#------------------------------------------------------------------------------
#$Date: 2016-02-04 03:25:28 +0200 (Thu, 04 Feb 2016) $
#$Revision: 175672 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/48/4344855.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4344855
loop_
_publ_author_name
'Fernandes, Tiago A.'
'Santos, Carla I. M.'
'André, Vânia'
'Kłak, Julia'
'Kirillova, Marina V.'
'Kirillov, Alexander M.'
_publ_section_title
;
 Copper(II) Coordination Polymers Self-Assembled from Aminoalcohols and
 Pyromellitic Acid: Highly Active Precatalysts for the Mild Water-Promoted
 Oxidation of Alkanes.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              125
_journal_paper_doi               10.1021/acs.inorgchem.5b01983
_journal_volume                  55
_journal_year                    2015
_chemical_formula_sum            'C23 H28 Cu N2 O7'
_chemical_formula_weight         508.01
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                83.799(4)
_cell_angle_beta                 85.737(4)
_cell_angle_gamma                65.227(4)
_cell_formula_units_Z            2
_cell_length_a                   10.9067(11)
_cell_length_b                   11.0800(12)
_cell_length_c                   11.1272(12)
_cell_measurement_temperature    293(2)
_cell_volume                     1213.2(2)
_computing_cell_refinement       'BRUKER SMART (Bruker, 2005)'
_computing_data_collection       'BRUKER APEX2 (Bruker, 2005)'
_computing_data_reduction        'BRUKER SAINT (Bruker, 2005)'
_computing_molecular_graphics    'ORTEP 3.2 (Farrugia, 1997) and Mercury 2.2'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR 97 (Altomare et al, 1999)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0607
_diffrn_reflns_av_unetI/netI     0.0457
_diffrn_reflns_laue_measured_fraction_full 0.999
_diffrn_reflns_laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            66251
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.102
_diffrn_reflns_theta_min         2.624
_exptl_absorpt_coefficient_mu    0.944
_exptl_absorpt_correction_T_max  0.688
_exptl_absorpt_correction_T_min  0.576
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker,2005)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.391
_exptl_crystal_density_meas      ?
_exptl_crystal_description       block
_exptl_crystal_F_000             530
_exptl_crystal_size_max          0.8
_exptl_crystal_size_mid          0.5
_exptl_crystal_size_min          0.4
_refine_diff_density_max         0.603
_refine_diff_density_min         -0.355
_refine_diff_density_rms         0.067
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         7776
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0830
_refine_ls_R_factor_gt           0.0439
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0378P)²+0.6009P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0852
_refine_ls_wR_factor_ref         0.0973
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5368
_reflns_number_total             7776
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic5b01983_si_004.cif
_cod_data_source_block           shelx
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_database_code               4344855
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Cu1 Cu 0.5000 0.5000 0.0000 0.02356(8) Uani 1 2 d S . P
Cu2 Cu 0.5000 0.0000 0.5000 0.02074(8) Uani 1 2 d S . P
O2 O 0.50047(15) 0.51940(14) 0.17246(11) 0.0310(3) Uani 1 1 d . . .
O1W O 0.8131(3) 0.1544(2) 0.4265(2) 0.0731(6) Uani 1 1 d . . .
O3 O 0.68425(15) 0.34044(15) 0.23273(13) 0.0390(4) Uani 1 1 d . . .
O5 O 0.44669(18) 0.27254(15) 0.31340(12) 0.0406(4) Uani 1 1 d . . .
O4 O 0.48174(15) 0.18304(12) 0.50405(11) 0.0285(3) Uani 1 1 d . . .
N1 N 0.40481(18) 0.37634(17) 0.04202(15) 0.0295(4) Uani 1 1 d . . .
O6 O 0.44277(16) 0.03283(15) 0.29062(14) 0.0355(3) Uani 1 1 d . . .
C1 C 0.2624(2) 0.4446(3) 0.0028(2) 0.0434(5) Uani 1 1 d . . .
H1A H 0.2630 0.4550 -0.0867 0.052 Uiso 1 1 calc R U .
H1B H 0.2220 0.5352 0.0314 0.052 Uiso 1 1 calc R U .
C2 C 0.1736(2) 0.3743(2) 0.0470(2) 0.0402(5) Uani 1 1 d . . .
C3 C 0.1549(3) 0.2866(3) -0.0205(3) 0.0599(7) Uani 1 1 d . . .
H3 H 0.2007 0.2677 -0.0968 0.072 Uiso 1 1 calc R U .
C4 C 0.0698(3) 0.2253(4) 0.0216(4) 0.0774(10) Uani 1 1 d . . .
H4 H 0.0596 0.1634 -0.0251 0.093 Uiso 1 1 calc R U .
C5 C 0.0017(3) 0.2536(4) 0.1286(4) 0.0724(10) Uani 1 1 d . . .
H5 H -0.0568 0.2120 0.1566 0.087 Uiso 1 1 calc R U .
C6 C 0.0162(3) 0.3407(4) 0.1959(3) 0.0692(9) Uani 1 1 d . . .
H6 H -0.0327 0.3610 0.2707 0.083 Uiso 1 1 calc R U .
C7 C 0.1030(3) 0.4012(3) 0.1555(2) 0.0537(6) Uani 1 1 d . . .
H7 H 0.1134 0.4618 0.2038 0.064 Uiso 1 1 calc R U .
C8 C 0.4799(2) 0.2452(2) -0.0073(2) 0.0397(5) Uani 1 1 d . . .
H8A H 0.4835 0.2575 -0.0967 0.048 Uiso 1 1 calc R U .
H8B H 0.4320 0.1873 0.0169 0.048 Uiso 1 1 calc R U .
C9 C 0.6218(3) 0.1784(2) 0.0385(2) 0.0481(6) Uani 1 1 d . . .
H9A H 0.6182 0.1560 0.1269 0.058 Uiso 1 1 calc R U .
H9B H 0.6718 0.0943 -0.0004 0.058 Uiso 1 1 calc R U .
O1 O 0.69157(17) 0.26230(19) 0.01357(15) 0.0498(4) Uani 1 1 d . . .
C10 C 0.5766(2) 0.43801(19) 0.25162(15) 0.0247(4) Uani 1 1 d . . .
C11 C 0.53331(18) 0.46980(17) 0.38013(14) 0.0203(3) Uani 1 1 d . . .
C13 C 0.48844(18) 0.39008(16) 0.46019(15) 0.0199(3) Uani 1 1 d . . .
C12 C 0.54369(18) 0.57906(17) 0.42021(15) 0.0222(3) Uani 1 1 d . . .
H12 H 0.5732 0.6339 0.3652 0.027 Uiso 1 1 calc R U .
C14 C 0.47127(18) 0.27278(17) 0.42070(16) 0.0224(3) Uani 1 1 d . . .
N2 N 0.70346(17) -0.05822(17) 0.47630(15) 0.0296(3) Uani 1 1 d . . .
C16 C 0.7701(2) -0.1154(2) 0.5932(2) 0.0403(5) Uani 1 1 d . . .
H16A H 0.8616 -0.1164 0.5882 0.048 Uiso 1 1 calc R U .
H16B H 0.7802 -0.2087 0.6093 0.048 Uiso 1 1 calc R U .
C15 C 0.3108(2) 0.0355(2) 0.3043(2) 0.0413(5) Uani 1 1 d . . .
H15A H 0.3183 -0.0570 0.3196 0.050 Uiso 1 1 calc R U .
H15B H 0.2625 0.0746 0.2281 0.050 Uiso 1 1 calc R U .
C17 C 0.7609(2) -0.1499(3) 0.3783(2) 0.0443(6) Uani 1 1 d . . .
H17A H 0.7117 -0.1053 0.3036 0.053 Uiso 1 1 calc R U .
H17B H 0.7438 -0.2305 0.4010 0.053 Uiso 1 1 calc R U .
C18 C 0.9101(2) -0.1935(3) 0.3506(2) 0.0462(6) Uani 1 1 d . . .
C23 C 0.9566(3) -0.1108(4) 0.2773(3) 0.0681(8) Uani 1 1 d . . .
H23 H 0.8945 -0.0242 0.2487 0.082 Uiso 1 1 calc R U .
C19 C 1.0027(3) -0.3158(3) 0.3932(3) 0.0768(10) Uani 1 1 d . . .
H19 H 0.9744 -0.3743 0.4444 0.092 Uiso 1 1 calc R U .
C21 C 1.1818(4) -0.2718(6) 0.2861(4) 0.1047(17) Uani 1 1 d . . .
H21 H 1.2745 -0.2991 0.2631 0.126 Uiso 1 1 calc R U .
C20 C 1.1410(4) -0.3547(5) 0.3605(4) 0.1026(15) Uani 1 1 d . . .
H20 H 1.2058 -0.4393 0.3907 0.123 Uiso 1 1 calc R U .
C22 C 1.0917(4) -0.1529(6) 0.2458(4) 0.0970(14) Uani 1 1 d . . .
H22 H 1.1209 -0.0955 0.1941 0.116 Uiso 1 1 calc R U .
H1N H 0.400(4) 0.371(4) 0.114(4) 0.116 Uiso 1 1 d . U .
H2N H 0.720(4) 0.014(4) 0.453(4) 0.116 Uiso 1 1 d . U .
H6N H 0.437(5) 0.097(5) 0.282(5) 0.145 Uiso 1 1 d . U .
H1W H 0.852(5) 0.191(5) 0.474(5) 0.145 Uiso 1 1 d . U .
H2W H 0.779(5) 0.215(5) 0.364(5) 0.145 Uiso 1 1 d . U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Cu1 O2 180.0 . 2_665
O2 Cu1 N1 88.85(6) . .
O2 Cu1 N1 91.15(6) 2_665 .
O2 Cu1 N1 91.15(6) . 2_665
O2 Cu1 N1 88.85(6) 2_665 2_665
N1 Cu1 N1 180.0 . 2_665
O4 Cu2 O4 180.0 2_656 .
O4 Cu2 N2 88.16(6) 2_656 2_656
O4 Cu2 N2 91.84(6) . 2_656
O4 Cu2 N2 91.84(6) 2_656 .
O4 Cu2 N2 88.16(6) . .
N2 Cu2 N2 180.0 2_656 .
O4 Cu2 O6 86.60(5) 2_656 .
O4 Cu2 O6 93.40(5) . .
N2 Cu2 O6 81.58(6) 2_656 .
N2 Cu2 O6 98.42(6) . .
O4 Cu2 O6 93.40(5) 2_656 2_656
O4 Cu2 O6 86.60(5) . 2_656
N2 Cu2 O6 98.42(6) 2_656 2_656
N2 Cu2 O6 81.58(6) . 2_656
O6 Cu2 O6 180.0 . 2_656
C10 O2 Cu1 128.27(13) . .
H1W O1W H2W 106(4) . .
C14 O4 Cu2 131.50(12) . .
C8 N1 C1 113.12(17) . .
C8 N1 Cu1 111.89(13) . .
C1 N1 Cu1 109.55(13) . .
C8 N1 H1N 113(3) . .
C1 N1 H1N 105(3) . .
Cu1 N1 H1N 104(3) . .
C15 O6 Cu2 99.54(12) . .
C15 O6 H6N 109(4) . .
Cu2 O6 H6N 95(4) . .
N1 C1 C2 115.07(18) . .
N1 C1 H1A 108.5 . .
C2 C1 H1A 108.5 . .
N1 C1 H1B 108.5 . .
C2 C1 H1B 108.5 . .
H1A C1 H1B 107.5 . .
C7 C2 C3 117.7(2) . .
C7 C2 C1 120.1(2) . .
C3 C2 C1 122.2(2) . .
C2 C3 C4 120.9(3) . .
C2 C3 H3 119.6 . .
C4 C3 H3 119.6 . .
C5 C4 C3 120.2(3) . .
C5 C4 H4 119.9 . .
C3 C4 H4 119.9 . .
C6 C5 C4 120.4(3) . .
C6 C5 H5 119.8 . .
C4 C5 H5 119.8 . .
C5 C6 C7 120.0(3) . .
C5 C6 H6 120.0 . .
C7 C6 H6 120.0 . .
C2 C7 C6 120.9(3) . .
C2 C7 H7 119.5 . .
C6 C7 H7 119.5 . .
N1 C8 C9 110.92(18) . .
N1 C8 H8A 109.5 . .
C9 C8 H8A 109.5 . .
N1 C8 H8B 109.5 . .
C9 C8 H8B 109.5 . .
H8A C8 H8B 108.0 . .
O1 C9 C8 111.5(2) . .
O1 C9 H9A 109.3 . .
C8 C9 H9A 109.3 . .
O1 C9 H9B 109.3 . .
C8 C9 H9B 109.3 . .
H9A C9 H9B 108.0 . .
O3 C10 O2 126.33(17) . .
O3 C10 C11 118.54(16) . .
O2 C10 C11 115.04(16) . .
C12 C11 C13 119.60(15) . .
C12 C11 C10 118.33(15) . .
C13 C11 C10 122.02(15) . .
C12 C13 C11 119.28(15) 2_666 .
C12 C13 C14 118.85(15) 2_666 .
C11 C13 C14 121.85(15) . .
C11 C12 C13 121.12(15) . 2_666
C11 C12 H12 119.4 . .
C13 C12 H12 119.4 2_666 .
O5 C14 O4 126.21(16) . .
O5 C14 C13 119.42(15) . .
O4 C14 C13 114.36(15) . .
C16 N2 C17 112.92(18) . .
C16 N2 Cu2 109.75(13) . .
C17 N2 Cu2 111.89(13) . .
C16 N2 H2N 107(3) . .
C17 N2 H2N 106(3) . .
Cu2 N2 H2N 109(3) . .
N2 C16 C15 111.13(18) . 2_656
N2 C16 H16A 109.4 . .
C15 C16 H16A 109.4 2_656 .
N2 C16 H16B 109.4 . .
C15 C16 H16B 109.4 2_656 .
H16A C16 H16B 108.0 . .
O6 C15 C16 112.15(18) . 2_656
O6 C15 H15A 109.2 . .
C16 C15 H15A 109.2 2_656 .
O6 C15 H15B 109.2 . .
C16 C15 H15B 109.2 2_656 .
H15A C15 H15B 107.9 . .
N2 C17 C18 115.65(19) . .
N2 C17 H17A 108.4 . .
C18 C17 H17A 108.4 . .
N2 C17 H17B 108.4 . .
C18 C17 H17B 108.4 . .
H17A C17 H17B 107.4 . .
C19 C18 C23 118.1(3) . .
C19 C18 C17 121.5(3) . .
C23 C18 C17 120.3(3) . .
C22 C23 C18 120.7(4) . .
C22 C23 H23 119.7 . .
C18 C23 H23 119.7 . .
C18 C19 C20 119.5(4) . .
C18 C19 H19 120.2 . .
C20 C19 H19 120.2 . .
C22 C21 C20 119.7(4) . .
C22 C21 H21 120.1 . .
C20 C21 H21 120.1 . .
C21 C20 C19 120.4(4) . .
C21 C20 H20 119.8 . .
C19 C20 H20 119.8 . .
C21 C22 C23 121.5(4) . .
C21 C22 H22 119.3 . .
C23 C22 H22 119.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O2 1.9546(12) .
Cu1 O2 1.9546(12) 2_665
Cu1 N1 2.0384(17) .
Cu1 N1 2.0384(17) 2_665
Cu2 O4 1.9582(12) 2_656
Cu2 O4 1.9582(12) .
Cu2 N2 2.0396(17) 2_656
Cu2 N2 2.0396(17) .
Cu2 O6 2.4069(16) .
Cu2 O6 2.4069(16) 2_656
O2 C10 1.260(2) .
O1W H1W 0.93(5) .
O1W H2W 0.90(5) .
O3 C10 1.241(2) .
O5 C14 1.243(2) .
O4 C14 1.258(2) .
N1 C8 1.481(3) .
N1 C1 1.490(3) .
N1 H1N 0.79(4) .
O6 C15 1.425(3) .
O6 H6N 0.68(5) .
C1 C2 1.506(3) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 C7 1.374(4) .
C2 C3 1.377(4) .
C3 C4 1.392(4) .
C3 H3 0.9500 .
C4 C5 1.349(5) .
C4 H4 0.9500 .
C5 C6 1.348(5) .
C5 H5 0.9500 .
C6 C7 1.397(4) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 C9 1.509(3) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 O1 1.423(3) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.504(2) .
C11 C12 1.384(2) .
C11 C13 1.393(2) .
C13 C12 1.393(2) 2_666
C13 C14 1.502(2) .
C12 C13 1.393(2) 2_666
C12 H12 0.9500 .
N2 C16 1.482(3) .
N2 C17 1.489(3) .
N2 H2N 0.90(4) .
C16 C15 1.510(3) 2_656
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C15 C16 1.510(3) 2_656
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C17 C18 1.509(3) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 C19 1.366(4) .
C18 C23 1.388(4) .
C23 C22 1.376(4) .
C23 H23 0.9500 .
C19 C20 1.415(5) .
C19 H19 0.9500 .
C21 C22 1.325(7) .
C21 C20 1.360(7) .
C21 H21 0.9500 .
C20 H20 0.9500 .
C22 H22 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C8 N1 C1 C2 64.5(3) . .
Cu1 N1 C1 C2 -169.97(17) . .
N1 C1 C2 C7 89.7(3) . .
N1 C1 C2 C3 -93.4(3) . .
C7 C2 C3 C4 -1.5(4) . .
C1 C2 C3 C4 -178.5(3) . .
C2 C3 C4 C5 1.5(5) . .
C3 C4 C5 C6 -0.4(5) . .
C4 C5 C6 C7 -0.6(5) . .
C3 C2 C7 C6 0.4(4) . .
C1 C2 C7 C6 177.5(2) . .
C5 C6 C7 C2 0.6(4) . .
C1 N1 C8 C9 -178.11(19) . .
Cu1 N1 C8 C9 57.6(2) . .
N1 C8 C9 O1 -54.9(3) . .
Cu1 O2 C10 O3 15.5(3) . .
Cu1 O2 C10 C11 -167.96(11) . .
O3 C10 C11 C12 106.6(2) . .
O2 C10 C11 C12 -70.3(2) . .
O3 C10 C11 C13 -71.0(2) . .
O2 C10 C11 C13 112.2(2) . .
C12 C11 C13 C12 -0.8(3) . 2_666
C10 C11 C13 C12 176.72(17) . 2_666
C12 C11 C13 C14 178.13(16) . .
C10 C11 C13 C14 -4.4(3) . .
C13 C11 C12 C13 0.8(3) . 2_666
C10 C11 C12 C13 -176.80(17) . 2_666
Cu2 O4 C14 O5 13.4(3) . .
Cu2 O4 C14 C13 -167.77(12) . .
C12 C13 C14 O5 151.71(18) 2_666 .
C11 C13 C14 O5 -27.2(3) . .
C12 C13 C14 O4 -27.2(2) 2_666 .
C11 C13 C14 O4 153.93(17) . .
C17 N2 C16 C15 -166.49(18) . 2_656
Cu2 N2 C16 C15 -40.9(2) . 2_656
Cu2 O6 C15 C16 42.25(19) . 2_656
C16 N2 C17 C18 -58.2(3) . .
Cu2 N2 C17 C18 177.42(18) . .
N2 C17 C18 C19 100.9(3) . .
N2 C17 C18 C23 -81.1(3) . .
C19 C18 C23 C22 1.9(5) . .
C17 C18 C23 C22 -176.2(3) . .
C23 C18 C19 C20 -0.9(5) . .
C17 C18 C19 C20 177.2(3) . .
C22 C21 C20 C19 1.2(6) . .
C18 C19 C20 C21 -0.7(6) . .
C20 C21 C22 C23 -0.1(6) . .
C18 C23 C22 C21 -1.5(6) . .
