3) 3_545 7_556
Ge1 Gd2 Ge1 84.19(4) 7_546 7_556
Ge1 Gd2 Ge2 78.31(3) 3 5_656
Ge1 Gd2 Ge2 78.31(3) 3_545 5_656
Co Gd2 Ge2 45.02(3) 5_656 5_656
Ge2 Gd2 Ge2 71.70(3) 3 5_656
Ge2 Gd2 Ge2 71.70(3) 3_545 5_656
Co Gd2 Ge2 43.76(2) 3 5_656
Co Gd2 Ge2 43.76(2) 3_545 5_656
Ge1 Gd2 Ge2 126.52(2) 7_546 5_656
Ge1 Gd2 Ge2 126.52(2) 7_556 5_656
Ge1 Gd2 In 150.64(3) 3 3_545
Ge1 Gd2 In 88.44(3) 3_545 3_545
Co Gd2 In 98.44(2) 5_656 3_545
Ge2 Gd2 In 110.70(3) 3 3_545
Ge2 Gd2 In 58.99(3) 3_545 3_545
Co Gd2 In 156.60(3) 3 3_545
Co Gd2 In 93.06(3) 3_545 3_545
Ge1 Gd2 In 52.41(2) 7_546 3_545
Ge1 Gd2 In 103.27(3) 7_556 3_545
Ge2 Gd2 In 130.197(16) 5_656 3_545
Ge1 Gd2 In 88.44(3) 3 3
Ge1 Gd2 In 150.64(3) 3_545 3
Co Gd2 In 98.44(2) 5_656 3
Ge2 Gd2 In 58.99(3) 3 3
Ge2 Gd2 In 110.70(3) 3_545 3
Co Gd2 In 93.06(3) 3 3
Co Gd2 In 156.60(3) 3_545 3
Ge1 Gd2 In 103.27(3) 7_546 3
Ge1 Gd2 In 52.41(2) 7_556 3
Ge2 Gd2 In 130.197(17) 5_656 3
In Gd2 In 77.53(3) 3_545 3
Ge2 Co Ge2 122.45(7) 7_556 7_546
Ge2 Co Ge1 111.04(4) 7_556 .
Ge2 Co Ge1 111.04(4) 7_546 .
Ge2 Co Ge2 101.29(4) 7_556 .
Ge2 Co Ge2 101.29(4) 7_546 .
Ge1 Co Ge2 107.78(5) . .
Ge2 Co Gd2 67.80(3) 7_556 5_656
Ge2 Co Gd2 67.80(3) 7_546 5_656
Ge1 Co Gd2 176.51(5) . 5_656
Ge2 Co Gd2 75.71(4) . 5_656
Ge2 Co Gd2 161.40(4) 7_556 3_445
Ge2 Co Gd2 74.80(3) 7_546 3_445
Ge1 Co Gd2 63.56(3) . 3_445
Ge2 Co Gd2 65.97(3) . 3_445
Gd2 Co Gd2 118.63(3) 5_656 3_445
Ge2 Co Gd2 74.80(3) 7_556 3_455
Ge2 Co Gd2 161.40(4) 7_546 3_455
Ge1 Co Gd2 63.56(3) . 3_455
Ge2 Co Gd2 65.97(3) . 3_455
Gd2 Co Gd2 118.63(3) 5_656 3_455
Gd2 Co Gd2 87.29(4) 3_445 3_455
Ge2 Co Gd1 66.34(3) 7_556 1_556
Ge2 Co Gd1 66.34(3) 7_546 1_556
Ge1 Co Gd1 104.71(5) . 1_556
Ge2 Co Gd1 147.51(5) . 1_556
Gd2 Co Gd1 71.80(3) 5_656 1_556
Gd2 Co Gd1 131.67(2) 3_445 1_556
Gd2 Co Gd1 131.67(2) 3_455 1_556
Ge2 Co Gd1 58.07(3) 7_556 7_556
Ge2 Co Gd1 123.75(5) 7_546 7_556
Ge1 Co Gd1 57.05(2) . 7_556
Ge2 Co Gd1 134.91(3) . 7_556
Gd2 Co Gd1 120.55(3) 5_656 7_556
Gd2 Co Gd1 120.55(4) 3_445 7_556
Gd2 Co Gd1 69.78(3) 3_455 7_556
Gd1 Co Gd1 65.77(3) 1_556 7_556
Ge2 Co Gd1 123.75(5) 7_556 7_546
Ge2 Co Gd1 58.07(3) 7_546 7_546
Ge1 Co Gd1 57.05(2) . 7_546
Ge2 Co Gd1 134.91(3) . 7_546
Gd2 Co Gd1 120.55(3) 5_656 7_546
Gd2 Co Gd1 69.78(3) 3_445 7_546
Gd2 Co Gd1 120.55(4) 3_455 7_546
Gd1 Co Gd1 65.77(3) 1_556 7_546
Gd1 Co Gd1 76.43(4) 7_556 7_546
Ge1 In Ge1 180.00(3) 5_556 1_554
Ge1 In Gd1 55.880(16) 5_556 3_445
Ge1 In Gd1 124.120(16) 1_554 3_445
Ge1 In Gd1 124.120(16) 5_556 7
Ge1 In Gd1 55.880(16) 1_554 7
Gd1 In Gd1 180.000(10) 3_445 7
Ge1 In Gd1 124.120(16) 5_556 7_545
Ge1 In Gd1 55.880(16) 1_554 7_545
Gd1 In Gd1 100.47(3) 3_445 7_545
Gd1 In Gd1 79.53(3) 7 7_545
Ge1 In Gd1 55.880(16) 5_556 3_455
Ge1 In Gd1 124.120(16) 1_554 3_455
Gd1 In Gd1 79.53(3) 3_445 3_455
Gd1 In Gd1 100.47(3) 7 3_455
Gd1 In Gd1 180.000(14) 7_545 3_455
Ge1 In Gd2 59.83(2) 5_556 3_455
Ge1 In Gd2 120.17(2) 1_554 3_455
Gd1 In Gd2 115.59(2) 3_445 3_455
Gd1 In Gd2 64.41(2) 7 3_455
Gd1 In Gd2 111.66(2) 7_545 3_455
Gd1 In Gd2 68.34(2) 3_455 3_455
Ge1 In Gd2 120.17(2) 5_556 7_545
Ge1 In Gd2 59.83(2) 1_554 7_545
Gd1 In Gd2 64.41(2) 3_445 7_545
Gd1 In Gd2 115.59(2) 7 7_545
Gd1 In Gd2 68.34(2) 7_545 7_545
Gd1 In Gd2 111.66(2) 3_455 7_545
Gd2 In Gd2 180.000(10) 3_455 7_545
Ge1 In Gd2 59.83(2) 5_556 3_445
Ge1 In Gd2 120.17(2) 1_554 3_445
Gd1 In Gd2 68.34(2) 3_445 3_445
Gd1 In Gd2 111.66(2) 7 3_445
Gd1 In Gd2 64.41(2) 7_545 3_445
Gd1 In Gd2 115.59(2) 3_455 3_445
Gd2 In Gd2 77.53(3) 3_455 3_445
Gd2 In Gd2 102.47(3) 7_545 3_445
Ge1 In Gd2 120.17(2) 5_556 7
Ge1 In Gd2 59.83(2) 1_554 7
Gd1 In Gd2 111.66(2) 3_445 7
Gd1 In Gd2 68.34(2) 7 7
Gd1 In Gd2 115.59(2) 7_545 7
Gd1 In Gd2 64.41(2) 3_455 7
Gd2 In Gd2 102.47(3) 3_455 7
Gd2 In Gd2 77.53(3) 7_545 7
Gd2 In Gd2 180.0 3_445 7
Co Ge1 Ge1 118.63(6) . 5_556
Co Ge1 In 132.51(4) . 1_556
Ge1 Ge1 In 108.87(6) 5_556 1_556
Co Ge1 Gd1 78.56(3) . 7_556
Ge1 Ge1 Gd1 132.56(2) 5_556 7_556
In Ge1 Gd1 69.25(3) 1_556 7_556
Co Ge1 Gd1 78.56(3) . 7_546
Ge1 Ge1 Gd1 132.56(2) 5_556 7_546
In Ge1 Gd1 69.25(3) 1_556 7_546
Gd1 Ge1 Gd1 92.52(4) 7_556 7_546
Co Ge1 Gd2 68.60(3) . 3_445
Ge1 Ge1 Gd2 69.77(3) 5_556 3_445
In Ge1 Gd2 133.14(2) 1_556 3_445
Gd1 Ge1 Gd2 147.04(4) 7_556 3_445
Gd1 Ge1 Gd2 78.58(3) 7_546 3_445
Co Ge1 Gd2 68.60(3) . 3_455
Ge1 Ge1 Gd2 69.77(3) 5_556 3_455
In Ge1 Gd2 133.14(2) 1_556 3_455
Gd1 Ge1 Gd2 78.58(3) 7_556 3_455
Gd1 Ge1 Gd2 147.04(4) 7_546 3_455
Gd2 Ge1 Gd2 91.72(4) 3_445 3_455
Co Ge1 Gd2 136.57(2) . 7_546
Ge1 Ge1 Gd2 61.22(3) 5_556 7_546
In Ge1 Gd2 67.76(2) 1_556 7_546
Gd1 Ge1 Gd2 136.81(3) 7_556 7_546
Gd1 Ge1 Gd2 76.14(3) 7_546 7_546
Gd2 Ge1 Gd2 72.16(3) 3_445 7_546
Gd2 Ge1 Gd2 130.98(3) 3_455 7_546
Co Ge1 Gd2 136.57(2) . 7_556
Ge1 Ge1 Gd2 61.22(3) 5_556 7_556
In Ge1 Gd2 67.76(2) 1_556 7_556
Gd1 Ge1 Gd2 76.14(3) 7_556 7_556
Gd1 Ge1 Gd2 136.81(3) 7_546 7_556
Gd2 Ge1 Gd2 130.98(3) 3_445 7_556
Gd2 Ge1 Gd2 72.16(3) 3_455 7_556
Gd2 Ge1 Gd2 84.19(4) 7_546 7_556
Co Ge2 Co 122.45(7) 7_556 7_546
Co Ge2 Co 78.71(4) 7_556 .
Co Ge2 Co 78.71(4) 7_546 .
Co Ge2 Gd1 78.23(4) 7_556 .
Co Ge2 Gd1 78.23(4) 7_546 .
Co Ge2 Gd1 130.92(5) . .
Co Ge2 Gd2 142.63(4) 7_556 3_445
Co Ge2 Gd2 65.08(4) 7_546 3_445
Co Ge2 Gd2 66.62(3) . 3_445
Gd1 Ge2 Gd2 135.574(19) . 3_445
Co Ge2 Gd2 65.08(4) 7_556 3_455
Co Ge2 Gd2 142.63(4) 7_546 3_455
Co Ge2 Gd2 66.62(3) . 3_455
Gd1 Ge2 Gd2 135.574(19) . 3_455
Gd2 Ge2 Gd2 87.84(4) 3_445 3_455
Co Ge2 Gd1 145.85(4) 7_556 7_545
Co Ge2 Gd1 67.46(3) 7_546 7_545
Co Ge2 Gd1 134.13(2) . 7_545
Gd1 Ge2 Gd1 72.02(3) . 7_545
Gd2 Ge2 Gd1 71.33(3) 3_445 7_545
Gd2 Ge2 Gd1 129.65(4) 3_455 7_545
Co Ge2 Gd1 67.46(3) 7_556 7
Co Ge2 Gd1 145.85(4) 7_546 7
Co Ge2 Gd1 134.13(2) . 7
Gd1 Ge2 Gd1 72.02(3) . 7
Gd2 Ge2 Gd1 129.65(4) 3_445 7
Gd2 Ge2 Gd1 71.33(3) 3_455 7
Gd1 Ge2 Gd1 87.37(4) 7_545 7
Co Ge2 Gd2 61.44(3) 7_556 5_656
Co Ge2 Gd2 61.44(3) 7_546 5_656
Co Ge2 Gd2 59.27(4) . 5_656
Gd1 Ge2 Gd2 71.65(4) . 5_656
Gd2 Ge2 Gd2 108.30(3) 3_445 5_656
Gd2 Ge2 Gd2 108.30(3) 3_455 5_656
Gd1 Ge2 Gd2 121.57(3) 7_545 5_656
Gd1 Ge2 Gd2 121.57(3) 7 5_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 Ge1 2.9400(10) 7_556
Gd1 Ge1 2.9400(10) 7_546
Gd1 Ge2 2.9769(13) .
Gd1 Ge2 3.0753(11) 7_545
Gd1 Ge2 3.0753(11) 7
Gd1 Co 3.1012(15) 1_554
Gd1 In 3.3209(9) 3
Gd1 In 3.3209(9) 3_545
Gd1 Co 3.4338(12) 7_556
Gd1 Co 3.4338(12) 7_546
Gd1 Gd1 3.5593(12) 7_545
Gd1 Gd1 3.5593(12) 7
Gd2 Ge1 2.9598(10) 3
Gd2 Ge1 2.9598(10) 3_545
Gd2 Co 2.9995(17) 5_656
Gd2 Ge2 3.0622(10) 3
Gd2 Ge2 3.0622(10) 3_545
Gd2 Co 3.0776(11) 3
Gd2 Co 3.0776(11) 3_545
Gd2 Ge1 3.1687(11) 7_546
Gd2 Ge1 3.1687(11) 7_556
Gd2 Ge2 3.3814(14) 5_656
Gd2 In 3.3924(9) 3_545
Gd2 In 3.3924(9) 3
Co Ge2 2.4234(10) 7_556
Co Ge2 2.4234(10) 7_546
Co Ge1 2.4503(17) .
Co Ge2 2.4683(17) .
Co Gd2 2.9996(17) 5_656
Co Gd2 3.0776(11) 3_445
Co Gd2 3.0776(11) 3_455
Co Gd1 3.1013(15) 1_556
Co Gd1 3.4338(12) 7_556
Co Gd1 3.4338(12) 7_546
In Ge1 2.9044(13) 5_556
In Ge1 2.9044(13) 1_554
In Gd1 3.3209(9) 3_445
In Gd1 3.3209(9) 7
In Gd1 3.3209(9) 7_545
In Gd1 3.3209(9) 3_455
In Gd2 3.3923(9) 3_455
In Gd2 3.3923(9) 7_545
In Gd2 3.3923(9) 3_445
In Gd2 3.3923(9) 7
Ge1 Ge1 2.5493(19) 5_556
Ge1 In 2.9044(13) 1_556
Ge1 Gd1 2.9399(10) 7_556
Ge1 Gd1 2.9399(10) 7_546
Ge1 Gd2 2.9598(10) 3_445
Ge1 Gd2 2.9598(10) 3_455
Ge1 Gd2 3.1687(11) 7_546
Ge1 Gd2 3.1687(11) 7_556
Ge2 Co 2.4234(10) 7_556
Ge2 Co 2.4234(10) 7_546
Ge2 Gd2 3.0623(10) 3_445
Ge2 Gd2 3.0623(10) 3_455
Ge2 Gd1 3.0753(11) 7_545
Ge2 Gd1 3.0753(11) 7
Ge2 Gd2 3.3814(14) 5_656
