#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:18:40 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179530 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/27/4342729.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342729
loop_
_publ_author_name
'Wójcik, Katarzyna'
'Preda, Ana Maria'
'Mertens, Lutz'
'Ecorchard, Petra'
'Rüffer, Tobias'
'Lang, Heinrich'
'Mehring, Michael'
_publ_section_title
;
 Iron-bismuth halido compounds: molecules, clusters, and polymers.
;
_journal_issue                   8
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3905
_journal_page_last               3912
_journal_paper_doi               10.1021/acs.inorgchem.5b00088
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'Bi3 Cl11, 2(C14 H18 Fe N O2), Bi Cl3'
_chemical_formula_sum            'C28 H36 Bi4 Cl14 Fe2 N2 O4'
_chemical_formula_weight         1908.51
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.255(3)
_cell_angle_beta                 112.110(3)
_cell_angle_gamma                106.598(3)
_cell_formula_units_Z            2
_cell_length_a                   12.8907(4)
_cell_length_b                   15.1214(5)
_cell_length_c                   15.7675(6)
_cell_measurement_reflns_used    10887
_cell_measurement_temperature    105
_cell_measurement_theta_max      65.3527
_cell_measurement_theta_min      3.1671
_cell_volume                     2601.20(19)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      105
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.958
_diffrn_measurement_device_type  'oxford gemini s'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0335
_diffrn_reflns_av_sigmaI/netI    0.0353
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            16924
_diffrn_reflns_theta_full        65.49
_diffrn_reflns_theta_max         65.49
_diffrn_reflns_theta_min         3.77
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 50
_diffrn_standards_interval_time  5
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    37.265
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.27081
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            violet
_exptl_crystal_density_diffrn    2.437
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.322
_refine_diff_density_min         -1.972
_refine_diff_density_rms         0.272
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     489
_refine_ls_number_reflns         8596
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0434
_refine_ls_R_factor_gt           0.0371
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0677P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0922
_refine_ls_wR_factor_ref         0.0949
_reflns_number_gt                7366
_reflns_number_total             8596
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b00088_si_003.cif
_cod_data_source_block           kacja04
_cod_depositor_comments
'Adding full bibliography for 4342729--4342730.cif.'
_cod_original_cell_volume        2601.20(15)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4342729
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7397(7) 0.6874(6) 0.5618(6) 0.0172(16) Uani 1 1 d .
C2 C 0.6722(7) 0.6890(5) 0.4679(6) 0.0168(16) Uani 1 1 d .
C3 C 0.7273(7) 0.7811(5) 0.4599(6) 0.0162(16) Uani 1 1 d .
C4 C 0.8253(7) 0.8393(6) 0.5511(6) 0.0212(18) Uani 1 1 d .
C5 C 0.8349(8) 0.7821(6) 0.6139(6) 0.0209(17) Uani 1 1 d .
C6 C 0.7135(8) 0.6073(7) 0.6037(7) 0.031(2) Uani 1 1 d .
H6A H 0.7743 0.6259 0.6687 0.047 Uiso 1 1 calc R
H6B H 0.7136 0.5504 0.5666 0.047 Uiso 1 1 calc R
H6C H 0.6356 0.5938 0.6028 0.047 Uiso 1 1 calc R
C7 C 0.5609(7) 0.6076(6) 0.3897(6) 0.0218(17) Uani 1 1 d .
H7A H 0.5422 0.5530 0.4128 0.033 Uiso 1 1 calc R
H7B H 0.5752 0.5895 0.3352 0.033 Uiso 1 1 calc R
H7C H 0.4941 0.6285 0.3712 0.033 Uiso 1 1 calc R
C8 C 0.6796(8) 0.8150(6) 0.3727(6) 0.0234(18) Uani 1 1 d .
H8A H 0.7325 0.8799 0.3852 0.035 Uiso 1 1 calc R
H8B H 0.6000 0.8135 0.3594 0.035 Uiso 1 1 calc R
H8C H 0.6763 0.7730 0.3183 0.035 Uiso 1 1 calc R
C9 C 0.9017(8) 0.9450(6) 0.5783(7) 0.028(2) Uani 1 1 d .
H9A H 0.8780 0.9673 0.5229 0.041 Uiso 1 1 calc R
H9B H 0.9853 0.9536 0.6019 0.041 Uiso 1 1 calc R
H9C H 0.8903 0.9815 0.6275 0.041 Uiso 1 1 calc R
C10 C 0.9224(8) 0.8136(7) 0.7176(6) 0.029(2) Uani 1 1 d .
H10A H 0.9086 0.7603 0.7432 0.044 Uiso 1 1 calc R
H10B H 0.9114 0.8658 0.7521 0.044 Uiso 1 1 calc R
H10C H 1.0035 0.8351 0.7243 0.044 Uiso 1 1 calc R
C11 C 0.7994(9) 0.6255(7) 0.3852(7) 0.037(2) Uani 1 1 d .
C12 C 0.9694(9) 0.7945(6) 0.4742(8) 0.032(2) Uani 1 1 d .
C13 C 1.0207(8) 0.6317(6) 0.6200(7) 0.0256(19) Uani 1 1 d .
C14 C 1.0989(9) 0.5917(8) 0.6785(9) 0.050(3) Uani 1 1 d .
H14A H 1.1277 0.6248 0.7451 0.075 Uiso 1 1 calc R
H14B H 1.1665 0.5994 0.6642 0.075 Uiso 1 1 calc R
H14C H 1.0550 0.5241 0.6654 0.075 Uiso 1 1 calc R
C15 C 1.3094(7) 1.3141(6) -0.0117(6) 0.0175(16) Uani 1 1 d .
C16 C 1.2228(7) 1.2275(5) -0.0859(6) 0.0163(16) Uani 1 1 d .
C17 C 1.1908(7) 1.1554(6) -0.0439(6) 0.0192(17) Uani 1 1 d .
C18 C 1.2581(7) 1.1966(6) 0.0577(6) 0.0214(18) Uani 1 1 d .
C19 C 1.3335(7) 1.2932(6) 0.0773(6) 0.0221(18) Uani 1 1 d .
C20 C 1.3694(8) 1.4065(6) -0.0252(8) 0.033(2) Uani 1 1 d .
H20A H 1.4243 1.4535 0.0363 0.050 Uiso 1 1 calc R
H20B H 1.3094 1.4298 -0.0600 0.050 Uiso 1 1 calc R
H20C H 1.4134 1.3961 -0.0607 0.050 Uiso 1 1 calc R
C21 C 1.1777(8) 1.2141(7) -0.1920(6) 0.028(2) Uani 1 1 d .
H21A H 1.2127 1.2743 -0.2020 0.042 Uiso 1 1 calc R
H21B H 1.0912 1.1934 -0.2220 0.042 Uiso 1 1 calc R
H21C H 1.2005 1.1660 -0.2197 0.042 Uiso 1 1 calc R
C22 C 1.1074(8) 1.0517(6) -0.0974(8) 0.033(2) Uani 1 1 d .
H22A H 1.1004 1.0173 -0.0524 0.050 Uiso 1 1 calc R
H22B H 1.1395 1.0225 -0.1350 0.050 Uiso 1 1 calc R
H22C H 1.0291 1.0490 -0.1390 0.050 Uiso 1 1 calc R
C23 C 1.2593(10) 1.1405(9) 0.1286(8) 0.043(3) Uani 1 1 d .
H23A H 1.3109 1.1836 0.1926 0.064 Uiso 1 1 calc R
H23B H 1.2892 1.0908 0.1168 0.064 Uiso 1 1 calc R
H23C H 1.1786 1.1115 0.1214 0.064 Uiso 1 1 calc R
C24 C 1.4249(8) 1.3623(8) 0.1739(7) 0.035(2) Uani 1 1 d .
H24A H 1.4638 1.4232 0.1668 0.052 Uiso 1 1 calc R
H24B H 1.4844 1.3363 0.2034 0.052 Uiso 1 1 calc R
H24C H 1.3854 1.3718 0.2134 0.052 Uiso 1 1 calc R
C25 C 1.0123(7) 1.1893(6) -0.0051(7) 0.0215(18) Uani 1 1 d .
C26 C 1.1721(8) 1.3618(6) 0.1080(6) 0.0259(19) Uani 1 1 d .
C27 C 1.0206(8) 1.3700(6) -0.1327(6) 0.0264(19) Uani 1 1 d .
C28 C 0.9486(10) 1.4127(8) -0.1930(8) 0.045(3) Uani 1 1 d .
H28A H 0.8780 1.4053 -0.1831 0.067 Uiso 1 1 calc R
H28B H 0.9246 1.3810 -0.2591 0.067 Uiso 1 1 calc R
H28C H 0.9951 1.4803 -0.1773 0.067 Uiso 1 1 calc R
O1 O 0.7619(8) 0.5704(6) 0.3113(6) 0.059(2) Uani 1 1 d .
O2 O 1.0376(7) 0.8468(5) 0.4568(7) 0.049(2) Uani 1 1 d .
O3 O 0.9300(6) 1.1310(5) -0.0097(6) 0.0376(17) Uani 1 1 d .
O4 O 1.1882(7) 1.4175(6) 0.1739(5) 0.047(2) Uani 1 1 d .
Cl1 Cl 0.6271(2) 1.22050(13) 0.27238(15) 0.0277(4) Uani 1 1 d .
Cl2 Cl 0.8582(2) 1.35510(18) 0.53961(18) 0.0423(6) Uani 1 1 d .
Cl3 Cl 0.5593(2) 1.36397(16) 0.43160(17) 0.0370(5) Uani 1 1 d .
Cl4 Cl 0.63257(18) 1.25262(13) 0.62349(14) 0.0232(4) Uani 1 1 d .
Cl5 Cl 0.37521(16) 1.10841(13) 0.36219(14) 0.0205(4) Uani 1 1 d .
Cl6 Cl 0.15021(17) 0.86658(14) 0.25498(15) 0.0261(4) Uani 1 1 d .
Cl7 Cl 0.64531(15) 1.03886(12) 0.48503(13) 0.0164(4) Uani 1 1 d .
Cl8 Cl 0.40720(19) 0.92979(14) 0.18580(15) 0.0260(4) Uani 1 1 d .
Cl9 Cl 0.56091(16) 0.89666(13) 0.01972(14) 0.0190(4) Uani 1 1 d .
Cl10 Cl 0.75752(19) 1.02798(17) 0.28475(17) 0.0329(5) Uani 1 1 d .
Cl11 Cl 0.76962(16) 1.15982(13) 0.11871(14) 0.0198(4) Uani 1 1 d .
Cl12 Cl 0.8731(2) 1.35197(17) 0.0079(2) 0.0430(6) Uani 1 1 d .
Cl13 Cl 0.5791(3) 1.3443(2) -0.14683(18) 0.0532(7) Uani 1 1 d .
Cl14 Cl 0.6681(2) 1.38193(15) 0.10416(15) 0.0302(5) Uani 1 1 d .
Fe1 Fe 0.85420(11) 0.71671(8) 0.49526(9) 0.0163(3) Uani 1 1 d .
Fe2 Fe 1.15037(10) 1.27416(8) 0.00545(9) 0.0128(2) Uani 1 1 d .
Bi1 Bi 0.64303(3) 1.23811(2) 0.45913(2) 0.01664(9) Uani 1 1 d .
Bi2 Bi 0.37206(2) 0.937422(19) 0.34869(2) 0.01295(9) Uani 1 1 d .
Bi3 Bi 0.60451(2) 1.059148(19) 0.15430(2) 0.01378(9) Uani 1 1 d .
Bi4 Bi 0.66072(3) 1.26305(2) -0.02724(2) 0.01535(9) Uani 1 1 d .
N1 N 0.9583(6) 0.6624(5) 0.5735(5) 0.0204(14) Uani 1 1 d .
N2 N 1.0733(6) 1.3363(4) -0.0816(5) 0.0164(14) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe -1.1336 3.1974 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.0111 8.9310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C5 107.4(7) . .
C2 C1 C6 127.3(7) . .
C5 C1 C6 125.1(8) . .
C2 C1 Fe1 71.0(4) . .
C5 C1 Fe1 70.1(4) . .
C6 C1 Fe1 128.0(6) . .
C1 C2 C3 108.3(7) . .
C1 C2 C7 126.2(7) . .
C3 C2 C7 125.5(7) . .
C1 C2 Fe1 69.8(4) . .
C3 C2 Fe1 68.9(4) . .
C7 C2 Fe1 127.2(5) . .
C2 C3 C4 108.2(7) . .
C2 C3 C8 125.4(7) . .
C4 C3 C8 126.0(7) . .
C2 C3 Fe1 71.6(4) . .
C4 C3 Fe1 71.4(4) . .
C8 C3 Fe1 128.5(5) . .
C5 C4 C3 108.0(7) . .
C5 C4 C9 125.4(8) . .
C3 C4 C9 126.5(8) . .
C5 C4 Fe1 70.2(4) . .
C3 C4 Fe1 69.0(4) . .
C9 C4 Fe1 129.0(5) . .
C4 C5 C1 108.0(7) . .
C4 C5 C10 126.9(8) . .
C1 C5 C10 125.1(8) . .
C4 C5 Fe1 70.7(4) . .
C1 C5 Fe1 69.8(4) . .
C10 C5 Fe1 127.7(6) . .
C1 C6 H6A 109.5 . .
C1 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C1 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C2 C7 H7A 109.5 . .
C2 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C2 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C3 C8 H8A 109.5 . .
C3 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C3 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C4 C9 H9A 109.5 . .
C4 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C4 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C5 C10 H10A 109.5 . .
C5 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C5 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O1 C11 Fe1 175.9(10) . .
O2 C12 Fe1 175.2(9) . .
N1 C13 C14 179.4(11) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C19 107.2(7) . .
C16 C15 C20 126.0(8) . .
C19 C15 C20 126.7(8) . .
C16 C15 Fe2 71.3(4) . .
C19 C15 Fe2 70.4(4) . .
C20 C15 Fe2 126.7(5) . .
C17 C16 C15 108.7(7) . .
C17 C16 C21 125.8(7) . .
C15 C16 C21 125.5(7) . .
C17 C16 Fe2 70.5(4) . .
C15 C16 Fe2 69.4(4) . .
C21 C16 Fe2 128.3(5) . .
C16 C17 C18 107.9(7) . .
C16 C17 C22 125.6(8) . .
C18 C17 C22 126.4(8) . .
C16 C17 Fe2 70.8(4) . .
C18 C17 Fe2 69.1(4) . .
C22 C17 Fe2 129.1(5) . .
C19 C18 C17 107.9(7) . .
C19 C18 C23 127.0(9) . .
C17 C18 C23 124.5(9) . .
C19 C18 Fe2 71.0(4) . .
C17 C18 Fe2 71.4(4) . .
C23 C18 Fe2 129.8(6) . .
C18 C19 C15 108.3(7) . .
C18 C19 C24 126.5(9) . .
C15 C19 C24 125.2(8) . .
C18 C19 Fe2 69.7(4) . .
C15 C19 Fe2 69.9(4) . .
C24 C19 Fe2 127.0(6) . .
C15 C20 H20A 109.5 . .
C15 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C15 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C16 C21 H21A 109.5 . .
C16 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C16 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C17 C22 H22A 109.5 . .
C17 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C17 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C18 C23 H23A 109.5 . .
C18 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C18 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C19 C24 H24A 109.5 . .
C19 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C19 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
O3 C25 Fe2 174.5(7) . .
O4 C26 Fe2 178.6(8) . .
N2 C27 C28 175.3(11) . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
Bi3 Cl1 Bi1 124.55(7) . .
Bi1 Cl4 Bi2 102.41(6) . 2_676
Bi2 Cl5 Bi1 104.62(6) . .
Bi2 Cl7 Bi2 97.39(5) 2_676 .
Bi2 Cl8 Bi3 130.55(7) . .
Bi3 Cl9 Bi3 95.78(5) . 2_675
C11 Fe1 C12 92.5(5) . .
C11 Fe1 N1 95.8(4) . .
C12 Fe1 N1 94.7(4) . .
C11 Fe1 C3 101.5(4) . .
C12 Fe1 C3 100.8(3) . .
N1 Fe1 C3 156.1(3) . .
C11 Fe1 C1 112.2(4) . .
C12 Fe1 C1 153.7(4) . .
N1 Fe1 C1 91.7(3) . .
C3 Fe1 C1 66.6(3) . .
C11 Fe1 C5 152.0(4) . .
C12 Fe1 C5 114.2(4) . .
N1 Fe1 C5 90.7(3) . .
C3 Fe1 C5 66.4(3) . .
C1 Fe1 C5 40.2(3) . .
C11 Fe1 C4 140.3(4) . .
C12 Fe1 C4 89.0(3) . .
N1 Fe1 C4 123.7(3) . .
C3 Fe1 C4 39.7(3) . .
C1 Fe1 C4 66.5(3) . .
C5 Fe1 C4 39.1(3) . .
C11 Fe1 C2 88.2(4) . .
C12 Fe1 C2 139.1(4) . .
N1 Fe1 C2 125.9(3) . .
C3 Fe1 C2 39.5(3) . .
C1 Fe1 C2 39.2(3) . .
C5 Fe1 C2 66.2(3) . .
C4 Fe1 C2 66.0(3) . .
C26 Fe2 C25 94.0(4) . .
C26 Fe2 N2 92.6(3) . .
C25 Fe2 N2 95.6(3) . .
C26 Fe2 C18 106.6(4) . .
C25 Fe2 C18 96.3(3) . .
N2 Fe2 C18 156.7(3) . .
C26 Fe2 C15 108.7(4) . .
C25 Fe2 C15 154.5(3) . .
N2 Fe2 C15 94.9(3) . .
C18 Fe2 C15 66.6(3) . .
C26 Fe2 C19 88.7(4) . .
C25 Fe2 C19 133.3(4) . .
N2 Fe2 C19 131.0(3) . .
C18 Fe2 C19 39.3(3) . .
C15 Fe2 C19 39.7(3) . .
C26 Fe2 C17 146.0(4) . .
C25 Fe2 C17 88.7(3) . .
N2 Fe2 C17 120.9(3) . .
C18 Fe2 C17 39.6(3) . .
C15 Fe2 C17 66.0(3) . .
C19 Fe2 C17 65.8(3) . .
C26 Fe2 C16 148.0(4) . .
C25 Fe2 C16 117.3(3) . .
N2 Fe2 C16 90.8(3) . .
C18 Fe2 C16 65.8(3) . .
C15 Fe2 C16 39.3(3) . .
C19 Fe2 C16 65.6(3) . .
C17 Fe2 C16 38.8(3) . .
Cl3 Bi1 Cl2 94.06(9) . .
Cl3 Bi1 Cl4 91.49(7) . .
Cl2 Bi1 Cl4 91.98(7) . .
Cl3 Bi1 Cl1 84.45(7) . .
Cl2 Bi1 Cl1 93.22(7) . .
Cl4 Bi1 Cl1 173.62(6) . .
Cl3 Bi1 Cl5 81.76(7) . .
Cl2 Bi1 Cl5 175.74(7) . .
Cl4 Bi1 Cl5 87.31(6) . .
Cl1 Bi1 Cl5 87.24(6) . .
Cl6 Bi2 Cl5 91.58(6) . .
Cl6 Bi2 Cl7 91.37(6) . 2_676
Cl5 Bi2 Cl7 85.71(6) . 2_676
Cl6 Bi2 Cl8 92.66(7) . .
Cl5 Bi2 Cl8 90.69(6) . .
Cl7 Bi2 Cl8 174.67(6) 2_676 .
Cl6 Bi2 Cl4 89.48(6) . 2_676
Cl5 Bi2 Cl4 166.76(6) . 2_676
Cl7 Bi2 Cl4 81.07(5) 2_676 2_676
Cl8 Bi2 Cl4 102.45(6) . 2_676
Cl6 Bi2 Cl7 173.27(6) . .
Cl5 Bi2 Cl7 85.00(5) . .
Cl7 Bi2 Cl7 82.61(5) 2_676 .
Cl8 Bi2 Cl7 93.18(6) . .
Cl4 Bi2 Cl7 92.54(5) 2_676 .
Cl10 Bi3 Cl11 90.20(6) . .
Cl10 Bi3 Cl1 93.06(8) . .
Cl11 Bi3 Cl1 89.89(6) . .
Cl10 Bi3 Cl9 92.91(7) . .
Cl11 Bi3 Cl9 91.06(6) . .
Cl1 Bi3 Cl9 173.95(6) . .
Cl10 Bi3 Cl8 90.22(7) . .
Cl11 Bi3 Cl8 176.25(6) . .
Cl1 Bi3 Cl8 93.81(6) . .
Cl9 Bi3 Cl8 85.21(5) . .
Cl10 Bi3 Cl9 172.13(6) . 2_675
Cl11 Bi3 Cl9 82.54(5) . 2_675
Cl1 Bi3 Cl9 89.98(6) . 2_675
Cl9 Bi3 Cl9 84.22(5) . 2_675
Cl8 Bi3 Cl9 96.82(5) . 2_675
Cl14 Bi4 Cl12 93.57(8) . .
Cl14 Bi4 Cl13 92.51(8) . .
Cl12 Bi4 Cl13 93.45(10) . .
C13 N1 Fe1 179.1(7) . .
C27 N2 Fe2 175.4(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.415(12) .
C1 C5 1.445(12) .
C1 C6 1.487(11) .
C1 Fe1 2.102(8) .
C2 C3 1.420(11) .
C2 C7 1.506(11) .
C2 Fe1 2.117(8) .
C3 C4 1.424(12) .
C3 C8 1.518(12) .
C3 Fe1 2.081(7) .
C4 C5 1.411(12) .
C4 C9 1.507(11) .
C4 Fe1 2.113(7) .
C5 C10 1.492(12) .
C5 Fe1 2.106(8) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 O1 1.149(12) .
C11 Fe1 1.778(9) .
C12 O2 1.153(11) .
C12 Fe1 1.788(9) .
C13 N1 1.131(11) .
C13 C14 1.436(13) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.421(11) .
C15 C19 1.426(12) .
C15 C20 1.483(11) .
C15 Fe2 2.098(7) .
C16 C17 1.407(11) .
C16 C21 1.506(12) .
C16 Fe2 2.123(7) .
C17 C18 1.424(13) .
C17 C22 1.502(11) .
C17 Fe2 2.119(7) .
C18 C19 1.412(12) .
C18 C23 1.506(12) .
C18 Fe2 2.088(7) .
C19 C24 1.495(12) .
C19 Fe2 2.105(8) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 O3 1.138(10) .
C25 Fe2 1.801(8) .
C26 O4 1.136(11) .
C26 Fe2 1.790(9) .
C27 N2 1.135(11) .
C27 C28 1.435(13) .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
Cl1 Bi3 2.6886(19) .
Cl1 Bi1 2.836(2) .
Cl2 Bi1 2.502(2) .
Cl3 Bi1 2.4624(19) .
Cl4 Bi1 2.623(2) .
Cl4 Bi2 2.9633(18) 2_676
Cl5 Bi2 2.5473(17) .
Cl5 Bi1 3.0490(19) .
Cl6 Bi2 2.4635(19) .
Cl7 Bi2 2.6903(18) 2_676
Cl7 Bi2 3.0877(18) .
Cl8 Bi2 2.7614(19) .
Cl8 Bi3 2.9938(19) .
Cl9 Bi3 2.7372(18) .
Cl9 Bi3 3.0857(19) 2_675
Cl10 Bi3 2.476(2) .
Cl11 Bi3 2.5466(18) .
Cl12 Bi4 2.475(2) .
Cl13 Bi4 2.482(2) .
Cl14 Bi4 2.468(2) .
Fe1 N1 1.925(7) .
Fe2 N2 1.917(7) .
Bi2 Cl7 2.6903(18) 2_676
Bi2 Cl4 2.9633(19) 2_676
Bi3 Cl9 3.0857(19) 2_675
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C5 C1 C2 C3 2.7(8) . .
C6 C1 C2 C3 177.9(8) . .
Fe1 C1 C2 C3 -58.3(5) . .
C5 C1 C2 C7 -177.1(7) . .
C6 C1 C2 C7 -1.9(13) . .
Fe1 C1 C2 C7 122.0(8) . .
C5 C1 C2 Fe1 60.9(5) . .
C6 C1 C2 Fe1 -123.9(8) . .
C1 C2 C3 C4 -3.5(8) . .
C7 C2 C3 C4 176.3(7) . .
Fe1 C2 C3 C4 -62.4(5) . .
C1 C2 C3 C8 -176.5(7) . .
C7 C2 C3 C8 3.3(12) . .
Fe1 C2 C3 C8 124.7(7) . .
C1 C2 C3 Fe1 58.9(5) . .
C7 C2 C3 Fe1 -121.4(8) . .
C2 C3 C4 C5 3.0(8) . .
C8 C3 C4 C5 175.9(7) . .
Fe1 C3 C4 C5 -59.6(5) . .
C2 C3 C4 C9 -173.8(7) . .
C8 C3 C4 C9 -0.9(12) . .
Fe1 C3 C4 C9 123.7(8) . .
C2 C3 C4 Fe1 62.5(5) . .
C8 C3 C4 Fe1 -124.5(7) . .
C3 C4 C5 C1 -1.3(8) . .
C9 C4 C5 C1 175.5(7) . .
Fe1 C4 C5 C1 -60.1(5) . .
C3 C4 C5 C10 -178.1(7) . .
C9 C4 C5 C10 -1.2(12) . .
Fe1 C4 C5 C10 123.2(8) . .
C3 C4 C5 Fe1 58.8(5) . .
C9 C4 C5 Fe1 -124.4(7) . .
C2 C1 C5 C4 -0.8(8) . .
C6 C1 C5 C4 -176.2(7) . .
Fe1 C1 C5 C4 60.7(5) . .
C2 C1 C5 C10 176.0(7) . .
C6 C1 C5 C10 0.6(12) . .
Fe1 C1 C5 C10 -122.5(8) . .
C2 C1 C5 Fe1 -61.5(5) . .
C6 C1 C5 Fe1 123.1(8) . .
C19 C15 C16 C17 1.9(8) . .
C20 C15 C16 C17 178.0(7) . .
Fe2 C15 C16 C17 -59.7(5) . .
C19 C15 C16 C21 -175.3(7) . .
C20 C15 C16 C21 0.8(12) . .
Fe2 C15 C16 C21 123.1(7) . .
C19 C15 C16 Fe2 61.6(5) . .
C20 C15 C16 Fe2 -122.3(8) . .
C15 C16 C17 C18 -0.3(8) . .
C21 C16 C17 C18 176.9(7) . .
Fe2 C16 C17 C18 -59.3(5) . .
C15 C16 C17 C22 -176.1(7) . .
C21 C16 C17 C22 1.1(12) . .
Fe2 C16 C17 C22 124.8(7) . .
C15 C16 C17 Fe2 59.1(5) . .
C21 C16 C17 Fe2 -123.7(7) . .
C16 C17 C18 C19 -1.5(8) . .
C22 C17 C18 C19 174.3(7) . .
Fe2 C17 C18 C19 -61.9(5) . .
C16 C17 C18 C23 -173.6(7) . .
C22 C17 C18 C23 2.2(12) . .
Fe2 C17 C18 C23 126.0(8) . .
C16 C17 C18 Fe2 60.4(5) . .
C22 C17 C18 Fe2 -123.8(8) . .
C17 C18 C19 C15 2.7(8) . .
C23 C18 C19 C15 174.5(7) . .
Fe2 C18 C19 C15 -59.5(5) . .
C17 C18 C19 C24 -176.2(7) . .
C23 C18 C19 C24 -4.4(13) . .
Fe2 C18 C19 C24 121.6(8) . .
C17 C18 C19 Fe2 62.2(5) . .
C23 C18 C19 Fe2 -126.0(8) . .
C16 C15 C19 C18 -2.8(8) . .
C20 C15 C19 C18 -178.9(7) . .
Fe2 C15 C19 C18 59.4(5) . .
C16 C15 C19 C24 176.1(7) . .
C20 C15 C19 C24 0.0(12) . .
Fe2 C15 C19 C24 -121.7(8) . .
C16 C15 C19 Fe2 -62.2(5) . .
C20 C15 C19 Fe2 121.7(8) . .
O1 C11 Fe1 C12 -66(14) . .
O1 C11 Fe1 N1 -161(14) . .
O1 C11 Fe1 C3 36(14) . .
O1 C11 Fe1 C1 105(14) . .
O1 C11 Fe1 C5 96(14) . .
O1 C11 Fe1 C4 25(15) . .
O1 C11 Fe1 C2 73(14) . .
O2 C12 Fe1 C11 84(11) . .
O2 C12 Fe1 N1 -180(100) . .
O2 C12 Fe1 C3 -18(11) . .
O2 C12 Fe1 C1 -76(11) . .
O2 C12 Fe1 C5 -87(11) . .
O2 C12 Fe1 C4 -56(11) . .
O2 C12 Fe1 C2 -6(11) . .
C2 C3 Fe1 C11 72.9(6) . .
C4 C3 Fe1 C11 -169.8(6) . .
C8 C3 Fe1 C11 -48.2(8) . .
C2 C3 Fe1 C12 167.6(5) . .
C4 C3 Fe1 C12 -75.0(6) . .
C8 C3 Fe1 C12 46.6(8) . .
C2 C3 Fe1 N1 -62.6(9) . .
C4 C3 Fe1 N1 54.8(9) . .
C8 C3 Fe1 N1 176.4(7) . .
C2 C3 Fe1 C1 -36.6(5) . .
C4 C3 Fe1 C1 80.8(5) . .
C8 C3 Fe1 C1 -157.6(8) . .
C2 C3 Fe1 C5 -80.5(5) . .
C4 C3 Fe1 C5 36.8(5) . .
C8 C3 Fe1 C5 158.4(8) . .
C2 C3 Fe1 C4 -117.3(7) . .
C8 C3 Fe1 C4 121.6(9) . .
C4 C3 Fe1 C2 117.3(7) . .
C8 C3 Fe1 C2 -121.0(9) . .
C2 C1 Fe1 C11 -56.4(6) . .
C5 C1 Fe1 C11 -173.9(5) . .
C6 C1 Fe1 C11 66.6(8) . .
C2 C1 Fe1 C12 102.5(9) . .
C5 C1 Fe1 C12 -15.0(11) . .
C6 C1 Fe1 C12 -134.6(10) . .
C2 C1 Fe1 N1 -153.3(5) . .
C5 C1 Fe1 N1 89.2(5) . .
C6 C1 Fe1 N1 -30.4(8) . .
C2 C1 Fe1 C3 36.9(4) . .
C5 C1 Fe1 C3 -80.6(5) . .
C6 C1 Fe1 C3 159.9(8) . .
C2 C1 Fe1 C5 117.5(6) . .
C6 C1 Fe1 C5 -119.5(9) . .
C2 C1 Fe1 C4 80.3(5) . .
C5 C1 Fe1 C4 -37.2(5) . .
C6 C1 Fe1 C4 -156.7(8) . .
C5 C1 Fe1 C2 -117.5(6) . .
C6 C1 Fe1 C2 123.0(9) . .
C4 C5 Fe1 C11 -106.4(9) . .
C1 C5 Fe1 C11 12.1(10) . .
C10 C5 Fe1 C11 131.4(9) . .
C4 C5 Fe1 C12 54.3(6) . .
C1 C5 Fe1 C12 172.8(5) . .
C10 C5 Fe1 C12 -67.9(8) . .
C4 C5 Fe1 N1 149.8(5) . .
C1 C5 Fe1 N1 -91.7(5) . .
C10 C5 Fe1 N1 27.6(8) . .
C4 C5 Fe1 C3 -37.4(5) . .
C1 C5 Fe1 C3 81.1(5) . .
C10 C5 Fe1 C3 -159.6(9) . .
C4 C5 Fe1 C1 -118.5(7) . .
C10 C5 Fe1 C1 119.3(9) . .
C1 C5 Fe1 C4 118.5(7) . .
C10 C5 Fe1 C4 -122.2(10) . .
C4 C5 Fe1 C2 -80.7(5) . .
C1 C5 Fe1 C2 37.8(5) . .
C10 C5 Fe1 C2 157.1(8) . .
C5 C4 Fe1 C11 135.2(7) . .
C3 C4 Fe1 C11 15.8(8) . .
C9 C4 Fe1 C11 -104.8(10) . .
C5 C4 Fe1 C12 -132.2(6) . .
C3 C4 Fe1 C12 108.4(6) . .
C9 C4 Fe1 C12 -12.2(9) . .
C5 C4 Fe1 N1 -37.2(6) . .
C3 C4 Fe1 N1 -156.6(4) . .
C9 C4 Fe1 N1 82.8(9) . .
C5 C4 Fe1 C3 119.4(7) . .
C9 C4 Fe1 C3 -120.6(11) . .
C5 C4 Fe1 C1 38.2(5) . .
C3 C4 Fe1 C1 -81.2(5) . .
C9 C4 Fe1 C1 158.2(10) . .
C3 C4 Fe1 C5 -119.4(7) . .
C9 C4 Fe1 C5 120.0(11) . .
C5 C4 Fe1 C2 81.2(5) . .
C3 C4 Fe1 C2 -38.2(4) . .
C9 C4 Fe1 C2 -158.8(10) . .
C1 C2 Fe1 C11 129.5(5) . .
C3 C2 Fe1 C11 -110.5(6) . .
C7 C2 Fe1 C11 8.8(8) . .
C1 C2 Fe1 C12 -138.8(6) . .
C3 C2 Fe1 C12 -18.7(8) . .
C7 C2 Fe1 C12 100.5(8) . .
C1 C2 Fe1 N1 33.6(6) . .
C3 C2 Fe1 N1 153.7(5) . .
C7 C2 Fe1 N1 -87.1(8) . .
C1 C2 Fe1 C3 -120.0(7) . .
C7 C2 Fe1 C3 119.3(9) . .
C3 C2 Fe1 C1 120.0(7) . .
C7 C2 Fe1 C1 -120.7(9) . .
C1 C2 Fe1 C5 -38.7(5) . .
C3 C2 Fe1 C5 81.3(5) . .
C7 C2 Fe1 C5 -159.4(8) . .
C1 C2 Fe1 C4 -81.6(5) . .
C3 C2 Fe1 C4 38.4(5) . .
C7 C2 Fe1 C4 157.6(8) . .
O4 C26 Fe2 C25 130(40) . .
O4 C26 Fe2 N2 -134(40) . .
O4 C26 Fe2 C18 32(40) . .
O4 C26 Fe2 C15 -38(40) . .
O4 C26 Fe2 C19 -3(40) . .
O4 C26 Fe2 C17 37(41) . .
O4 C26 Fe2 C16 -38(41) . .
O3 C25 Fe2 C26 -112(9) . .
O3 C25 Fe2 N2 155(9) . .
O3 C25 Fe2 C18 -5(9) . .
O3 C25 Fe2 C15 41(9) . .
O3 C25 Fe2 C19 -20(9) . .
O3 C25 Fe2 C17 34(9) . .
O3 C25 Fe2 C16 61(9) . .
C19 C18 Fe2 C26 -66.4(6) . .
C17 C18 Fe2 C26 176.3(5) . .
C23 C18 Fe2 C26 56.4(10) . .
C19 C18 Fe2 C25 -162.4(5) . .
C17 C18 Fe2 C25 80.2(5) . .
C23 C18 Fe2 C25 -39.6(10) . .
C19 C18 Fe2 N2 77.5(10) . .
C17 C18 Fe2 N2 -39.9(10) . .
C23 C18 Fe2 N2 -159.7(9) . .
C19 C18 Fe2 C15 37.3(5) . .
C17 C18 Fe2 C15 -80.1(5) . .
C23 C18 Fe2 C15 160.1(11) . .
C17 C18 Fe2 C19 -117.4(7) . .
C23 C18 Fe2 C19 122.8(12) . .
C19 C18 Fe2 C17 117.4(7) . .
C23 C18 Fe2 C17 -119.8(12) . .
C19 C18 Fe2 C16 80.4(5) . .
C17 C18 Fe2 C16 -37.0(4) . .
C23 C18 Fe2 C16 -156.8(11) . .
C16 C15 Fe2 C26 -179.7(5) . .
C19 C15 Fe2 C26 63.5(5) . .
C20 C15 Fe2 C26 -58.2(9) . .
C16 C15 Fe2 C25 28.8(10) . .
C19 C15 Fe2 C25 -88.0(10) . .
C20 C15 Fe2 C25 150.2(9) . .
C16 C15 Fe2 N2 -85.3(5) . .
C19 C15 Fe2 N2 157.9(5) . .
C20 C15 Fe2 N2 36.2(8) . .
C16 C15 Fe2 C18 79.8(5) . .
C19 C15 Fe2 C18 -37.0(5) . .
C20 C15 Fe2 C18 -158.7(9) . .
C16 C15 Fe2 C19 116.8(6) . .
C20 C15 Fe2 C19 -121.7(10) . .
C16 C15 Fe2 C17 36.5(5) . .
C19 C15 Fe2 C17 -80.3(5) . .
C20 C15 Fe2 C17 157.9(9) . .
C19 C15 Fe2 C16 -116.8(6) . .
C20 C15 Fe2 C16 121.5(10) . .
C18 C19 Fe2 C26 118.6(6) . .
C15 C19 Fe2 C26 -122.0(5) . .
C24 C19 Fe2 C26 -2.5(9) . .
C18 C19 Fe2 C25 24.4(7) . .
C15 C19 Fe2 C25 143.8(5) . .
C24 C19 Fe2 C25 -96.7(9) . .
C18 C19 Fe2 N2 -149.2(5) . .
C15 C19 Fe2 N2 -29.8(6) . .
C24 C19 Fe2 N2 89.7(9) . .
C15 C19 Fe2 C18 119.4(7) . .
C24 C19 Fe2 C18 -121.1(11) . .
C18 C19 Fe2 C15 -119.4(7) . .
C24 C19 Fe2 C15 119.5(10) . .
C18 C19 Fe2 C17 -38.3(5) . .
C15 C19 Fe2 C17 81.1(5) . .
C24 C19 Fe2 C17 -159.4(9) . .
C18 C19 Fe2 C16 -81.0(5) . .
C15 C19 Fe2 C16 38.4(4) . .
C24 C19 Fe2 C16 157.9(9) . .
C16 C17 Fe2 C26 -125.2(7) . .
C18 C17 Fe2 C26 -6.4(9) . .
C22 C17 Fe2 C26 114.1(10) . .
C16 C17 Fe2 C25 139.7(5) . .
C18 C17 Fe2 C25 -101.5(5) . .
C22 C17 Fe2 C25 19.0(9) . .
C16 C17 Fe2 N2 44.0(5) . .
C18 C17 Fe2 N2 162.8(4) . .
C22 C17 Fe2 N2 -76.7(9) . .
C16 C17 Fe2 C18 -118.8(7) . .
C22 C17 Fe2 C18 120.5(10) . .
C16 C17 Fe2 C15 -37.0(5) . .
C18 C17 Fe2 C15 81.8(5) . .
C22 C17 Fe2 C15 -157.7(10) . .
C16 C17 Fe2 C19 -80.6(5) . .
C18 C17 Fe2 C19 38.1(5) . .
C22 C17 Fe2 C19 158.6(9) . .
C18 C17 Fe2 C16 118.8(7) . .
C22 C17 Fe2 C16 -120.7(10) . .
C17 C16 Fe2 C26 120.4(7) . .
C15 C16 Fe2 C26 0.6(9) . .
C21 C16 Fe2 C26 -118.9(9) . .
C17 C16 Fe2 C25 -46.7(6) . .
C15 C16 Fe2 C25 -166.5(5) . .
C21 C16 Fe2 C25 74.0(8) . .
C17 C16 Fe2 N2 -143.4(5) . .
C15 C16 Fe2 N2 96.8(5) . .
C21 C16 Fe2 N2 -22.7(7) . .
C17 C16 Fe2 C18 37.7(5) . .
C15 C16 Fe2 C18 -82.1(5) . .
C21 C16 Fe2 C18 158.4(8) . .
C17 C16 Fe2 C15 119.8(7) . .
C21 C16 Fe2 C15 -119.5(9) . .
C17 C16 Fe2 C19 81.1(5) . .
C15 C16 Fe2 C19 -38.7(5) . .
C21 C16 Fe2 C19 -158.2(8) . .
C15 C16 Fe2 C17 -119.8(7) . .
C21 C16 Fe2 C17 120.7(9) . .
Bi2 Cl4 Bi1 Cl3 157.36(8) 2_676 .
Bi2 Cl4 Bi1 Cl2 -108.52(8) 2_676 .
Bi2 Cl4 Bi1 Cl1 107.0(5) 2_676 .
Bi2 Cl4 Bi1 Cl5 75.68(6) 2_676 .
Bi3 Cl1 Bi1 Cl3 -154.11(11) . .
Bi3 Cl1 Bi1 Cl2 112.11(11) . .
Bi3 Cl1 Bi1 Cl4 -103.5(5) . .
Bi3 Cl1 Bi1 Cl5 -72.13(9) . .
Bi2 Cl5 Bi1 Cl3 176.55(8) . .
Bi2 Cl5 Bi1 Cl2 -172.0(9) . .
Bi2 Cl5 Bi1 Cl4 -91.56(7) . .
Bi2 Cl5 Bi1 Cl1 91.76(7) . .
Bi1 Cl5 Bi2 Cl6 -174.12(7) . .
Bi1 Cl5 Bi2 Cl7 94.63(6) . 2_676
Bi1 Cl5 Bi2 Cl8 -81.44(7) . .
Bi1 Cl5 Bi2 Cl4 91.4(3) . 2_676
Bi1 Cl5 Bi2 Cl7 11.69(6) . .
Bi3 Cl8 Bi2 Cl6 148.59(10) . .
Bi3 Cl8 Bi2 Cl5 56.98(10) . .
Bi3 Cl8 Bi2 Cl7 9.5(7) . 2_676
Bi3 Cl8 Bi2 Cl4 -121.36(9) . 2_676
Bi3 Cl8 Bi2 Cl7 -28.05(10) . .
Bi2 Cl7 Bi2 Cl6 26.7(5) 2_676 .
Bi2 Cl7 Bi2 Cl5 86.31(6) 2_676 .
Bi2 Cl7 Bi2 Cl7 0.0 2_676 2_676
Bi2 Cl7 Bi2 Cl8 176.72(6) 2_676 .
Bi2 Cl7 Bi2 Cl4 -80.65(5) 2_676 2_676
Bi1 Cl1 Bi3 Cl10 -43.13(10) . .
Bi1 Cl1 Bi3 Cl11 -133.32(10) . .
Bi1 Cl1 Bi3 Cl9 127.7(5) . .
Bi1 Cl1 Bi3 Cl8 47.30(10) . .
Bi1 Cl1 Bi3 Cl9 144.14(9) . 2_675
Bi3 Cl9 Bi3 Cl10 -172.65(6) 2_675 .
Bi3 Cl9 Bi3 Cl11 -82.40(6) 2_675 .
Bi3 Cl9 Bi3 Cl1 16.5(6) 2_675 .
Bi3 Cl9 Bi3 Cl8 97.37(6) 2_675 .
Bi3 Cl9 Bi3 Cl9 0.0 2_675 2_675
Bi2 Cl8 Bi3 Cl10 57.05(11) . .
Bi2 Cl8 Bi3 Cl11 153.5(9) . .
Bi2 Cl8 Bi3 Cl1 -36.03(11) . .
Bi2 Cl8 Bi3 Cl9 149.95(10) . .
Bi2 Cl8 Bi3 Cl9 -126.47(10) . 2_675
C14 C13 N1 Fe1 -173(100) . .
C11 Fe1 N1 C13 129(46) . .
C12 Fe1 N1 C13 36(46) . .
C3 Fe1 N1 C13 -95(46) . .
C1 Fe1 N1 C13 -118(46) . .
C5 Fe1 N1 C13 -78(46) . .
C4 Fe1 N1 C13 -56(46) . .
C2 Fe1 N1 C13 -139(46) . .
C28 C27 N2 Fe2 35(18) . .
C26 Fe2 N2 C27 -82(8) . .
C25 Fe2 N2 C27 12(8) . .
C18 Fe2 N2 C27 133(8) . .
C15 Fe2 N2 C27 169(8) . .
C19 Fe2 N2 C27 -172(8) . .
C17 Fe2 N2 C27 104(8) . .
C16 Fe2 N2 C27 130(8) . .
