#------------------------------------------------------------------------------
#$Date: 2016-02-04 03:17:46 +0200 (Thu, 04 Feb 2016) $
#$Revision: 175660 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/48/4344827.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4344827
loop_
_publ_author_name
'Koppaka, Anjaneyulu'
'Yempally, Veeranna'
'Zhu, Lei'
'Fortman, George C.'
'Temprado, Manuel'
'Hoff, Carl D.'
'Captain, Burjor'
_publ_section_title
;
 Synthesis of [Pt(SnBu(t)3)(IBu(t))(μ-H)]2, a Coordinatively Unsaturated
 Dinuclear Compound which Fragments upon Addition of Small Molecules to
 Form Mononuclear Pt-Sn Complexes.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              307
_journal_paper_doi               10.1021/acs.inorgchem.5b02441
_journal_volume                  55
_journal_year                    2015
_chemical_formula_sum            'C42 H90 O2 Pt2 Sn4'
_chemical_formula_weight         1492.08
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.1493(5)
_cell_angle_beta                 99.4757(5)
_cell_angle_gamma                102.9447(5)
_cell_formula_units_Z            1
_cell_length_a                   9.1706(3)
_cell_length_b                   11.9962(4)
_cell_length_c                   12.7070(5)
_cell_measurement_reflns_used    9949
_cell_measurement_temperature    100
_cell_measurement_theta_max      32.66
_cell_measurement_theta_min      2.20
_cell_volume                     1324.75(8)
_computing_cell_refinement       'SAINT+  V7.46A (Bruker, 2007)'
_computing_data_collection       'APEX2 v2.2-0 (Bruker, 2007)'
_computing_data_reduction        'SAINT+  V7.46A (Bruker, 2007)'
_computing_molecular_graphics    'XSHELL v4.02 (Bruker, 2000)'
_computing_publication_material  'XCIF v6.12 (Bruker, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART APEX2 CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1218
_diffrn_reflns_av_sigmaI/netI    0.0858
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            20487
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.00
_diffrn_reflns_theta_min         1.65
_exptl_absorpt_coefficient_mu    7.144
_exptl_absorpt_correction_T_max  0.7465
_exptl_absorpt_correction_T_min  0.4005
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS 2007/4 Bruker)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.870
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             714
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.628
_refine_diff_density_min         -1.701
_refine_diff_density_rms         0.218
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     245
_refine_ls_number_reflns         7688
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0420
_refine_ls_R_factor_gt           0.0391
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0308P)²+1.8667P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0974
_refine_ls_wR_factor_ref         0.0993
_reflns_number_gt                7055
_reflns_number_total             7688
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b02441_si_002.cif
_cod_data_source_block           collect_5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4344827
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.36933(4) 0.40509(2) 0.91566(2) 0.01091(7) Uani 0.50 1 d P . 1
Pt2 Pt 0.43481(4) 0.39980(2) 0.91023(2) 0.01225(7) Uani 0.50 1 d P . 1
Sn1 Sn 0.23666(3) 0.25090(2) 0.740815(19) 0.01610(7) Uani 1 1 d . A 1
Sn2 Sn 0.49257(2) 0.61087(2) 0.873034(18) 0.01380(7) Uani 1 1 d . . 1
O11 O 0.0695(7) 0.4599(7) 0.9575(6) 0.0338(15) Uani 0.50 1 d P B 1
O21 O 0.7252(8) 0.3504(7) 0.8450(7) 0.0401(17) Uani 0.50 1 d P C 1
C11 C 0.1798(9) 0.4378(8) 0.9397(6) 0.0220(14) Uani 0.50 1 d P B 1
C21 C 0.6146(9) 0.3654(8) 0.8661(7) 0.0250(16) Uani 0.50 1 d P C 1
C31 C 0.1184(6) 0.3349(4) 0.6178(3) 0.0291(9) Uani 1 1 d . A 1
C32 C 0.2288(9) 0.4435(5) 0.5996(4) 0.0542(17) Uani 1 1 d . A 1
H32A H 0.1757 0.4811 0.5490 0.081 Uiso 1 1 calc R A 1
H32B H 0.3112 0.4219 0.5713 0.081 Uiso 1 1 calc R A 1
H32C H 0.2688 0.4957 0.6671 0.081 Uiso 1 1 calc R A 1
C33 C -0.0148(10) 0.3703(8) 0.6595(5) 0.074(3) Uani 1 1 d . A 1
H33A H 0.0236 0.4256 0.7251 0.111 Uiso 1 1 calc R A 1
H33B H -0.0832 0.3030 0.6734 0.111 Uiso 1 1 calc R A 1
H33C H -0.0684 0.4045 0.6060 0.111 Uiso 1 1 calc R A 1
C34 C 0.0574(6) 0.2536(5) 0.5087(4) 0.0338(10) Uani 1 1 d . A 1
H34A H 0.0104 0.2936 0.4573 0.051 Uiso 1 1 calc R A 1
H34B H -0.0166 0.1866 0.5174 0.051 Uiso 1 1 calc R A 1
H34C H 0.1403 0.2297 0.4831 0.051 Uiso 1 1 calc R A 1
C35 C 0.0597(5) 0.1274(6) 0.7964(5) 0.0485(16) Uani 1 1 d . A 1
C36 C -0.0154(8) 0.1891(10) 0.8733(7) 0.096(4) Uani 1 1 d . A 1
H36A H -0.0627 0.2419 0.8378 0.144 Uiso 1 1 calc R A 1
H36B H 0.0599 0.2316 0.9354 0.144 Uiso 1 1 calc R A 1
H36C H -0.0915 0.1334 0.8960 0.144 Uiso 1 1 calc R A 1
C37 C -0.0628(7) 0.0555(9) 0.6984(8) 0.104(4) Uani 1 1 d . A 1
H37A H -0.1169 -0.0141 0.7188 0.156 Uiso 1 1 calc R A 1
H37B H -0.0143 0.0357 0.6398 0.156 Uiso 1 1 calc R A 1
H37C H -0.1332 0.1004 0.6759 0.156 Uiso 1 1 calc R A 1
C38 C 0.1332(7) 0.0415(6) 0.8546(6) 0.0582(19) Uani 1 1 d . A 1
H38A H 0.2086 0.0837 0.9168 0.087 Uiso 1 1 calc R A 1
H38B H 0.1808 0.0007 0.8060 0.087 Uiso 1 1 calc R A 1
H38C H 0.0558 -0.0131 0.8773 0.087 Uiso 1 1 calc R A 1
C39 C 0.3831(7) 0.1541(6) 0.6642(4) 0.0478(16) Uani 1 1 d . A 1
C40 C 0.2831(11) 0.0466(7) 0.5878(5) 0.078(3) Uani 1 1 d . A 1
H40A H 0.2182 0.0694 0.5316 0.117 Uiso 1 1 calc R A 1
H40B H 0.2215 -0.0012 0.6274 0.117 Uiso 1 1 calc R A 1
H40C H 0.3465 0.0038 0.5563 0.117 Uiso 1 1 calc R A 1
C41 C 0.4876(9) 0.1134(9) 0.7510(5) 0.084(3) Uani 1 1 d . A 1
H41A H 0.5615 0.0832 0.7188 0.126 Uiso 1 1 calc R A 1
H41B H 0.4272 0.0538 0.7809 0.126 Uiso 1 1 calc R A 1
H41C H 0.5392 0.1778 0.8075 0.126 Uiso 1 1 calc R A 1
C42 C 0.4789(8) 0.2301(9) 0.6027(5) 0.078(3) Uani 1 1 d . A 1
H42A H 0.5494 0.1907 0.5765 0.117 Uiso 1 1 calc R A 1
H42B H 0.5344 0.3012 0.6496 0.117 Uiso 1 1 calc R A 1
H42C H 0.4140 0.2470 0.5426 0.117 Uiso 1 1 calc R A 1
C51 C 0.3239(8) 0.7183(7) 0.8802(6) 0.0199(13) Uiso 0.50 1 d P D 1
C52 C 0.4093(11) 0.8431(8) 0.9366(7) 0.0232(17) Uiso 0.50 1 d P D 1
H52A H 0.3384 0.8910 0.9368 0.035 Uiso 0.50 1 calc PR D 1
H52B H 0.4869 0.8739 0.8982 0.035 Uiso 0.50 1 calc PR D 1
H52C H 0.4557 0.8418 1.0097 0.035 Uiso 0.50 1 calc PR D 1
C53 C 0.2133(10) 0.6672(8) 0.9503(7) 0.0258(15) Uiso 0.50 1 d P D 1
H53A H 0.1547 0.7212 0.9686 0.039 Uiso 0.50 1 calc PR D 1
H53B H 0.2702 0.6526 1.0154 0.039 Uiso 0.50 1 calc PR D 1
H53C H 0.1457 0.5958 0.9108 0.039 Uiso 0.50 1 calc PR D 1
C54 C 0.2353(10) 0.7216(8) 0.7683(7) 0.0265(16) Uiso 0.50 1 d P D 1
H54A H 0.1694 0.6463 0.7382 0.040 Uiso 0.50 1 calc PR D 1
H54B H 0.3057 0.7435 0.7218 0.040 Uiso 0.50 1 calc PR D 1
H54C H 0.1751 0.7772 0.7744 0.040 Uiso 0.50 1 calc PR D 1
C61 C 0.6603(8) 0.6770(7) 0.7733(6) 0.0196(13) Uiso 0.50 1 d P E 1
C62 C 0.7893(14) 0.7728(12) 0.8412(12) 0.040(3) Uiso 0.50 1 d P E 1
H62A H 0.8671 0.7940 0.8001 0.060 Uiso 0.50 1 calc PR E 1
H62B H 0.8314 0.7464 0.9050 0.060 Uiso 0.50 1 calc PR E 1
H62C H 0.7514 0.8390 0.8618 0.060 Uiso 0.50 1 calc PR E 1
C63 C 0.5864(15) 0.7306(13) 0.6819(11) 0.053(3) Uiso 0.50 1 d P E 1
H63A H 0.4798 0.6921 0.6605 0.079 Uiso 0.50 1 calc PR E 1
H63B H 0.6352 0.7218 0.6212 0.079 Uiso 0.50 1 calc PR E 1
H63C H 0.5979 0.8116 0.7068 0.079 Uiso 0.50 1 calc PR E 1
C64 C 0.7217(18) 0.5803(15) 0.7239(13) 0.063(4) Uiso 0.50 1 d P E 1
H64A H 0.7850 0.6087 0.6751 0.095 Uiso 0.50 1 calc PR E 1
H64B H 0.6381 0.5175 0.6851 0.095 Uiso 0.50 1 calc PR E 1
H64C H 0.7809 0.5532 0.7803 0.095 Uiso 0.50 1 calc PR E 1
C55 C 0.3622(9) 0.7413(8) 0.8379(7) 0.0227(14) Uiso 0.50 1 d P F 2
C56 C 0.4470(10) 0.8542(8) 0.9159(7) 0.0207(16) Uiso 0.50 1 d P F 2
H56A H 0.3945 0.9136 0.9033 0.031 Uiso 0.50 1 calc PR F 2
H56B H 0.5492 0.8783 0.9039 0.031 Uiso 0.50 1 calc PR F 2
H56C H 0.4503 0.8412 0.9892 0.031 Uiso 0.50 1 calc PR F 2
C57 C 0.2006(10) 0.6995(9) 0.8555(8) 0.0302(17) Uiso 0.50 1 d P F 2
H57A H 0.2037 0.6794 0.9265 0.045 Uiso 0.50 1 calc PR F 2
H57B H 0.1473 0.6326 0.8022 0.045 Uiso 0.50 1 calc PR F 2
H57C H 0.1485 0.7601 0.8490 0.045 Uiso 0.50 1 calc PR F 2
C58 C 0.3584(10) 0.7691(8) 0.7225(7) 0.0282(16) Uiso 0.50 1 d P F 2
H58A H 0.3010 0.8260 0.7118 0.042 Uiso 0.50 1 calc PR F 2
H58B H 0.3110 0.6997 0.6708 0.042 Uiso 0.50 1 calc PR F 2
H58C H 0.4607 0.7989 0.7129 0.042 Uiso 0.50 1 calc PR F 2
C65 C 0.6839(8) 0.6283(7) 0.7850(6) 0.0197(13) Uiso 0.50 1 d P G 2
C66 C 0.7736(14) 0.7538(11) 0.8064(11) 0.037(2) Uiso 0.50 1 d P G 2
H66A H 0.8074 0.7796 0.8829 0.055 Uiso 0.50 1 calc PR G 2
H66B H 0.7097 0.8006 0.7773 0.055 Uiso 0.50 1 calc PR G 2
H66C H 0.8605 0.7610 0.7723 0.055 Uiso 0.50 1 calc PR G 2
C67 C 0.6220(9) 0.5941(8) 0.6619(7) 0.0238(15) Uiso 0.50 1 d P G 2
H67A H 0.7058 0.5960 0.6252 0.036 Uiso 0.50 1 calc PR G 2
H67B H 0.5659 0.6478 0.6376 0.036 Uiso 0.50 1 calc PR G 2
H67C H 0.5559 0.5173 0.6464 0.036 Uiso 0.50 1 calc PR G 2
C68 C 0.7861(10) 0.5530(8) 0.8246(7) 0.0261(16) Uiso 0.50 1 d P G 2
H68A H 0.7349 0.4729 0.7987 0.039 Uiso 0.50 1 calc PR G 2
H68B H 0.8091 0.5668 0.9023 0.039 Uiso 0.50 1 calc PR G 2
H68C H 0.8791 0.5716 0.7979 0.039 Uiso 0.50 1 calc PR G 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Pt2 Pt1 C11 173.9(3) . .
Pt2 Pt1 C21 8.6(2) . .
C11 Pt1 C21 174.8(3) . .
Pt2 Pt1 Sn1 91.93(4) . .
C11 Pt1 Sn1 93.4(2) . .
C21 Pt1 Sn1 83.5(2) . .
Pt2 Pt1 Sn2 78.68(4) . .
C11 Pt1 Sn2 96.5(3) . .
C21 Pt1 Sn2 80.9(2) . .
Sn1 Pt1 Sn2 113.223(12) . .
Pt2 Pt1 Sn2 77.06(4) . 2_667
C11 Pt1 Sn2 101.2(2) . 2_667
C21 Pt1 Sn2 83.95(19) . 2_667
Sn1 Pt1 Sn2 133.541(13) . 2_667
Sn2 Pt1 Sn2 108.590(11) . 2_667
Pt2 Pt1 Pt2 80.12(4) . 2_667
C11 Pt1 Pt2 94.2(2) . 2_667
C21 Pt1 Pt2 88.3(2) . 2_667
Sn1 Pt1 Pt2 168.838(16) . 2_667
Sn2 Pt1 Pt2 57.728(9) . 2_667
Sn2 Pt1 Pt2 52.442(8) 2_667 2_667
Pt2 Pt1 Pt1 68.87(4) . 2_667
C11 Pt1 Pt1 105.5(2) . 2_667
C21 Pt1 Pt1 77.1(2) . 2_667
Sn1 Pt1 Pt1 159.319(19) . 2_667
Sn2 Pt1 Pt1 57.014(10) . 2_667
Sn2 Pt1 Pt1 51.576(9) 2_667 2_667
Pt2 Pt1 Pt1 11.251(6) 2_667 2_667
Pt1 Pt2 C21 168.7(3) . .
Pt1 Pt2 C11 4.6(2) . .
C21 Pt2 C11 171.8(3) . .
Pt1 Pt2 Sn2 87.47(4) . .
C21 Pt2 Sn2 95.3(3) . .
C11 Pt2 Sn2 83.88(19) . .
Pt1 Pt2 Sn1 74.68(4) . .
C21 Pt2 Sn1 94.1(3) . .
C11 Pt2 Sn1 78.69(18) . .
Sn2 Pt2 Sn1 111.687(12) . .
Pt1 Pt2 Sn2 90.01(4) . 2_667
C21 Pt2 Sn2 99.0(3) . 2_667
C11 Pt2 Sn2 88.77(17) . 2_667
Sn2 Pt2 Sn2 112.287(11) . 2_667
Sn1 Pt2 Sn2 132.429(13) . 2_667
Pt1 Pt2 Pt2 87.82(4) . 2_667
C21 Pt2 Pt2 103.0(3) . 2_667
C11 Pt2 Pt2 83.55(19) . 2_667
Sn2 Pt2 Pt2 58.758(11) . 2_667
Sn1 Pt2 Pt2 160.83(2) . 2_667
Sn2 Pt2 Pt2 53.530(10) 2_667 2_667
Pt1 Pt2 Pt1 99.88(4) . 2_667
C21 Pt2 Pt1 91.0(3) . 2_667
C11 Pt2 Pt1 95.61(19) . 2_667
Sn2 Pt2 Pt1 59.859(9) . 2_667
Sn1 Pt2 Pt1 170.577(15) . 2_667
Sn2 Pt2 Pt1 54.123(8) 2_667 2_667
Pt2 Pt2 Pt1 12.065(6) 2_667 2_667
C35 Sn1 C39 109.2(3) . .
C35 Sn1 C31 107.71(18) . .
C39 Sn1 C31 109.11(18) . .
C35 Sn1 Pt1 103.64(18) . .
C39 Sn1 Pt1 117.14(15) . .
C31 Sn1 Pt1 109.58(12) . .
C35 Sn1 Pt2 111.62(17) . .
C39 Sn1 Pt2 103.86(15) . .
C31 Sn1 Pt2 115.18(13) . .
Pt1 Sn1 Pt2 13.393(6) . .
C61 Sn2 C51 111.2(3) . .
C61 Sn2 Pt2 123.0(2) . .
C51 Sn2 Pt2 121.8(2) . .
C61 Sn2 Pt1 135.0(2) . .
C51 Sn2 Pt1 108.0(2) . .
Pt2 Sn2 Pt1 13.849(7) . .
C61 Sn2 Pt2 124.8(2) . 2_667
C51 Sn2 Pt2 98.7(2) . 2_667
Pt2 Sn2 Pt2 67.713(11) . 2_667
Pt1 Sn2 Pt2 68.150(10) . 2_667
C61 Sn2 Pt1 113.2(2) . 2_667
C51 Sn2 Pt1 110.0(2) . 2_667
Pt2 Sn2 Pt1 67.700(9) . 2_667
Pt1 Sn2 Pt1 71.411(11) . 2_667
Pt2 Sn2 Pt1 12.931(6) 2_667 2_667
O11 C11 Pt1 177.6(7) . .
O11 C11 Pt2 176.2(7) . .
Pt1 C11 Pt2 1.49(6) . .
O21 C21 Pt2 175.9(8) . .
O21 C21 Pt1 178.4(8) . .
Pt2 C21 Pt1 2.78(6) . .
C32 C31 C33 108.8(5) . .
C32 C31 C34 108.0(4) . .
C33 C31 C34 109.2(5) . .
C32 C31 Sn1 110.0(3) . .
C33 C31 Sn1 108.9(3) . .
C34 C31 Sn1 111.9(3) . .
C36 C35 C37 109.4(6) . .
C36 C35 C38 108.6(5) . .
C37 C35 C38 107.6(6) . .
C36 C35 Sn1 111.4(5) . .
C37 C35 Sn1 110.2(4) . .
C38 C35 Sn1 109.6(3) . .
C42 C39 C40 109.8(6) . .
C42 C39 C41 109.6(6) . .
C40 C39 C41 107.6(6) . .
C42 C39 Sn1 110.1(5) . .
C40 C39 Sn1 109.5(4) . .
C41 C39 Sn1 110.2(3) . .
C54 C51 C53 110.0(6) . .
C54 C51 C52 109.5(7) . .
C53 C51 C52 108.0(7) . .
C54 C51 Sn2 112.5(5) . .
C53 C51 Sn2 107.8(5) . .
C52 C51 Sn2 108.8(5) . .
C62 C61 C64 110.3(9) . .
C62 C61 C63 106.1(9) . .
C64 C61 C63 108.6(9) . .
C62 C61 Sn2 110.1(7) . .
C64 C61 Sn2 110.8(8) . .
C63 C61 Sn2 110.8(6) . .
C57 C55 C56 110.9(7) . .
C57 C55 C58 109.8(7) . .
C56 C55 C58 106.6(7) . .
C68 C65 C66 109.9(7) . .
C68 C65 C67 111.1(7) . .
C66 C65 C67 107.4(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 Pt2 0.6316(3) .
Pt1 C11 1.929(8) .
Pt1 C21 2.560(8) .
Pt1 Sn1 2.6300(4) .
Pt1 Sn2 2.6361(4) .
Pt1 Sn2 2.8226(3) 2_667
Pt1 Pt2 3.0197(4) 2_667
Pt1 Pt1 3.1894(6) 2_667
Pt2 C21 1.938(8) .
Pt2 C11 2.558(8) .
Pt2 Sn2 2.5873(4) .
Pt2 Sn1 2.7253(4) .
Pt2 Sn2 2.7509(3) 2_667
Pt2 Pt2 2.9771(5) 2_667
Pt2 Pt1 3.0197(4) 2_667
Sn1 C35 2.211(5) .
Sn1 C39 2.225(4) .
Sn1 C31 2.226(4) .
Sn2 C61 2.224(8) .
Sn2 C51 2.230(7) .
Sn2 Pt2 2.7508(3) 2_667
Sn2 Pt1 2.8225(3) 2_667
O11 C11 1.150(10) .
O21 C21 1.138(10) .
C31 C32 1.529(8) .
C31 C33 1.531(7) .
C31 C34 1.533(7) .
C35 C36 1.499(11) .
C35 C37 1.547(10) .
C35 C38 1.550(8) .
C39 C42 1.503(11) .
C39 C40 1.520(10) .
C39 C41 1.539(7) .
C51 C54 1.528(11) .
C51 C53 1.534(12) .
C51 C52 1.546(12) .
C61 C62 1.507(16) .
C61 C64 1.511(17) .
C61 C63 1.531(15) .
C55 C57 1.518(12) .
C55 C56 1.537(12) .
C55 C58 1.540(12) .
C65 C68 1.511(11) .
C65 C66 1.512(15) .
C65 C67 1.543(11) .
