#------------------------------------------------------------------------------
#$Date: 2017-03-04 15:11:13 +0200 (Sat, 04 Mar 2017) $
#$Revision: 193425 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/51/4345171.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345171
loop_
_publ_author_name
'Yang, Dandan'
'Tian, Yun'
'Xu, Wenlong'
'Cao, Xiaowei'
'Zheng, Shaojun'
'Ju, Qiang'
'Huang, Wei'
'Fang, Zhenlan'
_publ_section_title
;
 A Series of Lanthanide-Based Metal-Organic Frameworks: Synthesis,
 Structures, and Multicolor Tuning of Single Component.
;
_journal_issue                   4
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2345
_journal_page_last               2353
_journal_paper_doi               10.1021/acs.inorgchem.7b00074
_journal_volume                  56
_journal_year                    2017
_chemical_formula_sum            'C84 H58 Dy4 O39'
_chemical_formula_weight         2341.30
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 117.618(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.6550(17)
_cell_length_b                   29.042(6)
_cell_length_c                   18.670(3)
_cell_measurement_reflns_used    9791
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      34.03
_cell_measurement_theta_min      2.44
_cell_volume                     4158.1(14)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0641
_diffrn_reflns_av_sigmaI/netI    0.0646
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -42
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            44373
_diffrn_reflns_theta_full        31.05
_diffrn_reflns_theta_max         31.05
_diffrn_reflns_theta_min         1.40
_exptl_absorpt_coefficient_mu    3.649
_exptl_absorpt_correction_T_max  0.856
_exptl_absorpt_correction_T_min  0.693
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.870
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       sheet
_exptl_crystal_F_000             2276
_refine_diff_density_max         3.415
_refine_diff_density_min         -2.481
_refine_diff_density_rms         0.275
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     572
_refine_ls_number_reflns         13271
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0942
_refine_ls_R_factor_gt           0.0603
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0992P)²+25.2999P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1734
_refine_ls_wR_factor_ref         0.1947
_reflns_number_gt                9749
_reflns_number_total             13271
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic7b00074_si_004.cif
_cod_data_source_block           d:IAM16-5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 4345169--4345171.cif.
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               4345171
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.23549(4) -0.014295(9) 0.426966(18) 0.02260(9) Uani 1 1 d .
Dy2 Dy -0.27700(5) -0.009978(10) 0.12927(2) 0.03285(11) Uani 1 1 d .
O5 O 0.4651(6) 0.04830(14) 0.4951(3) 0.0251(9) Uani 1 1 d .
O4 O 0.2375(6) 0.05055(15) 0.5172(3) 0.0288(10) Uani 1 1 d .
O3 O 0.5978(8) 0.24456(16) 0.6604(3) 0.0488(16) Uani 1 1 d .
O14 O 0.0714(10) -0.4556(2) 0.2986(4) 0.0600(19) Uani 1 1 d .
O1W O -0.0689(7) -0.0182(2) 0.3992(4) 0.0467(15) Uani 1 1 d .
H1W H -0.0748 -0.0300 0.4377 0.070 Uiso 1 1 calc R
O11 O 0.1343(7) -0.07827(18) 0.3404(4) 0.0402(13) Uani 1 1 d .
O1 O 0.5183(10) 0.45435(19) 0.5546(5) 0.0601(19) Uani 1 1 d .
O10 O 0.4749(8) -0.44439(18) 0.6147(3) 0.0397(13) Uani 1 1 d .
O7 O 0.2299(7) -0.05732(17) 0.5304(3) 0.0355(11) Uani 1 1 d .
O15 O -0.0756(9) -0.4562(2) 0.1654(4) 0.0470(15) Uani 1 1 d .
O13 O -0.3030(8) -0.26363(18) 0.2407(6) 0.070(2) Uani 1 1 d .
O2W O 0.3834(8) -0.0055(2) 0.3442(3) 0.0400(13) Uani 1 1 d .
H2W H 0.4309 0.0197 0.3527 0.060 Uiso 1 1 calc R
O2 O 0.2904(9) 0.4255(2) 0.4522(4) 0.0482(15) Uani 1 1 d .
O9 O 0.4214(12) -0.4482(2) 0.7193(5) 0.072(3) Uani 1 1 d .
O8 O 0.0248(7) -0.26213(18) 0.5607(5) 0.0544(18) Uani 1 1 d .
O12 O -0.1021(10) -0.05712(19) 0.2327(4) 0.060(2) Uani 1 1 d .
O6 O 0.4336(10) -0.0709(2) 0.6547(4) 0.067(2) Uani 1 1 d .
O5W O -0.3503(13) 0.0137(3) 0.2355(5) 0.078(3) Uani 1 1 d .
H5W H -0.4205 -0.0045 0.2375 0.116 Uiso 1 1 calc R
O4W O -0.1883(11) 0.0224(4) 0.0312(5) 0.092(4) Uani 1 1 d .
H4W H -0.2750 0.0312 -0.0092 0.139 Uiso 1 1 calc R
C5 C 0.5482(9) 0.2860(2) 0.6213(4) 0.0307(14) Uani 1 1 d .
C10 C 0.4989(9) 0.1465(2) 0.5226(4) 0.0286(13) Uani 1 1 d .
H7 H 0.5167 0.1369 0.4795 0.034 Uiso 1 1 calc R
C2 C 0.4652(10) 0.3740(2) 0.5565(4) 0.0298(14) Uani 1 1 d .
C16 C 0.2335(8) -0.1305(2) 0.5847(4) 0.0239(12) Uani 1 1 d .
C7 C 0.3528(10) 0.3376(2) 0.5198(4) 0.0321(15) Uani 1 1 d .
H4 H 0.2493 0.3428 0.4729 0.039 Uiso 1 1 calc R
C8 C 0.5264(9) 0.2038(2) 0.6198(4) 0.0324(15) Uani 1 1 d .
C6 C 0.3918(9) 0.2933(2) 0.5516(5) 0.0342(16) Uani 1 1 d .
H3 H 0.3149 0.2691 0.5268 0.041 Uiso 1 1 calc R
C39 C -0.0892(9) -0.3895(2) 0.2349(4) 0.0319(15) Uani 1 1 d .
C11 C 0.4245(8) 0.11676(19) 0.5560(4) 0.0203(11) Uani 1 1 d .
C1 C 0.4224(11) 0.4210(2) 0.5192(5) 0.0358(16) Uani 1 1 d .
C25 C 0.3036(10) -0.3847(2) 0.6312(4) 0.0297(14) Uani 1 1 d .
C14 C 0.3721(8) 0.06922(18) 0.5221(4) 0.0194(11) Uani 1 1 d .
C15 C 0.3032(10) -0.0827(2) 0.5909(4) 0.0291(14) Uani 1 1 d .
C29 C -0.0113(10) -0.0870(2) 0.2818(4) 0.0335(15) Uani 1 1 d .
C12 C 0.3967(9) 0.1307(2) 0.6197(4) 0.0293(13) Uani 1 1 d .
H6 H 0.3415 0.1113 0.6402 0.035 Uiso 1 1 calc R
C33 C -0.2159(10) -0.2225(2) 0.2486(6) 0.0411(19) Uani 1 1 d .
C36 C -0.2168(10) -0.3042(2) 0.2424(6) 0.043(2) Uani 1 1 d .
C31 C -0.2377(11) -0.1455(2) 0.2017(5) 0.0399(18) Uani 1 1 d .
H20 H -0.2982 -0.1229 0.1637 0.048 Uiso 1 1 calc R
C30 C -0.0790(9) -0.1351(2) 0.2684(4) 0.0282(13) Uani 1 1 d .
C21 C 0.3308(10) -0.1645(3) 0.6395(5) 0.0382(17) Uani 1 1 d .
H9 H 0.4388 -0.1571 0.6822 0.046 Uiso 1 1 calc R
C28 C 0.4046(11) -0.4291(2) 0.6568(5) 0.0366(17) Uani 1 1 d .
C13 C 0.4523(10) 0.1744(2) 0.6530(5) 0.0359(16) Uani 1 1 d .
H5 H 0.4392 0.1836 0.6976 0.043 Uiso 1 1 calc R
C18 C 0.0042(9) -0.1861(2) 0.5172(5) 0.0400(18) Uani 1 1 d .
H11 H -0.1071 -0.1931 0.4769 0.048 Uiso 1 1 calc R
C17 C 0.0699(10) -0.1415(2) 0.5234(5) 0.0372(17) Uani 1 1 d .
H12 H 0.0035 -0.1191 0.4862 0.045 Uiso 1 1 calc R
C4 C 0.6643(11) 0.3218(2) 0.6574(5) 0.043(2) Uani 1 1 d .
H2 H 0.7704 0.3164 0.7028 0.052 Uiso 1 1 calc R
C35 C 0.0097(11) -0.1693(3) 0.3232(6) 0.045(2) Uani 1 1 d .
H17 H 0.1153 -0.1626 0.3681 0.054 Uiso 1 1 calc R
C20 C 0.2696(10) -0.2093(3) 0.6316(5) 0.0404(18) Uani 1 1 d .
H10 H 0.3387 -0.2322 0.6666 0.049 Uiso 1 1 calc R
C24 C 0.2266(10) -0.3661(3) 0.6758(5) 0.0368(16) Uani 1 1 d .
H14 H 0.2343 -0.3817 0.7208 0.044 Uiso 1 1 calc R
C3 C 0.6211(11) 0.3657(2) 0.6251(5) 0.0424(19) Uani 1 1 d .
H1 H 0.6978 0.3899 0.6499 0.051 Uiso 1 1 calc R
C42 C -0.0263(10) -0.4375(2) 0.2311(5) 0.0350(15) Uani 1 1 d .
C23 C 0.1391(11) -0.3248(3) 0.6535(5) 0.0411(18) Uani 1 1 d .
H13 H 0.0883 -0.3124 0.6835 0.049 Uiso 1 1 calc R
C40 C -0.1081(15) -0.3766(3) 0.3012(5) 0.056(3) Uani 1 1 d .
H22 H -0.0756 -0.3970 0.3442 0.067 Uiso 1 1 calc R
C37 C -0.1912(12) -0.3152(3) 0.1774(6) 0.052(2) Uani 1 1 d .
H24 H -0.2153 -0.2938 0.1365 0.063 Uiso 1 1 calc R
C26 C 0.2896(12) -0.3612(3) 0.5638(5) 0.0433(19) Uani 1 1 d .
H15 H 0.3412 -0.3732 0.5339 0.052 Uiso 1 1 calc R
C34 C -0.0570(12) -0.2136(3) 0.3121(7) 0.058(3) Uani 1 1 d .
H18 H 0.0062 -0.2370 0.3477 0.069 Uiso 1 1 calc R
C9 C 0.5468(10) 0.1906(2) 0.5533(5) 0.0335(15) Uani 1 1 d .
H8 H 0.5920 0.2111 0.5295 0.040 Uiso 1 1 calc R
C22 C 0.1271(9) -0.3017(2) 0.5857(5) 0.0364(17) Uani 1 1 d .
C32 C -0.3053(11) -0.1898(3) 0.1919(5) 0.0428(19) Uani 1 1 d .
H19 H -0.4105 -0.1970 0.1472 0.051 Uiso 1 1 calc R
C27 C 0.2000(13) -0.3201(3) 0.5409(6) 0.048(2) Uani 1 1 d .
H16 H 0.1889 -0.3049 0.4949 0.058 Uiso 1 1 calc R
C38 C -0.1283(12) -0.3588(3) 0.1736(5) 0.0442(19) Uani 1 1 d .
H23 H -0.1129 -0.3670 0.1291 0.053 Uiso 1 1 calc R
C41 C -0.1737(15) -0.3344(3) 0.3052(6) 0.060(3) Uani 1 1 d .
H21 H -0.1889 -0.3264 0.3498 0.072 Uiso 1 1 calc R
C19 C 0.1040(9) -0.2195(2) 0.5708(5) 0.0294(14) Uani 1 1 d .
O3W O 0.030(2) -0.0279(7) 0.1335(11) 0.082(5) Uiso 0.50 1 d P
H3W H 0.0866 -0.0451 0.1715 0.123 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Dy1 O11 90.1(2) . .
O7 Dy1 O15 139.9(2) . 2
O11 Dy1 O15 99.1(2) . 2
O7 Dy1 O2W 143.6(2) . .
O11 Dy1 O2W 77.51(19) . .
O15 Dy1 O2W 76.3(2) 2 .
O7 Dy1 O1W 73.45(19) . .
O11 Dy1 O1W 78.2(2) . .
O15 Dy1 O1W 70.5(2) 2 .
O2W Dy1 O1W 134.7(2) . .
O7 Dy1 O5 73.72(17) . 3_656
O11 Dy1 O5 92.48(17) . 3_656
O15 Dy1 O5 143.67(19) 2 3_656
O2W Dy1 O5 72.79(19) . 3_656
O1W Dy1 O5 145.79(17) . 3_656
O7 Dy1 O4 80.94(17) . .
O11 Dy1 O4 159.27(17) . .
O15 Dy1 O4 76.9(2) 2 .
O2W Dy1 O4 120.22(16) . .
O1W Dy1 O4 81.3(2) . .
O5 Dy1 O4 102.76(15) 3_656 .
O7 Dy1 O5 106.29(17) . .
O11 Dy1 O5 149.43(17) . .
O15 Dy1 O5 84.9(2) 2 .
O2W Dy1 O5 74.04(16) . .
O1W Dy1 O5 130.72(19) . .
O5 Dy1 O5 68.66(15) 3_656 .
O4 Dy1 O5 51.18(14) . .
O7 Dy1 C14 95.73(18) . .
O11 Dy1 C14 173.89(19) . .
O15 Dy1 C14 77.5(2) 2 .
O2W Dy1 C14 96.67(17) . .
O1W Dy1 C14 105.1(2) . .
O5 Dy1 C14 87.47(15) 3_656 .
O4 Dy1 C14 25.27(16) . .
O5 Dy1 C14 26.12(15) . .
O12 Dy2 O14 83.5(2) . 2
O12 Dy2 O1 161.6(3) . 4_465
O14 Dy2 O1 92.4(3) 2 4_465
O12 Dy2 O2 83.4(2) . 2_545
O14 Dy2 O2 135.4(3) 2 2_545
O1 Dy2 O2 111.5(2) 4_465 2_545
O12 Dy2 O10 88.4(2) . 4_455
O14 Dy2 O10 147.9(2) 2 4_455
O1 Dy2 O10 85.6(2) 4_465 4_455
O2 Dy2 O10 73.8(2) 2_545 4_455
O12 Dy2 O5W 78.6(3) . .
O14 Dy2 O5W 75.6(3) 2 .
O1 Dy2 O5W 83.0(3) 4_465 .
O2 Dy2 O5W 141.7(2) 2_545 .
O10 Dy2 O5W 72.3(2) 4_455 .
O12 Dy2 O4W 122.9(3) . .
O14 Dy2 O4W 75.5(3) 2 .
O1 Dy2 O4W 72.8(3) 4_465 .
O2 Dy2 O4W 76.5(3) 2_545 .
O10 Dy2 O4W 133.3(2) 4_455 .
O5W Dy2 O4W 141.2(3) . .
O12 Dy2 O3W 66.2(5) . .
O14 Dy2 O3W 68.1(4) 2 .
O1 Dy2 O3W 128.6(5) 4_465 .
O2 Dy2 O3W 67.6(4) 2_545 .
O10 Dy2 O3W 135.4(4) 4_455 .
O5W Dy2 O3W 131.2(5) . .
O4W Dy2 O3W 56.7(5) . .
C14 O5 Dy1 128.6(4) . 3_656
C14 O5 Dy1 92.7(4) . .
Dy1 O5 Dy1 111.34(15) 3_656 .
C14 O4 Dy1 95.2(4) . .
C5 O3 C8 120.5(6) . .
C42 O14 Dy2 148.4(6) . 2_545
Dy1 O1W H1W 109.5 . .
C29 O11 Dy1 131.6(5) . .
C1 O1 Dy2 173.1(6) . 4_666
C28 O10 Dy2 140.4(5) . 4_656
C15 O7 Dy1 150.9(5) . .
C42 O15 Dy1 150.1(6) . 2_545
C33 O13 C36 118.0(6) . .
Dy1 O2W H2W 109.5 . .
C1 O2 Dy2 118.2(5) . 2
C19 O8 C22 119.6(5) . .
C29 O12 Dy2 172.1(6) . .
Dy2 O5W H5W 109.5 . .
Dy2 O4W H4W 109.5 . .
O3 C5 C4 115.0(6) . .
O3 C5 C6 124.2(6) . .
C4 C5 C6 120.8(6) . .
C9 C10 C11 120.2(6) . .
C9 C10 H7 119.9 . .
C11 C10 H7 119.9 . .
C3 C2 C7 119.0(6) . .
C3 C2 C1 121.0(6) . .
C7 C2 C1 119.9(7) . .
C17 C16 C21 119.0(6) . .
C17 C16 C15 119.9(6) . .
C21 C16 C15 121.1(6) . .
C2 C7 C6 121.2(7) . .
C2 C7 H4 119.4 . .
C6 C7 H4 119.4 . .
C13 C8 O3 117.8(7) . .
C13 C8 C9 120.7(6) . .
O3 C8 C9 121.1(7) . .
C7 C6 C5 118.6(6) . .
C7 C6 H3 120.7 . .
C5 C6 H3 120.7 . .
C38 C39 C40 119.5(7) . .
C38 C39 C42 121.2(7) . .
C40 C39 C42 119.2(7) . .
C12 C11 C10 120.4(6) . .
C12 C11 C14 119.7(5) . .
C10 C11 C14 119.9(6) . .
O1 C1 O2 121.7(7) . .
O1 C1 C2 120.0(8) . .
O2 C1 C2 118.3(7) . .
C26 C25 C24 119.1(7) . .
C26 C25 C28 120.2(7) . .
C24 C25 C28 120.7(6) . .
O4 C14 O5 119.9(5) . .
O4 C14 C11 121.4(5) . .
O5 C14 C11 118.6(5) . .
O4 C14 Dy1 59.5(3) . .
O5 C14 Dy1 61.1(3) . .
C11 C14 Dy1 169.1(4) . .
O7 C15 O6 123.9(6) . .
O7 C15 C16 117.3(6) . .
O6 C15 C16 118.7(6) . .
O12 C29 O11 122.7(7) . .
O12 C29 C30 117.7(7) . .
O11 C29 C30 119.6(7) . .
C11 C12 C13 119.3(7) . .
C11 C12 H6 120.3 . .
C13 C12 H6 120.3 . .
C34 C33 C32 121.5(7) . .
C34 C33 O13 122.6(8) . .
C32 C33 O13 115.7(8) . .
C37 C36 C41 121.3(7) . .
C37 C36 O13 118.9(9) . .
C41 C36 O13 119.5(9) . .
C32 C31 C30 120.0(7) . .
C32 C31 H20 120.0 . .
C30 C31 H20 120.0 . .
C35 C30 C31 119.1(6) . .
C35 C30 C29 120.7(7) . .
C31 C30 C29 120.1(6) . .
C20 C21 C16 121.1(7) . .
C20 C21 H9 119.4 . .
C16 C21 H9 119.4 . .
O9 C28 O10 122.9(7) . .
O9 C28 C25 118.6(7) . .
O10 C28 C25 118.4(6) . .
C8 C13 C12 120.0(7) . .
C8 C13 H5 120.0 . .
C12 C13 H5 120.0 . .
C19 C18 C17 120.0(7) . .
C19 C18 H11 120.0 . .
C17 C18 H11 120.0 . .
C16 C17 C18 120.2(6) . .
C16 C17 H12 119.9 . .
C18 C17 H12 119.9 . .
C5 C4 C3 119.4(7) . .
C5 C4 H2 120.3 . .
C3 C4 H2 120.3 . .
C30 C35 C34 120.6(8) . .
C30 C35 H17 119.7 . .
C34 C35 H17 119.7 . .
C21 C20 C19 119.1(7) . .
C21 C20 H10 120.4 . .
C19 C20 H10 120.4 . .
C23 C24 C25 120.4(7) . .
C23 C24 H14 119.8 . .
C25 C24 H14 119.8 . .
C2 C3 C4 120.9(7) . .
C2 C3 H1 119.5 . .
C4 C3 H1 119.5 . .
O15 C42 O14 125.4(7) . .
O15 C42 C39 119.3(7) . .
O14 C42 C39 115.2(6) . .
C24 C23 C22 119.5(7) . .
C24 C23 H13 120.3 . .
C22 C23 H13 120.3 . .
C41 C40 C39 121.3(8) . .
C41 C40 H22 119.4 . .
C39 C40 H22 119.4 . .
C36 C37 C38 118.9(8) . .
C36 C37 H24 120.5 . .
C38 C37 H24 120.5 . .
C27 C26 C25 120.5(8) . .
C27 C26 H15 119.7 . .
C25 C26 H15 119.7 . .
C33 C34 C35 119.4(8) . .
C33 C34 H18 120.3 . .
C35 C34 H18 120.3 . .
C10 C9 C8 119.2(6) . .
C10 C9 H8 120.4 . .
C8 C9 H8 120.4 . .
C27 C22 C23 120.5(7) . .
C27 C22 O8 121.3(8) . .
C23 C22 O8 118.0(8) . .
C33 C32 C31 119.3(7) . .
C33 C32 H19 120.3 . .
C31 C32 H19 120.3 . .
C22 C27 C26 120.1(8) . .
C22 C27 H16 120.0 . .
C26 C27 H16 120.0 . .
C39 C38 C37 120.1(9) . .
C39 C38 H23 120.0 . .
C37 C38 H23 120.0 . .
C40 C41 C36 118.8(9) . .
C40 C41 H21 120.6 . .
C36 C41 H21 120.6 . .
C18 C19 O8 115.3(6) . .
C18 C19 C20 120.5(6) . .
O8 C19 C20 124.1(6) . .
Dy2 O3W H3W 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O7 2.319(5) .
Dy1 O11 2.350(5) .
Dy1 O15 2.351(5) 2
Dy1 O2W 2.435(6) .
Dy1 O1W 2.440(6) .
Dy1 O5 2.513(5) 3_656
Dy1 O4 2.521(5) .
Dy1 O5 2.555(4) .
Dy1 C14 2.914(6) .
Dy2 O12 2.277(6) .
Dy2 O14 2.293(6) 2
Dy2 O1 2.324(7) 4_465
Dy2 O2 2.383(6) 2_545
Dy2 O10 2.429(5) 4_455
Dy2 O5W 2.444(7) .
Dy2 O4W 2.475(9) .
Dy2 O3W 2.671(18) .
O5 C14 1.284(7) .
O5 Dy1 2.513(5) 3_656
O4 C14 1.249(7) .
O3 C5 1.369(8) .
O3 C8 1.387(7) .
O14 C42 1.260(10) .
O14 Dy2 2.293(6) 2_545
O1W H1W 0.8200 .
O11 C29 1.253(9) .
O1 C1 1.248(10) .
O1 Dy2 2.324(7) 4_666
O10 C28 1.275(9) .
O10 Dy2 2.429(5) 4_656
O7 C15 1.247(8) .
O15 C42 1.223(9) .
O15 Dy1 2.351(5) 2_545
O13 C33 1.383(9) .
O13 C36 1.388(9) .
O2W H2W 0.8200 .
O2 C1 1.249(10) .
O2 Dy2 2.383(6) 2
O9 C28 1.239(9) .
O8 C19 1.385(8) .
O8 C22 1.394(8) .
O12 C29 1.242(9) .
O6 C15 1.250(9) .
O5W H5W 0.8200 .
O4W H4W 0.8200 .
C5 C4 1.385(9) .
C5 C6 1.392(9) .
C10 C9 1.384(9) .
C10 C11 1.387(9) .
C10 H7 0.9300 .
C2 C3 1.384(11) .
C2 C7 1.384(9) .
C2 C1 1.499(9) .
C16 C17 1.383(10) .
C16 C21 1.390(9) .
C16 C15 1.499(9) .
C7 C6 1.392(9) .
C7 H4 0.9300 .
C8 C13 1.375(11) .
C8 C9 1.388(11) .
C6 H3 0.9300 .
C39 C38 1.363(11) .
C39 C40 1.373(11) .
C39 C42 1.512(9) .
C11 C12 1.379(9) .
C11 C14 1.498(8) .
C25 C26 1.388(10) .
C25 C24 1.393(10) .
C25 C28 1.505(9) .
C29 C30 1.490(9) .
C12 C13 1.396(9) .
C12 H6 0.9300 .
C33 C34 1.361(13) .
C33 C32 1.365(11) .
C36 C37 1.368(14) .
C36 C41 1.370(13) .
C31 C32 1.389(10) .
C31 C30 1.395(10) .
C31 H20 0.9300 .
C30 C35 1.377(10) .
C21 C20 1.386(10) .
C21 H9 0.9300 .
C13 H5 0.9300 .
C18 C19 1.374(9) .
C18 C17 1.397(10) .
C18 H11 0.9300 .
C17 H12 0.9300 .
C4 C3 1.385(10) .
C4 H2 0.9300 .
C35 C34 1.386(11) .
C35 H17 0.9300 .
C20 C19 1.387(10) .
C20 H10 0.9300 .
C24 C23 1.377(10) .
C24 H14 0.9300 .
C3 H1 0.9300 .
C23 C22 1.393(12) .
C23 H13 0.9300 .
C40 C41 1.368(11) .
C40 H22 0.9300 .
C37 C38 1.395(12) .
C37 H24 0.9300 .
C26 C27 1.377(11) .
C26 H15 0.9300 .
C34 H18 0.9300 .
C9 H8 0.9300 .
C22 C27 1.368(12) .
C32 H19 0.9300 .
C27 H16 0.9300 .
C38 H23 0.9300 .
C41 H21 0.9300 .
O3W H3W 0.8200 .
