#------------------------------------------------------------------------------
#$Date: 2017-03-04 15:11:13 +0200 (Sat, 04 Mar 2017) $
#$Revision: 193425 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/51/4345169.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345169
loop_
_publ_author_name
'Yang, Dandan'
'Tian, Yun'
'Xu, Wenlong'
'Cao, Xiaowei'
'Zheng, Shaojun'
'Ju, Qiang'
'Huang, Wei'
'Fang, Zhenlan'
_publ_section_title
;
 A Series of Lanthanide-Based Metal-Organic Frameworks: Synthesis,
 Structures, and Multicolor Tuning of Single Component.
;
_journal_issue                   4
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2345
_journal_page_last               2353
_journal_paper_doi               10.1021/acs.inorgchem.7b00074
_journal_volume                  56
_journal_year                    2017
_chemical_formula_sum            'C84 H57 Eu4 O39'
_chemical_formula_weight         2298.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 117.644(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.694(2)
_cell_length_b                   29.112(7)
_cell_length_c                   18.738(4)
_cell_measurement_reflns_used    8563
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      29.23
_cell_measurement_theta_min      2.43
_cell_volume                     4201.2(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0514
_diffrn_reflns_av_sigmaI/netI    0.0516
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       40
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            39260
_diffrn_reflns_theta_full        29.29
_diffrn_reflns_theta_max         29.29
_diffrn_reflns_theta_min         1.40
_exptl_absorpt_coefficient_mu    3.041
_exptl_absorpt_correction_T_max  0.894
_exptl_absorpt_correction_T_min  0.826
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.817
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       sheet
_exptl_crystal_F_000             2250
_refine_diff_density_max         2.942
_refine_diff_density_min         -3.492
_refine_diff_density_rms         0.253
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     577
_refine_ls_number_reflns         11407
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0852
_refine_ls_R_factor_gt           0.0571
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0957P)²+30.8973P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1650
_refine_ls_wR_factor_ref         0.1878
_reflns_number_gt                8563
_reflns_number_total             11407
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic7b00074_si_002.cif
_cod_data_source_block           d:IAM16-3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 4345169--4345171.cif.
;
_cod_original_sg_symbol_H-M      P21/c
_cod_original_formula_sum        C84H57Eu4O39
_cod_database_code               4345169
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.61809(4) -0.014208(10) 0.927196(19) 0.02386(10) Uani 1 1 d .
Eu2 Eu 0.53226(6) -0.009818(12) 0.62901(2) 0.03724(13) Uani 1 1 d .
O1 O 0.5930(11) 0.4545(2) 1.0545(5) 0.070(2) Uani 1 1 d .
O1W O 0.8660(8) -0.0178(2) 0.8994(4) 0.0485(15) Uani 1 1 d .
H1W H 0.9487 -0.0297 0.9377 0.073 Uiso 1 1 calc R
O2 O 0.6177(9) 0.4251(2) 0.9524(4) 0.0555(17) Uani 1 1 d .
O2W O 0.3041(7) -0.0057(2) 0.8434(4) 0.0445(14) Uani 1 1 d .
H2W H 0.2732 0.0194 0.8521 0.067 Uiso 1 1 calc R
O3 O 0.7235(10) 0.24453(18) 1.1600(4) 0.0550(18) Uani 1 1 d .
O3W O 0.238(2) -0.0286(6) 0.6340(10) 0.071(4) Uani 0.50 1 d P
H3W H 0.2577 -0.0462 0.6715 0.107 Uiso 0.50 1 calc PR
O4 O 0.7978(6) 0.05054(16) 1.0169(3) 0.0324(11) Uani 1 1 d .
O4W O 0.2500(9) 0.0248(4) 0.5280(5) 0.083(3) Uani 1 1 d .
H4W H 0.2582 0.0327 0.4880 0.124 Uiso 1 1 calc R
O5 O 0.5243(6) 0.04835(15) 0.9951(3) 0.0285(10) Uani 1 1 d .
O5W O 0.8216(10) 0.0142(3) 0.7354(5) 0.083(3) Uani 1 1 d .
H5W H 0.8952 -0.0042 0.7377 0.124 Uiso 1 1 calc R
O6 O 0.8783(12) -0.0703(2) 1.1554(4) 0.075(3) Uani 1 1 d .
O7 O 0.8308(7) -0.05710(19) 1.0305(3) 0.0407(13) Uani 1 1 d .
O8 O 1.0954(11) -0.2622(2) 1.0608(5) 0.064(2) Uani 1 1 d .
O9 O 1.0163(9) -0.4474(3) 1.2201(5) 0.077(3) Uani 1 1 d .
O10 O 0.7544(8) -0.4443(2) 1.1151(4) 0.0476(15) Uani 1 1 d .
O11 O 0.5466(8) -0.07806(19) 0.8409(4) 0.0431(13) Uani 1 1 d .
O12 O 0.5705(12) -0.0570(2) 0.7339(4) 0.067(2) Uani 1 1 d .
O13 O 0.7833(12) -0.2633(2) 0.7403(6) 0.080(3) Uani 1 1 d .
O14 O 0.5267(12) -0.4553(2) 0.7981(4) 0.066(2) Uani 1 1 d .
O15 O 0.4084(9) -0.4560(2) 0.6651(4) 0.0510(16) Uani 1 1 d .
C1 C 0.6188(11) 0.4207(3) 1.0194(6) 0.0423(19) Uani 1 1 d .
C2 C 0.6499(10) 0.3742(2) 1.0566(4) 0.0335(15) Uani 1 1 d .
C3 C 0.6293(14) 0.3659(3) 1.1249(5) 0.051(2) Uani 1 1 d .
H1 H 0.6011 0.3899 1.1493 0.061 Uiso 1 1 calc R
C4 C 0.6509(14) 0.3217(3) 1.1567(5) 0.049(2) Uani 1 1 d .
H2 H 0.6353 0.3163 1.2018 0.058 Uiso 1 1 calc R
C5 C 0.6956(11) 0.2859(2) 1.1213(4) 0.0362(17) Uani 1 1 d .
C6 C 0.7124(12) 0.2932(3) 1.0517(5) 0.0412(19) Uani 1 1 d .
H3 H 0.7386 0.2690 1.0268 0.049 Uiso 1 1 calc R
C7 C 0.6892(12) 0.3374(3) 1.0203(5) 0.0389(17) Uani 1 1 d .
H4 H 0.7003 0.3426 0.9739 0.047 Uiso 1 1 calc R
C8 C 0.7117(12) 0.2036(2) 1.1188(4) 0.0368(17) Uani 1 1 d .
C9 C 0.5596(11) 0.1904(2) 1.0528(5) 0.0390(17) Uani 1 1 d .
H8 H 0.4671 0.2108 1.0293 0.047 Uiso 1 1 calc R
C10 C 0.5458(10) 0.1464(2) 1.0220(5) 0.0329(15) Uani 1 1 d .
H7 H 0.4422 0.1367 0.9791 0.039 Uiso 1 1 calc R
C11 C 0.6882(9) 0.1168(2) 1.0556(4) 0.0247(13) Uani 1 1 d .
C12 C 0.8429(10) 0.1310(2) 1.1193(4) 0.0330(15) Uani 1 1 d .
H6 H 0.9390 0.1117 1.1399 0.040 Uiso 1 1 calc R
C13 C 0.8538(12) 0.1745(3) 1.1522(5) 0.0404(18) Uani 1 1 d .
H5 H 0.9559 0.1840 1.1962 0.049 Uiso 1 1 calc R
C14 C 0.6726(9) 0.0692(2) 1.0219(4) 0.0260(13) Uani 1 1 d .
C15 C 0.8783(9) -0.0825(2) 1.0909(4) 0.0329(15) Uani 1 1 d .
C16 C 0.9360(10) -0.1301(2) 1.0847(4) 0.0306(14) Uani 1 1 d .
C17 C 0.9769(12) -0.1416(3) 1.0239(5) 0.0419(19) Uani 1 1 d .
H12 H 0.9694 -0.1193 0.9868 0.050 Uiso 1 1 calc R
C18 C 1.0288(14) -0.1858(3) 1.0174(5) 0.048(2) Uani 1 1 d .
H11 H 1.0588 -0.1929 0.9771 0.057 Uiso 1 1 calc R
C19 C 1.0357(11) -0.2192(2) 1.0709(5) 0.0364(16) Uani 1 1 d .
C20 C 0.9931(13) -0.2090(3) 1.1317(5) 0.049(2) Uani 1 1 d .
H10 H 0.9947 -0.2317 1.1669 0.058 Uiso 1 1 calc R
C21 C 0.9480(12) -0.1642(3) 1.1391(5) 0.0428(19) Uani 1 1 d .
H9 H 0.9252 -0.1568 1.1815 0.051 Uiso 1 1 calc R
C22 C 1.0429(12) -0.3014(3) 1.0863(5) 0.0409(18) Uani 1 1 d .
C23 C 1.1669(12) -0.3244(3) 1.1537(5) 0.046(2) Uani 1 1 d .
H13 H 1.2777 -0.3122 1.1830 0.055 Uiso 1 1 calc R
C24 C 1.1234(11) -0.3655(3) 1.1766(5) 0.0417(18) Uani 1 1 d .
H14 H 1.2043 -0.3807 1.2223 0.050 Uiso 1 1 calc R
C25 C 0.9587(11) -0.3843(2) 1.1313(5) 0.0359(16) Uani 1 1 d .
C26 C 0.8374(12) -0.3612(3) 1.0636(5) 0.051(2) Uani 1 1 d .
H15 H 0.7273 -0.3735 1.0330 0.061 Uiso 1 1 calc R
C27 C 0.8823(14) -0.3194(3) 1.0421(6) 0.056(2) Uani 1 1 d .
H16 H 0.8013 -0.3037 0.9970 0.067 Uiso 1 1 calc R
C28 C 0.9079(11) -0.4287(3) 1.1580(5) 0.0416(19) Uani 1 1 d .
C29 C 0.5765(11) -0.0870(3) 0.7822(4) 0.0379(17) Uani 1 1 d .
C30 C 0.6154(10) -0.1348(2) 0.7687(4) 0.0309(14) Uani 1 1 d .
C31 C 0.6392(13) -0.1454(3) 0.7018(5) 0.046(2) Uani 1 1 d .
H20 H 0.6228 -0.1228 0.6638 0.055 Uiso 1 1 calc R
C32 C 0.6872(13) -0.1893(3) 0.6916(6) 0.049(2) Uani 1 1 d .
H19 H 0.7029 -0.1964 0.6470 0.059 Uiso 1 1 calc R
C33 C 0.7111(13) -0.2222(3) 0.7479(6) 0.049(2) Uani 1 1 d .
C34 C 0.6816(17) -0.2131(3) 0.8123(7) 0.068(3) Uani 1 1 d .
H18 H 0.6918 -0.2364 0.8483 0.081 Uiso 1 1 calc R
C35 C 0.6367(14) -0.1691(3) 0.8232(6) 0.053(2) Uani 1 1 d .
H17 H 0.6206 -0.1625 0.8679 0.063 Uiso 1 1 calc R
C36 C 0.7019(14) -0.3042(3) 0.7423(6) 0.049(2) Uani 1 1 d .
C37 C 0.5450(16) -0.3145(3) 0.6782(7) 0.060(3) Uani 1 1 d .
H24 H 0.4863 -0.2928 0.6382 0.071 Uiso 1 1 calc R
C38 C 0.4736(14) -0.3587(3) 0.6737(6) 0.052(2) Uani 1 1 d .
H23 H 0.3698 -0.3669 0.6294 0.062 Uiso 1 1 calc R
C39 C 0.5583(12) -0.3892(3) 0.7347(4) 0.0381(17) Uani 1 1 d .
C40 C 0.7116(15) -0.3765(3) 0.8009(6) 0.063(3) Uani 1 1 d .
H22 H 0.7662 -0.3971 0.8433 0.076 Uiso 1 1 calc R
C41 C 0.7845(17) -0.3341(4) 0.8051(7) 0.069(3) Uani 1 1 d .
H21 H 0.8878 -0.3259 0.8496 0.083 Uiso 1 1 calc R
C42 C 0.4909(12) -0.4371(3) 0.7313(5) 0.0409(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O11 90.1(2) . .
O7 Eu1 O15 140.1(2) . 2_656
O11 Eu1 O15 99.2(2) . 2_656
O7 Eu1 O1W 73.4(2) . .
O11 Eu1 O1W 78.3(2) . .
O15 Eu1 O1W 70.7(2) 2_656 .
O7 Eu1 O2W 143.8(2) . .
O11 Eu1 O2W 77.2(2) . .
O15 Eu1 O2W 75.9(2) 2_656 .
O1W Eu1 O2W 134.3(2) . .
O7 Eu1 O5 73.79(18) . 3_657
O11 Eu1 O5 92.41(18) . 3_657
O15 Eu1 O5 143.5(2) 2_656 3_657
O1W Eu1 O5 145.81(18) . 3_657
O2W Eu1 O5 73.1(2) . 3_657
O7 Eu1 O4 80.76(19) . .
O11 Eu1 O4 158.78(19) . .
O15 Eu1 O4 76.8(2) 2_656 .
O1W Eu1 O4 80.8(2) . .
O2W Eu1 O4 120.81(17) . .
O5 Eu1 O4 103.23(16) 3_657 .
O7 Eu1 O5 106.38(19) . .
O11 Eu1 O5 149.38(19) . .
O15 Eu1 O5 84.7(2) 2_656 .
O1W Eu1 O5 130.7(2) . .
O2W Eu1 O5 74.31(17) . .
O5 Eu1 O5 68.75(16) 3_657 .
O4 Eu1 O5 51.71(16) . .
O7 Eu1 C14 95.7(2) . .
O11 Eu1 C14 174.0(2) . .
O15 Eu1 C14 77.3(2) 2_656 .
O1W Eu1 C14 104.8(2) . .
O2W Eu1 C14 97.12(19) . .
O5 Eu1 C14 87.79(17) 3_657 .
O4 Eu1 C14 25.51(18) . .
O5 Eu1 C14 26.41(18) . .
O7 Eu1 Eu1 90.29(15) . 3_657
O11 Eu1 Eu1 123.47(15) . 3_657
O15 Eu1 Eu1 115.20(17) 2_656 3_657
O1W Eu1 Eu1 153.52(16) . 3_657
O2W Eu1 Eu1 70.12(15) . 3_657
O5 Eu1 Eu1 34.75(10) 3_657 3_657
O4 Eu1 Eu1 76.01(12) . 3_657
O5 Eu1 Eu1 34.00(11) . 3_657
C14 Eu1 Eu1 55.19(14) . 3_657
O12 Eu2 O14 83.6(2) . 2_656
O12 Eu2 O1 159.8(3) . 4_565
O14 Eu2 O1 93.1(3) 2_656 4_565
O12 Eu2 O2 83.8(2) . 2_646
O14 Eu2 O2 135.7(3) 2_656 2_646
O1 Eu2 O2 111.6(3) 4_565 2_646
O12 Eu2 O10 87.5(3) . 4
O14 Eu2 O10 147.1(3) 2_656 4
O1 Eu2 O10 84.5(2) 4_565 4
O2 Eu2 O10 74.1(2) 2_646 4
O12 Eu2 O5W 77.9(3) . .
O14 Eu2 O5W 75.5(3) 2_656 .
O1 Eu2 O5W 82.0(3) 4_565 .
O2 Eu2 O5W 141.5(2) 2_646 .
O10 Eu2 O5W 71.6(2) 4 .
O12 Eu2 O4W 126.1(3) . .
O14 Eu2 O4W 76.2(3) 2_656 .
O1 Eu2 O4W 71.8(3) 4_565 .
O2 Eu2 O4W 77.6(3) 2_646 .
O10 Eu2 O4W 132.8(2) 4 .
O5W Eu2 O4W 140.0(3) . .
O12 Eu2 O3W 66.8(4) . .
O14 Eu2 O3W 68.8(5) 2_656 .
O1 Eu2 O3W 130.4(4) 4_565 .
O2 Eu2 O3W 67.2(4) 2_646 .
O10 Eu2 O3W 135.1(4) 4 .
O5W Eu2 O3W 131.6(4) . .
O4W Eu2 O3W 59.3(4) . .
O12 Eu2 C1 101.8(2) . 2_646
O14 Eu2 C1 147.2(3) 2_656 2_646
O1 Eu2 C1 91.8(3) 4_565 2_646
O2 Eu2 C1 20.4(2) 2_646 2_646
O10 Eu2 C1 65.7(2) 4 2_646
O5W Eu2 C1 137.3(2) . 2_646
O4W Eu2 C1 74.6(2) . 2_646
O3W Eu2 C1 83.5(4) . 2_646
C1 O1 Eu2 171.9(7) . 4_566
Eu1 O1W H1W 109.5 . .
C1 O2 Eu2 117.8(6) . 2_656
Eu1 O2W H2W 109.5 . .
C5 O3 C8 120.6(6) . .
Eu2 O3W H3W 109.5 . .
C14 O4 Eu1 94.7(4) . .
Eu2 O4W H4W 109.5 . .
C14 O5 Eu1 129.0(4) . 3_657
C14 O5 Eu1 92.1(4) . .
Eu1 O5 Eu1 111.25(16) 3_657 .
Eu2 O5W H5W 109.5 . .
C15 O7 Eu1 150.7(5) . .
C22 O8 C19 118.9(6) . .
C28 O10 Eu2 140.2(5) . 4_556
C29 O11 Eu1 131.6(5) . .
C29 O12 Eu2 170.9(6) . .
C33 O13 C36 118.3(7) . .
C42 O14 Eu2 149.4(6) . 2_646
C42 O15 Eu1 150.4(6) . 2_646
O2 C1 O1 121.2(8) . .
O2 C1 C2 118.4(7) . .
O1 C1 C2 120.4(8) . .
O2 C1 Eu2 41.8(4) . 2_656
O1 C1 Eu2 81.8(5) . 2_656
C2 C1 Eu2 153.8(6) . 2_656
C7 C2 C3 118.7(7) . .
C7 C2 C1 120.2(7) . .
C3 C2 C1 120.9(7) . .
C4 C3 C2 120.3(7) . .
C4 C3 H1 119.8 . .
C2 C3 H1 119.8 . .
C5 C4 C3 120.1(8) . .
C5 C4 H2 119.9 . .
C3 C4 H2 119.9 . .
O3 C5 C4 115.5(7) . .
O3 C5 C6 124.0(7) . .
C4 C5 C6 120.5(7) . .
C7 C6 C5 118.6(7) . .
C7 C6 H3 120.7 . .
C5 C6 H3 120.7 . .
C2 C7 C6 121.7(7) . .
C2 C7 H4 119.2 . .
C6 C7 H4 119.2 . .
C13 C8 C9 121.1(6) . .
C13 C8 O3 116.8(7) . .
C9 C8 O3 121.8(8) . .
C8 C9 C10 119.5(7) . .
C8 C9 H8 120.2 . .
C10 C9 H8 120.2 . .
C9 C10 C11 119.7(7) . .
C9 C10 H7 120.2 . .
C11 C10 H7 120.2 . .
C12 C11 C10 120.5(6) . .
C12 C11 C14 120.0(6) . .
C10 C11 C14 119.5(6) . .
C11 C12 C13 119.6(7) . .
C11 C12 H6 120.2 . .
C13 C12 H6 120.2 . .
C8 C13 C12 119.5(7) . .
C8 C13 H5 120.2 . .
C12 C13 H5 120.2 . .
O4 C14 O5 120.5(6) . .
O4 C14 C11 121.2(6) . .
O5 C14 C11 118.3(6) . .
O4 C14 Eu1 59.8(3) . .
O5 C14 Eu1 61.5(3) . .
C11 C14 Eu1 169.1(4) . .
O7 C15 O6 123.7(7) . .
O7 C15 C16 117.3(7) . .
O6 C15 C16 118.9(7) . .
C17 C16 C21 118.1(7) . .
C17 C16 C15 120.7(6) . .
C21 C16 C15 121.3(7) . .
C16 C17 C18 120.9(7) . .
C16 C17 H12 119.5 . .
C18 C17 H12 119.5 . .
C19 C18 C17 119.9(7) . .
C19 C18 H11 120.1 . .
C17 C18 H11 120.1 . .
C18 C19 C20 120.5(7) . .
C18 C19 O8 115.2(7) . .
C20 C19 O8 124.2(7) . .
C19 C20 C21 118.7(7) . .
C19 C20 H10 120.6 . .
C21 C20 H10 120.6 . .
C20 C21 C16 121.8(7) . .
C20 C21 H9 119.1 . .
C16 C21 H9 119.1 . .
C27 C22 C23 120.8(7) . .
C27 C22 O8 121.1(8) . .
C23 C22 O8 117.8(9) . .
C24 C23 C22 119.3(8) . .
C24 C23 H13 120.3 . .
C22 C23 H13 120.3 . .
C23 C24 C25 120.2(8) . .
C23 C24 H14 119.9 . .
C25 C24 H14 119.9 . .
C26 C25 C24 119.7(7) . .
C26 C25 C28 119.8(7) . .
C24 C25 C28 120.4(7) . .
C25 C26 C27 119.4(9) . .
C25 C26 H15 120.3 . .
C27 C26 H15 120.3 . .
C22 C27 C26 120.6(8) . .
C22 C27 H16 119.7 . .
C26 C27 H16 119.7 . .
O9 C28 O10 123.5(8) . .
O9 C28 C25 118.2(7) . .
O10 C28 C25 118.2(7) . .
O12 C29 O11 122.2(7) . .
O12 C29 C30 118.1(7) . .
O11 C29 C30 119.7(7) . .
C35 C30 C31 118.8(7) . .
C35 C30 C29 121.1(7) . .
C31 C30 C29 120.0(7) . .
C32 C31 C30 120.3(8) . .
C32 C31 H20 119.8 . .
C30 C31 H20 119.8 . .
C33 C32 C31 119.2(8) . .
C33 C32 H19 120.4 . .
C31 C32 H19 120.4 . .
C32 C33 C34 121.4(8) . .
C32 C33 O13 116.0(8) . .
C34 C33 O13 122.2(9) . .
C33 C34 C35 119.3(9) . .
C33 C34 H18 120.3 . .
C35 C34 H18 120.3 . .
C30 C35 C34 120.8(8) . .
C30 C35 H17 119.6 . .
C34 C35 H17 119.6 . .
C41 C36 C37 121.7(8) . .
C41 C36 O13 119.7(10) . .
C37 C36 O13 118.4(9) . .
C36 C37 C38 118.9(9) . .
C36 C37 H24 120.5 . .
C38 C37 H24 120.5 . .
C39 C38 C37 119.5(9) . .
C39 C38 H23 120.3 . .
C37 C38 H23 120.3 . .
C38 C39 C40 119.8(8) . .
C38 C39 C42 121.5(8) . .
C40 C39 C42 118.7(7) . .
C41 C40 C39 121.2(9) . .
C41 C40 H22 119.4 . .
C39 C40 H22 119.4 . .
C36 C41 C40 118.6(10) . .
C36 C41 H21 120.7 . .
C40 C41 H21 120.7 . .
O15 C42 O14 124.9(8) . .
O15 C42 C39 119.1(7) . .
O14 C42 C39 116.0(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.324(5) .
Eu1 O11 2.351(5) .
Eu1 O15 2.356(6) 2_656
Eu1 O1W 2.444(6) .
Eu1 O2W 2.449(6) .
Eu1 O5 2.513(5) 3_657
Eu1 O4 2.526(5) .
Eu1 O5 2.562(5) .
Eu1 C14 2.914(6) .
Eu1 Eu1 4.1885(9) 3_657
Eu2 O12 2.292(6) .
Eu2 O14 2.300(6) 2_656
Eu2 O1 2.346(7) 4_565
Eu2 O2 2.401(6) 2_646
Eu2 O10 2.459(6) 4
Eu2 O5W 2.478(7) .
Eu2 O4W 2.511(8) .
Eu2 O3W 2.663(14) .
Eu2 C1 3.189(8) 2_646
O1 C1 1.261(11) .
O1 Eu2 2.346(7) 4_566
O1W H1W 0.8200 .
O2 C1 1.259(11) .
O2 Eu2 2.401(6) 2_656
O2W H2W 0.8200 .
O3 C5 1.368(9) .
O3 C8 1.397(8) .
O3W H3W 0.8200 .
O4 C14 1.259(8) .
O4W H4W 0.8200 .
O5 C14 1.297(8) .
O5 Eu1 2.513(5) 3_657
O5W H5W 0.8200 .
O6 C15 1.259(10) .
O7 C15 1.251(9) .
O8 C22 1.394(9) .
O8 C19 1.399(9) .
O9 C28 1.234(9) .
O10 C28 1.280(10) .
O10 Eu2 2.459(6) 4_556
O11 C29 1.267(9) .
O12 C29 1.241(10) .
O13 C33 1.389(10) .
O13 C36 1.394(10) .
O14 C42 1.258(10) .
O14 Eu2 2.300(6) 2_646
O15 C42 1.237(9) .
O15 Eu1 2.356(6) 2_646
C1 C2 1.489(10) .
C1 Eu2 3.189(8) 2_656
C2 C7 1.391(10) .
C2 C3 1.393(11) .
C3 C4 1.392(11) .
C3 H1 0.9300 .
C4 C5 1.385(11) .
C4 H2 0.9300 .
C5 C6 1.395(10) .
C6 C7 1.392(10) .
C6 H3 0.9300 .
C7 H4 0.9300 .
C8 C13 1.385(12) .
C8 C9 1.382(12) .
C9 C10 1.385(10) .
C9 H8 0.9300 .
C10 C11 1.397(10) .
C10 H7 0.9300 .
C11 C12 1.384(10) .
C11 C14 1.502(8) .
C12 C13 1.392(10) .
C12 H6 0.9300 .
C13 H5 0.9300 .
C15 C16 1.498(9) .
C16 C17 1.383(11) .
C16 C21 1.390(10) .
C17 C18 1.388(11) .
C17 H12 0.9300 .
C18 C19 1.377(10) .
C18 H11 0.9300 .
C19 C20 1.384(11) .
C20 C21 1.386(11) .
C20 H10 0.9300 .
C21 H9 0.9300 .
C22 C27 1.356(14) .
C22 C23 1.394(12) .
C23 C24 1.382(12) .
C23 H13 0.9300 .
C24 C25 1.393(11) .
C24 H14 0.9300 .
C25 C26 1.390(11) .
C25 C28 1.522(10) .
C26 C27 1.393(13) .
C26 H15 0.9300 .
C27 H16 0.9300 .
C29 C30 1.483(10) .
C30 C35 1.377(11) .
C30 C31 1.398(11) .
C31 C32 1.386(11) .
C31 H20 0.9300 .
C32 C33 1.366(13) .
C32 H19 0.9300 .
C33 C34 1.371(13) .
C34 C35 1.383(12) .
C34 H18 0.9300 .
C35 H17 0.9300 .
C36 C41 1.369(15) .
C36 C37 1.369(15) .
C37 C38 1.413(14) .
C37 H24 0.9300 .
C38 C39 1.363(12) .
C38 H23 0.9300 .
C39 C40 1.385(12) .
C39 C42 1.502(10) .
C40 C41 1.373(13) .
C40 H22 0.9300 .
C41 H21 0.9300 .
