#------------------------------------------------------------------------------
#$Date: 2016-02-04 02:11:27 +0200 (Thu, 04 Feb 2016) $
#$Revision: 175544 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/46/4344644.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4344644
loop_
_publ_author_name
'An, Ran'
'Zhao, Hui'
'Hu, Huai-Ming'
'Wang, Xiaofang'
'Yang, Meng-Lin'
'Xue, Ganglin'
_publ_contact_author
;
    Porf. Huai-Ming Hu
    College of Chemistry and Materials Science
    Northwest University
    Xi'an 710127
    People's Republic of China
;
_publ_section_title
;
 Synthesis, Structure, White-Light Emission, and Temperature Recognition
 Properties of Eu/Tb Mixed Coordination Polymers.
;
_journal_issue                   2
_journal_name_full               'Inorganic chemistry'
_journal_page_first              871
_journal_page_last               876
_journal_paper_doi               10.1021/acs.inorgchem.5b02375
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C24 H19 Eu N4 O8 S'
_chemical_formula_sum            'C24 H19 Eu N4 O8 S'
_chemical_formula_weight         675.45
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-12-17 # Formatted by publCIF

;
_cell_angle_alpha                94.943(5)
_cell_angle_beta                 91.170(4)
_cell_angle_gamma                98.950(4)
_cell_formula_units_Z            2
_cell_length_a                   8.958(2)
_cell_length_b                   9.063(2)
_cell_length_c                   14.401(4)
_cell_measurement_reflns_used    2521
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.40
_cell_measurement_theta_min      2.66
_cell_volume                     1150.0(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0216
_diffrn_reflns_av_sigmaI/netI    0.0481
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5701
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.28
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.880
_exptl_absorpt_correction_T_max  0.745
_exptl_absorpt_correction_T_min  0.561
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.951
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             668
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.441
_refine_diff_density_min         -0.579
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         3967
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.0345
_refine_ls_R_factor_gt           0.0305
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0235P)²+1.2832P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0642
_refine_ls_wR_factor_ref         0.0665
_reflns_number_gt                3631
_reflns_number_total             3967
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b02375_si_004.cif
_cod_data_source_block           nw1811_0m
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4344644
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu -0.05213(2) 0.43442(2) 0.850230(15) 0.01933(8) Uani 1 1 d .
S1 S 0.45975(12) 0.58173(13) 0.23358(8) 0.0244(3) Uani 1 1 d .
N1 N -0.0421(4) 0.6362(4) 0.7318(2) 0.0237(8) Uani 1 1 d .
N2 N 0.0724(4) 0.3805(4) 0.6936(2) 0.0219(8) Uani 1 1 d .
N3 N 0.2255(4) 0.8355(4) 0.4646(2) 0.0251(9) Uani 1 1 d .
N4 N 0.3240(4) 0.6256(4) 0.4336(2) 0.0258(9) Uani 1 1 d .
H4 H 0.3768 0.5635 0.4071 0.031 Uiso 1 1 calc R
O1 O 0.2982(3) 0.5503(4) 0.2101(2) 0.0296(8) Uani 1 1 d .
O2 O 0.4985(4) 0.4997(4) 0.3105(2) 0.0327(8) Uani 1 1 d .
O3 O 0.5504(4) 0.5613(4) 0.1536(2) 0.0367(8) Uani 1 1 d .
O4 O 0.1258(3) 0.2774(4) 0.8955(2) 0.0286(7) Uani 1 1 d .
O5 O 0.0976(4) 0.3907(4) 1.0330(2) 0.0326(8) Uani 1 1 d .
O6 O 0.1679(3) -0.1761(3) 1.1893(2) 0.0271(7) Uani 1 1 d .
O7 O 0.2142(4) -0.2764(4) 1.0522(2) 0.0326(8) Uani 1 1 d .
C1 C -0.1094(5) 0.7556(5) 0.7471(3) 0.0319(11) Uani 1 1 d .
H1 H -0.1708 0.7599 0.7982 0.038 Uiso 1 1 calc R
C2 C -0.0944(5) 0.8742(5) 0.6923(3) 0.0294(11) Uani 1 1 d .
H2 H -0.1452 0.9550 0.7058 0.035 Uiso 1 1 calc R
C3 C -0.0029(5) 0.8700(5) 0.6175(3) 0.0252(10) Uani 1 1 d .
H3 H 0.0104 0.9488 0.5797 0.030 Uiso 1 1 calc R
C4 C 0.0700(5) 0.7468(5) 0.5986(3) 0.0205(9) Uani 1 1 d .
C5 C 0.1700(5) 0.7310(5) 0.5230(3) 0.0228(10) Uani 1 1 d .
C6 C 0.2295(5) 0.5995(5) 0.5052(3) 0.0220(10) Uani 1 1 d .
C7 C 0.1980(5) 0.4743(5) 0.5582(3) 0.0215(10) Uani 1 1 d .
C8 C 0.2468(5) 0.3364(5) 0.5390(3) 0.0266(10) Uani 1 1 d .
H8 H 0.3054 0.3209 0.4876 0.032 Uiso 1 1 calc R
C9 C 0.2088(5) 0.2248(5) 0.5954(3) 0.0270(10) Uani 1 1 d .
H9 H 0.2400 0.1320 0.5831 0.032 Uiso 1 1 calc R
C10 C 0.1216(5) 0.2528(5) 0.6724(3) 0.0256(10) Uani 1 1 d .
H10 H 0.0967 0.1763 0.7111 0.031 Uiso 1 1 calc R
C11 C 0.1078(5) 0.4915(5) 0.6363(3) 0.0197(9) Uani 1 1 d .
C12 C 0.0453(5) 0.6285(5) 0.6563(3) 0.0200(9) Uani 1 1 d .
C13 C 0.3196(5) 0.7683(5) 0.4116(3) 0.0256(10) Uani 1 1 d .
C14 C 0.4224(5) 0.8448(5) 0.3465(3) 0.0229(10) Uani 1 1 d .
C15 C 0.4537(5) 1.0000(6) 0.3643(3) 0.0304(11) Uani 1 1 d .
H15 H 0.4042 1.0462 0.4120 0.037 Uiso 1 1 calc R
C16 C 0.5551(6) 1.0873(6) 0.3139(3) 0.0355(12) Uani 1 1 d .
H16 H 0.5736 1.1909 0.3273 0.043 Uiso 1 1 calc R
C17 C 0.6292(5) 1.0198(6) 0.2432(3) 0.0319(12) Uani 1 1 d .
H17 H 0.6993 1.0778 0.2091 0.038 Uiso 1 1 calc R
C18 C 0.5995(5) 0.8665(6) 0.2229(3) 0.0282(11) Uani 1 1 d .
H18 H 0.6503 0.8218 0.1753 0.034 Uiso 1 1 calc R
C19 C 0.4951(5) 0.7779(5) 0.2723(3) 0.0230(10) Uani 1 1 d .
C20 C 0.1633(5) 0.3041(5) 0.9798(3) 0.0219(10) Uani 1 1 d .
C21 C 0.2806(5) 0.2251(5) 1.0207(3) 0.0215(10) Uani 1 1 d .
H21A H 0.3182 0.2767 1.0804 0.026 Uiso 1 1 calc R
H21B H 0.3649 0.2254 0.9795 0.026 Uiso 1 1 calc R
C22 C 0.2111(5) 0.0647(5) 1.0336(3) 0.0300(11) Uani 1 1 d .
H22A H 0.1165 0.0655 1.0651 0.036 Uiso 1 1 calc R
H22B H 0.1882 0.0103 0.9727 0.036 Uiso 1 1 calc R
C23 C 0.3118(5) -0.0175(5) 1.0888(3) 0.0307(11) Uani 1 1 d .
H23A H 0.3989 -0.0341 1.0528 0.037 Uiso 1 1 calc R
H23B H 0.3479 0.0435 1.1459 0.037 Uiso 1 1 calc R
C24 C 0.2284(5) -0.1642(5) 1.1121(3) 0.0241(10) Uani 1 1 d .
O8 O 0.1977(4) 0.5969(4) 0.8705(2) 0.0294(8) Uani 1 1 d D
H8A H 0.212(6) 0.650(5) 0.921(2) 0.035 Uiso 1 1 d D
H8B H 0.279(4) 0.563(5) 0.858(3) 0.035 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O1 86.05(11) 2_567 2_566
O5 Eu1 O4 113.67(11) 2_567 .
O1 Eu1 O4 147.75(11) 2_566 .
O5 Eu1 O6 131.56(11) 2_567 2_557
O1 Eu1 O6 75.31(11) 2_566 2_557
O4 Eu1 O6 72.55(11) . 2_557
O5 Eu1 O7 79.39(12) 2_567 2_557
O1 Eu1 O7 77.70(11) 2_566 2_557
O4 Eu1 O7 81.15(11) . 2_557
O6 Eu1 O7 53.29(11) 2_557 2_557
O5 Eu1 O8 78.58(11) 2_567 .
O1 Eu1 O8 137.75(11) 2_566 .
O4 Eu1 O8 73.40(11) . .
O6 Eu1 O8 141.82(11) 2_557 .
O7 Eu1 O8 135.73(11) 2_557 .
O5 Eu1 N2 147.66(12) 2_567 .
O1 Eu1 N2 97.97(11) 2_566 .
O4 Eu1 N2 79.06(11) . .
O6 Eu1 N2 79.99(11) 2_557 .
O7 Eu1 N2 132.88(11) 2_557 .
O8 Eu1 N2 77.07(11) . .
O5 Eu1 N1 89.62(12) 2_567 .
O1 Eu1 N1 68.75(11) 2_566 .
O4 Eu1 N1 132.86(11) . .
O6 Eu1 N1 122.29(11) 2_557 .
O7 Eu1 N1 145.33(11) 2_557 .
O8 Eu1 N1 72.01(11) . .
N2 Eu1 N1 62.75(11) . .
O5 Eu1 C24 105.82(13) 2_567 2_557
O1 Eu1 C24 75.49(12) 2_566 2_557
O4 Eu1 C24 74.65(12) . 2_557
O6 Eu1 C24 26.50(11) 2_557 2_557
O7 Eu1 C24 26.80(12) 2_557 2_557
O8 Eu1 C24 146.56(12) . 2_557
N2 Eu1 C24 106.24(13) . 2_557
N1 Eu1 C24 139.85(12) . 2_557
O5 Eu1 O5 68.20(12) 2_567 .
O1 Eu1 O5 138.55(10) 2_566 .
O4 Eu1 O5 45.94(9) . .
O6 Eu1 O5 97.52(9) 2_557 .
O7 Eu1 O5 66.33(10) 2_557 .
O8 Eu1 O5 69.93(10) . .
N2 Eu1 O5 121.32(10) . .
N1 Eu1 O5 138.87(10) . .
C24 Eu1 O5 80.88(11) 2_557 .
O5 Eu1 Eu1 39.33(8) 2_567 2_567
O1 Eu1 Eu1 118.41(8) 2_566 2_567
O4 Eu1 Eu1 74.58(7) . 2_567
O6 Eu1 Eu1 115.74(7) 2_557 2_567
O7 Eu1 Eu1 68.30(8) 2_557 2_567
O8 Eu1 Eu1 70.29(8) . 2_567
N2 Eu1 Eu1 142.58(8) . 2_567
N1 Eu1 Eu1 120.72(8) . 2_567
C24 Eu1 Eu1 91.92(9) 2_557 2_567
O5 Eu1 Eu1 28.87(6) . 2_567
O3 S1 O2 113.1(2) . .
O3 S1 O1 112.5(2) . .
O2 S1 O1 111.5(2) . .
O3 S1 C19 106.8(2) . .
O2 S1 C19 107.8(2) . .
O1 S1 C19 104.5(2) . .
C1 N1 C12 117.9(4) . .
C1 N1 Eu1 121.7(3) . .
C12 N1 Eu1 120.1(3) . .
C10 N2 C11 117.7(4) . .
C10 N2 Eu1 121.4(3) . .
C11 N2 Eu1 120.2(3) . .
C13 N3 C5 104.2(4) . .
C6 N4 C13 107.5(4) . .
C6 N4 H4 126.3 . .
C13 N4 H4 126.3 . .
S1 O1 Eu1 163.0(2) . 2_566
C20 O4 Eu1 111.2(3) . .
C20 O5 Eu1 162.3(3) . 2_567
C20 O5 Eu1 81.3(3) . .
Eu1 O5 Eu1 111.80(12) 2_567 .
C24 O6 Eu1 93.8(3) . 2_557
C24 O7 Eu1 93.1(3) . 2_557
N1 C1 C2 124.3(4) . .
N1 C1 H1 117.8 . .
C2 C1 H1 117.8 . .
C3 C2 C1 118.4(4) . .
C3 C2 H2 120.8 . .
C1 C2 H2 120.8 . .
C2 C3 C4 119.4(4) . .
C2 C3 H3 120.3 . .
C4 C3 H3 120.3 . .
C3 C4 C12 118.8(4) . .
C3 C4 C5 124.3(4) . .
C12 C4 C5 116.9(4) . .
N3 C5 C6 111.4(4) . .
N3 C5 C4 128.1(4) . .
C6 C5 C4 120.4(4) . .
N4 C6 C5 104.9(4) . .
N4 C6 C7 131.2(4) . .
C5 C6 C7 123.8(4) . .
C8 C7 C11 117.8(4) . .
C8 C7 C6 125.7(4) . .
C11 C7 C6 116.5(4) . .
C9 C8 C7 120.0(4) . .
C9 C8 H8 120.0 . .
C7 C8 H8 120.0 . .
C8 C9 C10 118.3(4) . .
C8 C9 H9 120.9 . .
C10 C9 H9 120.9 . .
N2 C10 C9 124.2(4) . .
N2 C10 H10 117.9 . .
C9 C10 H10 117.9 . .
N2 C11 C7 122.0(4) . .
N2 C11 C12 117.6(4) . .
C7 C11 C12 120.4(4) . .
N1 C12 C4 121.2(4) . .
N1 C12 C11 117.1(4) . .
C4 C12 C11 121.7(4) . .
N3 C13 N4 112.0(4) . .
N3 C13 C14 124.0(4) . .
N4 C13 C14 123.5(4) . .
C15 C14 C19 117.9(4) . .
C15 C14 C13 114.9(4) . .
C19 C14 C13 127.2(4) . .
C16 C15 C14 122.3(5) . .
C16 C15 H15 118.8 . .
C14 C15 H15 118.8 . .
C15 C16 C17 119.2(5) . .
C15 C16 H16 120.4 . .
C17 C16 H16 120.4 . .
C18 C17 C16 120.0(5) . .
C18 C17 H17 120.0 . .
C16 C17 H17 120.0 . .
C17 C18 C19 121.1(4) . .
C17 C18 H18 119.5 . .
C19 C18 H18 119.5 . .
C18 C19 C14 119.4(4) . .
C18 C19 S1 116.1(3) . .
C14 C19 S1 124.5(3) . .
O4 C20 O5 121.0(4) . .
O4 C20 C21 119.7(4) . .
O5 C20 C21 119.2(4) . .
C20 C21 C22 109.3(3) . .
C20 C21 H21A 109.8 . .
C22 C21 H21A 109.8 . .
C20 C21 H21B 109.8 . .
C22 C21 H21B 109.8 . .
H21A C21 H21B 108.3 . .
C23 C22 C21 113.6(4) . .
C23 C22 H22A 108.8 . .
C21 C22 H22A 108.8 . .
C23 C22 H22B 108.8 . .
C21 C22 H22B 108.8 . .
H22A C22 H22B 107.7 . .
C24 C23 C22 110.9(4) . .
C24 C23 H23A 109.5 . .
C22 C23 H23A 109.5 . .
C24 C23 H23B 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 108.1 . .
O6 C24 O7 119.8(4) . .
O6 C24 C23 120.6(4) . .
O7 C24 C23 119.6(4) . .
O6 C24 Eu1 59.7(2) . 2_557
O7 C24 Eu1 60.1(2) . 2_557
C23 C24 Eu1 175.7(3) . 2_557
Eu1 O8 H8A 115(4) . .
Eu1 O8 H8B 122(4) . .
H8A O8 H8B 108(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.296(3) 2_567
Eu1 O1 2.381(3) 2_566
Eu1 O4 2.411(3) .
Eu1 O6 2.423(3) 2_557
Eu1 O7 2.432(3) 2_557
Eu1 O8 2.477(3) .
Eu1 N2 2.580(4) .
Eu1 N1 2.599(4) .
Eu1 C24 2.801(5) 2_557
Eu1 O5 3.014(3) .
Eu1 Eu1 4.4158(12) 2_567
S1 O3 1.438(3) .
S1 O2 1.452(3) .
S1 O1 1.457(3) .
S1 C19 1.794(5) .
N1 C1 1.323(6) .
N1 C12 1.356(5) .
N2 C10 1.315(6) .
N2 C11 1.359(5) .
N3 C13 1.331(6) .
N3 C5 1.363(6) .
N4 C6 1.360(5) .
N4 C13 1.364(6) .
N4 H4 0.8600 .
O1 Eu1 2.381(3) 2_566
O4 C20 1.246(5) .
O5 C20 1.268(5) .
O5 Eu1 2.296(3) 2_567
O6 C24 1.253(5) .
O6 Eu1 2.423(3) 2_557
O7 C24 1.265(5) .
O7 Eu1 2.432(3) 2_557
C1 C2 1.379(6) .
C1 H1 0.9300 .
C2 C3 1.368(6) .
C2 H2 0.9300 .
C3 C4 1.388(6) .
C3 H3 0.9300 .
C4 C12 1.405(6) .
C4 C5 1.437(6) .
C5 C6 1.386(6) .
C6 C7 1.417(6) .
C7 C8 1.394(6) .
C7 C11 1.410(6) .
C8 C9 1.359(6) .
C8 H8 0.9300 .
C9 C10 1.397(6) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.449(6) .
C13 C14 1.469(6) .
C14 C15 1.392(7) .
C14 C19 1.404(6) .
C15 C16 1.370(7) .
C15 H15 0.9300 .
C16 C17 1.378(7) .
C16 H16 0.9300 .
C17 C18 1.378(7) .
C17 H17 0.9300 .
C18 C19 1.384(6) .
C18 H18 0.9300 .
C20 C21 1.498(6) .
C21 C22 1.518(6) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 C23 1.512(6) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 C24 1.489(6) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 Eu1 2.801(5) 2_557
O8 H8A 0.84(2) .
O8 H8B 0.845(19) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Eu1 N1 C1 -23.3(4) 2_567 .
O1 Eu1 N1 C1 62.6(4) 2_566 .
O4 Eu1 N1 C1 -146.1(3) . .
O6 Eu1 N1 C1 118.0(4) 2_557 .
O7 Eu1 N1 C1 47.2(5) 2_557 .
O8 Eu1 N1 C1 -101.4(4) . .
N2 Eu1 N1 C1 174.2(4) . .
C24 Eu1 N1 C1 91.2(4) 2_557 .
O5 Eu1 N1 C1 -78.4(4) . .
Eu1 Eu1 N1 C1 -48.7(4) 2_567 .
O5 Eu1 N1 C12 150.4(3) 2_567 .
O1 Eu1 N1 C12 -123.7(3) 2_566 .
O4 Eu1 N1 C12 27.6(4) . .
O6 Eu1 N1 C12 -68.3(3) 2_557 .
O7 Eu1 N1 C12 -139.1(3) 2_557 .
O8 Eu1 N1 C12 72.3(3) . .
N2 Eu1 N1 C12 -12.2(3) . .
C24 Eu1 N1 C12 -95.1(3) 2_557 .
O5 Eu1 N1 C12 95.3(3) . .
Eu1 Eu1 N1 C12 125.0(3) 2_567 .
O5 Eu1 N2 C10 149.4(3) 2_567 .
O1 Eu1 N2 C10 -115.4(3) 2_566 .
O4 Eu1 N2 C10 32.0(3) . .
O6 Eu1 N2 C10 -41.9(3) 2_557 .
O7 Eu1 N2 C10 -34.8(4) 2_557 .
O8 Eu1 N2 C10 107.3(3) . .
N1 Eu1 N2 C10 -176.5(4) . .
C24 Eu1 N2 C10 -38.3(4) 2_557 .
O5 Eu1 N2 C10 50.8(4) . .
Eu1 Eu1 N2 C10 77.7(4) 2_567 .
O5 Eu1 N2 C11 -21.5(4) 2_567 .
O1 Eu1 N2 C11 73.7(3) 2_566 .
O4 Eu1 N2 C11 -138.8(3) . .
O6 Eu1 N2 C11 147.2(3) 2_557 .
O7 Eu1 N2 C11 154.3(3) 2_557 .
O8 Eu1 N2 C11 -63.6(3) . .
N1 Eu1 N2 C11 12.7(3) . .
C24 Eu1 N2 C11 150.9(3) 2_557 .
O5 Eu1 N2 C11 -120.1(3) . .
Eu1 Eu1 N2 C11 -93.1(3) 2_567 .
O3 S1 O1 Eu1 -70.1(8) . 2_566
O2 S1 O1 Eu1 161.7(7) . 2_566
C19 S1 O1 Eu1 45.4(7) . 2_566
O5 Eu1 O4 C20 4.8(3) 2_567 .
O1 Eu1 O4 C20 -118.8(3) 2_566 .
O6 Eu1 O4 C20 -123.6(3) 2_557 .
O7 Eu1 O4 C20 -69.5(3) 2_557 .
O8 Eu1 O4 C20 73.9(3) . .
N2 Eu1 O4 C20 153.5(3) . .
N1 Eu1 O4 C20 118.2(3) . .
C24 Eu1 O4 C20 -96.1(3) 2_557 .
O5 Eu1 O4 C20 -4.0(3) . .
Eu1 Eu1 O4 C20 0.3(3) 2_567 .
O5 Eu1 O5 C20 -167.7(3) 2_567 .
O1 Eu1 O5 C20 136.7(2) 2_566 .
O4 Eu1 O5 C20 3.7(2) . .
O6 Eu1 O5 C20 60.4(3) 2_557 .
O7 Eu1 O5 C20 104.7(3) 2_557 .
O8 Eu1 O5 C20 -82.3(3) . .
N2 Eu1 O5 C20 -22.4(3) . .
N1 Eu1 O5 C20 -105.7(3) . .
C24 Eu1 O5 C20 81.1(3) 2_557 .
Eu1 Eu1 O5 C20 -167.7(3) 2_567 .
O5 Eu1 O5 Eu1 0.0 2_567 2_567
O1 Eu1 O5 Eu1 -55.6(2) 2_566 2_567
O4 Eu1 O5 Eu1 171.4(2) . 2_567
O6 Eu1 O5 Eu1 -131.90(13) 2_557 2_567
O7 Eu1 O5 Eu1 -87.64(14) 2_557 2_567
O8 Eu1 O5 Eu1 85.36(14) . 2_567
N2 Eu1 O5 Eu1 145.27(13) . 2_567
N1 Eu1 O5 Eu1 62.05(19) . 2_567
C24 Eu1 O5 Eu1 -111.20(15) 2_557 2_567
C12 N1 C1 C2 -1.2(7) . .
Eu1 N1 C1 C2 172.6(4) . .
N1 C1 C2 C3 -0.7(8) . .
C1 C2 C3 C4 0.8(7) . .
C2 C3 C4 C12 1.1(6) . .
C2 C3 C4 C5 -179.2(4) . .
C13 N3 C5 C6 -0.4(5) . .
C13 N3 C5 C4 176.0(4) . .
C3 C4 C5 N3 8.5(7) . .
C12 C4 C5 N3 -171.7(4) . .
C3 C4 C5 C6 -175.4(4) . .
C12 C4 C5 C6 4.4(6) . .
C13 N4 C6 C5 0.5(5) . .
C13 N4 C6 C7 -175.9(5) . .
N3 C5 C6 N4 0.0(5) . .
C4 C5 C6 N4 -176.7(4) . .
N3 C5 C6 C7 176.7(4) . .
C4 C5 C6 C7 0.0(7) . .
N4 C6 C7 C8 -8.9(8) . .
C5 C6 C7 C8 175.3(4) . .
N4 C6 C7 C11 171.9(4) . .
C5 C6 C7 C11 -3.9(6) . .
C11 C7 C8 C9 -0.8(6) . .
C6 C7 C8 C9 -180.0(4) . .
C7 C8 C9 C10 -0.5(7) . .
C11 N2 C10 C9 0.6(7) . .
Eu1 N2 C10 C9 -170.5(3) . .
C8 C9 C10 N2 0.6(7) . .
C10 N2 C11 C7 -2.0(6) . .
Eu1 N2 C11 C7 169.2(3) . .
C10 N2 C11 C12 176.1(4) . .
Eu1 N2 C11 C12 -12.7(5) . .
C8 C7 C11 N2 2.1(6) . .
C6 C7 C11 N2 -178.6(4) . .
C8 C7 C11 C12 -175.9(4) . .
C6 C7 C11 C12 3.3(6) . .
C1 N1 C12 C4 3.1(6) . .
Eu1 N1 C12 C4 -170.8(3) . .
C1 N1 C12 C11 -175.0(4) . .
Eu1 N1 C12 C11 11.1(5) . .
C3 C4 C12 N1 -3.1(6) . .
C5 C4 C12 N1 177.1(4) . .
C3 C4 C12 C11 174.9(4) . .
C5 C4 C12 C11 -4.8(6) . .
N2 C11 C12 N1 1.0(6) . .
C7 C11 C12 N1 179.1(4) . .
N2 C11 C12 C4 -177.1(4) . .
C7 C11 C12 C4 1.0(6) . .
C5 N3 C13 N4 0.7(5) . .
C5 N3 C13 C14 -171.2(4) . .
C6 N4 C13 N3 -0.8(5) . .
C6 N4 C13 C14 171.2(4) . .
N3 C13 C14 C15 20.4(6) . .
N4 C13 C14 C15 -150.6(4) . .
N3 C13 C14 C19 -162.3(4) . .
N4 C13 C14 C19 26.7(7) . .
C19 C14 C15 C16 -1.9(7) . .
C13 C14 C15 C16 175.6(4) . .
C14 C15 C16 C17 -0.1(7) . .
C15 C16 C17 C18 0.9(7) . .
C16 C17 C18 C19 0.3(7) . .
C17 C18 C19 C14 -2.3(7) . .
C17 C18 C19 S1 176.3(3) . .
C15 C14 C19 C18 3.1(6) . .
C13 C14 C19 C18 -174.1(4) . .
C15 C14 C19 S1 -175.5(3) . .
C13 C14 C19 S1 7.3(7) . .
O3 S1 C19 C18 -1.7(4) . .
O2 S1 C19 C18 120.2(4) . .
O1 S1 C19 C18 -121.0(4) . .
O3 S1 C19 C14 176.9(4) . .
O2 S1 C19 C14 -61.2(4) . .
O1 S1 C19 C14 57.6(4) . .
Eu1 O4 C20 O5 7.9(5) . .
Eu1 O4 C20 C21 -176.2(3) . .
Eu1 O5 C20 O4 -145.3(8) 2_567 .
Eu1 O5 C20 O4 -6.0(4) . .
Eu1 O5 C20 C21 38.8(12) 2_567 .
Eu1 O5 C20 C21 178.2(4) . .
O4 C20 C21 C22 -75.6(5) . .
O5 C20 C21 C22 100.3(5) . .
C20 C21 C22 C23 -170.4(4) . .
C21 C22 C23 C24 170.8(4) . .
Eu1 O6 C24 O7 -2.5(4) 2_557 .
Eu1 O6 C24 C23 175.1(4) 2_557 .
Eu1 O7 C24 O6 2.5(4) 2_557 .
Eu1 O7 C24 C23 -175.1(3) 2_557 .
C22 C23 C24 O6 -95.8(5) . .
C22 C23 C24 O7 81.8(5) . .
C22 C23 C24 Eu1 -4(5) . 2_557
